Five Boynton Road Hopping Brook Park Holliston, MA 01746 USA
TEL: 508-429-1110 FAX: 508-429-7433 WEB: www.walchem.com Disinfection Sensors W A L C H E M An Iwaki America Company
Notice
2010 WALCHEM, An Iwaki America Incorporated Company (hereinafter Walchem) Five Boynton Road, Holliston, MA 01746 USA (508) 429-1110 All Rights Reserved Printed in USA
Proprietary Material The information and descriptions contained herein are the property of WALCHEM. Such information and descriptions may not be copied or reproduced by any means, or disseminated or distributed without the express prior written permission of WALCHEM, Five Boynton Road, Holliston, MA 01746.
Statement of Limited Warranty WALCHEM warrants equipment of its manufacture, and bearing its identification to be free from defects in workmanship and material for a period of 24 months for electronics and 12 months for mechanical parts and electrodes from date of delivery from the factory or authorized distributor under normal use and service and otherwise when such equipment is used in accordance with instructions furnished by WALCHEM and for the purposes disclosed in writing a the time of purchase, if any. WALCHEMs liability under this warranty shall be limited to replacement or repair, F.O.B. Holliston, MA U.S.A. of any defective equipment or part which, having been returned to WALCHEM, transportation charges prepaid, has been inspected and determined by WALCHEM to be defective. Replacement elastomeric parts and glass components are expendable and are not covered by any warranty.
THIS WARRANTY IS IN LIEU OF ANY OTHER WARRANTY, EITHER EXPRESS OR IMPLIED, AS TO DESCRIPTION, QUALITY, MERCHANTABILITY, and FITNESS FOR ANY PARTICULAR PURPOSE OR USE, OR ANY OTHER MATTER.
P/N 180307.J Jun 2010
Table of Contents
1.0 Introduction .................................................................................. 1 Sensor.............................................................................................................1 Flow Cell..........................................................................................................1 2.0 Installation .................................................................................... 1 Assembling the Sensor....................................................................................1 Flow Cell Placement........................................................................................2 Installing Sensor into Flow Cell .......................................................................3 Typical Installation...........................................................................................4 Typical Installation Using Walchem Flow Switch Manifold..............................5 Wiring Instructions...........................................................................................7 3.0 Operation ...................................................................................... 9 Conditioning.....................................................................................................9 Calibration.......................................................................................................9 4.0 Troubleshooting......................................................................... 10 The disinfectant reading is much lower than the manual analysis ................10 The disinfectant reading is much higher than the manual analysis...............10 Sensor Error..................................................................................................11 Disinfectant Reading is Unstable...................................................................11 Calibration Failure .........................................................................................11 5.0 Maintenance ............................................................................... 12 Cleaning the Membrane................................................................................12 Replacing the Membrane ..............................................................................12 Sensor Storage..............................................................................................13 6.0 Specifications ............................................................................. 14
1.0 Introduction
The WCDB (chlorine dioxide), WFCB (free chlorine), WFCXB (free chlorine with extended pH range), WOZB (ozone) and WPAB (Peracetic acid) sensors consist of an amperometric sensor assembly and a flow cell. Assembly of these parts is required, so please read these instructions carefully. The sensor is capable of measuring the disinfectant in clean water or in water contaminated with debris thanks to our unique flow cell design.
The WFCB free chlorine sensor membrane is not compatible with water containing surfactants!
Sensor The sensor assembly includes the sensor body with 6 meters (20 feet) of cable, a replaceable membrane cap, a 100-ml bottle of electrolyte fill solution, special abrasive paper, a clip ring, a washer set and an o-ring. Make sure that all parts are included.
The oxidizer molecules diffuse through the membrane and in the acidic environment of the electrolyte fill solution, a redox reaction occurs at the electrodes in the sensor. The current generated by this reaction is converted to a robust voltage signal that is linear with the concentration of the oxidizer.
Flow Cell The flow cell consists of a translucent flow cell body, mounting nut and o-ring. Make sure that all parts are included.
The flow cell is required to prevent bubble formation on the membrane and to provide proper flow velocity across the face of the membrane. The sensor will not read accurately if it is not installed in the flow cell, with a flow rate between 30 and 100 liters per hour, at an operating pressure of 1 atmosphere or less.
2.0 Installation
Assembling the Sensor CAUTION: Wear gloves and safety glasses during assembly of the sensor since the electrolyte is a STRONG ACID. It is recommended to perform this operation over a sink with running water available. After using, re-cap any remaining electrolyte and store the bottle upside-down until the next use.
Free Chlorine Sensors
1. Clean just the tip of the working electrode with the special abrasive paper supplied. Avoid touching the electrodes! Place the special abrasive paper on top of a clean paper towel and rub the electrode tip over the abrasive paper, holding the electrode at a slight angle. Repeat several times at different angles. Never touch or clean the brown electrode shaft.
2. Remove the rubber band from the groove in the membrane cap just until the vent hole underneath is exposed, then fill the membrane cap to the top with the electrolyte fill solution. Never shake the electrolyte bottle, it must stay free of bubbles!
3. Hold the sensor body vertically with the tip pointing down and SLOWLY screw on the membrane cap until it is hand tight. Be prepared for some electrolyte solution to squeeze out from the vent hole in the cap.
4. Rinse your hands, the sensor, and all surfaces contaminated with electrolyte solution with running water. Check the sensor for leaks, especially at the membrane and the membrane cap threads. If any leaks are detected, tighten the membrane cap or replace it. Move the rubber band back into the groove. Never remove the membrane cap with the rubber band covering the vent hole, or the membrane will be damaged!
5. Push the cable onto the end of the sensor, aligning the pins with the holes. Turn the connector until hand tight to seal the cable connection.
Other Sensors
1. Remove the black protective tube from the electrode tip, and clean just the tip of the working electrode with the special abrasive paper supplied. Avoid touching the electrodes! Place the special abrasive paper on top of a clean paper towel and rub the electrode tip over the abrasive paper, holding the electrode at a slight angle Repeat several times at different angles. Never touch or clean the brown electrode shaft.
2. Open the vial containing the membrane cap. Empty out the water. Make sure that only one grey rubber band is in the groove covering the vent hole in the membrane cap. Fill the membrane cap to the top with the electrolyte fill solution.
3. Hold the sensor body vertically with the tip pointing down and SLOWLY screw on the membrane cap until it is hand tight. Be prepared for some electrolyte solution to squeeze out from the vent hole in the cap.
4. Push the second grey band into the groove in the cap, making sure that the bands are smooth and flush.
5. Rinse your hands, the sensor, and all surfaces contaminated with electrolyte solution with running water. Check the sensor for leaks, especially at the membrane and the membrane cap threads. If any leaks are detected, tighten the membrane cap or replace it.
6. Push the cable onto the end of the sensor, aligning the pins with the holes. Turn the connector until hand tight to seal the cable connection.
Flow Cell Placement Instructions for mounting the sensor into the process can vary greatly with the circumstances that are encountered in your application. Here are some general guidelines to assist you. Refer also to the typical installation drawings.
The sensor should be mounted such that the measuring surfaces will always stay wet. If the membrane dries out, it will respond slowly to changing disinfectant values for 24 hours, and if dried out repeatedly, will fail prematurely. If the sensor is left dry for longer than 24 hours, the membrane cap must be replaced!
The flow cell should be placed on the discharge side of a circulation pump or downhill from a gravity feed. Flow into the cell must come from the bottom side that has the x NPT
reducing bushing installed. The reducing bushing provides the flow velocity required for accurate readings and must not be removed!
A U trap should be installed so that if the flow stops, the sensor is still immersed in the water. The outlet of the flow cell must be plumbed to open atmosphere unless the system pressure is at or below 1 atmosphere. If the flow through the line cannot be stopped to allow for cleaning and calibration of the sensor, then it should be placed in a by-pass line with isolation valves to allow for sensor removal. Install the sensor vertically, with the measuring surface pointing down, at least 5 degrees above horizontal. (Refer to Installation drawings)
Flow rate regulation must be done upstream from the sensor, because any flow restriction downstream can increase the pressure above atmospheric and damage the membrane cap!
The sensor should be installed in an area where there is good solution movement and where it will respond rapidly to chemical additions. The placement of the sensor relative to the placement of chemical replenishment, along with the quality of the mixing, and the replenishment chemical flow rate are critical to accurate process control.
To avoid biological growth on the membrane, which can block measurement, never leave the sensor in water without oxidant for longer than 24 hours.
Installing Sensor into Flow Cell 1. Assemble the flow cell as shown below from the top down. The reducer should already be installed in the flow cell body.
2. Slide the 102586 nut over the membrane end of the sensor, followed by the 103419-T top washer, followed by the 103422 o-ring, followed by the 103419-B bottom washer (concave side up), followed by the 103421 clip ring. The clip ring must be pushed up until it snaps into the groove in the sensor body.
3. Place the 102594 o-ring in the top o-ring groove of the 102881 flow cell body.
4. Place the sensor body into the flow cell body, and tighten the 102586 nut until it is hand- tight. Before tightening completely, pull the sensor up until the clip ring is up against the bottom washer.
Typical Installation ISOLATION VALVE (NORMALLY OPEN) 1 2 3 4 5 6 7 8 9 10 1/4" NPT ROTAMETER 30-100 LPH RECIRCULATION PUMP FROM PROCESS 20 FT (6M) 3/4" NPT TO PROCESS
Typical Installation Using Walchem Flow Switch Manifold Sample Valve Flow Control Valve Water In Water Out To Open Atmosphere Rotameter Flow Cell Flow Switch Sensor
Sensor Parts Exploded View
Disinfection Sensor Washer Set p/n 103419 O-Ring p/n 103422 Nut, p/n 102586 Cable, p/n 191303 Membrane cap Clip Ring groove Clip ring O-Ring p/n 102594 Body, p/n 191279-R
Wiring Instructions
WebMaster The sensor is provided with a 2-twisted pair, shielded, 24 AWG, 35 pF/foot capacitance cable. The wiring to the controller is as follows:
If the required cable length exceeds the 6 meters (20 feet) that is supplied, wire the housing to a 190851 terminal box, then use a p/n 100084 cable to reach the instrument. The maximum cable length is 305 meters (1000 feet).
WDIS410 The sensor is provided with a 2-twisted pair, shielded, 24 AWG, 35 pF/foot capacitance cable. The wiring to the controller is as follows:
If the required cable length exceeds the 6 meters (20 feet) that is supplied, wire the housing to a 190851 terminal box, then use a p/n 100084 cable to reach the instrument. The maximum cable length is 305 meters (1000 feet).
Power Supply (115 VAC or 230 VAC) Contact Closure: Polarity not critical Interlock Function +5V T- T+ GROUND STUD L1 L2/N G R N
1 2 0 V G R N / Y E L
2 4 0 V WHT 120V BLU 240V B L K
1 2 0 V B R N
2 4 0 V IN + IN - + 5 V - 5 V -5V IN+IN- IN- DIG IN 2 DIG IN 3 IN+IN- DIG IN 1 IN+ IN- IN+ DIG IN 4 IN+ IN- DIG IN 5 IN+IN- IN - D IG IN 2 D IG IN 3 IN + IN - D IG IN 1 IN + IN - IN + D IG IN 4 IN + IN - D IG IN 5 IN + IN - L1 L2/N L2 L2 L2 L2 L2 L2 BLEED N.C. N.O. N.C. BOI 1 N.O. N.C. FEED N.C. BIO 2 N.O. N.C. N.O. N.O. ALARM N.C. N.O. WFCB WCDB WOZB WPAB G R E E N W H I T E R E D B L A C K
3.0 Operation This section describes how to prepare the sensor for use.
Conditioning The sensor requires conditioning to acclimate the electrodes prior to generating stable readings. Conditioning consists of installing the sensor in the flow cell, ensuring that the sensor remains wet at all times with water containing the disinfectant to be measured, and supplying power to the sensor.
The following conditioning times are recommended: New Sensor 12 24 hours After membrane or electrolyte replacement 1 hour
Calibration The frequency of calibration is a function of many factors. These factors include: 1. The accuracy required by the application. 2. The value of the off-specification product versus the cost of calibration. 3. The coating or abrasive nature of the application. 4. The stability of the sensor and controller as a system.
The frequency of calibration is really determined by experience. At a new installation, calibration might initially be checked every day by comparing the controller reading to a DPD test or other manual analysis and logging the results. If the reading drifts off significantly in one direction you should consider calibrating. Resist the temptation to calibrate to correct for small errors that may be a result of normal variations in the test methods.
A calibration MUST be performed on initial installation, or after cleaning or replacing the membrane or electrolyte. A sensor installed in clean water can hold its calibration for several months.
DO NOT attempt to perform a calibration until the following condition have been met: 1. The sensor has been conditioned as described above. 2. The sensor has equilibrated to the temperature of the water (for the zero calibration) or the sample (for the 1 point process calibration).
Zero Calibration 1. Remove the sensor from the flow cell and place it in a beaker of clean, oxidizer-free water. 2. Allow the sensor 15 minutes to equilibrate to the water temperature. 3. Go to the Zero Calibration menu of the controller. Refer to the controller instructions. 4. Stir the water with the sensor until the mV reading is stable for at least 5 minutes. 5. When the reading is stable, continue to the final steps of the calibration. 6. Return the sensor to the flow cell and check for leaks.
One Point Process Calibration
1. Ensure that the sensor is conditioned and equilibrated to the temperature of the sample. 2. Ensure that the sample flow rate is between 30 and 100 liters/hour. 3. Perform a DPD test or other manual analysis on the sample water. 4. Go to the One Point Process Calibration menu of the controller. Refer to the controller instructions. 5. When the reading is stable, continue to the final steps of the calibration.
NOTE: Disinfectant concentration can change rapidly in the sample! Minimize the time between performing the DPD test or manual analysis and finishing the calibration!
4.0 Troubleshooting
The disinfectant reading is much lower than the manual analysis
Possible Causes Corrective Actions Insufficient conditioning Wait for the appropriate amount of time before attempting a calibration. Insufficient sample flow Increase flow rate to between 30 and 100 liter per hour. Air bubbles on membrane Dislodge bubbles. Adjust flow rate higher if necessary. Dirty membrane Clean membrane Faulty membrane Replace membrane cap. High Pressure Reduce pressure to below 1 atmosphere and refill cap with electrolyte No electrolyte fill solution in membrane cap Fill membrane cap with electrolyte. Replace membrane cap if it will not hold solution. Faulty sensor Replace sensor Faulty analysis equipment or reagents Consult test equipment instructions
The disinfectant reading is much higher than the manual analysis
Possible Causes Corrective Actions Insufficient conditioning Wait for the appropriate amount of time before attempting a calibration. Faulty membrane Replace membrane cap. Faulty sensor Replace sensor Faulty analysis equipment or reagents Consult test equipment instructions Ozone or chlorine in the water (ClO2 or O3 sensors) Remove source of contamination Bromine, Ozone, Iodine, ClO2, Di-/Trichloramine, or Bromamine in the water (Cl2 sensor) Remove source of contamination
Sensor Error This error message appears if the signal from the sensor is outside the range of 1400 to 1400 mVDC (WebMaster) or 2000 to 2000 (WDIS).
Possible Causes Corrective Actions Faulty wiring Check wiring Faulty sensor Replace sensor Faulty controller sensor input Go to the Sensor Input menu and perform a self test. If this passes, then the problem is with the sensor or its wiring. If it fails, then disconnect the sensor from the circuit board and try the self test again. If it still fails, replace the circuit board.
Disinfectant Reading is Unstable
Possible Causes Corrective Actions Air bubbles on membrane Dislodge bubbles. Adjust flow rate higher if necessary. Faulty membrane Replace membrane cap. Faulty wiring Check wiring Faulty controller sensor input Go to the Sensor Input menu and perform a self test. If this passes, then the problem is with the sensor or its wiring. If it fails, then disconnect the sensor from the circuit board and try the self test again. If it still fails, replace the circuit board.
Calibration Failure For WebMaster The controller will display a calibration failure if the offset calculated in the Zero Calibration is outside of the range 20 to 40 mV or the slope calculated in the One Point Process Calibration is outside of the range -10 to -100 mV per ppm of ClO2, Cl2 and ozone, or 1 to 10 mV per ppm of PAA. For WDIS: The expected response is 100 mV/ppm for Cl2, ClO2, and Ozone, or 10 mV/ppm for Peracetic Acid. The acceptable range is for 100 mV (or 10 mV for PAA) to equal 0.5 to 2.0 ppm. The range of mV for a Zero Calibration is 100 mV to 100 mV.
Possible Causes Corrective Actions Insufficient conditioning Wait for the appropriate amount of time before attempting a calibration. Insufficient sample flow Increase flow rate to between 30 and 100 liters per hour Air bubbles on membrane Dislodge bubbles. Adjust flow rate higher if necessary. Dirty membrane Clean membrane Faulty membrane Replace membrane cap. High Pressure Reduce pressure to below 1 atmosphere and refill cap with electrolyte No electrolyte fill solution in membrane cap Fill membrane cap with electrolyte. Replace membrane cap if it will not hold solution. Faulty sensor Replace sensor Faulty analysis equipment or reagents Consult test equipment instructions Ozone or chlorine in the water Remove source of contamination Faulty wiring Check wiring Faulty controller sensor input Go to the Sensor Input Page and perform a self test. If this passes, then the problem is with the sensor or its wiring. If it fails, then disconnect the sensor from the circuit board and try the self test again. If it still fails, replace the circuit board.
5.0 Maintenance The sections below describe how to clean and replace the membrane cap and electrolyte solution, and also how to store the sensor when not in use.
See section 4.0 Troubleshooting for assistance in determining when maintenance may be required.
Cleaning the Membrane Instructions for cleaning the membrane vary depending upon the type of contamination. Follow the directions for replacing the membrane shown below, replacing step 3 with one of these cleaning methods:
For general deposits: Rinse in clear cold water.
For calcium scale: Soak in dilute (1% by volume) hydrochloric acid, then rinse in clear cold water.
For oils: Rinse in isopropyl alcohol. DO NOT use cleaners or detergents containing surfactants, as these will reduce the life of the membrane.
If the sensor still cannot be calibrated after cleaning, replace the membrane cap as described below.
Replacing the Membrane CAUTION: Wear gloves and safety glasses during assembly of the sensor since the electrolyte is a STRONG ACID. It is recommended to perform this operation over a sink with running water available. After using, re-cap any remaining electrolyte until the next use.
1. Always move the gray band(s) to uncover the vent hole before removing the membrane cap, or else the membrane will be destroyed! Hold the sensor vertically with the membrane facing down and carefully unscrew the membrane cap.
2. Rinse the electrolyte fill solution off the cap and electrodes with cold water.
3. Discard the old membrane cap.
4. Unpack the new membrane cap, taking care not to touch the membrane or get it dirty.
5. Fill the membrane cap to the top with the electrolyte fill solution.
6. Hold the sensor body vertically with the tip pointing down and SLOWLY screw on the membrane cap until it is hand tight. Be prepared for some electrolyte solution to squeeze out from the cap
7. Rinse your hands, the sensor, and all surfaces contaminated with electrolyte solution with running water.
8. Check the sensor for leaks, especially at the membrane and the membrane cap threads. If any leaks are detected, tighten the membrane cap or replace it. Move the rubber band(s) back into the groove.
Sensor Storage The sensor may be stored for up to one month in the flow cell assuming that the membrane is always kept submerged in water.
For long term storage, up to 3 years, follow this procedure: CAUTION: Wear gloves and safety glasses during assembly of the sensor since the electrolyte is a STRONG ACID. It is recommended to perform this operation over a sink with running water available. After using, re-cap any remaining electrolyte until the next use.
1. Hold the sensor vertically with the membrane facing down and carefully unscrew the membrane cap. Always move the gray bands to uncover the vent hole before removing the cap!
2. Rinse the electrolyte fill solution off the cap and electrodes with cold water.
3. Allow the parts to air dry.
4. Loosely screw the membrane cap back on and store the sensor in a clean dry place. The electrode tip must not touch the membrane.
The old membrane cap used to protect the sensor during storage must be discarded and replaced when the sensor is put back into service.
6.0 Specifications
Chlorine Dioxide Peracetic Acid Ozone Free Chlorine/Bromine Free Chlorine/Bromine High pH Range Range (Nominal) 0-20 mg/l 0-2000 mg/l 0-20 mg/l 0-20 mg/l 0-20 mg/l Range (WDIS) 0 16.75 mg/l 0 1675 mg/l 0 16.75 mg/l 0-13.25 mg/l 0-12.5 mg/l Range (WM1,WIND) 0 10 mg/l 0-10 mg/l 0-10 mg/l 0 8 mg/l 0-7.5 mg/l Resolution 0.01 mg/l 1 mg/l 0.01 mg/l 0.01 mg/l 0.01 mg/l Sensitivity Free Chlorine (5%), Ozone (2500%) Ozone (250%), ClO 2 (100%), H 2 O 2 (0.5%) ClO2 (6%) HOCl (100%) HOBr (100%) Ozone ClO2 (900%) HOCl (100%) HOBr (100%) Ozone ClO2 (100%) HOCl with isocyanuric acid Flow Rate of Sample 30 to 100 liters/hour (0.13 to 0.44 gallons/minute) pH Range of Sample 1.0 11.0 1.0 7.0 2.0 11.0 6.8 8.0 (pH must be stable within +/- 0.10) 4.0-12.0 Conductivity Range of Sample 50 to 10,000 S/cm Up to 4% NaCl 50 to 10,000 S/cm Response Time 30 sec 3 min 50 sec 30 sec 2 min Run-In Time 60 min 60 min 60 min 60 min 120 min Calibration Weekly Change Electrolyte 6 months 3 months Change Membrane Cap 1 year Electrical Power Requirements 5 VDC, 5 mA maximum Signal 0 to -2000 mVDC Maximum Cable Length 1000 ft (305 m) Cable Required 2 twisted pair, 22 AWG, shielded, 35 pF/ft (Walchem 100084 or Belden 8723) Mechanical Operating Temperature 0 to 55C (32 to 131F) 0 to 50C (32 to 122F) 0 to 45C (32 to 113 F) Operating Pressure 0 to 1 atm (0 to 14.7 psi) Storage Temperature 0 to 50C (32 to 122F) Shelf Life 3 years Flow Cell Inlet NPTF Flow Cell Outlet NPTF Wetted Materials of Construction Sensor PVC, Polycarbonate, silicone rubber, stainless steel PVC, Polycarbonate, silicone rubber PVC, Polycarbonate, silicone rubber, stainless steel Flow Cell Body Isoplast O-Ring FKM
FIVE BOYNTON ROAD HOPPING BROOK PARK HOLLISTON, MA 01746 USA TEL: 508-429-1110 FAX: 508-429-7433 Web: www.walchem.com
