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Material Safety Data Sheet: 1. Identification of The Product

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Unilever Australia

219 North Rocks Road


North Rocks NSW
Australia 2151
Tel: +61 2 98719200
Fax: +61 2 98719568

MATERIAL SAFETY DATA SHEET


1. IDENTIFICATION OF THE PRODUCT

Product Name/s: Variant/s Manufacturer’s Product Codes


Finished Goods Code: Formula Code:
Surf Concentrate Powder Sunshine Fresh All pack sizes 6076-03
Surf Concentrate Powder Tropical Breeze All pack sizes 6074-03
Surf Concentrate Powder Cool Fresh All pack sizes 6078-02

Recommended Use: Fabric Detergent Powder


Supplier: Unilever Australasia
A.B.N: 66 004 050 828
Telephone: +61 2 9871 9200 +64 4 5666949 (NZ)
Facsimile: +61 2 9872 4966 +64 4 5683396 (NZ)
Emergency Telephone: 1 800 227 200 0 800 108 806 (NZ)

2. HAZARDS IDENTIFICATION
HAZARDOUS SUBSTANCE – NON-DANGEROUS GOOD

Hazard Category: Xi: Irritant


Risk Phrase(s): R36 Irritating to eyes
Safety Phrase(s): S2 Keep out of reach of children
S22 Do not breathe dust
S26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice
HSNO Classification: 6.3A, 6.4A, 9.1D

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS No. Proportion %


Sodium Carbonate 497-19-8 30-60%
Anionic Surfactant - <10%
Nonionic Surfactant - <10%
Sodium Silicate 1344-09-8 <10%
Fluorescer - <10%
Other ingredients determined not to - To 100%
be hazardous

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4. FIRST AID MEASURES

Ingestion: Remove product from mouth. Drink 1 or 2 glasses of water (or


milk). If large amount swallowed or symptoms develop obtain
medical attention.
Eye contact: Hold eyes open, flood with water for at least 15 minutes and see
a doctor.
Skin contact: Wash accidental spillage from skin. Remove contaminated
Clothing. Obtain medical attention if symptoms develop.
Inhalation: Remove from source of exposure to fresh air. Obtain medical
attention immediately.
Symptoms: Symptoms may vary depending on the level of exposure
Notes to physician: Symptomatic and general supportive treatment should be given.
Treatment: Treat Symptomatically

5. FIREFIGHTING MEASURES

Suitable extinguishing Extinguish with water, CO2, foam or dry chemical. Fire fighters
media: should wear self-contained breathing apparatus for risk of
exposure to decomposition products.
Specific hazards: Not flammable but may give off toxic fumes if involved in a fire.
Hazards from Burning can produce CO2, CO, water vapour, and sulfur oxide.
decomposition products:

6. ACCIDENTAL RELEASE MEASURES

Small spills: For spills during personal use, rinse with plenty of water. Normal
good housekeeping practices required.
Large spills: For major spills of bulk product, protective clothing consisting of
overalls, safety glasses and gloves should be worn. Shovel or
vacuum up spill, avoiding the formation of dust, and collect in
suitable containers for disposal. Wash or vacuum any remaining
powder. Compressed air must not be used to clean up spills.
It is essential to avoid crushing or grinding the powder, as this
could break open the coating surrounding the encapsulated
enzyme and generate enzyme dust.
People with a history of respiratory problems must not be
employed in the clean up of sizeable spills.

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7. HANDLING AND STORAGE

Precautions for Handling: When handling bulk product wear safety glasses and protective
gloves. Avoid prolonged contact with skin. Avoid excessive
inhalation.
Precautions for Storage: An eyewash station should be installed next to where bulk product
is made or stored.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

National occupational No exposure standard allocated for finished product.


exposure limits:
The blanket recommendation for DUSTS: 10 mg/m3
Engineering measures: When handling bulk product, ensure adequate ventilation. Avoid
breathing powder or dust.
Personal protection When handling bulk product wear safety glasses and protective
equipment: gloves. Avoid prolonged contact with skin. Avoid excessive
inhalation.
Manufacturing, packaging Not defined as a Dangerous Good by the Australian Code for
and transport: Transport of Dangerous Goods by Road or Rail.
Preparation and use of Keep away from foodstuffs and drinks. Wash hands before
product: breaks and at end of shifts.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form/Colour/Odour: White powder


Specific Gravity (20C): 0.65
Boiling Point (C): Not applicable
Rel Vapour Density (air=1): Not applicable
Melting Range (C): Not applicable
Vapour Pressure (20C): Not applicable
Flash Point (C): Not available
Flammability Limits (%): Not available
pH: 1% solution - 10.0 – 10.5
Autoignition Temp (C): Not applicable
% Volatile by volume: Not applicable
Solubility in water (mg/l): Not available

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10. STABILITY AND REACTIVITY

Stability: Product is stable when stored and used in accordance with


manufacturers directions.

11. TOXICOLOGICAL INFORMATION

ACUTE EFFECTS
Ingestion: Unlikely to be harmful unless an excessive amount is swallowed
Eye contact: Irritating to eyes.
Skin contact: May cause irritation.
Inhalation: May cause irritation.
Long Term Effects: No specific chronic effects expected.
Acute Toxicity/Chronic
Acute oral toxicity assessed to be greater than 2000 mg/kg body
Toxicity:
weight.

12. ECOLOGICAL INFORMATION

Ecotoxicity: Not available


Persistence & Not available
degradability:
Mobility: Not available

13. DISPOSAL CONSIDERATIONS

Refer to State Land Waste Management Authority. Empty cartons can be rinsed and disposed
through council recycling service if this type of packaging is accepted.

14. TRANSPORT INFORMATION

UN Number: None Allocated


Proper shipping name: None Allocated
Class: None Allocated
Subsidiary Risk 1: None Allocated
Packing group: None Allocated
Hazchem code: None Allocated
EPG: None Allocated
Segregation Dangerous None Allocated
Goods:
Marine Transport: None Allocated

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Air Transport: None Allocated

15. REGULATORY INFORMATION

SUSDP Poisons Schedule None allocated.


Number:
Prohibition/Licensing There are no applicable prohibition or notification, licensing
Requirements: requirements, including for carcinogens under Commonwealth,
State or Territory legislation.
Industrial Chemicals All ingredients are listed on or exempt from the Australian
(Notifications and inventory of Chemical Substances (AICS).
Assessment) Act 1989:
Hazardous Substances &
Cleaning Products (Subsidiary Hazard) Group Standard
New Organisms Act (NZ):
HSR002530

16. OTHER INFORMATION


Date of Revision: 11 December, 2007

Contact Point
Title / Position: Quality Assurance Manager
Section: Quality Assurance, Unilever Australasia
Telephone: (02) 9871 9316
Poison Information Centre 24 Hour Telephone: 131126

DISCLAIMER
This information is based on our current knowledge and is intended to describe the product for the purpose
of health, safety and environmental requirements only. Since Unilever Australasia cannot anticipate or
control the conditions under which the product may be used, each user must, prior to usage, review this
MSDS in the context of how the user intends to handle and use the product.

Page 5 of 5 MSDS Surf Conc Powder Gen Dec 07

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