Orotol Plus GB 1219
Orotol Plus GB 1219
Orotol Plus GB 1219
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( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
Corrosion (GHS05)
Signal word
Danger
Hazard components for labelling
DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. : 5538-94-3
POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3
Hazard statements
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements
P280 Wear protective gloves and eye/face protection.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P353 Rinse skin with water [or shower].
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to hazardous or special waste collection point.
2.3 Other hazards
None
3.2 Mixtures
Description
Orotol® plus contains quaternary ammonium compounds, alkaline cleaning agents, complexing agents, special antifoaming
agents, fragrances and auxiliary agents in aqueous solution.
Hazardous ingredients
TETRAPOTASSIUM DIPHOSPHATE ; REACH No. : 01-2119489369-18 ; EC No. : 230-785-7; CAS No. : 7320-34-5
Weight fraction : ≥ 5 - < 10 %
Classification 1272/2008 [CLP] : Skin Irrit. 2 ; H315 Eye Irrit. 2 ; H319 STOT SE 3 ; H335 Aquatic Chronic 4 ; H413
DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; REACH No. : - ; EC No. : 226-901-0; CAS No. : 5538-94-3
Weight fraction : ≥3-<5%
Classification 1272/2008 [CLP] : Acute Tox. 2 ; H310 Acute Tox. 3 ; H301 Skin Corr. 1B ; H314 Eye Dam. 1 ; H318
Aquatic Acute 1 ; H400 Aquatic Chronic 1 ; H410
DODECYLDIMETHYLBENZYLAMMONIUM CHLORIDE ; REACH No. : 012119970550-39 ; EC No. : 287-089-1; CAS No. : 85409-
22-9
Weight fraction : ≥ 0,5 - < 1 %
Classification 1272/2008 [CLP] : Skin Corr. 1B ; H314 Eye Dam. 1 ; H318 Acute Tox. 4 ; H302 Aquatic Acute 1 ; H400
Aquatic Chronic 1 ; H410
POTASSIUM HYDROXIDE ; REACH No. : 01-2119487136-33 ; EC No. : 215-181-3; CAS No. : 1310-58-3
Weight fraction : ≥ 0,5 - < 1 %
Classification 1272/2008 [CLP] : Met. Corr. 1 ; H290 Skin Corr. 1A ; H314 Eye Dam. 1 ; H318 Acute Tox. 4 ; H302
EUCALYPTOL ; REACH No. : 01-2119967772-24 ; EC No. : 207-431-5; CAS No. : 470-82-6
Weight fraction : < 0,1 %
Classification 1272/2008 [CLP] : Flam. Liq. 3 ; H226 Skin Sens. 1 ; H317
Additional information
Full text of H- and EUH-phrases: see section 16.
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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
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( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.
6.3 Methods and material for containment and cleaning up
For cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Collect in closed
and suitable containers for disposal.
Other information
Treat the recovered material as prescribed in the section on waste disposal.
6.4 Reference to other sections
None
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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
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( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
Eye/face protection
Eye glasses with side protection DIN EN 166
Skin protection
Hand protection
Short-term exposure (Level 2: < 30 min): disposable gloves to EN374 category III, e.g. nitrile rubber, material
thickness 0.1 mm.
Long-term exposure (Level 6: < 480 min): protective gloves to EN374 category III, e.g. nitrile rubber, material
thickness 0.7 mm.
When handling with chemical substances, protective gloves must be worn with the CE-label including the four
control digits.
Body protection
Body protection: not required.
Respiratory protection
Usually no personal respirative protection necessary.
General information
Keep away from food, drink and animal feedingstuffs. Avoid contact with skin, eyes and clothes. Remove
contaminated, saturated clothing. Wash hands before breaks and after work. Separate storage of work clothes. When
using do not eat, drink, smoke, sniff.
Other protection measures
Provide adequate ventilation.
10.1 Reactivity
None, if handled according to order.
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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
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( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
12.1 Toxicity
Aquatic toxicity
Acute (short-term) fish toxicity
Parameter : LC50 ( TETRAPOTASSIUM DIPHOSPHATE ; CAS No. : 7320-34-5 )
Species : Oncorhynchus mykiss (Rainbow trout)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : > 100 mg/l
Exposure time : 96 h
Method : OECD 203
Parameter : LC50 ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. : 5538-94-3 )
Species : Oncorhynchus mykiss (Rainbow trout)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 0,35 mg/l
Exposure time : 96 h
Parameter : LC50 ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. : 5538-94-3 )
Species : Lepomis macrochirus (Bluegill)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 0,55 mg/l
Exposure time : 48 h
Parameter : LC50 ( DODECYLDIMETHYLBENZYLAMMONIUM CHLORIDE ; CAS No. : 85409-22-9 )
Species : Pimephales promelas (fathead minnow)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 0,28 mg/l
Exposure time : 96 h
Parameter : LC50 ( DODECYLDIMETHYLBENZYLAMMONIUM CHLORIDE ; CAS No. : 85409-22-9 )
Species : Oncorhynchus mykiss (Rainbow trout)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 0,85 mg/l
Exposure time : 96 h
Method : OECD 203
Parameter : LC50 ( POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3 )
Species : Gambusia affinis (Mosquito fish)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 80 mg/l
Exposure time : 96 h
Parameter : LC50 ( POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3 )
Species : Poecilia reticulata (Guppy)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 165 mg/l
Exposure time : 24 h
Parameter : LC50 ( EUCALYPTOL ; CAS No. : 470-82-6 )
Species : Pimephales promelas (fathead minnow)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 102 mg/l
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( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
Exposure time : 96 h
Chronic (long-term) fish toxicity
Parameter : NOEC
Species : Poecilia reticulata (Guppy)
Evaluation parameter : Chronic (long-term) fish toxicity
Effective dose : 1,1 mg/l
Exposure time : 96 h
Method : OECD 203
Acute (short-term) toxicity to crustacea
Parameter : EC50
Species : Daphnia magna (Big water flea)
Evaluation parameter : Acute (short-term) daphnia toxicity
Effective dose : 1,1 mg/l
Exposure time : 48 h
Method : OECD 202
Chronic (long-term) toxicity to crustacea
Parameter : NOEC
Species : Daphnia magna (Big water flea)
Evaluation parameter : Chronic (long-term) daphnia toxicity
Effective dose : 0,26 mg/l
Exposure time : 48 h
Method : OECD 202
Acute (short-term) toxicity to aquatic algae and cyanobacteria
Parameter : ErC50
Species : Desmodesmus subspicatus
Evaluation parameter : Inhibition of growth rate
Effective dose : 4,42 mg/l
Exposure time : 72 h
Method : OECD 201
Chronic (long-term) algae toxicity
Parameter : NOEC
Species : Desmodesmus subspicatus
Evaluation parameter : Chronic (long-term) algae toxicity
Effective dose : 1,25 mg/l
Exposure time : 96 h
Method : OECD 201
Toxicity to microorganisms
Parameter : EC50 ( TETRAPOTASSIUM DIPHOSPHATE ; CAS No. : 7320-34-5 )
Evaluation parameter : Bacteria toxicity
Effective dose : > 1000 mg/l
Exposure time : 3h
Parameter : EC50 ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. : 5538-94-3 )
Species : Bacteria toxicity
Effective dose : 5 - 22 mg/l
Exposure time : 3h
Method : OECD 209
Parameter : EC50 ( DODECYLDIMETHYLBENZYLAMMONIUM CHLORIDE ; CAS No. : 85409-22-9 )
Evaluation parameter : Bacteria toxicity
Effective dose : 7,75 mg/l
Exposure time : 3h
Method : OECD 209
Parameter : EC50 ( POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3 )
Evaluation parameter : Bacteria toxicity
Effective dose : 22 mg/l
Exposure time : 15 min
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( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
Terrestrial toxicity
Toxicity to birds
Bird reproduction toxicity
Parameter : Bird reproduction toxicity ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. :
5538-94-3 )
Species : Colinus virginianus (bobwhite quail)
Evaluation parameter : Acute and subchronic bird toxicity
Effective dose : 1300 ppm
Exposure time : 192 h
Parameter : Bird reproduction toxicity ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. :
5538-94-3 )
Species : Anas platyrhynchos (maillard duck)
Evaluation parameter : Acute and subchronic bird toxicity
Effective dose : > 2500 ppm
Exposure time : 192 h
Sewage treatment plant
Technically correct releases of minimal concentrations to adapted biological sewage plants, will not disturb the
biodegradability of activated sludge.
12.2 Persistence and degradability
Abiotic degradation
No data available.
Biodegradation
The product is easily biodegradable according to OECD criteria. Method : OECD 301 D.
12.3 Bioaccumulative potential
No information available.
12.4 Mobility in soil
Distribution
There are no data available on the preparation itself.
12.5 Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6 Other adverse effects
No information available.
12.7 Additional ecotoxicological information
Prevent from flowing into surface water/ground water.
14.1 UN number
UN 1719
14.2 UN proper shipping name
Land transport (ADR/RID)
CAUSTIC ALKALI LIQUID, N.O.S. ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE · POTASSIUM HYDROXIDE )
Sea transport (IMDG)
CAUSTIC ALKALI LIQUID, N.O.S. ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE · POTASSIUM HYDROXIDE )
Air transport (ICAO-TI / IATA-DGR)
CAUSTIC ALKALI LIQUID, N.O.S. ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE · POTASSIUM HYDROXIDE )
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( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
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( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
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( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
The above information describes exclusively the safety requirements of the product and is based on our present-day
knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data
sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of
mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily
valid for the new made-up material.
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