Fire Barrier Silicone Sealant

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 08 August 2018 Revision date: 08 August 2018 Version: 1.0

SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : Fire Barrier Silicone Sealant
Product code : INSS2460, INSS2460+
1.2. Recommended use and restrictions on use
Use of the substance/mixture : Fill, Void Or Cavity Materials
1.3. Supplier
International Fireproof Technology, Inc.
17528 Von Karman Ave.
Irvine, CA 92614
T 949-975-8588
tom@painttoprotect.com (Tom Hsiang)

1.4. Emergency telephone number

Emergency number : CHEMTREC 1-800-424-9300

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS-US classification
Acute toxicity (oral) Category 4 Harmful if swallowed
Serious eye damage/eye irritation Category 2B Causes eye irritation

2.2. GHS Label elements, including precautionary statements

GHS-US labeling
Hazard pictograms (GHS-US) :

Signal word (GHS-US) : Warning

Hazard statements (GHS-US) : Harmful if swallowed
Causes eye irritation
Precautionary statements (GHS-US) : Wash hands thoroughly after handling.
Do not eat, drink or smoke when using this product.
If swallowed: Call a POISON CENTER if you feel unwell
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing
Rinse mouth.
If eye irritation persists: Get medical advice/attention.
Dispose of contents/container to hazardous or special waste collection point, in accordance
with local, regional, national and/or international regulation

2.3. Other hazards which do not result in classification

Other hazards not contributing to the : Titanium dioxide is in a form that is not available for respiration. Silica is in a form that is not
classification available for respiration.
2.4. Unknown acute toxicity (GHS US)
Not applicable

SECTION 3: Composition/Information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
Ammonium polyphosphate (CAS-No.) 68333-79-9 25 - 35 Acute Tox. 4 (Oral), H302
Eye Irrit. 2B, H320

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Fire Barrier Silicone Sealant
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Name Product identifier % GHS-US classification

Tridymite (CAS-No.) 15468-32-3 5 - 15 Carc. 1A, H350
Titanium dioxide (CAS-No.) 13463-67-7 1-5 Carc. 2, H351

Full text of hazard classes and H-statements : see section 16

SECTION 4: First-aid measures

4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or
doctor/physician if you feel unwell.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed
by warm water rinse.
First-aid measures after eye contact : In case of eye contact, immediately rinse with clean water for 10-15 minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a POISON
CENTER or doctor/physician if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects after skin contact : May cause slight temporary irritation.
Symptoms/effects after eye contact : Causes eye irritation.
Symptoms/effects after ingestion : Harmful if swallowed. Swallowing a small quantity of this material will result in serious health
hazard.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.
Unsuitable extinguishing media : None known.
5.2. Specific hazards arising from the chemical
Fire hazard : On combustion, forms: carbon oxides (CO and CO2).
Explosion hazard : No direct explosion hazard.
Reactivity : Stable under normal conditions of use.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Avoid contact with spilled material.

6.1.1. For non-emergency personnel

Protective equipment : Wear personal protective equipment.
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Do not allow uncontrolled discharge of product into the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Shovel
or sweep up and put in a closed container for disposal. Collect spillage. Store away from other
materials.

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Fire Barrier Silicone Sealant
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

6.4. Reference to other sections

For further information refer to section 8: "Exposure controls/personal protection". For disposal of residues refer to section 13: "Disposal considerations".

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Use only outdoors or in a well-ventilated area. Avoid contact with eyes.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Handle in accordance with good industrial hygiene and safety
practice.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep only in the original container in a cool well ventilated place.
Incompatible materials : Keep away from strong acids, strong bases and oxidizing agents.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Ammonium polyphosphate (68333-79-9)
Not applicable
Tridymite (15468-32-3)
OSHA OSHA PEL (TWA) (mg/m³) 50 µg/m³
IDLH US IDLH (mg/m³) 25 mg/m³ (respirable dust)
NIOSH NIOSH REL (TWA) (mg/m³) 0.05 mg/m³ (respirable dust)

Titanium dioxide (13463-67-7)

ACGIH Local name Titanium dioxide
ACGIH ACGIH TWA (mg/m³) 10 mg/m³
ACGIH Remark (ACGIH) LRT irr; A4
ACGIH Regulatory reference ACGIH 2018
OSHA OSHA PEL (TWA) (mg/m³) 15 mg/m³
OSHA Regulatory reference (US-OSHA) OSHA
IDLH US IDLH (mg/m³) 5000 mg/m³

8.2. Appropriate engineering controls

Appropriate engineering controls : Ensure adequate ventilation. Emergency eye wash fountains and safety showers should be
available in the immediate vicinity of any potential exposure.

8.3. Individual protection measures/Personal protective equipment

Hand protection:
Impermeable protective gloves

Eye protection:
Chemical goggles or safety glasses

Respiratory protection:
Not necessary under the recommended storage and handling conditions

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Paste. Viscous.
Color : white black or gray
Odor : characteristic
Odor threshold : No data available

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Fire Barrier Silicone Sealant
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

pH : Not available
Melting point : Not available
Freezing point : No data available
Boiling point : > 100 °C
Flash point : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : No data available
Vapor pressure : No data available
Relative vapor density at 20 °C : No data available
Relative density : No data available
Specific gravity / density : 1.3 ± 0.1
Solubility : Not miscible.
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : 100 - 150 Pa.s
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
Stable under normal conditions of use.
10.2. Chemical stability
Stable at ambient temperature and under normal conditions of use.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
None under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from strong acids, strong bases and oxidizing agents.
10.6. Hazardous decomposition products
No hazardous decomposition products known at room temperature. On combustion, forms: carbon oxides (CO and CO2).

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity (oral) : Oral: Harmful if swallowed.
Acute toxicity (dermal) : Not classified (Based on available data, the classification criteria are not met)
Acute toxicity (inhalation) : Not classified (Based on available data, the classification criteria are not met)
ATE US (oral) 1033 mg/kg body weight
Ammonium polyphosphate (68333-79-9)
LD50 oral rat 300 - 2000 mg/kg

Titanium dioxide (13463-67-7)

LD50 oral rat > 10000 mg/kg
Skin corrosion/irritation : Not classified (Based on available data, the classification criteria are not met)
pH: Not available
Serious eye damage/irritation : Causes eye irritation.
pH: Not available

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Fire Barrier Silicone Sealant
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Respiratory or skin sensitization : Not classified (Based on available data, the classification criteria are not met)
Germ cell mutagenicity : Not classified (Based on available data, the classification criteria are not met)
Carcinogenicity : Not classified (Based on available data, the classification criteria are not met)
Fire Barrier Silicone Sealant
Additional information Titanium dioxide is in a form that is not available for respiration
Silica is in a form that is not available for respiration

Tridymite (15468-32-3)
IARC group 1 - Carcinogenic to humans
National Toxicity Program (NTP) Status Known Human Carcinogens
In OSHA Hazard Communication Carcinogen Yes
list
Titanium dioxide (13463-67-7)
IARC group 2B - Possibly carcinogenic to humans
In OSHA Hazard Communication Carcinogen Yes
list
Reproductive toxicity : Not classified (Based on available data, the classification criteria are not met)
Specific target organ toxicity – single exposure : Not classified (Based on available data, the classification criteria are not met)

Specific target organ toxicity – repeated : Not classified (Based on available data, the classification criteria are not met)
exposure

Aspiration hazard : Not classified

(Based on available data, the classification criteria are not met)
Viscosity, kinematic : No data available

Likely routes of exposure : Inhalation. Ingestion. Eyes. Skin.

Symptoms/effects after skin contact : May cause slight temporary irritation.
Symptoms/effects after eye contact : Causes eye irritation.
Symptoms/effects after ingestion : Harmful if swallowed. Swallowing a small quantity of this material will result in serious health
hazard.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : This material has not been tested for environmental effects.

Ammonium polyphosphate (68333-79-9)

LC50 fish 1 > 500 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [static])
LC50 fish 2 123 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through])

12.2. Persistence and degradability

No additional information available

12.3. Bioaccumulative potential

No additional information available

12.4. Mobility in soil

No additional information available

12.5. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Disposal methods
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.

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Fire Barrier Silicone Sealant
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

Department of Transportation (DOT)
In accordance with DOT

Not regulated

Transportation of Dangerous Goods

Not regulated

Transport by sea

Not regulated

Air transport

Not regulated

SECTION 15: Regulatory information

15.1. US Federal regulations

Ammonium polyphosphate (68333-79-9)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

Titanium dioxide (13463-67-7)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

15.2. International regulations

CANADA
Ammonium polyphosphate (68333-79-9)
Listed on the Canadian DSL (Domestic Substances List)

Titanium dioxide (13463-67-7)

Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
Ammonium polyphosphate (68333-79-9)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Tridymite (15468-32-3)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)
Titanium dioxide (13463-67-7)
Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

National regulations
Ammonium polyphosphate (68333-79-9)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Japanese ISHL (Industrial Safety and Health Law)
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
Listed on the TCSI (Taiwan Chemical Substance Inventory)

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Fire Barrier Silicone Sealant
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Tridymite (15468-32-3)
Listed on IARC (International Agency for Research on Cancer)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Japanese ISHL (Industrial Safety and Health Law)
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed as carcinogen on NTP (National Toxicology Program)
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on the TCSI (Taiwan Chemical Substance Inventory)
Titanium dioxide (13463-67-7)
Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Japanese ISHL (Industrial Safety and Health Law)
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on INSQ (Mexican National Inventory of Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
Listed on the TCSI (Taiwan Chemical Substance Inventory)
15.3. US State regulations

WARNING: This product can expose you to Titanium dioxide, which is known to the State of California to cause cancer. For more
information go to www.P65Warnings.ca.gov.
Component Carcinogenicity Developmental Reproductive Reproductive No significant Maximum
toxicity toxicity male toxicity risk level (NSRL) allowable
female dose level
(MADL)
Titanium X
dioxide(13463-67-7)

SECTION 16: Other information

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Revision date : 08 August 2018

Other information : None.

Full text of H-phrases:

H302 Harmful if swallowed
H320 Causes eye irritation
H350 May cause cancer
H351 Suspected of causing cancer

SDS US (GHS HazCom 2012)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product

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