AS Organic
AS Organic
AS Organic
Catalytic Cracking
Catto D CaHu Hz
Ala03 8 02 Brokenpieces of porous pot Pumice as catalyst
5000C temperature
2 Thermal Cracking
3 Complete combustion
M Incomplete combustion
p
Room Temperature
R ketones
c o e r
r k
R Carboxylic Acid
C O R
H E
H Carbon Dioxide
g e CO2
A
3000CTemperature
70 atm pressure
H3POu as catalyst
Alkyl Halides
1 Nucleophilic substitution with NaOH
R
Snl
p
Est 88
R
a
C't OH R E OH
1
R R E
b E
p
1 B
sa Br digits H it
OH
R Br NaOH R OH NaBr
Aqueous conditions
Heat Provided
B Br t NaCN R CN t NaBr
Ethanol as solvent heat provided
3 Nucleophilic Substitution with Ammonia
R Br NH3 R N H2 HBr
Ethanol as solvent heat provided
H H
NaOH as reactant
HÉ Ethanol as solvent
Heat Provided
Alcohols
1 Oxidation of Alcohols
Heatunder
Primary Alcohol Distills Aldehyde Y carboxylicAcid
heat ketone
Secondary Alcohol
Tertiary Alcohol No Reaction
R OH Na R Ona t 42172
3 Reaction with Carboxylic Acids Esterification
5 Dehydration of alcohols
H
Y H
qt't M
qt G
It H2O
g
H I eHz CHz
concentrated Arson
1800C Temperature
R OH Pelz R Ch t H3PO3
heat
R OH PCL5 R CL HCL POLO
room temperature
R OH SOCK R Ch t 802 t HCl
heat in pyradine as solvent
Carbonyl Compounds
1 Reduction of carbonyl compounds
2 Nucleophilic Addition
Cgi
O HELI OH
r r e r R C r
Een En in
HCNas reagent
Traceamounts of Naen as catalyst
5 Fehlings lest
R C O s R C O
I OH
Oxidation reaction
Carboxylic Acid forms
works only for Aldehydes
Nitrile Reactions
1 Hydrolysis
B C ON R e eOzH
OH OH
dilute HCl and heat under reflux
2 Reduction
R ON R CHINA2
Use Nals in ethanol heat
Carboxylic Acid
1 Reaction with metals
R Coat t Na R CO2Na t 42172
4 Esterification
B CO2H L OH
t R CO2 L t H2O
Concentrated Sulfuric Acid Heat
7
Hydrolysis of esters
Acid CH3 000 OH CH3OH Chs Coat
Dilute All heat under reflux
Alkaline CH3 000 0173 0173OH CH3CO2Na
Aq NaOH room temperature
nodosomiest
Alkaline solution of 12
warm
CH13 Iodoform
R É OH R É o
Yellow ppt forms