SAFETY DATA SHEET

Issue Date: 09-Oct-2019 Revision Date: 09-Oct-2019 Version: 2

1. PRODUCT AND COMPANY IDENTIFICATION

Product identifier
Product Name: EVERGREEN® Crop Protection EC 60-6

EPA Registration Number: 1021-1770

Other means of identification

Part Code: 7448A

Recommended use of the chemical and restrictions on use:

Recommended Use: Insecticide.

Details of the supplier of the safety data sheet

Manufacturer Address: FAX #:

McLaughlin Gormley King Company (763) 544-6437
7325 Aspen Lane North
Minneapolis, MN 55428
USA
Telephone Number: (800) 645-6466, or (763) 544-0341
e-Mail Address: mgk-sds@mgk.com

Emergency telephone numbers:

24 Hour TRANSPORTATION Emergency: CHEMTREC®: (800) 424-9300
International: (703) 527-3887

24 Hour MEDICAL Emergency: SafetyCall®: (888) 740-8712, or (952) 852-9509

Comments: MGK® Hours of operation are 8:00 a.m. to 4:30 p.m. CST, 14:00 to 22:30 GMT.
For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to
(888) 740-8712, or (952) 852-9509.

2. HAZARDS IDENTIFICATION

Classification:

OSHA Regulatory Status:

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).

Skin corrosion/irritation Category 2

Skin sensitization Category 1

Label elements
Emergency Overview
WARNING

Hazard statements
•H315-Causesski ni
rr
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ati
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•H317-Maycauseanal l
ergi
cski
nreacti
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Appearance: Clear , amber - brown Physical state: Liquid Odor Sweet - Solvent

Precautionary Statements - Prevention:

P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P272 - Contaminated work clothing should not be allowed out of the workplace
P280 - Wear protective gloves

Precautionary Statements - Response:

P321 - Specific treatment (see Section 4/ First Aid).
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P362 - Take off contaminated clothing and wash before reuse
P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention

Precautionary Statements - Storage:

P404 - Store in a closed container

Precautionary Statements - Disposal:

P501 - Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC):

Not applicable

3. COMPOSITION/ INFORMATION ON INGREDIENTS

Chemical Name CAS No. Weight-%

Pyrethrins 8003-34-7 6.00
Piperonyl Butoxide (PBO) 51-03-6 60.0

*The exact percentage (concentration) of composition has been withheld as a trade secret

Comments: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications.

4. FIRST AID MEASURES

Aspiration pneumonia hazard: •Notappl

i
cabl
e

Description of first aid measures:

Eye contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove
contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call
a poison control center or doctor for treatment advice.

Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for
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15-20 minutes. Call a poison control centeror doctor for treatment advice.

Ingestion: If swallowed, IMMEDIATELY call a poison control center or doctor for treatment
advice. Have person sip a glass of water if able to swallow. Do not induce vomiting
unless told to do so by a poison control center or a doctor. Never give anything by
mouth to an unconscious person.

Inhalation: Remove affected person to fresh air. If person is not breathing, call 911 or an
ambulance, then give artificial respiration, preferably mouth-to-mouth if possible.
Call a poison control center or doctor for further treatment advice.

Self-protection of the First Use personal protective equipment as required.

Responder:

Note to physicians:
For skin effects, a highly efficient therapeutic agent for Pyrethrin/ Pyrethroid
exposure is topical application of tocopherol acetate (Vitamin E).

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Use. Dry chemical. Carbon dioxide (CO2). Water spray (fog). Alcohol resistant foam.

Unsuitable extinguishing media:

Caution: Use of water spray when fighting fire may be inefficient.

Hazardous combustion products: Carbon monoxide, Carbon dioxide (CO2).

Specific hazards arising from the chemical

No information available.

Explosion data
Sensitivity to Mechanical Impact: None.
Sensitivity to Static Discharge: None.

Protective equipment and precautions for firefighters:

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent)
and full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions: Use personal protective equipment as required. Evacuate personnel to safe areas.
Keep people away from and upwind of spill/leak.

Environmental precautions: Prevent entry into waterways, sewers, basements or confined areas. Do not flush
into surface water or sanitary sewer system. Prevent further leakage or spillage if
safe to do so. Prevent product from entering drains.

Methods and material for containment and cleaning up

Methods for containment: Prevent further leakage or spillage if safe to do so.

Methods for cleaning up: Pick up and transfer to properly labeled containers. Cover liquid spill with sand,
earth or other non-combustible absorbent material. Cover powder spill with plastic
sheet or tarp to minimize spreading. Dam up. Soak up with inert absorbent
material.
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7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling: Use personal protective equipment as required. Avoid contact with skin, eyes or
clothing. Wash contaminated clothing before reuse. Do not breathe
dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this
product. Use with local exhaust ventilation.

Conditions for safe storage, including any incompatibilities

Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Keep out of the
reach of children. Keep containers tightly closed in a cool, well-ventilated place.
Keep in properly labeled containers.

8. EXPOSURE CONTROLS/ PERSONAL PROTECTION

Control parameters

Exposure Guidelines:

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Supplier OEL
Pyrethrins TWA: 5 mg/m3 TWA: 5 mg/m3 IDLH: 5000 mg/m3 -
8003-34-7 (vacated) TWA: 5 mg/m3 TWA: 5 mg/m3

NIOSH IDLH Immediately Dangerous to Life or Health

Appropriate engineering controls

Engineering Controls: Safety showers

Eyewash stations
Ventilation systems

Individual protection measures, such as personal protective equipment

Eye/face protection: Protective eyewear is recommended, but is not required.

Skin and body protection: Wear protective gloves and protective clothing.

Respiratory protection: If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA

approved respiratory protection should be worn. Positive-pressure supplied air
respirators may be required for high airborne contaminant concentrations.
Respiratory protection must be provided in accordance with current local
regulations.

General Hygiene When using do not eat, drink or smoke. Wash contaminated clothing before reuse.
Considerations: Regular cleaning of equipment, work area and clothing is recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties:

Physical state: Liquid

Appearance: Clear , amber - brown
Odor Sweet - Solvent
Odor threshold: No information available
Color (Gardner Scale): 7
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Property: Values: Comment :•Met

hod
pH: 5.10 @ 10% in H2O
Melting point / freezing point: No information available
Boiling point / boiling range: No information available
Flash point: > 93.3 °C / > 200.0 °F Tag Closed Cup

Evaporation rate: No information available

Flammability (solid, gas): No information available
Upper flammability limit (UEL): No information available
Lower flammability limit (LEL): No information available
Vapor pressure: No information available
Vapor density: No information available
Specific Gravity: No information available
Water solubility: No information available
Partition coefficient; n-Octanol/ No information available
Water:
Autoignition temperature: No information available
Decomposition temperature: No information available
Kinematic viscosity: No information available
Dynamic viscosity: 57.5 cPs @ 22.0 °C
Refractive Index: 1.4875 @ 25.0 °C

Other Information:
Density: 1.017 g/cm3 @ 20.0 °C
VOC Content (%): 0.26

Miscibility/ Solubility:
Water: Partially miscible
Alcohol: Miscible
Aromatic solvents: Miscible
Petroleum distillates: Miscible

10. STABILITY AND REACTIVITY

Reactivity
No data available

Chemical stability
Stable under recommended storage conditions.

Possibility of Hazardous Reactions

None under normal processing.

Hazardous polymerization: Hazardous polymerization does not occur.

Conditions to avoid
Extremes of temperature and direct sunlight.

Incompatible materials:
Incompatible with strong acids and bases. Incompatible with oxidizing agents.

Hazardous Decomposition Products

Carbon monoxide, Carbon dioxide (CO2).

11. TOXICOLOGICAL INFORMATION

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Numerical measures of toxicity - Product Information

Oral LD50 >3,129 mg/kg (rat)

Dermal LD50 >5,000 mg/kg (rabbit)
Inhalation LC50 >5.06 mg/L, (rat; 4 hours)
Eye contact: Irritation clearing in 48 hours. (rabbit).
Skin Contact: Moderate irritation at 72 hours. (rabbit).
Skin Irritation Index: 3.5

Sensitization: Positive. (guinea pig).

Piperonyl Butoxide: Marginally higher incidences of benign liver tumors in mice were observed
Carcinogenicity/ Oncogenicity: following lifetime high dose exposures to PBO. The significance of these
observations is questionable and under review. The doses at which tumors were
observed for PBO greatly exceeded potential human exposure from labeled uses.
Doses at which these effects were observed greatly exceeded anticipated human
dietary intake. At anticipated dietary exposure levels, it is highly unlikely that this
product will result in carcinogenic effects.

Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed
by OSHA, IARC or NTP.

Reproductive toxicity: No information available.

Developmental Toxicity No information available.
Teratogenicity: No information available.
STOT - single exposure: No information available.
STOT - repeated exposure: No information available.
Chronic toxicity: Avoid repeated exposure.
Target Organ Effects: Central nervous system, Respiratory system, Skin.

12. ECOLOGICAL INFORMATION

Ecotoxicity:

Persistence and degradability

No information available.

Bioaccumulation
No information available.

Other adverse effects: No information available

Environmental hazards (EPA):

Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless
in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the
permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to
sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your
State Water Board or Regional Office of the EPA.

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal of wastes: Disposal should be in accordance with applicable regional, national and local laws
and regulations. For more information, see product label.
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Contaminated packaging: For more information, see product label.

14. TRANSPORT INFORMATION

DOT (Department of Transportation)

UN/ID Number: UN3082

Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s., RQ (Pyrethrins)
Hazard Class: 9
Packing Group: III

Other DOT Shipping This material is not regulated as a hazardous material by the DOT in quantities
Information: less than 16.67 Lbs. per shipping unit.

Shipping name for quantities less than 16.67 Lbs. per shipping unit:

Insecticides, Insect or Animal Repellent, Liquid

Hazard Class:This material is not hazardous.

Air (IATA/ ICAO)

UN/ID Number: UN3082

Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s., RQ (Pyrethrins)
Hazard Class: 9
Packing Group: III

Other IATA / ICAO Shipping This material is not regulated as a hazardous material by IATA / ICAO in
Information: quantities less than 16.67 Lbs. per shipping unit.

Shipping name for quantities less than 16.67 Lbs. per shipping unit:

Insecticides, Insect or Animal Repellent, Liquid

Hazard Class:This material is not hazardous.

Vessel (IMO/ IMDG)

UN/ID Number: UN3082

Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s., RQ (Pyrethrins)
Hazard Class: 9
Packing Group: III

Other IMO / IMDG Shipping This material is not regulated as a hazardous material by IMO / IMDG in quantities
Information: less than 16.67 Lbs. per shipping unit.

Shipping name for quantities less than 16.67 Lbs. per shipping unit:

Insecticides, Insect or Animal Repellent, Liquid

Hazard Class:This material is not hazardous.

15. REGULATORY INFORMATION

US Federal Regulations

SARA 313
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Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains
a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal
Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
Piperonyl Butoxide (PBO) - 51-03-6 1.0

SARA 311/312 Hazard

Categories
Acute health hazard Yes
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No

CWA (Clean Water Act)

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40
CFR 122.21 and 40 CFR 122.42)

Chemical Name CWA - Reportable CWA - Toxic CWA - Priority CWA - Hazardous
Quantities Pollutants Pollutants Substances
Pyrethrins 1 lb - - -
8003-34-7

CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the
Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Chemical Name Hazardous Substances CERCLA/SARA RQ Reportable Quantity (RQ):

RQs
Pyrethrins 1 lb - RQ 1 lb final RQ
8003-34-7 RQ 0.454 kg final RQ

US State Regulations:

California Proposition 65:

This product does not contain any intentionally added Proposition 65 chemicals

U.S. EPA Label Information:

EPA Registration Number: 1021-1770

Difference between SDS and EPA (FIFRA) Pesticide label:

This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject
to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria
and hazard information required for Safety Data Sheets (SDS), and for workplace labels of non-pesticide chemicals.
The pesticide label also includes other important information, including directions for use. The hazard information
required on the pesticide label is reproduced below:

Signal word: CAUTION

Precautionary Statements:
•Harmf ulifswallowed.
•Prolongedorf r
equentlyrepeat
edski
ncont
actmaycauseal
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ergi
creact
ionsi
nsomei
ndi
vi
dual
s.

International Inventories:
TSCA Complies
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DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Does not comply
IECSC Complies
KECL Does not comply
PICCS Does not comply
AICS Does not comply

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical
Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION.

NFPA Health hazards 2 Flammability 1 Instability 0 Physical and

Chemical Properties
-
HMIS Health hazards 2 Flammability 1 Physical hazards 0 Personal protection
X

Chronic Hazard Star Legend * = Chronic Health Hazard

Issue Date: Revision Date: Revision Note:

28-Oct-2019 09-Oct-2019 - SDS sections updated
-1
-2
-5
-8
- 14
- 15
- 16

SDS Prepared By: Troy Azzivitto, MGK® Chemistry Department.

e-Mail Address: mgk-sds@mgk.com

Disclaimer: The information provided in this Safety Data Sheet (SDS) is provided in good faith
and believed to be accurate at the time of preparation of the SDS. However, to the
extent consistent with applicable law, MGK® and its subsidiaries or affiliates
extend no warranties, make no representations, and assume no responsibility as
to the accuracy, suitability, or completeness of such information. Additionally, to
the extent consistent with applicable law, neither MGK® nor any of its subsidiaries
or affiliates represents or guarantees that this information or product may be used
without infringing the intellectual property rights of others. Except to the extent a
particular use and particular information are expressly stated on the product label,
itistheuser s’ownr esponsi bi l
it
yt odeter mi net hesui tabili
tyofthisi nformat i
onf or
their own particular use of this product. If necessary, contact MGK® to confirm
that you have the most current product label and SDS.

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This Safety Data Sheet (SDS) serves different purposes than and DOES NOT
REPLACE OR MODIFY THE EPA-APPROVED PRODUCT LABEL (attached to
and accompanying the product container). This SDS provides important health,
safety, and environmental information for employers, employees, emergency
responders and others handling large quantities of the product in activities
generally other than product use as required by the Occupational Health and
Saf etyAct( 29CFR1910. 1200,“ Hazcom” ).Thepr oductl abelprovidesi nformat i
on
specifically for product use in the ordinary course. Use, storage and disposal of
pesticide products is regulated by the EPA under the authority of FIFRA through
the product label. All necessary hazard classification and appropriate
precautionary use, storage, and disposal information is set forth on that label or
labeling accompanying the pesticide or to which reference is made on the label. It
is a violation of federal law to use an EPA-registered pesticide product in any
manner inconsistent with its labeling.

End of Safety Data Sheet.

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