Psychrometry
Psychrometry
Psychrometry
Psychrometrics
• The science which investigates the thermal properties of moist air, considers the measurement
and control of the moisture content of air, and studies the effect of atmospheric moisture on
material and human comfort may properly be termed “psychrometrics’’.
• Dry air. The international joint committee on Psychrometric Data has adopted the following
exact composition of air expressed in mole fractions (Volumetric) Oxygen 0.2095, Nitrogen
0.7809, Argon 0.0093, Carbon dioxide 0.0003. Traces of rare gases are neglected. Molecular
weight of air for all air conditioning calculations will be taken as 28.97. Hence the gas constant,
Dry air is never found in practice. Air always contains some moisture. Hence the common
designation “air” usually means moist air. The term ‘dry air’ is used to indicate the water free
contents of air having any degree of moisture.
• Adiabatic saturation temperature. It is the temperature at which the water or ice can
saturate air by evaporating adiabatically into it. It is numerically equivalent to the measured
wet bulb temperature (Tw).
• Wet bulb depression. It is the difference between dry-bulb and wet bulb temperatures (Td –
Tw).
23 October 2020 Dr. R. Shanthi 3
• Dew point temperature (DPT). It is the temperature to which air must be cooled at constant
pressure in order to cause condensation of any of its water vapour. It is equal to steam table
saturation temperature corresponding to the actual partial pressure of water vapour in the air
(Tdp).
• Dew point depression. It is the difference between the dry bulb and dew point temperatures
(Td – Tdp).
• Specific humidity (Humidity ratio). It is the ratio of the mass of water vapour per unit
mass of dry air in the mixture of vapour and air, it is generally expressed as grams of water per
kg of dry air. For a given barometric pressure it is a function of dew point temperature alone.
• Relative humidity (RH), (φ). It is the ratio of the partial pressure of water vapour in the
mixture to the saturated partial pressure at the dry bulb temperature, expressed as
percentage.
• Latent heat. It is the heat that does not affect the temperature but changes the state of
substance when added to or abstracted from it.
• Enthalpy. It is the combination energy which represents the sum of internal and flow energy
in a steady flow process and is expressed as kJ per kg of dry air (h).
of gases. This law states that the total pressure of a mixture of gases is equal to the sum of
partial pressures.
• For calculating partial pressure of water vapour in the air many equations have been proposed,
Ra = 0.287 kJ/kg K
Rv = 0.462 kJ/kg K
where va = Specific volume of dry air, and vv = Specific volume of water vapour.
where pvs = Partial pressure of water vapour when air is fully saturated (pvs can be calculated
from steam tables corresponding to the dry bulb temperature of the air)
𝑝𝑣
∅=
𝑝𝑣𝑠
𝑝𝑣 𝑉 = 𝑚𝑣 𝑅𝑇
𝑝𝑣𝑠 𝑉 = 𝑚𝑣𝑠 𝑅𝑇
𝑚𝑣 𝑅𝑇
∅=
𝑚𝑣𝑠 𝑅𝑇
𝑚𝑣 𝑝𝑣
∅= =
𝑚𝑣𝑠 𝑝𝑣𝑠
𝒉 = 𝑪𝒑 𝑻𝒂 + 𝑾 𝒉𝒈 + 𝟏. 𝟖𝟖 𝑻𝒅 − 𝑻𝒅𝒑
Given:
p = 1.0132 bar
h= 80 kJ/kg
DBT, Td = 32°C
WBT, Tw = 26°C (0.0182)
Solutuion:
(b) the specific humidity
From Psychrometric chart,
W1 = 0.0182 kg vap/ kg of dry air
From steam tables for pv = 0.03 bar, T = 24.1°C 𝑝𝑣 𝑝𝑡 − 𝑝𝑣𝑠 0.03 1.0132 − 0.048
𝜇= =
𝑝𝑣𝑠 𝑝𝑡 − 𝑝𝑣 0.048 1.0132 − 0.03
Dew point temperature, Tdp = 24.1°C
𝝁 =?
𝝁 = 𝟎. 𝟔𝟏𝟒
23 October 2020 Dr. R. Shanthi 16
(f) the density of the air in the mixture (h) the enthalpy of the mixture
We Know that p= pa + pv From chart, h= 80 kJ/kg
Partial pressure of dry air in the mixture, pa= p – pv (or)
pa= 1.0132 – 0.03 = 0.9832 bar 𝒉 = 𝒉𝒂 + 𝑾𝒉𝒗
pa Va = Ra Td
𝒉 = 𝑪𝒑 𝑻𝒂 + 𝑾 𝒉𝒈 + 𝟏. 𝟖𝟖 𝑻𝒅 − 𝑻𝒅𝒑
1 𝑝𝑎 0.9832 × 105 From steam tables, for Td = 32°C, hg = 2559.9 kJ/kg
𝜌𝑎 = = =
𝑉𝑎 𝑅𝑎 𝑇𝑎 0.287 × 103 × (32 + 273) ℎ = 1.005 × 32 + 0.0189 × 2559.9 + 1.88 32 − 24.1
𝝆𝒂 =? 𝒉 =?
𝝆𝒂 = 𝟏. 𝟏𝟐 𝒌𝒈/𝒎𝟑 𝒅𝒓𝒚𝒂𝒊𝒓 𝒉 = 𝟖𝟎. 𝟖𝟐 𝒌𝑱/𝒌𝒈 (approx)
(g) the density of the vapour in the mixture (or)
𝝆𝒗 = 𝑾 × 𝝆𝒂 𝒉 = 𝑪𝒑 𝑻𝒂 + 𝑾 𝒉𝒈 + 𝟏. 𝟖𝟖 𝑻𝒅 − 𝑻𝒅𝒑
𝑘𝑔 𝑣𝑎𝑝 𝑘𝑔 𝑑𝑟𝑦 𝑎𝑖𝑟 From steam tables, for Tdp = 24.1°C, hg = 2545.5 kJ/kg
𝜌𝑣 = 0.0189 3 air × 1.12 3
𝑚 𝑑𝑟𝑦 𝑎𝑖𝑟 𝑚 𝑑𝑟𝑦𝑎𝑖𝑟
ℎ = 1.005 × 32 + 0.0189 × 2545.5 + 1.88 32 − 24.1
𝝆𝒗 =? 𝒉 =?
𝝆𝒗 = 𝟎. 𝟎𝟐𝟏𝒌𝒈 𝒗𝒂𝒑/𝒎𝟑 𝒅𝒓𝒚𝒂𝒊𝒓 𝒉 = 𝟖𝟎. 𝟓𝟓 𝒌𝑱/𝒌𝒈
23 October 2020 Dr. R. Shanthi 17
Problem 2: The atmospheric conditions are ; 20°C and specific humidity of 0.0095 kg/kg of dry air.
Calculate the following : (i) Partial pressure of vapour (ii) Relative humidity (iii) Dew point temperature.
Given: From Steam tables for Td = 20°C, p = 0.0234 bar
DBT, Td = 20°C 𝑝𝑣𝑠 = 0.0234 𝑏𝑎𝑟
Specific humidity, W = 0.0095 kg/kg of dry air
0.001524
∅=
Solution: 0.0234
∅=?
(i) Partial pressure of vapour, pv :
∅ = 𝟎. 𝟔𝟓 = 𝟔𝟓%
𝑝𝑣
𝑆𝑝𝑒𝑐𝑖𝑓𝑖𝑐 ℎ𝑢𝑚𝑖𝑑𝑖𝑡𝑦, 𝑊 = 0.622 (iii) Dew point temperature, Tdp :
𝑝 − 𝑝𝑣
𝑝𝑣 The dew point temperature is the saturation
0.0095 = 0.622
1.0132 − 𝑝𝑣
temperature of water vapour at a pressure of 0.01524
𝒑𝒗 =?
bar, Tdp [from steam tables by interpolation]
𝒑𝒗 = 0.01524 bar
Tdp= 13.24°C
(ii) Relative humidity:
𝑝𝑣
∅=
𝑝𝑣𝑠
23 October 2020 Dr. R. Shanthi 18
Problem 3: 0.004 kg of water vapour per kg of atmospheric air is removed and temperature of air after
removing the water vapour becomes 20°C. Determine : (i) Relative humidity (ii) Dew point temperature.
Assume that condition of atmospheric air is 30°C and 55% R.H. and pressure is 1.0132 bar.
0.0171
𝑅𝑒𝑙𝑎𝑡𝑖𝑣𝑒 ℎ𝑢𝑚𝑖𝑑𝑖𝑡𝑦, ∅ =
0.0234
∅ =?
∅ = 0.73 or 73%.
(ii) Dew point temperature, Tdp :
The dew point temperature is the saturation temperature of water vapour at a pressure
of 0.0171 bar, Tdp
Tdp= 15°C
1. Sensible heating
2. Sensible cooling
• Thus the heating can be achieved by passing the air over heating coil
like electric resistance heating coils or steam coils.
• The by-pass factor (BF) for the process is defined as the ratio of the
difference between the mean surface temperature of the coil and
leaving air temperature to the difference between the mean surface
temperature and the entering air temperature.
𝑻𝒅𝟑 − 𝑻𝒅𝟐
𝑩𝑭 =
𝑻𝒅𝟑 − 𝑻𝒅𝟏
𝑾𝟏 = 𝑾𝟐
Energy balance,
∅𝟐 = 𝟒𝟐. 𝟓 %
𝑝𝑣 𝒎𝒂 =?
𝑅𝑒𝑙𝑎𝑡𝑖𝑣𝑒 ℎ𝑢𝑚𝑖𝑑𝑖𝑡𝑦, ∅ =
𝑝𝑣𝑠
𝒎𝒂 = 𝟏𝟎𝟔. 𝟓 𝒌𝒈/𝒎𝒊𝒏
𝑝𝑣
0.75 =
0.0234 Amount of heat added per minute = 𝒎𝒂 (h2 –h1)
𝒑𝒗 =?
= 106.5 (58.5 – 47.5) = ?
𝒑𝒗 = 0.01755 bar
Mass of dry air in 90 m3 of air supplied = 1171.5 kJ/kg
𝑝𝑎 𝑉 = 𝑚𝑎 𝑅𝑎 𝑇
𝑝𝑎 𝑉 𝑝 − 𝑝𝑣 𝑉
𝑚𝑎 = =
𝑚𝑎 𝑅𝑎 𝑇 𝑅𝑎 𝑇
• Thus sensible cooling can be achieved by passing the air over cooling
coil like evaporating coil of the refrigeration cycle or secondary brine
coil.
• During the process, the specific humidity remains constant and dry
bulb temperature decreases.
• The by-pass factor (BF) for the process is defined as the ratio of the
difference between the mean surface temperature of the coil and
leaving air temperature to the difference between the mean surface
temperature and the entering air temperature.
Td3 Td2 Td1
𝑻𝒅𝟐 − 𝑻𝒅𝟑
𝑩𝑭 =
𝑻𝒅𝟏 − 𝑻𝒅𝟑
𝑾𝟏 = 𝑾𝟐
Energy balance,
∅1 = 50 % h2 = 71 kJ/kg
Td2 = 25°C
∅ 2 = 82.5%
Solution:
From Chart,
h1 = 80 kJ/kg
W = 0.0175 kg/kg of dry air
h2 = 71 J/kg
∅𝟐 = 𝟖𝟐. 𝟓 %
∅𝟐 = 𝟖𝟐. 𝟓 %
23 October 2020 Dr. R. Shanthi 28
(ii) Heat removed from air.
Corresponding to 25ºC, from steam tables, 1.0132 − 0.0262 × 105 × 40
𝑚𝑎 =
0.287 × 103 (25 + 273)
pvs = 0.0262 bar
𝑝𝑣 𝒎𝒂 =?
𝑅𝑒𝑙𝑎𝑡𝑖𝑣𝑒 ℎ𝑢𝑚𝑖𝑑𝑖𝑡𝑦, ∅ =
𝑝𝑣𝑠
𝒎𝒂 = 𝟒𝟕 𝒌𝒈
𝑝𝑣
0.825 =
0.0317 Amount of heat added per minute = 𝒎𝒂 (h1 –h2)
𝒑𝒗 =?
= 47 (80 – 71) = ?
𝒑𝒗 = 0.0262 bar
Mass of dry air in 90 m3 of air supplied = 423 kJ/kg
𝑝𝑎 𝑉 = 𝑚𝑎 𝑅𝑎 𝑇
𝑝𝑎 𝑉 𝑝 − 𝑝𝑣 𝑉
𝑚𝑎 = =
𝑚𝑎 𝑅𝑎 𝑇 𝑅𝑎 𝑇
𝒎𝟏 + 𝒎𝟐 = 𝒎𝟑
𝒎𝟏 𝑾𝟏 + 𝒎𝟐 𝑾𝟐 = 𝒎𝟑 𝑾𝟑 -------(1)
𝒎𝟏 𝒉𝟏 + 𝒎𝟐 𝒉𝟐 = 𝒎𝟑 𝒉𝟑 --------(2)
From chart,
h1 = 80 kJ/kg 𝑻d2 = 13°C
W2 = 0.0086
W1 = 0.0216 kg/kg of dry air kg/kg of dry air
h2 = 44 kJ/kg
W2 = 0.0086 kg/kg of dry air
Td2 = 20°C Td3 = 22°C
Td1 = 35°C
23 October 2020 Dr. R. Shanthi 31
𝒎𝟏 + 𝒎𝟐 = 𝒎𝟑
From Chart,
𝑚3 = 2 + 1 = 3 𝑘𝑔
For 𝒉𝟑 = 𝟓𝟔 𝒌𝑱/𝒌𝒈 and 𝑾𝟑 = 𝟎. 𝟎𝟏𝟐𝟗 𝒌𝒈/𝒌𝒈𝒐𝒇𝒅𝒓𝒚𝒂𝒊𝒓
𝒎𝟏 𝑾𝟏 + 𝒎𝟐 𝑾𝟐 = 𝒎𝟑 𝑾𝟑
DBT of the mixture, Td3 = 22°C
1 × 0.0216 + 2 × 0.0086 = 3 × 𝑊3 RH of the mixture, ∅3 = 80%
𝑾𝟑 =?
𝑾𝟑 = 𝟎. 𝟎𝟏𝟐𝟗 𝒌𝒈/𝒌𝒈𝒐𝒇𝒅𝒓𝒚𝒂𝒊𝒓
𝒎𝟏 𝒉𝟏 + 𝒎𝟐 𝒉𝟐 = 𝒎𝟑 𝒉𝟑
1 × 80 + 2 × 44 = 3 × ℎ3
𝒉𝟑 =?
𝒉𝟑 = 𝟓𝟔 𝒌𝑱/𝒌𝒈
𝑉2 20
𝑚2 = = =?
𝑣2 0.89
𝒎𝟐 = 𝟐𝟐. 𝟒𝟕 𝒌𝒈/𝒎𝒊𝒏
𝒎𝟏 𝑾𝟏 + 𝒎𝟐 𝑾𝟐 = 𝒎𝟑 𝑾𝟑
60.24 × 0.0099 + 22.47 × 0.018 = (60.24 + 22.47) × 𝑊3
𝑾𝟑 =?
𝑾𝟑 = 𝟎. 𝟎𝟏𝟐𝟏 𝒌𝒈/𝒌𝒈𝒐𝒇𝒅𝒓𝒚𝒂𝒊𝒓
𝒎𝟏 𝒉𝟏 + 𝒎𝟐 𝒉𝟐 = 𝒎𝟑 𝒉𝟑
60.24 × 39 + 22.47 × 79 = (60.24 + 22.47) × ℎ3
𝒉𝟑 =?
𝒉𝟑 = 𝟒𝟗. 𝟖𝟕 𝒌𝑱/𝒌𝒈
𝑉 150
𝑚𝑎 = =
𝑣1 0.885
𝒎𝒂 = ?
𝒎𝒂 = 𝟏𝟔𝟗. 𝟒𝟗 𝒌𝒈 𝒐𝒇 𝒅𝒓𝒚 𝒂𝒊𝒓/𝒎𝒊𝒏
Amount of water vapour added to the air per minute, 𝑚𝑣 = 𝑚𝑎 𝑊2 − 𝑊1
From chart, W1= 0.0065 kg/kg of dry air and W2= 0.0084 kg/kg of dry air
𝑚𝑣 = 169.49 0.0084 − 0.0065
𝒎𝒗 =?
𝒎𝒗 = 𝟎. 𝟑𝟐𝟐 𝒌𝒈/𝒎𝒊𝒏
Given:
Td1 = 10°C,
∅1 = 30 %
Td2 = 22°C 3
Td3 = 25°C
∅3 = 60 %
1 2
1 2
Td2 = 22°C Td3 = 25°C
v1=0.805 m3/kg W1=W2= 0.002kg/kg of dry
T = 10°C
23 October 2020 Dr. R. d1
Shanthi 38
(a) The rate of heat supply in the heating section,
Mass balance -(2-3 process)
1 - 2 process:
𝒎𝒂 𝑾𝟐 + 𝒎𝒗𝟐 = 𝒎𝒂 𝑾𝟑
The rate of heat supply in the heating section = 𝒎𝒂 (h2 –h1)
𝑚𝑣2 = 𝑚𝑎 (𝑊3 −𝑊2 )
From chart, v1=0.805 m3/kg of dry air
= 55.9 × (0.012 − 0.002)
𝑉1 45
𝑚𝑎 = = 𝒎𝒗𝟐 = 𝟎. 𝟓𝟓𝟗 𝒌𝒈/𝒎𝒊𝒏
𝑣1 0.805
𝒎𝒂 = ?
𝒎𝒂 = 𝟓𝟓. 𝟗 𝒌𝒈 𝒐𝒇 𝒅𝒓𝒚 𝒂𝒊𝒓/𝒎𝒊𝒏
The rate of heat supply in the heating section = 55.9 ×(27 –15)
𝐐 = 𝟔𝟕𝟎. 𝟖 𝒌𝑱/𝒌𝒈
(b) The mass flow rate of the steam requires in the
humidifying section.
Let 𝒎𝒗𝟐 be the amount of steam sprayed in the humidifying
section.
Given:
Td1 = 3°C,
∅1 = 100 %
Td3 = 22°C,
∅3 = 55 %
𝑅𝑎 𝑇𝑑3 𝑅𝑎 × 𝑇𝑑3
𝑣𝑎3 = =
𝑝𝑎2 (𝑝 − 𝑝𝑣3 )
𝑊3 − 𝑊1 0.00434
𝑚𝑎𝑠𝑠 𝑜𝑓 𝑠𝑝𝑟𝑎𝑦 𝑤𝑎𝑡𝑒𝑟 = = =?
𝑣𝑎3 0.843
𝒎𝒂𝒔𝒔 𝒐𝒇 𝒔𝒑𝒓𝒂𝒚 𝒘𝒂𝒕𝒆𝒓 = 0.005124 kg moisture/m3
1 2
Td3 = 22°C
23 October 2020 Td1 = 3°C
Dr. R. Shanthi 43
Cooling and dehumidification
• The removal of water vapour from air is termed as dehumidification. Td3
• Dehumidification is possible only if the air is cooled below the dew point
temperature of the air.
• It is necessary to maintain the coil surface temperature below the dew
point temperature for effective dehumidification. This temperature is
called ‘apparatus dew point’ (ADP).
• Td1 – Temp entering the coil
• Td3 – Coil surface temperature
• Td2 – dew point temperature
• Under ideal conditions, the air leaving the coil will at condition ‘3’. No
cooling 100 % efficient. SO the condition of the air coming out of the coil
will be represented by point ‘4’ somewhere between ‘1’ and ‘3’ depending
upon the coil effectiveness
Td3 Td4 Td1
ADP = 13°C 1
Solution:
h2 = 56 kJ/kg
Fromh1 Chart,
= 82 kJ/kg
h3 = 48 kJ/kg
h4 = 37 kJ/kg
h3 = 48 kJ/kg
3
2 W2 = 0.012kg/kg
h2 = 56 kJ/kg of dry air
𝑨𝑫𝑷= 13°C
h4 = 37 kJ/kg
4
3 2
4
Td4= 13°C
Td3= 17°C 0.892 m3/kg