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01-Periodic Table Allen Material

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PERIODIC PROPERTIES

REVISION MATERIAL
PERIODIC PROPERTIES INORGANIC CHEMISTRY
KEY CONCEPT

INORGANIC CHEMISTRY 1
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REVISION MATERIAL (INORGANIC CHEMISTRY) Path to success KOTA (RAJASTHAN)

EXERCISE
SINGLE CORRECT ANSWER TYPE
1. In the ions P3- , S2- and Cl– the increasing order of size is:-
(A) Cl– , S2- , P3- (B) P3- , S2- ,Cl– (C) S2-, Cl– , P3- (D) S2-, P3—, Cl–
2. The second ionisation potentials in electron volts of oxygen and fluorine atoms are respectively given
by :-
(A) 35.1, 38.3 (B) 38.3, 38.3 (C) 38.3, 35.1 (D) 35.1, 35.1
3. Electron addition would be easier in :-
(A) O (B) O+ (C) O– (D) O+2
4. O(g) + 2e– O2–(g) Heg = 744.7 KJ/mole. The positive value of Heg is due to :-
(A) Energy is released to add on 1 e– to O–1 (B) Energy is required to add on 1 e– to O–1
(C) Energy is needed to add on 1e– to O (D) None of the above is correct
5. Which order is wrong :-
(A) Electronegativity – P < N < O < F (B) Ist ionisation potential – B < Be < O < N
(C) Basic property – MgO > CaO > FeO > Fe2O3 (D) Reactivity – Be < Li < K < Cs
6. 1 2 3 4
H3C – CH = C = CH2
In the given compound which carbon atom will show maximum electronegativity -
(A) Fourth (B) First
(C) Third (D) EN of all the carbon atoms is same
7. Decreasing order of size of ions is :-
(A) Br– > S–2 > Cl– > N–3 (B) N3– > S–2 > Cl– > Br–
(C) Br– > Cl– > S–2 > N–3 (D) N–3 > Cl– > S–2 > Br–
8. The right order of ionization potential of Li, Be, B & C is :
(A) C > Be > B > Li (B) C > B > Be > Li (C) C > B > Li > Be (D) B > C > Be > Li
9. The correct order of second ionization potential of C, N, O and F is
(A) C > N > O > F (B) O > N > F > C (C) O > F > N > C (D) F > O > N > C
10. The correct sequence of the electron affinity of C, N, O and F is :
(A) C > N < O < F (B) O > N > C > F (C) C < N > O < F (D) C > N > O > F
11. The decreasing order of the ionization potential of the following elements is :
(A) Ne > Cl > P > S > Al > Mg (B) Ne > Cl > P > S > Mg > Al
(C) Ne > Cl > S > P > Mg > Al (D) Ne > Cl > S > P > Al > Mg
12. In which of the following arrangements the order is not according to the property indicated
against it ?

(A) Al3+ < Mg2+ < Na+ < F - increasing ionic size
(B) B < C < N < O - increasing first ionization potential
(C) I < Br < F < Cl - increasing electron gain ethalpy (with negative sign)
(D) Li < Na < K < Rb - increasing metallic radius
2 INORGANIC CHEMISTRY
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PERIODIC PROPERTIES
13. Lanthanoid contraction is caused due to :
(A) the same effective nuclear charge from Ce to Lu
(B) the imperfect shielding on outer electrons by 4f electrons from the nuclear charge
(C) the appreciable shielding on outer electrons by 4f electrons from the nuclear charge
(D) the appreciable shielding on outer electrons by 5d electrons from the nuclear charge
14. Which of the following ion is smallest in size ?
(A) Cl– (B) Na+ (C) H+ (D) S2–
15. Size of which elements are mainly respresented as non-bonded radii -
(A) Halogen (B) Chalcogens (C) Noble gas (D) Pnicogens
16. Highest ionisation potential in a period is shown by -
(A) Alkali metals (B) Noble gases (C) Halogens (D) Representative elements
17. The first four I.E. values of an element are 284, 412, 656 and 3210 kJ mol–1 . The number of valence
electrons in the element are :
(A) one (B) two (C) three (D) four
18. If the ionisation energy is IE, electron affinity is EA and electronegativity is X then which of the
following relation is correct :-
(A) 2X – EA – IE = 0 (B) 2EA – X – IE = 0
(C) 2IE – X – EA = 0 (D) All of the above
19. Which of the following order is correct for the acidic strength of oxides -
(A) CaO < CO2 < N2O5 (B) N2O5 < CO2 < CaO
(C) CO2 < N2O5 < CaO (D) N2O5 = CO2 < CaO
20. Arrange in the order of increasing basic strength (NO2, K2O, ZnO) :-
(A) NO2 < ZnO < K2O (B) K2O < ZnO < NO2
(C) NO2 < K2O < ZnO (D) K2O < NO2 < ZnO
INTEGER ANSWER TYPE
21. Element with maximum I.E in periodic table exist in which period number of long form of periodic
table.
22. Element with minimum I.E in periodic table exist in which group number of long form of periodic
table.
23. If group number of elements having highest negative electrongain enthalpy in respective periods is
xy, then x + y is
24. How many of noble gas having negative electron gain enthalpy.
He, Ne, Ar, Kr, Xe, Rn
25. What is the period number of element which has maximum electron affinity among all known elements
in long form of periodic table.
INORGANIC CHEMISTRY 3
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REVISION MATERIAL (INORGANIC CHEMISTRY) Path to success KOTA (RAJASTHAN)

26. Among the following in how many process energy is released ?


(A) N(g) + e– N–(g) (B) Be(g) + e– Be–(g)
(C) O(g) + e– O–(g) (D) Mg–(g) Mg(g) + e–
(E) O(g) O+ +(g) + e– (F) O–(g) + e– O(g)
– – – –
(G) H (g) H(g) + e (H) O (g) – e O2–(g)
(I) Mg+(g) Mg2+ + e– (J) P(g) + e– P–(g)
27. How many elements from the following are not transition elements ?
Zr, Co, Cd, Hg, Au, Cu
28. The first four ionization energy values of an element are 120, 240, 520, and 6420 kcal. The
number of valence electrons in the element is :
29. How many unpaired electron(s) is/are present in tri-positive titanium ion ?
30. Find the number of metals from the following: As, Fe, Xe, Li, B, Cl, Ba, P, I, Si.

ANSWER KEY
1. (A) 2. (C) 3. (D) 4. (B) 5. (C) 6. (C)
7. (A) 8. (A) 9. (C) 10. (A) 11. (B) 12. (B)
13. (B) 14. (C) 15. (C) 16. (B) 17. (C) 18. (A)
19. (A) 20. (A) 21. 1 22. 1 23. 8 24. 0
25. 3 26. 3 27. 2 28. 3 29. 1 30. 3

4 INORGANIC CHEMISTRY

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