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John

D a l t o n ’ s
Atomic Theory
The atomic theory was a philosophical speculation that all things can
be accounted for by innumerable combinations of hard, small,
indivisible particles (called atoms) of various sizes but of the same
primary material; or the modern scientific theory of matter according
to which the chemical elements that combine to form the great
variety of substances consist themselves of aggregations of similar
subunits (atoms) possessing nuclear and electron substructure
characteristic of each element. The ancient atomic theory was
proposed in the 5th century BCE by the Greek philosophers Leucippus
and Democritus. It was revived in the 1st century BCE by the Roman
philosopher and poet Lucretius. The modern atomic theory, which has
undergone continuous refinement, began to flourish at the beginning
of the 19th century with the work of the English chemist John Dalton.
John Dalton
Was an English chemist, physicist and influential scientist of the
eighteenth and nineteenth centuries, John Dalton was born into a
Quaker family on September 5 or 6, 1766, in Eaglesfield, Cumberland,
England and died on July 27, 1844 Manchester England . The members
of the Dalton family were tradesmen, but his mother came from a
wealthy family. John was the youngest of the three surviving ch po
ildren, and he attended a Quaker grammar school. At the age of
twelve, John's older brother took over the school and often asked
John to assist in teaching.
Furthermore
In 1793, John Dalton joined the faculty of the Manchester Academy, The New
College, as a mathematics instructor. During that time, he also published his
work Meteorological Observations and Essays. Through the duration of his
early research years, Dalton proposed many ideas such as that of the
atmosphere being composed of a mixture of gases. He also studied color
blindness and the atomic masses of atoms. The atomic mass research later
led to several scientific laws and theories.

In his fifties, John Dalton was awarded an honorary doctorate from Oxford,
was elected into the fellowship of the Royal Society of London and became
one of eight members of the French Academy of Sciences.
Dalton’s
Atomic Theory
Dalton's study of gases, their atomic
masses, and their tendency to
combine atoms in small, whole-
number ratios of fixed mass led to the
development of Dalton's Atomic
Theory, most of which holds true
today.
Atomic Theory
Dalton’s atomic theory was a scientific theory on the nature of matter in the year 1803. It stated that
all matter was made up of small, indivisible particles known as ‘atoms’. It was the first complete
attempt to describe all matter in terms of atoms and their properties.

Dalton based his theory on two laws: the law of conservation of mass and the law of constant
composition.
The law of conservation of mass says that matter is not created or destroyed in a closed system.
That means if we have a chemical reaction, the amount of each element must be the same in the
starting materials and the products. The law of constant composition says that a pure compound will
always have the same proportion of the same elements.

The postulates of Dalton's theory were:


- All matter is made up of tiny, indivisible particles called atoms.
- All atoms of a specific element are identical in mass, size, and other properties. However, atoms of
different elements exhibit different properties and vary in mass and size.
- Atoms can neither be created nor destroyed. Furthermore, atoms cannot be divided into smaller
particles.
- Atoms of different elements can combine with each other in fixed whole-number ratios in order to
form compounds.
- Atoms can be rearranged, combined, or separated in chemical reactions.
Atomic Theory
Although, there were some limitations to Dalton's Theory.

It does not account for subatomic particles. Dalton’s atomic theory stated that atoms
were indivisible. However, the discovery of subatomic particles (such as protons, electrons,
and neutrons) disproved this postulate. It does not account for isotopes. As per Dalton’s
atomic theory, all atoms of an element have identical masses and densities. However,
different isotopes of elements have different atomic masses (For example: hydrogen,
deuterium, and tritium). It does not account for isobars: This theory states that the masses
of the atoms of two different elements must differ. However, it is possible for two different
elements to share the same mass number. Such atoms are called isobars. Elements need
not combine in simple, whole-number ratios to form compounds. Certain complex organic
compounds do not feature simple ratios of constituent atoms. Example: sugar/sucrose.
The theory does not account for allotropes. The differences in the properties of diamond
and graphite, both of which contain only carbon, cannot be explained by Dalton’s atomic
theory.
How?
Due to his interest and fascination in gases and how they interact with each other, John
Dalton created a study that examined the properties of atmospheric gases.

This study was conducted in 1803 and it involved the combination of oxygen with one-
two volumes of nitric oxide contained in closed vessels over water. This study showed
that oxygen interacted with either one or two volumes of nitric oxide, this was an
observation of integral multiple proportions. Although it is to be noted that future
attempts to recreate this study have been unsuccessful which leads some people to
believe that these results were fraudulent.

John Dalton stated that when two elements combine with each other to form two or
more compounds, the ratios of the masses of one element that combines with the fixed
mass of the other are whole numbers. This is now called John Dalton's law of integral
multiple proportions and it served as a basis for his atomic theory and how atoms not
only make up matter, but how they interact with each other as well.
Why was it
rejected?
John Dalton proposed his theory on 1808. It is not the
same for Rutherford's atomic theory for subatomic
particles: Dalton's atomic theory stated that atoms
were indivisible. However, the discovery of subatomic
particles (such as protons, electrons, and neutrons)
disproved this postulate.. Thereforre another model of
an atom was made
I t s t i m e
t o a s k !
Atomic Theory
e f e r e n c e s :
R
https://www.khanacademy.org/science/chemistry/electronic-structure-of-
atoms/history-of-atomic-structure/a/daltons-atomic-theory-version-2

https://www.britannica.com/biography/John-
Dalton/Atomic-theory

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