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He a lt h 0
0 0
Fire
0 0
Re a c t iv it y 0
P e rs o n a l A
P ro t e c t io n
p. 1
Skin Contact: Not applicable.
Serious Skin Contact: Not available.
Inhalation: Not applicable.
Serious Inhalation: Not available.
Ingestion: Not Applicable
Serious Ingestion: Not available.
Small Spill: Mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Precautions: No specific safety phrase has been found applicable for this product.
Storage: Not applicable.
p. 2
Odor: Odorless.
Taste: Not available.
Molecular Weight: 18.02 g/mole
Color: Colorless.
pH (1% soln/water): 7 [Neutral.]
Boiling Point: 100°C (212°F)
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: 1 (Water = 1)
Vapor Pressure: 2.3 kPa (@ 20°C)
Vapor Density: 0.62 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not applicable
Solubility: Not Applicable
p. 3
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Not available.
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 4
Protective Equipment:
Not applicable. Lab coat. Not applicable. Safety glasses.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 5
He a lt h 1
1 1
Fire
1 0
Re a c t iv it y 0
P e rs o n a l A
P ro t e c t io n
Potential Acute Health Effects: Slightly hazardous in case of eye contact (irritant), of ingestion, of inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.
Eye Contact: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be
used.
Skin Contact: No known effect on skin contact, rinse with water for a few minutes.
Serious Skin Contact: Not available.
p. 1
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation: Not available.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Precautions:
Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a
fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. If ingested, seek medical advice
immediately and show the container or the label.
Storage:
Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in a
cool, well-ventilated place. Combustible materials should be stored away from extreme heat and away from strong oxidizing
agents.
p. 2
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure Limits: Not available.
p. 3
Polymerization: No.
Waste Disposal:
p. 4
Fire Hazard: 1
Reactivity: 0
Personal Protection: a
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Not applicable. Lab coat. Not applicable. Safety glasses.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 5
He a lt h 1
0 0
Fire
1 0
Re a c t iv it y 0
P e rs o n a l E
P ro t e c t io n
Toxicological Data on Ingredients: Sodium chloride: ORAL (LD50): Acute: 3000 mg/kg [Rat.]. 4000 mg/kg [Mouse].
DERMAL (LD50): Acute: >10000 mg/kg [Rabbit]. DUST (LC50): Acute: >42000 mg/m 1 hours [Rat].
Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for
bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or
prolonged exposure is not known to aggravate medical condition.
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
p. 1
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention if symptoms appear.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Precautions:
Keep locked up.. Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. If ingested,
seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing
agents, acids.
p. 2
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
p. 3
Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, high temperatures.
Incompatibility with various substances: Reactive with oxidizing agents, metals, acids.
Corrosivity: Not considered to be corrosive for metals and glass.
Special Remarks on Reactivity:
Hygroscopic. Reacts with most nonnoble metals such as iron or steel, building materials (such as cement) Sodium chloride is
rapidly attacked by bromine trifluoride. Violent reaction with lithium.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
p. 4
Special Remarks on the Products of Biodegradation: Not available.
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Federal and State Regulations: TSCA 8(b) inventory: Sodium chloride (Rock Salt)
Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
R40- Possible risks of irreversible effects. S24/25- Avoid contact with skin and eyes.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.
References:
-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.
Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of
Chemical Safety Data, Edition II.
Other Special Considerations: Not available.
Created: 10/09/2005 06:30 PM
p. 5
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
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Toxicological Data on Ingredients: Potassium chloride: ORAL (LD50): Acute: 2500 mg/kg [Guinea pig]. 2600 mg/kg [Rat].
1500 mg/kg [Mouse].
Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for
bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance
may be toxic to blood, cardiovascular system. Repeated or prolonged exposure to the substance can produce target organs
damage.
Eye Contact:
p. 1
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Precautions:
Do not ingest. Do not breathe dust. If ingested, seek medical advice immediately and show the container or the label. Keep
away from incompatibles such as oxidizing agents, acids, moisture.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic
p. 2
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
p. 3
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Hygroscopic. Incompatible with KMnO4, H2SO4, BrF3, and BrCl3. May react violently with BrF3.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 4
Special Provisions for Transport: Not applicable.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 5
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Toxicological Data on Ingredients: Potassium bromide: ORAL (LD50): Acute: 3070 mg/kg [Rat]. 3120 mg/kg [Mouse].
Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to the nervous system. The substance may be toxic to
central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage.
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention if irritation occurs.
p. 1
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Precautions:
Do not ingest. Do not breathe dust. If ingested, seek medical advice immediately and show the container or the label. Keep
away from incompatibles such as oxidizing agents, acids.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.
p. 2
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
p. 3
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Hygroscopic; keep container tightly closed. Incompatible with heavy metal salts. Reacts violently with bromine trifluoride
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 4
Section 15: Other Regulatory Information
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 5
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Toxicological Data on Ingredients: Potassium Iodide LD50: Not available. LC50: Not available. Lowest Published Lethal
Dose: LDL [Mouse] - Route: Oral; Dose: 1862 mg/kg LDL [Rabbit] - Route: Oral; Dose: 916 mg/kg
Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.
TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female,
Development toxin [POSSIBLE]. The substance may be toxic to thyroid. Repeated or prolonged exposure to the substance
can produce target organs damage.
Eye Contact:
p. 1
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention if irritation occurs.
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Precautions:
Do not breathe dust. Wear suitable protective clothing. If you feel unwell, seek medical attention and show the label when
possible. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, moisture.
p. 2
Storage:
Moisture Sensitive. Light Sensitive. Air SensitiveKeep container tightly closed in light-resistant containers. Keep container in a
cool, well-ventilated area.
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
p. 3
Instability Temperature: Not available.
Conditions of Instability:
Light, moisture, incompatible materials. It is stable under ordinary conditions of use and storage. On long exposure to air, it
becomes yellow due to release of iodine.
Incompatibility with various substances: Reactive with oxidizing agents, reducing agents, organic materials, metals, acids.
Corrosivity:
Corrosive in presence of steel, of aluminum, of zinc. Non-corrosive in presence of glass, of copper, of stainless steel(304), of
stainless steel(316).
Special Remarks on Reactivity:
Moisture Sensitive. Light Sensitive. Air Sensitive. Air causes decomposition to iodine. Reacts violently with strong oxidizers,
bromotrifluorides, chlorotrifluorides, fluorine perchlorate, metallic salts. Attacks metals in moist environments. Also
incompatible with salts of alkaloids, chloral hydrate, calomel (mercurous chloride), potassium chlorate, tartaric and other
acids, oxidants, diazonium salts, charcoal, ozone, strong reducers, alkali metals, metals (brass, aluminum magnesium, zinc,
cadmium, copper, tin, nickel, steel), metallic salts, organic materials, light.
Special Remarks on Corrosivity:
Incompatible with water, producing a corrosive. Corrosive in all concentrations to most metals, except stainless steel, titanium,
and tantalum.
Polymerization: Will not occur.
p. 4
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 5
Other Special Considerations: Not available.
Created: 10/11/2005 12:21 PM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
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Toxicological Data on Ingredients: Potassium sulfate: ORAL (LD50): Acute: 6600 mg/kg [Rat].
Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids
open. Cold water may be used. Do not use an eye ointment. Seek medical attention.
p. 1
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running
water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.
Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation: Not available.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Precautions:
Do not ingest. Do not breathe dust. Wear suitable protective clothing In case of insufficient ventilation, wear suitable
respiratory equipment If ingested, seek medical advice immediately and show the container or the label. Avoid contact with
skin and eyes
Storage:
No specific storage is required. Use shelves or cabinets sturdy enough to bear the weight of the chemicals. Be sure that it is
not necessary to strain to reach materials, and that shelves are not overloaded.
p. 2
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
p. 3
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: No.
Waste Disposal:
p. 4
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Splash goggles.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 5
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Potential Acute Health Effects: Hazardous in case of ingestion. Slightly hazardous in case of eye contact (irritant), of
inhalation.
Potential Chronic Health Effects:
Hazardous in case of ingestion. Slightly hazardous in case of inhalation. CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not
available.
Eye Contact: No known effect on eye contact, rinse with water for a few minutes.
Skin Contact: No known effect on skin contact, rinse with water for a few minutes.
Serious Skin Contact: Not available.
p. 1
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation: Not available.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
If the product is in its solid form: Use a shovel to put the material into a convenient waste disposal container. If the product is
in its liquid form: Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by
spreading water on the contaminated surface and allow to evacuate through the sanitary system.
Precautions:
Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a
fume hood. Ground all equipment containing material. Do not breathe dust.
Storage:
Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in a
cool, well-ventilated place. Combustible materials should be stored away from extreme heat and away from strong oxidizing
agents.
p. 2
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure Limits: Not available.
p. 3
Polymerization: No.
Waste Disposal:
p. 4
HMIS (U.S.A.):
Health Hazard: 0
Fire Hazard: 1
Reactivity: 0
Personal Protection: a
National Fire Protection Association (U.S.A.):
Health: 0
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Not applicable. Lab coat. Not applicable. Safety glasses.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 5
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Toxicological Data on Ingredients: Hydrogen chloride: GAS (LC50): Acute: 4701 ppm 0.5 hours [Rat].
p. 1
respiratory tract, skin, eyes, Circulatory System, teeth. Repeated or prolonged exposure to the substance can produce target
organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation.
Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial
infection. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one
or many human organs.
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Serious Ingestion: Not available.
p. 2
Special Remarks on Explosion Hazards:
Hydrogen chloride in contact with the following can cause an explosion, ignition on contact, or other violent/vigorous reaction:
Acetic anhydride AgClO + CCl4 Alcohols + hydrogen cyanide, Aluminum Aluminum-titanium alloys (with HCl vapor), 2-Amino
ethanol, Ammonium hydroxide, Calcium carbide Ca3P2 Chlorine + dinitroanilines (evolves gas), Chlorosulfonic acid Cesium
carbide Cesium acetylene carbide, 1,1-Difluoroethylene Ethylene diamine Ethylene imine, Fluorine, HClO4 Hexalithium
disilicide H2SO4 Metal acetylides or carbides, Magnesium boride, Mercuric sulfate, Oleum, Potassium permanganate,
beta-Propiolactone Propylene oxide Rubidium carbide, Rubidium, acetylene carbide Sodium (with aqueous HCl), Sodium
hydroxide Sodium tetraselenium, Sulfonic acid, Tetraselenium tetranitride, U3P4 , Vinyl acetate. Silver perchlorate with carbon
tetrachloride in the presence of hydrochloric acid produces trichloromethyl perchlorate which detonates at 40 deg. C.
Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If
necessary: Neutralize the residue with a dilute solution of sodium carbonate.
Large Spill:
Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.
Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray
to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.
Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentration
level above TLV. Check TLV on the MSDS and with local authorities.
Precautions:
Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.
In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show
the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, organic
materials, metals, alkalis, moisture. May corrode metallic surfaces. Store in a metallic or coated fiberboard drum using a strong
polyethylene inner package.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
CEIL: 5 (ppm) from OSHA (PEL) [United States] CEIL: 7 (mg/m3) from OSHA (PEL) [United States] CEIL: 5 from NIOSH
CEIL: 7 (mg/m3) from NIOSH TWA: 1 STEL: 5 (ppm) [United Kingdom (UK)] TWA: 2 STEL: 8 (mg/m3) [United Kingdom
(UK)]Consult local authorities for acceptable exposure limits.
p. 3
Physical state and appearance: Liquid.
Odor: Pungent. Irritating (Strong.)
Taste: Not available.
Molecular Weight: Not applicable.
Color: Colorless to light yellow.
pH (1% soln/water): Acidic.
Boiling Point: 50.5°C (122.9°F)
Melting Point: -46.2°C (-51.2°F) to -25.4 C
Critical Temperature: Not available.
Specific Gravity: 1.19 (Water = 1)
Vapor Pressure: 16 kPa (@ 20°C) average
Vapor Density: 1.267 (Air = 1)
Volatility: Not available.
Odor Threshold: 0.25 to 10 ppm
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, diethyl ether.
Solubility: Soluble in cold water, hot water, diethyl ether.
p. 4
perchlorate), Cesium acetylene carbide, Cesium carbide, Cesium telluroacylates, Chlorine + dinitroanilines (evolves
gas), Chloroacetaldehyde oxime, Chlorosulfonic acid, Cyanogen chloride (when catalyzed by HCl), 1,1-Difluoroethylene,
Dinitroanilines, Ethylene, Ethylene diamine, Ethyl 2-formylpropionate oxime (when generated by using HCl as a catalyst),
Special Remarks on Corrosivity:
Highly corrosive. Incompatible with copper and copper alloys. It attacks nearly all metals (mercury, gold, platinium, tantalum,
silver, and certain alloys are exceptions). It is one of the most corrosive of the nonoxidizing acids in contact with copper alloys.
No corrosivity data on zinc, steel. Severe Corrosive effect on brass and bronze
Polymerization: Will not occur.
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation.
Toxicity to Animals:
Acute oral toxicity (LD50): 900 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 1108 ppm, 1 hours [Mouse]. Acute toxicity of
the vapor (LC50): 3124 ppm, 1 hours [Rat]. (Hydrochloric Acid)
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrochloric acid]. May cause damage to the
following organs: kidneys, liver, mucous membranes, upper respiratory tract, skin, eyes, Circulatory System, teeth.
Other Toxic Effects on Humans:
Very hazardous in case of skin contact (corrosive, irritant, permeator), of ingestion, . Hazardous in case of eye contact
(corrosive), of inhalation (lung corrosive).
Special Remarks on Toxicity to Animals:
Lowest Published Lethal Doses (LDL/LCL) LDL [Man] -Route: Oral; 2857 ug/kg LCL [Human] - Route: Inhalation; Dose: 1300
ppm/30M LCL [Rabbit] - Route: Inhalation; Dose: 4413 ppm/30M
Special Remarks on Chronic Effects on Humans:
May cause adverse reproductive effects (fetoxicity). May affect genetic material.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Corrosive. Causes severe skin irritation and burns. Eyes: Corrosive. Causes severe
eye irritation/conjuntivitis, burns, corneal necrosis. Inhalation: May be fatal if inhaled. Material is extremely destructive to
tissue of the mucous membranes and upper respiratory tract. Inhalation of hydrochloric acid fumes produces nose, throat,
and larryngeal burning, and irritation, pain and inflammation, coughing, sneezing, choking sensation, hoarseness, laryngeal
spasms, upper respiratory tract edema, chest pains, as well has headache, and palpitations. Inhalation of high concentrations
can result in corrosive burns, necrosis of bronchial epithelium, constriction of the larynx and bronchi, nasospetal perforation,
glottal closure, occur, particularly if exposure is prolonged. May affect the liver. Ingestion: May be fatal if swallowed. Causes
irritation and burning, ulceration, or perforation of the gastrointestinal tract and resultant peritonitis, gastric hemorrhage and
infection. Can also cause nausea, vomitting (with "coffee ground" emesis), diarrhea, thirst, difficulty swallowing, salivation,
chills, fever, uneasiness, shock, strictures and stenosis (esophogeal, gastric, pyloric). May affect behavior (excitement),
the cardiovascular system (weak rapid pulse, tachycardia), respiration (shallow respiration), and urinary system (kidneys-
renal failure, nephritis). Acute exposure via inhalation or ingestion can also cause erosion of tooth enamel. Chronic Potential
Health Effects: Prolonged or repeated inhalation and/or ingestion may affect liver, bleeding of nose and gums, nasal and oral
mucosal ulceration, conjunctivitis, respiratory tract (changes in pulmonary function, chronic bronchitis, overt respiratory tract
abnormalities), teeth (yellowing of teethand erosion of tooth enamel), kidneys, and behavior (muscle contraction or spasticity).
Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated eye contact with vapor/mist can cause
conjunctivitis dyspnea, bronchitis. Chemical pneumonitis and pulmonary edema can also
p. 5
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 6
Reactivity: 1
Specific hazard:
Protective Equipment:
Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Face shield.
References:
-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.
Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of
Chemical Safety Data, Edition II. -Guide de la loi et du règlement sur le transport des marchandises dangeureuses au canada.
Centre de conformité internatinal Ltée. 1986.
Other Special Considerations: Not available.
Created: 10/09/2005 05:45 PM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 7
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Toxicological Data on Ingredients: Sodium borate: ORAL (LD50): Acute: 2660 mg/kg [Rat.].
Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids
open. Cold water may be used. Do not use an eye ointment. Seek medical attention.
p. 1
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running
water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.
Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation: Not available.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with
a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and dispose of according to
local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Neutralize the residue with a dilute solution
of acetic acid. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary
system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local
authorities.
Precautions:
Do not ingest. Do not breathe dust. Wear suitable protective clothing If ingested, seek medical advice immediately and show
the container or the label. Avoid contact with skin and eyes Keep away from incompatibles such as oxidizing agents.
p. 2
Storage:
No specific storage is required. Use shelves or cabinets sturdy enough to bear the weight of the chemicals. Be sure that it is
not necessary to strain to reach materials, and that shelves are not overloaded.
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 0.31 (ppm) TWA: 5 (mg/m3) from ACGIH [1995] Consult local authorities for acceptable exposure limits.
p. 3
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Reactive with oxidizing agents.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: Not available.
Waste Disposal:
p. 4
Federal and State Regulations:
Pennsylvania RTK: Sodium borate Massachusetts RTK: Sodium borate TSCA 8(b) inventory: Sodium borate
Other Regulations: Not available..
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC): R36/38- Irritating to eyes and skin.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.
References:
-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.
Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of
Chemical Safety Data, Edition II.
Other Special Considerations: Not available.
Created: 10/09/2005 06:29 PM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 5
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Toxicological Data on Ingredients: Sodium hydroxide LD50: Not available. LC50: Not available.
p. 1
Section 4: First Aid Measures
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.
p. 2
cause serious explosions. Dry mixtures of sodium hydroxide and sodium tetrahydroborate liberate hydrogen explosively at
230-270 deg. C. Sodium Hydroxide reacts with sodium salt of trichlorophenol + methyl alcohol + trichlorobenzene + heat to
cause an explosion.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with
a dilute solution of acetic acid.
Large Spill:
Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray
to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.
Neutralize the residue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration level
above TLV. Check TLV on the MSDS and with local authorities.
Precautions:
Keep container dry. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitable
respiratory equipment. If you feel unwell, seek medical attention and show the label when possible. Avoid contact with skin
and eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis, moisture.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic. Deliquescent.
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Exposure Limits:
STEL: 2 (mg/m3) from ACGIH (TLV) [United States] TWA: 2 CEIL: 2 (mg/m3) from OSHA (PEL) [United States] CEIL: 2 (mg/
m3) from NIOSHConsult local authorities for acceptable exposure limits.
p. 3
pH (1% soln/water): 13.5 [Basic.]
Boiling Point: 1388°C (2530.4°F)
Melting Point: 323°C (613.4°F)
Critical Temperature: Not available.
Specific Gravity: 2.13 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility: Easily soluble in cold water.
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
p. 4
Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans:
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. May cause damage to the following organs: mucous
membranes, upper respiratory tract, skin, eyes.
Other Toxic Effects on Humans:
Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (corrosive, irritant,
permeator), of eye contact (corrosive), of ingestion, .
Special Remarks on Toxicity to Animals:
Lowest Published Lethal Dose: LDL [Rabbit] - Route: Oral; Dose: 500 mg/kg
Special Remarks on Chronic Effects on Humans: May affect genetic material. Investigation as a mutagen (cytogenetic
analysis)
Special Remarks on other Toxic Effects on Humans:
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 5
Other Classifications:
WHMIS (Canada): CLASS E: Corrosive solid.
DSCL (EEC):
R35- Causes severe burns. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39- Wear suitable gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 2
Personal Protection: j
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 0
Reactivity: 1
Specific hazard:
Protective Equipment:
Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate. Splash goggles.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 6
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Toxicological Data on Ingredients: Sodium thiosulfate pentahydrate LD50: Not available. LC50: Not available.
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention if irritation occurs.
p. 1
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Precautions:
Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
If you feel unwell, seek medical attention and show the label when possible. Keep away from incompatibles such as oxidizing
agents, acids, alkalis.
p. 2
Storage: Hygroscopic. Keep container tightly closed. Keep container in a cool, well-ventilated area.
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
p. 3
Conditions of Instability: Incompatible materials, moisture
Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
It is a strong reducing and can react with oxidizers. Reacts with acids to release sulfur dioxide. Sodium Thiosulfate
pentahydrate dissolves in its own water of hydation; it effloresces in warm dry air. Sodium Thiosulfate pentahydrate loses
water at 100 deg. C. It is incompatible with iodine, acids, lead, mercury, and silver salts (e.g. silver nitrate), halogens.
Hygroscopic; keep container tightly closed. Protect from moisture
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 4
DOT Classification: Not a DOT controlled material (United States).
Identification: Not applicable.
Special Provisions for Transport: Not applicable.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 5
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Toxicological Data on Ingredients: Iodine: ORAL (LD50): Acute: 14000 mg/kg [Rat]. 22000 mg/kg [Mouse].
p. 1
Section 4: First Aid Measures
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. WARM water MUST be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.
p. 2
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be
careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Precautions:
Keep container dry. Do not ingest. Do not breathe dust. Never add water to this product. In case of insufficient ventilation,
wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25°C (77°F).
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Exposure Limits:
STEL: 1 (mg/m3) from ACGIH (TLV) [United States] STEL: 0.1 (ppm) from ACGIH (TLV) [United States] TWA: 1 CEIL: 1 (mg/
m3) from OSHA (PEL) [United States] TWA: 0.1 CEIL: 0.1 (ppm) from OSHA (PEL) [United States] STEL: 0.1 (ppm) [United
Kingdom (UK)] STEL: 1.1 (mg/m3) [United Kingdom (UK)]Consult local authorities for acceptable exposure limits.
p. 3
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: The product is more soluble in oil; log(oil/water) = 2.5
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, methanol, diethyl ether.
Solubility:
Easily soluble in diethyl ether. Soluble in methanol. Very slightly soluble in cold water, hot water.
p. 4
to high concentrations of vapor can cause Dendritic Keratitis in which the corneal epithelium is sloughed off. Inhalation:
Excessive inhalation of iodine vapors may cause respiratory tract, nasal, and mucous membrane irritation with possible burns.
Symptoms may include coughing, tightness in the chest, burning sensations to the mucosal, tracheal, and pulmonary tissues,
rhinitis, dyspnea/respiratory distress, coughing, sneezing, pulmonary edema, chemical pneumonitis, edema of the larynx and
bronchi, pharyngitis, swelling of the parotid gland, and cachexia. High exposure may lead to lung disease and may also affect
behavior/central nervous system (delirium, hallucination, depression, seizure, dizziness, headache, stupor, somnolence).
Ingestion: Ingestion of large doses may cause irritation of mouth of the digestive tract with thirst, nausea, vomiting, abdominal
pain, hypermotility, and diarrhea, staining of mouth, esophagus, lips, mucous membranes, metallic taste, abdominal pain,
fever. It ma y also affect the cardiovascular system (tachycardia, hypotension, cardiovascular collapse), behavior/central
nervous system(delirium, dizziness, headache, hallucinations, seizures,
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 5
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Personal Protection: j
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate. Splash goggles.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 6
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Toxicological Data on Ingredients: Ascorbic acid: ORAL (LD50): Acute: 11900 mg/kg [Rat]. 3367 mg/kg [Mouse].
Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for
bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or
prolonged exposure is not known to aggravate medical condition.
Eye Contact:
p. 1
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention if irritation occurs.
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Precautions:
p. 2
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not
breathe dust. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles
such as oxidizing agents.
Storage:
Keep container tightly closed. Keep container in a cool, well-ventilated area. Air Sensitive Sensitive to light. Store in light-
resistant containers.
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
p. 3
Section 10: Stability and Reactivity Data
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 4
Section 14: Transport Information
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 5
He a lt h 2
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Chemical Name: Sodium Carbonate, Anhydrous For non-emergency assistance, call: 1-281-441-4400
Toxicological Data on Ingredients: Sodium carbonate: ORAL (LD50): Acute: 4090 mg/kg [Rat]. 6600 mg/kg [Mouse]. DUST
(LC50): Acute: 2300 mg/m 2 hours [Rat]. 1200 mg/m 2 hours [Mouse].
Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation
(lung irritant).
Potential Chronic Health Effects:
Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS:
Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may
be toxic to upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce target organs
damage.
p. 1
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with
a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and dispose of according to
local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Neutralize the residue with a dilute solution
of acetic acid. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary
system.
p. 2
Section 7: Handling and Storage
Precautions:
Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable
respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with
skin and eyes. Keep away from incompatibles such as acids.
Storage:
Hygroscopic. Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24°C (75.2°F).
Hygroscopic
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
p. 3
Soluble in hot water, glycerol. Partially soluble in cold water. Insoluble in acetone, alcohol.
p. 4
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 5
Created: 10/10/2005 08:26 PM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 6
He a lt h 1
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P ro t e c t io n
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. WARM water MUST be used. Get medical attention if irritation occurs.
p. 1
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Precautions:
Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a
fume hood. Ground all equipment containing material. Do not breathe dust. Keep away from incompatibles such as oxidizing
agents.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24°C (75.2°F).
p. 2
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
p. 3
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 4
Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
This product is not classified according to the EU regulations. Not applicable.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 1
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 5
He a lt h 2
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Toxicological Data on Ingredients: Methyl orange: ORAL (LD50): Acute: 60 mg/kg [Rat].
p. 1
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. WARM water MUST be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Seek
medical attention.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Serious Ingestion: Not available.
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for
assistance on disposal.
p. 2
Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate
the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable
protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice
immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as
oxidizing agents.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25°C (77°F).
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
p. 3
Section 10: Stability and Reactivity Data
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 4
Identification: : Dye, solid, toxic, n.o.s. (Methyl orange) UNNA: 3143 PG: III
Special Provisions for Transport: Not available.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 5
He a lt h 2
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Toxicological Data on Ingredients: Ethyl alcohol 200 Proof: ORAL (LD50): Acute: 7060 mg/kg [Rat.]. 3450 mg/kg [Mouse].
VAPOR (LC50): Acute: 20000 ppm 8 hours [Rat]. 39000 mg/m 4 hours [Mouse]. Phenolphthalein, powder LD50: Not available.
LC50: Not available.
p. 1
for human [Ethyl alcohol 200 Proof]. DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol
200 Proof]. Classified Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 200 Proof]. The substance is toxic to blood,
the reproductive system, liver, upper respiratory tract, skin, central nervous system (CNS). The substance may be toxic to
kidneys. Repeated or prolonged exposure to the substance can produce target organs damage.
Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids
open. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention if symptoms appear.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical
attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.
p. 2
Containers should be grounded. CAUTION: MAY BURN WITH NEAR INVISIBLE FLAME Vapor may travel considerable
distance to source of ignition and flash back. (Ethyl alcohol 200 Proof)
Special Remarks on Explosion Hazards:
Ethanol has an explosive reaction with the oxidized coating around potassium metal. Ethanol ignites and then explodes on
contact with acetic anhydride + sodium hydrosulfate (ignites and may explode), disulfuric acid + nitric acid, phosphorous(III)
oxide platinum, potassium-tert-butoxide+ acids. Ethanol forms explosive products in reaction with the following compound :
ammonia + silver nitrate (forms silver nitride and silver fulminate), iodine + phosphorus (forms ethane iodide), magnesium
perchlorate (forms ethyl perchlorate), mercuric nitrate, nitric acid + silver (forms silver fulminate) silver nitrate (forms ethyl
nitrate) silver(I) oxide + ammonia or hydrazine (forms silver nitride and silver fulminate), sodium (evolves hydrogen gas). (Ethyl
alcohol 200 Proof)
Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill:
Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confined
areas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS
and with local authorities.
Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do
not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear
suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids, alkalis.
Storage:
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and
sealed until ready for use. Avoid all possible sources of ignition (spark or flame).
Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
Ethyl alcohol 200 Proof TWA: 1000 (ppm) from ACGIH (TLV) [United States] [1999] TWA: 1000 (ppm) from OSHA (PEL)
[United States] TWA: 1900 (mg/m3) from OSHA (PEL) [United States] TWA: 1000 (ppm) from NIOSH TWA: 1000 (ppm)
[United Kingdom (UK)] TWA: 1920 (mg/m3) [United Kingdom (UK)] TWA: 1000 STEL: 1250 (ppm) [Canada]Consult local
authorities for acceptable exposure limits.
p. 3
Physical state and appearance: Liquid.
Odor: Not available.
Taste: Not available.
Molecular Weight: Not applicable.
Color: Colorless.
pH (1% soln/water): Neutral.
Boiling Point: The lowest known value is 78.5°C (173.3°F) (Ethyl alcohol 200 Proof). Weighted average: 79.58°C (175.2°F)
Melting Point: May start to solidify at -114.1°C (-173.4°F) based on data for: Ethyl alcohol 200 Proof.
Critical Temperature: The lowest known value is 243°C (469.4°F) (Ethyl alcohol 200 Proof).
Specific Gravity: Weighted average: 0.8 (Water = 1)
Vapor Pressure: The highest known value is 5.7 kPa (@ 20°C) (Ethyl alcohol 200 Proof). Weighted average: 5.53 kPa (@
20°C)
Vapor Density: The highest known value is 1.59 (Air = 1) (Ethyl alcohol 200 Proof). Weighted average: 1.54 (Air = 1)
Volatility: Not available.
Odor Threshold: The highest known value is 100 ppm (Ethyl alcohol 200 Proof)
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, methanol, diethyl ether, acetone.
Solubility:
Easily soluble in cold water, hot water, methanol, diethyl ether. Soluble in acetone.
p. 4
Section 11: Toxicological Information
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 5
Federal and State Regulations:
California prop. 65: This product contains the following ingredients for which the State of California has found to cause
cancer, birth defects or other reproductive harm, which would require a warning under the statute: Ethyl alcohol 200 Proof;
Phenolphthalein, powder California prop. 65: This product contains the following ingredients for which the State of California
has found to cause birth defects which would require a warning under the statute: Ethyl alcohol 200 Proof California prop. 65:
This product contains the following ingredients for which the State of California has found to cause cancer which would require
a warning under the statute: Ethyl alcohol 200 Proof; Phenolphthalein, powder Rhode Island RTK hazardous substances:
Ethyl alcohol 200 Proof Pennsylvania RTK: Ethyl alcohol 200 Proof Florida: Ethyl alcohol 200 Proof Massachusetts RTK: Ethyl
alcohol 200 Proof New Jersey: Ethyl alcohol 200 Proof TSCA 8(b) inventory: Water; Ethyl alcohol 200 Proof; Phenolphthalein,
powder
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada):
CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS D-2A: Material causing other toxic effects
(VERY TOXIC).
DSCL (EEC):
R11- Highly flammable. R22- Harmful if swallowed. R45- May cause cancer. S2- Keep out of the reach of children. S46-
If swallowed, seek medical advice immediately and show this container or label. S53- Avoid exposure - obtain special
instructions before use.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 3
Reactivity: 0
Personal Protection: h
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 3
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Splash goggles.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 6
He a lt h 2
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Toxicological Data on Ingredients: Barium chloride dihydrate LD50: Not available. LC50: Not available.
Eye Contact:
p. 1
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek medical attention.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Serious Ingestion: Not available.
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be
careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
p. 2
Precautions:
Keep locked up.. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation,
wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 0.5 (mg (Ba)/m) from ACGIH (TLV) [United States] Consult local authorities for acceptable exposure limits.
p. 3
Section 10: Stability and Reactivity Data
p. 4
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
p. 5
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 6
He a lt h 3
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P ro t e c t io n
Toxicological Data on Ingredients: Silver nitrate: ORAL (LD50): Acute: 1173 mg/kg [Rat]. 50 mg/kg [Mouse]. 473 mg/kg
[Guinea pig].
p. 1
Section 4: First Aid Measures
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
p. 2
Large Spill:
Oxidizing material. Corrosive solid. Stop leak if without risk. Do not get water inside container. Avoid contact with a
combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material.
Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance
on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with
local authorities.
Precautions:
Keep container dry. Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Do
not ingest. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory
equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and
eyes.
Storage:
Keep container tightly closed. Keep container in a cool, well-ventilated area. Separate from acids, alkalies, reducing agents
and combustibles. See NFPA 43A, Code for the Storage of Liquid and Solid Oxidizers. Sensitive to light. Store in light-resistant
containers.
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Exposure Limits:
TWA: 0.01 (mg/m Ag) from ACGIH (TLV) [United States] TWA: 0.01 (mg/m Ag) from OSHA (PEL) [United States]3 Consult
local authorities for acceptable exposure limits.
p. 3
Specific Gravity: 4.35 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: 5.8 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, diethyl ether.
Solubility:
Easily soluble in cold water, hot water. Soluble in diethyl ether. Very slightly soluble in acetone. Solubility in water: 122 g/100
ml water @ 0 deg. C. Solubility in water: 952 g /100 ml water @ 190 deg. C Solubility in alcohol: 1 g/30 ml alcohol; 1g/ 6.5 ml
boiling alcohol. Solubility in acetone: 1 g/ 253 ml acetone
Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 50 mg/kg [Mouse].
Chronic Effects on Humans:
Causes damage to the following organs: lungs. May cause damage to the following organs: mucous membranes, skin, eyes.
Other Toxic Effects on Humans:
Very hazardous in case of skin contact (irritant), of ingestion. Hazardous in case of skin contact (permeator), of inhalation.
Slightly hazardous in case of skin contact (corrosive).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
May affect genetic material (mutagenic). May cause cancer based on animal test data. May cause adverse reproductive
effects.
Special Remarks on other Toxic Effects on Humans:
p. 4
Acute Potential Health Effects: Skin: Causes severe irritation and burns. It may cause dermatitis. It may be absorbed through
the skin. Eyes: Causes severe irritation, corneal opacification, bleeding conjunctiva, burns of conjunctiva, argyria, blindness
Inhalation: Causes irritaiton of the respiratory tract and mucous membranes with possible chemical burns. Symptoms may
include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, vomiting. Ingestion: Severe
gastrointestinal tract irritation and burns, pain and burning in the mouth, violent abdominal pain, argryia -grayish/blackening of
skin and mucous membranes, throat and abdomen, salivation, vomiting of black material, diarrhea, hypermotility, ulcerative
gingivitis . May affect kidneys (lesions of kidneys, anuria, ), lungs
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 5
eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible). S46- If swallowed, seek medical advice immediately and show this container or label. S60- This material and its
container must be disposed of as hazardous waste. S61- Avoid release to the environment. Refer to special instructions/
Safety data sheets.
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Personal Protection: j
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves (impervious). Synthetic apron. Wear appropriate respirator when ventilation is inadequate. Splash goggles.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 6
He a lt h 2
1 1
Fire
2 0
Re a c t iv it y 0
P e rs o n a l E
P ro t e c t io n
Toxicological Data on Ingredients: Ammonium sulfate: ORAL (LD50): Acute: 2840 mg/kg [Rat]. 640 mg/kg [Mouse].
Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.
p. 1
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Precautions:
p. 2
Keep away from heat. Keep away from sources of ignition. Do not ingest. Do not breathe dust. Wear suitable protective
clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately
and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing
agents.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
p. 3
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Excess heat, incompatible materials.
Incompatibility with various substances:
Highly reactive with oxidizing agents. Reactive with alkalis.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Incompatible with the following: Potassium + ammonium nitrate, potassium chlorate, potassium nitrate, potassium nitrite,
sodium hypochlorite, sodium/potassium alloy + ammonium nitrate. Substance should not contact either zinc or copper bearing
materials. Reacts with alkali to release ammonia.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
p. 4
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
p. 5
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 6
He a lt h 0
0 0
Fire
0 0
Re a c t iv it y 0
P e rs o n a l A
P ro t e c t io n
p. 1
Skin Contact: Not applicable.
Serious Skin Contact: Not available.
Inhalation: Not applicable.
Serious Inhalation: Not available.
Ingestion: Not Applicable
Serious Ingestion: Not available.
Small Spill: Mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Precautions: No specific safety phrase has been found applicable for this product.
Storage: Not applicable.
p. 2
Odor: Odorless.
Taste: Not available.
Molecular Weight: 18.02 g/mole
Color: Colorless.
pH (1% soln/water): 7 [Neutral.]
Boiling Point: 100°C (212°F)
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: 1 (Water = 1)
Vapor Pressure: 2.3 kPa (@ 20°C)
Vapor Density: 0.62 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not applicable
Solubility: Not Applicable
p. 3
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Not available.
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 4
Protective Equipment:
Not applicable. Lab coat. Not applicable. Safety glasses.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 5
ICE MATERIAL SAFETY DATA SHEET N/A=Not Applicable
Prepared by: Regulatory Affairs Dept. (Prepared According to 29 CFR 1910.1200) Effective Date: 8/09 Revision: N/A
SECTION 1-PRODUCT IDENTIFICATION AND SUPPLIER INFORMATION
Manufacturer’s Name: Product Name: Liquid Pretreat De-Icer Supplier’s Name:
Misco Products Corporation Generic Name: Ice melt & Remover
Manufacturer’s Address: Chemical Family: Inhibited Calcium Chloride Blend Supplier’s Address:
1048 Stinson Drive Reading, PA 19605 Formula: Proprietary
Manufacturer’s Phone #: (610) 926-4106 Supplier’s Phone #:
SECTION 2-INGREDIENT INFORMATION
CHEMICAL NAME CAS NO. WT. % PEL TWA-TLV STEL-TLV
Water 7732-18-5 to 100
Calcium Chloride 10043-52-4 25 to 35
Magnesium Chloride 7791-18-6 0 to 5
Urea 57-13-6 0 to 5
Corrosion Inhibitor N/A 0 to 5
FOR EMERGENCY MEDICAL OR TRANSPORT INFORMATION: CHEM-TEL, Inc. @ 800-255-3924 (24 hours, 7 days per week)
This product contains the following toxic chemical(s) subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act
of 1986 and of 40 CFR 372.
CAS# Chemical Name Percent by Weight
None
This product contains the following chemical(s) which have been established to be either a carcinogen or suspected carcinogen.
CAS# Chemical Name Percent by Weight
None
SECTION 11-OTHER INFORMATION
This company cannot anticipate all conditions of handling and use of this product. Therefore, this company accepts no responsibility for results obtained by the
application of this information, or the safety and suitability of our products either alone or in combination with other products. It is the responsibility of the user to
provide a safe workplace, using the health and safety information contained herein as a guide. This company will accept no liability for damages or loss incurred from the
improper handling and use of this product
He a lt h 1
0 0
F ir e
1 0
Re a c t iv it y 0
Pe rson a l E
P r o t e c t io n
Toxicological Data on Ingredients: Potassium Iodide LD50: Not available. LC50: Not available. Lowest Published Lethal
Dose: LDL [Mouse] - Route: Oral; Dose: 1862 mg/kg LDL [Rabbit] - Route: Oral; Dose: 916 mg/kg
Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.
TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female,
Development toxin [POSSIBLE]. The substance may be toxic to thyroid. Repeated or prolonged exposure to the substance
can produce target organs damage.
Eye Contact:
p. 1
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention if irritation occurs.
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.
Precautions:
Do not breathe dust. Wear suitable protective clothing. If you feel unwell, seek medical attention and show the label when
possible. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, moisture.
p. 2
Storage:
Moisture Sensitive. Light Sensitive. Air SensitiveKeep container tightly closed in light-resistant containers. Keep container in a
cool, well-ventilated area.
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
p. 3
Instability Temperature: Not available.
Conditions of Instability:
Light, moisture, incompatible materials. It is stable under ordinary conditions of use and storage. On long exposure to air, it
becomes yellow due to release of iodine.
Incompatibility with various substances: Reactive with oxidizing agents, reducing agents, organic materials, metals, acids.
Corrosivity:
Corrosive in presence of steel, of aluminum, of zinc. Non-corrosive in presence of glass, of copper, of stainless steel(304), of
stainless steel(316).
Special Remarks on Reactivity:
Moisture Sensitive. Light Sensitive. Air Sensitive. Air causes decomposition to iodine. Reacts violently with strong oxidizers,
bromotrifluorides, chlorotrifluorides, fluorine perchlorate, metallic salts. Attacks metals in moist environments. Also
incompatible with salts of alkaloids, chloral hydrate, calomel (mercurous chloride), potassium chlorate, tartaric and other
acids, oxidants, diazonium salts, charcoal, ozone, strong reducers, alkali metals, metals (brass, aluminum magnesium, zinc,
cadmium, copper, tin, nickel, steel), metallic salts, organic materials, light.
Special Remarks on Corrosivity:
Incompatible with water, producing a corrosive. Corrosive in all concentrations to most metals, except stainless steel, titanium,
and tantalum.
Polymerization: Will not occur.
p. 4
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
p. 5
Other Special Considerations: Not available.
Created: 10/11/2005 12:21 PM
Last Updated: 11/01/2010 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 6
SAFETY DATA SHEET
Creation Date 09-Apr-2010 Revision Date 26-Dec-2021 Revision Number 5
1. Identification
Product Name Copper(II) sulfate
Company
Fisher Scientific Company Acros Organics
One Reagent Lane One Reagent Lane
Fair Lawn, NJ 07410 Fair Lawn, NJ 07410
Tel: (201) 796-7100
Emergency Telephone Number For information US call: 001-800-ACROS-01 / Europe call: +32 14 57 52 11
Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99
CHEMTREC Tel. No.US:001-800-424-9300 / Europe:001-703-527-3887
2. Hazard(s) identification
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label Elements
Signal Word
Warning
Hazard Statements
Harmful if swallowed
Causes skin irritation
______________________________________________________________________________________________
Page 1 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________
Precautionary Statements
Prevention
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Skin
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Ingestion
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Very toxic to aquatic life with long lasting effects
3. Composition/Information on Ingredients
Component CAS No Weight %
Cupric sulfate 7758-98-7 98
4. First-aid measures
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get
medical attention.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention if
symptoms occur.
Inhalation Remove to fresh air. Do not use mouth-to-mouth method if victim ingested or inhaled the
substance; give artificial respiration with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device. Get medical attention. If not breathing,
give artificial respiration.
Ingestion Do NOT induce vomiting. Call a physician or poison control center immediately.
5. Fire-fighting measures
______________________________________________________________________________________________
Page 2 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________
Suitable Extinguishing Media Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.
NFPA
Health Flammability Instability Physical hazards
2 0 1 N/A
Methods for Containment and Clean Sweep up and shovel into suitable containers for disposal. Avoid dust formation.
Up
Storage. Keep containers tightly closed in a dry, cool and well-ventilated place. Store under an inert
atmosphere. Incompatible Materials. Strong bases. Metals. Alkali metals. Finely powdered
metals.
Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA)
Cupric sulfate TWA: 1 mg/m3 IDLH: 100 mg/m3
TWA: 1 mg/m3
Legend
______________________________________________________________________________________________
Page 3 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________
Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations
and safety showers are close to the workstation location.
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
Conditions to Avoid Avoid dust formation. Incompatible products. Excess heat. Exposure to moisture.
Incompatible Materials Strong bases, Metals, Alkali metals, Finely powdered metals
______________________________________________________________________________________________
Page 4 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________
Product Information
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
Cupric sulfate LD50 = 481 mg/kg ( Rat ) LD50 > 1000 mg/kg ( Rabbit ) Not listed
Toxicologically Synergistic No information available
Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Other Adverse Effects The toxicological properties have not been fully investigated.
Mobility Will likely be mobile in the environment due to its water solubility.
______________________________________________________________________________________________
Page 5 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________
Legend:
TSCA US EPA (TSCA) - Toxic Substances Control Act, (40 CFR Part 710)
X - Listed
'-' - Not Listed
International Inventories
Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), China (IECSC), Korea
(KECL).
Component CAS No DSL NDSL EINECS PICCS ENCS ISHL AICS IECSC KECL
Cupric sulfate 7758-98-7 X - 231-847-6 X X X X X KE-08956
SARA 313
Component CAS No Weight % SARA 313 - Threshold
Values %
Cupric sulfate 7758-98-7 98 1.0
______________________________________________________________________________________________
Page 6 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________
CERCLA This material, as supplied, contains one or more substances regulated as a hazardous
substance under the Comprehensive Environmental Response Compensation and Liability
Act (CERCLA) (40 CFR 302)
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. Department of Homeland This product does not contain any DHS chemicals.
Security
Component REACH (1907/2006) - Annex XIV - REACH (1907/2006) - Annex XVII - REACH Regulation (EC
Substances Subject to Restrictions on Certain Dangerous 1907/2006) article 59 - Candidate
Authorization Substances List of Substances of Very High
Concern (SVHC)
Cupric sulfate - Use restricted. See item 75. -
(see link for restriction details)
https://echa.europa.eu/substances-restricted-under-reach
Safety, health and environmental regulations/legislation specific for the substance or mixture
Component CAS No Seveso III Directive Seveso III Directive Rotterdam Basel Convention
(2012/18/EC) - (2012/18/EC) - Convention (PIC) (Hazardous Waste)
Qualifying Quantities Qualifying Quantities
for Major Accident for Safety Report
Notification Requirements
Cupric sulfate 7758-98-7 Not applicable Not applicable Not applicable Annex I - Y22
______________________________________________________________________________________________
Page 7 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text
End of SDS
______________________________________________________________________________________________
Page 8 / 8
Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 1 of 7
Rhodamine B, 1%
Supplier Details:
Fisher Science Education
15 Jet View Drive, Rochester, NY 14624
Irritant
Acute toxicity (oral, dermal, inhalation), category 4
Eye irritation, category 2A
Environmentally Damaging
Acute hazards to the aquatic environment, category 3
Chronic hazards to the aquatic environment, category 3
Hazard statements:
Harmful if swallowed
Causes serious eye irritation
Harmful to aquatic life with long lasting effects
Precautionary statements:
If medical advice is needed, have product container or label at hand
Keep out of reach of children
Read label before use
Do not eat, drink or smoke when using this product
Wash skin thoroughly after handling
Avoid release to the environment
Wear protective gloves/protective clothing/eye protection/face protection
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
Continue rinsing
D2B
NFPA/HMIS
Ingredients:
Control Parameters: , , OSHA PEL TWA (Total Dust) 15 mg/m3 (50 mppcf*)
, , ACGIH TLV TWA (inhalable particles) 10 mg/m3
Appropriate Engineering controls: Emergency eye wash fountains and safety showers should be available in
the immediate vicinity of use/handling.Provide exhaust ventilation or
other engineering controls to keep the airborne concentrations of vapor
or dusts (total/respirable) below the applicable workplace exposure limits
(Occupational Exposure Limits-OELs) indicated above.It is recommended
that all dust control equipment such as local exhaust ventilation and
material transport systems involved in handling of this product contain
explosion relief vents or an explosion suppression system or an oxygen
deficient environment.Ensure that dust-handling systems (such as
exhaust ducts, dust collectors, vessels, and processing equipment) are
designed in a manner to prevent the escape of dust into the work area
(i.e., there is no leakage from the equipment).Normal ventilation is
adequate.
Respiratory protection: Not required under normal conditions of use. Where risk assessment
shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a
backup to engineering controls.When necessary use NIOSH approved
breathing equipment.
Protection of skin: Select glove material impermeable and resistant to the substance.Select
glove material based on rates of diffusion and degradation.Dispose of
contaminated gloves after use in accordance with applicable laws and
good laboratory practices.Use proper glove removal technique without
touching outer surface. Avoid skin contact with used gloves.Wear
protective clothing.
Eye protection: Wear equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN
166(EU).Safety glasses or goggles are appropriate eye protection.
General hygienic measures: Perform routine housekeeping.Wash hands before breaks and at the end
of work.Avoid contact with skin, eyes, and clothing.Before wearing wash
contaminated clothing.
Decomposition
Evaporation rate: Not determined Not determined
temperature:
Acute Toxicity:
Corrosion Irritation:
Ecotoxicity
Fish LC50 - Oncorhynchus mykiss (rainbow trout) - 217 mg/l - 96 h: 81-88-9 (Rhodamine B)
Invertebrates EC50 - Daphnia magna (Water flea) - 22.9 mg/l - 48 h: 81-88-9 (Rhodamine B)
Persistence and degradability: Not readily biodegradable.
Bioaccumulative potential: Bioconcentration factor (BCF): < 0.2
Mobility in soil:
Other adverse effects:
UN-Number
Not Regulated.
UN proper shipping name
Not Regulated.
Transport hazard class(es)
Packing group:Not Regulated
Environmental hazard:
Transport in bulk:
Special precautions for user:
Proposition 65 (California):
Canada
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the
SDS contains all the information required by the Controlled Products Regulations.Note:. The responsibility to
provide a safe workplace remains with the user.The user should consider the health hazards and safety information
contained herein as a guide and should take those precautions required in an individual operation to instruct
employees and develop work practice procedures for a safe work environment.The information contained herein is,
to the best of our knowledge and belief, accurate.However, since the conditions of handling and use are beyond
our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this
material.It is the responsibility of the user to comply with all applicable laws and regulations applicable to this
material.
GHS Full Text Phrases:
Toxicological Data on Ingredients: Sand LD50: Not available. LC50: Not available. Quartz: LCL (Human) - Route:
Inhalation; Dose: 300 ug/m3/10Y.
Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC. Classified A2 (Suspected for human.) by ACGIH.
MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not
available. The substance may be toxic to lungs, upper respiratory tract. Repeated or prolonged exposure to the substance can
produce target organs damage.
p. 1
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention if irritation occurs.
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a
concentration level above TLV. Check TLV on the MSDS and with local authorities.
Precautions:
Keep locked up.. Do not breathe dust. Wear suitable protective clothing. If you feel unwell, seek medical attention and show
the label when possible. Keep away from incompatibles such as oxidizing agents, alkalis.
p. 2
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24°C (75.2°F).
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 0.05 (mg/m3) from ACGIH (TLV) [United States] Respirable [Quartz or Crystalline Silica] TWA: 0.05 (mg/m3) from
NIOSH Respirable. [Quartz or Crystalline Silica]Consult local authorities for acceptable exposure limits.
p. 3
Conditions of Instability: Incompatibles
Incompatibility with various substances: Reactive with oxidizing agents, alkalis.
Corrosivity: Not available.
Special Remarks on Reactivity:
Incompatible with oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide, oxygen difluroide. When exposed
to high temperature quartz can change crystalline structure to form tridymite (above 870 C) or crystobalite (above 1470 C).
Soluble in hydrofluoric acid and produces a corrosive gas - silicon tetrafluoride. Quartz is attacked by strong alkalis and
hydrofluoric acid.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
p. 4
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
References:
-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.
Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of
Chemical Safety Data, Edition II.
Other Special Considerations: Not available.
Created: 10/09/2005 06:23 PM
p. 5
Last Updated: 11/01/2010 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.
p. 6
Tata Chemicals Ltd. MSDS – CEMENT
2. HAZARD IDENTIFICATION
Hazard Classification ACGIH TLV-
NIOSH REL
OSHA PEL TWA
Hazardous Substances (8-Hour
(8-Hour TWA) (1995–1996)
TWA)
(8-Hour TWA)
Calcium sulphate 5 mg
(CAS#7778-18-9) respirable dust
/m
3 10 mg total
[Gypsum (CAS#13397- 3
dust/m
24-5)] 10 mg total
3
Nominal 5% by weight dust / m
Calcium Oxide
(CAS#1306-78-8) 3 3
5 mg / m 2 mg / m
(Free Lime) < 4% by
weight
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Tata Chemicals Ltd. MSDS – CEMENT
10 mg of
0.10 mg 0.05 mg
Crystalline silica respirable dust
3 respirable respirable
(CAS#14808-60-7 /m 3 3
quartz / m quartz / m
(%SiO2+2)
LABEL ELEMENTS
Signal word Danger
Hazard statement
Precautionary statement
Cement 100%
Inhalation Move the person to a non-polluted area. The dust in the throat and nasal ducts
must be removed immediately. Consult a physician if the irritation persists.
Skin Wash the affected area thoroughly with soap and water before continuing. If
irritation, pain or other skin trouble occurs, seek medical advice. Clothing
contaminated by wet cement, concrete or mortar should be removed and
washed thoroughly before use.
Antidote
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Tata Chemicals Ltd. MSDS – CEMENT
Most important Eye Contact- Eye contact with cement (dry or wet) may cause serious and
symptoms/ effects, potentially irreversible injuries.
acute and or delayed Inhalation- Frequent inhalation of large quantities of cement dust over a long
period of time increases the risk of developing lung diseases.
Skin contact- Cement may have an irritating effect on moist skin (due to
transpiration or humidity) after prolonged contact. Prolonged skin contact with
wet cement or fresh concrete may causes serious burns because they develop
without pain being felt (for example when kneeling in-fresh concrete even when
wearing trousers). Repeated skin contact with wet cement may cause contact
dermatitis.
Ingestion- No Relevant routes of entry, only by accident
Indication of
immediate medical
attention and special
treatment needed
Precautions for the Do not attempt to wash Portland cement down drains. Dispose of waste
environment material according to local, state and federal regulations.
Clean up method ● Recover the spillage in a dry state if possible. Minimize generation of
airborne dust. The product can be slurred by the addition of water but will
subsequently set as a hard material.
● Do not wash cement down sewage and drainage system
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Tata Chemicals Ltd. MSDS – CEMENT
7. HANDLING AND STORAGE
Incompatibilities Moisture (Water). Keep away from unintentional contact with water.
Personal protection
Exposure limits
TLV-TWA NA TLV-STEL NA
Appropriate Use local exhaust or general dilution ventilation to control exposure below
Engineering applicable limits.
Control
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Tata Chemicals Ltd. MSDS – CEMENT
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Solid grey Molecular Specific No data
particles Weight gravity available
Evaporation Viscosity @ PH
rate 25 oC
Octanol / No data No data
Water Available available
Partition
Coefficient
Condition to If stored appropriately dry cements are stable and compatible with most building
avoid materials. When mixed with water they cure and form a stable mixture which may
not react with the environment.
Presence of moisture during storage may cause lumps and product quality loss.
Avoid uncontrolled application of aluminium powder with wet cement as it liberates
hydrogen.
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Tata Chemicals Ltd. MSDS – CEMENT
11. TOXICOLOGICAL INFORMATION
Routes of Inhalation.
exposure
Updated as On : 21.06.2021 70 | P a g e
Tata Chemicals Ltd. MSDS – CEMENT
14. TRANSPORT INFORMATION
UN No. …… IMDG No. ---
Shipping Name cement Hazard class ---
Packing group --- Hazard Sub class ---
Marine Pollutant --- Labels required ---
Warning Statement ---
Packaging /
Precaution
Shipping Marking
PHRASES R:
R37/38 Irritates respiratory system and skin
R41 Risk of serious damage to eyes
R43 Possible sensitization in case of skin contact.
PHRASES S:
S 2 Keep out of the reach of children
S22 Do not breathe dust
S24/25 Avoid contact with eyes and skin
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection
S46 If swallowed, seek medical advice immediately and show this container or label
The information provided in this Material Safety data sheet is correct to the best of our knowledge,
information and belief at the date of its publication.The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with other
materials
Updated as On : 21.06.2021 71 | P a g e
Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017
1. Identification
Product identifier
Product name Lubricating Oil
2. Hazard(s) identification
Label elements
Hazard statements NC Not Classified
Other hazards
This substance is not classified as PBT or vPvB according to current EU criteria.
3. Composition/information on ingredients
Substances
Product name Lubricating Oil
4. First-aid measures
1/8
Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017
Lubricating Oil
General information If in doubt, get medical attention promptly. Show this Safety Data Sheet to the medical
personnel.
Skin Contact No specific recommendations. Rinse with water. Get medical attention if any discomfort
continues.
Eye contact Remove any contact lenses and open eyelids wide apart. Rinse with water. Get medical
attention if any discomfort continues.
Protection of first aiders Use protective equipment appropriate for surrounding materials.
Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation.
5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry
powder or water fog. Use fire-extinguishing media suitable for the surrounding fire.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Hazardous combustion Thermal decomposition or combustion products may include the following substances:
products Harmful gases or vapors.
Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing. Standard Firefighter's clothing including helmets, protective boots and gloves will
provide a basic level of protection for chemical incidents.
2/8
Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017
Lubricating Oil
Environmental precautions
Environmental precautions Avoid discharge into drains or watercourses or onto the ground.
Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.
Advice on general Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash
occupational hygiene before reuse. Wash contaminated clothing before reuse.
Control parameters
Occupational exposure limits
Long-term exposure limit (8-hour TWA): OSHA 5 mg/m³
Long-term exposure limit (8-hour TWA): ACGIH 5 mg/m³
Short-term exposure limit (15-minute): ACGIH 10 mg/m³
OSHA = Occupational Safety and Health Administration.
ACGIH = American Conference of Governmental Industrial Hygienists.
Exposure controls
Protective equipment
Eye/face protection No specific eye protection required during normal use. Large Spillages: Eyewear complying
with an approved standard should be worn if a risk assessment indicates eye contact is
possible.
3/8
Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017
Lubricating Oil
Hand protection No specific hand protection recommended. Large Spillages: Wear protective gloves.
Other skin and body Wear appropriate clothing to prevent repeated or prolonged skin contact.
protection
Hygiene measures Wash after use and before eating, smoking and using the toilet. Do not eat, drink or smoke
when using this product.
Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation is
inadequate, suitable respiratory protection must be worn.
Color Water-white.
Odor Odorless.
pH Not applicable.
Volatility 3% wt (Max)
Reactivity See the other subsections of this section for further details.
Stability Stable at normal ambient temperatures and when used as recommended. Stable under the
prescribed storage conditions.
4/8
Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017
Lubricating Oil
Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.
Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.
Hazardous decomposition Does not decompose when used and stored as recommended. Thermal decomposition or
products combustion products may include the following substances: Harmful gases or vapors.
Skin corrosion/irritation
Animal data Based on available data the classification criteria are not met.
Respiratory sensitization
Respiratory sensitization Based on available data the classification criteria are not met.
Skin sensitization
Skin sensitization Based on available data the classification criteria are not met.
Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.
Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.
Reproductive toxicity - Based on available data the classification criteria are not met.
development
Aspiration hazard
Aspiration hazard Based on available data the classification criteria are not met.
5/8
Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017
Lubricating Oil
General information No specific health hazards known. The severity of the symptoms described will vary
dependent on the concentration and the length of exposure.
Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation.
Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have
hazardous effects on the environment.
Toxicity Based on available data the classification criteria are not met.
Bioaccumulative potential
Bio-Accumulative Potential No data available on bioaccumulation.
Mobility in soil
Mobility No data available.
Disposal methods Dispose of surplus products and those that cannot be recycled via a licensed waste disposal
contractor. Waste packaging should be collected for reuse or recycling. Incineration or landfill
should only be considered when recycling is not feasible. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of the local water
authority.
General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, DOT).
UN Number
Not applicable.
6/8
Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017
Lubricating Oil
Packing group
Not applicable.
Environmental hazards
US Federal Regulations
SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities
None of the ingredients are listed or exempt.
US State Regulations
California Proposition 65 Carcinogens and Reproductive Toxins
None of the ingredients are listed or exempt.
7/8
Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017
Lubricating Oil
Inventories
US - TSCA
None of the ingredients are listed or exempt.
Revision 7
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
8/8
Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 02.09.2015 Page 1 of 6
Vegetable Oil
Hazard statements:
Precautionary statements:
If medical advice is needed, have product container or label at hand
Keep out of reach of children
Read label before use
Ingredients:
Control Parameters: 8001-22-7, Vegetable Oil, This material has no known Exposure Limits.
Appropriate Engineering controls: Provide exhaust ventilation or other engineering controls to keep the
airborne concentrations of vapor and mists below the applicable
workplace exposure limits (Occupational Exposure Limits-OELs) indicated
above.
Respiratory protection: Not required under normal conditions of use. Where risk assessment
shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a
backup to engineering controls.When necessary use NIOSH approved
breathing equipment.
Protection of skin: Select glove material impermeable and resistant to the substance.Select
glove material based on rates of diffusion and degradation. Dispose of
contaminated gloves after use in accordance with applicable laws and
good laboratory practices.Use proper glove removal technique without
touching outer surface. Avoid skin contact with used gloves.Wear
protective clothing.
Eye protection: Wear equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN
166(EU).Safety glasses or goggles are appropriate eye protection.
General hygienic measures: Perform routine housekeeping. Wash hands before breaks and at the end
of work. Avoid contact with skin, eyes, and clothing.Before wearing wash
contaminated clothing.
Decomposition
Evaporation rate: Not Determined Not Determined
temperature:
Carcinogenicity: Vegetable Oil 8001-22-7: Not listed as a carcinogen (ACGIH, IARC, NTP)
UN-Number
Not Regulated
UN proper shipping name
Not Regulated
Transport hazard class(es)
Packing group:Not Regulated
Environmental hazard:
Transport in bulk:
Special precautions for user:
Proposition 65 (California):
Canada
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the
SDS contains all the information required by the Controlled Products Regulations.Note:. The responsibility to
provide a safe workplace remains with the user.The user should consider the health hazards and safety information
contained herein as a guide and should take those precautions required in an individual operation to instruct
employees and develop work practice procedures for a safe work environment.The information contained herein is,
to the best of our knowledge and belief, accurate.However, since the conditions of handling and use are beyond
our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this
material.It is the responsibility of the user to comply with all applicable laws and regulations applicable to this
material.
GHS Full Text Phrases: