Riah Kim - Determine The Formula of Hydrated Copper II Sulfate 1
Riah Kim - Determine The Formula of Hydrated Copper II Sulfate 1
Riah Kim - Determine The Formula of Hydrated Copper II Sulfate 1
Ms. Rebancos
DP Chemistry 11
31 October 2017
Determining the Formula of Hydrated Copper(II) Sulfate
Aim:
The aim of this lab is to determine the formula of hydrated copper(II) sulfate by determining the
number of moles of water of crystallization in crystals of a hydrated salt CuSO4·xH2O by
heating it to constant mass in a crucible.
Research Question:
What is the effect of the mass of hydrated copper(II) sulfate on the mass of water lost during the
decomposition process of hydrated copper(II) sulfate measured in grams( ± 0.01 g) when the
heating temperature(same burner, same heating power), the crucible are kept constant and for
each trial the crystal had enough time to be fully decomposed?
Hypothesis:
If the mass of hydrated copper(II) sulfate increases, then the mass of water lost during the
decomposition process would increase as well, due to the law of definite proportions.
Background:
A hydrate is a compound that contains H2O. It is usually in the form of a crystal that can
be heated, and this means that the crystals contain water molecules within their structure in
definite proportions. And the water here, also known as water of crystallization, can be lost by
turning into steam. This usually causes the hydrate to lose its crystalline structure. The substance
that is left over after the hydrate has lost its water is called an anhydrate. By measuring the
compound before heating and after, the amount of water in the original hydrate can be
determined and the formula can be discovered. The formula for the crystal shows the number of
water molecules present per formula unit of crystal, and a dot is put before the water.
Substances that absorb water from the air to form hydrates are called deliquescent.
Hydrates that lose water of crystallization to form the anhydrous substances are called
efflorescent.(“Hydrate | Chemical Compound”) Usually the uptake and loss of water are
reversible processes, and sometimes these processes result in changes in colour. For example,
copper sulfate pentahydrate (CuSO4·5H2O) is blue and anhydrous copper sulfate (CuSO4) is
white.
As mentioned in the previous paragraph, the reaction between anhydrous copper sulfate
and water is reversible: water is driven off from hydrated copper sulfate when heated, so the
forward reaction is endothermic; energy is transferred from the surroundings. The backward
reaction is called exothermic; energy is transferred to the surroundings.(“BBC - GCSE Bitesize:
Reversible Reactions”)
Variables:
Independent mass of hydrated g ( ± 0.01 g) I will put in different amount of
copper(II) sulfate hydrated copper(II) sulfate for each
sample.
Dependent mass of water lost g ( ± 0.01 g) Not manipulated - depends on the
mass of hydrated copper(II) sulfate.
Crucible No unit I will use the same crucible with the
same mass and thickness - so the
thickness of the crucible doesn’t
affect the heating time.
Materials:
Procedure:
1. The empty crucible was weighed, and then between 2.00 g and 3.00 g of hydrated
copper(II) sulfate was weighed and added. All masses were recorded accurate to the
nearest 0.01 g.
2. The crucible was placed on the pipe-clay triangle on the ring clamp fixed to the ring
stand, over the Bunsen burner.
3. The crucible and contents were heated over a medium Bunsen flame so that the water of
crystallisation is driven off steadily. The blue colour of the hydrated compound was
gradually faded to the greyish-white of anhydrous copper(II) sulfate. Overheating
should have been avoided since it might have caused further decomposition, and the
heating should have stopped immediately when the colour starts to blacken. If
overheated, toxic or corrosive fumes might have been evolved.
4. The crucible and contents were cooled. The crucible and contents were re-weighed once
cold.
5. Steps 3 and 4 were repeated until it was heated to constant mass and consistent readings
were being gathered.
Trial 1 39.51
Mass of crucible + lid + It was greyish white, and some
CuSO4(anhydrous) after heating Trial 2 39.51 blueish white were also visible.
Uncertainty Calculation:
- 0.01 ÷ 2.32 = 0.004 g
1. Calculate the molar masses of H2O and CuSO4 (Relative atomic masses: H=1.01,
O=16.00, S=32.06, Cu=63.55).
a. H2O: 2(1.01) + 16.00 = 18.02 (g mol-1)
b. CuSO4: 63.55 + 32.06 + 4(16.00) = 159.61 (g mol-1)
2. Calculate the mass of water driven off, and the mass of anhydrous copper(II) sulfate
formed in your experiment.
a. Mass of water driven off: 0.85 g
b. Mass of anhydrous copper(II) sulfate: 1.47 g
3. Calculate the number of moles of anhydrous copper(II) sulfate formed
a. 1.47 / 159.61 = 0.00921 mol
4. Calculate the number of moles of water driven off.
a. 0.85 / 18.02 = 0.0472 mol
5. Calculate how many moles of water would have been driven off if one mole of
anhydrous copper(II) sulfate had been formed.
a. 0.00921 : 0.0472 = 1 : x
0.0472 = 0.00921 · x
0.0472 ÷ 0.00921 = x
x = 5.12
5.12 moles of water would have been driven off.
6. Determine the formula for hydrated copper(II) sulfate.
a. CuSO4 · 5.12H2O ≈ CuSO4 · 5H2O
My research question was what the effect of the mass of hydrated copper(II) sulfate on
the mass of water lost during the decomposition process of hydrated copper(II) sulfate
measured in grams( ± 0.01 g) is when the heating temperature(same burner, same heating
power), the crucible are kept constant and for each trial the crystal had enough time to be fully
decomposed. My hypothesis was that if the mass of hydrated copper(II) sulfate increases, then
the mass of water lost during the decomposition process would increase as well, due to the law
of definite proportions. My hypothesis was not so supported with the data I currently have,
since I have only done one trial. But theoretically, my hypothesis to the research question
would be supported due to the law of definite proportions. The Law of Definite Proportions is
a rule that states that a hydrate always contains the same exact proportion of salt and water by
mass(Law of definite proportions | Chemistry). For this experiment, I only did one trial using
2.32 grams of hydrated copper(II) sulfate. According to the data that I gathered, hydrated
copper(II) sulfate weighed less after the decomposition, becoming anhydrous copper(II) sulfate.
Before the heating process, CuSO4·xH2O without the crucible weighed 2.32 g, and after the
reaction, CuSO4 weighed 1.47 g. This means that 0.86 g of water was “burned off” after the
decomposition. So the conclusion that can be drawn from this experiment would be that water
was lost after the decomposition due to the heat, resulting in the loss of mass.
Evaluation:
After calculating the number of moles of anhydrous copper(II) sulfate formed and the
number of moles of water driven off, I was able to calculate how many moles of water would
have been driven off if one mole of anhydrous copper(II) sulfate had been formed. The result I
got from this would be the value of coefficient(x) in CuSO4·xH2O. The number that I got was
5.12, meaning that 5.12 moles of water would have driven off. So my final formula would be
CuSO4·5.12H2O. If I round it off to one significant figure, it would be approximately
CuSO4·5H2O, which is the correct formula for copper(II) sulfate pentahydrate(Pubchem). Even
though the value is approximately the same as the theoretical value, there still is an error range
of 0.12 moles.
When I calculated my percentage error, I got 2.4%. By looking at this, I would conclude
that my data were accurate. The reason why the percentage error was not 0% would be because
some of the crystal might have been removed or added when it was stirred, to break down
small clods, by a wooden stick. Some crystals could have stuck to the stick and therefore
removed from the crucible, and those removed crystals might have been re-added to the
crystals in the crucible later when it was stirred again, making the mass not constant. The
uncertainty values of CuSO4·XH2O, CuSO4 and H2O lost after heating were 0.004g, 0.007g,
and 0.012g. The values are generally low, which make my data highly credible.
The strength of my investigation was that when I measured the mass of the crystal twice,
I got the same value, 39.51 g, for both, meaning the hydrated copper(II) sulfate was fully
decomposed and H2O was evaporated fully. Another strength could be that I have a low
percentage error of 2.4%, which means that this experiment was pretty successful and that the
procedures I used are reliable and approvable. One limitation would be that the strength of fire
was not consistent. The fire kept dying out so we had to light the fire again several times, and
even when we lighted successfully, it was hard to adjust the level/strength of the fire. When I
was turning the valve, it was difficult to adjust it to a proper extent; the fire was either too weak
or too strong. Due to this, the water of crystallisation might not have been driven off steadily.
Another limitation was that I was able to do only one trial, so I couldn’t really find out if the
mass of hydrated copper(II) sulfate has effect on the mass of water lost through decomposition.
So one area where I can improve my experiment would be the number of trials; If I were
to do this experiment again, I would do more than one trial so I can figure out the answer for the
research question experimentally. Another point where I could improve on is about time. For this
experiment, I did not measure for how long I heated the crucible; instead of timing during the
heating process using a stopwatch, I just waited until the color of the copper(II) sulfate went
greyish white. Even though the procedure did not say anything about measuring time and it only
said “heat until the color of the crystal fades to greyish white”, I think it would have been useful
to record the time. Involving time could lead to a possible extension to this investigation. If I
measured time, I could even have calculated how long it takes to fully decompose a hydrated
copper(II) sulfate crystal depending on the mass. This relates back to having more than one trial;
I can do various trials, time each, and find the correlation between the time taken to become
anhydrous copper(II) sulfate and the mass of crystals. And then I could also have create a general
formula/equation that shows the correlation.
Works Cited
“BBC - GCSE Bitesize: Reversible Reactions.” N.p., n.d. Web. 29 Oct. 2017.
“Hydrate | Chemical Compound.” Encyclopedia Britannica. N.p., n.d. Web. 29 Oct. 2017.
“Law of Definite Proportions | Chemistry.” Encyclopedia Britannica. N.p., n.d. Web. 29 Oct.
2017.
Pubchem. “Copper(II) Sulfate Pentahydrate.” N.p., n.d. Web. 30 Oct. 2017.