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Substance key: 000000411792 Revision Date: 05.12.2016
Version : 1 - 0 / RA Date of printing : 12.06.2021

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Trade Name: HOSTAGEL PH1

Material number: 240111
Recommended use: Viscosifier
Producer or Importer name: Clariant Produkte (Deutschland) GmbH
Address: 65926 Frankfurt am Main
Telephone no. : +49 69 305 18000
MSDS made by: Clariant (Argentina) S.A.
Emergency phone: +54 0800 222 2933 (CIQUIME) (24 h)

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 3

Acute toxicity (Oral) : Category 4

Acute toxicity (Dermal) : Category 3

Skin corrosion : Sub-category 1C

Serious eye damage : Category 1

Acute aquatic toxicity : Category 1

Chronic aquatic toxicity : Category 2

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : H226 Flammable liquid and vapour.

H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements :
Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/
equipment.

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P242 Use non-sparking tools.

P243 Take action to prevent static discharges.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER/doctor if you feel unwell. Rinse mouth.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/doctor.
P361 + P364 Take off immediately all contaminated clothing
and wash it before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam to extinguish.
P391 Collect spillage.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification

Harmful if swallowed.
Causes burns.
Very toxic to aquatic organisms.
Flammable solvent vapours may collect in the vapour spaces of closed containers. Keep away
from fire and other sources of ignition.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Substance name : Blend of amine components

Hazardous components
Chemical name CAS-No. Concentration (% w/w)
C18-Alkyltrimethyl ammonium chloride 112-03-8 >= 10 - < 20

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Propan-2-ol 67-63-0 >= 1 - < 5

SECTION 4. FIRST AID MEASURES

General advice : Remove/Take off immediately all contaminated clothing.

Get medical advice/ attention if you feel unwell.

If inhaled : If inhaled, remove to fresh air.

Get medical advice/ attention.

In case of skin contact : In case of contact, immediately flush skin with soap and plenty
of water.
Get medical attention immediately.

In case of eye contact : Get medical attention immediately.

If swallowed : If swallowed, seek medical advice immediately and show this

container or label.
Do NOT induce vomiting.

Most important symptoms : No symptoms known currently.

and effects, both acute and No hazards known at this time.
delayed

Notes to physician : Treat symptomatically.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray jet

Alcohol-resistant foam
Dry powder
Carbon dioxide (CO2)

Unsuitable extinguishing : High volume water jet

media

Specific hazards during : In case of fires, hazardous combustion gases are formed:
firefighting Carbon monoxide (CO)
Nitrogen oxides (NOx)
Hydrogen chloride

Special protective equipment : Self-contained breathing apparatus

for firefighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Wear suitable protective equipment.

protective equipment and Ensure adequate ventilation.
emergency procedures

Environmental precautions : The product should not be allowed to enter drains, water

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courses or the soil.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Treat recovered material as described in the section "Disposal
considerations".

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Take measures to prevent the build up of electrostatic charge.
fire and explosion

Advice on safe handling : Use only in well-ventilated areas.

Handle and open container with care.

Technical : hygroscopic
measures/Precautions

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
Propan-2-ol 67-63-0 CMP 400 ppm AR OEL
Further information: Irritation
CMP - CPT 500 ppm AR OEL
Further information: Irritation
Biological occupational exposure limits
Components CAS-No. Control Biological Samplin Permissible Basis
parameters specimen g time concentratio
n
Propan-2-ol 67-63-0 Acetone Urine 2 mg/g AR BEI
Creatinine
Acetone Urine End of 40 mg/l ACGIH
shift at BEI
end of
workwee
k
Personal protective equipment
Respiratory protection : Use respiratory protection in case of insufficient exhaust
ventilation or prolonged exposure
Full mask to standard DIN EN 136
Filter A (organic gases and vapours) to standard DIN EN 141
The use of filter apparatus presupposes that the environment
atmosphere contains at least 17% oxygen by volume, and
does not exceed the maximum gas concentration, usually
0.5% by volume. Relevant guidelines to be considered

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include EN 136/141/143/371/372 as well as other national

regulations.

Hand protection
Remarks : Long-term exposure Impervious butyl rubber gloves Minimum
thickness (glove): not determined With solid dry substances
permeation is not to be expected, therefore the breakthrough-
time for this protective glove has not been measured.

For short-term exposure (splash protection): Nitrile rubber

gloves. Minimum thickness (glove): not determined With
solid dry substances permeation is not to be expected,
therefore the breakthrough-time for this protective glove
has not been measured.

These types of protective gloves are offered by various

manufacturers. Please note the manufacturers´ detailed
statements, especially about the minimum thickness and
the minimum breakthrough time. Consider also the
particular working conditions under which the gloves are
being used.

Eye protection : Depending on the risk, wear sufficient eye protection (safety
glasses with side protection or goggles, and if necessary,
face shield.)

Skin and body protection : Depending on the degree of hazard, when handling corrosive
substances, aprons, boots or full protective clothing made of
suitable materials (e.g. rubberized or PVC-coated) must also
be worn.

Protective measures : Observe the usual precautions for handling chemicals.

Hygiene measures : Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it
before reuse.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : paste

Colour : yellow to brownish

Odour : amine-like

Odour Threshold : not tested.

pH : 8-9

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(20 °C)
Concentration: 10 g/l
Method: DIN EN 1262

Melting point : approx. 15 °C

Method: ISO 3016

Boiling point : approx. 82 °C

not determined Data relate to solvent
Flash point : 45 °C
Method: DIN EN 22719 / ISO 2719 (closed cup), Seta closed
cup
Combustion test negative, does not support combustion, not
classified as a hazardous substance.

Evaporation rate : not tested.

Self-ignition : Not applicable

Upper explosion limit : 12,7 %(V)

Data relate to solvent

Lower explosion limit : 2 %(V)

Data relate to solvent

Combustion number : Not applicable

Vapour pressure : 43 mbar (20 °C)

Data relate to solvent

Relative vapour density : 2,1

The data refer to the solvent

Density : approx. 0,905 g/cm3 (25 °C)

Method: DIN 51757

Bulk density : Not applicable

Solubility(ies)
Water solubility : miscible

Solubility in other solvents : not tested.

Solvent: fat

Partition coefficient: n- : not tested.

octanol/water

Auto-ignition temperature : 425 °C

Data relate to solvent

Decomposition temperature : > 350 °C

Heating rate : 3 K/min
Method: DSC

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Information refers to the main component.

Viscosity
Viscosity, dynamic : approx. 130 mPa.s (approx. 25 °C)
Method: DIN 53015

Viscosity, kinematic : not tested.

Explosive properties : no data available

Oxidizing properties : Not applicable

Minimum ignition energy : not tested.

Particle size : Not applicable

SECTION 10. STABILITY AND REACTIVITY

Reactivity : See section 10.3. "Possibility of hazardous reactions"

Chemical stability : Stable under normal conditions.

Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions

Conditions to avoid : Keep away from heat.

Keep away from open flames, hot surfaces and sources of
ignition.

Incompatible materials : not known

Hazardous decomposition : When handled and stored appropriately, no dangerous

products decomposition products are known

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate: 860,22 mg/kg
Method: Calculation method

Acute inhalation toxicity : Remarks: not tested.

Acute dermal toxicity : Acute toxicity estimate: 516,13 mg/kg

Method: Calculation method

Components:
Propan-2-ol:
Acute oral toxicity : LD50 (Rat): 5.840 mg/kg
Method: OECD Test Guideline 401

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GLP: no

Acute inhalation toxicity : LC50 (Rat, male and female): > 25 mg/l
Exposure time: 6 h
Method: OECD Test Guideline 403
GLP: yes

Acute dermal toxicity : LD50 (Rabbit): ca. 12.800 mg/kg

Method: OECD Test Guideline 402
GLP: no

Skin corrosion/irritation
Product:
Remarks: not tested.

Components:
Propan-2-ol:
Species: Rabbit
Exposure time: 4 h
Method: Other
Result: No skin irritation
GLP: no

Serious eye damage/eye irritation

Product:
Remarks: not tested.

Components:
Propan-2-ol:
Species: rabbit eye
Result: Severe eye irritation
Method: OECD Test Guideline 405
GLP: no

Respiratory or skin sensitisation

Product:
Remarks: not tested.

Components:
Propan-2-ol:
Test Type: Guinea pig maximization test
Exposure routes: Skin contact
Species: Guinea pig
Method: OECD Test Guideline 406
Result: Does not cause skin sensitisation.
GLP: yes

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Germ cell mutagenicity

Product:
Germ cell mutagenicity - : No information available.
Assessment

Components:
Propan-2-ol:
Genotoxicity in vitro : Test Type: In vitro gene mutation study in mammalian cells
Species: Chinese hamster ovary cells
Concentration: 500 - 5000 µg/ml
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
GLP: yes

: Test Type: Ames test

Species: Salmonella typhimurium
Concentration: 100 - 10000 µg/plate
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
GLP: no

Genotoxicity in vivo : Test Type: Micronucleus test

Species: Mouse (male and female)
Strain: ICR
Cell type: Bone marrow
Application Route: Intraperitoneal injection
Exposure time: Single exposure
Dose: 350-1173-2500-3500 mg/kg
Method: OECD Test Guideline 474
Result: negative
GLP: yes

Germ cell mutagenicity - : It is concluded that the product is not mutagenic based on
Assessment evaluation of several mutagenicity tests.

Carcinogenicity
Product:
Carcinogenicity - : No information available.
Assessment

Components:
Propan-2-ol:
Carcinogenicity - : Did not show carcinogenic effects in animal experiments.
Assessment

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Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment

No information available.

Components:
Propan-2-ol:
Effects on fertility :
Test Type: Two-generation study
Species: Rat
Sex: male and female
Dose: 100 - 500 - 1000 mg/kg
Frequency of Treatment: daily
Sprague-Dawley
Application Route: oral (gavage)
Group: yes
NOAEL: 500 mg/kg,
F1: 500 mg/kg,
F2: 500 mg/kg,
Method: OECD Test Guideline 416
GLP: yes

Effects on foetal : Species: Rat

development Application Route: oral (gavage)
Exposure time: day 6 to 15 of gestation
Dose: 400 - 800 - 1200 mg/kg
Group: yes
400 mg/kg
400 mg/kg
Number of exposures: daily
Method: OECD Test Guideline 414
GLP: yes

Reproductive toxicity - : No reproductive toxicity to be expected.

Assessment No teratogenic effects to be expected.

STOT - single exposure

Product:
Remarks: not tested.

Components:
Propan-2-ol:
Assessment: May cause drowsiness or dizziness.

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STOT - repeated exposure

Product:
Remarks: not tested.

Components:
Propan-2-ol:
Assessment: The substance or mixture is not classified as specific target organ toxicant,
repeated exposure.

Repeated dose toxicity

Product:
Remarks: not tested.

Components:
Propan-2-ol:
Application Route: Oral
Remarks: This information is not available.

Species: Rat, male and female

NOAEL: ca. 12,5 mg/l
Application Route: Inhalation
Exposure time: 2 a
Number of exposures: 6 hours/day, 5 days/week
Dose: 500 - 2500 - 5000 ppm
Group: yes
Method: Other
GLP: yes

Application Route: Skin contact

Remarks: This information is not available.

Aspiration toxicity
Product:
no data available

Components:
Propan-2-ol:
No aspiration toxicity classification

Further information
Product:
Remarks: The classification was made by the conventional (calculation) method of the CLP
Regulation (EC) No 1272/2008.
no data available

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SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Product:
Toxicity to fish :
Remarks: not tested.

Toxicity to daphnia and other :

aquatic invertebrates Remarks: not tested.

Toxicity to algae :
Remarks: not tested.

Toxicity to microorganisms : Remarks: not tested.

Further information
The following percentage of the mixture consists of ingredient(s) with unknown hazards to the
aquatic environment: 74,4 %
Components:
C18-Alkyltrimethyl ammonium chloride:
M-Factor (Acute aquatic : 10
toxicity)
M-Factor (Chronic aquatic : 1
toxicity)
Propan-2-ol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 9.640 -
10.000 mg/l
Exposure time: 96 h
Test Type: flow-through test
Analytical monitoring: yes
Method: OECD Test Guideline 203
GLP: no

Toxicity to daphnia and other : LC50 (Daphnia magna (Water flea)): > 10.000 mg/l
aquatic invertebrates Exposure time: 24 h
Test Type: static test
Analytical monitoring: no
Method: OECD Test Guideline 202
GLP: no
Remarks: The details of the toxic effect relate to the nominal
concentration.

Toxicity to algae : EC10 (Scenedesmus quadricauda (Green algae)): ca. 1.800

mg/l
Exposure time: 7 d
Test Type: static test
Analytical monitoring: no
Method: Other
GLP: no

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Toxicity to fish (Chronic : Remarks: not required

toxicity)
Toxicity to daphnia and other : Remarks: not required
aquatic invertebrates
(Chronic toxicity)
Toxicity to microorganisms : EC10 (Pseudomonas putida): ca. 1.050 mg/l
Exposure time: 16 h
Test Type: aquatic
Analytical monitoring: no
Method: DIN 38412 T.8
GLP: no

Toxicity to soil dwelling : Remarks: Not applicable

organisms
Plant toxicity : IC50 (Lactuca sativa (lettuce)): 2.100 mg/l
Exposure time: 3 d
End point: emergence
Analytical monitoring: no
Method: Other
GLP: no

Sediment toxicity : Remarks: Not applicable

Toxicity to terrestrial : Remarks: Not applicable

organisms
Persistence and degradability
Product:
Biodegradability : Remarks: not tested.

Components:
Propan-2-ol:
Biodegradability : aerobic
Inoculum: activated sludge, domestic
Biochemical Oxygen Demand (BOD)
Result: Readily biodegradable.
Biodegradation: 53 %
Exposure time: 5 d
Method: Directive 67/548/EEC, Annex V, C.5
GLP: no

Stability in water : Remarks: Not applicable

Bioaccumulative potential
Product:
Bioaccumulation : Remarks: not tested.

Components:
Propan-2-ol:
Bioaccumulation : Remarks: Not applicable

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Mobility in soil
Product:
Distribution among : Remarks: not tested.
environmental compartments
Components:
Propan-2-ol:
Distribution among : Remarks: Not applicable
environmental compartments
Other adverse effects
Product:
Additional ecological : The classification was made by the conventional (calculation)
information method of the CLP Regulation (EC) No 1272/2008.
This information is not available.

Components:
Propan-2-ol:
Environmental fate and : not available
pathways
Results of PBT and vPvB : This substance is not considered to be persistent,
assessment bioaccumulating and toxic (PBT).

Additional ecological : slightly water endangering

information Do not allow to enter ground water, waterways or waste water.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : In accordance with local authority regulations, take to special
waste incineration plant

Contaminated packaging : Packaging that cannot be cleaned should be disposed of as

product waste

SECTION 14. TRANSPORT INFORMATION

MERCO
Proper shipping name: Polyamines, liquid, corrosive, flammable, n.o.s.
Class: 8
Packing group: II
UN no. UN 2734
Primary risk: 8
Secondary risk: 3
Hazard no. : 83
Remarks Shipment permitted
Hazard inducer(s): OLEYLAMINOXETHYLATE
2-Propanol

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IATA
Proper shipping name: Amines, liquid, corrosive, flammable, n.o.s.
Class: 8
Packing group: II
UN/ID number: UN 2734
Primary risk: 8
Secondary risk: 3
Remarks Shipment permitted
Hazard inducer(s): OLEYLAMINOXETHYLATE
2-Propanol
IMDG
Proper shipping name: Amines, liquid, corrosive, flammable, n.o.s.
Class: 8
Packing group: II
UN no. UN 2734
Primary risk: 8
Secondary risk: 3
Remarks Shipment permitted
Hazard inducer(s): OLEYLAMINOXETHYLATE
2-Propanol
Hazard inducer/Marine OLEYLAMINOXETHYLATE
pollutant:
Marine pollutant: Marine Pollutant
EmS : F-E S-C
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or

mixture
International Regulations

SECTION 16. OTHER INFORMATION

Full text of other abbreviations

AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; CPR - Controlled Products Regulations; DIN -
Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada);
ECx - Concentration associated with x% response; ELx - Loading rate associated with x%
response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan);
ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response
Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC -
International Agency for Research on Cancer; IATA - International Air Transport Association; IBC
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation
Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International
Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety
and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea

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Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 -

Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International
Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch -
Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed
(Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican
Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD
- Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety
and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS -
Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure
Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of
the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals;
SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan
Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations
Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very
Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System

Further information
Other information : Observe national and local legal requirements

This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application.
Nothing included in this information waives any of Clariant's General Terms and Conditions of
Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial
property rights must be observed. Due to possible changes in our products and applicable
national and international regulations and laws, the status of our products could change. Material
Safety Data Sheets providing safety precautions, that should be observed when handling or
storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.

AR / EN

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