Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)

bbb

Melpool 70/G
Version number: 5.0 Revision: 2018-08-07
Replaces version of: 2017-10-20 (4) First version: 2010-11-11

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name Melpool 70/G

Registration number (REACH) not relevant (mixture)

CAS number not relevant (mixture)

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses Oxidizing agent

Disinfectant
Bleaching agent

Uses advised against Do not use for squirting or spraying

Do not use for products which come into direct
contact with the skin

1.3 Details of the supplier of the safety data sheet

Melspring International B.V. Telephone: ++31 (0) 26 - 38420 - 00
Arnhemsestraatweg 8 Telefax: ++31 (0) 26 - 38420 - 11
NL-6881 NG Velp
Netherlands

e-mail (competent person) sdb@csb-online.de

Please do not use this e-mail adress to ask for the latest safety data sheet. For this purpose contact
Melspring International B.V.

1.4 Emergency telephone number

As above or next toxicological information centre.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

Classification

Section Hazard class Category Hazard class and Hazard state-

category ment
2.14 oxidising solid 2 Ox. Sol. 2 H272

3.1O acute toxicity (oral) 4 Acute Tox. 4 H302

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Classification

Section Hazard class Category Hazard class and Hazard state-

category ment
3.2 skin corrosion/irritation 1B Skin Corr. 1B H314

3.3 serious eye damage/eye irritation 1 Eye Dam. 1 H318

4.1A hazardous to the aquatic environment - acute 1 Aquatic Acute 1 H400

hazard

for full text of abbreviations: see SECTION 16

The most important adverse physicochemical, human health and environmental effects

Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi-
dermis and into the dermis.
Spillage and fire water can cause pollution of watercourses.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)

Signal word danger

Pictograms

GHS03, GHS05,
GHS07, GHS09

Hazard statements
H272 May intensify fire; oxidiser.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H400 Very toxic to aquatic life.

Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P220 Keep away from clothing and other combustible materials.
P260 Do not breathe dust.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water or shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.

Supplemental hazard information

EUH031 Contact with acids liberates toxic gas.

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Child-resistant fastening yes

Tactile warning of danger yes

Hazardous ingredients for labelling calcium hypochlorite

2.3 Other hazards

Warning! Do not use together with other products. May release dangerous gases (chlorine).

Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

SECTION 3: Composition/information on ingredients

3.1 Substances
not relevant (mixture)

3.2 Mixtures

Description of the mixture

Hazardous ingredients

Name of sub- Identifier Wt% Classification acc. to Pictograms M-Factors

stance GHS
calcium hypochlor- CAS No ≥ 70 Ox. Sol. 2 / H272 M-factor (acute) =
ite 7778-54-3 Acute Tox. 4 / H302 10.0
Skin Corr. 1B / H314
EC No Eye Dam. 1 / H318
231-908-7 Aquatic Acute 1 / H400

Index No
017-012-00-7

calcium dihydroxide CAS No 1 – < 10 Skin Irrit. 2 / H315

1305-62-0 Eye Dam. 1 / H318
STOT SE 3 / H335
EC No
215-137-3

calcium chloride CAS No 1 – < 10 Eye Irrit. 2 / H319

10043-52-4

EC No
233-140-8

Index No
017-013-00-2

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SECTION 4: First aid measures

4.1 Description of first aid measures

General notes

Self-protection of the first aider.

Remove affected person from the danger area and lay down.
Do not leave affected person unattended.
Take off immediately all contaminated clothing.
In all cases of doubt, or when symptoms persist, seek medical advice.

Following inhalation

Provide fresh air.

Get medical advice/attention.

Following skin contact

Rinse skin with water/shower.

Call a physician immediately. Causes poorly healing wounds.
Wash contaminated clothing before reuse.

Following eye contact

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Remove contact lenses, if present and easy to do. Continue rinsing.

Following ingestion

Rinse mouth immediately and drink plenty of water.

Do NOT induce vomiting.
Get medical advice/attention.
Provide fresh air.

Notes for the doctor

none

4.2 Most important symptoms and effects, both acute and delayed
Symptoms may develop several hours following exposure; medical observation therefore necessary
for at least 48 hours.

4.3 Indication of any immediate medical attention and special treatment needed
none

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

excess of water

Unsuitable extinguishing media

All but water

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5.2 Special hazards arising from the substance or mixture

Hazardous decomposition products: Section 10.
Oxidising property.
In contact with Water, Combustible materials: Danger of fire, Explosion risk.

Hazardous combustion products

carbon monoxide (CO), carbon dioxide (CO2), hydrogen chloride (HCl), chlorine compound, toxic sub-
stances

5.3 Advice for firefighters

Keep containers cool with water spray.
In case of fire and/or explosion do not breathe fumes.
Co-ordinate firefighting measures to the fire surroundings.
Do not allow firefighting water to enter drains or water courses.
Collect contaminated firefighting water separately.
Fight fire with normal precautions from a reasonable distance.

Special protective equipment for firefighters

wear self-contained breathing apparatus

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

Remove persons to safety.

Ventilate affected area.
Wearing of suitable protective equipment (including personal protective equipment referred to under
Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing.

For emergency responders

Wear breathing apparatus if exposed to vapours/dust/spray/gases.

6.2 Environmental precautions

Keep away from drains, surface and ground water.
Retain contaminated washing water and dispose of it.
If substance has entered a water course or sewer, inform the responsible authority.

6.3 Methods and material for containment and cleaning up

Advices on how to contain a spill

take up mechanically

Advices on how to clean up a spill

Collect spillage.

Other information relating to spills and releases

Place in appropriate containers for disposal.

Ventilate affected area.

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6.4 Reference to other sections

Hazardous combustion products: see section 5.
Personal protective equipment: see section 8.
Incompatible materials: see section 10.
Disposal considerations: see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes.
Do not breathe dust.
Used in Fume hood.

Measures to prevent fire as well as aerosol and dust generation

Use local and general ventilation.

Keep away from sources of ignition - No smoking.

Specific notes/details

Dust deposits may accumulate on all deposition surfaces in a technical room.

Handling of incompatible substances or mixtures

Keep away from

organic absorbing material, pulp/paper

Measures to protect the environment

Avoid release to the environment.

Advice on general occupational hygiene

Do not eat, drink and smoke in work areas.

Wash hands after use.
Preventive skin protection (barrier creams/ointments) is recommended.
Remove contaminated clothing and protective equipment before entering eating areas.

7.2 Conditions for safe storage, including any incompatibilities

Flammability hazards

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Take precautionary measures against static discharge.
Keep valves and fittings free from oil and grease.

Incompatible substances or mixtures

Incompatible materials: see section 10.

Observe hints for combined storage.
Keep/store away from clothing/combustible materials.
Take any precaution to avoid mixing with combustibles.
Store away from acids.
Keep away from acids.
Store away from reducing agents.

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Protect against external exposure, such as

heat, frost, direct light irradiation

Consideration of other advice

Keep away from food, drink and animal feedingstuffs.

Store in a dry place. Store in a closed container.
Store in a well-ventilated place. Keep cool.
Keep locked up and out of the reach of children.
Protect against Impurities.

Ventilation requirements

Provision of sufficient ventilation.

Packaging compatibilities

Only packagings which are approved (e.g. acc. to ADR) may be used.

7.3 Specific end use(s)

No information available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limit values (Workplace Exposure Limits)

Coun- Name of agent CAS No Nota- Identi- TWA TWA STEL STEL Source
try tion fier [ppm] [mg/m³] [ppm] [mg/m³]
EU calcium dihydrox- 1305-62-0 r IOELV 1 4 2017/2398/
ide EU

EU chlorine 7782-50-5 IOELV 0.5 1.5 2017/2398/

EU

GB dust i WEL 10 EH40/2005

GB dust r WEL 4 EH40/2005

GB calcium hydrox- 1305-62-0 WEL 5 EH40/2005

ide

GB chlorine 7782-50-5 WEL 0.5 1.5 EH40/2005

Notation
i inhalable fraction
r respirable fraction
STEL short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-
minute period (unless otherwise specified)
TWA time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period
of 8 hours time-weighted average (unless otherwise specified)

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Relevant DNELs of components of the mixture

Name of sub- CAS No End- Threshold Protection goal, Used in Exposure time
stance point level route of expos-
ure
calcium dihydroxide 1305-62-0 DNEL 1 mg/m³ human, inhalatory worker (in- chronic - local
dustry) effects

calcium dihydroxide 1305-62-0 DNEL 4 mg/m³ human, inhalatory worker (in- acute - local ef-
dustry) fects

calcium chloride 10043-52-4 DNEL 5 mg/m³ human, inhalatory worker (in- chronic - local
dustry) effects

calcium chloride 10043-52-4 DNEL 10 mg/m³ human, inhalatory worker (in- acute - local ef-
dustry) fects

Relevant PNECs of components of the mixture

Name of substance CAS No Endpoint Threshold level Environmental com-

partment
calcium dihydroxide 1305-62-0 PNEC 0.49 mg/l freshwater

calcium dihydroxide 1305-62-0 PNEC 0.32 mg/l marine water

calcium dihydroxide 1305-62-0 PNEC 3 mg/l sewage treatment plant

(STP)

calcium dihydroxide 1305-62-0 PNEC 1,080 mg/kg soil

8.2 Exposure controls

Appropriate engineering controls

General ventilation.

Individual protection measures (personal protective equipment)

Eye/face protection

Wear eye/face protection.

Hand protection

Material Material thickness Breakthrough times of the glove material

no information available no information avail- no information available
able

Wear suitable gloves.

Chemical protection gloves are suitable, which are tested according to EN 374.
Check leak-tightness/impermeability prior to use.
In the case of wanting to use the gloves again, clean them before taking off and air them well.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves.

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Respiratory protection

In case of inadequate ventilation wear respiratory protection.

Particulate filter device (EN 143).

Environmental exposure controls

Use appropriate container to avoid environmental contamination.

Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance

Physical state solid

Form granulate

Colour white

Odour like chlorine

Odour threshold these information are not available

Other safety parameters

pH (value) not applicable

Melting point/freezing point not applicable (spontaneous decomposition)

Initial boiling point and boiling range not applicable

Flash point not applicable

Evaporation rate not applicable

Flammability (solid, gas) non-combustible

Explosion limits of dust clouds these information are not available

Vapour pressure not applicable

Density these information are not available

Vapour density not applicable

Bulk density 1 g/cm³

Relative density 2 (water = 1)

Solubility(ies)

Water solubility 200,000 mg/kg at 20 °C, not miscible in any propor-

tion

Partition coefficient

n-octanol/water (log KOW) these information are not available

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Auto-ignition temperature not relevant

(Solid matter)

Relative self-ignition temperature for solids these information are not available

Decomposition temperature 180 °C

Viscosity

Kinematic viscosity not relevant

(solid matter)

Dynamic viscosity not relevant

(solid matter)

Explosive properties not explosive

Oxidising properties oxidiser

9.2 Other information

Self-Accelerating Decomposition Temperature:
52ºC (45kg/Plastic packaging)
>52ºC (<45kg/Plastic packaging)
<52ºC (>45kg/Plastic packaging)

SECTION 10: Stability and reactivity

10.1 Reactivity
The mixture contains reactive substance(s).
Oxidising property.

If heated:

slow decomposition of the material

10.2 Chemical stability

See below "Conditions to avoid".
Spontaneous decomposition of the material.

10.3 Possibility of hazardous reactions

Risk of vigorous reaction, ignition and explosion in contact with combustible or flammable substances,
Reducing agents.
Substances Contains Nitrogen: Explosive, Toxic substances.
Dangerous/dangerous reactions with: Acids.

10.4 Conditions to avoid

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Humidity.
High temperatures

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10.5 Incompatible materials

water, acids, reducing agents, Combustible materials, amine, ammonia (NH3), metallic oxides contain-
ing heavy metals, Chlorinated isocyanurates

DO NOT MIX WITH OTHER CHLORINE MATERIALS, SUBSTANCES

Release of toxic materials with:

acids

10.6 Hazardous decomposition products

Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill
and heating are not known.
Hazardous combustion products: see section 5.
Oxygen.
Toxic substances: Chlorine, Hydrogen chloride (HCl).

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Classification procedure

If not otherwise specified the classification is based on:

Ingredients of the mixture (additivity formula).

Classification according to GHS (1272/2008/EC, CLP)

Acute toxicity

Shall not be classified as acutely toxic (dermal).

Harmful if swallowed.
Inhalation.
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.

Exposure route Endpoint Value Species

mg/
oral LD50 790 – 1,260 kg rat

dermal LD50 >2,000 mg/kg rabbit

Acute toxicity of components of the mixture

Name of substance CAS No Expos- End- Value Species Method Source

ure point
route
calcium hypochlorite 7778-54-3 oral LD50 850 rat
mg/
kg

calcium dihydroxide 1305-62-0 oral LD50 >2,000 rat OECD ECHA

mg/
kg Guideline
425

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Acute toxicity of components of the mixture

Name of substance CAS No Expos- End- Value Species Method Source

ure point
route
calcium dihydroxide 1305-62-0 dermal LD50 >2,500 rabbit OECD ECHA
mg
/kg Guideline
402

calcium chloride 10043-52-4 oral LD50 2,120 rat OECD ECHA

mg
/kg Guideline
401

calcium chloride 10043-52-4 dermal LD50 >5,000 rabbit ECHA

mg
/kg

Skin corrosion/irritation

Causes severe skin burns and eye damage.

Serious eye damage/eye irritation

Causes serious eye damage.

Respiratory or skin sensitisation

Skin sensitisation
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.
Respiratory sensitisation
Classification could not be established because:
Data are lacking, inconclusive, or conclusive but not sufficient for classification.

Germ cell mutagenicity

Classification could not be established because:

Data are lacking, inconclusive, or conclusive but not sufficient for classification.

Carcinogenicity

Classification could not be established because:

Data are lacking, inconclusive, or conclusive but not sufficient for classification.

Reproductive toxicity

Classification could not be established because:

Data are lacking, inconclusive, or conclusive but not sufficient for classification.

Specific target organ toxicity - single exposure

Classification could not be established because:

Data are lacking, inconclusive, or conclusive but not sufficient for classification.

Specific target organ toxicity - repeated exposure

Classification could not be established because:

Data are lacking, inconclusive, or conclusive but not sufficient for classification.

Aspiration hazard

Shall not be classified as presenting an aspiration hazard.

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SECTION 12: Ecological information

12.1 Toxicity

Aquatic toxicity (acute)

Very toxic to aquatic organisms.

Endpoint Value Species Exposure time

mg
LC50 0.15 /l fish 96 h

LC50 0.22 mg/l fish 96 h

Aquatic toxicity (acute) of components of the mixture

Name of sub- CAS No Endpoint Value Species Method Source Expos-

stance ure
time
calcium hypo- 7778-54-3 EC50 0.073 mg/l daphnia magna 48 h
chlorite

calcium hypo- 7778-54-3 LC50 0.049 – 0.16 bluegill 96 h

chlorite mg/ (lepomis mac-
l
rochirus)

calcium di- 1305-62-0 LC50 50.6 mg/l rainbow trout OECD ECHA 96 h
hydroxide (Oncorhynchus Guideline
mykiss) 201

calcium di- 1305-62-0 EC50 49.1 mg/l daphnia magna OECD ECHA 48 h
hydroxide Guideline
202

calcium di- 1305-62-0 ErC50 184.6 mg/l algae OECD ECHA 72 h

hydroxide (pseudokirch- Guideline
neriella subcap- 201
itata)

calcium chlor- 10043-52-4 LC50 4,630 mg/l fathead min- ECHA 96 h

ide now
(pimephales
promelas)

calcium chlor- 10043-52-4 LC50 2,400 mg/l daphnia magna OECD ECHA 48 h
ide Guideline
202

calcium chlor- 10043-52-4 EC50 2,900 mg/l algae OECD ECHA 72 h

ide (pseudokirch- Guideline
neriella subcap- 201
itata)

calcium chlor- 10043-52-4 ErC50 >4,000 mg/l algae OECD ECHA 72 h

ide (pseudokirch- Guideline
neriella subcap- 201
itata)

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Aquatic toxicity (chronic)

Test data are not available for the complete mixture.

Aquatic toxicity (chronic) of components of the mixture

Name of sub- CAS No Endpoint Value Species Method Source Expos-

stance ure
time
calcium di- 1305-62-0 LC50 53.1 mg/l Crustaceae ECHA 14 d
hydroxide (Crangon sp.)

calcium di- 1305-62-0 EC50 300.4 mg/l microorgan- OECD ECHA 3h

hydroxide isms Guideline
209

calcium di- 1305-62-0 NOEC 32 mg/l Crustaceae ECHA 14 d

hydroxide (Crangon sp.)

calcium chlor- 10043-52-4 LC50 920 mg/l daphnia magna ECHA 21 d

ide

calcium chlor- 10043-52-4 EC50 610 mg/l daphnia magna ECHA 21 d

ide

12.2 Persistence and degradability

Biodegradation

The study does not need to be conducted, the relevant substances in the mixture are inorganic.

Persistence

Data are not available.

12.3 Bioaccumulative potential

Data are not available.

12.4 Mobility in soil

Data are not available.

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Other adverse effects

Data are not available.

Endocrine disrupting potential

None of the ingredients are listed.

Remarks
Wassergefährdungsklasse, WGK (water hazard class): 2 Keep away from drains, surface and ground
water.

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SECTION 13: Disposal considerations

13.1 Waste treatment methods

This material and its container must be disposed of as hazardous waste.

Sewage disposal-relevant information

Do not empty into drains.

Waste treatment of containers/packagings

It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.
Handle contaminated packages in the same way as the substance itself.

Remarks
Please consider the relevant national or regional provisions.

SECTION 14: Transport information

14.1 UN number 3487

14.2 UN proper shipping name CALCIUM HYPOCHLORITE, HYDRATED MIXTURE,

CORROSIVE

14.3 Transport hazard class(es)

Class 5.1

Subsidiary risk(s) 8
(corrosive effects)

14.4 Packing group II

14.5 Environmental hazards hazardous to the aquatic environment

Environmentally hazardous substance (aquatic calcium hypochlorite

environment)

14.6 Special precautions for user

Provisions for dangerous goods (ADR) should be complied within the premises.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
The cargo is not intended to be carried in bulk.

14.8 Information for each of the UN Model Regulations

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN)

UN number 3487

Proper shipping name UN3487, CALCIUM HYPOCHLORITE, HYDRATED

MIXTURE, CORROSIVE, 5.1 (8), II, (E), environment-
ally hazardous

Class 5.1

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Classification code OC2

Packing group II

Danger label(s) 5.1+8, fish and tree

Environmental hazards yes

(hazardous to the aquatic environment)

Special provisions (SP) 314, 322

Excepted quantities (EQ) E2

Limited quantities (LQ) 1 kg

Transport category (TC) 2.

Tunnel restriction code (TRC) E

Hazard identification No 58

Emergency Action Code 1W

International Maritime Dangerous Goods Code (IMDG)

UN number 3487

Proper shipping name UN3487, CALCIUM HYPOCHLORITE, HYDRATED

MIXTURE, CORROSIVE, 5.1 (8), II, MARINE POLLUT-
ANT

Class 5.1

Subsidiary risk(s) 8

Marine pollutant yes (P)

(hazardous to the aquatic environment)

Packing group II

Danger label(s) 5.1+8, fish and tree

Special provisions (SP) 314, 322

Excepted quantities (EQ) E2

Limited quantities (LQ) 1 kg

EmS F-H, S-Q

Stowage category D

Segregation group 8 - Hypochlorites.

International Civil Aviation Organization (ICAO-IATA/DGR)

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UN number 3487

Proper shipping name UN3487, Calcium hypochlorite, hydrated mixture,

corrosive, 5.1 (8), II

Class 5.1

Subsidiary risk(s) 8

Environmental hazards yes

(hazardous to the aquatic environment)

Packing group II

Danger label(s) 5.1+8

Special provisions (SP) A8, A136

Excepted quantities (EQ) E2

Limited quantities (LQ) 2,5 kg

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture

Relevant provisions of the European Union (EU)

Restrictions according to REACH, Annex XVII

none of the ingredients are listed

List of substances subject to authorisation (REACH, Annex XIV) / SVHC - candidate list
none of the ingredients are listed

Seveso Directive

2012/18/EU (Seveso III)

No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap- Notes
plication of lower and upper-tier re-
quirements
E1 environmental hazards (hazardous to the aquatic 100 200 56)
environment, cat. 1)

P8 oxidising liquids and solids 50 200 55)

Notation
55) oxidising liquids, category 1, 2 or 3, or oxidising solids, category 1, 2 or 3
56) hazardous to the Aquatic Environment in category Acute 1 or Chronic 1

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Directive 2011/65/EU on the restriction of the use of certain hazardous substances in

electrical and electronic equipment (RoHS) - Annex II
none of the ingredients are listed

Regulation 166/2006/EC concerning the establishment of a European Pollutant Release

and Transfer Register (PRTR)
none of the ingredients are listed

Regulation 648/2004/EC on detergents

Labelling of contents

Wt% Constituents
≥30% chlorine-based bleaching agents

Directive 2000/60/EC establishing a framework for Community action in the field of water
policy (WFD)
none of the ingredients are listed

Regulation 98/2013/EU on the marketing and use of explosives precursors

none of the ingredients are listed

Regulation 649/2012/EU concerning the export and import of hazardous chemicals (PIC)
Chemicals subject to the international prior informed consent (PIC) procedure (the ‘PIC procedure’).

15.2 Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this mixture by the supplier.

SECTION 16: Other information

Indication of changes (revised safety data sheet)

Section Former entry (text/value) Actual entry (text/value)

2.2 Precautionary statements:
change in the listing (table)

2.2 Supplemental hazard information

2.2 Child-resistant fastening:

yes

2.2 Tactile warning of danger:

yes

8.1 Occupational exposure limit values (Workplace Ex-

posure Limits):
change in the listing (table)

15.1 Restrictions according to REACH, Annex XVII:

none of the ingredients are listed

15.1 2012/18/EU (Seveso III):

change in the listing (table)

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Abbreviations and acronyms

Abbr. Descriptions of used abbreviations

2017/2398/EU Directive of the European Parliament and of the Council amending Directive 2004/37/EC on the pro-
tection of workers from the risks related to exposure to carcinogens or mutagens at work

Acute Tox. Acute toxicity

ADN Accord européen relatif au transport international des marchandises dangereuses par voies de nav-
igation intérieures (European Agreement concerning the International Carriage of Dangerous Goods
by Inland Waterways)

ADR Accord européen relatif au transport international des marchandises dangereuses par route
(European Agreement concerning the International Carriage of Dangerous Goods by Road)

Aquatic Acute Hazardous to the aquatic environment - acute hazard

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical sub-
stances)

CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

DGR Dangerous Goods Regulations (see IATA/DGR)

DNEL Derived No-Effect Level

EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an
identifier of substances commercially available within the EU (European Union)

EH40/2005 EH40/2005 Workplace exposure limits (http://www.nationalarchives.gov.uk/doc/open-government-li-

cence/)

EINECS European Inventory of Existing Commercial Chemical Substances

ELINCS European List of Notified Chemical Substances

EmS Emergency Schedule

Eye Dam. Seriously damaging to the eye

Eye Irrit. Irritant to the eye

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United
Nations

IATA International Air Transport Association

IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO International Civil Aviation Organization

IMDG International Maritime Dangerous Goods Code

index No The Index number is the identification code given to the substance in Part 3 of Annex VI to Regula-
tion (EC) No 1272/2008

IOELV Indicative occupational exposure limit value

MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant")

M-factor Means a multiplying factor. It is applied to the concentration of a substance classified as hazardous
to the aquatic environment acute category 1 or chronic category 1, and is used to derive by the sum-
mation method the classification of a mixture in which the substance is present

NLP No-Longer Polymer

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Abbr. Descriptions of used abbreviations

Ox. Sol. Oxidising solid

PBT Persistent, Bioaccumulative and Toxic

PNEC Predicted No-Effect Concentration

ppm Parts per million

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regula-
tions concerning the International carriage of Dangerous goods by Rail)

Skin Corr. Corrosive to skin

Skin Irrit. Irritant to skin

STEL Short-term exposure limit

STOT SE Specific target organ toxicity - single exposure

SVHC Substance of Very High Concern

TWA Time-weighted average

vPvB Very Persistent and very Bioaccumulative

WEL Workplace exposure limit

Key literature references and sources for data

Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures.
2016 - ATP 9 2016/1179.
Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU.
Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN).
International Maritime Dangerous Goods Code (IMDG).
Dangerous Goods Regulations (DGR) for the air transport (IATA).

Classification procedure
Physical and chemical properties.
Health hazards.
Environmental hazards.
The method for classification of the mixture is based on ingredients of the mixture (additivity formula).

List of relevant phrases (code and full text as stated in chapter 2 and 3)

Code Text
H272 May intensify fire; oxidiser.

H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.

H315 Causes skin irritation.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

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Code Text
H335 May cause respiratory irritation.

H400 Very toxic to aquatic life.

Responsible for the safety data sheet

C.S.B. GmbH Telephone: +49 (0) 2151 - 652086 - 0

Düsseldorfer Str. 113 Telefax: +49 (0) 2151 - 652086 - 9
47809 Krefeld, Germany e-Mail: info@csb-online.de
Website: www.csb-online.de

Disclaimer
This information is based upon the present state of our knowledge.
This SDS has been compiled and is solely intended for this product.

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