Salt Spray Testing - Why It Should Not Be Used To Compare Different Types of Coatings

Information sheet
Salt spray testing why it should not

be used to compare different types
of coatings
For users of protective coatings in the construction,
A large number of peer-reviewed papers have also given
manufacturing or engineering industry, there is one aspect
clear warnings about the use of the salt spray test:
of corrosion science that requires careful understanding

that is the role and limitations of accelerated corrosion
testing. For decades, the so-called salt spray test
has generated misleading information about coating
performance and its results still feature prominently in the
marketing materials of products that, artificially, yield more
In fact, it has been recognised for many years that when

ranking the performance levels of organic coating systems,
there is little, if any, correlation between results from standard
salt spray tests and practical experience 2
Salt spray is the most widely used accelerated test. It was
favourable outcomes than in the real world.
developed more than 50 years ago for testing metallic coatings
What is wrong with the salt spray test?
that this test does not provide a good indication of outdoor
in marine environments. Although it has been demonstrated
Firstly, the test does have some value for quality control
service performance of coatings (even in a salt atmosphere),
of a specific material or coating. This is what the test was
its use has become entrenched in the coatings industry 3.
originally designed for and it is used successfully by some

industries for this purpose. Although, it is now largely
abandoned even by the automotive industry.
The well-known ASTM B-117 salt spray test provides a

comparison of cold-rolled and galvanized steel within several
hundred hours. Unfortunately, the salt spray test is unable
The serious misuse of the salt spray test is its use to
to predict the well-known superior corrosion resistance of
compare, or rank, different materials or coatings that have
galvanized relative to uncoated rolled steel sheet. 4
differing characteristics. It is especially misleading to use

the test to compare paints with metallic coatings. It is
equally misleading to compare different metallic coatings.
For example, comparisons between zinc and zinc alloy
coatings (such as those containing small additions of
magnesium and aluminium) can produce comparative
results that are vastly different to real in-field performance.
Unfortunately, material comparisons are still made using
the test despite the international standard for the test (ISO
9227) clearly stating that There is seldom a direct relation
between resistance to the action of salt spray and resistance to
corrosion in other media, because several factors influencing
the progress of corrosion, such as the formation of protective
films, vary greatly with the conditions encountered. Therefore,
the test results should not be regarded as a direct guide to
the corrosion resistance of the tested metallic materials in all
environments where these materials might be used. Also, the
performance of different materials during the test should not
be taken as a direct guide to the corrosion resistance of these
materials in service. 1
Salt spray provides rapid degradation but has shown

poor correlation with outdoor exposures; it often produces
degradation by mechanisms different from those seen
outdoors and has relatively poor precision. 3
Unfortunately, despite these warnings, salt spray testing
is still used in communications to introduce new coatings
and materials to the market.
Why salt spray testing gives misleading

results
To understand why the salt spray test fails to reliably
predict real corrosion performance, it is important to look
at the test procedure. Samples under test are inserted into
a temperature-controlled chamber where a salt-containing
solution is sprayed, at 35C, as a very fine fog mist over
the samples. As the spray is continuous, the samples
are constantly wet, and therefore, constantly subject to
corrosion. Performance is rated by recording the number
hours to reach defined levels of surface rusting. Test
duration ranges from 24 hours to 1000 hours or more
Instead, ISO 9227 recommends that salt spray tests are
for some materials.
suitable only as quality control tests for rapid analysis
There are some obvious reasons why the salt spray test
for discontinuities, pores and damage in paint or some

metallic coatings.
does not correlate with real world exposure conditions,

in particular:
The surface of the test coupons is constantly wet, with
Magnesium ions, whether from the environment (sea
no cyclic drying, which does not happen in reality. This
salt) or in a zinc alloy, promote the formation of protective
prevents metals, such as zinc, from forming a passive
corrosion products in the presence of sodium chloride,
film as it would in the field.
thus reducing corrosion rates. This explains why zinc-
The chloride content is very high (normally 5% NaCl)

resulting in highly accelerated conditions with different
acceleration factors for different metals and metal
constituents.
These are unusual and severe conditions that probably
never occur during normal outdoor exposure.
magnesium-aluminium coatings show artificially better

performance, as compared to zinc, in accelerated tests
involving high time of wetness and high chloride load.
This effect also occurs in field exposure tests in some, e.g.
marine, atmospheres but with a substantially lower level of
improvement than is indicated by salt spray test results.
Summary
The use of salt spray test results to guide selection of
protective coatings for steel remains a serious problem in
the engineering community. Despite the well understood
limitations of the test in the corrosion world, it still used to
promote the use of coatings whose properties happen to
produce apparently favourable results. It is hoped that this
article has given some insight into the scientific background
to the limitations of this type of accelerated testing. Despite
the attractiveness of quick and short-term information,
there is no substitute for corrosion data generated from
long-term exposure testing and case history information
from real structures or components in service.
Figure 1 Salt spray chambers create test conditions

that are rarely, if ever, observed in practice.
Salt spray testing cannot successfully

compare corrosion resistance of materials
It is well accepted that the good performance of metallic
zinc coatings in real outdoor conditions relies on drying
between periods of wetness. The development of a passive
and relatively stable oxide and/or carbonate film during
the drying cycle contributes to the excellent performance
of galvanized coatings. The continual wetness during the
salt spray test does not allow this passive oxide/carbonate
layer to develop. The test therefore artificially reduces the
performance of zinc coatings.
References
1 ISO 9227 Corrosion tests in artificial atmospheres salt
spray tests.
2 Skerry, J S, Alavi, A and Lindgren, K I. Environmental
and Electrochemical Test Methods for the Evaluation of
Protective Organic Coatings, J of Coatings Technology, vol
60, No 765, p97.1988.
3 Appleman, B. Cyclic Accelerated Testing: The Prospects
for Improved Coating Performance Evaluation, J
Protective Coatings & Linings, p71-79. Nov 1989.
4 Townsend, H E. Development of an Improved Laboratory
Corrosion Test by the Automotive and Steel Industries,
When painted material is evaluated using the salt spray

test, there is no exposure to ultraviolet light, a common
Proceedings of the 4th Annual ESD Advanced Coating

Conference, Dearborn, USA, 1994.
cause of breakdown of paints. This is a serious omission,

since the main failure mechanism that causes painted
steel to deteriorate is not included as a condition in
the salt spray test.
example, small additions of magnesium or aluminium to a

zinc coating will produce salt spray test results that differ
Swerea KIMAB is a leading institute within corrosion and

materials research, based in Stockholm, specialising in
surface technology, corrosion and corrosion protection of
metals, corrosion testing and field exposures, corrosion of
polymers and material analysis and metallography.
Tel: + 44 (0)1883 331277

Fax: + 44 (0)1883 331287
email: mail@egga.com
www.egga.com
June 2013
when comparing different variants of zinc coatings. For
European General Galvanizers Association

Maybrook House
Godstone Road
Caterham
Surrey CR3 6RE, United Kingdom
assistance of L Sjgren, Coordinator - Consulting services

and Corrosion in Infrastructure, Swerea KIMAB AB.
The salt spray test can give similarly misleading results
significantly from real exposure conditions.
This information sheet has been prepared with the

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Information sheet

Salt spray testing why it should not

A large number of peer-reviewed papers have also given

manufacturing or engineering industry, there is one aspect

clear warnings about the use of the salt spray test:

of corrosion science that requires careful understanding

In fact, it has been recognised for many years that when

favourable outcomes than in the real world.

developed more than 50 years ago for testing metallic coatings

What is wrong with the salt spray test?

that this test does not provide a good indication of outdoor

in marine environments. Although it has been demonstrated

service performance of coatings (even in a salt atmosphere),

of a specific material or coating. This is what the test was

its use has become entrenched in the coatings industry 3.

originally designed for and it is used successfully by some

The well-known ASTM B-117 salt spray test provides a

The serious misuse of the salt spray test is its use to

to predict the well-known superior corrosion resistance of

compare, or rank, different materials or coatings that have

galvanized relative to uncoated rolled steel sheet. 4

differing characteristics. It is especially misleading to use

Salt spray provides rapid degradation but has shown

Why salt spray testing gives misleading

Instead, ISO 9227 recommends that salt spray tests are

for some materials.

suitable only as quality control tests for rapid analysis

for discontinuities, pores and damage in paint or some

does not correlate with real world exposure conditions,

The surface of the test coupons is constantly wet, with

Magnesium ions, whether from the environment (sea

no cyclic drying, which does not happen in reality. This

salt) or in a zinc alloy, promote the formation of protective

prevents metals, such as zinc, from forming a passive

corrosion products in the presence of sodium chloride,

film as it would in the field.

thus reducing corrosion rates. This explains why zinc-

The chloride content is very high (normally 5% NaCl)

magnesium-aluminium coatings show artificially better

Figure 1 Salt spray chambers create test conditions

Salt spray testing cannot successfully

When painted material is evaluated using the salt spray

Proceedings of the 4th Annual ESD Advanced Coating

cause of breakdown of paints. This is a serious omission,

example, small additions of magnesium or aluminium to a

Swerea KIMAB is a leading institute within corrosion and

Tel: + 44 (0)1883 331277

when comparing different variants of zinc coatings. For

European General Galvanizers Association

assistance of L Sjgren, Coordinator - Consulting services

The salt spray test can give similarly misleading results

significantly from real exposure conditions.

This information sheet has been prepared with the

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