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MSDS Fleetguard ES Complete EG Premix LT16587 EN

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Page : 1 / 14

SAFETY DATA SHEET


Revision nr : 5.0
Issue date : 11/09/2017
Supersedes : 08/09/2015
ES COMPLEAT EG PREMIX
LT16587 EU

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Product form : Mixture
Trade name/designation : ES COMPLEAT EG PREMIX
Product code : ES Compleat EG 50/50 Premix: CC2748M (5L); CC2750M (20L pail); CC2826M
(208L drum); CC2852M (1000L tote); CC2827M (bulk); CC2827 RS (Bulk); CC2827
RSJ (5L); CC2827 RSP (20L); CC2827 RSD (208L); CC2827 RST (1000L)
ES Compleat EG 60/40 Premix: CC2907 ES5L (5L); CC2907 ES20L (20L); CC2907
ES208L (208L Drum); CC2907 ES1000L (1.000L tote); CC2907 ES (bulk); ; CC2907
RS (bulk); CC2907 RSJ (5L); CC2907 RSP (20L); CC2907 RSD (208L)
ES Compleat EG 40/60 Premix: CC2919 ES5L (5L); CC2919 ES20L (20L); CC2919
ES208L (208L Drum); CC2919 ES1000L (1.000L tote); CC2919 ES (bulk)
Product group : Trade product
Document no. : LT16587 EU
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Professional use
Use of the substance/mixture : Coolant

1.2.2. Uses advised against


No data available

1.3. Details of the supplier of the safety data sheet


Cummins Filtration
Unit 3 / Valley Drive / Valley Park / Rugby
CV21 1 TN Warwickshire - The United Kingdom
T +44 (0)1788 853600
Cummins Filtration
Zone Industrielle du Grand Guelen
29556 Quimper Cedex 9 - France
T
+33 (0) 2 98 76 49 49
Cummins Filtration
Catenbergstraat 1
2840 Rumst - Belgium
T +32 3 456 3000
productinfosds@cummins.com
OOO Cummins
Klyazma 1G, Khimki, Moscow Region
141402 - Russia
T +7 495 926 86 24/25
dbu.russia@cummins.com

1.4. Emergency telephone number


Emergency number : +44 (0) 1235 239670 (Carechem24)
Only available during office hours.
Country Official advisory body Address Emergency number
Ireland National Poisons Information Centre Beaumont Hospital Beaumont Road +353 1 809 21 66 (public,
9 Dublin
Beaumont Hospital 8am - 10pm, 7/7)
+353 01 809 2566
(Professionals, 24/7)
United Kingdom National Poisons Information Service Claremont Place 0844 892 0111 (UK only,
Newcastle-upon-Tyne
(Newcastle Centre) NE1 4LP Newcastle 24/7, healthcare
Regional Drugs and Therapeutics Centre, Wolfson Unit professionals only)
Page : 2 / 14
SAFETY DATA SHEET
Revision nr : 5.0
Issue date : 11/09/2017
Supersedes : 08/09/2015
ES COMPLEAT EG PREMIX
LT16587 EU

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to
Regulation (EU) 2015/830 (REACH Annex II)
Acute Tox. 4 (Oral) H302
STOT RE 2 H373

Full text of hazard classes and H-statements : see section 16

2.2. Label elements


Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display

Hazard pictograms (CLP) :

GHS07 GHS08

Signal word : Warning


Hazardous ingredients : ethanediol, ethylene glycol; 2,2' -OXYBISETHANOL, DIETHYLENE GLYCOL;
sodium nitrite
Hazard statements (CLP) : H302 - Harmful if swallowed.
H373 - May cause damage to organs (kidneys) through prolonged or repeated
exposure (oral).
Precautionary statements (CLP) : P264 - Wash hands, forearms and face thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P301+P312 - IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P314 - Get medical advice/attention if you feel unwell.
P330 - Rinse mouth.
P501 - Dispose of contents/container to hazardous or special waste collection point,
in accordance with local, regional, national and/or international regulation

2.3. Other hazards


Other hazards : PBT/vPvB data : This information is not available.

SECTION 3: Composition/information on ingredients


3.1. Substances
Not applicable

3.2. Mixtures

Substance name Product identifier % Classification according


to Regulation (EC) No.
1272/2008 [CLP]
ethanediol, ethylene glycol (CAS-No.) 107-21-1 40 - 60 Acute Tox. 4 (Oral), H302
(EC-No.) 203-473-3 STOT RE 2, H373
(EC Index) 603-027-00-1
2,2' -OXYBISETHANOL, DIETHYLENE GLYCOL (CAS-No.) 111-46-6 0,1 - 1 Acute Tox. 4 (Oral), H302
(EC-No.) 203-872-2 STOT RE 2, H373
(EC Index) 603-140-00-6
sodium nitrite (CAS-No.) 7632-00-0 0,1 - 0,5 Ox. Sol. 3, H272
(EC-No.) 231-555-9 Acute Tox. 3 (Oral), H301
(EC Index) 007-010-00-4 Eye Irrit. 2, H319
Aquatic Acute 1, H400
Page : 3 / 14
SAFETY DATA SHEET
Revision nr : 5.0
Issue date : 11/09/2017
Supersedes : 08/09/2015
ES COMPLEAT EG PREMIX
LT16587 EU

Full text of H-statements: see section 16

SECTION 4: First aid measures


4.1. Description of first aid measures
Additional advice : First aider: Pay attention to self-protection. See also section 8 . Never give anything
by mouth to an unconscious person. Show this safety data sheet to the doctor in
attendance. Treat symptomatically. In case of doubt or persistent symptoms, consult
always a physician.
Inhalation : Keep at rest. Provide fresh air. In case of doubt or persistent symptoms, consult
always a physician.
Skin contact : Wash with plenty of water/. Take off immediately all contaminated clothing. Wash
contaminated clothing before reuse. In case of doubt or persistent symptoms,
consult always a physician.
Eyes contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses. In case of doubt or persistent symptoms, consult
always a physician.
Ingestion : Call a physician immediately. Rinse mouth out with water. Drink 1 or 2 glasses of
water. Do NOT induce vomiting. Never give anything by mouth to an unconscious
person.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation : May cause respiratory irritation. Dizziness. The following symptoms may occur:
Cough. Headache.
Skin contact : mild skin irritation . May cause skin irritation in susceptible persons. Components of
the product may be absorbed into the body through the skin.
Eyes contact : May cause eye irritation with susceptible persons. The following symptoms may
occur: erythema (redness). Pain .
Ingestion : Harmful if swallowed. Weakness. Ingestion of larger amounts may cause defects to
the central nervous system (e.g. dizziness, headache). Kidney injury may occur. The
absorption of this product into the body may lead to the formation of
methaemoglobine that, in sufficient concentration, causes cyanosis. The following
symptoms may occur: Vomiting. Unconsciousness. Nausea . Abdominal pain.
Chronic symptoms : May cause damage to organs (kidneys) through prolonged or repeated exposure
(oral).
4.3. Indication of any immediate medical attention and special treatment needed
No data available

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media : Water spray, Alcohol resistant foam, Carbon dioxide, Dry extinguishing powder.
Unsuitable extinguishing media : Strong water jet .
5.2. Special hazards arising from the substance or mixture
Specific hazards : Provide adequate ventilation. Evacuate personnel to a safe area. On heating there is
a risk of a build-up of pressure in hermetically sealed containers or tanks. Vapours
are heavier than air and may spread along floors. Hazardous decomposition
products COx. Formaldehyde . Do not allow run-off from fire-fighting to enter drains
or water courses.
5.3. Advice for firefighters
Firefighting instructions : Special protective equipment for firefighters. . Wear a self-contained breathing
apparatus and chemical protective clothing. Use water spray or fog for cooling
exposed containers.
Page : 4 / 14
SAFETY DATA SHEET
Revision nr : 5.0
Issue date : 11/09/2017
Supersedes : 08/09/2015
ES COMPLEAT EG PREMIX
LT16587 EU

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
For non-emergency personnel : Stay upwind/keep distance from source. Provide adequate ventilation. Use personal
protective equipment as required. Concerning personal protective equipment to use,
see section 8. Do not eat, drink or smoke in areas where product is used. Do not
breathe vapour/aerosol. Avoid contact with skin, eyes and clothing. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do
not ingest.

6.1.2. For emergency responders


For emergency responders : Ensure procedures and training for emergency decontamination and disposal are in
place.
6.2. Environmental precautions
Do not allow to enter into surface water or drains.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Provide adequate ventilation. Stop leak if safe to do so. Dilute with plenty of water.
Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth,
diatomaceous earth, vermiculite) and transfer to a container for disposal according to
local / national regulations (see section 13). Site should have a spill plan to ensure
that adequate safeguards are in place to minimize the impact of episodic releases.
6.4. Reference to other sections
Concerning personal protective equipment to use, see section 8 . Concerning disposal elimination after cleaning, see section 13.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Precautions for safe handling : Use only in well ventilated areas. Use personal protective equipment as required.
Concerning personal protective equipment to use, see section 8 . Do not ingest. Do
not breathe vapour/aerosol. Avoid contact with skin, eyes and clothing. After use
replace the closing cap immediately. Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources. No smoking. Take any precaution to avoid
mixing with combustibles...
Hygiene measures : Keep good industrial hygiene. Wash hands and face before breaks and immediately
after handling of the product. Keep away from food, drink and animal feedingstuffs.
When using do not eat, drink or smoke. Separate working clothes from town clothes.
Take off contaminated clothing.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Keep container tightly closed in a cool, well-ventilated place. Keep away from heat,
hot surfaces, sparks, open flames and other ignition sources. No smoking. Refer to
the detailed list of incompatible materials in section 10 Stability/Reactivity. Keep
locked-up.
7.3. Specific end use(s)
No data available

SECTION 8: Exposure controls/personal protection


8.1. Control parameters
ethanediol, ethylene glycol (107-21-1)
EU IOELV TWA (mg/m³) 52 mg/m³
EU IOELV TWA (ppm) 20 ppm
EU IOELV STEL (mg/m³) 104 mg/m³
EU IOELV STEL (ppm) 40 ppm
EU Notes Possibility of significant uptake through the skin
Page : 5 / 14
SAFETY DATA SHEET
Revision nr : 5.0
Issue date : 11/09/2017
Supersedes : 08/09/2015
ES COMPLEAT EG PREMIX
LT16587 EU

ethanediol, ethylene glycol (107-21-1)


Austria MAK (mg/m³) 26 mg/m³
Austria MAK (ppm) 10 ppm
Austria MAK Short time value (mg/m³) 52 mg/m³
Austria MAK Short time value (ppm) 20 ppm
Bulgaria OEL TWA (mg/m³) 52 mg/m³
Bulgaria OEL TWA (ppm) 20 ppm
Bulgaria OEL STEL (mg/m³) 104 mg/m³
Bulgaria OEL STEL (ppm) 40 ppm
Croatia GVI (granična vrijednost izloženosti) (mg/m³) 52 mg/m³
Croatia GVI (granična vrijednost izloženosti) (ppm) 20 ppm
Croatia KGVI (kratkotrajna granična vrijednost 104 mg/m³
izloženosti) (mg/m³)
Croatia KGVI (kratkotrajna granična vrijednost 40 ppm
izloženosti) (ppm)
Cyprus OEL TWA (mg/m³) 52 mg/m³
Cyprus OEL TWA (ppm) 20 ppm
Cyprus OEL STEL (mg/m³) 104 mg/m³
Cyprus OEL STEL (ppm) 40 ppm
Czech Republic Expoziční limity (PEL) (mg/m³) 50 mg/m³
Denmark Grænseværdie (langvarig) (mg/m³) 26 mg/m³
10 mg/m³ (atomized)
Denmark Grænseværdie (langvarig) (ppm) 10 ppm
Estonia OEL TWA (mg/m³) 52 mg/m³ (total concentration of aerosol and
vapor)
Estonia OEL TWA (ppm) 20 ppm (total concentration of aerosol and
vapor)
Estonia OEL STEL (mg/m³) 104 mg/m³ (total concentration of aerosol and
vapor)
Estonia OEL STEL (ppm) 40 ppm (total concentration of aerosol and
vapor)
Finland HTP-arvo (8h) (mg/m³) 50 mg/m³
Finland HTP-arvo (8h) (ppm) 20 ppm
Finland HTP-arvo (15 min) 100 mg/m³
Finland HTP-arvo (15 min) (ppm) 40 ppm
France VME (mg/m³) 52 mg/m³ (indicative limit-vapor)
France VME (ppm) 20 ppm (indicative limit-vapor)
France VLE (mg/m³) 104 mg/m³ (indicative limit-vapor)
France VLE (ppm) 40 ppm (indicative limit-vapor)
Germany TRGS 900 Occupational exposure limit value 26 mg/m³ (The risk of damage to the embryo or
(mg/m³) fetus can be excluded when AGW and BGW
values are observed)
Germany TRGS 900 Occupational exposure limit value 10 ppm (The risk of damage to the embryo or
(ppm) fetus can be excluded when AGW and BGW
values are observed)
Gibraltar 8h mg/m3 52 mg/m³
Gibraltar 8h ppm 20 ppm
Gibraltar Short-term mg/m3 104 mg/m³
Gibraltar Short-term ppm 40 ppm
Greece OEL TWA (mg/m³) 125 mg/m³ (vapor)
Page : 6 / 14
SAFETY DATA SHEET
Revision nr : 5.0
Issue date : 11/09/2017
Supersedes : 08/09/2015
ES COMPLEAT EG PREMIX
LT16587 EU

ethanediol, ethylene glycol (107-21-1)


Greece OEL TWA (ppm) 50 ppm (vapor)
Greece OEL STEL (mg/m³) 125 mg/m³ (vapor)
Greece OEL STEL (ppm) 50 ppm (vapor)
Hungary AK-érték 52 mg/m³
Hungary CK-érték 104 mg/m³
Ireland OEL (8 hours ref) (mg/m³) 10 mg/m³ (particulate)
52 mg/m³ (vapour)
Ireland OEL (8 hours ref) (ppm) 20 ppm (vapour)
Ireland OEL (15 min ref) (mg/m3) 104 mg/m³ (vapour)
Ireland OEL (15 min ref) (ppm) 40 ppm (particulate)
Italy OEL TWA (mg/m³) 52 mg/m³
Italy OEL TWA (ppm) 20 ppm
Italy OEL STEL (mg/m³) 104 mg/m³
Italy OEL STEL (ppm) 40 ppm
Latvia OEL TWA (mg/m³) 52 mg/m³
Latvia OEL TWA (ppm) 20 ppm
Lithuania IPRV (mg/m³) 25 mg/m³ (aerosol and vapor)
Lithuania IPRV (ppm) 10 ppm (aerosol and vapor)
Lithuania TPRV (mg/m³) 50 mg/m³ (aerosol and vapor)
Lithuania TPRV (ppm) 20 ppm (aerosol and vapor)
Luxembourg OEL TWA (mg/m³) 52 mg/m³
Luxembourg OEL TWA (ppm) 20 ppm
Luxembourg OEL STEL (mg/m³) 104 mg/m³
Luxembourg OEL STEL (ppm) 40 ppm
Malta OEL TWA (mg/m³) 52 mg/m³
Malta OEL TWA (ppm) 20 ppm
Malta OEL STEL (mg/m³) 104 mg/m³
Malta OEL STEL (ppm) 40 ppm
Netherlands Grenswaarde TGG 8H (mg/m³) 52 mg/m³ (fume)
10 mg/m³ (droplets)
Netherlands Grenswaarde TGG 15MIN (mg/m³) 104 mg/m³
Poland NDS (mg/m³) 15 mg/m³
Poland NDSCh (mg/m³) 50 mg/m³
Portugal OEL TWA (mg/m³) 52 mg/m³ (indicative limit value)
Portugal OEL TWA (ppm) 20 ppm (indicative limit value)
Portugal OEL STEL (mg/m³) 104 mg/m³ (indicative limit value)
Portugal OEL STEL (ppm) 40 ppm (indicative limit value)
Portugal OEL - Ceilings (mg/m³) 100 mg/m³ (aerosol only)
Romania OEL TWA (mg/m³) 52 mg/m³
Romania OEL TWA (ppm) 20 ppm
Romania OEL STEL (mg/m³) 104 mg/m³
Romania OEL STEL (ppm) 40 ppm
Slovakia NPHV (priemerná) (mg/m³) 52 mg/m³
Slovakia NPHV (priemerná) (ppm) 20 ppm
Page : 7 / 14
SAFETY DATA SHEET
Revision nr : 5.0
Issue date : 11/09/2017
Supersedes : 08/09/2015
ES COMPLEAT EG PREMIX
LT16587 EU

ethanediol, ethylene glycol (107-21-1)


Slovakia NPHV (Hraničná) (mg/m³) 104 mg/m³
Slovenia OEL TWA (mg/m³) 52 mg/m³
Slovenia OEL TWA (ppm) 20 ppm
Slovenia OEL STEL (mg/m³) 104 mg/m³
Slovenia OEL STEL (ppm) 40 ppm
Spain VLA-ED (mg/m³) 52 mg/m³ (indicative limit value)
Spain VLA-ED (ppm) 20 ppm (indicative limit value)
Spain VLA-EC (mg/m³) 104 mg/m³
Spain VLA-EC (ppm) 40 ppm
Sweden nivågränsvärde (NVG) (mg/m³) 25 mg/m³ (the limit value applies to the
combined concentration of vapor and aerosol-
aerosol and vapor)
Sweden nivågränsvärde (NVG) (ppm) 10 ppm (the limit value applies to the combined
concentration of vapor and aerosol-aerosol and
vapor)
Sweden kortidsvärde (KTV) (mg/m³) 104 mg/m³ (aerosol and vapor)
Sweden kortidsvärde (KTV) (ppm) 40 ppm (aerosol and vapor)
United Kingdom WEL TWA (mg/m³) 10 mg/m³ (particulates)
52 mg/m³ (vapour)
United Kingdom WEL TWA (ppm) 20 ppm (vapour)
United Kingdom WEL STEL (mg/m³) 104 mg/m³ (vapour)
30 mg/m³ (calculated-particulate)
United Kingdom WEL STEL (ppm) 40 ppm (vapour)
Norway Grenseverdier (AN) (mg/m³) 20 mg/m³ (equal to the standard for nuisance
dust-dust)
52 mg/m³ (total sum of limit values for both
vapor and dust)
Norway Grenseverdier (AN) (ppm) 52 ppm (total sum of limit values for both vapor
and dust-total dust and vapor)
Norway Grenseverdier (Korttidsverdi) (mg/m3) 104 mg/m³ (value from the regulation-dust)
Norway Grenseverdier (Korttidsverdi) (ppm) 40 ppm (value from the regulation)
Switzerland MAK (mg/m³) 26 mg/m³
Switzerland MAK (ppm) 10 ppm
Switzerland KZGW (mg/m³) 52 mg/m³
Switzerland KZGW (ppm) 20 ppm
Australia TWA (mg/m³) 10 mg/m³ (particulate)
52 mg/m³ (vapour)
Australia TWA (ppm) 20 ppm (vapour)
Australia STEL (mg/m³) 104 mg/m³ (vapour)
Australia STEL (ppm) 40 ppm (vapour)
Canada (Quebec) PLAFOND (mg/m³) 127 mg/m³ (mist and vapour)
Canada (Quebec) PLAFOND (ppm) 50 ppm (mist and vapour)
USA - ACGIH ACGIH TWA (ppm) 25 ppm (vapor fraction)
USA - ACGIH ACGIH STEL (mg/m³) 10 mg/m³ (inhalable particulate matter, aerosol
only)
USA - ACGIH ACGIH STEL (ppm) 50 ppm (vapor fraction)
2,2' -OXYBISETHANOL, DIETHYLENE GLYCOL (111-46-6)
Austria MAK (mg/m³) 44 mg/m³
Page : 8 / 14
SAFETY DATA SHEET
Revision nr : 5.0
Issue date : 11/09/2017
Supersedes : 08/09/2015
ES COMPLEAT EG PREMIX
LT16587 EU

2,2' -OXYBISETHANOL, DIETHYLENE GLYCOL (111-46-6)


Austria MAK (ppm) 10 ppm
Austria MAK Short time value (mg/m³) 176 mg/m³
Austria MAK Short time value (ppm) 40 ppm
Bulgaria OEL TWA (mg/m³) 10 mg/m³
Croatia GVI (granična vrijednost izloženosti) (mg/m³) 101 mg/m³
Croatia GVI (granična vrijednost izloženosti) (ppm) 23 ppm
Denmark Grænseværdie (langvarig) (mg/m³) 11 mg/m³
Denmark Grænseværdie (langvarig) (ppm) 2,5 ppm
Estonia OEL TWA (mg/m³) 45 mg/m³
Estonia OEL TWA (ppm) 10 ppm
Estonia OEL STEL (mg/m³) 90 mg/m³
Estonia OEL STEL (ppm) 20 ppm
Germany TRGS 900 Occupational exposure limit value 44 mg/m³ (The risk of damage to the embryo or
(mg/m³) fetus can be excluded when AGW and BGW
values are observed)
Germany TRGS 900 Occupational exposure limit value 10 ppm (The risk of damage to the embryo or
(ppm) fetus can be excluded when AGW and BGW
values are observed)
Ireland OEL (8 hours ref) (mg/m³) 100 mg/m³
Ireland OEL (8 hours ref) (ppm) 23 ppm
Ireland OEL (15 min ref) (mg/m3) 300 mg/m³ (calculated)
Ireland OEL (15 min ref) (ppm) 69 ppm (calculated)
Latvia OEL TWA (mg/m³) 10 mg/m³
Lithuania IPRV (mg/m³) 45 mg/m³
Lithuania IPRV (ppm) 10 ppm
Lithuania TPRV (mg/m³) 90 mg/m³
Lithuania TPRV (ppm) 20 ppm
Poland NDS (mg/m³) 10 mg/m³ (inhalable fraction)
Romania OEL TWA (mg/m³) 500 mg/m³
Romania OEL TWA (ppm) 115 ppm
Romania OEL STEL (mg/m³) 800 mg/m³
Romania OEL STEL (ppm) 184 ppm
Slovakia NPHV (priemerná) (mg/m³) 44 mg/m³
Slovakia NPHV (priemerná) (ppm) 10 ppm
Slovakia NPHV (Hraničná) (mg/m³) 90 mg/m³
Slovenia OEL TWA (mg/m³) 44 mg/m³
Slovenia OEL TWA (ppm) 10 ppm
Slovenia OEL STEL (mg/m³) 176 mg/m³
Slovenia OEL STEL (ppm) 40 ppm
Sweden nivågränsvärde (NVG) (mg/m³) 45 mg/m³
Sweden nivågränsvärde (NVG) (ppm) 10 ppm
Sweden kortidsvärde (KTV) (mg/m³) 90 mg/m³
Sweden kortidsvärde (KTV) (ppm) 20 ppm
United Kingdom WEL TWA (mg/m³) 101 mg/m³
Page : 9 / 14
SAFETY DATA SHEET
Revision nr : 5.0
Issue date : 11/09/2017
Supersedes : 08/09/2015
ES COMPLEAT EG PREMIX
LT16587 EU

2,2' -OXYBISETHANOL, DIETHYLENE GLYCOL (111-46-6)


United Kingdom WEL TWA (ppm) 23 ppm
United Kingdom WEL STEL (mg/m³) 303 mg/m³ (calculated)
United Kingdom WEL STEL (ppm) 69 ppm (calculated)
Switzerland MAK (mg/m³) 44 mg/m³
Switzerland MAK (ppm) 10 ppm
Switzerland KZGW (mg/m³) 176 mg/m³
Switzerland KZGW (ppm) 40 ppm
Australia TWA (mg/m³) 100 mg/m³
Australia TWA (ppm) 23 ppm
sodium nitrite (7632-00-0)
Lithuania NRV (mg/m³) 0,1 mg/m³

8.2. Exposure controls


Engineering measure(s) : Provide adequate ventilation. Use only in area provided with appropriate exhaust
ventilation. Emergency eye wash fountains and safety showers should be available
in the immediate vicinity of any potential exposure. Organisational measures to
prevent /limit releases, dispersion and exposure. See also section 7.
Personal protective equipment : Choose body protection according to the amount and concentration of the
dangerous substance at the work place.
Hand protection : Protective gloves complying with EN 374. The selection of specific gloves for a
specific application and time of use in a working area, should also take into account
other factors on the working space, such as (but not limited to): other chemicals that
are possibly used, physical requirements (protection against cutting/drilling, skill,
thermal protection), and the instructions/specification of the supplier of gloves.
Eye protection : tightly fitting safety goggles /. Safety glasses (EN166)
Respiratory protection : Not required for normal conditions of use. In case of insufficient ventilation, wear
suitable respiratory equipment. Full face mask (EN 136) (EN 136). Half-face mask
(DIN EN 140) (EN 140). Filter type: A (EN 141). Self-contained breathing apparatus
(EN 133) .

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : Blue.
Odour : Characteristic.
Odour threshold : No data available
pH : 10,2 - 10,8
Relative evaporation rate (butylacetate=1) : No data available
Melting / freezing point : No data available
Freezing point : No data available
Initial boiling point and boiling range : 107 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Not applicable,(liquid)
Vapour pressure : No data available
Vapour density : No data available
Relative density : 1,056 - 1,088
Page : 10 / 14
SAFETY DATA SHEET
Revision nr : 5.0
Issue date : 11/09/2017
Supersedes : 08/09/2015
ES COMPLEAT EG PREMIX
LT16587 EU

Solubility : No data available


Partition coefficient n-octanol/water : No data available
Kinematic viscosity : No data available
Dynamic viscosity : No data available
Explosive properties : Not applicable.
Oxidising properties : Not applicable.
Explosive limits : No data available
9.2. Other information
VOC content : No data available

SECTION 10: Stability and reactivity


10.1. Reactivity
Non flammable. Combustible. Reference to other sections: 10.5.
10.2. Chemical stability
The product is stable under storage at normal ambient temperatures.
10.3. Possibility of hazardous reactions
Hazardous polymerisation does not occur.
10.4. Conditions to avoid
Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. See also section 7 : Handling and storage .
10.5. Incompatible materials
oxidising substances. acids and bases . See also section 7 : Handling and storage .
10.6. Hazardous decomposition products
Burning produces noxious and toxic fumes. Hazardous decomposition products. Carbon oxides. Formaldehyde .

SECTION 11: Toxicological information


11.1. Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed.
ATE CLP (oral) 781,9687212511 mg/kg bodyweight
ethanediol, ethylene glycol (107-21-1)
LD50/oral/rat 4700 mg/kg
LD50/dermal/rat 10600 mg/kg
2,2' -OXYBISETHANOL, DIETHYLENE GLYCOL (111-46-6)
LD50/oral/rat 12565 mg/kg
LD50/dermal/rabbit 11890 mg/kg
LC50/inhalation/4h/rat > 4600 mg/m³ (Exposure time: 4 h)
sodium nitrite (7632-00-0)
LD50/oral/rat 85 mg/kg
LC50/inhalation/4h/rat 5,5 mg/l/4h
Skin corrosion/irritation : Not classified (Based on available data, the classification criteria are not met.)
pH: 10,2 - 10,8
Serious eye damage/irritation : Not classified (Based on available data, the classification criteria are not met.)
pH: 10,2 - 10,8
Respiratory or skin sensitisation : Not classified (Based on available data, the classification criteria are not met.)
Germ cell mutagenicity : Not classified (Based on available data, the classification criteria are not met.)
Carcinogenicity : Not classified (Based on available data, the classification criteria are not met.)
Reproductive toxicity : Not classified (Based on available data, the classification criteria are not met.)
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STOT-single exposure : Not classified (Based on available data, the classification criteria are not met.)
STOT-repeated exposure : May cause damage to organs (kidneys) through prolonged or repeated exposure
(oral).
Aspiration hazard : Not classified (Based on available data, the classification criteria are not met.)

SECTION 12: Ecological information


12.1. Toxicity
Environmental properties : Not classified.

ethanediol, ethylene glycol (107-21-1)


LC50 fish 1 41000 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss)
EC50 Daphnia 1 46300 mg/l (Exposure time: 48 h - Species: Daphnia magna)
LC50 fish 2 14 - 18 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static])
2,2' -OXYBISETHANOL, DIETHYLENE GLYCOL (111-46-6)
LC50 fish 1 75200 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 84000 mg/l (Exposure time: 48 h - Species: Daphnia magna)
sodium nitrite (7632-00-0)
LC50 fish 1 0,19 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through])
EC50 Daphnia 1 87 mg/l
LC50 fish 2 0,092 - 0,13 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-
through])

12.2. Persistence and degradability


ES COMPLEAT EG PREMIX
Persistence and degradability The product itself has not been tested.
12.3. Bioaccumulative potential
ES COMPLEAT EG PREMIX
Partition coefficient n-octanol/water No data available
ethanediol, ethylene glycol (107-21-1)
Partition coefficient n-octanol/water -1,93
2,2' -OXYBISETHANOL, DIETHYLENE GLYCOL (111-46-6)
BCF fish 1 100 - 180
Partition coefficient n-octanol/water -1,98 (at 25 °C)
sodium nitrite (7632-00-0)
Partition coefficient n-octanol/water -3,7 (at 25 °C)
12.4. Mobility in soil
ES COMPLEAT EG PREMIX
Ecology - soil The product itself has not been tested.
12.5. Results of PBT and vPvB assessment
No data available

12.6. Other adverse effects


Additional information : No information available

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Product/Packaging disposal : Refer to manufacturer/supplier for information on recovery/recycling. Collect and
recommendations dispose of waste product at an authorised disposal facility. Dispose of contaminated
materials in accordance with current regulations.
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Additional information : Delivery to an approved waste disposal company. In accordance with local and
national regulations.
European waste catalogue (2001/573/EC, : The following Waste Codes are only suggestions:
75/442/EEC, 91/689/EEC) 07 02 04* - other organic solvents, washing liquids and mother liquors /
150110 - packaging containing residues of or contaminated by dangerous
substances .
Waste codes should be assigned by the user, preferably in discussion with the waste
disposal authorities.

SECTION 14: Transport information


In accordance with ADR / RID / IMDG / IATA / ADN
ADR IMDG IATA ADN RID
14.1. UN number
Not applicable Not applicable Not applicable Not applicable Not applicable
14.2. UN proper shipping name
NA Not applicable Not applicable Not applicable Not applicable
14.3. Transport hazard class(es)
Not applicable Not applicable Not applicable Not applicable Not applicable
Not applicable Not applicable Not applicable Not applicable Not applicable
14.4. Packing group
Not applicable Not applicable Not applicable Not applicable Not applicable
14.5. Environmental hazards
Dangerous for the Dangerous for the Dangerous for the Dangerous for the Dangerous for the
environment : No environment : No environment : No environment : No environment : No
Marine pollutant : No
Not applicable

14.6. Special precautions for user


Special precautions for user : Not applicable

- Overland transport
No data available

- Transport by sea
No data available

- Air transport
No data available

- Inland waterway transport


No data available

- Rail transport
No data available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Code: IBC : Not applicable.

SECTION 15: Regulatory information


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006:
3. Liquid substances or mixtures which are regarded as dangerous in accordance with ES COMPLEAT EG PREMIX - ethanediol,
Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or ethylene glycol - 2,2' -OXYBISETHANOL,
categories set out in Annex I to Regulation (EC) No 1272/2008 DIETHYLENE GLYCOL
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3(b) Substances or mixtures fulfilling the criteria for any of the following hazard classes or ES COMPLEAT EG PREMIX - ethanediol,
categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, ethylene glycol - 2,2' -OXYBISETHANOL,
3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than DIETHYLENE GLYCOL
narcotic effects, 3.9 and 3.10
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances

VOC content : No data available

15.1.2. National regulations

Germany
VwVwS Annex reference : Water hazard class (WGK) 1, low hazard to waters (Classification according to
VwVwS, Annex 4)
12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Immission Control Act - 12.BImSchV

TA Luft : 5.2.5 Organic Substances

Netherlands
Waterbezwaarlijkheid : 11 - Weinig schadelijk voor in het water levende organismen (B)
Saneringsinspanningen : B - Lozing minimaliseren; toepassen van best uitvoerbare technieken
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de : None of the components are listed
voortplanting giftige stoffen – Borstvoeding
NIET-limitatieve lijst van voor de : None of the components are listed
voortplanting giftige stoffen –
Vruchtbaarheid
NIET-limitatieve lijst van voor de : None of the components are listed
voortplanting giftige stoffen – Ontwikkeling

Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product

15.2. Chemical safety assessment

Not required

SECTION 16: Other information


Indication of changes:
SECTION : 1, 2, 3, 4, 6, 8, 11, 14, 15, 16.
Abbreviations and acronyms:
ADN = Accord Européen relatif au Transport International des Marchandises Dangereuses par voie de Navigation du Rhin
ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route
CLP = Classification, Labelling and Packaging Regulation according to 1272/2008/EC
IATA = International Air Transport Association
IMDG = International Maritime Dangerous Goods Code
LEL = Lower Explosive Limit/Lower Explosion Limit
UEL = Upper Explosion Limit/Upper Explosive Limit
REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals
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CSR = CSR = Chemical Safety Report


EC50 = Median Effective Concentration
LD50 = Median lethal dose
LC50 = Median lethal concentration
N.O.S. = Not Otherwise Specified
DNEL = DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
TLV = Threshold limits
TWA = time weighted average
STEL = Short term exposure limit
persistent, bioaccumulating and toxic (PBT).
vPvB = very persistent and very bioaccumulating
WGK = Wassergefährdungsklasse (Water Hazard Class under German Federal Water Management Act)
Sources of key data used to compile the : European Chemicals Bureau (http://esis.jrc.ec.europa.eu) SDS Supplier No LT16587
datasheet EU reviewed 04/06/2009.
Training advice : Manipulations are to be done only by qualified and authorised persons. Normal use
of this product shall imply use in accordance with the instructions on the packaging.
Training staff on good practice.
Full text of H- and EUH-statements:
Acute Tox. 3 (Oral) Acute toxicity Category 3
Acute Tox. 4 (Oral) Acute toxicity Category 4
Aquatic Acute 1 Hazardous to the aquatic environment - Aquatic Acute 1
Eye Irrit. 2 Serious eye damage/eye irritation Category 2
Ox. Sol. 3 Oxidizing solid Category 3
STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2
H272 May intensify fire; oxidiser.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.

According to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Labelling according to Regulation (EC) No. 1272/2008 [CLP]

DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling,
storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we
do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected
with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the
product is used as a component in another product, this SDS information may not be applicable.

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