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    Speciality Ingredients For Coatings Water Based Paints: Ecolabel

    Uploaded by

    Dang Chi Cong

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Speciality Ingredients For Coatings Water Based Paints: Ecolabel

    Uploaded by

    Dang Chi Cong
    80 views45 pages

    Original Title

    doc_429_yannickory_pt

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    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    80 views45 pages

    Speciality Ingredients For Coatings Water Based Paints: Ecolabel

    Uploaded by

    Dang Chi Cong

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 45

    &

    Speciality Ingredients for Coatings


    for Ecolabel Water Based Paints

    Yannick Ory APT Seminar 4th April 2014


    Regional Account Manager
    Ashland Specialty Ingredients
    2

    Ashland Specialty Ingredients


    2011 +

    Ashland Speciality Ingredients

    Ashland Specialty Ingredients


    ASI Portfolio for Coatings
    1) Rheology Modifiers
    Natrosol™ Culminal ™ Combizell ™ Blanose ™
    Aquaflow™

    2) Foam Control Agents


    Drewplus™, Drew ™, Advantage™

    3) Neutralizing Agents
    pHLEX™

    4) Dispersants
    Jaypol™

    5) Wetting and Surface Agents


    Dextrol™, Strodex™ Drewslip™

    6) Biocides
    Nuosept™, Fungitrol™ + Wood Care
    4

    Ashland Specialty Ingredients


    1) Rheology Modifiers, Cellulosics
    Hydroxy Ethyl Cellulose HEC
    Méthyl Cellulose MC

    NATROSOL® CULMINAL® COMBIZELL ®


    Carboxy Méthyl Cellulose CMC Blanose®

    BLANOSE®
    5

    Ashland Specialty Ingredients


    Zwijndrecht
    A&D
    HEC production

    R&D
    For Paints Paints, E-Pol
    and Epol

    Helicopter
    Ashland Specialty Ingredients view of our Natrosol® plant in Holland
    Performance Comparison Cellulosics in
    Paint Applications

    Ashland Specialty Ingredients


    Effect of the selection of the
    Cellulosic Ether on the Paint behaviour
    1000
    Storage Transportation Processing
    Post application Application
    100
    Viscosity [Pa.s]

    10

    GR
    MBR
    0,1 HHR
    Sag Package, Brushing,
    Settling & Levelling Appearance& Feel Spraying & Rolling
    0,01
    0,001 0,01 0,1 1 10 100 1000 10000 100000
    Shear rate [s-1]
    Brookfield
    Stormer ICI
    8

    Ashland Specialty Ingredients


    Natrosol™ Average Brookfield viscosity
    mPa.s at 2%, 25 ° C

    Ashland Specialty Ingredients


    Why B ?
    To maintain the paint viscosity over time :

    Raw materials, water and production environment bring


    bring :
    Bacteria, Fungi, Yeasts

    Enzymes

    Cellulose Polymer degradation


    10

    Ashland Specialty Ingredients


    Idealized Structure of Conventional
    Natrosol™ :

    11

    Ashland Specialty Ingredients


    Idealized Structure of Natrosol™B
    = Enzyme Resistance :
    OH
    OH
    CH2
    CH2
    CH2
    CH2
    OH O
    O CH2 CH2
    CH2 CH2 CH2
    CH2 O O
    H O CH2 H OH CH2
    O O
    O OH H H O OH H H O
    O
    H H OH H H
    O
    OH H
    O H H H
    O
    CH2 H O CH2 H O
    O CH2 O CH2
    CH2 CH2 CH2 CH2
    CH2 OH CH2 OH
    O O
    CH2 CH2
    CH2 CH2
    O OH
    CH2
    CH2
    OH
    12

    Ashland Specialty Ingredients


    Natrosol® Biostable

    13

    Ashland Specialty Ingredients


    Natrosol® B

    Average Brookfield viscosity


    mPa.s at 2%, 25 °c

    14

    Ashland Specialty Ingredients


    15

    Ashland Specialty Ingredients


    How to bring Spatter Resistance &
    Contribute to the Leveling

    NATROSOL® PLUS 330 PA

    16

    Ashland Specialty Ingredients


    Natrosol® Plus 330 = HMHEC

    Oxy-ethylene

    Cellulose

    Alkyl Hydroxyethyl

    17

    Ashland Specialty Ingredients


    Thickening mechanism
    Natrosol Plus 330
    HMHEC
    Thickening mechanism

    Hydrohobe

    Latex
    particle

    Hydrogen bonds
    18

    Ashland Specialty Ingredients


    Latex type effects
    Latex Chemistry

    Vinyl VA- VAE Acrylic Alkyd Styrene


    Acrylic VeoVa Emulsion Acrylic

    Increasing Hydrophobicity

    19

    Ashland Specialty Ingredients


    Rheology Options for Paints & Coatings
    High performance HMHEC rheology additives

    HEC Natrosol® Plus 330 PA

    20

    Ashland Specialty Ingredients


    Spatter collected after
    application of a paint
    made with
    Natrosol® Plus 330 PA

    Spatter collected after


    application of a paint
    21
    made with
    Ashland Specialty Ingredients Natrosol® 250 H4BR
    Natrosol Plus 330
    – Outstanding spatter resistance

    – Improved leveling

    – Improved brushing viscosity

    A High Quality Cellulose Ether for your


    High Quality Paint
    22

    Ashland Specialty Ingredients


    1) Rheology Modifiers, Synthetics
    Aquaflow tool box

    23

    Ashland Specialty Ingredients


    24
    Kennedy, Texas Aquaflow plant
    Ashland Specialty Ingredients
    Structure of Aquaflow N-Series

    Hydrophilic

    Hydrophobic
    Hydrophobic

    = Alkyl Chain

    25

    Ashland Specialty Ingredients


    Associative Thickening of Aquaflow

    Paint

    Latex

    26

    Ashland Specialty Ingredients


    Latex type effects
    Latex Chemistry

    Vinyl VA- VAE Acrylic Alkyd Styrene


    Acrylic VeoVa Emulsion Acrylic

    Increasing Hydrophobicity

    27

    Ashland Specialty Ingredients


    Difference between Aquaflow and HEUR :
    pH stability

    Viscosity retention of 4 % solutions after 21 days at 25 C

    100
    viscosity retention %

    80
    60 HEUR
    40 Aquaflow

    20
    0
    12 11 10 9 8 7 6 5 4 3 2
    pH of solution
    28

    Ashland Specialty Ingredients


    Position of Aquaflow vs HEUR

    Performance
    •More predictable Viscosity Response
    •Less pH, Electrolyte Sensitive
    •Improved Color Acceptance
    •Improved Viscosity Change On Tinting
    Aquaflow
    HEUR

    Economic Advantage
    29

    Ashland Specialty Ingredients


    Xceptional
    Leveling &
    Sag-resistance
    Sag Resistance Leveling

    Viscosity Retention upon


    Tinting (VRT)

    Aquaflow Aquaflow Conventional


    XLS-500 XLS-525 NSAT’s
    2000-5000
    Low as is supplied viscosity 1200 mPa.s 1600 mPa.s
    mPa.s30
    Ashland Specialty Ingredients
    Balance sag resistance & leveling | VRT | TE | Low as-is viscosity

    Aquaflow XLS-series value : Sag Resistance

    ° LS-NSAT / Compet°
    Compet° ° HS-NSAT Aquaflow XLS-500/NHS-300
    *

    * HS-NSATs = high shear non ionic synthetic associative thickener


    31

    Ashland Specialty Ingredients


    Balance sag resistance & leveling | VRT | TE | Low as-is viscosity

    Aquaflow® XLS-series value : Leveling


    High gloss top coat based on alkyd emulsion PVC 18

    32

    Ashland Specialty Ingredients


    Balance sag resistance & leveling | VRT | TE | Low as-is viscosity

    Aquaflow XLS-series value : Viscosity


    Retention on Tinting (VRT)
    Example 1 : Viscosity Retention upon tinting in a Deep Tone base paint, PVC 43%,
    based on Styrene Acrylic binder Acronal S 559.
    Paint5 viscosity loss measured after 5 wt% tinting paste orange, red and blue added :
    Stormer viscosity loss after tinting (KU)

    0
    Aquaflow XLS-500 Aquaflow XLS-525 Compet°1 Compet°2 Compet°3

    -5

    -10

    -15

    -20

    -25

    33
    -30
    Ashland Specialty Ingredients
    Outstanding Combination

    Natrosol™ Plus 330 & Aquaflow™

    Spatter resistance Leveling, color acceptance

    34

    Ashland Specialty Ingredients


    2) Foam Control Agents

    Anti-foams - Defoamers - Air release agents

    Dissolution De-aerators

    DREWPLUS ®
    Foam Control Solutions
    35

    Ashland Specialty Ingredients


    36

    Ashland Specialty Ingredients


    37

    Ashland Specialty Ingredients


    38

    Ashland Specialty Ingredients


    3) Neutralizing Agents

    39

    Ashland Specialty Ingredients


    3) Dispersants

    40

    Ashland Specialty Ingredients


    5) Wetting & Surface Agents

    Drewslip 870 : for

    ¤ Anti blocking
    ¤ Anti tack
    ¤ Anti dirt pick up
    ¤ Soft touch

    41

    Ashland Specialty Ingredients


    To increase the
    Scrub resistance :
    Dextrol  OC -180

    42

    Ashland Specialty Ingredients


    Color Properties : Strodex  PK 90 to solve
    • syneresis Strodex  PK 90

    • flocculation
    • color stability

    Paint PVC 38, Styr Acryl Natrosol 250 HBR

    • Wetting of iron oxide pigments.


    • Tint strength and color development.
    • Rub up and color acceptance.
    • Color float resistance.
    43

    Ashland Specialty Ingredients


    To boost the gloss :
    Strodex PK 0-VOC

    44

    Ashland Specialty Ingredients


    To improve Surface
    Wetting, substrate
    Adhesion and solve
    Cissing :
    Dextrol OC -180

    45

    Ashland Specialty Ingredients

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