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Orotol Plus GB 1219

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Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : Orotol® plus Disinfection of suction system


Revision date : 16.12.2019 Version (Revision) : 6.0.0 (5.0.0)
Print date : 19.02.2020

SECTION 1: Identification of the substance/mixture and of the company/ undertaking

1.1 Product identifier


Orotol® plus Disinfection of suction system
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Orotol® plus is a highly effective aldehyde-free concentrate for the simultaneous disinfection, deodorization, cleaning
and care of dental suction systems as well as spittoon bowls, being likewise suitable for all amalgam separators.
Products Category [PC]
PC 0 - Other
Disinfectants
Uses advised against
None, if handled according to order.
Remark
The product is intended for professional use.
1.3 Details of the supplier of the safety data sheet
Supplier (manufacturer/importer/only representative/downstream
user/distributor)
orochemie GmbH + Co. KG
Street : Max-Planck-Straße 27
Postal code/city : 70806 Kornwestheim
Telephone : +49 7154 1308-0
Telefax : +49 7154 1308-40
Information contact : DÜRR DENTAL SE, Höpfigheimer Str. 17, 74321 Bietigheim-Bissingen, Germany
Tel: +49 7142 705-0, Fax: +49 7142 705-500, info@duerrdental.com
in Great Britain/Ireland:
DÜRR DENTAL [Products] UK Ltd., 14 Linnell Way - Telford Way Industrial Estate, Kettering Northants NN16 8PS,
United Kingdom
Tel: +44 1536 526740, Fax.: +44 1536 526749, info@duerruk.com
1.4 Emergency telephone number
INT: +49 6132 84463 (24 h/7 d)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture


Classification according to Regulation (EC) No 1272/2008 [CLP]
Met. Corr. 1 ; H290 - Corrosive to metals : Category 1 ; May be corrosive to metals.
Skin Corr. 1C ; H314 - Skin corrosion/irritation : Category 1C ; Causes severe skin burns and eye damage.
Eye Dam. 1 ; H318 - Serious eye damage/eye irritation : Category 1 ; Causes serious eye damage.
Aquatic Chronic 3 ; H412 - Hazardous to the aquatic environment : Chronic 3 ; Harmful to aquatic life with long lasting
effects.
Classification procedure
The classification was carried out according to the calculation method of Regulation No. (EC) 1272/2008 [CLP] as well
as in-house investigations.
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms

Page : 1 / 13
( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : Orotol® plus Disinfection of suction system


Revision date : 16.12.2019 Version (Revision) : 6.0.0 (5.0.0)
Print date : 19.02.2020

Corrosion (GHS05)
Signal word
Danger
Hazard components for labelling
DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. : 5538-94-3
POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3
Hazard statements
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements
P280 Wear protective gloves and eye/face protection.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P353 Rinse skin with water [or shower].
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to hazardous or special waste collection point.
2.3 Other hazards
None

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Description
Orotol® plus contains quaternary ammonium compounds, alkaline cleaning agents, complexing agents, special antifoaming
agents, fragrances and auxiliary agents in aqueous solution.
Hazardous ingredients
TETRAPOTASSIUM DIPHOSPHATE ; REACH No. : 01-2119489369-18 ; EC No. : 230-785-7; CAS No. : 7320-34-5
Weight fraction : ≥ 5 - < 10 %
Classification 1272/2008 [CLP] : Skin Irrit. 2 ; H315 Eye Irrit. 2 ; H319 STOT SE 3 ; H335 Aquatic Chronic 4 ; H413
DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; REACH No. : - ; EC No. : 226-901-0; CAS No. : 5538-94-3
Weight fraction : ≥3-<5%
Classification 1272/2008 [CLP] : Acute Tox. 2 ; H310 Acute Tox. 3 ; H301 Skin Corr. 1B ; H314 Eye Dam. 1 ; H318
Aquatic Acute 1 ; H400 Aquatic Chronic 1 ; H410
DODECYLDIMETHYLBENZYLAMMONIUM CHLORIDE ; REACH No. : 012119970550-39 ; EC No. : 287-089-1; CAS No. : 85409-
22-9
Weight fraction : ≥ 0,5 - < 1 %
Classification 1272/2008 [CLP] : Skin Corr. 1B ; H314 Eye Dam. 1 ; H318 Acute Tox. 4 ; H302 Aquatic Acute 1 ; H400
Aquatic Chronic 1 ; H410
POTASSIUM HYDROXIDE ; REACH No. : 01-2119487136-33 ; EC No. : 215-181-3; CAS No. : 1310-58-3
Weight fraction : ≥ 0,5 - < 1 %
Classification 1272/2008 [CLP] : Met. Corr. 1 ; H290 Skin Corr. 1A ; H314 Eye Dam. 1 ; H318 Acute Tox. 4 ; H302
EUCALYPTOL ; REACH No. : 01-2119967772-24 ; EC No. : 207-431-5; CAS No. : 470-82-6
Weight fraction : < 0,1 %
Classification 1272/2008 [CLP] : Flam. Liq. 3 ; H226 Skin Sens. 1 ; H317
Additional information
Full text of H- and EUH-phrases: see section 16.

Page : 2 / 13
( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : Orotol® plus Disinfection of suction system


Revision date : 16.12.2019 Version (Revision) : 6.0.0 (5.0.0)
Print date : 19.02.2020

SECTION 4: First aid measures

4.1 Description of first aid measures


General information
Remove contaminated, saturated clothing immediately. In case of accident or unwellness, seek medical advice
immediately (show directions for use or safety data sheet if possible).
Following inhalation
Provide fresh air. In case of respiratory tract irritation, consult a physician.
In case of skin contact
Wash with plenty of water. When in doubt or if symptoms are observed, get medical advice.
After eye contact
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart
and consult an ophthalmologist.
After ingestion
If swallowed, immediately drink: Water Never give anything by mouth to an unconscious person or a person with
cramps. Do NOT induce vomiting. Call a physician immediately.
4.2 Most important symptoms and effects, both acute and delayed
Causes severe skin burns and eye damage.
4.3 Indication of any immediate medical attention and special treatment needed
None

SECTION 5: Firefighting measures

5.1 Extinguishing media


Suitable extinguishing media
Carbon dioxide (CO2) Extinguishing powder Water spray jet Water mist The product itself does not burn. Co-ordinate
fire-fighting measures to the fire surroundings.
Unsuitable extinguishing media
Full water jet
5.2 Special hazards arising from the substance or mixture
None known.
Hazardous combustion products
None known.
5.3 Advice for firefighters
Adapt protective equipment to surrounding fire.
Special protective equipment for firefighters
Adapt protective equipment to surrounding fire.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


Use personal protection equipment. See protective measures under point 7 and 8.
For non-emergency personnel
Use personal protection equipment. See protective measures under point 7 and 8.
For emergency responders
Personal protection equipment
See protective measures under point 7 and 8.
6.2 Environmental precautions

Page : 3 / 13
( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : Orotol® plus Disinfection of suction system


Revision date : 16.12.2019 Version (Revision) : 6.0.0 (5.0.0)
Print date : 19.02.2020

Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.
6.3 Methods and material for containment and cleaning up
For cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Collect in closed
and suitable containers for disposal.
Other information
Treat the recovered material as prescribed in the section on waste disposal.
6.4 Reference to other sections
None

SECTION 7: Handling and storage

7.1 Precautions for safe handling


Keep/Store only in original container. Please note safety instructions and directions for use on the drum. Handle and
open container with care. Provide adequate ventilation. Do not breathe vapour/aerosol.
Protective measures
Measures to prevent fire
Usual measures for fire prevention. When using do not smoke.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep/Store only in original container. Keep container tightly closed. Keep in a cool, well-ventilated place. Do not store
in temperatures below 5 °C.
Hints on joint storage
Store the foodstuffs separately.
7.3 Specific end use(s)
None

SECTION 8: Exposure controls/personal protection

8.1 Control parameters


Occupational exposure limit values
POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3
Limit value type (country of origin) : TLV/STEL ( GB )
Limit value : 2 mg/m3
DNEL-/PNEC-values
There are no data available on the preparation itself.
DNEL/DMEL
TETRAPOTASSIUM DIPHOSPHATE ; CAS No. : 7320-34-5
Limit value type : DNEL Consumer (systemic)
Exposure route : Inhalation
Exposure frequency : Long-term
Limit value : 0,68 mg/l
Limit value type : DNEL Consumer (systemic)
Exposure route : Oral
Exposure frequency : Long-term
Limit value : > 70 mg/kg
Safety factor : 24 h
Limit value type : DNEL Consumer (systemic)
Exposure route : Inhalation
Exposure frequency : Long-term
Limit value : 10,87 mg/m3

Page : 4 / 13
( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : Orotol® plus Disinfection of suction system


Revision date : 16.12.2019 Version (Revision) : 6.0.0 (5.0.0)
Print date : 19.02.2020

Limit value type : DNEL worker (systemic)


Exposure route : Inhalation
Exposure frequency : Long-term
Limit value : 2,79 mg/m3
Limit value type : DNEL worker (systemic)
Exposure route : Inhalation
Exposure frequency : Long-term
Limit value : 44,08 mg/m3
DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. : 5538-94-3
Limit value type : DNEL/DMEL (Consumer)
Exposure route : Oral
Exposure frequency : Long-term
Limit value : 7,5 mg/kg
Safety factor : 24 h
Limit value type : DNEL/DMEL (Consumer)
Exposure route : Dermal
Limit value : 7,5 mg/kg
Safety factor : 24 h
Limit value type : DNEL/DMEL (Industrial)
Exposure route : Inhalation
Exposure frequency : Long-term
Limit value : 44 mg/m3
Limit value type : DNEL/DMEL (Industrial)
Exposure route : Dermal
Exposure frequency : Long-term
Limit value : 12,5 mg/kg
Safety factor : 24 h
POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3
Limit value type : DNEL Consumer (local)
Exposure route : Inhalation
Exposure frequency : Long-term
Limit value : 1 mg/m3
Limit value type : DNEL worker (local)
Exposure route : Inhalation
Exposure frequency : Long-term
Limit value : 1 mg/m3
PNEC
TETRAPOTASSIUM DIPHOSPHATE ; CAS No. : 7320-34-5
Limit value type : PNEC (Aquatic, freshwater)
Limit value : 0,05 mg/l
Limit value type : PNEC (Aquatic, intermittent release)
Limit value : 0,5 mg/l
Limit value type : PNEC (Aquatic, marine water)
Limit value : 0,005 mg/l
Limit value type : PNEC (Sewage treatment plant)
Limit value : 50 mg/l
DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. : 5538-94-3
Limit value type : PNEC (Aquatic, freshwater)
Limit value : 0,001 mg/l
Limit value type : PNEC (Aquatic, marine water)
Limit value : 0,00001 mg/l
Limit value type : PNEC (Sewage treatment plant)
Limit value : 0,5 mg/l
8.2 Exposure controls
Personal protection equipment

Page : 5 / 13
( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : Orotol® plus Disinfection of suction system


Revision date : 16.12.2019 Version (Revision) : 6.0.0 (5.0.0)
Print date : 19.02.2020

Eye/face protection
Eye glasses with side protection DIN EN 166
Skin protection
Hand protection
Short-term exposure (Level 2: < 30 min): disposable gloves to EN374 category III, e.g. nitrile rubber, material
thickness 0.1 mm.
Long-term exposure (Level 6: < 480 min): protective gloves to EN374 category III, e.g. nitrile rubber, material
thickness 0.7 mm.
When handling with chemical substances, protective gloves must be worn with the CE-label including the four
control digits.
Body protection
Body protection: not required.
Respiratory protection
Usually no personal respirative protection necessary.
General information
Keep away from food, drink and animal feedingstuffs. Avoid contact with skin, eyes and clothes. Remove
contaminated, saturated clothing. Wash hands before breaks and after work. Separate storage of work clothes. When
using do not eat, drink, smoke, sniff.
Other protection measures
Provide adequate ventilation.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties


Appearance : Liquid
Colour : yellow
Odour : Lemon
Safety characteristics
Melting point/freezing point : ( 1013 hPa ) not determined
Initial boiling point and boiling
( 1013 hPa ) approx. 100 °C
range :
Decomposition temperature : ( 1013 hPa ) not determined
Flash point : not applicable
Auto-ignition temperature : not applicable
Lower explosion limit : not applicable
Upper explosion limit : not applicable
Density : ( 20 °C ) 1,084 - 1,09 g/cm3
Water solubility : ( 20 °C ) 100 Wt %
pH : 12,3 - 12,9
pH : ( 20 °C / 20 g/l ) 10 - 10,4
log P O/W : not determined
Odour threshold : not determined
Maximum VOC content (EC) : 6,6 Wt %
Oxidising liquids : Not applicable.
Explosive properties : Not applicable.
Corrosive to metals : May be corrosive to metals.
9.2 Other information
None

SECTION 10: Stability and reactivity

10.1 Reactivity
None, if handled according to order.

Page : 6 / 13
( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : Orotol® plus Disinfection of suction system


Revision date : 16.12.2019 Version (Revision) : 6.0.0 (5.0.0)
Print date : 19.02.2020

10.2 Chemical stability


Stable under recommended storage and handling conditions (see section 7). Reactions with acids: development of heat.
10.3 Possibility of hazardous reactions
Reactions with acids possible
10.4 Conditions to avoid
No information available.
10.5 Incompatible materials
Acid
10.6 Hazardous decomposition products
None known.

SECTION 11: Toxicological information

11.1 Information on toxicological effects


Acute toxicity
Acute oral toxicity
Parameter : LD50
Exposure route : Oral
Species : Rat
Effective dose : > 2000 mg/kg
Method : OECD 401
Parameter : ATEmix calculated
Exposure route : Oral
Effective dose : not relevant
Parameter : ATE ( DODECYLDIMETHYLBENZYLAMMONIUM CHLORIDE ; CAS No. : 85409-22-9 )
Exposure route : Oral
Effective dose : 500 mg/kg
Parameter : ATE ( POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3 )
Exposure route : Oral
Effective dose : 500 mg/kg
Practical experience/human evidence
Causes severe skin burns and eye damage.
Acute dermal toxicity
Parameter : LD50
Exposure route : Dermal
Species : Rat
Effective dose : > 2000 mg/kg
Method : OECD 402
Parameter : ATEmix calculated
Exposure route : Dermal
Effective dose : not relevant
Acute inhalation toxicity
Parameter : ATEmix calculated
Exposure route : Inhalation (vapour)
Effective dose : not relevant
Parameter : LC50 ( TETRAPOTASSIUM DIPHOSPHATE ; CAS No. : 7320-34-5 )
Exposure route : Inhalation
Species : Rat
Effective dose : > 1,1 mg/l
Method : OECD 403
Corrosion
Rabbit´s eye: no irritation. 2 % solution. Method : OECD 405.

Page : 7 / 13
( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : Orotol® plus Disinfection of suction system


Revision date : 16.12.2019 Version (Revision) : 6.0.0 (5.0.0)
Print date : 19.02.2020

Respiratory or skin sensitisation


Guinea-pig: non-sensitizing (2 % solution). Method : OECD 406.
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
No information available.
11.5 Additional information
The classification was carried out according to the calculation method of Regulation No. (EC) 1272/2008 [CLP] as well
as in-house investigations.

SECTION 12: Ecological information

12.1 Toxicity
Aquatic toxicity
Acute (short-term) fish toxicity
Parameter : LC50 ( TETRAPOTASSIUM DIPHOSPHATE ; CAS No. : 7320-34-5 )
Species : Oncorhynchus mykiss (Rainbow trout)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : > 100 mg/l
Exposure time : 96 h
Method : OECD 203
Parameter : LC50 ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. : 5538-94-3 )
Species : Oncorhynchus mykiss (Rainbow trout)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 0,35 mg/l
Exposure time : 96 h
Parameter : LC50 ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. : 5538-94-3 )
Species : Lepomis macrochirus (Bluegill)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 0,55 mg/l
Exposure time : 48 h
Parameter : LC50 ( DODECYLDIMETHYLBENZYLAMMONIUM CHLORIDE ; CAS No. : 85409-22-9 )
Species : Pimephales promelas (fathead minnow)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 0,28 mg/l
Exposure time : 96 h
Parameter : LC50 ( DODECYLDIMETHYLBENZYLAMMONIUM CHLORIDE ; CAS No. : 85409-22-9 )
Species : Oncorhynchus mykiss (Rainbow trout)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 0,85 mg/l
Exposure time : 96 h
Method : OECD 203
Parameter : LC50 ( POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3 )
Species : Gambusia affinis (Mosquito fish)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 80 mg/l
Exposure time : 96 h
Parameter : LC50 ( POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3 )
Species : Poecilia reticulata (Guppy)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 165 mg/l
Exposure time : 24 h
Parameter : LC50 ( EUCALYPTOL ; CAS No. : 470-82-6 )
Species : Pimephales promelas (fathead minnow)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 102 mg/l

Page : 8 / 13
( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : Orotol® plus Disinfection of suction system


Revision date : 16.12.2019 Version (Revision) : 6.0.0 (5.0.0)
Print date : 19.02.2020

Exposure time : 96 h
Chronic (long-term) fish toxicity
Parameter : NOEC
Species : Poecilia reticulata (Guppy)
Evaluation parameter : Chronic (long-term) fish toxicity
Effective dose : 1,1 mg/l
Exposure time : 96 h
Method : OECD 203
Acute (short-term) toxicity to crustacea
Parameter : EC50
Species : Daphnia magna (Big water flea)
Evaluation parameter : Acute (short-term) daphnia toxicity
Effective dose : 1,1 mg/l
Exposure time : 48 h
Method : OECD 202
Chronic (long-term) toxicity to crustacea
Parameter : NOEC
Species : Daphnia magna (Big water flea)
Evaluation parameter : Chronic (long-term) daphnia toxicity
Effective dose : 0,26 mg/l
Exposure time : 48 h
Method : OECD 202
Acute (short-term) toxicity to aquatic algae and cyanobacteria
Parameter : ErC50
Species : Desmodesmus subspicatus
Evaluation parameter : Inhibition of growth rate
Effective dose : 4,42 mg/l
Exposure time : 72 h
Method : OECD 201
Chronic (long-term) algae toxicity
Parameter : NOEC
Species : Desmodesmus subspicatus
Evaluation parameter : Chronic (long-term) algae toxicity
Effective dose : 1,25 mg/l
Exposure time : 96 h
Method : OECD 201
Toxicity to microorganisms
Parameter : EC50 ( TETRAPOTASSIUM DIPHOSPHATE ; CAS No. : 7320-34-5 )
Evaluation parameter : Bacteria toxicity
Effective dose : > 1000 mg/l
Exposure time : 3h
Parameter : EC50 ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. : 5538-94-3 )
Species : Bacteria toxicity
Effective dose : 5 - 22 mg/l
Exposure time : 3h
Method : OECD 209
Parameter : EC50 ( DODECYLDIMETHYLBENZYLAMMONIUM CHLORIDE ; CAS No. : 85409-22-9 )
Evaluation parameter : Bacteria toxicity
Effective dose : 7,75 mg/l
Exposure time : 3h
Method : OECD 209
Parameter : EC50 ( POTASSIUM HYDROXIDE ; CAS No. : 1310-58-3 )
Evaluation parameter : Bacteria toxicity
Effective dose : 22 mg/l
Exposure time : 15 min

Page : 9 / 13
( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : Orotol® plus Disinfection of suction system


Revision date : 16.12.2019 Version (Revision) : 6.0.0 (5.0.0)
Print date : 19.02.2020

Terrestrial toxicity
Toxicity to birds
Bird reproduction toxicity
Parameter : Bird reproduction toxicity ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. :
5538-94-3 )
Species : Colinus virginianus (bobwhite quail)
Evaluation parameter : Acute and subchronic bird toxicity
Effective dose : 1300 ppm
Exposure time : 192 h
Parameter : Bird reproduction toxicity ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE ; CAS No. :
5538-94-3 )
Species : Anas platyrhynchos (maillard duck)
Evaluation parameter : Acute and subchronic bird toxicity
Effective dose : > 2500 ppm
Exposure time : 192 h
Sewage treatment plant
Technically correct releases of minimal concentrations to adapted biological sewage plants, will not disturb the
biodegradability of activated sludge.
12.2 Persistence and degradability
Abiotic degradation
No data available.
Biodegradation
The product is easily biodegradable according to OECD criteria. Method : OECD 301 D.
12.3 Bioaccumulative potential
No information available.
12.4 Mobility in soil
Distribution
There are no data available on the preparation itself.
12.5 Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6 Other adverse effects
No information available.
12.7 Additional ecotoxicological information
Prevent from flowing into surface water/ground water.

SECTION 13: Disposal considerations

13.1 Waste treatment methods


No information available.

SECTION 14: Transport information

14.1 UN number
UN 1719
14.2 UN proper shipping name
Land transport (ADR/RID)
CAUSTIC ALKALI LIQUID, N.O.S. ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE · POTASSIUM HYDROXIDE )
Sea transport (IMDG)
CAUSTIC ALKALI LIQUID, N.O.S. ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE · POTASSIUM HYDROXIDE )
Air transport (ICAO-TI / IATA-DGR)
CAUSTIC ALKALI LIQUID, N.O.S. ( DIMETHYLDIOCTYLAMMONIUMCHLORIDE · POTASSIUM HYDROXIDE )

Page : 10 / 13
( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : Orotol® plus Disinfection of suction system


Revision date : 16.12.2019 Version (Revision) : 6.0.0 (5.0.0)
Print date : 19.02.2020

14.3 Transport hazard class(es)


Land transport (ADR/RID)
Class(es) : 8
Classification code : C5
Hazard identification number (Kemler
No.) : 80
Tunnel restriction code : E
Special provisions : LQ 5 l · E 1
Hazard label(s) : 8
Sea transport (IMDG)
Class(es) : 8
EmS-No. : F-A / S-B
Special provisions : LQ 5 l · E 1
Hazard label(s) : 8
Air transport (ICAO-TI / IATA-DGR)
Class(es) : 8
Special provisions : E1
Hazard label(s) : 8
14.4 Packing group
III
14.5 Environmental hazards
Land transport (ADR/RID) : No
Sea transport (IMDG) : No
Air transport (ICAO-TI / IATA-DGR) : No
14.6 Special precautions for user
None
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
not applicable

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or


15.1
mixture
EU legislation
Authorisations and/or restrictions on use
Restrictions on use
Use restriction according to REACH annex XVII, no. : 3
National regulations
Restrictions of occupation
According to directive 94/33/EC, juveniles are only allowed to handle this product as long as all effects of dangerous
substances are prevented.
15.2 Chemical safety assessment
For this mixture a chemical safety assessment has not been carried out.

SECTION 16: Other information

16.1 Indication of changes


02. Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Environmental hazards
16.2 Abbreviations and acronyms
ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road
ATE = Acute Toxicity Estimates

Page : 11 / 13
( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : Orotol® plus Disinfection of suction system


Revision date : 16.12.2019 Version (Revision) : 6.0.0 (5.0.0)
Print date : 19.02.2020

CAS = Chemical Abstracts Service


CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
CMR = Carcinogen, Mutagen or Reproductive toxicant
CO₂ = Carbon dioxide
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EC = European Commission
EC50 = Half maximal effective concentration
EN = European Standard (Norm)
EU = European Union
EUH statement = CLP-specific Hazard statement
EWC = European Waste Catalogue
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
H statement = GHS Hazard statement
IATA = International Air Transport Association ICAO-TI = International Civil Aviation Organization-Technical Instructions
IMDG = International Maritime Dangerous Goods
LC50 = Median lethal concentration
LD50 = Median lethal dose
LogPow = Logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol
of 1978. ("Marpol" = marine pollution)
NOEC/NOEL = No observed effect concentration/level
OECD = Organisation for Economic Co-operation and Development
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation [Regulation (EC) No.
1907/2006]
RID = The Regulations concerning the International Carriage of Dangerous Goods by Rail
RMM = Risk Management Measure
RRN = REACH Registration Number
STOT-RE = Specific Target Organ Toxicity - Repeated Exposure
STOT-SE = Specific Target Organ Toxicity - Single Exposure
SVHC = Substances of Very High Concern
TLV/STEL = Threshold limit value/short-term exposure limit
TLV/TWA = Threshold limit value/time weighted average
UN = United Nations
VOC = Volatile Organic Compound
vPvB = Very Persistent and Very Bioaccumulative
16.3 Key literature references and sources for data
None
Classification for mixtures and used evaluation method according to regulation (EC)
16.4
No 1272/2008 [CLP]
No information available.
16.5 Relevant H- and EUH-phrases (Number and full text)
H226 Flammable liquid and vapour.
H290 May be corrosive to metals.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H310 Fatal in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.

Page : 12 / 13
( EN / GB )
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : Orotol® plus Disinfection of suction system


Revision date : 16.12.2019 Version (Revision) : 6.0.0 (5.0.0)
Print date : 19.02.2020

16.6 Training advice


None
16.7 Additional information
Notice the directions for use on the label.

The above information describes exclusively the safety requirements of the product and is based on our present-day
knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data
sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of
mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily
valid for the new made-up material.

Page : 13 / 13
( EN / GB )

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