Safety Data Sheet

KERAPOXY CQ comp. A
Safety Data Sheet dated: 11/06/2021 - version 2
Date of first edition: 07/05/2021

SECTION 1: Identification
Product Identifier
Mixture identification:
Trade name: KERAPOXY CQ comp. A
Trade code: 90639990
Recommended use of the chemical and restrictions on use
Recommended use: Acid-resistant epoxy grout and adhesive for ceramic tiles
Uses advised against: Data not available
Supplier's details
Company: MAPEI Far East Pte Ltd
28, Tuas West Road - 638383 Singapore
sicurezza@mapei.it - www.mapei.com.sg
Emergency phone number
T. +65/68623488 (Mo-Fri 8.30am-5.30pm)

SECTION 2:Hazards identification

Classification of the substance or mixture

Skin Irrit. 2 Causes skin irritation.

Eye Irrit. 2A Causes serious eye irritation.
Skin Sens. 1A May cause an allergic skin reaction.
Adverse physicochemical, human health and environmental effects:
No other hazards
GHS label elements, including precautionary statements
Pictograms and Signal Words

Warning

Hazard statements:
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.

Precautionary statements:
P261 Avoid breathing mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.

P321 Specific treatment (see supplementary instructions on this label).

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents in accordance with local regulation.
Other hazards which do not result in a classification
Other Hazards: No other hazards
This product contains crystalline silica (quartz sand). IARC has classified crystalline silica as a Group 1 carcinogen. Both IARC and
NTP consider silica as a known human carcinogen. Evidence is based on the chronic and long-term exposure workers have had to
respirable sized crystalline silica dust particles. Because this product is in liquid or paste form, it does not pose a dust hazard;
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 respirable sized crystalline silica dust particles. Because this product is in liquid or paste form, it does not pose a dust hazard;
therefore, this classification is not relevant. (Note: sanding of the hardened product may create a silica dust hazard)
This preparation contains low molecular weight epoxy resins. Cross sensitisation to other epoxies is possible. Avoid also exposure to
spray mist and vapour.

SECTION 3:Composition/information on ingredients

Substances
N.A.
Mixtures
Mixture identification: KERAPOXY CQ comp. A

Hazardous components within the meaning of Singapore GHS and related classification:
Concentration Name Ident. Numb. Classification Registration Number
(% w/w)
≥10 - <20 % reaction product: bisphenol-A- CAS:25068-38-6 Eye Irrit. 2A, H319; Skin Irrit. 2, 01-2119456619-26-xxxx
(epichlorhydrin); epoxy resin EC:500-033-5 H315; Skin Sens. 1, H317; Aquatic
(number average molecular weight Index:603-074- Chronic 2, H411
<= 700) 00-8

≥2.5 - <5 % Formaldehyde, oligomeric reaction CAS:9003-36-5 Skin Irrit. 2, H315; Skin Sens. 1A, 01-2119454392-40-XXXX
products with 1-chloro-2,3- EC:500-006-8 H317; Aquatic Chronic 2, H411
epoxypropane and phenol

≥2.5 - <5 % oxirane, mono[(C12-14- CAS:68609-97-2 Skin Irrit. 2, H315; Skin Sens. 1, 01-2119485289-22-XXXX
alkyloxy)methyl] derivs. EC:271-846-8 H317
Index:603-103-
00-4

≥0.49 - <1 % Reaction mass of Bis(1,2,2,6,6- CAS:1065336-91- Skin Sens. 1, H317; Aquatic Acute 01-2119491304-40-xxxx
pentamethyl-4-piperidyl) sebacate 5 1, H400; Aquatic Chronic 1, H410
and Methyl 1,2,2,6,6-pentamethyl-4- EC:915-687-0
piperidyl sebacate

≥0.01 - <0.016 zinc pyrithione CAS:13463-41-7 Acute Tox. 3, H301; Acute Tox. 3,
% EC:236-671-3 H331; Eye Dam. 1, H318; Aquatic
Acute 1, H400; Aquatic Chronic 1,
H410, M-Chronic:10, M-Acute:100

SECTION 4: First-aid measures

Description of necessary first-aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
Remove contaminated clothing immediately and dispose of safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist
immediately.
Protect uninjured eye.
In case of Ingestion:
Do not induce vomiting, get medical attention showing the SDS and the hazard label.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
Most important symptoms/effects, acute and delayed
Eye irritation
Eye damages
Skin Irritation
Erythema
Indication of immediate medical attention and special treatment needed, if necessary
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).
Treatment:
(see paragraph 4.1)

SECTION 5: Fire-fighting measures

Suitable extinguishing media
Water.
Carbon dioxide (CO2).
Unsuitable extinguishing media:
None in particular.
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 None in particular.
Special hazards arising from the chemical
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
Hazardous combustion products: N.A.
Explosive properties: ==
Oxidizing properties: N.A.
Special protective actions for fire-fighters
Use suitable breathing apparatus.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Limit leakages with earth or sand.
Methods and material for containment and cleaning up
Suitable material for taking up: absorbing material, organic, sand
Retain contaminated washing water and dispose it.

SECTION 7: Handling and storage

Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals in the containers.
Contaminated clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
Conditions for safe storage, including any incompatibilities
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.

SECTION 8: Exposure controls/personal protection

Control parameters

Predicted No Effect Concentration (PNEC) values

Component CAS-No. PNEC Exposure Route Exposure Frequency Remark
Limit
reaction product: 25068-38-6 0,006 mg/l Fresh Water
bisphenol-A-
(epichlorhydrin); epoxy
resin (number average
molecular weight <=
700)

0,0006 Marine water

mg/l

0,0627 Freshwater
mg/kg sediments

0,00627 Marine water

mg/kg sediments

Formaldehyde, oligomeric 9003-36-5 10 mg/l Microorganisms in

reaction products with 1- sewage treatments
chloro-2,3-epoxypropane
and phenol

0,003 mg/l Fresh Water

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 0,294 Freshwater
mg/kg sediments

0,0003 Marine water

mg/l

0,0294 Marine water

mg/kg sediments

0,237 Soil
mg/kg

oxirane, mono[(C12-14- 68609-97-2 0,00072 Marine water

alkyloxy)methyl] derivs. mg/l

0,0072 Fresh Water

mg/l

66,77 Freshwater
mg/kg sediments

6,677 Marine water

mg/kg sediments

80,12 Soil
mg/kg

10 mg/l Microorganisms in
sewage treatments

Reaction mass of 1065336-91-5 0,0022 Fresh Water

Bis(1,2,2,6,6- mg/l
pentamethyl-4-piperidyl)
sebacate and Methyl
1,2,2,6,6-pentamethyl-4-
piperidyl sebacate

0,00022 Marine water

mg/l

0,009 mg/l Intermittent release

1,05 mg/kg Freshwater
sediments

0,11 mg/kg Marine water

sediments

0,21 mg/kg Soil

1 mg/l Microorganisms in
sewage treatments

Derived No Effect Level. (DNEL)

Component CAS-No. Worker Worker Consu Exposure Route Exposure Frequency Remark
Industr Profess mer
y ional
reaction product: 25068-38-6 8,3 Human Dermal Short Term, systemic
bisphenol-A- mg/kg effects
(epichlorhydrin); epoxy
resin (number average
molecular weight <=
700)

12,25 Human Inhalation Short Term, systemic

mg/m3 effects

8,3 Human Dermal Long Term, systemic

mg/kg effects

12,25 Human Inhalation Long Term, systemic

mg/m3 effects

3,571 Human Dermal Short Term, systemic

mg/kg effects

0,75 Human Oral Short Term, systemic

mg/kg effects

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 3,571 Human Dermal Long Term, systemic
mg/kg effects

0,75 Human Oral Long Term, systemic

mg/kg effects

Reaction mass of 1065336-91-5 2,5 1,25 Human Dermal Short Term, systemic
Bis(1,2,2,6,6- mg/kg mg/kg effects
pentamethyl-4-piperidyl)
sebacate and Methyl
1,2,2,6,6-pentamethyl-4-
piperidyl sebacate

2,35 0,58 Human Inhalation Short Term, systemic

mg/m3 mg/m3 effects

2,35 0,58 Human Inhalation Long Term, systemic

mg/m3 mg/m3 effects

2,5 1,25 Human Dermal Long Term, systemic

mg/kg mg/kg effects

1,25 Human Oral Short Term, systemic

mg/kg effects

1,25 Human Oral Long Term, systemic

mg/kg effects

Appropriate engineering controls

N.A.
Individual protection measures, such as personal protective equipment (PPE)
Eye protection:
Use close fitting safety goggles, don't use eye lens.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Protection for hands:
Suitable materials for safety gloves; EN ISO 374:
Polychloroprene - CR: thickness >=0,5mm; breakthrough time >=480min.
Nitrile rubber - NBR: thickness >=0,35mm; breakthrough time >=480min.
Butyl rubber - IIR: thickness >=0,5mm; breakthrough time >=480min.
Fluorinated rubber - FKM: thickness >=0,4mm; breakthrough time >=480min.
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Respiratory protection:
Personal Protective Equipment should comply with relevant CE standards (as EN ISO 374 for gloves and EN ISO 166 for goggles),
correctly maintained and stored. Consult the supplier to check the suitability of equipment against specific chemicals and for user
information.
In case of insufficient ventilation use mask with ABEKP filters (EN 14387).

SECTION 9: Physical and chemical properties

Physical state: Liquid
Appearance: paste
Color: various
Odour: Characteristic
Odour threshold: N.A.
pH: N.A.
Melting point / freezing point: N.A.
Initial boiling point and boiling range: N.A.
Flash point: N.A.
Evaporation rate: N.A.
Flammability (Solid, Gas): N.A.
Upper/lower flammability or explosive limits: N.A.
Vapour pressure: N.A.
Vapour density: N.A.
Relative density: 1.85 g/cm3
Solubility in water: Insoluble
Solubility in oil: soluble
Partition coefficient (n-octanol/water): N.A.
Auto-ignition temperature: N.A.
Decomposition temperature: N.A.
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 Decomposition temperature: N.A.
Viscosity: N.A.

SECTION 10: Stability and reactivity

Reactivity
Stable under normal conditions
Chemical stability
Data not available.
Possibility of hazardous reactions
None.
Conditions to avoid
Stable under normal conditions.
Incompatible materials
None in particular.
Hazardous decomposition products

SECTION 11: Toxicological information

Information on toxicological effects

Toxicological information of the mixture:

There is no toxicological data available on the mixture. Consider the individual concentration of
each component to assess toxicological effects resulting from exposure to the mixture.

Toxicological information on main components of the mixture:

reaction product: a) acute toxicity LD50 Oral Rat > 15000 mg/kg
bisphenol-A-
(epichlorhydrin); epoxy
resin (number average
molecular weight <=
700)

LD50 Skin Rabbit > 23000 mg/kg

LD50 Oral Rat = 11400 mg/kg
i) STOT-repeated NOAEL Oral Rat = 50 mg/kg
exposure

NOAEL Skin Rat = 100 mg/kg

Formaldehyde, oligomeric a) acute toxicity LD50 Oral Rat > 5000,00000 mg/kg
reaction products with 1-
chloro-2,3-epoxypropane
and phenol

LD50 Skin Rat > 2000 mg/kg

i) STOT-repeated NOAEL Oral = 250 mg/kg
exposure

oxirane, mono[(C12-14- a) acute toxicity LD50 Oral Rat = 19200 mg/kg

alkyloxy)methyl] derivs.

LD50 Skin Rabbit = 4000,00000 mg/kg

Reaction mass of a) acute toxicity LD50 Oral Rat = 3230 mg/kg

Bis(1,2,2,6,6-
pentamethyl-4-piperidyl)
sebacate and Methyl
1,2,2,6,6-pentamethyl-4-
piperidyl sebacate

zinc pyrithione a) acute toxicity LD50 Skin Rabbit = 100 mg/kg

LD50 Oral Rat = 177 mg/kg
LC50 Inhalation Rat 0,05 mg/l 4h
LD50 Skin Rabbit = 100 mg/kg

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If not differently specified, the information required in the regulation and listed below must be considered as N.A.
a) acute toxicity
b) skin corrosion/irritation
c) serious eye damage/irritation
d) respiratory or skin sensitisation
e) germ cell mutagenicity
f) carcinogenicity
g) reproductive toxicity
h) STOT-single exposure
Toxicological kinetics, metabolism
and distribution information

i) STOT-repeated exposure
j) aspiration hazard

SECTION 12: Ecological information

Toxicity
Adopt good working practices, so that the product is not released into the environment.
Eco-Toxicological Information:

List of components with eco-toxicological properties

Component Ident. Numb. Ecotox Infos
reaction product: bisphenol-A- CAS: 25068-38-6 - a) Aquatic acute toxicity : LC50 Fish > 2 mg/L 96
(epichlorhydrin); epoxy resin EINECS: 500-033-5
(number average molecular weight - INDEX: 603-074-
<= 700) 00-8

a) Aquatic acute toxicity : EC50 Daphnia > 1,8 mg/L 48

a) Aquatic acute toxicity : LC50 Algae > 11 mg/L 72
a) Aquatic acute toxicity : LC50 Daphnia = 1,3 mg/L 96
b) Aquatic chronic toxicity : NOEC Daphnia = 0,3 mg/L
Formaldehyde, oligomeric reaction CAS: 9003-36-5 - a) Aquatic acute toxicity : LC50 Fish = 5,70000 mg/L 96h
products with 1-chloro-2,3- EINECS: 500-006-8
epoxypropane and phenol

a) Aquatic acute toxicity : EC50 Daphnia = 2,55 mg/L 48h

a) Aquatic acute toxicity : EC50 Algae = 1,80000 mg/L 72h
oxirane, mono[(C12-14- CAS: 68609-97-2 - a) Aquatic acute toxicity : LC50 Fish > 100,00000 mg/L 96h
alkyloxy)methyl] derivs. EINECS: 271-846-8
- INDEX: 603-103-
00-4

a) Aquatic acute toxicity : EL50 Daphnia = 7,20000 mg/L 48h

a) Aquatic acute toxicity : EC50 Algae = 843,00000 mg/L 72h
b) Aquatic chronic toxicity : NOEC Algae = 500 mg/L 72h
Reaction mass of Bis(1,2,2,6,6- CAS: 1065336-91-5 a) Aquatic acute toxicity : EC50 Daphnia = 20 mg/L 24
pentamethyl-4-piperidyl) sebacate - EINECS: 915-687-
and Methyl 1,2,2,6,6-pentamethyl- 0
4-piperidyl sebacate

a) Aquatic acute toxicity : EC50 Algae = 0,22 mg/L 72

a) Aquatic acute toxicity : LC50 Fish = 0,97 mg/L 96
a) Aquatic acute toxicity : LC50 Fish = 7,9 mg/L 96
a) Aquatic acute toxicity : LC50 Fish = 0,9 mg/L 96
b) Aquatic chronic toxicity : NOEC Daphnia = 6,3 mg/L - 21 d
zinc pyrithione CAS: 13463-41-7 - G : LD50 Avian Colinus virginianus = 64 mg/kg NZ_CCID
EINECS: 236-671-3

Persistence and degradability

Component Persitence/Degradabili
ty:
oxirane, mono[(C12-14- Readily biodegradable
alkyloxy)methyl] derivs.

Bioaccumulative potential
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Bioaccumulative potential

Component Bioaccumulation
oxirane, mono[(C12-14- Not bioaccumulative
alkyloxy)methyl] derivs.

Mobility in soil

N.A.
Other adverse effects

SECTION 13: Disposal considerations

Disposal methods
The generation of waste should be avoided or minimized wherever possible. Recover if possible.
Methods of disposal:
Disposal of this product, solutions, packaging and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority requirements.
Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor.
Do not dispose of waste into sewers.
Disposal considerations:
Do not allow to enter drains or watercourses.
Dispose of product according to all federal, state and local applicable regulations.
If this product is mixed with other wastes, the original waste product code may no longer apply and the appropriate code should be
assigned.
Dispose of containers contaminated by the product in accordance with local or national legal provisions. For further information,
contact your local waste authority.
Special precautions:
This material and its container must be disposed of in a safe way. Care should be taken when handling untreated empty containers.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Empty containers or liners may retain some product residues. Do not re-use empty containers.

SECTION 14: Transport information

Not classified as dangerous in the meaning of transport regulations.
UN number
N.A.
UN proper shipping name
N.A.
Transport hazard class(es)
N.A.
Packing group, if applicable
N.A.
Environmental hazards
N.A.
Special precautions for user
N.A.
Road and Rail ( ADR-RID ) :
N.A.
ADR-Hazard identification number: NA
Air ( IATA ) :
N.A.
Sea ( IMDG ) :
N.A.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N.A.

SECTION 15: Safety, health and environmental regulations specific for the product in question
This Safety Data Sheet has been prepared according to:
SS 586 : Part 1 (2014)
SS 586 : Part 2 (2014)
SS 586 : Part 3 (2014)

SECTION 16: Other information

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Code Description
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
Key/legend to the abbreviations and acronyms
ACGIH: American Conference of Governmental Industrial Hygienists
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
AND: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ATE: Acute Toxicity Estimate
ATEmix: Acute toxicity Estimate (Mixtures)
BCF: Biological Concentration Factor
BEI: Biological Exposure Index
BOD: Biochemical Oxygen Demand
CAS: Chemical Abstracts Service (division of the American Chemical Society).
CAV: Poison Center
CE: European Community
CLP: Classification, Labeling, Packaging.
CMR: Carcinogenic, Mutagenic and Reprotoxic
COD: Chemical Oxygen Demand
COV: Volatile Organic Compound
CSA: Chemical Safety Assessment
CSR: Chemical Safety Report
DMEL: Derived Minimal Effect Level
DNEL: Derived No Effect Level.
DPD: Dangerous Preparations Directive
DSD: Dangerous Substances Directive
EC50: Half Maximal Effective Concentration
ECHA: European Chemicals Agency
EINECS: European Inventory of Existing Commercial Chemical Substances.
ES: Exposure Scenario
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of Chemicals.
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).
IC50: half maximal inhibitory concentration
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
IRCCS: Scientific Institute for Research, Hospitalization and Health Care
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
LDLo: Leathal Dose Low
N.A.: Not Applicable
N/A: Not Applicable
N/D: Not defined/ Not available
NA: Not available
NIOSH: National Institute for Occupational Safety and Health
NOAEL: No Observed Adverse Effect Level
OSHA: Occupational Safety and Health Administration.
PBT: Persistent, Bioaccumulative and Toxic
PGK: Packaging Instruction
PNEC: Predicted No Effect Concentration.
PSG: Passengers
RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
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 STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
vPvB: Very Persistent, Very Bioaccumulative.
WGK: German Water Hazard Class.
Date of revision of this SDS
Safety Data Sheet dated: 11/06/2021 - version 2
Paragraphs modified from the previous revision:
- 2. HAZARDS IDENTIFICATION
- 3. COMPOSITION/INFORMATION ON INGREDIENTS
- 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
- 11. TOXICOLOGICAL INFORMATION
- 12. ECOLOGICAL INFORMATION

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