13-11 Paper 2
13-11 Paper 2
13-11 Paper 2
JEE
Test Stream JEE MAIN + ADVANCED Test Pattern
(Advanced)
1. A proton is either released at rest or launched with a certain velocity in a uniform electric field. Which of the graphs in figure could possibly show
how the kinetic energy of the proton changes during the proton's motion ?
a.
b.
c.
d.
Solution.
Answer. a,b
2. In a solid sphere of radius R = 2m, electric field intensity varies as E = C (r2 – 2r) 0 ≤ r ≤ 2m Where C is an appropriate constant
Answer. a,d
3. Three equal point changes (Q) are kept at the three corners of an equilateral triangle ABC of side a. P is a point having equal distance a from A, B
and C. If E is the magnitude of electric field and V is the potential at point P, then
a. E =
b. E =
c. V =
d. E =
∴
∴ =
= . =
Answer. b,c
4. A point charge is placed outside a uncharged conducting spherical shell as shown in figure. There are two points P and Q inside the shell. Select
Solution. Electric potential due to outer charge q and induced charge (combined) is same at every point inside the sphere. So total electric potential
at P & Q is same. But electric potential due to induced charges at P & Q is not same as potential due to 'q' at both points is not same.
induced charge distribution is non-uniform as shown.
Answer. a,c,d
5. Consider a non-conducting ring of radius 'a' in x-y plane. The two semi-circular portions have linear charge densities +λ and –λ as shown. Then :
Solution. Dipole moment will be angle of 30° to '–x' –axis of magnitude = (λ.πa) = 4λa2.
Answer. a,c
6. A planet of mass M and radius R has uniform density. The gravitational field at distance x from centre is g, then gravitational potential is V, the
gravitational pressure is p. Neglect atmosphere.
d. For x < R, .
Solution.
Answer. a,b,c,d
Essay - 118396-97739 :
Three sides of a square of side ℓ are occupied by positive charges of density λ C/m.
a.
b.
c.
d.
Answer. b
b. Along X axis
c.
d. tan–12
Answer. b
Essay - 118396-97742 :
A cube has side of length L = 0.3 m. It is placed with one corner at origin as shown in figure. The electric field is not uniform but is given by
a. S2, S4 and S5
c. S1 , S2 and S3
d. S2, S3 and S4
Answer. b
a. – 0.054 ∈0 C
b. 0.081 ∈0 C
c. 0.135 ∈0 C
d. 0.054 ∈0C
Answer. a
Essay - 118396-97750 :
A thin conducting spherical shell of radius 'a' is surrounded by a thin uncharged concentric conducting shell of radius 2a. A point charge q is placed
at a distance 4a from common centre of conducting shells. The inner shell is then grounded. (q = –4µC, a = 10 cm)
Solution.
Answer. 4.00
Solution. Ans.
The inner shell is grounded, hence its potential is zero. The net charge on isolated outer shell is zero. Let the charge on inner shell be q.
∴ Potential at centre of inner shell is zero as no electric field is present inside inner shell.
The region in between conducting shells is shielded from charges on outside the outer surface of shell. Hence, charge distribution on outer surface
of inner shell and inner surface of outer shell is uniform.
The distribution of induced charge on outer surface of outer shell depends only on point charge q, hence is nonuniform. The charge distribution on
all surfaces, is as shown.
∴ VC = V C – V A = =
Answer. 45.00
Essay - 118396-97751 :
Now consider two identical, oppositely oriented electric dipoles. separated by a distance r. as shown in the diagram. It is convenient when
considering the interaction between the dipoles to choose the zero of potential energy such that the potential energy is zero when the dipoles are
13. Assume that d << r, Give an approximation of your expression for the potential energy of interaction between dipoles to lowest order in d.
Rewrite this approximation in terms of only p, r, and fundamental constants if . Find C.
Solution.
Answer. -1.00
14. What is the force (magnitude and direction) exerted on one dipole by the other ? Continue to make the assumption that d << r, and again
express your result in terms of only p, r and fundamental constants. If force is in magnitude, find C1.
Solution. There are two +q – q pairs separated by a distance d, each having potential energy There are two +q - –q pairs separated by a
distance r, each having potential energy There are a + q - + q pair and a – q - – q pair separated by a distance , each having
potential energy Note that the latter two terms go to zero as r becomes large, whereas the first term is not dependent on r. Thus the
given zero convention will include only the latter two terms. We have Using the binomial
or, in terms of p. c. We can infer by symmetry that the force must be in the direction along the line separating the
dipoles. Since the potential energy decreases with decreasing distance, the force is attractive. Its magnitude can be determined by taking the
derivative of the potential energy. with the negative sign confirming that the force is attractive.
Answer. 3.00
Essay - 118396-97756 :
Consider a situation in which a negatively charged particle of mass M and charge –q revolves in elliptical path around a fixed charge Q. The closest
and farthest distance of the moving particle from fixed charge is a and 4a respectively. Point A and B are the two extreme points of the major axis
of ellipse as shown in the figure. Charge Q is present at one of the Foci of the ellipse.
15. The speed (in SI units) of revolving particle when it reaches point A, will be? Use and
Solution. Total mechanical energy of path is for speed at A
VA = 10m/s
Answer. 10.00
16. The radius of curvature of path (in SI units) of revolving particle at point B, will be ? Use [a = 25(S.I units)]
Solution. Speed at B
VB = 40 m/s
;
,
Answer. 40.00
17. Two stars, each of mass M and separated by a distance d, orbit about their center of mass. A planetoid of mass m (m << M) moves along the
axis of this system perpendicular to the orbital plane. Let Tp be the period of simple harmonic motion for the planetoid for small displacements
from the center of mass along the z-axis, and let Ts be the period of motion for the two stars. What is ?
The orbital period T will be given by the centripetal force law or The planetoid is a distance z above
the plane. The distance to either star is then . Only the part of the force that is perpendicular to the plane survives the vector addition, so
the net force is given by This expression is exact. But if z << d, then we can approximate this as This is a
restoring force; the planetoid will execute simple harmonic oscillations with period where k is the effective force constant, or TP =
Answer. 2
Solution.
⇒ g = 4ge
Answer. 42
19. What minimum speed (in mm/s) is required for a long, thin spear of mass M = 100 gm, which is uniformly charged by a positive charge Q = 4 μC
along its length L = 20 cm, for the spear to pass completely through two adjacent layers of thickness h = 9 cm each, in which the electric field is
directed both against the velocity of the spear (in the first layer) and along it (in the second layer). In each case the intensity of the electric field is E
= 100 V/m
Solution.
Let's consider how the electric force affecting the spear depends on the position of the spearhead (figure). Since there is no field outside the layers,
the force is zero when x > 2h or x < 0. As the spear penetrates the layers, the braking force grows linearly with distance attaining a maximum when
the spearhead exits the first layer. As the spearhead penetrates the second layer, the braking force continually decreases. The braking force
becomes zero when the spearhead exits the second layer. The force remains zero until the tail of the spear enters the first layer. At this time the
electric force causes the spear to speed up. If the speed of the spear has not dropped to zero before this time, the spear will pass completely
through both layers.
The minimum value for the initial speed required to pass through both layers can be determined from energy conservation by calculating the initial
kinetic energy to the work performed by the braking force. The latter can be easily calculated for such a simple dependence of force on distance
Therefore
Answer. 18
Solution.
Answer. b,c,d
21. For equilibrium LiCl.3NH3(s) ⇌ LiCl.NH3(s) + 2NH3(g), ΔG° = –2.24 Kcal/mole at 127°C. A 5 litre vessel contains 0.2 mole of LiCl.NH3(s) and
certain moles of NH3. Choose the correct statement(s) :
[R = 2 cal/K-mole = 0.08 L-bar/K-mol; ln 2 = 0.7]
a. With increase in temperature and pressure, ΔG° of the reaction will increase.
∴
(C) ΔG° depends only on temperature.
(D) Since decomposition reactions are endothermic reaction
∴ qsurr. = –Ve
∴ ΔSsurr. = = –Ve
∴ On increasing temperature unfavourable change in entropy of surrounding will decrease
Answer. b,d
a. ΔH > 0
b. ΔS > 0
c. ΔU > 0
d. ΔG > 0
Answer. a,b,c,d
Right Marks: 4.00
23. A system undergoes three reversible processes sequentially. 1 – 2 is an isobaric process, 2 – 3 is a polytropic process with x = and 3 – 1 is an
a. Wnet = –8 × 105 J
b. Qnet = 105 J
d.
For process : 1 → 2
W12 = – PΔV
= – 4 × 105 [1.4 – 1] = – 1.6 × 105 Joule.
For process : 2 → 3
W23 =
Answer. c,d
24. A mixture of 5.0 × 10–5 mol H2(g) and 5.0 × 10–5 mol SO2(g) is placed in a 10.0 L container at 25°C. The container has a pinhole leak. After a
period of time, the partial pressure of H2(g) in the container :
Solution. Since rate of H2 is higher then SO2 so, drop of partial pressure of H2 inside container will be high.
Answer. a
25. Which of the following reaction(s) do(es) not represent ΔH0 formation of the product :
a. SO2(g) + O2(g) → SO3(g)
b. O3(g) → O2(g)
Answer. b,c
Essay - 118396-98754 :
A sample of certain mass of an ideal non-linear polyatomic gas is expanded against constant pressure of 1 atm, adiabatically from volume 2L,
pressure 6 atm and temperature 300 K to state where its final volume is 8L. (Neglect vibrational degrees of freedom)
[Take 1L atm = 100 J, R = 8.0 J/mol/K = 0.08 atm-lit./K-mole, log 2 = 0.3, log 3 = 0.48, log e = 2.3]
a. 3.312
b. 5.312
c. 6.312
d. 7.728
= 0.5 × 3 × 8 × ℓn + 0.5 × 8 × ℓn
= 3.312 J/K
Answer. a
a. –200
b. –400
c. –600
d. –800
Solution. ΔΗ = nCP ΔT
= 0.5 × 4 × 8 × [250 – 300] = – 800 Joule
Answer. d
Essay - 118396-98756 :
Non-ideal gas behavior can be described as follows : Boyle's law predicts that at very high pressures, a gas volume becomes extremely small and
approaches zero. This cannot be, however, because the molecules themselves occupy space and are practically incompressible. Because of the
finite size of the molecules, the PV product at high pressures is larger than predicted for an ideal gas, and the compressibility factor is greater than
one. Another consideration is that intermolecular forces exist in gases shows that because of attractive forces between the molecules, the force of
the collisions of gas molecules with the container walls is less than expected for an ideal gas. Intermolecular forces of attraction account for
compressibility factors of less than one.
28. Which of the following statement is not correct regarding compressibility factor (Z) of real gas ?
b. For a gas in which only repulsive forces are existing and are significant, 'z' will always be greater than 1.
c. As pressure tends to zero, compressibility factor of all real gases approaches towards unity.
Answer. d
29. Density of a Vander Waal's gas at 500 K and 1 atm is found to be 0.8 kg/m3. It is also found that the gas diffuses times slower than pure
O2 gas under identical conditions. the value of Z for the real gas is (R = 0.08 atm-ℓ/mol-K) :
a.
b.
c. 1.8
d. 0.8
Answer. b
Essay - 118396-98777 :
A manometer attached to 36 litre flask contains some inert gas & ammonium carbamate [NH2COONH4(s)] having no difference in mercury level
initially as shown. NH2COONH4(s) decomposed completely on heating according to reaction NH2COONH4(s) → 2NH3(g) + CO2(g)
If same amount of NH2COONH4(s) is decomposed completely in separate container and produced NH3(g), which
required 500 ml of 2N H3PO4 solution for complete neutralisation. During the process temperature remains at 300K. [R = 0.08 atm-litre mole–1 K–1]
30. The difference in height of Hg column (in mm) after complete decomposition of NH2COONH4(s) is:
Answer. 760.00
Answer. 1.50
Essay - 118396-98780 :
Suppose a chemical reaction is spontaneous below 400 K and non-spontaneous above 400 K under standard condition. ΔH° and ΔS° of reaction do
not vary with temperature and ΔH° = –50 kJ.
Answer. 125.00
Answer. 12.50
Essay - 118396-98783 :
Following reaction is at equilibrium in basic medium at 300 K. I2(s) ⇌ I–(aq.) + IO3–(aq.) Equilibrium concentration at 300 K are, [I–] = 0.1 M, [IO3–] =
0.1 M
Given (I–, aq) = – 50 kJ/mol
(IO–3, aq) = – 123.5 kJ/mol
(H2O, ℓ) = – 233 kJ/mol
(OH–, aq) = – 150 kJ/mol
R= J mol–1 K–1, log10e = 2.3
Answer. 172.50
Answer. 30.00
36. Pure PCl5 is introduced into an evacuated chamber comes to equilibrium at 27°C and 1 bar. The equilibrium mixture contains 40% chlorine by
volume.
PCl5(g) ⇌ PCl3(g) + Cl2(g)
Calculate ΔG° (in cal/mole) of the reaction.
(Use : ln 2 = 0.7, ln 10 = 2.3
∴ α=
∴ ΔG° = –RT ℓn KP
= –2 × 300 × ℓn
= 2 × 300 × [2.3 – 3 × 0.7]
= 2 × 300 × 0.2 = 120 cal/mole.
Answer. 120
37. The graph of compressibility factor (Z) vs. P for one mole of a real gas is shown in following diagram. The
graph is plotted at constant temperature 273 K. If the slope of graph at very high pressure is atm–1, then calculate volume of one mole
of real gas molecules (in L/mol).
[Given : NA = 6 × 1023 and R = L atm K–1 mol–1)
b=8
∴ Volume of one mole molecules =
Answer. 2
38. Given : Enthalpy of formation of H2O(ℓ) and OH–(aq.) are –285 kJ/mol and –227.3 kJ/mol respectively.
Enthalpy of neutralization of CH3COOH with NaOH = –55 kJ/mol
The enthalpy of dissociation (in J/mole) of CH3COOH is.
is
a. a + b + c = –2
b. a + b = –1
c. a + b = –5
d. a + b = 5
comparing with
, we get
a = –3, b = –2, c = 3
∴ a + b + c = –3 –2 + 3 = –2
a + b = –5
Answer. a,c
40. Let 'n' be a +ve integer with f(n) = 1! + 2! + 3!+...+n! and p(x), q(x) be polynomials in 'x' such that f(n + 2) = p(n). f(n + 1) + q(n). f(n) for all n > 1
then
a. p(x) = x + 3
b. q(x) = – x – 2
c. p(x) = – x – 2
d. q(x) = – x + 3
Answer. a,b
b. Number of integral value of k for which h(f(x)) > 0 and h(g(x)) < 0 ∀ x ∈ R is 20
c. Number of integral value of k for which h(f(x)) > 0 and h(g(x)) < 0 ∀ x ∈ R is 19
Solution. f(x) =
(A)
Range of f is (0, 8]
(B) h(f(x)) > 0 and h(g(x)) < 0
⇒ h(0) > 0 ⇒ k > 0
and h(8) > 0 ⇒ –64 – 24 + k > 0 ⇒ k > 88
Also, h(9) < 0 ⇒ –81 – 27 + k < 0 ⇒ k < 108
⇒ Number of integral value of k is 19.
(D) Maximum value of g(f(x)) is g(8) = 64 + 9 = 73.
Answer. a,c,d
42. Let the function be given by , then which of the following options is/are true for f(x) ?
c.
Solution.
Maximum at x = –1 and minimum at x = 1
Answer. b,c
a.
b.
c.
d.
∴ ⇒
⇒ (p + q) can be or
Answer. a,c
44. Given where x.y < 0, then the integer(s) which are in the range of S is (are)
a. 1
b. 2
c. 4
d. 3
Solution. S = cosec–1
∵ xy < 0 let x < 0 & y > 0
∴ ⇒
and ⇒
∴
If x > 0, y < 0
then
and
Answer. a,b
Essay - 118396-98631 :
Let ƒ : N × N → N be a function such that ƒ(1, 1) = 2, ƒ(α + 1, β) = ƒ(α, β) + α and ƒ(α, β + 1) = ƒ(α, β) – β ∀ α, β ∈ N and ƒ(a, b) = 2001, then answer the
following
a. 4000
b. 3999
c. 2999
d. 2000
= ƒ(1, b – 1) – (b – 1) +
= ƒ(1, 1) – +
⇒ (a – b)(a + b – 1) = 2.1999
then 1999 is prime and a – b < a + b – 1
⇒ a – b = 1, a + b – 1 = 3998
⇒ a = 2000
b = 1999
If a – b = 2, a + b – 1 = 1999
⇒ a = 1001, b = 999
⇒ (a, b) = (2000, 1999) or (1001, 999)
Answer. b
a. 1
b. 2
c. 3
d. 4
= ƒ(1, b – 1) – (b – 1) +
= ƒ(1, 1) – +
⇒ (a – b)(a + b – 1) = 2.1999
then 1999 is prime and a – b < a + b – 1
⇒ a – b = 1, a + b – 1 = 3998
⇒ a = 2000
b = 1999
If a – b = 2, a + b – 1 = 1999
⇒ a = 1001, b = 999
⇒ (a, b) = (2000, 1999) or (1001, 999)
Answer. b
Essay - 118396-98666 :
Let and such that 2sinα and cos β are roots of the equation x2 – ax + b = 0.
On the basis of above information, answer the following questions :
a.
b. (0, π)
c.
d.
Solution.
⇒ a = 2sinα + cosβ = 1
b = 2sinα. cosβ = –2
ƒ(x) = cot–1(x2 – 2x)
= cot–1(–1 + (x – 1)2)
Answer. c
a. 0
b. 1
c. 2
d. 3
Solution.
⇒ a = 2sinα + cosβ = 1
b = 2sinα. cosβ = –2
2 sin–1x = 3x
Graphically number of
solutions = 3
Answer. d
Essay - 118396-98511 :
Let f : R → R defined as f(x) = ||x|2 – 4|x| + 3| then
49. The number of solution of the equation f(x).g(x) = 1 where g(x) = 3|x|
Solution.
Answer. 8.00
50. The number of solutions of the equation f(x) = h(x) where h(x) = |tan–1x| + 3
Solution.
⇒ 3 solutions
Answer. 3.00
Essay - 118396-98673 :
Let f1(x) and f2(x) are two linear polynomials defined from [1, 5] onto [0, 4] satisfying f1(4) = f2(2) = 3.
Solution. Equation MN :
y – 0 = 1. (x – 1)
y=x–1
Equation of LP :
y – 0 = –1.(x – 1)
y=5–x
∵ f1(4) = 3 ⇒ f1(x) = x – 1
and f2(2) = 3 ⇒ f2(x)= 5 – x
Now
for domain
and 4x ≥ –1 ⇒ ∴
Answer. 3.00
52. Suppose g(x) is a polynomial with integral coefficients. If g(x) is divided by f1(x), we get remainder as 1 and when g(x) is divided by f2(x), we get
remainder as 9. If h(x) is the remainder when g(x) is divided by f1(x). f2(x), then the value of h(1005) is -
Answer. 2009.00
Essay - 118396-98674 :
Let f : A → B, be a one-one & onto function, where A is the domain of f(x).
53. If c ≠ 0, then b is -
Answer. 0.00
{x ≠ c}
Range is R ~ {1, 2}
Answer. 3.00
55. If ƒ : N → N and x2 > x1 ⇒ ƒ(x2) > ƒ(x1), ∀ x1, x2 ∈ N and ƒ(ƒ(n)) = 3n ∀ n ∈ N then value of ƒ(2) is
Answer. 3
Solution.
⇒ x2 ≤ 2 ⇒
No of integers = 3
Answer. 3
Solution. ∵
∴ .....(i)
or f(n + 4) = f(n) ∀ n ∈ N
hence f(n) is a periodic sequence with period 4
using (A) put n = 1, 2, 3
we get
Now f(2012) = f(4) = –3
f(2013) = f(1) = 2
= (–3)2 = 9
Answer. 9
Test Answer
1. (a,b) 2. (a,d) 3. (b,c) 4. (a,c,d) 5. (a,c) 6. (a,b,c,d) 7. (b) 8. (b) 9. (b) 10. (a)
11. (4.00) 12. (45.00) 13. (-1.00) 14. (3.00) 15. (10.00) 16. (40.00) 17. (2) 18. (42) 19. (18)
R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 20. (b,c,d)
R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000
30. (760.00)
21. (b,d) 22. (a,b,c,d) 23. (c,d) 24. (a) 25. (b,c) 26. (a) 27. (d) 28. (d) 29. (b) R_F:0.0000
R_T:0.0000
31. (1.50) 32. (125.00) 33. (12.50) 34. (172.50) 35. (30.00) 36. (120) 37. (2) 38. (2700)
R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 39. (a,c) 40. (a,b)
R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000
49. (8.00) 50. (3.00)
41. (a,c,d) 42. (b,c) 43. (a,c) 44. (a,b) 45. (b) 46. (b) 47. (c) 48. (d) R_F:0.0000 R_F:0.0000
R_T:0.0000 R_T:0.0000
51. (3.00) 52. (2009.00) 53. (0.00) 54. (3.00) 55. (3) 56. (3) 57. (9)
R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000 R_F:0.0000
R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000 R_T:0.0000