DIESEL - Shell E5 B7 Diesel (Mar 2021)
DIESEL - Shell E5 B7 Diesel (Mar 2021)
DIESEL - Shell E5 B7 Diesel (Mar 2021)
Shell E5 B7 Diesel
Restrictions on use :
This product must not be used in applications other than those
listed in Section 1 without first seeking the advice of the
supplier., This product is not to be used as a solvent or
cleaning agent; for lighting or brightening fires; as a skin
cleanser.
2. HAZARDS IDENTIFICATION
GHS Classification
Flammable liquids : Category 3
Aspiration hazard : Category 1
Acute toxicity (Inhalation) : Category 4
Skin irritation : Category 2
Carcinogenicity : Category 2
Specific target organ toxicity - : Category 2 (Blood, thymus, Liver)
repeated exposure
Short-term (acute) aquatic : Category 2
hazard
Long-term (chronic) aquatic : Category 2
hazard
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SAFETY DATA SHEET
Shell E5 B7 Diesel
Precautionary statements :
Prevention:
P210 Keep away from heat/ sparks/ open flames/ hot surfaces.
No smoking.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER or doctor/ physician.
P331 Do NOT induce vomiting.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
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Shell E5 B7 Diesel
Hazardous components
Further information
Contains:
Chemical name Identification number Concentration (% w/w)
Cumene 98-82-8 >= 0 - <= 0.5
Naphthalene 91-20-3 >= 0 - <= 0.5
4. FIRST-AID MEASURES
General advice : Not expected to be a health hazard when used under normal
conditions.
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SAFETY DATA SHEET
Shell E5 B7 Diesel
In case of skin contact : Remove contaminated clothing. Immediately flush skin with
large amounts of water for at least 15 minutes, and follow by
washing with soap and water if available. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical
facility for additional treatment.
When using high pressure equipment, injection of product
under the skin can occur. If high pressure injuries occur, the
casualty should be sent immediately to a hospital. Do not wait
for symptoms to develop.
Obtain medical attention even in the absence of apparent
wounds.
Most important symptoms : Respiratory irritation signs and symptoms may include a
and effects, both acute and temporary burning sensation of the nose and throat, coughing,
delayed and/or difficulty breathing.
Skin irritation signs and symptoms may include a burning
sensation, redness, swelling, and/or blisters.
Eye irritation signs and symptoms may include a burning
sensation, redness, swelling, and/or blurred vision.
If material enters lungs, signs and symptoms may include
coughing, choking, wheezing, difficulty in breathing, chest
congestion, shortness of breath, and/or fever.
If any of the following delayed signs and symptoms appear
within the next 6 hours, transport to the nearest medical
facility: fever greater than 101° F (38.3°C), shortness of
breath, chest congestion or continued coughing or wheezing.
Liver damage may be indicated by loss of appetite, jaundice
(yellowish skin and eye colour), fatigue, bleeding or easy
bruising and sometimes pain and swelling in the upper right
abdomen.
Protection of first-aiders : When administering first aid, ensure that you are wearing the
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SAFETY DATA SHEET
Shell E5 B7 Diesel
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
Unsuitable extinguishing : Do not use direct water jets on the burning product as they
media could cause a steam explosion and spread of the fire.
Simultaneous use of foam and water on the same surface is
to be avoided as water destroys the foam.
Hazchem Code : 3Y
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SAFETY DATA SHEET
Shell E5 B7 Diesel
Methods and materials for : For small liquid spills (< 1 drum), transfer by mechanical
containment and cleaning up means to a labeled, sealable container for product recovery or
safe disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove
contaminated soil and dispose of safely.
For large liquid spills (> 1 drum), transfer by mechanical
means such as vacuum truck to a salvage tank for recovery or
safe disposal. Do not flush away residues with water. Retain
as contaminated waste. Allow residues to evaporate or soak
up with an appropriate absorbent material and dispose of
safely. Remove contaminated soil and dispose of safely
Prevent from spreading or entering into drains, ditches or
rivers by using sand, earth, or other appropriate barriers.
Handling
General Precautions : Avoid breathing of or direct contact with material. Only use in
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Shell E5 B7 Diesel
Advice on safe handling : Ensure that all local regulations regarding handling and
storage facilities are followed.
Avoid inhaling vapour and/or mists.
Avoid prolonged or repeated contact with skin.
When using do not eat or drink.
Extinguish any naked flames. Do not smoke. Remove ignition
sources. Avoid sparks.
Earth all equipment.
Properly dispose of any contaminated rags or cleaning
materials in order to prevent fires.
Use local exhaust ventilation if there is risk of inhalation of
vapours, mists or aerosols.
The vapour is heavier than air, spreads along the ground and
distant ignition is possible.
Product Transfer : Avoid splash filling Wait 2 minutes after tank filling (for tanks
such as those on road tanker vehicles) before opening
hatches or manholes. Wait 30 minutes after tank filling ( for
large storage tanks) before opening hatches or manholes.
Keep containers closed when not in use. Contamination
resulting from product transfer may give rise to light
hydrocarbon vapour in the headspace of tanks that have
previously contained gasoline. This vapour may explode if
there is a source of ignition. Partly filled containers present a
greater hazard than those that are full, therefore handling,
transfer and sampling activities need special care. Even with
proper grounding and bonding, this material can still
accumulate an electrostatic charge. If sufficient charge is
allowed to accumulate, electrostatic discharge and ignition of
flammable air-vapour mixtures can occur. Be aware of
handling operations that may give rise to additional hazards
that result from the accumulation of static charges. These
include but are not limited to pumping (especially turbulent
flow), mixing, filtering, splash filling, cleaning and filling of
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Shell E5 B7 Diesel
Storage
Other data : Drum and small container storage:
Drums should be stacked to a maximum of 3 high.
Use properly labeled and closable containers.
Tank storage:
Tanks must be specifically designed for use with this product.
Bulk storage tanks should be diked (bunded).
Locate tanks away from heat and other sources of ignition.
Must be stored in a diked (bunded) well- ventilated area, away
from sunlight, ignition sources and other sources of heat.
Vapours from tanks should not be released to atmosphere.
Breathing losses during storage should be controlled by a
suitable vapour treatment system.
The vapour is heavier than air. Beware of accumulation in pits
and confined spaces.
Keep container tightly closed and in a cool, well-ventilated
place.
Keep in a cool place.
Electrostatic charges will be generated during pumping.
Electrostatic discharge may cause fire. Ensure electrical
continuity by bonding and grounding (earthing) all equipment
to reduce the risk.
The vapours in the head space of the storage vessel may lie
in the flammable/explosive range and hence may be
flammable.
Refer to section 15 for any additional specific legislation
covering the packaging and storage of this product.
Keep in a bunded area with a sealed (low permeability) floor,
to provide containment against spillage.
Prevent ingress of water.
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Shell E5 B7 Diesel
Specific use(s) : See additional references that provide safe handling practices
for liquids that are determined to be static accumulators:
American Petroleum Institute 2003 (Protection Against
Ignitions Arising out of Static, Lightning and Stray Currents) or
National Fire Protection Agency 77 (Recommended Practices
on Static Electricity).
IEC/TS 60079-32-1: Electrostatic hazards, guidance
Ensure that all local regulations regarding handling and
storage facilities are followed.
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Shell E5 B7 Diesel
Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or in the general
workplace may be required to confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also be appropriate.
Validated exposure measurement methods should be applied by a competent person and
samples analysed by an accredited laboratory.
Examples of sources of recommended exposure measurement methods are given below or
contact the supplier. Further national methods may be available.
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods
http://www.cdc.gov/niosh/
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods
http://www.osha.gov/
L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances
http://www.hse.gov.uk/
Institut für Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dguv.de/inhalt/index.jsp
Engineering measures : The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include:
Use sealed systems as far as possible.
Firewater monitors and deluge systems are recommended.
Adequate explosion-proof ventilation to control airborne
concentrations below the exposure guidelines/limits.
Local exhaust ventilation is recommended.
Eye washes and showers for emergency use.
General Information:
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Shell E5 B7 Diesel
Hand protection
Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. When prolonged or frequent
repeated contact occurs. Nitrile rubber. For incidental
contact/splash protection Neoprene, PVC gloves may be
suitable. For continuous contact we recommend gloves with
breakthrough time of more than 240 minutes with preference
for > 480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same but
recognize that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough
time maybe acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Suitability and durability of a glove is dependent on usage,
e.g. frequency and duration of contact, chemical resistance of
glove material, dexterity. Always seek advice from glove
suppliers. Contaminated gloves should be replaced. Personal
hygiene is a key element of effective hand care. Gloves must
only be worn on clean hands. After using gloves, hands
should be washed and dried thoroughly. Application of a non-
perfumed moisturizer is recommended.
Eye protection : If material is handled such that it could be splashed into eyes,
protective eyewear is recommended.
If a local risk assessment deems it so then chemical splash
goggles may not be required and safety glasses may provide
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Skin and body protection : Wear chemical resistant gloves/gauntlets and boots. Where
risk of splashing, also wear an apron.
Appearance : liquid
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Shell E5 B7 Diesel
Solubility(ies)
Water solubility : negligible
Solubility in other solvents : Data not available
Viscosity
Viscosity, kinematic : Method: Unspecified
Not applicable
2 - 4.5 mm2/s (40.0 °C / 104.0 °F)
Method: Unspecified
Method: Unspecified
Not applicable
Explosive properties : Classification Code: Not classified.
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Reactivity : The product does not pose any further reactivity hazards in
addition to those listed in the following sub-paragraph.
Conditions to avoid : Avoid heat, sparks, open flames and other ignition sources.
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Acute toxicity
Product:
Acute oral toxicity : LD50 rat: > 5,000 mg/kg
Remarks: Low toxicity:
Skin corrosion/irritation
Product:
Remarks: Irritating to skin.
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Shell E5 B7 Diesel
Remarks: Limited evidence of carcinogenic effect, Repeated skin contact has resulted in irritation
and skin cancer in animals.
Reproductive toxicity
Product:
:
Remarks: Not a developmental toxicant., Based on available
data, the classification criteria are not met., Does not impair
fertility.
Aspiration toxicity
Product:
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Shell E5 B7 Diesel
Further information
Product:
Remarks: Classifications by other authorities under varying regulatory frameworks may exist.
Ecotoxicity
Product:
Toxicity to fish (Acute :
toxicity) Remarks: LL/EL/IL50 > 1 <= 10 mg/l
Toxic
Toxicity to algae/aquatic :
plants (Acute toxicity) Remarks: LL/EL/IL50 > 1 <= 10 mg/l
Toxic
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Bioaccumulative potential
Product:
Bioaccumulation : Remarks: Contains constituents with the potential to
bioaccumulate.
13 DISPOSAL INFORMATION
Disposal methods
Waste from residues : Recover or recycle if possible.
Send to drum recoverer or metal reclaimer.It is the
responsibility of the waste generator to determine the toxicity
and physical properties of the material generated to determine
the proper waste classification and disposal methods in
compliance with applicable regulations.
Drain container thoroughly.Do not dispose into the
environment, in drains or in water courses
After draining, vent in a safe place away from sparks and
fire.Do not dispose of tank water bottoms by allowing them to
drain into the ground. This will result in soil and groundwater
contamination.
Residues may cause an explosion hazard. Do not puncture,
cut or weld uncleaned drums.Waste arising from a spillage or
tank cleaning should be disposed of in accordance with
prevailing regulations, preferably to a recognised collector or
contractor. The competence of the collector or contractor
should be established beforehand.
MARPOL - see International Convention for the Prevention of
Pollution from Ships (MARPOL 73/78) which provides
technical aspects at controlling pollutions from ships.
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Local legislation
Remarks : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
Local regulations may be more stringent than regional or
national requirements and must be complied with.
National Regulations
Hazchem Code : 3Y
International Regulations
ADR
UN number : 1202
Proper shipping name : GAS OIL
Class : 3
Packing group : III
Labels : 3
Environmentally hazardous : yes
IATA-DGR
UN/ID No. : UN 1202
Proper shipping name : GAS OIL
Class : 3
Packing group : III
Labels : 3
IMDG-Code
UN number : UN 1202
Proper shipping name : GAS OIL
Class : 3
Packing group : III
Labels : 3
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied. MARPOL Annex 1 rules apply for bulk shipments by sea.
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AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by Land
of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer;
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Further information
Training advice : Provide adequate information, instruction and training for
operators.
Other information : This product is intended for use in closed systems only.
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.
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