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Experiment #3 / Unit 6 Calorimetry - Measuring Heat Changes During A Physical or Chemical Change

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Experiment #3 / Unit 6

Calorimetry - Measuring Heat Changes During a Physical or Chemical Change

Introduction:
Physical and chemical changes are accompanied by energy changes. This
energy change normally involves heat. Physical and chemical changes may result in
an intake of heat and cause the temperature of the surroundings to decrease (an
endothermic change) or a release of heat that causes the temperature of the
surroundings to increase (an exothermic change). "Calorimetry" is the experimental
technique used to measure the heat gained/released in a physical or chemical
change. Calorimetry is an indirect method because a temperature change can not be
measured directly by putting a thermometer inside shuffling atoms. Calorimetry
employs water as a heat sink which either provides the heat to an endothermic
change or catches the heat produced by an exothermic change. The key to the
technique is that it is easy to measure the temperature change and subsequent heat
loss/gain for water. In this experiment, we will practice the technique of calorimetry by
using a crude calorimeter system to measure the heat changes involved in the
dissociation of ammonium chloride or ammonium nitrate (physical change) and the
reaction of magnesium with hydrochloric acid.

Procedure:
Dissociation of an Ammonium Compound
1. Obtain a coffee cup.
2. Measure 50.x mL of tap water in a graduated cylinder and pour into the
calorimeter. Set the cup in a beaker to stabilize it.
3. Mass 7-10 g of the ammonium salt (you choose between ammonium chloride and
ammonium nitrate) in a massing boat.
4. Obtain a thermometer and record the initial temperature of the water.
5. Add the salt and gently stir the solution with the thermometer and record the lowest
temperature reached. Make sure all the solid has dissociated.
6. Pour the solution into the recycle bucket and rinse the cup.

Reaction of a Metal with Acid


1. Obtain a coffee cup.
2. Measure 50.x mL of 0.50 M hydrochloric acid in a graduated cylinder and pour into
the calorimeter. Set the cup in a beaker to stabilize it.
3. Cut approximately 15 cm of Mg ribbon and mass it.
4. Obtain a thermometer and record the initial temperature of the water.
5. Add the metal and gently stir the solution with the thermometer and record the
highest temperature reached.
6. Dispose of the solution.

Chemistry Raleigh Charter High School Dr. Genez


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Data:
Dissociation of an Ammonium Compound
 volume of water
 identity of salt
 mass of ammonium salt
 initial temperature of the water
 lowest temperature reached by the solution

Reaction of a Metal with Acid


 volume of acid
 mass of magnesium
 initial temperature of the acid solution
 highest temperature reached by the solution

Calculations and Questions:


Dissociation of an Ammonium Compound
1. Write an equation for the dissociation of the salt. Include heat as a product/reactant
as appropriate.
2. Calculate the mass of the solution.
3. Calculate the heat lost by the solution in calories. Use 0.925 cal/g x oC as the
specific heat capacity of the solution.
4. How many calories did the dissociation process absorb?
5. Calculate the heat of solution (Hsoln) in kJ/mol for the ammonium salt.
6. Calculate the percent error for the experiment. The accepted value for the Hsoln of
NH4NO3 is +26.0 kJ/mol and NH4Cl is +16.0 kJ/mol.

Reaction of a Metal with Acid


1. Write both a total molecular and net ionic equation for the reaction. Include heat as
a product/reactant as appropriate..
2. Calculate the mass of the solution. Use 1.01 g/mL as the density of 0.50 M HCl.
3. Calculate the heat gained by the solution in calories. Use 0.952 cal/g x oC as its
specific heat capacity.
4. How many calories did the reaction produce?
5. Calculate the heat of reaction (Hrxn) in kcal/mol for the magnesium.
6. Calculate the percent error for the experiment. The accepted value for the Hrxn of
Mg is -110.41 kcal/mol.

Lab Report #6.3:


 title page
 procedure sheet
 data
 calculations and questions

Chemistry Raleigh Charter High School Dr. Genez


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