SAFETY DATA SHEET (REGULATION (EC) n° 1907/2006 - REACH) Date : 06/01/2020 Page 1/7

Version : N°1 (06/01/2020) Revision : N°3 (06/01/2020)

LABORATOIRES DUJARDIN-SALLERON
GLASS CLEANER - 972500

SAFETY DATA SHEET

(REACH regulation (EC) n° 1907/2006 - n° 2015/830)

SECTION 1 : IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier
Product name : GLASS CLEANER
Product code : 972500.
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Alkaline detergent ready to use for cleaning laboratory glassware
1.3. Details of the supplier of the safety data sheet
Registered company name : LABORATOIRES DUJARDIN-SALLERON.
Address : 872 route de la gare.37210.NOIZAY.FRANCE.
Telephone : +33 (0)2 47 25 58 25. Fax : +33 (0)2 47 25 58 30.
info@dujardin-salleron.com
www.dujardin-salleron.com
1.4. Emergency telephone number : +33 (0)1 45 42 59 59.
Association/Organisation : INRS / ORFILA http://www.centres-antipoison.net.

SECTION 2 : HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture
In compliance with EC regulation No. 1272/2008 and its amendments.
Skin irritation, Category 2 (Skin Irrit. 2, H315).
Eye irritation, Category 2 (Eye Irrit. 2, H319).
This mixture does not present a physical hazard. Refer to the recommendations regarding the other products present on the site.
This mixture does not present an environmental hazard. No known or foreseeable environmental damage under standard conditions of use.
2.2. Label elements
Detergent mixture (see section 15).
In compliance with EC regulation No. 1272/2008 and its amendments.
Hazard pictograms :

GHS07
Signal Word :
WARNING
Hazard statements :
H315 Causes skin irritation.
H319 Causes serious eye irritation.
Precautionary statements - Response :
P302 + P352 IF ON SKIN: Wash with plenty of water/...
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P321 Specific treatment (see ... on this label).
P337 + P313 If eye irritation persists: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
2.3. Other hazards
The mixture does not contain substances classified as ‘Substances of Very High Concern' (SVHC) >= 0.1% published by the European
CHemicals Agency (ECHA) under article 57 of REACH: http://echa.europa.eu/fr/candidate-list-table
The mixture fulfils neither the PBT nor the vPvB criteria for mixtures in accordance with annexe XIII of the REACH regulations EC
1907/2006.

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Version : N°1 (06/01/2020) Revision : N°3 (06/01/2020)
LABORATOIRES DUJARDIN-SALLERON
GLASS CLEANER - 972500

SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures
Composition :
Identification (EC) 1272/2008 Note %
INDEX: 019-002-00-8 GHS05, GHS07 [1] 0 <= x % < 1
CAS: 1310-58-3 Dgr
EC: 215-181-3 Acute Tox. 4, H302
REACH: 01-2119487136-33-XXXX Skin Corr. 1A, H314

POTASSIUM HYDROXIDE
(Full text of H-phrases: see section 16)
Information on ingredients :
[1] Substance for which maximum workplace exposure limits are available.

SECTION 4 : FIRST AID MEASURES

As a general rule, in case of doubt or if symptoms persist, always call a doctor.
NEVER induce swallowing by an unconscious person.
4.1. Description of first aid measures
In the event of splashes or contact with eyes :
Wash thoroughly with fresh, clean water for 15 minutes holding the eyelids open.
If there is any redness, pain or visual impairment, consult an ophthalmologist.
In the event of splashes or contact with skin :
Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.
Watch out for any remaining product between skin and clothing, watches, shoes, etc.
If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital.
In the event of swallowing :
Do not give the patient anything orally.
Seek medical attention immediately, showing the label.
4.2. Most important symptoms and effects, both acute and delayed
No data available.
4.3. Indication of any immediate medical attention and special treatment needed
No data available.

SECTION 5 : FIREFIGHTING MEASURES

Non-flammable.
5.1. Extinguishing media
Suitable methods of extinction
Use extinguishing measures that appropiate to local circumstances and the surrounding environment.
5.2. Special hazards arising from the substance or mixture
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
Do not breathe in smoke.
In the event of a fire, the following may be formed :
- carbon monoxide (CO)
- carbon dioxide (CO2)
5.3. Advice for firefighters
Use self-contained breathing apparatus and full protective suit.

SECTION 6 : ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
Consult the safety measures listed under headings 7 and 8.
For non first aid worker
Avoid any contact with the skin and eyes.

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LABORATOIRES DUJARDIN-SALLERON
GLASS CLEANER - 972500

For first aid worker

First aid workers will be equipped with suitable personal protective equipment (See section 8).
6.2. Environmental precautions
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums
for waste disposal.
Prevent any material from entering drains or waterways.
6.3. Methods and material for containment and cleaning up
Clean preferably with a detergent, do not use solvents.
If the soil becomes soiled, and after recovery of the product by blotting it with an inert, non-combustible absorbent material, wah the soiled
surface with large amounts of water.
6.4. Reference to other sections
No data available.

SECTION 7 : HANDLING AND STORAGE

Requirements relating to storage premises apply to all facilities where the mixture is handled.
7.1. Precautions for safe handling
Always wash hands after handling.
Remove and wash contaminated clothing before re-using.
Fire prevention :
Prevent access by unauthorised personnel.
Recommended equipment and procedures :
For personal protection, see section 8.
Observe precautions stated on label and also industrial safety regulations.
Avoid skin and eye contact with this mixture.
Prohibited equipment and procedures :
No smoking, eating or drinking in areas where the mixture is used.
7.2. Conditions for safe storage, including any incompatibilities
Keep containers tightly closed
Storage
Store frost-free
Packaging
Always keep in packaging made of an identical material to the original.
7.3. Specific end use(s)
Professional use only.

SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters
Occupational exposure limits :
- ACGIH TLV (American Conference of Governmental Industrial Hygienists, Threshold Limit Values, 2010) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
1310-58-3 2 mg/m3
- France (INRS - ED984 :2016) :
CAS VME-ppm : VME-mg/m3 : VLE-ppm : VLE-mg/m3 : Notes : TMP No :
1310-58-3 - - - 2 - -
- UK / WEL (Workplace exposure limits, EH40/2005, 2011) :
CAS TWA : STEL : Ceiling : Definition : Criteria :
1310-58-3 - ppm - ppm
- mg/m³ 2 mg/m³
Derived no effect level (DNEL) or derived minimum effect level (DMEL):
POTASSIUM HYDROXIDE (CAS: 1310-58-3)
Final use: Workers.
Exposure method: Inhalation.
Potential health effects: Long term local effects.
DNEL : 1 mg of substance/m3

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LABORATOIRES DUJARDIN-SALLERON
GLASS CLEANER - 972500

8.2. Exposure controls

Personal protection measures, such as personal protective equipment
Pictogram(s) indicating the obligation of wearing personal protective equipment (PPE) :

Use personal protective equipment that is clean and has been properly maintained.
Store personal protective equipment in a clean place, away from the work area.
Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation,
especially in confined areas.
- Eye / face protection
Avoid contact with eyes.
Use eye protectors designed to protect against liquid splashes
Before handling, wear safety goggles with protective sides accordance with standard EN166.
In the event of high danger, protect the face with a face shield.
Prescription glasses are not considered as protection.
Individuals wearing contact lenses should wear prescription glasses during work where they may be exposed to irritant vapours.
Provide eyewash stations in facilities where the product is handled constantly.
- Hand protection
Wear suitable protective gloves in the event of prolonged or repeated skin contact.
Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374.
Gloves must be selected according to the application and duration of use at the workstation.
Protective gloves need to be selected according to their suitability for the workstation in question : other chemical products that may be
handled, necessary physical protections (cutting, pricking, heat protection), level of dexterity required.
Type of gloves recommended :
- Natural latex
- PVC (polyvinyl chloride)
- Nitrile rubber (butadiene-acrylonitrile copolymer rubber (NBR))
Recommended properties :
- Impervious gloves in accordance with standard EN374
- Body protection
Avoid skin contact.
Wear suitable protective clothing.
Suitable type of protective clothing :
In the event of substantial spatter, wear liquid-tight protective clothing against chemical risks (type 3) in accordance with EN14605 to prevent
skin contact.
In the event of a risk of splashing, wear protective clothing against chemical risks (type 6) in accordance with EN13034 to prevent skin
contact.
Work clothing worn by personnel shall be laundered regularly.
After contact with the product, all parts of the body that have been soiled must be washed.

SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties
General information :
Physical state : Fluid liquid.
Important health, safety and environmental information
pH : 12.50 .
Strongly basic.
Boiling point/boiling range : Not specified.
Flash point interval : Not relevant.
Vapour pressure (50°C) : Below 110 kPa (1.10 bar).
Density : >1
Water solubility : Insoluble.
Melting point/melting range : Not specified.
Self-ignition temperature : Not specified.

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LABORATOIRES DUJARDIN-SALLERON
GLASS CLEANER - 972500

Decomposition point/decomposition range : Not specified.

9.2. Other information
No data available.

SECTION 10 : STABILITY AND REACTIVITY

10.1. Reactivity
No dangerous reaction if handling and storage conditions are observed.
10.2. Chemical stability
This mixture is stable under the recommended handling and storage conditions in section 7.
10.3. Possibility of hazardous reactions
No data available.
10.4. Conditions to avoid
Avoid :
- frost
10.5. Incompatible materials
No data available.
10.6. Hazardous decomposition products
The thermal decomposition may release/form :
- carbon monoxide (CO)
- carbon dioxide (CO2)

SECTION 11 : TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects
May cause irreversible damage to the skin; namely inflammation of the skin or the formation of erythema and eschar or oedema following
exposure up to four hours.
May have reversible effects on the eyes, such as eye irritation which is totally reversible by the end of observation at 21 days.
11.1.1. Substances
No toxicological data available for the substances.
11.1.2. Mixture
No toxicological data available for the mixture.

SECTION 12 : ECOLOGICAL INFORMATION

12.1. Toxicity
12.1.2. Mixtures
No aquatic toxicity data available for the mixture.
12.2. Persistence and degradability
No data available.
12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
No data available.
12.6. Other adverse effects
No data available.
German regulations concerning the classification of hazards for water (WGK, AwSV vom 18/04/2017, KBws) :
WGK 1 : Slightly hazardous for water.

SECTION 13 : DISPOSAL CONSIDERATIONS

Proper waste management of the mixture and/or its container must be determined in accordance with Directive 2008/98/EC.
13.1. Waste treatment methods
Do not pour into drains or waterways.

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LABORATOIRES DUJARDIN-SALLERON
GLASS CLEANER - 972500

Waste :
Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water,
air, soil, plants or animals.
Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.
Do not contaminate the ground or water with waste, do not dispose of waste into the environment.
Soiled packaging :
Empty container completely. Keep label(s) on container.
Give to a certified disposal contractor.

SECTION 14 : TRANSPORT INFORMATION

Exempt from transport classification and labelling.
14.1. UN number
-
14.2. UN proper shipping name
-
14.3. Transport hazard class(es)
-
14.4. Packing group
-
14.5. Environmental hazards
-
14.6. Special precautions for user
-

SECTION 15 : REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
- Classification and labelling information included in section 2:
The following regulations have been used:
- EU Regulation No. 1272/2008 amended by EU Regulation No. 2018/1480 (ATP 13)
- EU Regulation No. 1272/2008 amended by EU Regulation No. 2019/521 (ATP 12)
- Container information:
No data available.
- Particular provisions :
No data available.
- Labelling for detergents (EC Regulation No. 648/2004,907/2006) :
- less than 5 % : phosphates
- less than 5 % : anionic surfactants
- less than 5 % : nonionic surfactants
- less than 5 % : EDTA and salts thereof
- German regulations concerning the classification of hazards for water (WGK, AwSV vom 18/04/2017, KBws) :
WGK 1 : Slightly hazardous for water.
15.2. Chemical safety assessment
No data available.

SECTION 16 : OTHER INFORMATION

Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of
knowledge and on national and community regulations.
The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling instructions.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations.
The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a
guarantee of the properties thereof.
Wording of the phrases mentioned in section 3 :
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.

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LABORATOIRES DUJARDIN-SALLERON
GLASS CLEANER - 972500

Abbreviations :
DNEL : Derived No-Effect Level
ADR : European agreement concerning the international carriage of dangerous goods by Road.
IMDG : International Maritime Dangerous Goods.
IATA : International Air Transport Association.
ICAO : International Civil Aviation Organisation
RID : Regulations concerning the International carriage of Dangerous goods by rail.
WGK : Wassergefahrdungsklasse (Water Hazard Class).
GHS07 : Exclamation mark
PBT: Persistent, bioaccumulable and toxic.
vPvB : Very persistent, very bioaccumulable.
SVHC : Substances of very high concern.

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