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A D VA N C E D
N A N O M AT E R I A L S F O R
P O L L U TA N T S E N S I N G
A N D E N V I R O N M E N TA L
C ATA LY S I S
A D VA N C E D
N A N O M AT E R I A L S F O R
P O L L U TA N T S E N S I N G
A N D E N V I R O N M E N TA L
C ATA LY S I S
Edited by
QIDONG ZHAO
Elsevier
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ix
x LIST OF CONTRIBUTORS
xi
xii PREFACE
1.1 Introduction
Hollow micro and nanomaterials are a special class of func-
tional nanomaterials, defined as architectures with void space
surrounded by a shell [1,2]. Over the past two decades, the syn-
thesis of different hollow structures has become a hot research
topic and attracted tremendous research efforts.
Before 1998, most hollow materials were of spherical shape
and synthesized by using spray-drying or gas-blowing techniques
[3]. However, these methods only culminated in the simple
sol gel approaches for coating gold (Au) and (silver) Ag nano-
particles with silica [4,5] before 1998 with Caruso’s work on col-
loidal templating synthesis of hollow spheres [6]. The emerging
approaches enabled a more versatile synthesis paradigm for fab-
ricating hollow structures based on hard-templating ways.
Currently, various novel self-templated or template-free synthetic
approaches based on different mechanisms have been developed
such as galvanic replacement, controllable thermal transforma-
tion, ion exchange, and inside-out Ostwald ripening to tailor the
structural features of hollow nanostructures. Encouragingly, a
myriad of hollow nanostructures with hierarchical architectures,
polyhedral morphologies, multicompositions, and multishells
have been successfully constructed through rationally designed
strategies involving these mechanisms (Fig. 1.1).
Advanced Nanomaterials for Pollutant Sensing and Environmental Catalysis. DOI: https://doi.org/10.1016/B978-0-12-814796-2.00001-0
© 2020 Elsevier Inc. All rights reserved. 1
2 Chapter 1 HOLLOW MICRO- AND NANOMATERIALS: SYNTHESIS AND APPLICATIONS
Figure 1.1 Schematic illustration showing various hollow structures: (A) hollow
spheres, boxes, and tubes; (B) multishelled hollow spheres, boxes, and tubes;
and (C) yolk-shell, cube-in-box, and wire-in-tube structures. Reprinted with
permission from X.J. Wang, J. Feng, Y.C. Bai, Q. Zhang, Y.D. Yin, Synthesis, properties, and
applications of hollow micro-/nanostructures. Chem. Rev. 116 (2016) 10983 11060.
Copyright 2016, American Chemical Society.
1.2.3 Morphology
Until now, multishelled hollow structures are mostly spheri-
cal in morphology [62 66]. Well-defined, nonspherical,
Chapter 1 HOLLOW MICRO- AND NANOMATERIALS: SYNTHESIS AND APPLICATIONS 9
With the exception of The Ring and the Book, Don Juan,
containing approximately 16,000 lines, is probably the longest
original poem in English since the Faerie Queene; moreover, if we
exclude the Canterbury Tales, no other work in verse in our literature
attempts an actual “criticism of life” on so broad a scale. It is Byron’s
deliberate and exhaustive characterization of his age, the book in
which he divulges his opinions with the least reticence and the most
finality. With all their occasional brilliance and power, his earlier
satires had been essentially imitative and could be judged by pre-
existing standards. Later, in composing Beppo, Byron discovered that
he had found a kind of verse capable of free and varied treatment
and therefore especially suited to his improvising and discursive
genius; accordingly, in Don Juan, which is a longer and more
elaborate Beppo, he produced a masterpiece which, besides being
an adequate revelation of his complex personality, is unique in
276
English, anomalous in its manner and method.
Because it reflects nearly every side of Byron’s variable
individuality, Don Juan, though satirical in main intent, combines
satire with many other elements. It is tragic, sensuous, humorous,
melancholy, cynical, realistic, and exalted, with words for nearly
every emotion and temper. It contains a romantic story, full of
sentiment and tenderness; it rises into passages of lyric and
descriptive beauty, evidently heart-felt; yet these serious and
imaginative details are imbedded in a sub-stratum of satire.
Furthermore, its range in substance and style is very great; it
discusses matters in politics, in society, in literature, and in religion;
it shifts in a stanza from grave to gay, from the commonplace to the
sublime. It is a poem of freedom; free in thought and free in speech,
unrestricted by the ordinary laws of metre. “The soul of such writing
is its license,” wrote Byron to Murray in 1819.
The plot of Don Juan, dealing, like the picaresque romances of
Le Sage and Smollett, with a series of adventures in the life of a
wandering hero, and interrupted constantly by the comments of the
author, has little real unity. Considered as a satire, however, the
poem becomes unified through the personality behind the stanzas. It
is a colossal monument of egotism; wherever we read, we meet the
inevitable “I.” The poet’s interest in the progress of his characters is
so obviously subordinated to his desire for gossiping with his readers
that the plot seems, at times, to be almost forgotten. Thus Don Juan
is as subjective as Byron’s correspondence; indeed ideas were often
transferred directly from his letters to his verses. There are lines in
the poem which restate, sometimes in the same phraseology, the
confessions and the criticisms recorded by Lady Blessington in her
Conversations with Lord Byron. Autobiographical references are very
277
common, sometimes merely casual, sometimes used as a text for
278
satire. The powerful personality of the writer, expressed thus in
his work, furnishes it with a unity which is lacking in the plot.
It is probable that Byron himself had only a vague conception of
the structure and limits of his poem. His conflicting assertions,
usually half-jocular, concerning his plan or scheme are proof that he
cared little about adhering to a closely knit form. He is most to be
trusted when he says:
“Note or text,
279
I never know the word which will come next.”