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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 22.10.2019 Version number 4 Revision: 22.10.2019

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Trade name weberdry PUR seal
Safety data sheet no.: XXP014014
1.2 Relevant identified uses of the substance or mixture and uses advised against
The product is intended for industrial or professional use.
Application of the substance / the mixture Coating material
Uses advised against Uses other than those recommended.
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
SAINT-GOBAIN WEBER PORTUGAL S.A
ZONA INDUSTRIAL DE TABOEIRA
3800-055 AVEIRO
Portugal
Tel. +351 234 10 10 10
sara.lacerda@saint-gobain.com
1.4 Emergency telephone number: 112

* SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008

GHS02 flame

Flam. Liq. 3 H226 Flammable liquid and vapour.

GHS08 health hazard

Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.

GHS07

Skin Irrit. 2 H315 Causes skin irritation.

Eye Irrit. 2 H319 Causes serious eye irritation.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
Hazard pictograms

GHS02 GHS08

Signal word Danger

Hazard-determining components of labelling:
xylene
m-tolylidene diisocyanate
(Contd. on page 2)
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4,5-dichloro-2-octyl-2H-isothiazol-3-one
Hazard statements
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/container in accordance with local/regional/national/
international regulations.
Additional information:
EUH204 Contains isocyanates. May produce an allergic reaction.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Does not contain PBT substances.
vPvB: Does not contain vPvB substances.

SECTION 3: Composition/information on ingredients

3.2 Chemical characterisation: Mixtures
Description: Mixture of substances listed below with non hazardous additions.
Dangerous components:
CAS: 1330-20-7 xylene 10-20%
EINECS: 215-535-7 Flam. Liq. 3, H226; STOT RE 2, H373; Asp.
Index number: 601-022-00-9 Tox. 1, H304; Acute Tox. 4, H332; Skin Irrit. 2,
Reg.nr.: 01-2119488216-32-xxxx H315; Eye Irrit. 2, H319; STOT SE 3, H335; Aquatic
Chronic 3, H412
CAS: 26471-62-5 m-tolylidene diisocyanate 0.1-1%
EINECS: 247-722-4 Acute Tox. 2, H330; Resp. Sens. 1, H334; Carc.
Index number: 615-006-00-4 2, H351; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin
Reg.nr.: 01-2119454791-34-xxxx Sens. 1, H317; STOT SE 3, H335; Aquatic Chronic 3,
H412
Specific concentration limit: Resp. Sens. 1; H334: C ≥
0.1 %
CAS: 64359-81-5 4,5-dichloro-2-octyl-2H-isothiazol-3-one 0.1-1%
EINECS: 264-843-8 Acute Tox. 1, H330; Skin Corr. 1B, H314;
Aquatic Acute 1, H400; Acute Tox. 4, H302;
Acute Tox. 4, H312; Skin Sens. 1, H317; STOT SE 3,
H335
SVHC Void
Additional information For the wording of the listed hazard phrases refer to section 16.
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SECTION 4: First aid measures

4.1 Description of first aid measures
General information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at
least 48 hours after the accident.
Take affected persons out into the fresh air.
Seek immediate medical advice
Immediately remove any clothing soiled by the product.
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if
symptoms persist.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
After eye contact
Rinse opened eye for several minutes under running water. Rinse liquid should be tempered (20-
30°C).
Seek immediate medical advice.
After swallowing
Do not induce vomiting; call for medical help immediately.
Rinse out mouth and then drink plenty of water.
Drink plenty of water and provide fresh air. Call for a doctor immediately.
Seek immediate medical advice.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing agents CO2, powder or water spray. Fight larger fires with water spray.
For safety reasons unsuitable extinguishing agents Water with full jet
5.2 Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
Carbon dioxide (CO2)
5.3 Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear fully protective suit.
Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Keep away from ignition sources
Ensure adequate ventilation.
Wear protective clothing.
Wear protective equipment. Keep unprotected persons away.
6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
(Contd. on page 4)
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6.3 Methods and material for containment and cleaning up:
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in
sawdust or other combustible
absorbents.
Absorb liquid components with liquid-binding material.
Do not flush with water or aqueous cleansing agents.
6.4 Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
7.2 Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Provide ventilation for receptacles.
Information about storage in one common storage facility: Store away from foodstuffs.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Protect from heat and direct sunlight.
7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

Additional information about design of technical facilities: No further data; see item 7.
8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace:
DNELs
CAS: 1330-20-7 xylene
Oral Derived No Effect Level 12.5 mg/kgxday (consumer systemic long term value)
Dermal Derived No Effect Level 212 mg/kgxday (worker systemic long term value)
125 mg/kgxday (consumer systemic long term value)
Inhalative Derived No Effect Level 221 mg/m³ (worker systemic long term value)
65.3 mg/m³ (consumer systemic long term value)
CAS: 26471-62-5 m-tolylidene diisocyanate
Inhalative Derived No Effect Level 0.035 mg/m³ (worker systemic long term value)
0.14 mg/m³ (worker systemic short term value)
0.14 mg/m³ (worker local short term value)
0.035 mg/m³ (worker local long term value)
(Contd. on page 5)
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Ingredients with biological limit values:
CAS: 1330-20-7 xylene
BGW (Germany) 1.5 mg/l
Untersuchungsmaterial: Vollblut
Probennahmezeitpunkt: Expositionsende bzw. Schichtende
Parameter: Xylol

2000 mg/L
Untersuchungsmaterial: Urin
Probennahmezeitpunkt: Expositionsende bzw. Schichtende
Parameter: Methylhippur-(Tolur-)Säure (alle Isomere)
VLB (Spain) 1 g/g creatinina
Muestra: orina
Momento de Muestero: Final de la jornada laboral
Indicador Biológico: Ácidos metilhipúricos
IBE (Italy) 1.5 g/g creatinina
Campioni: urine
Momento del prelievo: a fine turno
Indicatore biologico: acido metilippurico
IBE (Portugal) 1.5 g/g creatinina
Amostra: urina
Momento da amostragem: Fim do turno
Indicador biológico: Ácidos (o, m, p)-metilhipúricos
BNO (Finland) 5.0 mmol/l
Altiste: virtsan
Näytteenottoajankohta: Työvuoron päätyttyä
Parametri: metyylihippuurihappo
CAS No. Designation of material % Type Value Unit
CAS: 1330-20-7 xylene
IOELV (European Union) Short-term value: 442 mg/m³, 100 ppm
Long-term value: 221 mg/m³, 50 ppm
Skin
AGW (Germany) Long-term value: 440 mg/m³, 100 ppm
2(II);DFG, EU, H
GV (Denmark) Long-term value: 109 mg/m³, 25 ppm
EH
LEP (Spain) Short-term value: 442 mg/m³, 100 ppm
Long-term value: 221 mg/m³, 50 ppm
vía dérmica, VLB, VLI
TWA (Italy) Short-term value: 651 mg/m³, 150 ppm
Long-term value: 434 mg/m³, 100 ppm
A4, IBE
VL (Italy) Short-term value: 442 mg/m³, 100 ppm
Long-term value: 221 mg/m³, 50 ppm
Pelle
VLE (Portugal) Short-term value: 150 ppm
Long-term value: 100 ppm
A4;IBE; Irritação ocular, do TRS; afeção do SNC
OEL (Sweden) Short-term value: 442 mg/m³, 100 ppm
Long-term value: 221 mg/m³, 50 ppm
H
(Contd. on page 6)
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HTP (Finland) Short-term value: 440 mg/m³, 100 ppm
Long-term value: 220 mg/m³, 50 ppm
iho
CAS: 26471-62-5 m-tolylidene diisocyanate
MAK (Germany) vgl. Abschn.XII
OEL (Sweden) Short-term value: 0.04 mg/m³, 0.005 ppm
Long-term value: 0.014 mg/m³, 0.002 ppm
C, M, S
HTP (Finland) Short-term value: 0.035 mg/m³
NCO
Additional information:
The applicable TRGS 900 (MAK list) was used as the basis for the preparation and/or revision of
this safety data sheet.
8.2 Exposure controls
Personal protective equipment:
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Respiratory protection:
Use suitable respiratory protective device in case of insufficient ventilation.
Use suitable respiratory protective device only when aerosol or
mist is formed.
In case of brief exposure or low pollution use respiratory filter device.
In case of intensive or longer exposure use self-contained respiratory protective device.
Short term filter device:
Filter A2/P2.
Protection of hands:
Protective gloves.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Material of gloves
Butyl rubber, BR
Fluorocarbon rubber (Viton)
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a mixture of several
substances, the resistance of the glove material can not be calculated in advance and has
therefore to be checked prior to the application.
Recommended thickness of the material: ≥ 0.5 (BR) ; 0.4 (Viton) mm
Penetration time of glove material
The determined penetration times according to EN 374 part III are not performed under practical
conditions. Therefore a maximum wearing time, which corresponds to 50% of the penetration time,
is recommended.
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes
(Permeation according to EN 374 Part 3: Level 2).
Eye protection: Tightly sealed goggles
Body protection: Protective work clothing.
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SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Colour: Various colours
Odour: Characteristic
Odour threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/freezing point: Undetermined.
Initial boiling point and boiling range: 130 °C
Flash point: 27 °C (xylene)
Flammability (solid, gas): Not applicable.
Ignition temperature: 488 °C (xylene)
Decomposition temperature: Not determined.
Auto-ignition temperature: Product is not selfigniting.
Explosive properties: Product is not explosive. However, formation of
explosive air/vapour mixtures are possible.
Explosion limits:
Lower: 0.8 Vol.%
Upper: Not determined.
Oxidising properties Not determined.
Vapour pressure: Not determined.
Density at 20 °C: 1.39-1.41 g/cm³
Bulk density: Not applicable.
Relative density Not determined.
Vapour density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix
Segregation coefficient (n-octanol/water) log
Pow: Not determined.
Viscosity:
dynamic at 20 °C: >90 mPas
kinematic: Not determined.
Solvent separation test: Not determined
Solvent content:
EU-VOC (g/L) 249.0 g/l
9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

10.1 Reactivity No further relevant information available.
(Contd. on page 8)
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10.2 Chemical stability
Thermal decomposition / Conditions to be avoided: Stable at environment temperature.
10.3 Possibility of hazardous reactions No dangerous reactions known
10.4 Conditions to avoid Avoid heat, sparkles, naked flame or other sources of ignition.
10.5 Incompatible materials: No further relevant information available.
10.6 Hazardous decomposition products:
Carbon monoxide
Carbon dioxide

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity Based on available data, the classification criteria are not met.
LD/LC50 values relevant for classification:
Components Type Value Species
Dermal LD50 9,434 mg/kg (Calculation)
Inhalative LC50/4 h 35 mg/l (Calculation)
CAS: 1330-20-7 xylene
Oral LD50 3,523 mg/kg (Rat)
Dermal LD50 12,126 mg/kg (Rabbit)
Inhalative LC50/4 h 27.124 mg/l (Rat)
CAS: 26471-62-5 m-tolylidene diisocyanate
Oral LD50 >4,130 mg/kg (Rat)
Dermal LD50 >9,400 mg/kg (Rabbit)
Inhalative LC50/4 h 0.1 mg/l (Rat)
Primary irritant effect:
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/irritation
Causes serious eye irritation.
Respiratory or skin sensitisation
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT-single exposure Based on available data, the classification criteria are not met.
STOT-repeated exposure
May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

12.1 Toxicity
Aquatic toxicity: No further relevant information available.
Type of test Effective concentration Method Assessment
CAS: 1330-20-7 xylene
LC50/96h 2.6 mg/l (Fish)
(Contd. on page 9)
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CAS: 26471-62-5 m-tolylidene diisocyanate
LC50/96h 133 mg/l (Fish)
EC50/48h 12.5-18.3 mg/l (Daphnia magna)
EC50/96h 3.2-4.3 mg/l (Algae)
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential
CAS: 26471-62-5 m-tolylidene diisocyanate
EBAB 3.43 log Pow (Bioaccumulation)
Behaviour in environmental systems:
12.4 Mobility in soil No further relevant information available.
Additional ecological information:
General notes: The product contains materials that are harmful to the environment.
12.5 Results of PBT and vPvB assessment
PBT: Does not contain PBT substances.
vPvB: Does not contain vPvB substances.
12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Recommendation
Dispose of the product in accordance with national and local regulations.
Must not be disposed together with household garbage. Do not allow product to reach sewage
system.
Contact manufacturer for recycling information.
European waste catalogue
Possible waste code. The concrete waste code depends on the source of the waste.
08 04 09* waste adhesives and sealants containing organic solvents or other hazardous
substances
HP3 Flammable
HP5 Specific Target Organ Toxicity (STOT)/Aspiration Toxicity
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

14.1 UN-Number
ADR, IMDG, IATA UN1866
14.2 UN proper shipping name
ADR 1866 RESIN SOLUTION
IMDG, IATA RESIN SOLUTION
(Contd. on page 10)
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14.3 Transport hazard class(es)

ADR

Class 3 (F1) Flammable liquids.

Label 3
IMDG, IATA

Class 3 Flammable liquids.

Label 3
14.4 Packing group
ADR, IMDG, IATA III
14.5 Environmental hazards: Not applicable.
14.6 Special precautions for user Warning: Flammable liquids.
Danger code (Kemler): 30
EMS Number: F-E,S-E
Segregation groups Acids
Stowage Category A
14.7 Transport in bulk according to Annex II
of Marpol and the IBC Code Not applicable.
Transport/Additional information:
ADR
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000
ml
Transport category 3
Tunnel restriction code E
Remarks: Containers >450 L = UN 1866 - 3(F1) - RESIN
SOLUTION, flammable
IMDG
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000
ml
Remarks: Containers >30 L = UN 1866 - 3(F1) - RESIN
SOLUTION, flammable
IATA
Remarks: Outside ADR/IMDG = UN 1866 - 3 (F1) - RESIN
SOLUTION, flammable
(Contd. on page 11)
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UN "Model Regulation": UN 1866 RESIN SOLUTION, 3, III

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Regulation (EC) No 1907/2006 (REACH) (Candidate List, Annexes XIV and XVII)
Regulation (EC) No 1272/2008 (CLP)
Directive 2004/42/CE (VOC), cf. section 9
Labelling according to Regulation (EC) No 1272/2008 cf. section 2
Directive 2012/18/EU
Named dangerous substances - ANNEX I None of the ingredients is listed.
Seveso category P5c FLAMMABLE LIQUIDS
Qualifying quantity (tonnes) for the application of lower-tier requirements 5,000 t
Qualifying quantity (tonnes) for the application of upper-tier requirements 50,000 t
REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
National regulations
Other regulations, limitations and prohibitive regulations
BG-Merkblätter: M 044 "Polyurethane production/Isocyanates"
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge. However,
this shall not constitute a guarantee for any specific product
features and shall not establish a legally valid contractual
relationship.
Relevant phrases
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H412 Harmful to aquatic life with long lasting effects.
Department issuing SDS: EHS department
Contact: Sara Lacerda, Tel.: +351 234 101 010
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organisation
(Contd. on page 12)
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GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern (REACH regulation)
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 3: Flammable liquids – Category 3
Acute Tox. 1: Acute toxicity – Category 1
Acute Tox. 2: Acute toxicity – Category 2
Acute Tox. 4: Acute toxicity – Category 4
Skin Corr. 1B: Skin corrosion/irritation – Category 1B
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Resp. Sens. 1: Respiratory sensitisation – Category 1
Skin Sens. 1: Skin sensitisation – Category 1
Carc. 2: Carcinogenicity – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
Asp. Tox. 1: Aspiration hazard – Category 1
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
* Data compared to the previous version altered.
According to Annex II of the REACH regulation, the modified sections in this version of the Safety
Data Sheet in comparison with the previous one are marked with asterisks.
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