Chem Ep PDF
Chem Ep PDF
Chem Ep PDF
Page 1 of 13
Number
Chemistry 5070//2
Paper 2 Theory
Time: 2 hours
Instructions to Candidates
Write your name, centre number and candidate number in the spaces at the top of this page.
There are twelve (12) questions in this paper
Section A
Answer all questions.
Write your answers in the spaces provided on the question paper.
Section B
Write your answers in the separate answer sheets provided Candidate’s use Examiner’s use
and fasten. Section A
INFORMATION FOR CANDIDATES Section B 9
©MCM/EP/2020
This question paper consists of 13 printed pages.
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Answer all the questions in the spaces provided on the question paper.
…………………………………………………………………………………………
…………………………………………………………………………………………
…………………………………………………………………………………………
……………………………………………………………………………………….. [3]
(b) Important skills which a chemist needs to have include correct measurement of quantities
and choosing correct pieces of apparatus/equipment for carrying out some experimental
procedures. State the name of a piece of apparatus which can be used to:
…………………………………………………………………………………..
………………………………………………………………………………….
…………………………………………………………………………………. [3]
[Total 6]
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A2 The graph below shows a heating curve for pure substance. The temperature rises with
State at A: …………………………………………………………….
Movement at A: ……………………………………………………………….
………………………………………………………………
Movement at C: ……………………………………………………………….
……………………………………………………………….. [2]
(c) What is the melting point and boiling point of the substance?
(d) Describe what happens to the temperature while the substance is changing its physical
state.
………………………………………………………………………………………
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……………………………………………………………………………………. [1]
[Total 7]
A3 The diagram below shows the structures of atoms of two elements A and B.
(a) State the Group and Period number of each of the two elements A and B.
(b) If atoms of element A and element B combined to form a compound, what type of
bonding would be involved? Using electron-shell diagram draw the structure of the
compound formed between A and B.
Structure of compound:
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[3]
[Total 5]
A4 A sample of iron filling had partly rusted upon being left under damp conditions. 3.5g of
Iron filling were added to 50cm3 of aqueous copper (II) sulphate. All the copper in copper (II)
………………………………………………………………………………………………………
……………………………………………………………………………………………………… [1]
(b). If neither the iron nor the copper (II) sulphate was in excess, calculate
(i) the mass of iron which was present in the iron fillings sample.
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[3]
[2]
(iii) The concentration of the copper (II) sulphate solution in moles per dm3
[3]
[Total 9]
A5 Lithium, sodium, potassium and rubidium are members of Group I of the Periodic Table.
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………………………………………………………………………………………. [1]
………………………………………………………………………………………..
……………………………………………………………………………………….. [2]
(c) Lithium reacts with water to form lithium hydroxide and hydrogen gas. Write the
balanced chemical equation for this reaction.
…………………………………………………………………………………………..
………………………………………………………………………………………….. [2]
(d) How would be the speed of reaction of lithium with water compare with that of rubidium
with water?
…………………………………………………………………………………………….
……………………………………………………………………………………………... [1]
[Total 6]
A6 Hydrogen reacts with chlorine to make hydrogen chloride. The reaction is exothermic. The
reaction can be represented by the equation below.
…………………………………………………………………………………………
…………………………………………………………………………………………
…………………………………………………………………………………………
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(ii) Calculate the energy released when 2.5 g of hydrogen reacts completely with
chlorine gas.
[3]
(b) Explain why the reaction is exothermic, in terms of the energy changes that takes place
during bond breaking and bond making.
……………………………………………………………………………………………………..
……………………………………………………………………………………………………..
…………………………………………………………………………………………………….
……………………………………………………………………………………………………[3]
(c) Nitrogen reacts with oxygen to form nitrogen (II) oxide. The energy profile diagram for
the reaction is shown below.
………………………………………………………………………………………………
…………………………………………………………………………………………….
(ii) Label on the diagram the activation energy for the reaction. [2]
[Total 8]
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……………………………………………………………………………………. [1]
……………………………………………………………………………………… [1]
………………………………………………………………………………………. [1]
……………………………………………………………………………………… [1]
……………………………………………………………………………………… [1]
[Total 5]
(a) One source of nitrogen dioxide in the air is from the gases from car engines. Explain
how nitrogen dioxide is formed in a car and indicate how its emission can be limited.
…………………………………………………………………………………………………..
…………………………………………………………………………………………………..
…………………………………………………………………………………………………
……………………………………………………………………………………………… [2]
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i. …………………………………………………………………………………
[Total 4]
B9. (a) Sodium sulphate is a soluble salt that can be prepared from dilute sulphuriic acid.
i. Name the other chemical that can be reacted with dilute sulphuric acid to prepare
the salt. [1]
ii. Write a balanced chemical equation with state symbols for the reaction above. [2]
iii. Describe in detail how you would prepare pure crystals of sodium sulphate using
the named reactants. [4]
(b). The salt prepared is a normal salt.
B10 An excess of zinc was added to 10 cm3 of 0.5 mol/dm3 hydrochloric acid, using the
apparatus below
(a) Calculate the maximum volume of hydrogen which could be produced in the reaction at
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r.t.p. [3]
The graph shows how the volume of hydrogen changed during the reaction.
(b) (i) Describe how the rate of reaction of reaction changes as the reaction progresses
(c) The experiment was repeated using dilute sulphuric acid of the same concentration.
Write a balanced equation for the reaction between zinc and sulphuric acid.
Suggest how both the rate of reaction and total volume of hydrogen obtained would
differ from the reaction between zinc and hydrochloric acid.
[5]
[Total 10]
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B11 The diagram below shows apparatus used in the silver-plating of an iron article. During the
electroplating, a current of 5A was passed through the aqueous electrolyte for 8.0 minutes.
(b) State the names of electrode X electrolyte Y which must be used in order for successful
plating to occur. [2]
(c) Write equations for the reactions occurring at the electrodes. [1]
(d) What mass of silver is deposited on the iron article? [2]
(e) If the iron article was to be coated with copper instead silver, State the materials needed
to be used for electrode X and electrolyte Y. [1]
(f) State two applications of electrolysis. [2]
[Total 10]
B12 The table shows the first four members of a particular homologous series.
Ethanol C2H5OH 46
Propanol C3H7OH 60
Butanol C4H9OH ?
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(a) (i) Name the homologous to which these compounds belong. [1]
(ii) state the conditions necessary for the reactions in b(i) above. [1]
Calculate the maximum mass of ethanol that can be made from 72 tonnes of Glucose. [3]
[Total 10]
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