Experiment #3 / Unit 6 Calorimetry - Measuring Heat Changes During A Physical or Chemical Change
Experiment #3 / Unit 6 Calorimetry - Measuring Heat Changes During A Physical or Chemical Change
Experiment #3 / Unit 6 Calorimetry - Measuring Heat Changes During A Physical or Chemical Change
Introduction:
Physical and chemical changes are accompanied by energy changes. This
energy change normally involves heat. Physical and chemical changes may result in
an intake of heat and cause the temperature of the surroundings to decrease (an
endothermic change) or a release of heat that causes the temperature of the
surroundings to increase (an exothermic change). "Calorimetry" is the experimental
technique used to measure the heat gained/released in a physical or chemical
change. Calorimetry is an indirect method because a temperature change can not be
measured directly by putting a thermometer inside shuffling atoms. Calorimetry
employs water as a heat sink which either provides the heat to an endothermic
change or catches the heat produced by an exothermic change. The key to the
technique is that it is easy to measure the temperature change and subsequent heat
loss/gain for water. In this experiment, we will practice the technique of calorimetry by
using a crude calorimeter system to measure the heat changes involved in the
dissociation of ammonium chloride or ammonium nitrate (physical change) and the
reaction of magnesium with hydrochloric acid.
Procedure:
Dissociation of an Ammonium Compound
1. Obtain a coffee cup.
2. Measure 50.x mL of tap water in a graduated cylinder and pour into the
calorimeter. Set the cup in a beaker to stabilize it.
3. Mass 7-10 g of the ammonium salt (you choose between ammonium chloride and
ammonium nitrate) in a massing boat.
4. Obtain a thermometer and record the initial temperature of the water.
5. Add the salt and gently stir the solution with the thermometer and record the lowest
temperature reached. Make sure all the solid has dissociated.
6. Pour the solution into the recycle bucket and rinse the cup.