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Toluene SDS

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Safety Data Sheet

Toluene
Version 1.3 Revision Date: 03/06/2015

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Toluene


Product Use Descrip- : Industrial chemical
tion
Manufacturer or supplier's details
Company : Nexeo Solutions LLC
Address 3 Waterway Square Place Suite 1000
Woodlands, Tx. 77380
United States of America

Emergency telephone number:


Health North America: 1-855-NEXEO4U (1-855-639-3648)
Health International: 1-855-NEXEO4U (1-855-639-3648)
Transport North America: CHEMTREC 800.424.9300

Additional Informa- : Responsible Party: Product Safety Group


tion: E-Mail: msds@nexeosolutions.com
SDS Requests: 1-855-429-2661
SDS Requests Fax: 1-281-500-2370
Website: www.nexeosolutions.com

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 2

Skin irritation : Category 2

Eye irritation : Category 2A

Reproductive toxicity : Category 2

Specific target organ tox- : Category 3 (Central nervous system)


icity - single exposure

Specific target organ tox- : Category 2 (Auditory system, Eyes)


icity - repeated exposure
(Inhalation)

Aspiration hazard : Category 1

GHS Label element

MSDS Number: 100000002760 1 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

Hazard pictograms :

Signal word : Danger

Hazard statements : H225 Highly flammable liquid and vapour.


H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H361 Suspected of damaging fertility or the unborn
child.
H373 May cause damage to organs through prolonged
or repeated exposure if inhaled.

Precautionary statements : Prevention:


P210 Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/
spray.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ eye protection/ face
protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a
POISON CENTER or doctor/ physician.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/
Take off immediately all contaminated clothing. Rinse
skin with water/ shower.
P304 + P340 + P312 IF INHALED: Remove victim to
fresh air and keep at rest in a position comfortable for
breathing. Call a POISON CENTER or doctor/ physician if
you feel unwell.
P331 Do NOT induce vomiting.
P370 + P378 In case of fire: Use dry sand, dry chemical
or alcohol-resistant foam for extinction.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved
waste disposal plant.

Potential Health Effects

Carcinogenicity:

MSDS Number: 100000002760 2 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

IARC No component of this product present at levels greater


than or equal to 0.1% is identified as probable, possible
or confirmed human carcinogen by IARC.

ACGIH No component of this product present at levels greater


than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by ACGIH.

OSHA No component of this product present at levels greater


than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by OSHA.

NTP No component of this product present at levels greater


than or equal to 0.1% is identified as a known or antic-
ipated carcinogen by NTP.

Emergency Overview
Appearance liquid

Colour colourless, transparent

Odour sweet, pungent, hydrocarbon-like, aromatic, pleasant

Hazard Summary No information available.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Substance

Hazardous components
CAS-No. Chemical Name Concentration (%)
108-88-3 Toluene 90 - 100

SECTION 4. FIRST AID MEASURES

General advice : Move out of dangerous area.


Show this safety data sheet to the doctor in atten-
dance.
Symptoms of poisoning may appear several hours
later.

If inhaled : Consult a physician after significant exposure.


If unconscious place in recovery position and seek
medical advice.

MSDS Number: 100000002760 3 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

In case of skin contact : If skin irritation persists, call a physician.


If on skin, rinse well with water.
If on clothes, remove clothes.

In case of eye contact : Flush eyes with water as a precaution.


Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.

If swallowed : Clean mouth with water and drink afterwards plenty


of water.
Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious per-
son.
Take victim immediately to hospital.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing : Alcohol-resistant foam


media Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing : High volume water jet


media

Specific hazards during : Do not allow run-off from fire fighting to enter drains
firefighting or water courses.

Hazardous combustion : No hazardous combustion products are known


products

Specific extinguishing : Use a water spray to cool fully closed containers.


methods

Further information : Collect contaminated fire extinguishing water sepa-


rately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing wa-
ter must be disposed of in accordance with local regu-
lations.
For safety reasons in case of fire, cans should be
stored separately in closed containments.

Special protective equip- : Wear self-contained breathing apparatus for firefight-


ment for firefighters ing if necessary.

MSDS Number: 100000002760 4 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

NFPA Flammable and Combustible Liquids Classification:


Flammable Liquid Class IB

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Use personal protective equipment.


protective equipment and Ensure adequate ventilation.
emergency procedures Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.

Environmental precau- : Prevent product from entering drains.


tions Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains
inform respective authorities.

Methods and materials : Contain spillage, and then collect with non-
for containment and combustible absorbent material, (e.g. sand, earth,
cleaning up diatomaceous earth, vermiculite) and place in con-
tainer for disposal according to local / national regula-
tions (see section 13).

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Avoid formation of aerosol.


Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before
use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in
the application area.
Take precautionary measures against static dis-
charges.
Provide sufficient air exchange and/or exhaust in work
rooms.
Open drum carefully as content may be under pres-
sure.
Dispose of rinse water in accordance with local and
national regulations.

Conditions for safe sto- : No smoking.


rage Keep container tightly closed in a dry and well-
ventilated place.
Containers which are opened must be carefully re-
sealed and kept upright to prevent leakage.
Observe label precautions.

MSDS Number: 100000002760 5 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

Electrical installations / working materials must comp-


ly with the technological safety standards.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters


CAS-No. Components Value type Control parame- Basis
(Form of ters / Permissi-
exposure) ble concentra-
tion
108-88-3 Toluene TWA 20 ppm ACGIH
TWA 100 ppm NIOSH REL
375 mg/m3
ST 150 ppm NIOSH REL
560 mg/m3
TWA 200 ppm OSHA Z-2
CEIL 300 ppm OSHA Z-2
Peak 500 ppm OSHA Z-2
TWA 100 ppm OSHA P0
375 mg/m3
STEL 150 ppm OSHA P0
560 mg/m3
Biological occupational exposure limits
Components CAS-No. Control Biological Sam- Permissi- Basis
parame- specimen pling ble con-
ters time centration
Toluene 108-88- Toluene In blood Prior to 0.02 mg/l ACGIH
3 last BEI
shift of
work-
week
Toluene Urine End of 0.03 mg/l ACGIH
shift BEI
(As
soon as
possible
after
expo-
sure
ceases)
o-Cresol Urine End of 0.3 mg/g ACGIH
shift Creatinine BEI
(As
soon as
possible
after

MSDS Number: 100000002760 6 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

expo-
sure
ceases)
Personal protective equipment
Respiratory protection : No personal respiratory protective equipment normally
required.
In the case of vapour formation use a respirator with
an approved filter.

Hand protection
Remarks : The suitability for a specific workplace should be dis-
cussed with the producers of the protective gloves.

Eye protection : Eye wash bottle with pure water


Tightly fitting safety goggles

Skin and body protection : impervious clothing


Choose body protection according to the amount and
concentration of the dangerous substance at the work
place.

Hygiene measures : When using do not eat or drink.


When using do not smoke.
Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : colourless, transparent

Odour : sweet, pungent, hydrocarbon-like, aromatic, pleasant

Odour Threshold : 1.74 - 5 ppm

pH : not applicable

Freezing Point (Melting : -95 °C (-139 °F)


point/freezing point)

Boiling Point (Boiling : 109 - 111 °C (228 - 232 °F)


point/boiling range)

Flash point : 4 - 7 °C (39 - 45 °F)

Evaporation rate : 2 - 2.4

MSDS Number: 100000002760 7 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

butyl acetate=1
Flammability (solid, gas) : No data available

Burning rate : No data available

Upper explosion limit : 6.7 - 8 %(V)

Lower explosion limit : 1.2 - 1.4 %(V)

Vapour pressure : 22.5 - 24 mmHg @ 20 °C (68 °F)

Relative vapour density : 3.14

Relative density : 0.87

Density : 7.218 lb/gal @ 25 °C (77 °F)

Bulk density : No data available

Solubility(ies)
Water solubility : soluble

Solubility in other sol- : No data available


vents

Partition coefficient: n- : No data available


octanol/water

Auto-ignition temperature : 536 °C

Thermal decomposition : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of


normal use.

Chemical stability : Stable under normal conditions.

Possibility of hazardous : Vapours may form explosive mixture with air.


reactions

Conditions to avoid : Extremes of temperature and direct sunlight.


Heat, flames and sparks.

Incompatible materials : Strong oxidizing agents

MSDS Number: 100000002760 8 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity

Product:
Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Acute dermal toxicity : Acute toxicity estimate : 5,000 mg/kg


Method: Calculation method

Components:
108-88-3:
Acute oral toxicity : LD50 (rat, male): > 5,580 mg/kg

Acute inhalation toxicity : LC50 (rat, male and female): 28.1 mg/l
Exposure time: 4 h
Test atmosphere: vapour
Method: OECD Test Guideline 403

Acute dermal toxicity : LD50 (rabbit): > 5,000 mg/kg

Skin corrosion/irritation

Product:
Result: Irritating to skin.

Components:
108-88-3:
Species: rabbit
Exposure time: 4 h
Result: Irritating to skin.

Serious eye damage/eye irritation

Product:
Result: Irritating to eyes.

Components:
108-88-3:
Species: rabbit

MSDS Number: 100000002760 9 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

Result: Irritating to eyes.


Method: OECD Test Guideline 405

Respiratory or skin sensitisation

Components:
108-88-3:
Test Type: Maximisation Test (GPMT)
Species: guinea pig
Result: Did not cause sensitisation on laboratory animals.
GLP: yes

Germ cell mutagenicity

Components:
108-88-3:
Genotoxicity in vitro : Test Type: Mammalian cell gene mutation assay
Test species: Mouse lymphoma cells
Metabolic activation: with and without metabolic acti-
vation
Method: OECD Test Guideline 476
Result: negative

Genotoxicity in vivo : Test Type: Dominant lethal assay


Test species: mouse (male)
Application Route: inhalation (vapour)
Exposure time: 6 h/d, 5 d/wk for 8 wks
Dose: 0, 100, 400 ppm
Method: OECD Test Guideline 478
Result: negative

Germ cell mutagenicity- : Tests on bacterial or mammalian cell cultures did not
Assessment show mutagenic effects.

Carcinogenicity

Components:
108-88-3:
Species: rat, (male and female)
Application Route: inhalation (vapour)
Exposure time: 103 wks
Dose: 0, 600, 1200 ppm
Frequency of Treatment: 6.5 h/d, 5 d/wk
NOAEL: No observed adverse effect level: 1,200 ppm

Method: OECD Test Guideline 453


Result: did not display carcinogenic properties
Symptoms: Erosion of nasal epithelium
GLP: yes

MSDS Number: 100000002760 10 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

Carcinogenicity - As- : Not classifiable as a human carcinogen.


sessment

Reproductive toxicity

Components:
108-88-3:
Effects on fertility : Test Type: Two-generation study
Species: rat, male and female
Application Route: Inhalation
Dose: 0, 100, 500, 2000 ppm
Frequency of Treatment: 7 days/week
General Toxicity - Parent: NOAEC: 500 ppm
General Toxicity F1: NOAEC: 500 ppm
Fertility: NOAEC: 2,000 ppm
Symptoms: Reduced maternal body weight gain. Re-
duced offspring weight gain.
Method: OECD Test Guideline 416
Result: Animal testing did not show any effects on
fertility.
GLP: yes

Test Type: Fertility


Species: rat, male and female
Application Route: inhalation (vapour)
Dose: 0, 600, 1200 ppm
Frequency of Treatment: 7 days/week
General Toxicity - Parent: NOAEC: 600 ppm
Symptoms: Decreased sperm count
Result: Animal testing did not show any effects on
fertility.

Effects on foetal devel- : Species: rat


opment Application Route: inhalation (vapour)
Dose: 0, 250, 750, 1500, 3000 ppm
Duration of Single Treatment: 10 d
Frequency of Treatment: 6 hr/day
General Toxicity Maternal: NOAEC: 750 ppm
Developmental Toxicity: NOAEC: 750 ppm
Symptoms: Maternal toxicity, Reduced body weight,
Skeletal malformations.
GLP: yes

Reproductive toxicity - : Some evidence of adverse effects on sexual function


Assessment and fertility, and/or on development, based on animal
experiments.

MSDS Number: 100000002760 11 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

STOT - single exposure


Product:No data available
Components:
108-88-3:
Exposure routes: Target Organs: Assessment: Remarks:
Inhalation Central nervous May cause drowsi-
system ness or dizziness.,
The substance or
mixture is classified
as specific target
organ toxicant, sin-
gle exposure, cate-
gory 3 with narcotic
effects.

STOT - repeated exposure

Product:No data available

Components:

108-88-3:
Exposure routes: Target Organs: Assessment: Remarks:
Inhalation Auditory system, May cause damage
Eyes to organs through
prolonged or re-
peated exposure.,
The substance or
mixture is classified
as specific target
organ toxicant, re-
peated exposure,
category 2.

Repeated dose toxicity

Components:
108-88-3:
Species: rat, male and female
NOAEL: 300
Application Route: inhalation (vapour)
Exposure time: 6, 12, or 18 mths
Number of exposures: 6 h/d, 5 d/wk
Dose: 0, 30, 100, 300 ppm
Method: OECD Test Guideline 453

Repeated dose toxicity - : Causes skin irritation.


Assessment

MSDS Number: 100000002760 12 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

Aspiration toxicity

Product:
May be fatal if swallowed and enters airways.

Components:
108-88-3:
Aspiration Toxicity - Category 1

Further information

Product:
Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nau-
sea and vomiting., Concentrations substantially above the TLV value may cause nar-
cotic effects., Solvents may degrease the skin.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:
108-88-3:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 5.5
mg/l
Exposure time: 96 h
Test Type: flow-through test

Toxicity to daphnia and : EC50 (Ceriodaphnia dubia): 3.78 mg/l


other aquatic inverte- Exposure time: 48 h
brates Test Type: Renewal

Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 134


mg/l
Exposure time: 3 h
Test Type: static test

Toxicity to bacteria : IC50 (Bacteria): 84 mg/l


Exposure time: 24 h
Test Type: Static

Ecotoxicology Assessment
Acute aquatic toxicity : Toxic to aquatic life.

Chronic aquatic toxicity : Toxic to aquatic life with long lasting effects.

MSDS Number: 100000002760 13 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

Persistence and degradability

Components:
108-88-3:
Biodegradability : Inoculum: Sewage
Biodegradation: 100 %
Remarks: Readily biodegradable

Bioaccumulative potential

Components:
108-88-3:
Partition coefficient: n- : log Pow: 2.73
octanol/water

Mobility in soil
No data available
Other adverse effects
No data available
Product:
Regulation 40 CFR Protection of Environment; Part 82 Protection
of Stratospheric Ozone - CAA Section 602 Class I Sub-
stances
Remarks This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).

Additional ecological in- : An environmental hazard cannot be excluded in the


formation event of unprofessional handling or disposal., Toxic to
aquatic life.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Dispose of in accordance with all applicable local,
state and federal regulations.
For assistance with your waste management needs -
including disposal, recycling and waste stream reduc-
tion, contact NEXEO's Environmental Services Group
at 800-637-7922.

Contaminated packaging : Empty remaining contents.


Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty

MSDS Number: 100000002760 14 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

drum.

SECTION 14. TRANSPORT INFORMATION

IATA (International Air Transport Association): UN1294, TOLUENE, 3, II, Flash


Point:4 - 7 °C(39 - 45 °F)

IMDG (International Maritime Dangerous Goods): UN1294, TOLUENE, 3, II

DOT (Department of Transportation): UN1294, TOLUENE, 3, II

SECTION 15. REGULATORY INFORMATION

OSHA Hazards : Flammable liquid, Moderate skin irritant, Teratogen,


Reproductive hazard

WHMIS Classification : B2: Flammable liquid


D2A: Very Toxic Material Causing Other Toxic Effects
D2B: Toxic Material Causing Other Toxic Effects

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity


Components CAS-No. Component Calculated product
RQ (lbs) RQ (lbs)
Toluene 108-88-3 1000 1000
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 : Fire Hazard


Hazards Acute Health Hazard
Chronic Health Hazard

SARA 302 : SARA 302: No chemicals in this material are subject


to the reporting requirements of SARA Title III,
Section 302.

SARA 313 : The following components are subject to reporting


levels established by SARA Title III, Section 313:

108-88-3 Toluene 100 %

Clean Air Act

MSDS Number: 100000002760 15 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12
(40 CFR 61):
108-88-3 Toluene 100 %
100-41-4 Ethylbenzene 0.0999 %
71-43-2 Benzene 0.0999 %
98-82-8 Cumene 0.0004 %
This product does not contain any chemicals listed under the U.S. Clean Air Act
Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).
The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI
Intermediate or Final VOC's (40 CFR 60.489):
108-88-3 Toluene 100 %
100-41-4 Ethylbenzene 0.0999 %
71-43-2 Benzene 0.0999 %
98-82-8 Cumene 0.0004 %
Clean Water Act
The following Hazardous Substances are listed under the U.S. CleanWater Act, Sec-
tion 311, Table 116.4A:
108-88-3 Toluene 100 %
100-41-4 Ethylbenzene 0.0999 %
71-43-2 Benzene 0.0999 %
The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section
311, Table 117.3:
108-88-3 Toluene 100 %
100-41-4 Ethylbenzene 0.0999 %
71-43-2 Benzene 0.0999 %
This product contains the following toxic pollutants listed under the U.S. Clean Water
Act Section 307
108-88-3 Toluene 100 %
US State Regulations

Massachusetts Right To Know


108-88-3 Toluene 90 - 100 %
71-43-2 Benzene 0 - 0.1 %
Pennsylvania Right To Know
108-88-3 Toluene 90 - 100 %
100-41-4 Ethylbenzene 0 - 0.1 %
71-43-2 Benzene 0 - 0.1 %

New Jersey Right To Know


108-88-3 Toluene 90 - 100 %

California Prop 65 WARNING! This product contains a chemical known to


the State of California to cause cancer.
100-41-4 Ethylbenzene
71-43-2 Benzene
98-82-8 Cumene
WARNING: This product contains a chemical known to
the State of California to cause birth defects or other

MSDS Number: 100000002760 16 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

reproductive harm.
108-88-3 Toluene
71-43-2 Benzene

The components of this product are reported in the following inventories:


Switzerland. New notified substances and declared : y (positive listing)
preparations (The formulation
contains substances
listed on the Swiss
Inventory)

United States TSCA Inventory : y (positive listing)


(On TSCA Inven-
tory)

Canadian Domestic Substances List (DSL) : y (positive listing)


(All components of
this product are on
the Canadian DSL.)

Australia Inventory of Chemical Substances (AICS) : y (positive listing)


(On the inventory,
or in compliance
with the inventory)

New Zealand. Inventory of Chemical Substances : y (positive listing)


(On the inventory,
or in compliance
with the inventory)

Japan. ENCS - Existing and New Chemical : y (positive listing)


Substances Inventory (On the inventory,
or in compliance
with the inventory)

Japan. ISHL - Inventory of Chemical Substances : y (positive listing)


(METI) (On the inventory,
or in compliance
with the inventory)

Korea. Korean Existing Chemicals Inventory (KECI) : y (positive listing)


(On the inventory,
or in compliance
with the inventory)

Philippines Inventory of Chemicals and Chemical : y (positive listing)


Substances (PICCS) (On the inventory,
or in compliance
with the inventory)

MSDS Number: 100000002760 17 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

China. Inventory of Existing Chemical Substances in : y (positive listing)


China (IECSC) (On the inventory,
or in compliance
with the inventory)

SECTION 16. OTHER INFORMATION

Further information

NFPA: HMIS III:


Flammability

HEALTH 2*
3
Instability
Health

2 0 FLAMMABILITY 3
PHYSICAL HAZARD 0

0 = not significant, 1 =Slight,


Special hazard. 2 = Moderate, 3 = High
4 =Extreme, * = Chronic

The information accumulated is based on the data of which we are aware and is
believed to be correct as of the date hereof. Since this information may be ap-
plied under conditions beyond our control and with which we may be unfamiliar
and since data made become available subsequently to the date hereof, we do
not assume any responsibility for the results of its use. Recipients are advised to
confirm in advance of need that the information is current, applicable, and suita-
ble to their circumstances. This MSDS has been prepared by NEXEO™ Solutions
EHS Product Safety Department (1-855-429-2661) MSDS@nexeosolutions.com.

Legecy MSDS: R0000565

Material number:
16076583, 20054, 16052078, 16044492, 16042922, 16020146, 758386, 744411,
744290, 710730, 710841, 659495, 638920, 605418, 599094, 591594, 583688,
577548, 74292, 554035, 554297, 554199, 554034, 550273, 547202, 508613,
508487, 102358, 87255, 86312, 53763, 87252, 102690, 70140, 85974, 53211,
54494, 53551, 86521, 53216, 69928, 102899, 69593, 103631, 54061, 70083,
86461, 102680, 53543, 69918, 85966, 53699, 127683, 508226, 508225, 503157,
502489, 500113, 500040, 20058, 20055, 20052, 20051, 20050, 20049, 508283

MSDS Number: 100000002760 18 / 19 Toluene


Safety Data Sheet
Toluene
Version 1.3 Revision Date: 03/06/2015

Key or legend to abbreviations and acronyms used in the safety data sheet
ACGIH American Conference of Gov- LD50 Lethal Dose 50%
ernment Industrial Hygienists
AICS Australia, Inventory of Chem- LOAEL Lowest Observed Adverse Effect
ical Substances Level
DSL Canada, Domestic Sub- NFPA National Fire Protection Agency
stances List
NDSL Canada, Non-Domestic Sub- NIOSH National Institute for Occupational
stances List Safety & Health
CNS Central Nervous System NTP National Toxicology Program
CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemicals
EC50 Effective Concentration NOAEL No Observable Adverse Effect Level
EC50 Effective Concentration 50% NOEC No Observed Effect Concentration
EGEST EOSCA Generic Exposure OSHA Occupational Safety & Health Admin-
Scenario Tool istration
EOSCA European Oilfield Specialty PEL Permissible Exposure Limit
Chemicals Association
EINECS European Inventory of Exist- PICCS Philipines Inventory of Commercial
ing Chemical Substances Chemical Substances
MAK Germany Maximum Concen- PRNT Presumed Not Toxic
tration Values
GHS Globally Harmonized System RCRA Resource Conservation Recovery Act
>= Greater Than or Equal To STEL Short-term Exposure Limit
IC50 Inhibition Concentration 50% SARA Superfund Amendments and Reau-
thorization Act.
IARC International Agency for Re- TLV Threshold Limit Value
search on Cancer
IECSC Inventory of Existing Chemi- TWA Time Weighted Average
cal Substances in China
ENCS Japan, Inventory of Existing TSCA Toxic Substance Control Act
and New Chemical Sub-
stances
KECI Korea, Existing Chemical In- UVCB Unknown or Variable Compositon,
ventory Complex Reaction Products, and
Biological Materials
<= Less Than or Equal To WHMIS Workplace Hazardous Materials In-
formation System
LC50 Lethal Concentration 50%

MSDS Number: 100000002760 19 / 19 Toluene

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