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Material Safety Data Sheet


Water MSDS

Section 1: Chemical Product and Company Identification

Product Name: Water Contact Information:


Catalog Codes: SLW1063 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 7732-18-5 Houston, Texas 77396
RTECS: ZC0110000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Water
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Dihydrogen oxide 1-800-424-9300
Chemical Name: Water International CHEMTREC, call: 1-703-527-3887
Chemical Formula: H2O For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Water 7732-18-5 100

Toxicological Data on Ingredients: Not applicable.

Section 3: Hazards Identification

Potential Acute Health Effects:


Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritating to the eyes. Non-
hazardous in case of ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs. Non-
corrosive to the eyes. Non-corrosive for lungs.
Potential Chronic Health Effects:
Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritating to the eyes.
Non-hazardous in case of ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs.
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.

Section 4: First Aid Measures

Eye Contact: Not applicable.

p. 1
Skin Contact: Not applicable.
Serious Skin Contact: Not available.
Inhalation: Not applicable.
Serious Inhalation: Not available.
Ingestion: Not Applicable
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances: Not Applicable
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill: Mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.

Section 7: Handling and Storage

Precautions: No specific safety phrase has been found applicable for this product.
Storage: Not applicable.

Section 8: Exposure Controls/Personal Protection

Engineering Controls: Not Applicable


Personal Protection: Safety glasses. Lab coat.
Personal Protection in Case of a Large Spill: Not Applicable
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

p. 2
Odor: Odorless.
Taste: Not available.
Molecular Weight: 18.02 g/mole
Color: Colorless.
pH (1% soln/water): 7 [Neutral.]
Boiling Point: 100°C (212°F)
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: 1 (Water = 1)
Vapor Pressure: 2.3 kPa (@ 20°C)
Vapor Density: 0.62 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not applicable
Solubility: Not Applicable

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Not available.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact.


Toxicity to Animals:
LD50: [Rat] - Route: oral; Dose: > 90 ml/kg LC50: Not available.
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans:
Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-hazardous in case of
ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs. Non-corrosive to the eyes. Non-
corrosive for lungs.
Special Remarks on Toxicity to Animals: Not available.

p. 3
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Water


Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
This product is not classified according to the EU regulations. Not applicable.
HMIS (U.S.A.):
Health Hazard: 0
Fire Hazard: 0
Reactivity: 0
Personal Protection: a
National Fire Protection Association (U.S.A.):
Health: 0
Flammability: 0
Reactivity: 0
Specific hazard:

p. 4
Protective Equipment:
Not applicable. Lab coat. Not applicable. Safety glasses.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/10/2005 08:33 PM
Last Updated: 11/01/2010 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Dextrose monohydrate MSDS

Section 1: Chemical Product and Company Identification

Product Name: Dextrose monohydrate Contact Information:


Catalog Codes: SLD2356, SLD3718, SLD1594 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 5996-10-1 Houston, Texas 77396
RTECS: LZ6600000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Dextrose monohydrate
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: D-Glucose 1-800-424-9300
Chemical Name: Not available. International CHEMTREC, call: 1-703-527-3887
Chemical Formula: C6H12O6.H20 For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Dextrose monohydrate 5996-10-1 100

Toxicological Data on Ingredients: Not applicable.

Section 3: Hazards Identification

Potential Acute Health Effects: Slightly hazardous in case of eye contact (irritant), of ingestion, of inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.

Section 4: First Aid Measures

Eye Contact: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be
used.
Skin Contact: No known effect on skin contact, rinse with water for a few minutes.
Serious Skin Contact: Not available.

p. 1
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation: Not available.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.


Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances: Not available.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:
Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a
fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. If ingested, seek medical advice
immediately and show the container or the label.
Storage:
Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in a
cool, well-ventilated place. Combustible materials should be stored away from extreme heat and away from strong oxidizing
agents.

Section 8: Exposure Controls/Personal Protection

p. 2
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid.


Odor: Not available.
Taste: Not available.
Molecular Weight: 198.17 g/mole
Color: Not available.
pH (1% soln/water): Not available.
Boiling Point: Decomposes.
Melting Point: 86°C (186.8°F)
Critical Temperature: Not available.
Specific Gravity: 1.54 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility: Easily soluble in cold water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.

p. 3
Polymerization: No.

Section 11: Toxicological Information

Routes of Entry: Not available.


Toxicity to Animals: Acute oral toxicity (LD50): 25800 mg/kg [Rat].
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans: Slightly hazardous in case of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Passes through the placental barrier in human.
Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Dextrose monohydrate


Other Regulations: Not available..
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
This product is not classified according to the EU regulations.
HMIS (U.S.A.):
Health Hazard: 1

p. 4
Fire Hazard: 1
Reactivity: 0
Personal Protection: a
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Not applicable. Lab coat. Not applicable. Safety glasses.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/10/2005 08:17 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Sodium chloride (Rock Salt) MSDS

Section 1: Chemical Product and Company Identification

Product Name: Sodium chloride (Rock Salt) Contact Information:


Catalog Codes: SLS2299 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 7647-14-5 Houston, Texas 77396
RTECS: VZ4725000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Sodium chloride
Order Online: ScienceLab.com
CI#: Not applicable.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Salt; Sea Salt 1-800-424-9300
Chemical Name: Sodium chloride International CHEMTREC, call: 1-703-527-3887
Chemical Formula: NaCl For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Sodium chloride 7647-14-5 100

Toxicological Data on Ingredients: Sodium chloride: ORAL (LD50): Acute: 3000 mg/kg [Rat.]. 4000 mg/kg [Mouse].
DERMAL (LD50): Acute: &gt;10000 mg/kg [Rabbit]. DUST (LC50): Acute: &gt;42000 mg/m 1 hours [Rat].

Section 3: Hazards Identification

Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for
bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or
prolonged exposure is not known to aggravate medical condition.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.

p. 1
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention if symptoms appear.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: When heated to decomposition it emits toxic fumes.
Special Remarks on Explosion Hazards:
Electrolysis of sodium chloride in presence of nitrogenous compounds to produce chlorine may lead to formation of explosive
nitrogen trichloride. Potentially explosive reaction with dichloromaleic anhydride + urea.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:
Keep locked up.. Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. If ingested,
seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing
agents, acids.

p. 2
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Solid crystalline powder.)


Odor: Slight.
Taste: Saline.
Molecular Weight: 58.44 g/mole
Color: White.
pH (1% soln/water): 7 [Neutral.]
Boiling Point: 1413°C (2575.4°F)
Melting Point: 801°C (1473.8°F)
Critical Temperature: Not available.
Specific Gravity: 2.165 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility:
Easily soluble in cold water, hot water. Soluble in glycerol, and ammonia. Very slightly soluble in alcohol. Insoluble in
Hydrochloric Acid.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

p. 3
Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, high temperatures.
Incompatibility with various substances: Reactive with oxidizing agents, metals, acids.
Corrosivity: Not considered to be corrosive for metals and glass.
Special Remarks on Reactivity:
Hygroscopic. Reacts with most nonnoble metals such as iron or steel, building materials (such as cement) Sodium chloride is
rapidly attacked by bromine trifluoride. Violent reaction with lithium.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals:
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral
toxicity (LD50): 3000 mg/kg [Rat.]. Acute dermal toxicity (LD50): >10000 mg/kg [Rabbit]. Acute toxicity of the dust (LC50):
>42000 mg/m3 1 hours [Rat].
Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/
or yeast.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Lowest Published Lethal Dose (LDL) [Man] - Route: Oral; Dose: 1000 mg/kg
Special Remarks on Chronic Effects on Humans:
Causes adverse reproductive effects in humans (fetotoxicity, abortion, ) by intraplacental route. High intake of sodium chloride,
whether from occupational exposure or in the diet, may increase risk of TOXEMIA OF PREGNANCY in susceptible women
(Bishop, 1978). Hypertonic sodium chloride solutions have been used to induce abortion in late pregnancy by direct infusion
into the uterus (Brown et al, 1972), but this route of administration is not relevant to occupational exposures. May cause
adverse reproductive effects and birth defects in animals, particularly rats and mice (fetotoxicity, abortion, musculoskeletal
abnormalities, and maternal effects (effects on ovaries, fallopian tubes) by oral, intraperitoneal, intraplacental, intrauterine,
parenteral, and subcutaneous routes. While sodium chloride has been used as a negative control n some reproductive
studies, it has also been used as an example that almost any chemical can cause birth defects in experimental animals
if studied under the right conditions (Nishimura & Miyamoto, 1969). In experimental animals, sodium chloride has caused
delayed effects on newborns, has been fetotoxic, and has caused birth defects and abortions in rats and mice (RTECS, 1997).
May affect genetic material (mutagenic)
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: Causes eye irritation. Ingestion: Ingestion of large
quantities can irritate the stomach (as in overuse of salt tablets) with nausea and vomiting. May affect behavior (muscle
spasicity/contraction, somnolence), sense organs, metabolism, and cardiovascular system. Continued exposure may
produce dehydration, internal organ congestion, and coma. Inhalation: Material is irritating to mucous membranes and upper
respiratory tract.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.

p. 4
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Sodium chloride (Rock Salt)
Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
R40- Possible risks of irreversible effects. S24/25- Avoid contact with skin and eyes.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.

Section 16: Other Information

References:
-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.
Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of
Chemical Safety Data, Edition II.
Other Special Considerations: Not available.
Created: 10/09/2005 06:30 PM

p. 5
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Potassium chloride MSDS

Section 1: Chemical Product and Company Identification

Product Name: Potassium chloride Contact Information:


Catalog Codes: SLP3334, SLP5143, SLP2317, SLP4126 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 7447-40-7 Houston, Texas 77396
RTECS: TS8050000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Potassium chloride
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: 1-800-424-9300
Chemical Name: Potassium Chloride International CHEMTREC, call: 1-703-527-3887
Chemical Formula: KCl For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Potassium chloride 7447-40-7 100

Toxicological Data on Ingredients: Potassium chloride: ORAL (LD50): Acute: 2500 mg/kg [Guinea pig]. 2600 mg/kg [Rat].
1500 mg/kg [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for
bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance
may be toxic to blood, cardiovascular system. Repeated or prolonged exposure to the substance can produce target organs
damage.

Section 4: First Aid Measures

Eye Contact:

p. 1
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available. Slightly explosive in presence of oxidizing materials.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: May result in explosion with potassium permanganate and sulfuric acid.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:
Do not ingest. Do not breathe dust. If ingested, seek medical advice immediately and show the container or the label. Keep
away from incompatibles such as oxidizing agents, acids, moisture.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic

p. 2
Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid.


Odor: Odorless.
Taste: Saline. (Strong.)
Molecular Weight: 74.55 g/mole
Color: White.
pH (1% soln/water): Not available.
Boiling Point: 1420°C (2588°F)
Melting Point: 770°C (1418°F)
Critical Temperature: Not available.
Specific Gravity: 1.987 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility:
Soluble in cold water, hot water. Very slightly soluble in methanol, n-octanol.

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents, acids.

p. 3
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Hygroscopic. Incompatible with KMnO4, H2SO4, BrF3, and BrCl3. May react violently with BrF3.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals: Acute oral toxicity (LD50): 1500 mg/kg [Mouse].
Chronic Effects on Humans: May cause damage to the following organs: blood, cardiovascular system.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
May affect genetic material. Passes through the placental barrier in animal.
Special Remarks on other Toxic Effects on Humans:
Actute Potential Health Effects: Skin: May cause skin irritation Eye: Dust may cause eye irritation. Inhalation: Dust may cause
respiratory tract irritation. Low hazard for usual industrial handling Ingestion: May affect behavior (coma, change in motor
activity, listlessness, vertigo, mental confusion, paresthesias, general weakness, flaccid paralysis), metabolism, blood (change
in clotting factor, electrolytic imbalance), cardiovascular (hypotension, circulatory disturbances, cardiac arrhythmias, heart
block), and respiratory, gastrointestinal (irritation of GI tract, nausea, vomiting, diarrhea, abdominal discomfort, purging), and
urinary(impairment of renal function) systems. Acute potassium intoxication by mouth is rare because large single doses
usually induce vomiting, and because in the absence of pre-existing kidney damage potassium is rapidly excreted. Maximal
nontoxic oral dose of KCl in man varies from 0.2g to 1 g of potassium/kg/day depending upon efficiency of individual excretory
mechanism; lower doses sometimes cause impairment of renal function as shown by reduced inulin, and urea clearance.
Chronic Potential Health Effects: May affect blood and cardiovascular system.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.

p. 4
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Potassium chloride


Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
R36- Irritating to eyes. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S39-
Wear eye/face protection.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/10/2005 08:49 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Potassium bromide MSDS

Section 1: Chemical Product and Company Identification

Product Name: Potassium bromide Contact Information:


Catalog Codes: SLP1369, SLP4993 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 7758-02-3 Houston, Texas 77396
RTECS: TS7650000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Potassium bromide
Order Online: ScienceLab.com
CI#: Not applicable.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Bromide salt of Potassium; Tripotassium 1-800-424-9300
tribromide
International CHEMTREC, call: 1-703-527-3887
Chemical Name: Potasium Bromide
For non-emergency assistance, call: 1-281-441-4400
Chemical Formula: KBr

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Potassium bromide 7758-02-3 100

Toxicological Data on Ingredients: Potassium bromide: ORAL (LD50): Acute: 3070 mg/kg [Rat]. 3120 mg/kg [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to the nervous system. The substance may be toxic to
central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention if irritation occurs.

p. 1
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks,
of heat.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:
Do not ingest. Do not breathe dust. If ingested, seek medical advice immediately and show the container or the label. Keep
away from incompatibles such as oxidizing agents, acids.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

p. 2
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Crystalline solid. Crystals solid.)


Odor: Odorless.
Taste: Saline. Bitter. Pungent. (Strong.)
Molecular Weight: 119 g/mole
Color: White.
pH (1% soln/water): 7 [Neutral.]
Boiling Point: 1435°C (2615°F)
Melting Point: 730°C (1346°F)
Critical Temperature: Not available.
Specific Gravity: 2.75 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility:
Easily soluble in cold water, hot water. Slightly soluble in diethyl ether. Insoluble in acetate. Solubility in water: 1 g/1.5 ml
Solubiltiy in boiling water: 1 g/1 ml Solubility in alcohol: 1 g/250 ml Solubility in boiling alcohol: 1g 21 ml

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, moisture
Incompatibility with various substances: Reactive with oxidizing agents, acids.

p. 3
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Hygroscopic; keep container tightly closed. Incompatible with heavy metal salts. Reacts violently with bromine trifluoride
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals: Acute oral toxicity (LD50): 3070 mg/kg [Rat].
Chronic Effects on Humans:
Causes damage to the following organs: the nervous system. May cause damage to the following organs: central nervous
system (CNS).
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: May affect genetic material (mutagenic)
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: May cause eye irritation. Inhalation: May cause
respiratory tract irritation. Ingestion: Causes gastrointestinal tract irritation (gastritis) with vomiting, diarrhea. It may also
affect the urinary system/kidneys (anuria, acute nephroisis, uremia, kidney hemolysis, fatty degeneratioin of the kidney,
kidney damage), liver (fatty liver degeneration. It may affect the brain/central nervous system (central nervous depression,
halllucinations, psychosis, drowsiness, irritability, confusion, mania, ataxia, vertigo, mental deterioration, somnolence), eyes
(enlarge pupils with subnormal reaction to light, miosis, diplopia).

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

p. 4
Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Potassium bromide


Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
DSCL (EEC):
This product is not classified according to the EU regulations. S24/25- Avoid contact with skin and eyes. S26- In case
of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28- After contact with skin, wash
immediately with plenty of water.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Safety glasses.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/10/2005 08:48 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Potassium Iodide MSDS

Section 1: Chemical Product and Company Identification

Product Name: Potassium Iodide Contact Information:


Catalog Codes: SLP2050, SLP1042, SLP2854 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 7681-11-0 Houston, Texas 77396
RTECS: TT2975000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Potassium Iodide
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: 1-800-424-9300
Chemical Name: Potassium Iodide International CHEMTREC, call: 1-703-527-3887
Chemical Formula: KI For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Potassium Iodide 7681-11-0 100

Toxicological Data on Ingredients: Potassium Iodide LD50: Not available. LC50: Not available. Lowest Published Lethal
Dose: LDL [Mouse] - Route: Oral; Dose: 1862 mg/kg LDL [Rabbit] - Route: Oral; Dose: 916 mg/kg

Section 3: Hazards Identification

Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.
TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female,
Development toxin [POSSIBLE]. The substance may be toxic to thyroid. Repeated or prolonged exposure to the substance
can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:

p. 1
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention if irritation occurs.
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Some hazardous decomposition products are: Hydrogen Iodide, Oxides of potassium , iodine
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Potassium iodide + Fluorine Perchlorate will explode on contact.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:
Do not breathe dust. Wear suitable protective clothing. If you feel unwell, seek medical attention and show the label when
possible. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, moisture.

p. 2
Storage:
Moisture Sensitive. Light Sensitive. Air SensitiveKeep container tightly closed in light-resistant containers. Keep container in a
cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Deliquescent crystals solid.)


Odor: Odorless.
Taste: Bitter. Saline. (Strong.)
Molecular Weight: 166 g/mole
Color: White.
pH (1% soln/water): Not available.
Boiling Point: 1330°C (2426°F)
Melting Point: 681°C (1257.8°F)
Critical Temperature: Not available.
Specific Gravity: 3.1 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, methanol, acetone.
Solubility:
Easily soluble in cold water, hot water. Soluble in methanol. Partially soluble in acetone.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

p. 3
Instability Temperature: Not available.
Conditions of Instability:
Light, moisture, incompatible materials. It is stable under ordinary conditions of use and storage. On long exposure to air, it
becomes yellow due to release of iodine.
Incompatibility with various substances: Reactive with oxidizing agents, reducing agents, organic materials, metals, acids.
Corrosivity:
Corrosive in presence of steel, of aluminum, of zinc. Non-corrosive in presence of glass, of copper, of stainless steel(304), of
stainless steel(316).
Special Remarks on Reactivity:
Moisture Sensitive. Light Sensitive. Air Sensitive. Air causes decomposition to iodine. Reacts violently with strong oxidizers,
bromotrifluorides, chlorotrifluorides, fluorine perchlorate, metallic salts. Attacks metals in moist environments. Also
incompatible with salts of alkaloids, chloral hydrate, calomel (mercurous chloride), potassium chlorate, tartaric and other
acids, oxidants, diazonium salts, charcoal, ozone, strong reducers, alkali metals, metals (brass, aluminum magnesium, zinc,
cadmium, copper, tin, nickel, steel), metallic salts, organic materials, light.
Special Remarks on Corrosivity:
Incompatible with water, producing a corrosive. Corrosive in all concentrations to most metals, except stainless steel, titanium,
and tantalum.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans:
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. DEVELOPMENTAL TOXICITY: Classified Reproductive
system/toxin/female, Development toxin [POSSIBLE]. May cause damage to the following organs: thyroid.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals:
Lowest Published Lethal Dose: LDL [Mouse] - Route: Oral; Dose: 1862 mg/kg LDL[Rabbit] - Route: Oral; Dose: 916 mg/kg
Special Remarks on Chronic Effects on Humans:
Can cause adverse reproductive efects and birth defects based on animal data. May affect genetic material based on animal
data
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: May cause eye irritation. Inhalation: May cause
respiratory tract and mucous membrane irritation and a productive cough. May cause pulmonary edema and inflammation
of the tonsils. Ingestion: Causes gastrointestinal tract irritation with nausea, vomiting and diarrhea. May affect behavior
(somnolence, muscle weakness), respiration (dyspnea). Serum-sickness type of hypersensitivity such as fever, arthralgia,
lymph node enlargement , and eosinophilia may appear. Thrombotic thrombocytopenic purpura, and fatal periarteritis nodosa
attributed to hypersensitivity to iodide has been described. Chronic Potential Health Effects: Can lead to iodism characterized
by salivation, nasal discharge, sneezing, conjunctivitis, fever, headache, laryngitis, bronchitis, stomatits, parotitis, anemia, and
skin rashes. Chronic ingestion may also affect metabolism (anorexia), and thyroid gland (hypothyroidism, goiter). Furthermore,
chronic ingestion of iodides (in animals) during pregnancy has resulted in fetal deaths, severe goiter and cretinoid appearance
of the newborn.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.

p. 4
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Potassium Iodide


Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
DSCL (EEC):
Not available Not applicable.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Safety glasses.

Section 16: Other Information

References: Not available.

p. 5
Other Special Considerations: Not available.
Created: 10/11/2005 12:21 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Potassium sulfate MSDS

Section 1: Chemical Product and Company Identification

Product Name: Potassium sulfate Contact Information:


Catalog Codes: SLP5365, SLP1528 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 7778-80-5 Houston, Texas 77396
RTECS: TT5900000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Potassium sulfate
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: 1-800-424-9300
Chemical Name: Not available. International CHEMTREC, call: 1-703-527-3887
Chemical Formula: K2SO4 For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Potassium sulfate 7778-80-5 100

Toxicological Data on Ingredients: Potassium sulfate: ORAL (LD50): Acute: 6600 mg/kg [Rat].

Section 3: Hazards Identification

Potential Acute Health Effects:


Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of
skin contact (permeator).
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, mucous membranes. Repeated or prolonged
exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids
open. Cold water may be used. Do not use an eye ointment. Seek medical attention.

p. 1
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running
water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.
Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation: Not available.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:
Do not ingest. Do not breathe dust. Wear suitable protective clothing In case of insufficient ventilation, wear suitable
respiratory equipment If ingested, seek medical advice immediately and show the container or the label. Avoid contact with
skin and eyes
Storage:
No specific storage is required. Use shelves or cabinets sturdy enough to bear the weight of the chemicals. Be sure that it is
not necessary to strain to reach materials, and that shelves are not overloaded.

p. 2
Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid.


Odor: Not available.
Taste: Not available.
Molecular Weight: 174.26 g/mole
Color: Not available.
pH (1% soln/water): Not available.
Boiling Point: 1689°C (3072.2°F)
Melting Point: 1067°C (1952.6°F)
Critical Temperature: Not available.
Specific Gravity: 2.66 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility: Partially soluble in cold water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Non-corrosive in presence of glass.

p. 3
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: No.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion.


Toxicity to Animals: Acute oral toxicity (LD50): 6600 mg/kg [Rat].
Chronic Effects on Humans: The substance is toxic to lungs, mucous membranes.
Other Toxic Effects on Humans:
Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Potassium sulfate


Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
DSCL (EEC): R36/38- Irritating to eyes and skin.

p. 4
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/10/2005 08:24 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Palm oil MSDS

Section 1: Chemical Product and Company Identification

Product Name: Palm oil Contact Information:


Catalog Codes: SLP4939 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 8002-75-3 Houston, Texas 77396
RTECS: RJ3696300 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Palm oil
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: 1-800-424-9300
Chemical Name: Not available. International CHEMTREC, call: 1-703-527-3887
Chemical Formula: Not available. For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Palm oil 8002-75-3 100

Toxicological Data on Ingredients: Not applicable.

Section 3: Hazards Identification

Potential Acute Health Effects: Hazardous in case of ingestion. Slightly hazardous in case of eye contact (irritant), of
inhalation.
Potential Chronic Health Effects:
Hazardous in case of ingestion. Slightly hazardous in case of inhalation. CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not
available.

Section 4: First Aid Measures

Eye Contact: No known effect on eye contact, rinse with water for a few minutes.
Skin Contact: No known effect on skin contact, rinse with water for a few minutes.
Serious Skin Contact: Not available.

p. 1
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation: Not available.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.


Auto-Ignition Temperature: 316°C (600.8°F)
Flash Points: CLOSED CUP: 162°C (323.6°F).
Flammable Limits: Not available.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not available.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
If the product is in its solid form: Use a shovel to put the material into a convenient waste disposal container. If the product is
in its liquid form: Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by
spreading water on the contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:
Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a
fume hood. Ground all equipment containing material. Do not breathe dust.
Storage:
Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in a
cool, well-ventilated place. Combustible materials should be stored away from extreme heat and away from strong oxidizing
agents.

Section 8: Exposure Controls/Personal Protection

p. 2
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid.


Odor: Not available.
Taste: Not available.
Molecular Weight: Not available.
Color: Not available.
pH (1% soln/water): Not applicable.
Boiling Point: Not available.
Melting Point: 35°C (95°F)
Critical Temperature: Not available.
Specific Gravity: 0.952 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not available.
Solubility: Insoluble in cold water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.

p. 3
Polymerization: No.

Section 11: Toxicological Information

Routes of Entry: Ingestion.


Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans:
Hazardous in case of ingestion. Slightly hazardous in case of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Palm oil


Other Regulations: Not available..
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
This product is not classified according to the EU regulations.

p. 4
HMIS (U.S.A.):
Health Hazard: 0
Fire Hazard: 1
Reactivity: 0
Personal Protection: a
National Fire Protection Association (U.S.A.):
Health: 0
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Not applicable. Lab coat. Not applicable. Safety glasses.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/10/2005 11:09 AM
Last Updated: 11/01/2010 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Hydrochloric acid, 37% MSDS

Section 1: Chemical Product and Company Identification

Product Name: Hydrochloric acid, 37% Contact Information:


Catalog Codes: SLH1360, SLH2206, SLH3052 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: Mixture. Houston, Texas 77396
RTECS: MW4025000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Hydrochloric acid
Order Online: ScienceLab.com
CI#: Not applicable.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Hydrochloric Acid; Muriatic Acid; Hydrochloric 1-800-424-9300
Acid 37% N.F, F.C.C., Electronic/Cleanroom grades
International CHEMTREC, call: 1-703-527-3887
Chemical Name: Not applicable.
For non-emergency assistance, call: 1-281-441-4400
Chemical Formula: Not applicable.

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Hydrogen chloride 7647-01-0 37
Water 7732-18-5 63

Toxicological Data on Ingredients: Hydrogen chloride: GAS (LC50): Acute: 4701 ppm 0.5 hours [Rat].

Section 3: Hazards Identification

Potential Acute Health Effects:


Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion, . Slightly
hazardous in case of inhalation (lung sensitizer). Non-corrosive for lungs. Liquid or spray mist may produce tissue damage
particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the
spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath.
Severe over-exposure can result in death. Inflammation of the eye is characterized by redness, watering, and itching. Skin
inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Potential Chronic Health Effects:
Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for
human.) by IARC [Hydrochloric acid]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, liver, mucous membranes, upper

p. 1
respiratory tract, skin, eyes, Circulatory System, teeth. Repeated or prolonged exposure to the substance can produce target
organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation.
Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial
infection. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one
or many human organs.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: of metals
Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards:
Non combustible. Calcium carbide reacts with hydrogen chloride gas with incandescence. Uranium phosphide reacts with
hydrochloric acid to release spontaneously flammable phosphine. Rubidium acetylene carbides burns with slightly warm
hydrochloric acid. Lithium silicide in contact with hydrogen chloride becomes incandescent. When dilute hydrochloric acid is
used, gas spontaneously flammable in air is evolved. Magnesium boride treated with concentrated hydrochloric acid produces
spontaneously flammble gas. Cesium acetylene carbide burns hydrogen chloride gas. Cesium carbide ignites in contact with
hydrochloric acid unless acid is dilute. Reacts with most metals to produce flammable Hydrodgen gas.

p. 2
Special Remarks on Explosion Hazards:
Hydrogen chloride in contact with the following can cause an explosion, ignition on contact, or other violent/vigorous reaction:
Acetic anhydride AgClO + CCl4 Alcohols + hydrogen cyanide, Aluminum Aluminum-titanium alloys (with HCl vapor), 2-Amino
ethanol, Ammonium hydroxide, Calcium carbide Ca3P2 Chlorine + dinitroanilines (evolves gas), Chlorosulfonic acid Cesium
carbide Cesium acetylene carbide, 1,1-Difluoroethylene Ethylene diamine Ethylene imine, Fluorine, HClO4 Hexalithium
disilicide H2SO4 Metal acetylides or carbides, Magnesium boride, Mercuric sulfate, Oleum, Potassium permanganate,
beta-Propiolactone Propylene oxide Rubidium carbide, Rubidium, acetylene carbide Sodium (with aqueous HCl), Sodium
hydroxide Sodium tetraselenium, Sulfonic acid, Tetraselenium tetranitride, U3P4 , Vinyl acetate. Silver perchlorate with carbon
tetrachloride in the presence of hydrochloric acid produces trichloromethyl perchlorate which detonates at 40 deg. C.

Section 6: Accidental Release Measures

Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If
necessary: Neutralize the residue with a dilute solution of sodium carbonate.
Large Spill:
Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.
Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray
to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.
Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentration
level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.
In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show
the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, organic
materials, metals, alkalis, moisture. May corrode metallic surfaces. Store in a metallic or coated fiberboard drum using a strong
polyethylene inner package.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
CEIL: 5 (ppm) from OSHA (PEL) [United States] CEIL: 7 (mg/m3) from OSHA (PEL) [United States] CEIL: 5 from NIOSH
CEIL: 7 (mg/m3) from NIOSH TWA: 1 STEL: 5 (ppm) [United Kingdom (UK)] TWA: 2 STEL: 8 (mg/m3) [United Kingdom
(UK)]Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

p. 3
Physical state and appearance: Liquid.
Odor: Pungent. Irritating (Strong.)
Taste: Not available.
Molecular Weight: Not applicable.
Color: Colorless to light yellow.
pH (1% soln/water): Acidic.
Boiling Point: 50.5°C (122.9°F)
Melting Point: -46.2°C (-51.2°F) to -25.4 C
Critical Temperature: Not available.
Specific Gravity: 1.19 (Water = 1)
Vapor Pressure: 16 kPa (@ 20°C) average
Vapor Density: 1.267 (Air = 1)
Volatility: Not available.
Odor Threshold: 0.25 to 10 ppm
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, diethyl ether.
Solubility: Soluble in cold water, hot water, diethyl ether.

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, water
Incompatibility with various substances:
Highly reactive with metals. Reactive with oxidizing agents, organic materials, alkalis, water.
Corrosivity:
Extremely corrosive in presence of aluminum, of copper, of stainless steel(304), of stainless steel(316). Non-corrosive in
presence of glass.
Special Remarks on Reactivity:
Reacts with water especially when water is added to the product. Absorption of gaseous hydrogen chloride on mercuric
sulfate becomes violent @ 125 deg. C. Sodium reacts very violently with gaseous hydrogen chloride. Calcium phosphide and
hydrochloric acid undergo very energetic reaction. It reacts with oxidizers releasing chlorine gas. Incompatible with, alkali
metals, carbides, borides, metal oxides, vinyl acetate, acetylides, sulphides, phosphides, cyanides, carbonates. Reacts with
most metals to produce flammable Hydrogen gas. Reacts violently (moderate reaction with heat of evolution) with water
especially when water is added to the product. Isolate hydrogen chloride from heat, direct, alkalies (reacts vigorously), organic
materials, and oxidizers (especially nitric acid and chlorates), amines, metals, copper and alloys (e.g. brass), hydroxides,
zinc (galvanized materials), lithium silicide (incandescence), sulfuric acid(increase in temperature and pressure) Hydrogen
chloride gas is emitted when this product is in contact with sulfuric acid. Adsorption of Hydrochloric Acid onto silicon dioxide
results in exothmeric reaction. Hydrogen chloride causes aldehydes and epoxides to violently polymerize. Hydrogen chloride
or Hydrochloric Acid in contact with the folloiwng can cause explosion or ignition on contact or other violent/vigorous reaction:
Acetic anhydride, Alcohols + hydrogen cyanide, Aluminum, Aluminum phosphide, Aluminum-titanium alloys (with HCl
vapor), 2-Amino ethanol, Ammonium, Ammonium hydroxide, 1,4-Benzoquinone diimine, Calcium acetylide (incandescence
upon warming), Calcium carbide, Calcium phosphide, Carbon tetrachloride + silver perchlorate (produce trichlormethyl

p. 4
perchlorate), Cesium acetylene carbide, Cesium carbide, Cesium telluroacylates, Chlorine + dinitroanilines (evolves
gas), Chloroacetaldehyde oxime, Chlorosulfonic acid, Cyanogen chloride (when catalyzed by HCl), 1,1-Difluoroethylene,
Dinitroanilines, Ethylene, Ethylene diamine, Ethyl 2-formylpropionate oxime (when generated by using HCl as a catalyst),
Special Remarks on Corrosivity:
Highly corrosive. Incompatible with copper and copper alloys. It attacks nearly all metals (mercury, gold, platinium, tantalum,
silver, and certain alloys are exceptions). It is one of the most corrosive of the nonoxidizing acids in contact with copper alloys.
No corrosivity data on zinc, steel. Severe Corrosive effect on brass and bronze
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation.
Toxicity to Animals:
Acute oral toxicity (LD50): 900 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 1108 ppm, 1 hours [Mouse]. Acute toxicity of
the vapor (LC50): 3124 ppm, 1 hours [Rat]. (Hydrochloric Acid)
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrochloric acid]. May cause damage to the
following organs: kidneys, liver, mucous membranes, upper respiratory tract, skin, eyes, Circulatory System, teeth.
Other Toxic Effects on Humans:
Very hazardous in case of skin contact (corrosive, irritant, permeator), of ingestion, . Hazardous in case of eye contact
(corrosive), of inhalation (lung corrosive).
Special Remarks on Toxicity to Animals:
Lowest Published Lethal Doses (LDL/LCL) LDL [Man] -Route: Oral; 2857 ug/kg LCL [Human] - Route: Inhalation; Dose: 1300
ppm/30M LCL [Rabbit] - Route: Inhalation; Dose: 4413 ppm/30M
Special Remarks on Chronic Effects on Humans:
May cause adverse reproductive effects (fetoxicity). May affect genetic material.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Corrosive. Causes severe skin irritation and burns. Eyes: Corrosive. Causes severe
eye irritation/conjuntivitis, burns, corneal necrosis. Inhalation: May be fatal if inhaled. Material is extremely destructive to
tissue of the mucous membranes and upper respiratory tract. Inhalation of hydrochloric acid fumes produces nose, throat,
and larryngeal burning, and irritation, pain and inflammation, coughing, sneezing, choking sensation, hoarseness, laryngeal
spasms, upper respiratory tract edema, chest pains, as well has headache, and palpitations. Inhalation of high concentrations
can result in corrosive burns, necrosis of bronchial epithelium, constriction of the larynx and bronchi, nasospetal perforation,
glottal closure, occur, particularly if exposure is prolonged. May affect the liver. Ingestion: May be fatal if swallowed. Causes
irritation and burning, ulceration, or perforation of the gastrointestinal tract and resultant peritonitis, gastric hemorrhage and
infection. Can also cause nausea, vomitting (with "coffee ground" emesis), diarrhea, thirst, difficulty swallowing, salivation,
chills, fever, uneasiness, shock, strictures and stenosis (esophogeal, gastric, pyloric). May affect behavior (excitement),
the cardiovascular system (weak rapid pulse, tachycardia), respiration (shallow respiration), and urinary system (kidneys-
renal failure, nephritis). Acute exposure via inhalation or ingestion can also cause erosion of tooth enamel. Chronic Potential
Health Effects: Prolonged or repeated inhalation and/or ingestion may affect liver, bleeding of nose and gums, nasal and oral
mucosal ulceration, conjunctivitis, respiratory tract (changes in pulmonary function, chronic bronchitis, overt respiratory tract
abnormalities), teeth (yellowing of teethand erosion of tooth enamel), kidneys, and behavior (muscle contraction or spasticity).
Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated eye contact with vapor/mist can cause
conjunctivitis dyspnea, bronchitis. Chemical pneumonitis and pulmonary edema can also

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:

p. 5
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material


Identification: : Hydrochloric acid, solution UNNA: 1789 PG: II
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:


Connecticut hazardous material survey.: Hydrochloric acid Illinois toxic substances disclosure to employee act: Hydrochloric
acid Illinois chemical safety act: Hydrochloric acid New York release reporting list: Hydrochloric acid Rhode Island RTK
hazardous substances: Hydrochloric acid Pennsylvania RTK: Hydrochloric acid Minnesota: Hydrochloric acid Massachusetts
RTK: Hydrochloric acid Massachusetts spill list: Hydrochloric acid New Jersey: Hydrochloric acid New Jersey spill list:
Hydrochloric acid Louisiana RTK reporting list: Hydrochloric acid Louisiana spill reporting: Hydrochloric acid California
Director's List of Hazardous Substances: Hydrochloric acid TSCA 8(b) inventory: Hydrochloric acid TSCA 4(a) proposed test
rules: Hydrochloric acid SARA 302/304/311/312 extremely hazardous substances: Hydrochloric acid SARA 313 toxic chemical
notification and release reporting: Hydrochloric acid CERCLA: Hazardous substances.: Hydrochloric acid: 5000 lbs. (2268 kg)
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada):
CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.
DSCL (EEC):
R25- Toxic if swallowed. R26- Very toxic by inhalation. R34- Causes burns. S1/2- Keep locked up and out of the reach of
children. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28- After contact
with skin, wash immediately with plenty of [***] S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 1
Personal Protection:
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 0

p. 6
Reactivity: 1
Specific hazard:
Protective Equipment:
Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Face shield.

Section 16: Other Information

References:
-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.
Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of
Chemical Safety Data, Edition II. -Guide de la loi et du règlement sur le transport des marchandises dangeureuses au canada.
Centre de conformité internatinal Ltée. 1986.
Other Special Considerations: Not available.
Created: 10/09/2005 05:45 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Sodium borate MSDS

Section 1: Chemical Product and Company Identification

Product Name: Sodium borate Contact Information:


Catalog Codes: SLS2566, SLS3988, SLS3193 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 1303-96-4 Houston, Texas 77396
RTECS: SC7310000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Sodium borate
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Sodium pyroborate 1-800-424-9300
Chemical Name: Sodium tetraborate decahydrate International CHEMTREC, call: 1-703-527-3887
Chemical Formula: Na2B4O7.10(H2O) For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Sodium borate 1303-96-4 100

Toxicological Data on Ingredients: Sodium borate: ORAL (LD50): Acute: 2660 mg/kg [Rat.].

Section 3: Hazards Identification

Potential Acute Health Effects:


Hazardous in case of skin contact (irritant), of eye contact (irritant). Slightly hazardous in case of skin contact (permeator), of
ingestion, of inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids
open. Cold water may be used. Do not use an eye ointment. Seek medical attention.

p. 1
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running
water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.
Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation: Not available.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Non combustible.
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with
a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and dispose of according to
local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Neutralize the residue with a dilute solution
of acetic acid. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary
system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local
authorities.

Section 7: Handling and Storage

Precautions:
Do not ingest. Do not breathe dust. Wear suitable protective clothing If ingested, seek medical advice immediately and show
the container or the label. Avoid contact with skin and eyes Keep away from incompatibles such as oxidizing agents.

p. 2
Storage:
No specific storage is required. Use shelves or cabinets sturdy enough to bear the weight of the chemicals. Be sure that it is
not necessary to strain to reach materials, and that shelves are not overloaded.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 0.31 (ppm) TWA: 5 (mg/m3) from ACGIH [1995] Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Solid crystalline powder.)


Odor: Odorless.
Taste: Not available.
Molecular Weight: 381.37 g/mole
Color: White.
pH (1% soln/water): 10 [Basic.]
Boiling Point: Decomposes.
Melting Point: 75°C (167°F)
Critical Temperature: Not available.
Specific Gravity: 1.73 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility:
Soluble in cold water, hot water. Insoluble in methanol.

Section 10: Stability and Reactivity Data

p. 3
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Reactive with oxidizing agents.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: Not available.

Section 11: Toxicological Information

Routes of Entry: Eye contact.


Toxicity to Animals: Acute oral toxicity (LD50): 2660 mg/kg [Rat.].
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans:
Hazardous in case of skin contact (irritant). Slightly hazardous in case of skin contact (permeator), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Ingestion of 5-10 grams has produced severe vomiting, diarrhea,
shock and death.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

p. 4
Federal and State Regulations:
Pennsylvania RTK: Sodium borate Massachusetts RTK: Sodium borate TSCA 8(b) inventory: Sodium borate
Other Regulations: Not available..
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC): R36/38- Irritating to eyes and skin.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.

Section 16: Other Information

References:
-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.
Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of
Chemical Safety Data, Edition II.
Other Special Considerations: Not available.
Created: 10/09/2005 06:29 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Sodium hydroxide MSDS
Section 1: Chemical Product and Company Identification

Product Name: Sodium hydroxide Contact Information:


Catalog Codes: SLS3298, SLS1081, SLS2503, SLS3925, Sciencelab.com, Inc.
SLS1705 14025 Smith Rd.
Houston, Texas 77396
CAS#: 1310-73-2
US Sales: 1-800-901-7247
RTECS: WB4900000 International Sales: 1-281-441-4400

TSCA: TSCA 8(b) inventory: Sodium hydroxide Order Online: ScienceLab.com

CI#: Not available. CHEMTREC (24HR Emergency Telephone), call:


1-800-424-9300
Synonym: Caustic Soda
International CHEMTREC, call: 1-703-527-3887
Chemical Name: Sodium Hydroxide
For non-emergency assistance, call: 1-281-441-4400
Chemical Formula: NaOH

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Sodium hydroxide 1310-73-2 100

Toxicological Data on Ingredients: Sodium hydroxide LD50: Not available. LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects:


Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion,
of inhalation. The amount of tissue damage depends on length of contact. Eye contact can result in corneal damage or
blindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal or
respiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking,
unconsciousness or death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.
TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to
mucous membranes, upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce target
organs damage. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can
produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or
lung damage.

p. 1
Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: metals
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available. Slightly explosive in presence of heat.
Fire Fighting Media and Instructions: Not available
Special Remarks on Fire Hazards:
sodium hydroxide + zinc metal dust causes ignition of the latter. Under proper conditions of temperature, pressure and state
of division, it can ignite or react violently with acetaldehyde, ally alcohol, allyl chloride, benzene-1,4-diol, chlorine trifluoride,
1,2 dichlorethylene, nitroethane, nitromethane, nitroparaffins, nitropropane, cinnamaldehyde, 2,2-dichloro-3,3-dimethylbutane.
Sodium hydroxide in contact with water may generate enough heat to ignite adjacent combustible materials. Phosphorous
boiled with NaOH yields mixed phosphines which may ignite spontanously in air. sodium hydroxide and cinnamaldehyde +
heat may cause ignition. Reaction with certain metals releases flammable and explosive hydrogen gas.
Special Remarks on Explosion Hazards:
Sodium hydroxide reacts to form explosive products with ammonia + silver nitrate. Benzene extract of allyl benzenesulfonate
prepared from allyl alcohol, and benzene sulfonyl chloride in presence of aquesous sodium hydroxide, under vacuum
distillation, residue darkened and exploded. Sodium Hydroxde + impure tetrahydrofuran, which can contain peroxides, can

p. 2
cause serious explosions. Dry mixtures of sodium hydroxide and sodium tetrahydroborate liberate hydrogen explosively at
230-270 deg. C. Sodium Hydroxide reacts with sodium salt of trichlorophenol + methyl alcohol + trichlorobenzene + heat to
cause an explosion.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with
a dilute solution of acetic acid.
Large Spill:
Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray
to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.
Neutralize the residue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration level
above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep container dry. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitable
respiratory equipment. If you feel unwell, seek medical attention and show the label when possible. Avoid contact with skin
and eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis, moisture.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic. Deliquescent.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Exposure Limits:
STEL: 2 (mg/m3) from ACGIH (TLV) [United States] TWA: 2 CEIL: 2 (mg/m3) from OSHA (PEL) [United States] CEIL: 2 (mg/
m3) from NIOSHConsult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Deliquescent solid.)


Odor: Odorless.
Taste: Not available.
Molecular Weight: 40 g/mole
Color: White.

p. 3
pH (1% soln/water): 13.5 [Basic.]
Boiling Point: 1388°C (2530.4°F)
Melting Point: 323°C (613.4°F)
Critical Temperature: Not available.
Specific Gravity: 2.13 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility: Easily soluble in cold water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, moisture, moist air
Incompatibility with various substances:
Highly reactive with metals. Reactive with oxidizing agents, reducing agents, acids, alkalis, moisture.
Corrosivity: Not available.
Special Remarks on Reactivity:
Hygroscopic. Much heat is evolved when solid material is dissolved in water. Therefore cold water and caution must be used
for this process. Sodium hydroxide solution and octanol + diborane during a work-up of a reaction mixture of oxime and
diborane in tetrahyrofuran is very exothermic, a mild explosion being noted on one occassion. Reactive with water, acids
(mineral, non-oxidizing, e.g. hydrochloric, hydrofluoric acid, muriatic acid, phosphoric), acids (mineral, oxidizing e.g. chromic
acid, hypochlorous acid, nitric acid, sulfuric acid), acids (organic e.g. acetic acid, benzoic acid, formic acid, methanoic acid,
oxalic acid), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, foraldehyde), carbamates (e.g. carbanolate, carbofuran),
esters (e.g. butyl acetate, ethyl acetate, propyl formate), halogenated organics (dibromoethane, hexachlorobenzene, methyl
chloride, trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones (acetone, acetophenone, MEK, MIBK), acid
chlorides, strong bases, strong oxidizing agents, strong reducing agents, flammable liquids, powdered metals and metals (i.e
aluminum, tin, zinc, hafnium, raney nickel), metals (alkali and alkaline e.g. cesium, potassium, sodium), metal compounds
(toxic e.g. berylium, lead acetate, nickel carbonyl, tetraethyl lead), mitrides (e.g. potassium nitride, sodium nitride), nitriles
(e.g. acetonitrile, methyl cyanide), nitro compounds (organic e.g. nitrobenzene, nitromethane), acetic anhydride, chlorohydrin,
chlorosulfonic acid, ethylene cyanohydrin, glyoxal, hydrosulfuric acid, oleum, propiolactone, acylonitrile, phorosous pentoxide,
chloroethanol, chloroform-methanol, tetrahydroborate, cyanogen azide, 1,2,4,5 tetrachlorobenzene, cinnamaldehyde. Reacts
with formaldehyde hydroxide to yield formic acid, and hydrogen.
Special Remarks on Corrosivity: Very caustic to aluminum and other metals in presence of moisture.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

p. 4
Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans:
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. May cause damage to the following organs: mucous
membranes, upper respiratory tract, skin, eyes.
Other Toxic Effects on Humans:
Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (corrosive, irritant,
permeator), of eye contact (corrosive), of ingestion, .
Special Remarks on Toxicity to Animals:
Lowest Published Lethal Dose: LDL [Rabbit] - Route: Oral; Dose: 500 mg/kg
Special Remarks on Chronic Effects on Humans: May affect genetic material. Investigation as a mutagen (cytogenetic
analysis)
Special Remarks on other Toxic Effects on Humans:

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material


Identification: : Sodium hydroxide, solid UNNA: 1823 PG: II
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:


Illinois toxic substances disclosure to employee act: Sodium hydroxide Illinois chemical safety act: Sodium hydroxide New
York release reporting list: Sodium hydroxide Rhode Island RTK hazardous substances: Sodium hydroxide Pennsylvania
RTK: Sodium hydroxide Minnesota: Sodium hydroxide Massachusetts RTK: Sodium hydroxide New Jersey: Sodium hydroxide
Louisiana spill reporting: Sodium hydroxide California Director's List of Hazardous Substances: Sodium hydroxide TSCA 8(b)
inventory: Sodium hydroxide CERCLA: Hazardous substances.: Sodium hydroxide: 1000 lbs. (453.6 kg)
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.

p. 5
Other Classifications:
WHMIS (Canada): CLASS E: Corrosive solid.
DSCL (EEC):
R35- Causes severe burns. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39- Wear suitable gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 2
Personal Protection: j
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 0
Reactivity: 1
Specific hazard:
Protective Equipment:
Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/09/2005 06:32 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Sodium thiosulfate pentahydrate MSDS

Section 1: Chemical Product and Company Identification

Product Name: Sodium thiosulfate pentahydrate Contact Information:


Catalog Codes: SLS2341, SLS2962 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 10102-17-7 Houston, Texas 77396
RTECS: WE6660000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: No products were found.
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Ametox, Antichlor; Sodium Hyposulfite, 1-800-424-9300
pentahydrate
International CHEMTREC, call: 1-703-527-3887
Chemical Name: Thiosulfuric Acid, disodium salt,
pentahydrate For non-emergency assistance, call: 1-281-441-4400

Chemical Formula: Na2S2O3.5H20

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Sodium thiosulfate pentahydrate 10102-17-7 100

Toxicological Data on Ingredients: Sodium thiosulfate pentahydrate LD50: Not available. LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects:


Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant).
Potential Chronic Health Effects:
Slightly hazardous in case of skin contact (irritant, sensitizer). CARCINOGENIC EFFECTS: Not available. MUTAGENIC
EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention if irritation occurs.

p. 1
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: When heated to decomposition it emits toxic fumes of sulfur oxides, hydrogen sulfide,
and sodium oxide
Special Remarks on Explosion Hazards: An explosion may occur if triturated with nitrates, chlorates, or permanganates.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:
Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
If you feel unwell, seek medical attention and show the label when possible. Keep away from incompatibles such as oxidizing
agents, acids, alkalis.

p. 2
Storage: Hygroscopic. Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid.


Odor: Odorless.
Taste: Saline.
Molecular Weight: 248.19 g/mole
Color: Colorless. White.
pH (1% soln/water): pH of a 5% solution: 6.0-8.4
Boiling Point: >100°C (212°F)
Melting Point: 48°C (118.4°F)
Critical Temperature: Not available.
Specific Gravity: 1.7 - 1.75(Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility:
Soluble in cold water, hot water. Solubility in water: 79 g/100 ml @ 4 deg. C (39 deg. F) 680 g/liter @ 20 deg. C

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.

p. 3
Conditions of Instability: Incompatible materials, moisture
Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
It is a strong reducing and can react with oxidizers. Reacts with acids to release sulfur dioxide. Sodium Thiosulfate
pentahydrate dissolves in its own water of hydation; it effloresces in warm dry air. Sodium Thiosulfate pentahydrate loses
water at 100 deg. C. It is incompatible with iodine, acids, lead, mercury, and silver salts (e.g. silver nitrate), halogens.
Hygroscopic; keep container tightly closed. Protect from moisture
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans:
Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans:
Acute Potenial Health Effects: Skin: It may cause mild skin irritation. Eyes: Can cause mechanical eye irritation. Inhalation:
May cause upper respiratory tract and mucous membrane irritation. Ingestion: Sodium Thiosulfate is an agent with a low
order of toxicity. Ingestion of large doses may cause gastrointestinal irritation disturbances with nausea, vomiting, addominal
cramping, diarrhea, metabolic acidosis, and hypernatremia. May also affect respiration (cyanosis, respiratory stimulation),
cardiovascular(hypotension), behavior (ataxia, convulsions) Chronic Potential Health Effects: Skin: Prolonged or repeated skin
contact may allergic dermatitis, and irritation. The toxicological preperties of this substance have not been fully investigated.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

p. 4
DOT Classification: Not a DOT controlled material (United States).
Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: No products were found.


Other Regulations: Not available.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
This product is not classified according to the EU regulations. S24/25- Avoid contact with skin and eyes. S28- After contact
with skin, wash immediately with plenty of water. S37- Wear suitable gloves. S45- In case of accident or if you feel unwell,
seek medical advice immediately (show the label where possible).
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Safety glasses.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/11/2005 12:38 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Iodine MSDS
Section 1: Chemical Product and Company Identification

Product Name: Iodine Contact Information:


Catalog Codes: SLI1513 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 7553-56-2 Houston, Texas 77396
RTECS: NN1575000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Iodine
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: 1-800-424-9300
Chemical Name: Iodine International CHEMTREC, call: 1-703-527-3887
Chemical Formula: I2 For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Iodine 7553-56-2 100

Toxicological Data on Ingredients: Iodine: ORAL (LD50): Acute: 14000 mg/kg [Rat]. 22000 mg/kg [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:


Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skin
contact (corrosive), of eye contact (corrosive). Slightly hazardous in case of skin contact (permeator). The amount of tissue
damage depends on length of contact. Eye contact can result in corneal damage or blindness. Skin contact can produce
inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by
burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking, unconsciousness or death.
Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching,
scaling, reddening, or, occasionally, blistering.
Potential Chronic Health Effects:
Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. CARCINOGENIC EFFECTS:
Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL
TOXICITY: Not available. The substance is toxic to thyroid. The substance may be toxic to blood, kidneys, liver, skin, eyes.
Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure of the eyes
to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin destruction, or dermatitis.
Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage.

p. 1
Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. WARM water MUST be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards:
Ignition on contact with bromine, ... chlorine trifluoride, ...metals (powdered) + water, aluminum-titanium alloys + heat, metal
acetylides, ... nonmetals, ... sodium phosphinate. Incandescent reaction with cesium oxide (above 150 deg C), bromine
trifluoride, metal acetylides or carbides [e.g. barium acetylide (above 122 deg C), calcium acetylide (above 305 deg C),
strontium acetylide (above 182 deg C), zirconium acetylide (above 400 degC)]. Magnesium burns vigorously when heated with
iodine vapor. Iodine unites with fluorine at ordinary temperature with a luminous flame
Special Remarks on Explosion Hazards:
Explosive reactions with iodine and: hafnium powder + heat; tetraamine copper (II) sulfate + ethanol; trioxygen difluoride;
polyacetylene (at 113 deg. C); potassium; sodium; butadiene+ ethanol +mercuric oxide;

Section 6: Accidental Release Measures

p. 2
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be
careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep container dry. Do not ingest. Do not breathe dust. Never add water to this product. In case of insufficient ventilation,
wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25°C (77°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Exposure Limits:
STEL: 1 (mg/m3) from ACGIH (TLV) [United States] STEL: 0.1 (ppm) from ACGIH (TLV) [United States] TWA: 1 CEIL: 1 (mg/
m3) from OSHA (PEL) [United States] TWA: 0.1 CEIL: 0.1 (ppm) from OSHA (PEL) [United States] STEL: 0.1 (ppm) [United
Kingdom (UK)] STEL: 1.1 (mg/m3) [United Kingdom (UK)]Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid.


Odor: Sharp Characteristic. (Strong.)
Taste: Not available.
Molecular Weight: 253.81 g/mole
Color: Purple solid with metalic luster. (Dark.)
pH (1% soln/water): Not available.
Boiling Point: 184.4°C (363.9°F)
Melting Point: 113.7°C (236.7°F)
Critical Temperature: Not available.
Specific Gravity: 4.93 (Water = 1)
Vapor Pressure: Not applicable.

p. 3
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: The product is more soluble in oil; log(oil/water) = 2.5
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, methanol, diethyl ether.
Solubility:
Easily soluble in diethyl ether. Soluble in methanol. Very slightly soluble in cold water, hot water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Heat, direct sunlight, incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents, reducing agents, metals.
Corrosivity:
Extremely corrosive in presence of steel, of stainless steel(304), of stainless steel(316). Non-corrosive in presence of glass, of
aluminum, of copper.
Special Remarks on Reactivity:
Incompatible with liquid chlorine, acetaldehyde, ammonia, salt + ethanol, ammonium hydroxide, methyl alcohol, antimony,
silver azide, lithium, potasssium , sodium, phosphorous, bromine pentafluoride, fluorine, oxygen difluoride, magnesium,
finely divided metals, organic solvents, rubber goods, plastics, zinc, aluminum, alkali metals, sulphur, ammonia solutions,
Bromine trifluoride, reducing agents, iron, ethanol + butadiene; ethanol + phosphorous; ethanol + methanol + HgO; foramide
+ pyrindine + sulfur trioxide; formamide; halogens or interhalogens; mercuric oxide; metal carbides; oxygen; pyridine; sodium
hydride. Violent reaction with iodine and aluminum + diethyl ether ... (and) titanium (above 113 deg C)
Special Remarks on Corrosivity:
Corrodes steel. No corrosive effect on bronze
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals: Acute oral toxicity (LD50): 14000 mg/kg [Rat].
Chronic Effects on Humans:
Causes damage to the following organs: thyroid. May cause damage to the following organs: blood, kidneys, liver, skin, eyes.
Other Toxic Effects on Humans:
Very hazardous in case of skin contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (corrosive), of
eye contact (corrosive). Slightly hazardous in case of skin contact (permeator).
Special Remarks on Toxicity to Animals:
Lowest Published Lethal Dose: LDL [Human] - Route: Oral; Dose: 28 mg/kg LCL [Rat] - Route: Inhalation; Dose: 137 ppm/1H
Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects (effects on new born).
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Corrosive action skin. Causes skin irritation and burns. It is corrosive and can cause
penetrating lesions and brown staining. It can be absorbed by the skin. Eyes: Causes eye irritation and burns. May cause
conjunctivitis. Exposure to vapor can cause burning sensation in the eyes, tearing, inflammation of the eye lids. Exposure

p. 4
to high concentrations of vapor can cause Dendritic Keratitis in which the corneal epithelium is sloughed off. Inhalation:
Excessive inhalation of iodine vapors may cause respiratory tract, nasal, and mucous membrane irritation with possible burns.
Symptoms may include coughing, tightness in the chest, burning sensations to the mucosal, tracheal, and pulmonary tissues,
rhinitis, dyspnea/respiratory distress, coughing, sneezing, pulmonary edema, chemical pneumonitis, edema of the larynx and
bronchi, pharyngitis, swelling of the parotid gland, and cachexia. High exposure may lead to lung disease and may also affect
behavior/central nervous system (delirium, hallucination, depression, seizure, dizziness, headache, stupor, somnolence).
Ingestion: Ingestion of large doses may cause irritation of mouth of the digestive tract with thirst, nausea, vomiting, abdominal
pain, hypermotility, and diarrhea, staining of mouth, esophagus, lips, mucous membranes, metallic taste, abdominal pain,
fever. It ma y also affect the cardiovascular system (tachycardia, hypotension, cardiovascular collapse), behavior/central
nervous system(delirium, dizziness, headache, hallucinations, seizures,

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material


Identification: : Corrosive Solid, n.o.s (Iodine) UNNA: 1759 PG: III
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:


Illinois toxic substances disclosure to employee act: Iodine Rhode Island RTK hazardous substances: Iodine Pennsylvania
RTK: Iodine Minnesota: Iodine Massachusetts RTK: Iodine Massachusetts spill list: Iodine New Jersey: Iodine California
Director's List of Hazardous Substances: Iodine TSCA 8(b) inventory: Iodine
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada):
CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive solid.
DSCL (EEC):
R38- Irritating to skin. R41- Risk of serious damage to eyes. S2- Keep out of the reach of children. S26- In case of contact with
eyes, rinse immediately with plenty of water and seek medical advice. S39- Wear eye/face protection. S46- If swallowed, seek
medical advice immediately and show this container or label.

p. 5
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Personal Protection: j
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/11/2005 12:09 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Ascorbic acid MSDS

Section 1: Chemical Product and Company Identification

Product Name: Ascorbic acid Contact Information:


Catalog Codes: SLA1306, SLA4315, SLA1972 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 50-81-7 Houston, Texas 77396
RTECS: CI7650000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Ascorbic acid
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Vitamin C, Ascorvit, Vicomin C, Acorbate, 1-800-424-9300
Ascorbutina, Catavin C, Cevex, Secorbate; 3-Keto-L-
gulofuranolactone; 3-Oxo-L-gulofuranolactone International CHEMTREC, call: 1-703-527-3887

Chemical Name: L-Ascorbic Acid For non-emergency assistance, call: 1-281-441-4400

Chemical Formula: C6H8O6

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Ascorbic acid 50-81-7 100

Toxicological Data on Ingredients: Ascorbic acid: ORAL (LD50): Acute: 11900 mg/kg [Rat]. 3367 mg/kg [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for
bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or
prolonged exposure is not known to aggravate medical condition.

Section 4: First Aid Measures

Eye Contact:

p. 1
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention if irritation occurs.
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.


Auto-Ignition Temperature: 660°C (1220°F)
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances:
Slightly flammable to flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Slightly explosive in presence of open
flames and sparks.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards:
As with most powdered organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Special Remarks on Explosion Hazards:
Fine dust dispersed in air in sufficient concentrations, and in the presences of an ignition source is a potential dust explosion

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:

p. 2
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not
breathe dust. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles
such as oxidizing agents.
Storage:
Keep container tightly closed. Keep container in a cool, well-ventilated area. Air Sensitive Sensitive to light. Store in light-
resistant containers.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Crystals solid. Powdered solid.)


Odor: Odorless.
Taste: Acid. Sharp. Pleasant
Molecular Weight: 176.13 g/mole
Color: White. White to slightly yellowish.
pH (1% soln/water): Not available.
Boiling Point: Decomposition temperature: >190°C (374°F)
Melting Point: Decomposition temperature: >190°C (374°F)
Critical Temperature: 783°C (1441.4°F)
Specific Gravity: 1.65 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: The product is more soluble in water; log(oil/water) = -2.1
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility:
Soluble in hot water. Partially soluble in cold water. Insoluble in diethyl ether. Solubility in Water: 1g/3ml water. Solubility
in water: 80% @ 100 deg. C and 45% @ 45 deg. C. Solubility in alcohol: 1g/30 ml alcohol. Solubility in absolute alcohol: 1
g/50 ml absolute alcohol. Solubility in glycerol: 1g/100 ml glycerol. Solubility in propylene glycol: 1 g/20 ml propylene glycol.
Insoluble in chloroform, benzene, petroleum ether, oils, fats, fat solvents.

p. 3
Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Heat, ignition sources, light, air, incompatible materials, dust generation
Incompatibility with various substances: Reactive with oxidizing agents.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Air and light sensitive. Aqueous solutions are rapidly oxidized by air, accelerated by alkalies, iron, copper.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals: Acute oral toxicity (LD50): 3367 mg/kg [Mouse].
Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/
or yeast.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
May affect genetic material (mutagenic). May cause adverse reproductive effects and birth defects (teratogenic) based on
animal test data. Human: passes through the placenta, excreted in maternal milk.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: May cause skin irritation. Low hazard for normal industrial handling. Eyes: May cause eye
irritation. Inhalation: May cause respiratory tract irritation. Low hazard for normal industrial handling. Ingestion: Ingestion of
small amounts during normal industrial handling is a low hazard. Ingestion of large amounts may cause gastrointestinal tract
irritation, hypermotility, diarrhea, acidification of the urine which may cause stones in the urinary tract and may cause renal
failure coordination, somnolence), eyes(lacrimation), blood (anemia). Chronic Potential Health Effects: Ingestion: Prolonged or
repeated ingestion may affect the blood/bone marrow and metabolism. . May also affect behavior (psychomotor

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

p. 4
Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Ascorbic acid


Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
This product is not classified according to the EU regulations. S24/25- Avoid contact with skin and eyes.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 1
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/09/2005 04:16 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Sodium carbonate MSDS

Section 1: Chemical Product and Company Identification

Product Name: Sodium carbonate Contact Information:


Catalog Codes: SLS3481, SLS1264, SLS4105, SLS1894, Sciencelab.com, Inc.
SLS3316 14025 Smith Rd.
Houston, Texas 77396
CAS#: 497-19-8
US Sales: 1-800-901-7247
RTECS: VZ4050000 International Sales: 1-281-441-4400

TSCA: TSCA 8(b) inventory: Sodium carbonate Order Online: ScienceLab.com

CI#: Not available. CHEMTREC (24HR Emergency Telephone), call:


1-800-424-9300
Synonym: Crystal Carbonate, Disodium Carbonate, Sal
Soda, Soda Asha, Washing Soda International CHEMTREC, call: 1-703-527-3887

Chemical Name: Sodium Carbonate, Anhydrous For non-emergency assistance, call: 1-281-441-4400

Chemical Formula: Na2-C-O3

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Sodium carbonate 497-19-8 100

Toxicological Data on Ingredients: Sodium carbonate: ORAL (LD50): Acute: 4090 mg/kg [Rat]. 6600 mg/kg [Mouse]. DUST
(LC50): Acute: 2300 mg/m 2 hours [Rat]. 1200 mg/m 2 hours [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation
(lung irritant).
Potential Chronic Health Effects:
Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS:
Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may
be toxic to upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce target organs
damage.

Section 4: First Aid Measures

p. 1
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Emits Na2O fumes when heated to decompositon.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards:
Sodium carbonate can ignite and burn fiercely in contact with fluoride. Sodium Carbonate in contact with fluorine decomposed
at ordinary temperature with incandescence.
Special Remarks on Explosion Hazards:
Reacts explosively with red-hot aluminum metal. Sodium carbonate + ammonia in arabic gum solution will explode.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with
a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and dispose of according to
local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Neutralize the residue with a dilute solution
of acetic acid. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary
system.

p. 2
Section 7: Handling and Storage

Precautions:
Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable
respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with
skin and eyes. Keep away from incompatibles such as acids.
Storage:
Hygroscopic. Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24°C (75.2°F).
Hygroscopic

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Solid powder.)


Odor: Odorless.
Taste: Alkaline.
Molecular Weight: 105.99 g/mole
Color: White.
pH (1% soln/water): 11.5 [Basic.]
Boiling Point: Not available.
Melting Point: 851°C (1563.8°F)
Critical Temperature: Not available.
Specific Gravity: Density: 2.532 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility:

p. 3
Soluble in hot water, glycerol. Partially soluble in cold water. Insoluble in acetone, alcohol.

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, moisture
Incompatibility with various substances:
Reactive with acids. Slightly reactive to reactive with moisture.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Hygroscopic. Combines with water with evolution of heat. Incompatible with phosphorus pentoxide, lithium, fluorine, fluoride,
ammonia + silver nitrate, 2,4,6-trinitrotoluene, ammonia, acids, sodium sulfide + water, hydrogen peroxide, red hot alumium
metal, sodium sulfide, zinc, calcium hydroxide. Sodium Carbonate is decomposed by acids with effervescence. Reacts
violently with F2, Lithium, and 2,4,6-trinitrotoluene. Sodium begins to decompose at 400 C to evolve CO2.
Special Remarks on Corrosivity: Hot concentrated solutions of sodium carbonate are mildly corrosive to steel.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals:
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral
toxicity (LD50): 4090 mg/kg [Rat]. Acute toxicity of the dust (LC50): 1200 mg/m3 2 hours [Mouse].
Chronic Effects on Humans: May cause damage to the following organs: upper respiratory tract, skin, eyes.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant).
Special Remarks on Toxicity to Animals: LDL (Lowest Published Lethal Dose) [Man] - Route: Oral; Dose: 714 mg/kg
Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects based on animal test data
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Causes skin irritation with possible burns depending on the concentration, site (abraded
or intact skin), and duration of exposure. Eyes: Causes eye irritation and possible burns. Concentrated solutions may cause
permanent corneal injury (permanent corneal opacity). Ingestion: Sodium carbonate ingestion may cause irritation of the
digestive tract resulting in nausea, vomiting, diarrhea, thirst, abdominal pain depending on concentration and amount ingested.
May also affect the cardiovascular system . Inhalation: Dust may cause respiratory tract and mucous membrane irritation
with coughing and shortness of breath (dyspnea), pulmonary edema. Chronic Potential Health Effects: Chronic inhalation
may result in decreased pulmonary function, nasal congestion, nosebleeds, perforation of the nasal septum. Other effects
of chronic exposure are skin (dermatitis and ulceration), and gastrointestinal complaints. However, the effects of chronic
exposure seem to be reversible if exposure is decreased.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

p. 4
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Sodium carbonate


Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): CLASS D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC):
R36/37/38- Irritating to eyes, respiratory system and skin. S22- Do not breathe dust. S26- In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 1
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 1
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.

p. 5
Created: 10/10/2005 08:26 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

p. 6
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1 1
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1 0
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P ro t e c t io n

Material Safety Data Sheet


Starch soluble MSDS

Section 1: Chemical Product and Company Identification

Product Name: Starch soluble Contact Information:


Catalog Codes: SLS2821 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 9005-84-9 Houston, Texas 77396
RTECS: GM5090000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Starch soluble
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Starch, soluble; Amylodextrin; Amglogen; 1-800-424-9300
Sugar polymer
International CHEMTREC, call: 1-703-527-3887
Chemical Name: Starch
For non-emergency assistance, call: 1-281-441-4400
Chemical Formula: (C6-H10-O5)n

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Starch soluble 9005-84-9 100

Toxicological Data on Ingredients: Not applicable.

Section 3: Hazards Identification

Potential Acute Health Effects:


Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation. Non-hazardous in case of ingestion.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. WARM water MUST be used. Get medical attention if irritation occurs.

p. 1
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.


Auto-Ignition Temperature: 380°C (716°F)
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances:
Slightly flammable to flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards: Dust-air mixtures may ignite or explode
Special Remarks on Explosion Hazards: Dust-air mixtures may ignite or explode

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:
Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a
fume hood. Ground all equipment containing material. Do not breathe dust. Keep away from incompatibles such as oxidizing
agents.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24°C (75.2°F).

p. 2
Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Powdered solid.)


Odor: Characteristic. (Slight.)
Taste: Not available.
Molecular Weight: Not available.
Color: White.
pH (1% soln/water): Not available.
Boiling Point: Not available.
Melting Point: Decomposes.
Critical Temperature: Not available.
Specific Gravity: Not available.
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Dispersed in hot water.
Solubility: Not available.

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Excess heat
Incompatibility with various substances: Reactive with oxidizing agents.
Corrosivity: Non-corrosive in presence of glass.

p. 3
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans:
Slightly hazardous in case of skin contact (irritant), of inhalation. Non-hazardous in case of ingestion.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: May irritate skin. No adverse effects expected. Eyes: Dust may cause mechanical
irritation. No adverse effects expected. Inhalation: Nuisance dust. May cause respiratory tract irritation. Symptoms are similar
to those caused by nuisance dust: coughing, sneezing. Ingestion: Not expected to be a health hazard. Chronic Potential
Health Effects: No adverse effects expected.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Starch soluble

p. 4
Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
This product is not classified according to the EU regulations. Not applicable.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 1
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/09/2005 06:39 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

p. 5
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Material Safety Data Sheet


Methyl orange MSDS

Section 1: Chemical Product and Company Identification

Product Name: Methyl orange Contact Information:


Catalog Codes: SLM2938, SLM4318 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 547-58-0 Houston, Texas 77396
RTECS: DB6327000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Methyl orange
Order Online: ScienceLab.com
CI#: 13025
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Acid Orange 52; Sodium 1-800-424-9300
Dimethylaminobenzenesulfonate; 4-
[Dimethylamino)pnenylazo]benzenesulfonic Acid, sodium International CHEMTREC, call: 1-703-527-3887
salt; Orange III; Tropaeolin D For non-emergency assistance, call: 1-281-441-4400
Chemical Name: Methyl Orange
Chemical Formula: C14H14N3NaO3S

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Methyl orange 547-58-0 100

Toxicological Data on Ingredients: Methyl orange: ORAL (LD50): Acute: 60 mg/kg [Rat].

Section 3: Hazards Identification

Potential Acute Health Effects:


Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Severe over-exposure can result
in death.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENIC
EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated exposure to a highly toxic material may
produce general deterioration of health by an accumulation in one or many human organs.

Section 4: First Aid Measures

p. 1
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. WARM water MUST be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Seek
medical attention.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.


Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...). Some metallic oxides.
Fire Hazards in Presence of Various Substances:
Slightly flammable to flammable in presence of heat. Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for
assistance on disposal.

Section 7: Handling and Storage

p. 2
Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate
the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable
protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice
immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as
oxidizing agents.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25°C (77°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Powdered solid.)


Odor: Odorless.
Taste: Not available.
Molecular Weight: 327.34 g/mole
Color: Orange-Yellow.
pH (1% soln/water): Not available.
Boiling Point: Not available.
Melting Point: >300°C (572°F)
Critical Temperature: Not available.
Specific Gravity: Not available.
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not available.
Solubility:
Partially soluble in hot water. Very slightly soluble in cold water. Insoluble in diethyl ether. Practically insoluble in alcohol.
Soluble in Pyrimidine.

p. 3
Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Excess heat, incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals: Acute oral toxicity (LD50): 60 mg/kg [Rat].
Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: May affect genetic material
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: Dust may cause eye irritation. This product contains
an anionic dye. Similar dyes have not caused injury to the cornea or conjunctiva in documented exposure cases with
human or rabbit eyes. Inhalation: Dust may cause respiratory tract irritation, Ingestion: Harmful is swallowed. May cause
gastrointestinal tract irritation with nausea, vomiting, and diarrhea. The toxicological properties of this substance have not been
fully investigated.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 6.1: Poisonous material.

p. 4
Identification: : Dye, solid, toxic, n.o.s. (Methyl orange) UNNA: 3143 PG: III
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Methyl orange


Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
R25- Toxic if swallowed. S28- After contact with skin, wash immediately with plenty of water. S45- In case of accident or if you
feel unwell, seek medical advice immediately (show the label where possible).
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 1
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/10/2005 08:40 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Phenolphthalein TS MSDS
Section 1: Chemical Product and Company Identification

Product Name: Phenolphthalein TS Contact Information:


Catalog Codes: SLP1345 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: Mixture. Houston, Texas 77396
RTECS: Not applicable. US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Water; Ethyl alcohol 200
Proof; Phenolphthalein, powder Order Online: ScienceLab.com

CI#: Not applicable. CHEMTREC (24HR Emergency Telephone), call:


1-800-424-9300
Synonym: Phenolphthalein TS
International CHEMTREC, call: 1-703-527-3887
Chemical Name: Not applicable.
For non-emergency assistance, call: 1-281-441-4400
Chemical Formula: Not applicable.

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Water 7732-18-5 5.0
Ethyl alcohol 200 Proof 64-17-5 94
Phenolphthalein, powder 77-09-8 1

Toxicological Data on Ingredients: Ethyl alcohol 200 Proof: ORAL (LD50): Acute: 7060 mg/kg [Rat.]. 3450 mg/kg [Mouse].
VAPOR (LC50): Acute: 20000 ppm 8 hours [Rat]. 39000 mg/m 4 hours [Mouse]. Phenolphthalein, powder LD50: Not available.
LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects:


Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Slightly hazardous in case of skin contact
(permeator). Non-corrosive for skin. Non-corrosive to the eyes. Non-corrosive for lungs.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Classified PROVEN by State of California Proposition 65 [Ethyl alcohol 200 Proof]. Classified
A4 (Not classifiable for human or animal.) by ACGIH [Ethyl alcohol 200 Proof]. Classified 1 (Clear evidence.) by NTP
[Phenolphthalein, powder]. Classified 2B (Possible for human.) by IARC [Phenolphthalein, powder]. MUTAGENIC EFFECTS:
Mutagenic for mammalian somatic cells. [Ethyl alcohol 200 Proof]. Mutagenic for bacteria and/or yeast. [Ethyl alcohol 200
Proof]. Mutagenic for mammalian somatic cells. [Phenolphthalein, powder]. TERATOGENIC EFFECTS: Classified PROVEN

p. 1
for human [Ethyl alcohol 200 Proof]. DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol
200 Proof]. Classified Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 200 Proof]. The substance is toxic to blood,
the reproductive system, liver, upper respiratory tract, skin, central nervous system (CNS). The substance may be toxic to
kidneys. Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids
open. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention if symptoms appear.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical
attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.


Auto-Ignition Temperature: The lowest known value is 363°C (685.4°F) (Ethyl alcohol 200 Proof).
Flash Points:
The lowest known value is CLOSED CUP: 12.78°C (55°F). OPEN CUP: 12.78°C (55°F). (Cleveland). (Ethyl alcohol 200 Proof)
Flammable Limits: The greatest known range is LOWER: 3.3% UPPER: 19% (Ethyl alcohol 200 Proof)
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances:
Highly flammable in presence of open flames and sparks, of heat. Slightly flammable to flammable in presence of oxidizing
materials. Non-flammable in presence of shocks, of reducing materials, of combustible materials, of organic materials, of
metals, of acids, of alkalis, of moisture.
Explosion Hazards in Presence of Various Substances:
Slightly explosive in presence of oxidizing materials, of acids. Non-explosive in presence of open flames and sparks, of
shocks.
Fire Fighting Media and Instructions:
Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,
water spray or fog.
Special Remarks on Fire Hazards:

p. 2
Containers should be grounded. CAUTION: MAY BURN WITH NEAR INVISIBLE FLAME Vapor may travel considerable
distance to source of ignition and flash back. (Ethyl alcohol 200 Proof)
Special Remarks on Explosion Hazards:
Ethanol has an explosive reaction with the oxidized coating around potassium metal. Ethanol ignites and then explodes on
contact with acetic anhydride + sodium hydrosulfate (ignites and may explode), disulfuric acid + nitric acid, phosphorous(III)
oxide platinum, potassium-tert-butoxide+ acids. Ethanol forms explosive products in reaction with the following compound :
ammonia + silver nitrate (forms silver nitride and silver fulminate), iodine + phosphorus (forms ethane iodide), magnesium
perchlorate (forms ethyl perchlorate), mercuric nitrate, nitric acid + silver (forms silver fulminate) silver nitrate (forms ethyl
nitrate) silver(I) oxide + ammonia or hydrazine (forms silver nitride and silver fulminate), sodium (evolves hydrogen gas). (Ethyl
alcohol 200 Proof)

Section 6: Accidental Release Measures

Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill:
Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confined
areas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS
and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do
not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear
suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids, alkalis.
Storage:
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and
sealed until ready for use. Avoid all possible sources of ignition (spark or flame).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
Ethyl alcohol 200 Proof TWA: 1000 (ppm) from ACGIH (TLV) [United States] [1999] TWA: 1000 (ppm) from OSHA (PEL)
[United States] TWA: 1900 (mg/m3) from OSHA (PEL) [United States] TWA: 1000 (ppm) from NIOSH TWA: 1000 (ppm)
[United Kingdom (UK)] TWA: 1920 (mg/m3) [United Kingdom (UK)] TWA: 1000 STEL: 1250 (ppm) [Canada]Consult local
authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

p. 3
Physical state and appearance: Liquid.
Odor: Not available.
Taste: Not available.
Molecular Weight: Not applicable.
Color: Colorless.
pH (1% soln/water): Neutral.
Boiling Point: The lowest known value is 78.5°C (173.3°F) (Ethyl alcohol 200 Proof). Weighted average: 79.58°C (175.2°F)
Melting Point: May start to solidify at -114.1°C (-173.4°F) based on data for: Ethyl alcohol 200 Proof.
Critical Temperature: The lowest known value is 243°C (469.4°F) (Ethyl alcohol 200 Proof).
Specific Gravity: Weighted average: 0.8 (Water = 1)
Vapor Pressure: The highest known value is 5.7 kPa (@ 20°C) (Ethyl alcohol 200 Proof). Weighted average: 5.53 kPa (@
20°C)
Vapor Density: The highest known value is 1.59 (Air = 1) (Ethyl alcohol 200 Proof). Weighted average: 1.54 (Air = 1)
Volatility: Not available.
Odor Threshold: The highest known value is 100 ppm (Ethyl alcohol 200 Proof)
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, methanol, diethyl ether, acetone.
Solubility:
Easily soluble in cold water, hot water, methanol, diethyl ether. Soluble in acetone.

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, heat, sources of ignition. (Ethyl alcohol 200 Proof)
Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Ethanol rapidly absorbs moisture from the air. Can react vigorously with oxiders. The following oxidants have been
demonstrated to undergo vigorous/explosive reaction with ethanol: barium perchlorate, bromine pentafluoride, calcium
hypochlorite, chloryl perchlorate, chromium trioxide, chromyl chloride, dioxygen difluoride, disulfuryl difluoride, fluorine nitrate,
hydrogen peroxide, iodine heptafluoride, nitric acid nitrosyl perchlorate, perchloric acid permanganic acid, peroxodisulfuric
acid, potassium dioxide, potassium perchlorate, potassium permanganate, ruthenium(VIII) oxide, silver perchlorate, silver
peroxide, uranium hexafluoride, uranyl perchlorate. Ethanol reacts violently/expodes with the following compounds: acetyl
bromide (evolves hydrogen bromide) acetyl chloride, aluminum, sesquibromide ethylate, ammonium hydroxide & silver
oxide, chlorate, chromic anhydride, cyanuric acid + water, dichloromethane + sulfuric acid + nitrate (or) nitrite, hydrogen
peroxide + sulfuric acid, iodine + methanol + mercuric oxide, manganese perchlorate + 2,2-dimethoxy propane, perchlorates,
permanganates + sulfuric acid, potassium superoxide, potassium tert-butoxide, silver & nitric acid, silver perchlorate, sodium
hydrazide, sulfuric acid + sodium dichromate, tetrachlorisilane + water. Ethanol is also incompatible with platinium, and
sodium. (Ethyl alcohol 200 Proof)
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

p. 4
Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact. Inhalation.


Toxicity to Animals: Acute oral toxicity (LD50): 3450 mg/kg [Mouse]. (Ethyl alcohol 200 Proof).
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified PROVEN by State of California Proposition 65 [Ethyl alcohol 200 Proof]. Classified
A4 (Not classifiable for human or animal.) by ACGIH [Ethyl alcohol 200 Proof]. Classified 1 (Clear evidence.) by NTP
[Phenolphthalein, powder]. Classified 2B (Possible for human.) by IARC [Phenolphthalein, powder]. MUTAGENIC EFFECTS:
Mutagenic for mammalian somatic cells. [Ethyl alcohol 200 Proof]. Mutagenic for bacteria and/or yeast. [Ethyl alcohol 200
Proof]. Mutagenic for mammalian somatic cells. [Phenolphthalein, powder]. TERATOGENIC EFFECTS: Classified PROVEN
for human [Ethyl alcohol 200 Proof]. DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol
200 Proof]. Classified Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 200 Proof]. Contains material which may
cause damage to the following organs: kidneys.
Other Toxic Effects on Humans:
Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
May affect genetic material (mutagenic) Causes adverse reproductive effects and birth defects (teratogenic) , based on
moderate to heavy consumption. May cause cancer based on animal data. Human: passes through the placenta, excreted in
maternal milk. (Ethyl alcohol 200 Proof)
Special Remarks on other Toxic Effects on Humans:
Acute potential health effects: Skin: causes skin irritation Eyes: causes eye irritation Ingestion: May affect behavior.
Moderately toxic and narcotic in high concentrations. May affect metabolism, gastrointestinal tract, blood, liver. May affect
respiratory tract, cardiovascular and urinary systems. Experimentaly tumorigen. Inhalation: May cause irritation of the
respiratory tract, headache, drowsiness, nausea, narcosis. (Ethyl alcohol 200 Proof)

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 3: Flammable liquid.


Identification: : Ethanol (Ethyl alcohol 200 Proof) UNNA: 1170 PG: II
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

p. 5
Federal and State Regulations:
California prop. 65: This product contains the following ingredients for which the State of California has found to cause
cancer, birth defects or other reproductive harm, which would require a warning under the statute: Ethyl alcohol 200 Proof;
Phenolphthalein, powder California prop. 65: This product contains the following ingredients for which the State of California
has found to cause birth defects which would require a warning under the statute: Ethyl alcohol 200 Proof California prop. 65:
This product contains the following ingredients for which the State of California has found to cause cancer which would require
a warning under the statute: Ethyl alcohol 200 Proof; Phenolphthalein, powder Rhode Island RTK hazardous substances:
Ethyl alcohol 200 Proof Pennsylvania RTK: Ethyl alcohol 200 Proof Florida: Ethyl alcohol 200 Proof Massachusetts RTK: Ethyl
alcohol 200 Proof New Jersey: Ethyl alcohol 200 Proof TSCA 8(b) inventory: Water; Ethyl alcohol 200 Proof; Phenolphthalein,
powder
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada):
CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS D-2A: Material causing other toxic effects
(VERY TOXIC).
DSCL (EEC):
R11- Highly flammable. R22- Harmful if swallowed. R45- May cause cancer. S2- Keep out of the reach of children. S46-
If swallowed, seek medical advice immediately and show this container or label. S53- Avoid exposure - obtain special
instructions before use.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 3
Reactivity: 0
Personal Protection: h
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 3
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/10/2005 11:18 AM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Barium chloride dihydrate MSDS

Section 1: Chemical Product and Company Identification

Product Name: Barium chloride dihydrate Contact Information:


Catalog Codes: SLB1885 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 10326-27-9 Houston, Texas 77396
RTECS: CQ8751000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: No products were found.
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Barium Dichloride Dihydrate 1-800-424-9300
Chemical Name: Barium Chloride Dihydrate International CHEMTREC, call: 1-703-527-3887
Chemical Formula: BaCl2.2H20 For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Barium chloride dihydrate 10326-27-9 100

Toxicological Data on Ingredients: Barium chloride dihydrate LD50: Not available. LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects:


Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation. Severe over-
exposure can result in death.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to kidneys, the nervous system, peripheral nervous
system, cardiovascular system, upper respiratory tract, central nervous system (CNS). The substance may be toxic to liver.
Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to a highly toxic
material may produce general deterioration of health by an accumulation in one or many human organs.

Section 4: First Aid Measures

Eye Contact:

p. 1
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek medical attention.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be
careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

p. 2
Precautions:
Keep locked up.. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation,
wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 0.5 (mg (Ba)/m) from ACGIH (TLV) [United States] Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid.


Odor: Odorless.
Taste: Bitter. Saline.
Molecular Weight: 244.26 g/mole
Color: White.
pH (1% soln/water): Not available.
Boiling Point: Not available.
Melting Point: 963°C (1765.4°F)
Critical Temperature: Not available.
Specific Gravity: Density: 3.86 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, methanol.
Solubility:
Easily soluble in cold water. Soluble in methanol. Insoluble in acetone. Practically insoluble in ethanol, ethyl acetate.

p. 3
Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents, acids.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
It is rapidly attacked by bromine trifluoride. Incompatible with 2-furan percarboxylic acid. Barium Chloride dihydrate loses water
at 100 to 113 deg. C.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans:
Causes damage to the following organs: kidneys, the nervous system, peripheral nervous system, cardiovascular system,
upper respiratory tract, central nervous system (CNS). May cause damage to the following organs: liver.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects. May affect genetic material
(mutagenic)
Special Remarks on other Toxic Effects on Humans:
Potential Health Effects: Skin: Causes skin irritation. Eyes: Causes eye irritation with redness and pain. May cause blurred
vision. Inhalation: respiratory tract and mucous membrane irritation. Ingestion: Ingestion may cause gastrointestinal tract
irritation with nausea, vomiting, colicky diarrhea, increased salivation, and severe abdominal pain. It may also cause mydriasis,
renal failure, hepatocellular damage, dyspnea, tachypnea, shallow breathing, respiratory failure, tinnitus, chest pain, cardiac
arrhythmias/disarrythmias, hypertension, bradycardia, hypokalemia, hypophosphatemia, vertigo, faintness, progressive
muscular paralysis, muscle weakness, dizziness, tremors, convulsions, and seizures. It may also affec the blood (changes in
leukocyte count, changes in serum composition).

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

p. 4
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 6.1: Poisonous material.


Identification: : Barium Compound, n.o.s. (Barium Chloride) UNNA: 1564 PG: III
Special Provisions for Transport: Marine Pollutant

Section 15: Other Regulatory Information

Federal and State Regulations: No products were found.


Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada): CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC).
DSCL (EEC):
R20- Harmful by inhalation. R25- Toxic if swallowed. S28- After contact with skin, wash immediately with plenty of water.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell,
seek medical advice immediately (show the label where possible). S46- If swallowed, seek medical advice immediately and
show this container or label.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/10/2005 08:14 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume

p. 5
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Silver nitrate MSDS
Section 1: Chemical Product and Company Identification

Product Name: Silver nitrate Contact Information:


Catalog Codes: SLS2122, SLS1327 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 7761-88-8 Houston, Texas 77396
RTECS: VW4725000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Silver nitrate
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Lunar caustic; Silver (1+) nitrate; Nitric acid, 1-800-424-9300
silver (1+) salt
International CHEMTREC, call: 1-703-527-3887
Chemical Name: Silver Nitrate
For non-emergency assistance, call: 1-281-441-4400
Chemical Formula: AgNO3

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Silver nitrate 7761-88-8 100

Toxicological Data on Ingredients: Silver nitrate: ORAL (LD50): Acute: 1173 mg/kg [Rat]. 50 mg/kg [Mouse]. 473 mg/kg
[Guinea pig].

Section 3: Hazards Identification

Potential Acute Health Effects:


Very hazardous in case of skin contact (irritant), of ingestion. Hazardous in case of skin contact (permeator), of eye contact
(irritant), of inhalation. Slightly hazardous in case of skin contact (corrosive). The amount of tissue damage depends on length
of contact. Eye contact can result in corneal damage or blindness. Skin contact can produce inflammation and blistering.
Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and
coughing. Severe over-exposure can produce lung damage, choking, unconsciousness or death. Prolonged exposure may
result in skin burns and ulcerations. Over-exposure by inhalation may cause respiratory irritation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs. The substance may be toxic to mucous
membranes, skin, eyes. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated
exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin
destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage.

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Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: organic materials, combustible materials
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Contact with combustible or organic materials may cause fire.
Special Remarks on Explosion Hazards:
Silver nitrate mixed with dry powdered magnesium may ignite explosively on contact with a drop of water. An explosive
fulminate may be formed if silver nitrate is mixed with alcohols. Highly explosive is formed by the addition of calcium carbide to
silver nitrate solution.

Section 6: Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.

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Large Spill:
Oxidizing material. Corrosive solid. Stop leak if without risk. Do not get water inside container. Avoid contact with a
combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material.
Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance
on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with
local authorities.

Section 7: Handling and Storage

Precautions:
Keep container dry. Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Do
not ingest. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory
equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and
eyes.
Storage:
Keep container tightly closed. Keep container in a cool, well-ventilated area. Separate from acids, alkalies, reducing agents
and combustibles. See NFPA 43A, Code for the Storage of Liquid and Solid Oxidizers. Sensitive to light. Store in light-resistant
containers.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Exposure Limits:
TWA: 0.01 (mg/m Ag) from ACGIH (TLV) [United States] TWA: 0.01 (mg/m Ag) from OSHA (PEL) [United States]3 Consult
local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Crystals solid.)


Odor: Not available.
Taste: Bitter. Metallic
Molecular Weight: 169.87 g/mole
Color: Colorless. White.
pH (1% soln/water): 6 - 7 [slightly acidic to neutral]
Boiling Point: Decomposition temperature: 440°C (824°F)
Melting Point: 212°C (413.6°F)
Critical Temperature: Not available.

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Specific Gravity: 4.35 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: 5.8 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, diethyl ether.
Solubility:
Easily soluble in cold water, hot water. Soluble in diethyl ether. Very slightly soluble in acetone. Solubility in water: 122 g/100
ml water @ 0 deg. C. Solubility in water: 952 g /100 ml water @ 190 deg. C Solubility in alcohol: 1 g/30 ml alcohol; 1g/ 6.5 ml
boiling alcohol. Solubility in acetone: 1 g/ 253 ml acetone

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, light
Incompatibility with various substances: Reactive with reducing agents, combustible materials, organic materials, alkalis.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Sensitive to light. Incompatible with antimony salts, arsenites, bromides, carbonates, chloarides, iodides, thiocyanates, ferrous
salts, hypophosphites, morphine salts, oils, creosote, phosphates, tannic acid, tartrates, vegetable decoctions, and extracts,
sodium hydroxide, charcoal, thimerosal, benzalkonium chloride, halogenated acids and their salts. alcohols. Silver nitrate
reacts with acetylene in presence of ammonia to form silver acetylide, a sensitive powerful detonator when dry. Reaction
between silver nitrate and chlorosulfonic acid is violent. Silver nitrate is reduced by hydrogen sulfide in the dark. Silver nitrate
is easily reduces to metallic silver by ferrous salts, arsenites, hypophosphites, tartrates, sugars, tannins, volatile oils.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 50 mg/kg [Mouse].
Chronic Effects on Humans:
Causes damage to the following organs: lungs. May cause damage to the following organs: mucous membranes, skin, eyes.
Other Toxic Effects on Humans:
Very hazardous in case of skin contact (irritant), of ingestion. Hazardous in case of skin contact (permeator), of inhalation.
Slightly hazardous in case of skin contact (corrosive).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
May affect genetic material (mutagenic). May cause cancer based on animal test data. May cause adverse reproductive
effects.
Special Remarks on other Toxic Effects on Humans:

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Acute Potential Health Effects: Skin: Causes severe irritation and burns. It may cause dermatitis. It may be absorbed through
the skin. Eyes: Causes severe irritation, corneal opacification, bleeding conjunctiva, burns of conjunctiva, argyria, blindness
Inhalation: Causes irritaiton of the respiratory tract and mucous membranes with possible chemical burns. Symptoms may
include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, vomiting. Ingestion: Severe
gastrointestinal tract irritation and burns, pain and burning in the mouth, violent abdominal pain, argryia -grayish/blackening of
skin and mucous membranes, throat and abdomen, salivation, vomiting of black material, diarrhea, hypermotility, ulcerative
gingivitis . May affect kidneys (lesions of kidneys, anuria, ), lungs

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 5.1: Oxidizing material.


Identification: : Silver nitrate UNNA: 1493 PG: II
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:


Connecticut hazardous material survey.: Silver nitrate Illinois chemical safety act: Silver nitrate New York acutely hazardous
substances: Silver nitrate Rhode Island RTK hazardous substances: Silver nitrate Pennsylvania RTK: Silver nitrate
Massachusetts RTK: Silver nitrate Massachusetts spill list: Silver nitrate New Jersey: Silver nitrate New Jersey spill list: Silver
nitrate Louisiana spill reporting: Silver nitrate California Director's List of Hazardous Substances: Silver nitrate TSCA 8(b)
inventory: Silver nitrate
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada):
CLASS C: Oxidizing material. CLASS E: Corrosive solid.
DSCL (EEC):
R8- Contact with combustible material may cause fire. R20/22- Harmful by inhalation and if swallowed. R34- Causes burns.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S24/25- Avoid
contact with skin and eyes. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28- After contact with skin, wash immediately with plenty of water S36/37/39- Wear suitable protective clothing, gloves and

p. 5
eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible). S46- If swallowed, seek medical advice immediately and show this container or label. S60- This material and its
container must be disposed of as hazardous waste. S61- Avoid release to the environment. Refer to special instructions/
Safety data sheets.
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Personal Protection: j
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves (impervious). Synthetic apron. Wear appropriate respirator when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/10/2005 08:53 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Ammonium sulfate MSDS
Section 1: Chemical Product and Company Identification

Product Name: Ammonium sulfate Contact Information:


Catalog Codes: SLA2851, SLA2011, SLA1168, SLA2674 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 7783-20-2 Houston, Texas 77396
RTECS: BS4500000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Ammonium sulfate
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Sulfluric Acid, Diammonium Salt 1-800-424-9300
Chemical Name: Ammonium Sulfate International CHEMTREC, call: 1-703-527-3887
Chemical Formula: (NH4)2SO4 For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Ammonium sulfate 7783-20-2 100

Toxicological Data on Ingredients: Ammonium sulfate: ORAL (LD50): Acute: 2840 mg/kg [Rat]. 640 mg/kg [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.

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Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.


Auto-Ignition Temperature: Not available.
Flash Points: CLOSED CUP: Higher than 93.3°C (200°F).
Flammable Limits: Not available.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances:
Flammable in presence of oxidizing materials. Slightly flammable to flammable in presence of heat.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available. Explosive in presence of oxidizing materials.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards:
A mixture of ammonium sulfate and potassium chlorate decomposes with incandescence when heated. When a little
ammonium sulfate is added to fused potassium nitrite, a vigorous reaction occurs attended by flame. Non combustible. This
substance itself does not burn, but may decompose upon heating to produce corrosive and/or toxic fumes.
Special Remarks on Explosion Hazards:
If accidently mixed with oxidizers like potassium chlorate, potassium nitrate or potassium nitrite, there is an explosion hazard
during fire. A mixture of ammonium sulfate and ammonium nitrate can easily be exploded by potassium or sodium-potassium
alloy.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:

p. 2
Keep away from heat. Keep away from sources of ignition. Do not ingest. Do not breathe dust. Wear suitable protective
clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately
and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing
agents.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Crystals solid.)


Odor: Odorless.
Taste: Not available.
Molecular Weight: 132.14 g/mole
Color: brownish gray to white
pH (1% soln/water): Not available.
Boiling Point: Not available.
Melting Point: 280°C (536°F)
Critical Temperature: Not available.
Specific Gravity: 1.77 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility:
Soluble in cold water. Insoluble in acetone.

Section 10: Stability and Reactivity Data

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Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Excess heat, incompatible materials.
Incompatibility with various substances:
Highly reactive with oxidizing agents. Reactive with alkalis.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Incompatible with the following: Potassium + ammonium nitrate, potassium chlorate, potassium nitrate, potassium nitrite,
sodium hypochlorite, sodium/potassium alloy + ammonium nitrate. Substance should not contact either zinc or copper bearing
materials. Reacts with alkali to release ammonia.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals: Acute oral toxicity (LD50): 640 mg/kg [Mouse].
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals:
Lowest Published Lethal Dose/Conc: LDL [Domestic animal - Goat, Sheep) - Route: Oral; Dose: 3500 mg/kg
Special Remarks on Chronic Effects on Humans:
It may be a possible mutagen. It has been tested for mutagenicity, but so far tests have been inconclusive or test information
has not been made available.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Causes skin irritation. Eyes: Causes eye irritation. Inhalation: May cause respiratory tract
irritation. Ingestion: When ingested, its osmolarity can draw water from the body into the bowel, acting as a laxative. However,
if enough is absorbed systemically it may produce Ammonia poisoning. Symptoms may include gastrointestinal (digestive)
tract irritation with nausea, vomiting, hypermotility, diarrhea. May also affect eyes (Mydriasis), behavior/central nervous system
(somnolence, tremor, convulsions, muscle contraction or spasticity), and respiratory system (respiratory stimulation, dyspnea).
Also, with ingestion of large doses of Ammonium Sulfate arises the possibility of sufficient absorption to produce diuresis, an
excessive discharge of urine, and kidney damage (renal tubular disorder, abnormal renal function). Chronic Potential Health
Effects: One Russian occupational standard study discussed chronic exposure effects which may include cardiac contraction,
neurotoxicity, and hypertension. This has not been confirmed in other ammonium sulfate exposed workers.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

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Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations:


Rhode Island RTK hazardous substances: Ammonium sulfate Pennsylvania RTK: Ammonium sulfate Florida: Ammonium
sulfate Massachusetts RTK: Ammonium sulfate New Jersey: Ammonium sulfate TSCA 8(b) inventory: Ammonium sulfate
Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
R16- Explosive when mixed with oxidizing substances. R36/38- Irritating to eyes and skin. S24/25- Avoid contact with skin and
eyes.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 1
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/10/2005 08:14 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume

p. 5
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet


Water MSDS

Section 1: Chemical Product and Company Identification

Product Name: Water Contact Information:


Catalog Codes: SLW1063 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 7732-18-5 Houston, Texas 77396
RTECS: ZC0110000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Water
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Dihydrogen oxide 1-800-424-9300
Chemical Name: Water International CHEMTREC, call: 1-703-527-3887
Chemical Formula: H2O For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Water 7732-18-5 100

Toxicological Data on Ingredients: Not applicable.

Section 3: Hazards Identification

Potential Acute Health Effects:


Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritating to the eyes. Non-
hazardous in case of ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs. Non-
corrosive to the eyes. Non-corrosive for lungs.
Potential Chronic Health Effects:
Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritating to the eyes.
Non-hazardous in case of ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs.
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.

Section 4: First Aid Measures

Eye Contact: Not applicable.

p. 1
Skin Contact: Not applicable.
Serious Skin Contact: Not available.
Inhalation: Not applicable.
Serious Inhalation: Not available.
Ingestion: Not Applicable
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances: Not Applicable
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill: Mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.

Section 7: Handling and Storage

Precautions: No specific safety phrase has been found applicable for this product.
Storage: Not applicable.

Section 8: Exposure Controls/Personal Protection

Engineering Controls: Not Applicable


Personal Protection: Safety glasses. Lab coat.
Personal Protection in Case of a Large Spill: Not Applicable
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

p. 2
Odor: Odorless.
Taste: Not available.
Molecular Weight: 18.02 g/mole
Color: Colorless.
pH (1% soln/water): 7 [Neutral.]
Boiling Point: 100°C (212°F)
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: 1 (Water = 1)
Vapor Pressure: 2.3 kPa (@ 20°C)
Vapor Density: 0.62 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not applicable
Solubility: Not Applicable

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Not available.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact.


Toxicity to Animals:
LD50: [Rat] - Route: oral; Dose: > 90 ml/kg LC50: Not available.
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans:
Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-hazardous in case of
ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs. Non-corrosive to the eyes. Non-
corrosive for lungs.
Special Remarks on Toxicity to Animals: Not available.

p. 3
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Water


Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
This product is not classified according to the EU regulations. Not applicable.
HMIS (U.S.A.):
Health Hazard: 0
Fire Hazard: 0
Reactivity: 0
Personal Protection: a
National Fire Protection Association (U.S.A.):
Health: 0
Flammability: 0
Reactivity: 0
Specific hazard:

p. 4
Protective Equipment:
Not applicable. Lab coat. Not applicable. Safety glasses.

Section 16: Other Information

References: Not available.


Other Special Considerations: Not available.
Created: 10/10/2005 08:33 PM
Last Updated: 11/01/2010 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

p. 5
ICE MATERIAL SAFETY DATA SHEET N/A=Not Applicable
Prepared by: Regulatory Affairs Dept. (Prepared According to 29 CFR 1910.1200) Effective Date: 8/09 Revision: N/A
SECTION 1-PRODUCT IDENTIFICATION AND SUPPLIER INFORMATION
Manufacturer’s Name: Product Name: Liquid Pretreat De-Icer Supplier’s Name:
Misco Products Corporation Generic Name: Ice melt & Remover
Manufacturer’s Address: Chemical Family: Inhibited Calcium Chloride Blend Supplier’s Address:
1048 Stinson Drive Reading, PA 19605 Formula: Proprietary
Manufacturer’s Phone #: (610) 926-4106 Supplier’s Phone #:
SECTION 2-INGREDIENT INFORMATION
CHEMICAL NAME CAS NO. WT. % PEL TWA-TLV STEL-TLV
Water 7732-18-5 to 100
Calcium Chloride 10043-52-4 25 to 35
Magnesium Chloride 7791-18-6 0 to 5
Urea 57-13-6 0 to 5
Corrosion Inhibitor N/A 0 to 5

SECTION 3-PHYSICAL DATA SECTION 4-FIRE AND EXPLOSION HAZARD DATA


Boiling Point (°F): 252° F. Specific Gravity: 1.332 – 1.335 Flash Point (Method Used): None
Vapor Pressure: 20mm Hg @68°F. Vapor Density (Air=1): >1 Upper Explosion Limit: N/A Lower Explosion Limit: N/A
% Volatile: 80+ pH: 5.0 – 8.0 Extinguishing Media: N/A
Solubility in Water: Complete Evaporation Rate (Water=1): >1 Special Firefighting Procedures: Non Flammable
Physical Description: Clear to amber color with virtually no odor Unusual Fire and Explosion Hazards: N/A
SECTION 5-REACTIVITY DATA
Stability: Stable Hazardous Polymerization: None
Hazards Decomposition Products: Alkaline vapors in a fire. Incompatibility (Materials to Avoid): Strong Acids, oxidizers, Chlorine
SECTION 6-STORAGE AND HANDLING INFORMATION
Keep out of reach of children. For use by trained personnel only. Wear protective gloves and eyewear when handling. Keep container closed during storage. For
institutional and industrial use only. Avoid contact with eyes, skin and clothing. Avoid breathing of vapors or mists. Use in well-ventilated area.
SECTION 7-HEALTH HAZARDS AND FIRST AID SECTION 8-SPECIAL PROTECTION INFORMATION
Effects of Overexposure: Respiratory Protection: Not required under normal use
Skin: May cause irritation with prolonged or repeated contact (dryness, redness) Ventilation Requirements: Not required under normal intended use
Eyes: Eye irritant. May cause conjunctivitis with possible corneal injury. Protective Gloves: Rubber or other chemical resistant.
Inhalation: Mists may be irritating to mucous membranes in the nose, throat, and Eye Protection: Safety glasses or chemical splash goggles.
lungs. Other Protective Equipment: Wear protective outer-wear when danger of mist
Ingestion: Irritating to the mouth and throat. May cause headache, nausea, contact may occur. Protective rubber boots should be worn.
abdominal pain.
First Aid Procedures: SECTION 9-SPILL OR LEAK PROCEDURES
Skin: Flush with water. Seek medical attention if irritation persists. Steps to be taken in Case Material is Released or Spilled: Floors will become
Eyes: Flush with large quantities of water, holding eyelids open. Seek medical slippery. Avoid walking in product. Ventilate area well. Keep unessential
attention immediately. personnel away. Mop up or otherwise absorb and hold disposal. Avoid discharge
Inhalation: Get to fresh air. Seek medical attention if irritation persists. to sewer or open waterways.
Ingestion: Do not induce vomiting. Drink large quantities of water. Seek medical Waste Disposal Method: Any method in accordance with local, state and federal
attention immediately. laws. Best method is to recycle or reuse for intended purpose. Consult local
authorities for disposal in public sewer. Do not dispose of into storm drain, stream,
river or to ground. Rinse container thoroughly before discarding in trash.
SECTION 10-REGULATORY INFORMATION
SARA Title III - Section 311/312 -Hazard Categories: Shipping Information: HMIS Hazardous Materials
No - Fire Hazard FOR CONTAINERS > 1 Gallon : Cleaning Compound Identification System
No - Sudden Release of Pressure Hazard Health 2
No - Reactivity Hazard FOR 1 GALLON CONTAINERS : Cleaning Compound Flammability 0
Yes - Immediate (acute) Health Hazard Reactivity 0
No - Delayed (chronic) Health Hazard FOR CONTAINERS < 1 GALLON : Cleaning Compound Personal Protection B

FOR EMERGENCY MEDICAL OR TRANSPORT INFORMATION: CHEM-TEL, Inc. @ 800-255-3924 (24 hours, 7 days per week)
This product contains the following toxic chemical(s) subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act
of 1986 and of 40 CFR 372.
CAS# Chemical Name Percent by Weight
None
This product contains the following chemical(s) which have been established to be either a carcinogen or suspected carcinogen.
CAS# Chemical Name Percent by Weight
None
SECTION 11-OTHER INFORMATION
This company cannot anticipate all conditions of handling and use of this product. Therefore, this company accepts no responsibility for results obtained by the
application of this information, or the safety and suitability of our products either alone or in combination with other products. It is the responsibility of the user to
provide a safe workplace, using the health and safety information contained herein as a guide. This company will accept no liability for damages or loss incurred from the
improper handling and use of this product
He a lt h 1
0 0
F ir e
1 0
Re a c t iv it y 0
Pe rson a l E
P r o t e c t io n

Material Safety Data Sheet


Potassium Iodide MSDS

Section 1: Chemical Product and Company Identification

Product Name: Potassium Iodide Contact Information:


Catalog Codes: SLP2050, SLP1042, SLP2854 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 7681-11-0 Houston, Texas 77396
RTECS: TT2975000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Potassium Iodide
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: 1-800-424-9300
Chemical Name: Potassium Iodide International CHEMTREC, call: 1-703-527-3887
Chemical Formula: KI For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Potassium Iodide 7681-11-0 100

Toxicological Data on Ingredients: Potassium Iodide LD50: Not available. LC50: Not available. Lowest Published Lethal
Dose: LDL [Mouse] - Route: Oral; Dose: 1862 mg/kg LDL [Rabbit] - Route: Oral; Dose: 916 mg/kg

Section 3: Hazards Identification

Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.
TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female,
Development toxin [POSSIBLE]. The substance may be toxic to thyroid. Repeated or prolonged exposure to the substance
can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:

p. 1
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention if irritation occurs.
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water
may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Some hazardous decomposition products are: Hydrogen Iodide, Oxides of potassium , iodine
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Potassium iodide + Fluorine Perchlorate will explode on contact.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:
Do not breathe dust. Wear suitable protective clothing. If you feel unwell, seek medical attention and show the label when
possible. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, moisture.

p. 2
Storage:
Moisture Sensitive. Light Sensitive. Air SensitiveKeep container tightly closed in light-resistant containers. Keep container in a
cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Deliquescent crystals solid.)


Odor: Odorless.
Taste: Bitter. Saline. (Strong.)
Molecular Weight: 166 g/mole
Color: White.
pH (1% soln/water): Not available.
Boiling Point: 1330°C (2426°F)
Melting Point: 681°C (1257.8°F)
Critical Temperature: Not available.
Specific Gravity: 3.1 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, methanol, acetone.
Solubility:
Easily soluble in cold water, hot water. Soluble in methanol. Partially soluble in acetone.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

p. 3
Instability Temperature: Not available.
Conditions of Instability:
Light, moisture, incompatible materials. It is stable under ordinary conditions of use and storage. On long exposure to air, it
becomes yellow due to release of iodine.
Incompatibility with various substances: Reactive with oxidizing agents, reducing agents, organic materials, metals, acids.
Corrosivity:
Corrosive in presence of steel, of aluminum, of zinc. Non-corrosive in presence of glass, of copper, of stainless steel(304), of
stainless steel(316).
Special Remarks on Reactivity:
Moisture Sensitive. Light Sensitive. Air Sensitive. Air causes decomposition to iodine. Reacts violently with strong oxidizers,
bromotrifluorides, chlorotrifluorides, fluorine perchlorate, metallic salts. Attacks metals in moist environments. Also
incompatible with salts of alkaloids, chloral hydrate, calomel (mercurous chloride), potassium chlorate, tartaric and other
acids, oxidants, diazonium salts, charcoal, ozone, strong reducers, alkali metals, metals (brass, aluminum magnesium, zinc,
cadmium, copper, tin, nickel, steel), metallic salts, organic materials, light.
Special Remarks on Corrosivity:
Incompatible with water, producing a corrosive. Corrosive in all concentrations to most metals, except stainless steel, titanium,
and tantalum.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans:
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. DEVELOPMENTAL TOXICITY: Classified Reproductive
system/toxin/female, Development toxin [POSSIBLE]. May cause damage to the following organs: thyroid.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals:
Lowest Published Lethal Dose: LDL [Mouse] - Route: Oral; Dose: 1862 mg/kg LDL[Rabbit] - Route: Oral; Dose: 916 mg/kg
Special Remarks on Chronic Effects on Humans:
Can cause adverse reproductive efects and birth defects based on animal data. May affect genetic material based on animal
data
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: May cause eye irritation. Inhalation: May cause
respiratory tract and mucous membrane irritation and a productive cough. May cause pulmonary edema and inflammation
of the tonsils. Ingestion: Causes gastrointestinal tract irritation with nausea, vomiting and diarrhea. May affect behavior
(somnolence, muscle weakness), respiration (dyspnea). Serum-sickness type of hypersensitivity such as fever, arthralgia,
lymph node enlargement , and eosinophilia may appear. Thrombotic thrombocytopenic purpura, and fatal periarteritis nodosa
attributed to hypersensitivity to iodide has been described. Chronic Potential Health Effects: Can lead to iodism characterized
by salivation, nasal discharge, sneezing, conjunctivitis, fever, headache, laryngitis, bronchitis, stomatits, parotitis, anemia, and
skin rashes. Chronic ingestion may also affect metabolism (anorexia), and thyroid gland (hypothyroidism, goiter). Furthermore,
chronic ingestion of iodides (in animals) during pregnancy has resulted in fetal deaths, severe goiter and cretinoid appearance
of the newborn.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.

p. 4
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Potassium Iodide


Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
DSCL (EEC):
Not available Not applicable.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Safety glasses.

Section 16: Other Information

References: Not available.

p. 5
Other Special Considerations: Not available.
Created: 10/11/2005 12:21 PM
Last Updated: 11/01/2010 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

p. 6
SAFETY DATA SHEET
Creation Date 09-Apr-2010 Revision Date 26-Dec-2021 Revision Number 5

1. Identification
Product Name Copper(II) sulfate

Cat No. : AC422870000; AC422870025; AC422870050; AC422870100;


AC422871000; AC422875000
CAS No 7758-98-7
Synonyms Cupric sulfate anhydrous; Cupric sulfate; Copper monosulfate

Recommended Use Laboratory chemicals.


Uses advised against Food, drug, pesticide or biocidal product use.

Details of the supplier of the safety data sheet

Company
Fisher Scientific Company Acros Organics
One Reagent Lane One Reagent Lane
Fair Lawn, NJ 07410 Fair Lawn, NJ 07410
Tel: (201) 796-7100

Emergency Telephone Number For information US call: 001-800-ACROS-01 / Europe call: +32 14 57 52 11
Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99
CHEMTREC Tel. No.US:001-800-424-9300 / Europe:001-703-527-3887

2. Hazard(s) identification
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Acute oral toxicity Category 4


Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2

Label Elements

Signal Word
Warning

Hazard Statements
Harmful if swallowed
Causes skin irritation

______________________________________________________________________________________________

Page 1 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________

Causes serious eye irritation

Precautionary Statements
Prevention
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Skin
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Ingestion
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Very toxic to aquatic life with long lasting effects

3. Composition/Information on Ingredients
Component CAS No Weight %
Cupric sulfate 7758-98-7 98

4. First-aid measures
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get
medical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention if
symptoms occur.

Inhalation Remove to fresh air. Do not use mouth-to-mouth method if victim ingested or inhaled the
substance; give artificial respiration with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device. Get medical attention. If not breathing,
give artificial respiration.

Ingestion Do NOT induce vomiting. Call a physician or poison control center immediately.

Most important symptoms and No information available.


effects
Notes to Physician Treat symptomatically

5. Fire-fighting measures

______________________________________________________________________________________________

Page 2 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________

Suitable Extinguishing Media Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.

Unsuitable Extinguishing Media No information available

Flash Point No information available


Method - No information available

Autoignition Temperature No information available


Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available

Specific Hazards Arising from the Chemical


Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Do not
allow run-off from fire-fighting to enter drains or water courses.

Hazardous Combustion Products


Toxic fumes. Sulfur oxides. Copper oxides.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

NFPA
Health Flammability Instability Physical hazards
2 0 1 N/A

6. Accidental release measures


Personal Precautions Use personal protective equipment as required. Ensure adequate ventilation. Avoid dust
formation. Avoid contact with skin, eyes or clothing.
Environmental Precautions Do not flush into surface water or sanitary sewer system. Do not allow material to
contaminate ground water system. Prevent product from entering drains. Local authorities
should be advised if significant spillages cannot be contained. Should not be released into
the environment.

Methods for Containment and Clean Sweep up and shovel into suitable containers for disposal. Avoid dust formation.
Up

7. Handling and storage


Handling Wear personal protective equipment/face protection. Ensure adequate ventilation. Avoid
dust formation. Avoid contact with skin, eyes or clothing. Avoid ingestion and inhalation.

Storage. Keep containers tightly closed in a dry, cool and well-ventilated place. Store under an inert
atmosphere. Incompatible Materials. Strong bases. Metals. Alkali metals. Finely powdered
metals.

8. Exposure controls / personal protection


Exposure Guidelines

Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA)
Cupric sulfate TWA: 1 mg/m3 IDLH: 100 mg/m3
TWA: 1 mg/m3

Legend

ACGIH - American Conference of Governmental Industrial Hygienists


NIOSH IDLH: NIOSH - National Institute for Occupational Safety and Health

______________________________________________________________________________________________

Page 3 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________

Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations
and safety showers are close to the workstation location.

Personal Protective Equipment

Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.

Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

9. Physical and chemical properties


Physical State Powder Solid
Appearance Grey
Odor Odorless
Odor Threshold No information available
pH 3.5-4.5
Melting Point/Range 200 °C / 392 °F
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity 3.6
Solubility 203 g/L (20°C)
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula Cu O4 S
Molecular Weight 159.6

10. Stability and reactivity


Reactive Hazard None known, based on information available

Stability Stable under normal conditions. Hygroscopic.

Conditions to Avoid Avoid dust formation. Incompatible products. Excess heat. Exposure to moisture.

Incompatible Materials Strong bases, Metals, Alkali metals, Finely powdered metals

Hazardous Decomposition Products Toxic fumes, Sulfur oxides, Copper oxides

Hazardous Polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

______________________________________________________________________________________________

Page 4 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________

11. Toxicological information


Acute Toxicity

Product Information
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
Cupric sulfate LD50 = 481 mg/kg ( Rat ) LD50 > 1000 mg/kg ( Rabbit ) Not listed
Toxicologically Synergistic No information available
Products
Delayed and immediate effects as well as chronic effects from short and long-term exposure

Irritation Irritating to eyes and skin

Sensitization No information available

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Component CAS No IARC NTP ACGIH OSHA Mexico


Cupric sulfate 7758-98-7 Not listed Not listed Not listed Not listed Not listed
Mutagenic Effects No information available

Reproductive Effects No information available.

Developmental Effects No information available.

Teratogenicity No information available.

STOT - single exposure None known


STOT - repeated exposure None known

Aspiration hazard No information available

Symptoms / effects,both acute and No information available


delayed

Endocrine Disruptor Information No information available

Other Adverse Effects The toxicological properties have not been fully investigated.

12. Ecological information


Ecotoxicity
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do not allow material to
contaminate ground water system. The product contains following substances which are hazardous for the environment.

Component Freshwater Algae Freshwater Fish Microtox Water Flea


Cupric sulfate Not listed LC50: = 0.1 mg/L, 96h Not listed EC50 = 0.024 mg/L/48h
(Oncorhynchus mykiss)

Persistence and Degradability May persist based on information available.

Bioaccumulation/ Accumulation No information available.

Mobility Will likely be mobile in the environment due to its water solubility.

13. Disposal considerations


Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.

______________________________________________________________________________________________

Page 5 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________

14. Transport information


DOT
UN-No UN3077
Proper Shipping Name Environmentally hazardous substances, solid, n.o.s.
Technical Name Cupric sulfate
Hazard Class 9
Packing Group III
TDG
UN-No UN3077
Proper Shipping Name Environmentally hazardous substances, solid, n.o.s.
Hazard Class 9
Packing Group III
IATA
UN-No UN3077
Proper Shipping Name Environmentally hazardous substances, solid, n.o.s.
Hazard Class 9
Packing Group III
IMDG/IMO
UN-No UN3077
Proper Shipping Name Environmentally hazardous substances, solid, n.o.s.
Hazard Class 9
Packing Group III
15. Regulatory information
United States of America Inventory

Component CAS No TSCA TSCA Inventory notification - TSCA - EPA Regulatory


Active-Inactive Flags
Cupric sulfate 7758-98-7 X ACTIVE -

Legend:
TSCA US EPA (TSCA) - Toxic Substances Control Act, (40 CFR Part 710)
X - Listed
'-' - Not Listed

TSCA 12(b) - Notices of Export Not applicable

International Inventories
Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP), Philippines (PICCS), Japan (ENCS), Japan (ISHL), Australia (AICS), China (IECSC), Korea
(KECL).

Component CAS No DSL NDSL EINECS PICCS ENCS ISHL AICS IECSC KECL
Cupric sulfate 7758-98-7 X - 231-847-6 X X X X X KE-08956

KECL - NIER number or KE number (http://ncis.nier.go.kr/en/main.do)

U.S. Federal Regulations

SARA 313
Component CAS No Weight % SARA 313 - Threshold
Values %
Cupric sulfate 7758-98-7 98 1.0

SARA 311/312 Hazard Categories See section 2 for more information

CWA (Clean Water Act)


Component CWA - Hazardous CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants
Substances Quantities
Cupric sulfate X 10 lb X -

______________________________________________________________________________________________

Page 6 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________

Clean Air Act Not applicable

OSHA - Occupational Safety and Not applicable


Health Administration

CERCLA This material, as supplied, contains one or more substances regulated as a hazardous
substance under the Comprehensive Environmental Response Compensation and Liability
Act (CERCLA) (40 CFR 302)

Component Hazardous Substances RQs CERCLA EHS RQs


Cupric sulfate 10 lb -

California Proposition 65 This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know


Regulations

Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island


Cupric sulfate X X X - -

U.S. Department of Transportation


Reportable Quantity (RQ): Y
DOT Marine Pollutant N
DOT Severe Marine Pollutant Y

U.S. Department of Homeland This product does not contain any DHS chemicals.
Security

Other International Regulations

Mexico - Grade No information available

Authorisation/Restrictions according to EU REACH

Component REACH (1907/2006) - Annex XIV - REACH (1907/2006) - Annex XVII - REACH Regulation (EC
Substances Subject to Restrictions on Certain Dangerous 1907/2006) article 59 - Candidate
Authorization Substances List of Substances of Very High
Concern (SVHC)
Cupric sulfate - Use restricted. See item 75. -
(see link for restriction details)

https://echa.europa.eu/substances-restricted-under-reach

Safety, health and environmental regulations/legislation specific for the substance or mixture

Component CAS No OECD HPV Persistent Organic Ozone Depletion Restriction of


Pollutant Potential Hazardous
Substances (RoHS)
Cupric sulfate 7758-98-7 Listed Not applicable Not applicable Not applicable

Component CAS No Seveso III Directive Seveso III Directive Rotterdam Basel Convention
(2012/18/EC) - (2012/18/EC) - Convention (PIC) (Hazardous Waste)
Qualifying Quantities Qualifying Quantities
for Major Accident for Safety Report
Notification Requirements
Cupric sulfate 7758-98-7 Not applicable Not applicable Not applicable Annex I - Y22

16. Other information


Prepared By Regulatory Affairs

______________________________________________________________________________________________

Page 7 / 8
Copper(II) sulfate Revision Date 26-Dec-2021
______________________________________________________________________________________________

Thermo Fisher Scientific


Email: EMSDS.RA@thermofisher.com

Creation Date 09-Apr-2010


Revision Date 26-Dec-2021
Print Date 26-Dec-2021
Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standard
replacing the current legislation under 29 CFR 1910.1200 to align with the Globally
Harmonized System of Classification and Labeling of Chemicals (GHS).

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text

End of SDS

______________________________________________________________________________________________

Page 8 / 8
Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 1 of 7
Rhodamine B, 1%

SECTION 1 : Identification of the substance/mixture and of the supplier


Product name : Rhodamine B, 1%
Manufacturer/Supplier Trade name:
Manufacturer/Supplier Article number: S25786
Recommended uses of the product and uses restrictions on use:
Manufacturer Details:
AquaPhoenix Scientific
9 Barnhart Drive, Hanover, PA 17331

Supplier Details:
Fisher Science Education
15 Jet View Drive, Rochester, NY 14624

Emergency telephone number:


Fisher Science Education Emergency Telephone No.: 800-535-5053

SECTION 2 : Hazards identification

Classification of the substance or mixture:

Irritant
Acute toxicity (oral, dermal, inhalation), category 4
Eye irritation, category 2A

Environmentally Damaging
Acute hazards to the aquatic environment, category 3
Chronic hazards to the aquatic environment, category 3

Acute Oral Tox. 4


Aquatic Acute 3
Aquatic Chronic 3
Eye Irritant Category 2A

Signal word :Warning

Hazard statements:
Harmful if swallowed
Causes serious eye irritation
Harmful to aquatic life with long lasting effects
Precautionary statements:
If medical advice is needed, have product container or label at hand
Keep out of reach of children
Read label before use
Do not eat, drink or smoke when using this product
Wash skin thoroughly after handling
Avoid release to the environment
Wear protective gloves/protective clothing/eye protection/face protection
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
Continue rinsing

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Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 2 of 7
Rhodamine B, 1%

Immediately call a POISON CENTER or doctor/physician


Rinse mouth
Dispose of contents and container to an approved waste disposal plant

Combustible Dust Hazard: :


May form combustible dust concentrations in air (during processing).

Other Non-GHS Classification:


WHMIS

D2B

NFPA/HMIS

NFPA SCALE (0-4) HMIS RATINGS (0-4)

SECTION 3 : Composition/information on ingredients

Ingredients:

CAS 81-88-9 Rhodamine B 1%

CAS 7732-18-5 DI Water 99 %

Percentages are by weight

SECTION 4 : First aid measures


Description of first aid measures
After inhalation: Loosen clothing as necessary and position individual in a comfortable position.Move exposed
to fresh air. Give artificial respiration if necessary. If breathing is difficult give oxygen.Get medical assistance if
cough or other symptoms appear.
After skin contact: Rinse/flush exposed skin gently using soap and water for 15-20 minutes.Seek medical
advice if discomfort or irritation persists.
After eye contact: Protect unexposed eye. Rinse/flush exposed eye(s) gently using water for 15-20 minutes.
Remove contact lens(es) if able to do so during rinsing. Immediately get medical assistance if irritation occurs.
After swallowing: Rinse mouth thoroughly. Do not induce vomiting. Have exposed individual drink sips of
water. Seek medical attention if irritation, discomfort or vomiting persists.Never give anything by mouth to an
unconscious person.

Most important symptoms and effects, both acute and delayed:

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Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 3 of 7
Rhodamine B, 1%

Irritation, Nausea,Headache, Shortness of breath.;


Indication of any immediate medical attention and special treatment needed:
If seeking medical attention, provide SDS document to physician.Physician should treat symptomatically.

SECTION 5 : Firefighting measures


Extinguishing media
Suitable extinguishing agents: Use appropriate fire suppression agents for adjacent combustible materials
or sources of ignition. Use water, dry chemical, chemical foam, carbon dioxide, or alcohol-resistant foam.
For safety reasons unsuitable extinguishing agents:
Special hazards arising from the substance or mixture:
Combustion products may include carbon oxides or other toxic vapors.Thermal decomposition can lead to
release of irritating gases and vapors.
Advice for firefighters:
Protective equipment: Use NIOSH-approved respiratory protection/breathing apparatus.
Additional information (precautions): Move product containers away from fire or keep cool with water
spray as a protective measure, where feasible.Use spark-proof tools and explosion-proof equipment.Avoid
generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source
is a potential dust explosion hazard.Avoid inhaling gases, fumes, dust, mist, vapor, and aerosols.Avoid contact
with skin, eyes, and clothing.

SECTION 6 : Accidental release measures


Personal precautions, protective equipment and emergency procedures:
Wear protective equipment. Use spark-proof tools and explosion-proof equipment.Ensure that air-handling
systems are operational.Ensure adequate ventilation.
Environmental precautions:
Prevent from reaching drains, sewer or waterway. Collect contaminated soil for characterization per Section 13.
Should not be released into environment.
Methods and material for containment and cleaning up:
Keep in suitable closed containers for disposal.Wear protective eyeware, gloves, and clothing. Refer to Section
8.Always obey local regulations.Dust deposits should not be allowed to accumulate on surfaces, as these may
form an explosive mixture if they are released into the atmosphere in sufficient concentration. Avoid dispersal
of dust in the air (i.e., clearing dust surfaces with compressed air). Collect solids in powder form using vacuum
with (HEPA filter). Evacuate personnel to safe areas.
Reference to other sections:

SECTION 7 : Handling and storage


Precautions for safe handling:
Minimize dust generation and accumulation. Follow good hygiene procedures when handling chemical
materials. Refer to Section 8.Remove contaminated clothing and wash before reuse.Do not eat, drink, smoke,
or use personal products when handling chemical substances. Avoid contact with eyes, skin, and clothing.
Conditions for safe storage, including any incompatibilities:
Store away from incompatible materials.Protect from freezing and physical damage.Keep away from food and
beverages.Provide ventilation for containers. Avoid storage near extreme heat, ignition sources or open flame.
Store in cool, dry conditions in well sealed containers. Store with like hazards

SECTION 8 : Exposure controls/personal protection

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Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 4 of 7
Rhodamine B, 1%

Control Parameters: , , OSHA PEL TWA (Total Dust) 15 mg/m3 (50 mppcf*)
, , ACGIH TLV TWA (inhalable particles) 10 mg/m3
Appropriate Engineering controls: Emergency eye wash fountains and safety showers should be available in
the immediate vicinity of use/handling.Provide exhaust ventilation or
other engineering controls to keep the airborne concentrations of vapor
or dusts (total/respirable) below the applicable workplace exposure limits
(Occupational Exposure Limits-OELs) indicated above.It is recommended
that all dust control equipment such as local exhaust ventilation and
material transport systems involved in handling of this product contain
explosion relief vents or an explosion suppression system or an oxygen
deficient environment.Ensure that dust-handling systems (such as
exhaust ducts, dust collectors, vessels, and processing equipment) are
designed in a manner to prevent the escape of dust into the work area
(i.e., there is no leakage from the equipment).Normal ventilation is
adequate.
Respiratory protection: Not required under normal conditions of use. Where risk assessment
shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a
backup to engineering controls.When necessary use NIOSH approved
breathing equipment.
Protection of skin: Select glove material impermeable and resistant to the substance.Select
glove material based on rates of diffusion and degradation.Dispose of
contaminated gloves after use in accordance with applicable laws and
good laboratory practices.Use proper glove removal technique without
touching outer surface. Avoid skin contact with used gloves.Wear
protective clothing.
Eye protection: Wear equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN
166(EU).Safety glasses or goggles are appropriate eye protection.
General hygienic measures: Perform routine housekeeping.Wash hands before breaks and at the end
of work.Avoid contact with skin, eyes, and clothing.Before wearing wash
contaminated clothing.

SECTION 9 : Physical and chemical properties

Appearance (physical Explosion limit lower: Not determined


Reddish-violet liquid
state,color): Explosion limit upper: Not determined

Odor: odorless Vapor pressure: Not determined

Odor threshold: Not determined Vapor density: Not determined

pH-value: Not Determined Relative density: Not determined

Melting/Freezing point: Not Determined Solubilities: soluble

Boiling point/Boiling Partition coefficient (n-


Not determined Not determined
range: octanol/water):

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Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 5 of 7
Rhodamine B, 1%

Flash point (closed Auto/Self-ignition


Not determined Not determined
cup): temperature:

Decomposition
Evaporation rate: Not determined Not determined
temperature:

Flammability a. Kinematic:Not determined


Not determined Viscosity:
(solid,gaseous): b. Dynamic: Not determined

Density: Not determined

SECTION 10 : Stability and reactivity

Reactivity:Nonreactive under normal conditions.


Chemical stability:Stable under normal conditions.
Possible hazardous reactions:None under normal processing
Conditions to avoid:Incompatible Materials.excess heat.Dust generation.
Incompatible materials:Oxidizing agents.Reducing agents.
Hazardous decomposition products:Carbon oxides.Nitrogen oxides.Hydrogen chloride

SECTION 11 : Toxicological information

Acute Toxicity:

Oral: 81-88-9 (Rhodamine B) LD50 Rat: 500 mg/kg

Chronic Toxicity: No additional information.

Corrosion Irritation:

Dermal: 81-88-9 (Rhodamine B) Rabbit: No skin irritation

Ocular: 81-88-9 (Rhodamine B) Rabbit: Severe eye irritation

Sensitization: No additional information.

Single Target Organ (STOT): No additional information.

Numerical Measures: No additional information.

IARC:: Group 3: Not classifiable as to its


carcinogenicity to humans (9-(2-
Carcinogenicity:
Carboxyphenyl)-3,6-
bis(diethylamino)xanthylium chloride)

Mutagenicity: No additional information.

Reproductive Toxicity: No additional information.

SECTION 12 : Ecological information

Ecotoxicity
Fish LC50 - Oncorhynchus mykiss (rainbow trout) - 217 mg/l - 96 h: 81-88-9 (Rhodamine B)
Invertebrates EC50 - Daphnia magna (Water flea) - 22.9 mg/l - 48 h: 81-88-9 (Rhodamine B)
Persistence and degradability: Not readily biodegradable.
Bioaccumulative potential: Bioconcentration factor (BCF): < 0.2

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Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 6 of 7
Rhodamine B, 1%

Mobility in soil:
Other adverse effects:

SECTION 13 : Disposal considerations

Waste disposal recommendations:


Contact a licensed professional waste disposal service to dispose of this material.Dispose of empty containers
as unused product.Product or containers must not be disposed with household garbage.It is the responsibility of
the waste generator to properly characterize all waste materials according to applicable regulatory entities (US
40CFR262.11).Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste
regulations. Ensure complete and accurate classification.

SECTION 14 : Transport information

UN-Number
Not Regulated.
UN proper shipping name
Not Regulated.
Transport hazard class(es)
Packing group:Not Regulated
Environmental hazard:
Transport in bulk:
Special precautions for user:

SECTION 15 : Regulatory information

United States (USA)


SARA Section 311/312 (Specific toxic chemical listings):
Acute
SARA Section 313 (Specific toxic chemical listings):
81-88-9 9-(2-Carboxyphenyl)-3,6-bis(diethylamino)xanthylium chloride
RCRA (hazardous waste code):
None of the ingredients is listed
TSCA (Toxic Substances Control Act):
All ingredients are listed.
CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act):
None of the ingredients is listed

Proposition 65 (California):

Chemicals known to cause cancer:


81-88-9 9-(2-Carboxyphenyl)-3,6-bis(diethylamino)xanthylium chloride
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed

Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com


Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 10.24.2014 Page 7 of 7
Rhodamine B, 1%

Chemicals known to cause developmental toxicity:


None of the ingredients is listed

Canada

Canadian Domestic Substances List (DSL):


All ingredients are listed.
Canadian NPRI Ingredient Disclosure list (limit 0.1%):
None of the ingredients is listed
Canadian NPRI Ingredient Disclosure list (limit 1%):
81-88-9 9-(2-Carboxyphenyl)-3,6-bis(diethylamino)xanthylium chloride

SECTION 16 : Other information

This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the
SDS contains all the information required by the Controlled Products Regulations.Note:. The responsibility to
provide a safe workplace remains with the user.The user should consider the health hazards and safety information
contained herein as a guide and should take those precautions required in an individual operation to instruct
employees and develop work practice procedures for a safe work environment.The information contained herein is,
to the best of our knowledge and belief, accurate.However, since the conditions of handling and use are beyond
our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this
material.It is the responsibility of the user to comply with all applicable laws and regulations applicable to this
material.
GHS Full Text Phrases:

Abbreviations and acronyms:


IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
CFR: Code of Federal Regulations (USA)
SARA: Superfund Amendments and Reauthorization Act (USA)
RCRA: Resource Conservation and Recovery Act (USA)
TSCA: Toxic Substances Control Act (USA)
NPRI: National Pollutant Release Inventory (Canada)
DOT: US Department of Transportation

Effective date : 10.24.2014


Last updated : 03.19.2015

Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com


He a lt h 1
0 0
F ir e
1 0
Re a c t iv it y 0
Pe rson a l E
P r o t e c t io n

Material Safety Data Sheet


Sand MSDS

Section 1: Chemical Product and Company Identification

Product Name: Sand Contact Information:


Catalog Codes: SLS3064 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 14808-60-7 Houston, Texas 77396
RTECS: VV73330000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Quartz
Order Online: ScienceLab.com
CI#: Not applicable.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Sand; Sea Sand 1-800-424-9300
Chemical Name: Not available. International CHEMTREC, call: 1-703-527-3887
Chemical Formula: SiO2 For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients


Composition:

Name CAS # % by Weight


Feldspars (Ca, K, Na) Alluminum Silicates
Quartz (Crystalline Silica) 14808-60-7

Toxicological Data on Ingredients: Sand LD50: Not available. LC50: Not available. Quartz: LCL (Human) - Route:
Inhalation; Dose: 300 ug/m3/10Y.

Section 3: Hazards Identification

Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC. Classified A2 (Suspected for human.) by ACGIH.
MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not
available. The substance may be toxic to lungs, upper respiratory tract. Repeated or prolonged exposure to the substance can
produce target organs damage.

Section 4: First Aid Measures

p. 1
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention if irritation occurs.
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.


Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Keep container tightly closed.
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a
concentration level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep locked up.. Do not breathe dust. Wear suitable protective clothing. If you feel unwell, seek medical attention and show
the label when possible. Keep away from incompatibles such as oxidizing agents, alkalis.

p. 2
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24°C (75.2°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 0.05 (mg/m3) from ACGIH (TLV) [United States] Respirable [Quartz or Crystalline Silica] TWA: 0.05 (mg/m3) from
NIOSH Respirable. [Quartz or Crystalline Silica]Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Granular solid.)


Odor: Odorless.
Taste: Tasteless.
Molecular Weight: Not available.
Color: Amber. Grey.
pH (1% soln/water): Not applicable.
Boiling Point: Not available.
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: 1.8 to 2.5+ (depending on mineral compostion) (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not available.
Solubility: Insoluble in cold water, hot water, methanol, diethyl ether, n-octanol.

Section 10: Stability and Reactivity Data

Stability: The product is stable.


Instability Temperature: Not available.

p. 3
Conditions of Instability: Incompatibles
Incompatibility with various substances: Reactive with oxidizing agents, alkalis.
Corrosivity: Not available.
Special Remarks on Reactivity:
Incompatible with oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide, oxygen difluroide. When exposed
to high temperature quartz can change crystalline structure to form tridymite (above 870 C) or crystobalite (above 1470 C).
Soluble in hydrofluoric acid and produces a corrosive gas - silicon tetrafluoride. Quartz is attacked by strong alkalis and
hydrofluoric acid.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.


Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC. Classified A2 (Suspected for human.) by ACGIH. May
cause damage to the following organs: lungs, upper respiratory tract.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
May contain more than 1% quartz and may cause cancer (tumorigenic). Quartz has been identified by IARC as a class 1
carcinogen.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: No adverse health effects expected. Eyes: May cause eye irritation. Ingestion: No
adverse health effects expected. Inhalation: Affects respiration and irritates respiratory tract. Acute pneumoconiosis from
overwhelming exposure to silica dust has occurred. Coughing and irritation of throat are early symptoms. Inhalation of quartz
is classified as a human carcinogen. Risk of cancer depends upon duration and level of exposure. May also affect liver.
Chronic exposure can also cause silicosis, a form of lung scaring that can cause shortness of breath, reduced lung function.
May also affect blood. Aggravation of Pre-existing Conditions: Inhalation may increase the progression of tuberculosis;
susceptibility is apparently not inceased. Persons with impaired respiratory function may be more susceptible to the effects of
this substance. Smoking can increase the risk of lung injury. Material is irritating to mucous membranes and upper respiratory
tract.

Section 12: Ecological Information

Ecotoxicity: Not available.


BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

p. 4
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).


Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations:


California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer,
birth defects or other reproductive harm, which would require a warning under the statute: Quartz California prop. 65: This
product contains the following ingredients for which the State of California has found to cause cancer which would require a
warning under the statute: Quartz TSCA 8(b) inventory: Quartz
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
R45- May cause cancer. S2- Keep out of the reach of children. S53- Avoid exposure - obtain special instructions before use.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.

Section 16: Other Information

References:
-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.
Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of
Chemical Safety Data, Edition II.
Other Special Considerations: Not available.
Created: 10/09/2005 06:23 PM

p. 5
Last Updated: 11/01/2010 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

p. 6
Tata Chemicals Ltd. MSDS – CEMENT

SAFETY DATA SHEET (SDS)


Name of chemical: CEMENT

1. PRODUCT IDENTIFICATION / COMPANY ADDRESS


Trade Name CEMENT Common CEMENT Synonyms Portland cement.
Name Also known as
hydraulic cement
Company Name / Address / Tata Chemicals Limited, Mithapur
Phone / Fax District: Devbhoomi Dwarka (Gujarat) 361 345 INDIA
Contact in case of Emergency Only:
+91(02892 675802 /03 )
Contact Person :+91 9227676113 Mr. Devendra Thakur

Chemical Name CEMENT

2. HAZARD IDENTIFICATION
Hazard Classification ACGIH TLV-
NIOSH REL
OSHA PEL TWA
Hazardous Substances (8-Hour
(8-Hour TWA) (1995–1996)
TWA)
(8-Hour TWA)

Portland Cement Clinker


50 million 10mg total
(CAS#65997-15-1) 3 3
particles/ft dust/m
Nominal 95% by weight

Calcium sulphate 5 mg
(CAS#7778-18-9) respirable dust
/m
3 10 mg total
[Gypsum (CAS#13397- 3
dust/m
24-5)] 10 mg total
3
Nominal 5% by weight dust / m

Calcium Oxide
(CAS#1306-78-8) 3 3
5 mg / m 2 mg / m
(Free Lime) < 4% by
weight

Magnesium Oxide (CAS


15 mg total 10 mg total dust
#1309-48-4) < 5% by 3 3
dust / m /m
weight

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Tata Chemicals Ltd. MSDS – CEMENT
10 mg of
0.10 mg 0.05 mg
Crystalline silica respirable dust
3 respirable respirable
(CAS#14808-60-7 /m 3 3
quartz / m quartz / m
(%SiO2+2)

LABEL ELEMENTS
Signal word Danger

Hazard statement

Precautionary statement

3. COMPOSITION / INFORMATION AND INGREDIENTS


Structural Mainly mixture of: Chemical Family Calcium compounds
Formula 3 CaO-SiO2,2CaO-SiO2, Molecular weight
3CaO-Al2O3,4CaO-Al2O3
Fe2O3-CaSO4. Contains less
than 1 % crystalline Silica.

CAS No Molecular Formula 3 CaO-SiO2,2CaO-SiO2,


3CaO-Al2O3,4CaO-Al2O3
Fe2O3-CaSO4.

Name Product identifier % Classification

Cement 100%

4. FIRST AID MEASURE


Ingestion Do not induce vomiting. Wash out mouth with water and give patient plenty of
water to drink, Seek medical help

Inhalation Move the person to a non-polluted area. The dust in the throat and nasal ducts
must be removed immediately. Consult a physician if the irritation persists.

Eyes A speedy response is essential in order to avoid permanent damage to the


eyes. Wash eyes immediately with plenty of clean water for at least 15 minutes
and seek medical advice without delay.

Skin Wash the affected area thoroughly with soap and water before continuing. If
irritation, pain or other skin trouble occurs, seek medical advice. Clothing
contaminated by wet cement, concrete or mortar should be removed and
washed thoroughly before use.

Antidote

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Tata Chemicals Ltd. MSDS – CEMENT
Most important Eye Contact- Eye contact with cement (dry or wet) may cause serious and
symptoms/ effects, potentially irreversible injuries.
acute and or delayed Inhalation- Frequent inhalation of large quantities of cement dust over a long
period of time increases the risk of developing lung diseases.
Skin contact- Cement may have an irritating effect on moist skin (due to
transpiration or humidity) after prolonged contact. Prolonged skin contact with
wet cement or fresh concrete may causes serious burns because they develop
without pain being felt (for example when kneeling in-fresh concrete even when
wearing trousers). Repeated skin contact with wet cement may cause contact
dermatitis.
Ingestion- No Relevant routes of entry, only by accident

Indication of
immediate medical
attention and special
treatment needed

5. FIRE FIGHTING MEASURES


Fire extinguishing In case of fire in adjacent areas, any suitable fire-extinguishing media may be
media used.

Hazardous Cement is non-flammable, non-combustible and may not cause or maintain


decomposition combustion processes of other materials.
products
Special fire fighting No special instruction
procedure
Precaution to Fire
Fighters

6. ACCIDENTAL RELEASE MEASURES


Personal precaution ● Avoid contact with eyes and skin, do not inhale the dust. Use personal
protection equipment, as mentioned under point number 8, No special
procedures are necessary.

Precautions for the Do not attempt to wash Portland cement down drains. Dispose of waste
environment material according to local, state and federal regulations.

Clean up method ● Recover the spillage in a dry state if possible. Minimize generation of
airborne dust. The product can be slurred by the addition of water but will
subsequently set as a hard material.
● Do not wash cement down sewage and drainage system

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Tata Chemicals Ltd. MSDS – CEMENT
7. HANDLING AND STORAGE

General ● Do not handle or store near food, drinks or tobacco products.


precaution ● Bagged cement used in open mixers: First put the water and then carefully add the
cement.
● Do not pour it from a great height. Mix slowly and carefully. Do not press the
empty bags, except if you put them in a clean bag.
● Carry the bags carefully to avoid straining and bruising your back, arms, shoulders
and legs. Load the bags carefully and use suitable control measures.

Personal Refer to Section 8.


protection
Storage ● Packed products should be stored in unopened bags clear of the ground in cool,
dry conditions and protected from excessive draught in order to avoid degradation
of quality.
● Bags should be stacked in a stable manner.

Incompatibilities Moisture (Water). Keep away from unintentional contact with water.

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Personal protection

Skin • Chemical protective gloves, gum Eyes • Wear appropriate protective


boots, and/or other chemical face shield and eyeglasses or
protective clothing to prevent all chemical safety goggles.
possible skin contact.
• A chemical protective acid-resistant
full-body encapsulating suit and
respiratory protection may be
required in some operations.
• Have a safety shower/eye-wash
fountain readily available in the
immediate work area.

Respiration • Use cartridge type gas mask to Other


evacuate from area.
• To attend emergency wear self-
contained breathing apparatus or
supplied airline.

Exposure limits
TLV-TWA NA TLV-STEL NA
Appropriate Use local exhaust or general dilution ventilation to control exposure below
Engineering applicable limits.
Control

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Tata Chemicals Ltd. MSDS – CEMENT
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Solid grey Molecular Specific No data
particles Weight gravity available

Odour/Odor Odorless Flash Point Not pH/ Acidity 11-13.5


o Pertinent
threshold C (in saturated
water solution,
T = 25°C):

Auto Ignition Not Pertinent Boiling Point Not Melting


Temp. oC o
C @ 760 mm Pertinent Point oC
Hg
Vapor Press. 1.41 kPa Vapour Water Slightly
Mm Hg @ 20 (10.6 mm Hg) Density Solubility @ Soluble
o
C at 20 ºC 20 oC
LEL % UEL % % Volatile

Evaporation Viscosity @ PH
rate 25 oC
Octanol / No data No data
Water Available available
Partition
Coefficient

10. STABILITY AND REACTIVITY

Chemical Dry cements are chemically Possibility of Will not spontaneously


Stability stable Hazardous occur. Adding water results
reaction in hydration and produces
(caustic) calcium hydroxide.

Hazardous Cement does not decompose in Incompatible Wet Portland cement is


Reactions/ any hazardous substances Materials alkaline. As such it is
Decomposition incompatible with acids,
products ammonium salts and
aluminum metal.

Condition to If stored appropriately dry cements are stable and compatible with most building
avoid materials. When mixed with water they cure and form a stable mixture which may
not react with the environment.
Presence of moisture during storage may cause lumps and product quality loss.
Avoid uncontrolled application of aluminium powder with wet cement as it liberates
hydrogen.

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Tata Chemicals Ltd. MSDS – CEMENT
11. TOXICOLOGICAL INFORMATION
Routes of Inhalation.
exposure

LD50 (oral / ---- LD50 (dermal/ LC50 (inhalation / ----


rats) mg/kg rats) mg/kg rats)

Target Organ lungs


Effects

Symptoms related to physical, chemical &


toxicological characteristics

12. ECOLOGICAL INFORMATION


Mobility in No data available
Soil

Persistence No data available


and
degradability
Bio No data available
accumulative
Potential
Effects on Large quantity of cement in water can raise pH and therefore can be toxic to water life
fish under certain circumstances.
(Ecotoxicity)
Effects on No recognized unusual toxicity to plants or animals.
birds
Effects on No
bees

13. DISPOSAL CONSIDERATIONS


Waste bags must be disposed of in accordance with federal, state and local environmental control
regulations

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Tata Chemicals Ltd. MSDS – CEMENT
14. TRANSPORT INFORMATION
UN No. …… IMDG No. ---
Shipping Name cement Hazard class ---
Packing group --- Hazard Sub class ---
Marine Pollutant --- Labels required ---
Warning Statement ---
Packaging /
Precaution
Shipping Marking

15. REGULATORY INFORMATION


LABELING:

PHRASES R:
R37/38 Irritates respiratory system and skin
R41 Risk of serious damage to eyes
R43 Possible sensitization in case of skin contact.

PHRASES S:
S 2 Keep out of the reach of children
S22 Do not breathe dust
S24/25 Avoid contact with eyes and skin
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection
S46 If swallowed, seek medical advice immediately and show this container or label

16. OTHER INFORMATION

The information provided in this Material Safety data sheet is correct to the best of our knowledge,
information and belief at the date of its publication.The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with other
materials

This data belongs to TATA Chemical Ltd. All rights reserved.

Updated as On : 21.06.2021 71 | P a g e
Revision date: 2/8/2019 Revision: 7 Supersedes date: 10/9/2017

SAFETY DATA SHEET


Lubricating Oil
According to Appendix D, OSHA Hazard Communication Standard 29 CFR §1910.1200

1. Identification

Product identifier
Product name Lubricating Oil

Chemical name Process Oil

Product number 1003, 1003B, 1003RB, 1003CN

Internal identification 1000-202

CAS number 64742-54-7

Recommended use of the chemical and restrictions on use


Application Firearm Lubrication

Uses advised against No specific uses advised against are identified.

Details of the supplier of the safety data sheet


Manufacturer Bushnell Holdings Inc
9200 Cody
Overland Park, KS 66214
1-800-423-3537
dangerous.goods@vistaoutdoor.com

Emergency telephone number


Emergency telephone Emergency Telephone Number (Hazardous Material/Dangerous Goods Transportation
Emergency Only) 1-800-424-9300 (Inside US Only) +01-703-527-3887 (Outside US) -
(CHEMTREC, Day and Night)

2. Hazard(s) identification

Classification of the substance or mixture


Physical hazards Not Classified

Health hazards Not Classified

Environmental hazards Not Classified

Label elements
Hazard statements NC Not Classified

Other hazards
This substance is not classified as PBT or vPvB according to current EU criteria.

3. Composition/information on ingredients

Substances
Product name Lubricating Oil

Chemical name Process Oil

CAS number 64742-54-7

4. First-aid measures

Description of first aid measures

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Lubricating Oil

General information If in doubt, get medical attention promptly. Show this Safety Data Sheet to the medical
personnel.

Inhalation No specific recommendations. If throat irritation or coughing persists, proceed as follows.


Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Loosen tight clothing such as collar, tie or belt. Get medical attention if any
discomfort continues.

Ingestion No specific recommendations. If throat irritation or coughing persists, proceed as follows.


Rinse mouth. Get medical attention if any discomfort continues.

Skin Contact No specific recommendations. Rinse with water. Get medical attention if any discomfort
continues.

Eye contact Remove any contact lenses and open eyelids wide apart. Rinse with water. Get medical
attention if any discomfort continues.

Protection of first aiders Use protective equipment appropriate for surrounding materials.

Most important symptoms and effects, both acute and delayed


General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation.

Ingestion No specific symptoms known. May cause discomfort if swallowed.

Skin contact No specific symptoms known. May cause discomfort.

Eye contact No specific symptoms known. May be slightly irritating to eyes.

Indication of immediate medical attention and special treatment needed


Notes for the doctor Treat symptomatically.

Specific treatments No special treatment required.

5. Fire-fighting measures

Extinguishing media
Suitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry
powder or water fog. Use fire-extinguishing media suitable for the surrounding fire.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

Special hazards arising from the substance or mixture


Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.

Hazardous combustion Thermal decomposition or combustion products may include the following substances:
products Harmful gases or vapors.

Advice for firefighters


Protective actions during Avoid breathing fire gases or vapors. Evacuate area. Cool containers exposed to heat with
firefighting water spray and remove them from the fire area if it can be done without risk. Cool containers
exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use
water spray to disperse vapors and protect men stopping the leak.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing. Standard Firefighter's clothing including helmets, protective boots and gloves will
provide a basic level of protection for chemical incidents.

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Lubricating Oil

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures


Personal precautions No specific recommendations. For personal protection, see Section 8.

Environmental precautions
Environmental precautions Avoid discharge into drains or watercourses or onto the ground.

Methods and material for containment and cleaning up


Methods for cleaning up Reuse or recycle products wherever possible. Absorb spillage to prevent material damage.
Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage.
Dispose of contents/container in accordance with national regulations.

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

7. Handling and storage

Precautions for safe handling


Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in
Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs.
Handle all packages and containers carefully to minimize spills. Keep container tightly sealed
when not in use. Avoid the formation of mists.

Advice on general Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash
occupational hygiene before reuse. Wash contaminated clothing before reuse.

Conditions for safe storage, including any incompatibilities


Storage precautions Store away from incompatible materials (see Section 10). No specific recommendations.

Storage class Unspecified storage.

Specific end uses(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.

8. Exposure Controls/personal protection

Control parameters
Occupational exposure limits
Long-term exposure limit (8-hour TWA): OSHA 5 mg/m³
Long-term exposure limit (8-hour TWA): ACGIH 5 mg/m³
Short-term exposure limit (15-minute): ACGIH 10 mg/m³
OSHA = Occupational Safety and Health Administration.
ACGIH = American Conference of Governmental Industrial Hygienists.

Exposure controls

Protective equipment

Appropriate engineering No specific ventilation requirements.


controls

Eye/face protection No specific eye protection required during normal use. Large Spillages: Eyewear complying
with an approved standard should be worn if a risk assessment indicates eye contact is
possible.

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Lubricating Oil

Hand protection No specific hand protection recommended. Large Spillages: Wear protective gloves.

Other skin and body Wear appropriate clothing to prevent repeated or prolonged skin contact.
protection

Hygiene measures Wash after use and before eating, smoking and using the toilet. Do not eat, drink or smoke
when using this product.

Respiratory protection No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation is
inadequate, suitable respiratory protection must be worn.

Environmental exposure Not regarded as dangerous for the environment.


controls

9. Physical and Chemical Properties

Information on basic physical and chemical properties


Appearance Clear liquid.

Color Water-white.

Odor Odorless.

pH Not applicable.

Melting point Not determined.

Initial boiling point and range 315°C/599°F

Flash point 192°C/378°F

Evaporation rate No information available.

Flammability (solid, gas) Class IIIB Liquid

Upper/lower flammability or Not available.


explosive limits

Vapor pressure < 0.01 mm Hg @ 25°C

Vapor density > 1.0 g/cc

Relative density 0.866

Bulk density 7.228 lb/gal

Solubility(ies) Insoluble in water.

Partition coefficient Not determined.

Auto-ignition temperature 210°C/410°F

Decomposition Temperature Not determined.

Volatility 3% wt (Max)

10. Stability and reactivity

Reactivity See the other subsections of this section for further details.

Stability Stable at normal ambient temperatures and when used as recommended. Stable under the
prescribed storage conditions.

Possibility of hazardous No potentially hazardous reactions known.


reactions

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Lubricating Oil

Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.

Hazardous decomposition Does not decompose when used and stored as recommended. Thermal decomposition or
products combustion products may include the following substances: Harmful gases or vapors.

11. Toxicological information

Information on toxicological effects


Toxicological effects Not regarded as a health hazard under current legislation.

Acute toxicity - oral


Notes (oral LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - dermal


Notes (dermal LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - inhalation


Notes (inhalation LC₅₀) Based on available data the classification criteria are not met.

Skin corrosion/irritation
Animal data Based on available data the classification criteria are not met.

Serious eye damage/irritation


Serious eye damage/irritation Based on available data the classification criteria are not met.

Respiratory sensitization
Respiratory sensitization Based on available data the classification criteria are not met.

Skin sensitization
Skin sensitization Based on available data the classification criteria are not met.

Germ cell mutagenicity


Genotoxicity - in vitro Based on available data the classification criteria are not met.

Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.

IARC carcinogenicity None of the ingredients are listed or exempt.

Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.

Reproductive toxicity - Based on available data the classification criteria are not met.
development

Specific target organ toxicity - single exposure


STOT - single exposure Not classified as a specific target organ toxicant after a single exposure.

Specific target organ toxicity - repeated exposure


STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure.

Aspiration hazard
Aspiration hazard Based on available data the classification criteria are not met.

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Lubricating Oil

General information No specific health hazards known. The severity of the symptoms described will vary
dependent on the concentration and the length of exposure.

Inhalation No specific symptoms known. Spray/mists may cause respiratory tract irritation.

Ingestion No specific symptoms known. May cause discomfort if swallowed.

Skin Contact No specific symptoms known. May cause discomfort.

Eye contact No specific symptoms known. May be slightly irritating to eyes.

Route of entry Ingestion Inhalation Skin and/or eye contact

Target Organs No specific target organs known.

12. Ecological Information

Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have
hazardous effects on the environment.

Toxicity Based on available data the classification criteria are not met.

Persistence and degradability


Persistence and degradability The degradability of the product is not known.

Bioaccumulative potential
Bio-Accumulative Potential No data available on bioaccumulation.

Partition coefficient Not determined.

Mobility in soil
Mobility No data available.

Other adverse effects


Other adverse effects None known.

13. Disposal considerations

Waste treatment methods


General information The generation of waste should be minimized or avoided wherever possible. Reuse or recycle
products wherever possible. This material and its container must be disposed of in a safe
way.

Disposal methods Dispose of surplus products and those that cannot be recycled via a licensed waste disposal
contractor. Waste packaging should be collected for reuse or recycling. Incineration or landfill
should only be considered when recycling is not feasible. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of the local water
authority.

14. Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, DOT).

UN Number
Not applicable.

UN proper shipping name


Not applicable.

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Lubricating Oil

Transport hazard class(es)


No transport warning sign required.

Packing group
Not applicable.

Environmental hazards

Environmentally Hazardous Substance


No.

Special precautions for user


Not applicable.

Transport in bulk according to Not applicable.


Annex II of MARPOL 73/78
and the IBC Code

15. Regulatory information

US Federal Regulations
SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities
None of the ingredients are listed or exempt.

CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA)


None of the ingredients are listed or exempt.

SARA Extremely Hazardous Substances EPCRA Reportable Quantities


None of the ingredients are listed or exempt.

SARA 313 Emission Reporting


None of the ingredients are listed or exempt.

CAA Accidental Release Prevention


None of the ingredients are listed or exempt.

FDA - Essential Chemical


None of the ingredients are listed or exempt.

FDA - Precursor Chemical


None of the ingredients are listed or exempt.

SARA (311/312) Hazard Categories


None of the ingredients are listed or exempt.

OSHA Highly Hazardous Chemicals


None of the ingredients are listed or exempt.

US State Regulations
California Proposition 65 Carcinogens and Reproductive Toxins
None of the ingredients are listed or exempt.

California Air Toxics "Hot Spots" (A-I)


None of the ingredients are listed or exempt.

California Air Toxics "Hot Spots" (A-II)


None of the ingredients are listed or exempt.

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Lubricating Oil

California Directors List of Hazardous Substances


None of the ingredients are listed or exempt.

Massachusetts "Right To Know" List


None of the ingredients are listed or exempt.

Rhode Island "Right To Know" List


None of the ingredients are listed or exempt.

Minnesota "Right To Know" List


None of the ingredients are listed or exempt.

New Jersey "Right To Know" List


None of the ingredients are listed or exempt.

Pennsylvania "Right To Know" List


None of the ingredients are listed or exempt.

Inventories
US - TSCA
None of the ingredients are listed or exempt.

US - TSCA 12(b) Export Notification


None of the ingredients are listed or exempt.

16. Other information

Classification abbreviations Asp. Tox. = Aspiration hazard


and acronyms

Training advice Only trained personnel should use this material.

Revision date 2/8/2019

Revision 7

Supersedes date 10/9/2017

SDS No. 4634

End of Safety Data Sheet

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

8/8
Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 02.09.2015 Page 1 of 6
Vegetable Oil

SECTION 1 : Identification of the substance/mixture and of the supplier


Product name : Vegetable Oil
Manufacturer/Supplier Trade name:
Manufacturer/Supplier Article number: S25622
Recommended uses of the product and restrictions on use:
Manufacturer Details:
AquaPhoenix Scientific, Inc
9 Barnhart Drive, Hanover, PA 17331
(717) 632-1291
Supplier Details:
Fisher Science Education
6771 Silver Crest Road, Nazareth, PA 18064
(724)517-1954
Emergency telephone number:
Fisher Science Education Emergency Telephone No.: 800-535-5053

SECTION 2 : Hazards identification

Classification of the substance or mixture:

Not classified for physical or health hazards according to GHS.

Hazard statements:
Precautionary statements:
If medical advice is needed, have product container or label at hand
Keep out of reach of children
Read label before use

Other Non-GHS Classification:


WHMIS
NFPA/HMIS

NFPA SCALE (0-4) HMIS RATINGS (0-4)

SECTION 3 : Composition/information on ingredients

Ingredients:

CAS 8001-22-7 Vegetable Oil 100 %

Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com


Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 02.09.2015 Page 2 of 6
Vegetable Oil

Percentages are by weight

SECTION 4 : First aid measures


Description of first aid measures
After inhalation: Loosen clothing as necessary and position individual in a comfortable position.Move exposed
to fresh air. Give artificial respiration if necessary. If breathing is difficult give oxygen.Get medical assistance if
cough or other symptoms appear.
After skin contact: Rinse/flush exposed skin gently using soap and water for 15-20 minutes.Seek medical
advice if discomfort or irritation persists.
After eye contact: Protect unexposed eye.Rinse/flush exposed eye(s) gently using water for 15-20
minutes.Remove contact lens(es) if able to do so during rinsing.Seek medical attention if irritation persists or if
concerned.
After swallowing: Rinse mouth thoroughly. Do not induce vomiting. Seek medical attention if irritation,
discomfort, or vomiting persists.Never give anything by mouth to an unconscious person.

Most important symptoms and effects, both acute and delayed:


Irritation.Headache.Nausea.Shortness of breath.;Not Determined
Indication of any immediate medical attention and special treatment needed:
If seeking medical attention provide SDS document to physician. Physician should treat symptomatically.

SECTION 5 : Firefighting measures


Extinguishing media
Suitable extinguishing agents: Use water, dry chemical, chemical foam, carbon dioxide, or alcohol-resistant
foam.
For safety reasons unsuitable extinguishing agents:
Special hazards arising from the substance or mixture:
Thermal decomposition can lead to release of irritating gases and vapors.
Advice for firefighters:
Protective equipment: Wear protective eyeware, gloves, and clothing. Refer to Section 8.Use NIOSH-
approved respiratory protection/breathing apparatus.
Additional information (precautions): Avoid inhaling gases, fumes, dust, mist, vapor, and aerosols. Avoid
contact with skin, eyes, and clothing.

SECTION 6 : Accidental release measures


Personal precautions, protective equipment and emergency procedures:
Ensure adequate ventilation.Ensure that air-handling systems are operational.
Environmental precautions:
Should not be released into environment.Prevent from reaching drains, sewer, or waterway.
Methods and material for containment and cleaning up:
Wear protective eyeware, gloves, and clothing. Refer to Section 8.Use spill berms to contain spill and absorb
spill from outside working way towards center. Place in appropriate container for disposal. For disposal, refer to
Section 13.
Reference to other sections:

SECTION 7 : Handling and storage

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Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 02.09.2015 Page 3 of 6
Vegetable Oil

Precautions for safe handling:


Avoid contact with skin, eyes, and clothing.Follow good hygiene procedures when handling chemical materials.
Refer to Section 8.Do not eat, drink, smoke, or use personal products when handling chemical substances.
Conditions for safe storage, including any incompatibilities:
Store in a cool location. Protect from freezing and physical damage.Provide ventilation for containers. Keep
container tightly sealed.Store away from incompatible materials. Store with similar hazards.

SECTION 8 : Exposure controls/personal protection

Control Parameters: 8001-22-7, Vegetable Oil, This material has no known Exposure Limits.
Appropriate Engineering controls: Provide exhaust ventilation or other engineering controls to keep the
airborne concentrations of vapor and mists below the applicable
workplace exposure limits (Occupational Exposure Limits-OELs) indicated
above.
Respiratory protection: Not required under normal conditions of use. Where risk assessment
shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a
backup to engineering controls.When necessary use NIOSH approved
breathing equipment.
Protection of skin: Select glove material impermeable and resistant to the substance.Select
glove material based on rates of diffusion and degradation. Dispose of
contaminated gloves after use in accordance with applicable laws and
good laboratory practices.Use proper glove removal technique without
touching outer surface. Avoid skin contact with used gloves.Wear
protective clothing.
Eye protection: Wear equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN
166(EU).Safety glasses or goggles are appropriate eye protection.
General hygienic measures: Perform routine housekeeping. Wash hands before breaks and at the end
of work. Avoid contact with skin, eyes, and clothing.Before wearing wash
contaminated clothing.

SECTION 9 : Physical and chemical properties

Appearance (physical Explosion limit lower: Not Determined


White Liquid
state,color): Explosion limit upper: Not Determined

Odor: Mild Vapor pressure: Not Determined

Odor threshold: Not Determined Vapor density: Not Determined

pH-value: Not Determined Relative density: Not determined

Melting/Freezing point: 22-31C Solubilities: Not water soluble.

Boiling point/Boiling Partition coefficient (n-


Not Determined Not Determined
range: octanol/water):

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Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 02.09.2015 Page 4 of 6
Vegetable Oil

Flash point (closed Auto/Self-ignition


>113C Not Determined
cup): temperature:

Decomposition
Evaporation rate: Not Determined Not Determined
temperature:

Flammability a. Kinematic:Not Determined


Not Determined Viscosity:
(solid,gaseous): b. Dynamic: Not Determined

Density: Not Determined

SECTION 10 : Stability and reactivity

Reactivity:Nonreactive under normal conditions.


Chemical stability:Stable under normal conditions.
Possible hazardous reactions:None under normal processing.
Conditions to avoid:Incompatible materials.High temperatures.Moisture.
Incompatible materials:Strong oxidizers.
Hazardous decomposition products:Oxides of carbon.

SECTION 11 : Toxicological information

Acute Toxicity: No additional information.

Chronic Toxicity: No additional information.

Corrosion Irritation: No additional information.

Sensitization: No additional information.

Single Target Organ (STOT): No additional information.

Numerical Measures: No additional information.

Carcinogenicity: Vegetable Oil 8001-22-7: Not listed as a carcinogen (ACGIH, IARC, NTP)

Mutagenicity: No additional information.

Reproductive Toxicity: No additional information.

SECTION 12 : Ecological information

Ecotoxicity Persistence and degradability: Not Determined


Bioaccumulative potential: Not Determined
Mobility in soil: Not Determined
Other adverse effects: Not Determined

SECTION 13 : Disposal considerations

Waste disposal recommendations:


Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste.
Chemical waste generators must also consult local, regional, and national hazardous waste regulations. Ensure
complete and accurate classification.

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Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 02.09.2015 Page 5 of 6
Vegetable Oil

SECTION 14 : Transport information

UN-Number
Not Regulated
UN proper shipping name
Not Regulated
Transport hazard class(es)
Packing group:Not Regulated
Environmental hazard:
Transport in bulk:
Special precautions for user:

SECTION 15 : Regulatory information

United States (USA)


SARA Section 311/312 (Specific toxic chemical listings):
SARA Section 313 (Specific toxic chemical listings):
None of the ingredients is listed
RCRA (hazardous waste code):
None of the ingredients is listed
TSCA (Toxic Substances Control Act):
All ingredients are listed.
CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act):
None of the ingredients is listed

Proposition 65 (California):

Chemicals known to cause cancer:


None of the ingredients is listed
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed
Chemicals known to cause developmental toxicity:
None of the ingredients is listed

Canada

Canadian Domestic Substances List (DSL):


All ingredients are listed.
Canadian NPRI Ingredient Disclosure list (limit 0.1%):
None of the ingredients is listed
Canadian NPRI Ingredient Disclosure list (limit 1%):
None of the ingredients is listed

SECTION 16 : Other information

Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com


Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 02.09.2015 Page 6 of 6
Vegetable Oil

This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the
SDS contains all the information required by the Controlled Products Regulations.Note:. The responsibility to
provide a safe workplace remains with the user.The user should consider the health hazards and safety information
contained herein as a guide and should take those precautions required in an individual operation to instruct
employees and develop work practice procedures for a safe work environment.The information contained herein is,
to the best of our knowledge and belief, accurate.However, since the conditions of handling and use are beyond
our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this
material.It is the responsibility of the user to comply with all applicable laws and regulations applicable to this
material.
GHS Full Text Phrases:

Abbreviations and acronyms:


IMDG: International Maritime Code for Dangerous Goods
PNEC: Predicted No-Effect Concentration (REACH)
CFR: Code of Federal Regulations (USA)
SARA: Superfund Amendments and Reauthorization Act (USA)
RCRA: Resource Conservation and Recovery Act (USA)
TSCA: Toxic Substances Control Act (USA)
NPRI: National Pollutant Release Inventory (Canada)
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)

Effective date : 02.09.2015


Last updated : 05.08.2015

Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com

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