Adv Petrophysics Fall07 Chapter8
Adv Petrophysics Fall07 Chapter8
Adv Petrophysics Fall07 Chapter8
RELATIVE PERMEABILITY
ko A ⎛ ∂Po ⎞
qo = − ⎜ ∂x + ρo g sin α ⎟ (8.1)
μo ⎝ ⎠
k w A ⎛ ∂Pw ⎞
qw = − ⎜ + ρ w g sin α ⎟ (8.2)
μ w ⎝ ∂x ⎠
8-1
k g A ⎛ ∂Pg ⎞
qg = − ⎜ + ρ g g sin α ⎟ (8.3)
μ g ⎝ ∂x ⎠
where α is the angle of inclination with the horizontal. Eqs.(8.1) to (8.3) show
that using the concept of an effective permeability, Darcy’s Law is applied to
each phase as if the other phases did not exist. Capillary equilibrium between
the phases gives
Po − Pw = Pc / ow ( S w ) (8.4)
Pg − Po = Pc / go ( So ) (8.5)
Pc / ow + Pc / go = Pc / gw (8.6)
ko
kro = (8.7)
k
kw
krw = (8.8)
k
kg
krg = (8.9)
k
kkro A ⎛ ∂Po ⎞
qo = − ⎜ + ρ o g sin α ⎟ (8.10)
μo ⎝ ∂x ⎠
8-2
kkrw A ⎛ ∂Pw ⎞
qw = − ⎜ + ρ w g sin α ⎟ (8.11)
μ w ⎝ ∂x ⎠
kkrg A ⎛ ∂Pg ⎞
qg = − ⎜ + ρ g g sin α ⎟ (8.12)
μ g ⎝ ∂x ⎠
8-3
permeability to the wetting phase attains a maximum end point value
(kwr).
5. The relative permeability curves are not defined in the saturation ranges
given by (1 − S nwr ) < S w < 1 and 0 < S w < S wirr .
6. Two phase flow occurs over the saturation range S wirr < S w < (1 − S nwr ) .
8-4
• Natural water influx calculations in a water wet reservoir in which water
displaces oil and/or gas.
• Oil displaces gas, which occurs when oil is forced into a gas cap.
8-5
Figure 8.2. Typical drainage relative permeability curves.
8-6
the injection rate of each phase are measured. The relative permeabilities are
calculated with the integrated forms of Darcy's law for two phase flow as
shown later. The saturations are usually calculated by material balance.
At steady state, the continuity equations for the wetting and non-
wetting phases for horizontal flow are
∂vw
=0 (8.13)
∂x
∂vnw
=0 (8.14)
∂x
k w ∂Pw
vw = − = a constant (8.15)
μ w ∂x
knw ∂Pnw
vnw = − = a constant (8.16)
μnw ∂x
Pnw − Pw = Pc ( S w ) (8.17)
μ w vw L μ w qw L
kw = = (8.18)
ΔPw AΔPw
Since Pc ( S w ) is uniform, ΔPw and ΔPnw are equal and the pressure drop across
the core can be measured in either phase and used to calculate the effective
8-7
permeabilities with Eqs.(8.18) and (8.19). The steady state saturation
distribution in the core can be calculated with Eq.(7.83), which is reproduced
here for convenience:
⎛ fw ⎞
⎜ − 1⎟
dS w
= ⎝ Fw ⎠
(7.83)
dxD N k dJ
cap rnw
dS w
with a specified inlet boundary condition. Of course, to do so, krw , krnw and
Pc ( S w ) must be known.
Figure 8.3 shows an apparatus that can be used for the steady state
experiment. A typical sequence of steps for obtaining the imbibition relative
permeability curves might be as follows:
1. Install the clean, dry core sample in the Hassler apparatus as shown in
Figure 8.3. Evacuate the core and saturate with the wetting phase.
Determine the absolute permeability of the core by wetting phase flow.
2. Displace the wetting phase with the non-wetting phase until no more
wetting phase flows from the core. Calculate the irreducible wetting
phase saturation and the initial non-wetting phase saturation.
Measure the steady state pressure drop and the non-wetting phase
8-8
injection rate and calculate the relative permeability to the non-wetting
phase at the irreducible wetting phase saturation by use of Eq.(8.19) as
μnw qnw L
krnw = (8.20)
kAΔPnw
3. Inject a mixture of the wetting and non-wetting phases at rates qnw and
qw such that the ratio, qw/qnw, is very much less than 1 until steady
4. Measure the pressure drop and calculate the wetting phase saturation
by material balance. Calculate the relative permeabilities to the non-
wetting and wetting phases at the latest wetting phase saturation using
Eq.(8.20) and (8.18) as
μ w qw L
krw = (8.21)
kAΔPw
5. Increase the ratio qw/qnw and repeat steps 3 and 4 to calculate the
6. Finally, inject only the wetting phase until no more non-wetting phase
flows from the core. Calculate the residual non-wetting phase
saturation. Measure the steady state pressure drop and the wetting
phase injection rate and calculate the relative permeability to the
wetting phase at residual non-wetting phase saturation. This completes
the relative permeability measurements.
8-9
Figure 8.3. Hassler’s apparatus for relative permeability measurement (Osoba
et al., 1951).
8-10
The various steady state methods such as the Penn State method,
single core dynamic method, dispersed feed method, Hafford method and
Hassler method differ primarily in the techniques used to minimize or
eliminate capillary end effect (Richardson et al., 1952). When capillary end
effect has been eliminated, all the steady state methods give the same results
as shown in Figures 8.6 and 8.7.
Figure 8.4. Steady state oil and gas pressure profiles at a relatively low
injection rate (Richardson et al., 1952).
8-11
Figure 8.5. Steady state oil and gas pressure profiles at a relatively high
injection rate (Richardson et al., 1952).
8-12
Figure 8.6. Relative permeability curves from six steady state methods, short
core section (Richardson et al., 1952).
8-13
Figure 8.7. Relative permeability curves from six steady state methods, long
core section (Richardson et al., 1952).
The major problem with the steady state method for relative
permeability measurements is that it takes too long to complete. It is not
unusual for a steady state experiment to take several weeks to complete. An
alternative and much faster technique is the unsteady state method or the
dynamic displacement method based on immiscible displacement theory.
Because the calculation of relative permeabilities from unsteady state
experiment is based on the solution of two-phase immiscible displacement
equation, we must first solve the two-phase immiscible displacement problem
before we can discuss the unsteady state relative permeability measurements.
8-14
8.3 THEORY OF ONE DIMENSIONAL IMMISCIBLE
DISPLACEMENT IN A POROUS MEDIUM
8.3.1 Mathematical Model of Two-Phase Immiscible Displacement
Consider the displacement of a non-wetting phase by a wetting phase in
a linear inclined core as shown in Figure 8.8. Darcy’s Law applied to each
phase gives
kkrnw A ⎛ ∂Pnw ⎞
qnw = − ⎜ + ρ nw g sin α ⎟ (8.22)
μnw ⎝ ∂x ⎠
kkrw A ⎛ ∂Pw ⎞
qw = − ⎜ + ρ w g sin α ⎟ (8.23)
μ w ⎝ ∂x ⎠
Pnw − Pw = Pc ( S w ) (8.17)
q = qw + qnw (8.24)
The true fractional flows of the wetting and non-wetting phases are defined as
follows:
qw qw
fw = = (8.25)
q qw + qnw
qnw qnw
f nw = = = 1 − fw (8.26)
q qw + qnw
∂S w ∂qw
φA + =0 (8.27)
∂t ∂x
8-15
Figure 8.8. Displacement of a non-wetting phase by a wetting phase in an
inclined core.
S w + Snw = 1 (8.28)
8-16
Substituting Eqs.(8.17) and (8.24) into (8.29) gives upon rearrangement
kkrnw A ⎡ ∂Pc ⎤
1+ ⎢ − ( ρ w − ρ nw ) g sin α ⎥
qw q μnw ⎣ ∂x ⎦
= (8.30)
q k μ
1 + rnw w
krw μnw
1
Fw = (8.31)
k μ
1 + rnw w
krw μnw
Substituting Eqs.(8.30) and (8.31) into (8.25) gives the true fractional flow of
the wetting phase as
⎧ kk A ⎡ ∂P ⎤⎫
f w = Fw ⎨1 + rnw ⎢ c − ( ρ w − ρ nw ) g sin α ⎥ ⎬ (8.32)
⎩ q μ nw ⎣ ∂x ⎦⎭
x
xD = (8.33)
L
σ cos θ
Pc ( S w ) = J ( Sw , Γ ) (8.34)
k /φ
Substituting Eqs.(8.83) and (8.34) into (8.32) gives the true fractional flow of
the wetting phase as
⎡ ⎛ Aσ cos θ kφ ⎞ ∂J ⎛ kA ( ρ w − ρ nw ) g sin α ⎞ ⎤
f w = Fw ⎢1 + ⎜ ⎟ krnw − krnw ⎜ ⎟⎥ (8.35)
⎜ q μnw L ⎟ ∂xD q μnw
⎢⎣ ⎝ ⎠ ⎝ ⎠ ⎥⎦
8-17
⎡ ∂J ⎤
f w = Fw ⎢1 + N cap krnw − krnw N g ⎥ (8.36)
⎣ ∂xD ⎦
Aσ cos θ kφ
N cap = (7.61)
q μnw L
and N g is given by
kA ( ρ w − ρ nw ) g sin α
Ng = (8.37)
qμnw
capillary end effect. It represents the ratio of capillary to viscous forces in the
displacement. N g is a new dimensionless number, which represents the ratio
krw μnw
M ( Sw ) = (8.38)
krnw μ w
kwr μnw
ME = (8.39)
knwr μ w
where kwr and knwr are the end-point relative permeabilities for the wetting and
8-18
∂J
1 + N cap krnw − krnw N g
∂xD
fw = (8.40)
⎛ 1 ⎞
⎜1 + ⎟
⎝ M⎠
1
Fw = (8.41)
⎛ 1 ⎞
⎜1 + ⎟
⎝ M⎠
8-19
of the wetting phase (the injected fluid) by use of a polymer. This is the
basis for polymer flooding as an improved oil recovery technique.
There are additional facts about the immiscible displacement that are
not apparent from the fractional flow equation. The fractional flow equation
indicates that the displacement efficiency can be improved by injecting the
wetting phase at a high enough rate to minimize capillary smearing of the
displacement front. This is generally true for a favorable mobility ratio
displacement. If the mobility ratio is unfavorable, an increase in rate can
result in viscous instability which reduces the displacement efficiency. The
fractional flow equation suggests that the effect of gravity will be eliminated if
the porous medium is horizontal. This is misleading because, in practice, if
there is a density contrast between the fluids, the injection rate is sufficiently
low and the core has a vertical dimension (which it does), gravity segregation
will occur even in a horizontal medium. In this case, the one dimensional
displacement model is inadequate to describe the displacement. A
multidimensional model is needed to correctly describe the gravity-dominated
displacement. The only fail proof way to eliminate the effect of gravity is to
eliminate the density contrast between the fluids or perform the displacement
in outer space. One can create a gravity number for displacement in a
horizontal core by replacing sin α in Eq.(8.37) by the aspect ratio (d/L).
The partial differential equation for the wetting phase saturation can be
derived as follows. Let
Ψ ( S w ) = Fw − krnw N g (8.42)
dJ
Ω ( S w ) = krnw (8.43)
dS w
8-20
∂S w
f w ( S w ) = Ψ ( S w ) + N cap Ω ( S w ) (8.44)
∂xD
∂S w ∂f w
+ =0 (8.45)
∂t D ∂xD
where t D is given by
qt
tD = (7.63)
Aφ L
Substituting Eq.(8.44) into (8.45) gives the partial differential equation for the
wetting phase saturation as
∂S w d Ψ ∂S w ∂ ⎡ ∂S w ⎤
+ + N cap ⎢Ω ( S w ) ⎥=0 (8.46)
∂t D dS w ∂xD ∂xD ⎣ ∂xD ⎦
∂S w df w ∂S w
+ =0 (8.47)
∂t D dS w ∂xD
where the true fractional flow of the wetting phase for horizontal
displacement is given by
8-21
dJ ∂S w
1 + N cap krnw
dS w ∂xD
fw = (8.48)
⎛ 1 ⎞
⎜1 + ⎟
⎝ M⎠
∂S w
It should be observed that the true fractional flow function contains ,
∂xD
which is unknown. Buckley and Leverett (1941) obtained an approximate
solution to Eq.(8.47) by making a key simplifying assumption. They dropped
the capillary pressure term from Eq.(8.48) and as a result, they approximated
the fractional flow of the wetting phase as
f w Fw (8.49)
Substituting Eq.(8.49) into (8.47) gives the partial differential equation for the
wetting phase saturation as
∂S w dFw ∂S w
+ =0 (8.50)
∂t D dS w ∂xD
∂S w ⎛ dxD ⎞ ∂S w dS w
+⎜ ⎟ = (8.51)
∂t D ⎝ dt D ⎠ ∂xD dt D
8-22
Subtracting Eq.(8.50) from (8.51) gives
⎛ dxD dFw ⎞ ∂S w dS w
⎜ − ⎟ = (8.52)
⎝ dt D dS w ⎠ ∂x D dt D
dxD dFw
− =0 (8.53)
dt D dS w
dS w
=0 (8.54)
dt D
Eq.(8.53) gives the characteristic path for the hyperbolic partial differential
equation given by Eq(8.54). Eq.(8.54) shows that along the characteristic
path given by Eq.(8.53), the saturation is a constant.
dFw
xDSw ( tD ) − xDSw ( 0) = ( t D − t D 0 ) (8.55)
dS w
If there was no prior injection, t D 0 will be zero and all the saturations from Swi
to (1 - Snwr) will be located at the inlet end of the system, making xDSw ( 0) equal
dFw
xDSw ( tD ) = t D (8.56)
dS w
dFw
xD = t D (8.57)
dS w
8-23
where xD is the dimensionless distance traveled by a given saturation at time
Qi ( t ) dFw
x= (8.58)
φ A dS w
⎛ dF ⎞
xD = t D ⎜ w ⎟ (8.59)
⎝ dS w ⎠ Sw1
xD dFw df w
z= = = (8.60)
t D dS w dS w
xD
versus , all the saturation profiles will collapse into one curve. If the
tD
saturation profiles in an immiscible displacement are imaged say by CT or by
NMR, then Eq.(8.60) can be used to calculate the true fractional flow curve,
including the effect of capillarity, as
xD
f w ( Sw ) = ∫
Sw
dS w (8.61)
S wirr tD
Given the relative permeability curves and the viscosity ratio, the
approximate fractional flow function and its derivative can be computed and
8-24
plotted as shown in Figure 8.9. In this figure, the S-shaped curve ADBC is
the approximate fractional flow curve (Fw) obtained from the relative
permeability curves and the viscosity ratio. The curve AFE is the derivative of
⎛ dF ⎞
this function ⎜ w ⎟ . Using Eq.(8.59) and this derivative function, the distance
⎝ dS w ⎠
traveled by each wetting phase saturation between Swirr and (1-Snwr) at a
given time t D can be computed. Figure 8.10 shows the saturation profile that
capillary pressure gradient is high and should not have been neglected.
front has traveled a distance x f into the medium. A volumetric balance of the
Qi ( t ) = ∫ φ A ( S w − S wirr )dx
xf
(8.62)
0
Qi ( t ) = φ Ax f ( S wf − S wirr ) − Qi ∫
S wf dFw
dS w (8.63)
1− Snwr dS w
8-25
Figure 8.9. Approximate fractional flow function and its first derivative. Note
the tangent construction.
8-26
Fw ( S wf )
φ Ax f = Qi ( t ) (8.64)
S wf − S wirr
From the Buckley-Leverett frontal advance equation, Eq.(8.58), one can also
obtain
⎛ dFw ⎞
φ Ax f = Qi ( t ) ⎜ ⎟ (8.65)
⎝ dS w ⎠ S wf
⎛ dFw ⎞ Fw ( S wf )
⎜ ⎟ = (8.66)
⎝ dS w ⎠ Swf S wf − S wirr
The saturation distribution in Figure 8.10 will be single valued if all the
saturations between Swirr and the frontal saturation, Swf, are eliminated.
Eq.(8.66) shows that the frontal saturation (Swf) is the saturation at which the
straight line passing through the point Sw = Swirr and Fw = 0 is tangent to the
approximate fractional flow curve, Fw. This line is shown in Figure 8.9 as AB.
This tangent construction was first suggested by Welge (1952). The effect of
the tangent construction is to correct the approximate fractional flow curve Fw
for the capillary term that was neglected to obtain the true fractional flow
curve fw. Such a correction is needed at the front (low wetting phase
saturation) where the capillary pressure gradient is high and should not have
been neglected. With the tangent construction correction in place, the true
fractional flow curve, fw, is now given by the curve ABC (Fig. 8.9) thereby
eliminating the S-shaped lower portion of Fw, which led to the tripple-valued
saturation solution of Figure 8.10. With this correction, the derivative of the
⎛ df ⎞
true fractional flow curve ⎜ w ⎟ used in the solution is given by the curve
⎝ dS w ⎠
EFG (Fig. 8.9). After the tangent construction, the true fractional flow curve
and its derivative are given by
8-27
Figure 8.11. Similarity transformation for an immiscible displacement.
8-28
⎧⎛ S − S ⎞ ⎛ dFw ⎞
⎪⎜
⎪
w wirr
⎟ F ( S ) = ( S − S ) ⎜ ⎟ for S wirr ≤ S w ≤ S wf
f w ( S w ) = ⎨⎜⎝ S wf − S wirr ⎟⎠
w wf w wf
⎝ w ⎠ Swf
dS (8.67)
⎪
⎪⎩ Fw ( S w ) for S wf ≤ S w ≤ 1.0
and
⎧⎛ dFw ⎞
⎪⎜ ⎟ = a constant for S wirr ≤ S w ≤ S wf
df w ⎪⎝ w ⎠ Swf
dS
=⎨ (8.68)
dS w ⎪⎛ dF ⎞
⎪⎜ dS ⎟ for S wf ≤ S w ≤ 1.0
w
⎩⎝ w ⎠ Sw
We now show that the intersection of the tangent line with the line Fw =
1 (point J in Fig. 8.9) gives the constant average wetting phase saturation
behind the front before and at wetting phase breakthrough. The slope of the
tangent line can be written as
⎛ dFw ⎞ 1 − Fw ( S wf )
⎜ ⎟ = (8.69)
⎝ dS w ⎠ Swf S wav − S wf
1 − Fw ( S wf )
S wav = S wf + (8.70)
⎛ dFw ⎞
⎜ ⎟
⎝ dS w ⎠ Swf
Before breakthrough, the average wetting phase saturation behind the front is
given by
8-29
1− Snwr
S wav =
∫
0
φ AxdS w
(8.71)
φ Ax f
Substituting Eq.(8.58) into (8.71) and integrating gives the average wetting
phase saturation behind the front as
1 − Fw ( S wf )
S wav = S wf + (8.72)
⎛ dFw ⎞
⎜ ⎟
⎝ dS w ⎠ Swf
8-30
8.3.3 Waterflood Performance Calculations from Buckley–Leverett
Theory
We now apply Buckley-Leverett theory to calculate a waterflood
performance from beginning to end. It is assumed that the true fractional flow
curve and its derivative have been computed using the relative permeability
curves, the viscosity ratio and the Welge tangent construction. Therefore, the
equations in this section are written in terms of the true fractional flow curve.
The methodology presented also applies to the calculation of the performance
of a gas flood using gas-oil drainage relative permeability curves.
S wav − S wirr
R= (8.73)
1 − S wirr
where R is the oil recovery as a fraction of the initial oil in place, Swav is the
average water saturation in the porous medium at the time of interest and
Swirr is the initial water saturation in the porous medium before water
8-31
qBwt = Qi ( t ) = Qo ( t ) (8.74)
where q is the constant water injection rate, in surface units, Bw is the water
the cumulative oil produced at time t in reservoir units. The cumulative oil
produced at surface conditions is
qBwt Qi ( t ) Qo ( t )
Cumulative Oil Produced = = = (8.75)
Bo Bo Bo
where Bo is the current oil formation volume factor. The oil recovery as a
qBwt Qi ( t ) Wi
R= = = (8.76)
φ AL (1 − S wirr ) φ AL (1 − S wirr ) (1 − S wirr )
qBwt ⎛ df w ⎞ Qi ( t ) ⎛ df w ⎞
x= ⎜ ⎟ = ⎜ ⎟ (8.77)
φ A ⎝ dS w ⎠ S φ A ⎝ dS w ⎠ S
w w
qBwt ⎛ df w ⎞ Qi ( t ) ⎛ df w ⎞
xf = ⎜ ⎟ = ⎜ ⎟ (8.78)
φ A ⎝ dS w ⎠ S φ A ⎝ dS w ⎠ S
wf wf
8-32
qBwt ⎛ df w ⎞ Qi ( t ) ⎛ df w ⎞
L= ⎜ ⎟ = ⎜ ⎟ (8.79)
φ A ⎝ dS w ⎠ S φ A ⎝ dS w ⎠ S
wf wf
qBwt Qi ( t ) 1
Wi = = = (8.80)
φ AL φ AL ⎛ df w ⎞
⎜ ⎟
⎝ dS w ⎠ Swf
where Wi is the pore volume of water injected. The cumulative oil recovery at
Wi qBwt Qi ( t ) 1
R= = = = (8.81)
1 − S wi φ AL (1 − S wi ) φ AL (1 − S wi ) ⎛ df ⎞
(1 − S wi ) ⎜ w ⎟
⎝ dS w ⎠ S wf
φ AL
tbt = (8.82)
⎛ df ⎞
qBw ⎜ w ⎟
⎝ dS w ⎠ Swf
or in dimensionless form as
1
t Dbt = (8.83)
⎛ df w ⎞
⎜ ⎟
⎝ dS w ⎠ Swf
The average water saturation in the porous medium behind the displacement
front before and at water breakthrough is given by
1− Sor
S wav =
∫ 0
φ AxdS w
(8.71)
φ Ax f
8-33
Figure 8.13 shows a typical water saturation distribution at time t before
breakthrough. From Figure 8.13, we see that the integral (area under the
curve) in Eq.(8.71) can be split into two parts as follows:
1− Sor
φ AS wf x f + ∫ φ AxdS w
S wf
S wav = (8.84)
φ Ax f
1− Sor
Qi ( t ) ∫ dFw
S wf
S wav = S wf + (8.85)
φ Ax f
Qi ( t ) ⎡⎣ f w (1 − Sor ) − f w ( S wf ) ⎤⎦
S wav = S wf + (8.86)
φ Ax f
Qi ( t ) ⎡⎣1 − f w ( S wf ) ⎤⎦
S wav = S wf + (8.87)
φ Ax f
Substituting Eq.(8.78) into (8.87) gives the average water saturation behind
the front as
⎡1 − f w ( S wf ) ⎤
S wav = S wf + ⎣ ⎦ (8.72)
⎛ df w ⎞
⎜ ⎟
⎝ dS w ⎠ S wf
It should be observed in Figure 8.9 that the average water saturation behind
the front up until water breakthrough as given in Eq.(8.72) is the same as the
water saturation at which the tangent to the fractional flow curve intersects
the Fw = 1 axis. Thus, the average water saturation in the porous medium at
8-34
saturation can then be substituted into Eq.(8.73) to calculate the oil recovery
at water breakthrough. We can easily show that the result obtained by this
approach will be the same as that obtained by Eq.(8.81). Substituting
Eq.(8.72) into Eq.(8.73) gives
8-35
⎡1 − f w ( S wf ) ⎤
S wf + ⎣ ⎦ −S
⎛ df w ⎞
wirr
⎜ ⎟
⎝ dS w ⎠ S
R= wf
(8.88)
1 − S wirr
From the equation of the tangent line in Figure 8.9, we find that
⎛ df w ⎞ f w ( S wf )
⎜ ⎟ = (8.66)
⎝ dS w ⎠ Swf S wf − S wirr
Substituting Eq.(8.66) into (8.88) gives the oil recovery at water breakthrough
as
1
R= (8.89)
⎛ df ⎞
(1 − S wi ) ⎜ w ⎟
⎝ dS w ⎠ S wf
qBwt ⎛ df w ⎞ Qi ( t ) ⎛ df w ⎞
L= ⎜ ⎟ = ⎜ ⎟ (8.90)
φ A ⎝ dS w ⎠ S φ A ⎝ dS w ⎠ S
w2 w2
where Sw2 is the water saturation at the outlet end of the porous medium
which now lies between Swf and (1 – Sor). Rearrangement of Eq.(8.90) gives
qBwt Qi ( t ) 1
Wi = = = (8.91)
φ AL φ AL ⎛ df w ⎞
⎜ ⎟
⎝ dS w ⎠ Sw 2
8-36
where Wi is the pore volumes of water injected since the initiation of water
Qi ( t ) − ∫ φ A ( S w − S wirr )dx = Qw ( t )
L
(8.92)
0
{
Qi ( t ) − ⎡⎣φ A ( S w − S wirr ) x ⎤⎦ 0 − ∫
L
Sw 2
1− Sor
φ AxdS w = Qw ( t ) } (8.93)
{
Qi ( t ) − φ AL ( S w 2 − S wirr ) − ∫
1− Sor
Sw 2 }
φ AxdS w = Qw ( t ) (8.94)
{
Qi ( t ) − φ AL ( S w 2 − S wirr ) − Qi ( t ) ∫
1− Sor
Sw 2 }
df w = Qw ( t ) (8.95)
{ }
Qi ( t ) − φ AL ( S w 2 − S wirr ) − Qi ( t ) ⎡⎣ f w (1 − Sor ) − f w ( S w 2 ) ⎤⎦ = Qw ( t ) (8.96)
or
{
Qi ( t ) − φ AL ( S w 2 − S wirr ) − Qi ( t ) ⎡⎣1 − f w ( S w 2 ) ⎤⎦ = Qw ( t ) } (8.97)
Qi ( t ) − Qw ( t ) Qi ( t )
S w 2 = S wirr + − ⎡1 − f w ( S w 2 ) ⎤⎦ (8.98)
φ AL φ AL ⎣
8-37
S w 2 = S wirr + N pD − Wi ⎡⎣1 − f w ( S w 2 ) ⎤⎦ (8.99)
N pD = S w 2 − S wi + Wi ⎡⎣1 − f w ( S w 2 ) ⎤⎦ (8.100)
where NpD is the oil recovery as a fraction of the total pore volume. We observe
that the sum of the first two terms on the right hand side of Eq.(8.99) is the
average water saturation in the porous medium after water breakthrough.
Thus, Eq.(8.99) can be rewritten as
Substituting Eq.(8.91) into (8.101) and rearranging gives the average water
saturation in the porous medium after water breakthrough as
⎡1 − f w ( S w 2 ) ⎤⎦
S wav = S w 2 + ⎣ (8.102)
⎛ df w ⎞
⎜ ⎟
⎝ dS w ⎠ S w2
fractional flow curve at the outlet water saturation intersects the Fw = 1 axis.
1− Sor
φ AS w 2 L + ∫ φ AxdS w
S wav = (8.103)
Sw 2
φ AL
8-38
1− Sor
Qi ( t ) ∫ df w
S wav = S w 2 + (8.104)
Sw 2
φ AL
Qi ( t ) ⎡⎣ f w (1 − Sor ) − f w ( S w 2 ) ⎤⎦
S wav = S w 2 + (8.105)
φ AL
8-39
Figure 8.15. Typical water saturation profile at time t after water
breakthrough.
Qi ( t ) ⎡⎣1 − f w ( S w 2 ) ⎤⎦
S wav = S w 2 + (8.106)
φ AL
Substituting Eq.(8.90) into (8.106) gives the average water saturation after
water breakthrough as
⎡1 − Fw ( S w 2 ) ⎤⎦
S wav = S w 2 + ⎣ (8.107)
⎛ dFw ⎞
⎜ ⎟
⎝ dS w ⎠ S w2
8-40
which is identical to Eq.(8.102).
Water Production
There is no water production before water breakthrough. After water
breakthrough, the water oil ratio is given by
⎛ fw ⎞
⎜ ⎟
qw ⎝ Bw ⎠ Bo ⎛ Fw ⎞
WOR = = = ⎜ ⎟ (8.108)
qo ⎛ f o ⎞ Bw ⎝ 1 − Fw ⎠
⎜ ⎟
⎝ Bo ⎠
The pore volumes of water produced is given by material balance on the water
as
Substituting Eq.(8.91) into (8.110) gives the pore volumes of water produced
as
1
Wp = − ( S wav − S wi ) (8.111)
⎛ df w ⎞
⎜ ⎟
⎝ dS w ⎠ Sw 2
Example 8.1
A waterflood is to be performed in a linear reservoir. The relative permeability
curves for the reservoir are adequately described by the following analytical
models:
8-41
krnw = knwr (1 − Se )
2
(8.113)
where Se is defined as
S w − S wirr
Se = (8.114)
1 − S wirr − Snwr
S wirr = 0.20
S nwr = 0.30
knwr = 0.95
k wr = 0.35
μnw = μo = 10 cp
μ w = 1 cp
Bo = 1.20 RB/STB
Bw = 1.0 RB/STB
breakthrough ( Swav ) and the true fractional flow curve ( fw ) and its
⎛ df ⎞
derivative ⎜ w ⎟ .
⎝ dS w ⎠
8-42
4. Plot the graphs of the true fractional flow curve and its derivative.
9. Calculate and plot the graph of oil recovery versus pore volume of water
injected before and after water breakthrough.
10. Calculate and plot the graph of water oil ratio versus oil recovery.
2. Figure 8.17 shows the approximate fractional flow curve calculated with
Eq.(8.41) and its derivative calculated by differentiating Fw with respect
to Sw analytically.
tD tD tD
0.20 0.30 1.00
Sw krw krnw Fw dFw fw df w xD xD xD Wi R WOR
dS w dS w
0.200 0.00000 0.950 0.00000 0.000 0.000 2.775 0.555 0.833 2.775 0.000 0.000 0.000
0.210 0.00000 0.912 0.00003 0.009 0.028 2.775 0.555 0.833 2.775 0.008 0.023 0.000
0.220 0.00002 0.876 0.00026 0.039 0.056 2.775 0.555 0.833 2.775 0.016 0.045 0.000
0.230 0.00008 0.839 0.00090 0.094 0.083 2.775 0.555 0.833 2.775 0.025 0.068 0.000
0.240 0.00018 0.804 0.00222 0.176 0.111 2.775 0.555 0.833 2.775 0.033 0.091 0.000
8-43
0.250 0.00035 0.770 0.00453 0.290 0.139 2.775 0.555 0.833 2.775 0.041 0.113 0.000
0.260 0.00060 0.736 0.00815 0.441 0.167 2.775 0.555 0.833 2.775 0.049 0.136 0.000
0.270 0.00096 0.703 0.01348 0.632 0.194 2.775 0.555 0.833 2.775 0.057 0.158 0.000
0.280 0.00143 0.670 0.02094 0.866 0.222 2.775 0.555 0.833 2.775 0.066 0.180 0.000
0.290 0.00204 0.639 0.03097 1.147 0.250 2.775 0.555 0.833 2.775 0.074 0.202 0.000
0.300 0.00280 0.608 0.04403 1.473 0.278 2.775 0.555 0.833 2.775 0.082 0.223 0.000
0.310 0.00373 0.578 0.06057 1.844 0.305 2.775 0.555 0.833 2.775 0.090 0.243 0.000
0.320 0.00484 0.549 0.08103 2.254 0.333 2.775 0.555 0.833 2.775 0.098 0.263 0.000
0.330 0.00615 0.520 0.10575 2.693 0.361 2.775 0.555 0.833 2.775 0.106 0.281 0.000
0.340 0.00768 0.492 0.13496 3.150 0.389 2.775 0.555 0.833 2.775 0.115 0.299 0.000
0.350 0.00945 0.466 0.16875 3.607 0.416 2.775 0.555 0.833 2.775 0.123 0.315 0.000
0.360 0.01147 0.439 0.20703 4.044 0.444 2.775 0.555 0.833 2.775 0.131 0.330 0.000
0.370 0.01376 0.414 0.24949 4.439 0.472 2.775 0.555 0.833 2.775 0.139 0.343 0.000
0.380 0.01633 0.389 0.29560 4.772 0.500 2.775 0.555 0.833 2.775 0.147 0.355 0.000
0.390 0.01921 0.365 0.34465 5.024 0.527 2.775 0.555 0.833 2.775 0.156 0.365 0.000
0.400 0.02240 0.342 0.39576 5.181 0.555 2.775 0.555 0.833 2.775 0.164 0.374 0.000
0.410 0.02593 0.320 0.44794 5.238 0.583 2.775 0.555 0.833 2.775 0.172 0.381 0.000
0.420 0.02981 0.298 0.50019 5.195 0.611 2.775 0.555 0.833 2.775 0.180 0.388 0.000
0.430 0.03407 0.277 0.55153 5.058 0.638 2.775 0.555 0.833 2.775 0.188 0.393 0.000
0.440 0.03871 0.257 0.60109 4.842 0.666 2.775 0.555 0.833 2.775 0.197 0.398 0.000
0.450 0.04375 0.238 0.64815 4.561 0.694 2.775 0.555 0.833 2.775 0.205 0.403 0.000
0.460 0.04921 0.219 0.69216 4.234 0.722 2.775 0.555 0.833 2.775 0.213 0.407 0.000
0.470 0.05511 0.201 0.73274 3.879 0.749 2.775 0.555 0.833 2.775 0.221 0.411 0.000
0.480 0.06147 0.184 0.76969 3.511 0.777 2.775 0.555 0.833 2.775 0.229 0.416 0.000
0.490 0.06829 0.168 0.80296 3.144 0.805 2.775 0.555 0.833 2.775 0.237 0.421 0.000
0.491 0.06900 0.166 0.80608 3.107 0.808 2.775 0.555 0.833 2.775 0.246 0.423 0.000
0.492 0.06971 0.164 0.80917 3.071 0.810 2.775 0.555 0.833 2.775 0.254 0.426 0.000
0.493 0.07043 0.163 0.81222 3.035 0.813 2.775 0.555 0.833 2.775 0.262 0.428 0.000
0.494 0.07115 0.161 0.81524 2.999 0.816 2.775 0.555 0.833 2.775 0.270 0.430 0.000
0.495 0.07188 0.160 0.81822 2.964 0.819 2.775 0.555 0.833 2.775 0.278 0.432 0.000
0.496 0.07262 0.158 0.82117 2.928 0.822 2.775 0.555 0.833 2.775 0.287 0.434 0.000
0.497 0.07335 0.157 0.82408 2.893 0.824 2.775 0.555 0.833 2.775 0.295 0.436 0.000
0.498 0.07410 0.155 0.82695 2.857 0.827 2.775 0.555 0.833 2.775 0.303 0.438 0.000
0.499 0.07485 0.154 0.82979 2.822 0.830 2.775 0.555 0.833 2.775 0.311 0.440 0.000
0.500 0.07560 0.152 0.83260 2.788 0.833 2.775 0.555 0.833 2.775 0.319 0.442 0.000
8-44
0.500 0.07568 0.152 0.83288 2.784 0.833 2.775 0.555 0.833 2.775 0.328 0.444 0.000
0.500 0.07575 0.152 0.83316 2.781 0.833 2.775 0.555 0.833 2.775 0.336 0.445 0.000
0.500 0.07583 0.152 0.83343 2.777 0.833 2.775 0.555 0.833 2.775 0.344 0.447 0.000
0.500 0.07583 0.152 0.83343 2.777 0.833 2.775 0.555 0.833 2.775 0.352 0.449 0.000
0.500 0.07586 0.151 0.83357 2.775 0.834 2.775 0.555 0.833 2.775 0.360 0.450 6.010
0.501 0.07636 0.150 0.83537 2.753 0.835 2.753 0.551 0.826 2.753 0.363 0.451 6.089
0.502 0.07712 0.149 0.83810 2.718 0.838 2.718 0.544 0.816 2.718 0.368 0.452 6.212
0.503 0.07789 0.147 0.84081 2.684 0.841 2.684 0.537 0.805 2.684 0.373 0.453 6.338
0.504 0.07866 0.146 0.84347 2.650 0.843 2.650 0.530 0.795 2.650 0.377 0.454 6.466
0.505 0.07944 0.144 0.84611 2.616 0.846 2.616 0.523 0.785 2.616 0.382 0.455 6.598
0.506 0.08023 0.143 0.84871 2.583 0.849 2.583 0.517 0.775 2.583 0.387 0.456 6.732
0.507 0.08102 0.142 0.85127 2.549 0.851 2.549 0.510 0.765 2.549 0.392 0.457 6.868
0.508 0.08181 0.140 0.85380 2.516 0.854 2.516 0.503 0.755 2.516 0.397 0.458 7.008
0.509 0.08261 0.139 0.85630 2.483 0.856 2.483 0.497 0.745 2.483 0.403 0.459 7.151
0.510 0.08341 0.137 0.85877 2.450 0.859 2.450 0.490 0.735 2.450 0.408 0.460 7.297
0.520 0.09175 0.123 0.88169 2.137 0.882 2.137 0.427 0.641 2.137 0.468 0.469 8.943
0.530 0.10062 0.110 0.90160 1.850 0.902 1.850 0.370 0.555 1.850 0.540 0.479 10.995
0.540 0.11005 0.097 0.91878 1.591 0.919 1.591 0.318 0.477 1.591 0.628 0.489 13.575
0.550 0.12005 0.086 0.93351 1.360 0.934 1.360 0.272 0.408 1.360 0.736 0.499 16.849
0.560 0.13064 0.074 0.94606 1.154 0.946 1.154 0.231 0.346 1.154 0.866 0.508 21.048
0.570 0.14183 0.064 0.95668 0.974 0.957 0.974 0.195 0.292 0.974 1.027 0.518 26.502
0.580 0.15364 0.055 0.96561 0.816 0.966 0.816 0.163 0.245 0.816 1.226 0.528 33.693
0.590 0.16609 0.046 0.97306 0.678 0.973 0.678 0.136 0.203 0.678 1.474 0.537 43.348
0.600 0.17920 0.038 0.97923 0.559 0.979 0.559 0.112 0.168 0.559 1.788 0.546 56.589
0.610 0.19298 0.031 0.98430 0.456 0.984 0.456 0.091 0.137 0.456 2.191 0.555 75.235
0.620 0.20745 0.024 0.98841 0.368 0.988 0.368 0.074 0.110 0.368 2.716 0.564 102.358
0.630 0.22262 0.019 0.99171 0.292 0.992 0.292 0.058 0.088 0.292 3.420 0.573 143.471
0.640 0.23852 0.014 0.99430 0.228 0.994 0.228 0.046 0.068 0.228 4.392 0.581 209.224
0.650 0.25515 0.009 0.99629 0.172 0.996 0.172 0.034 0.052 0.172 5.798 0.589 322.295
0.660 0.27254 0.006 0.99777 0.126 0.998 0.126 0.025 0.038 0.126 7.966 0.597 537.909
0.670 0.29070 0.003 0.99882 0.086 0.999 0.086 0.017 0.026 0.086 11.663 0.605 1020.015
0.680 0.30966 0.002 0.99951 0.052 1.000 0.052 0.010 0.016 0.052 19.193 0.612 2444.665
0.690 0.32942 0.000 0.99988 0.024 1.000 0.024 0.005 0.007 0.024 42.067 0.619 10402.648
0.700 0.35000 0.000 1.00000 0.000 1.000 0.000 0.000 0.000 0.000
8-45
Figure 8.16. Relative permeability curves for Example 8.1.
8-46
Figure 8.17. Approximate fractional flow curve and its derivative for Example
8.1.
S wf = 0.500035
⎛ df w ⎞
⎜ ⎟ = 2.775
⎝ dS w ⎠ Swf
S wav = 0.5603
4. The true fractional flow curve and its derivative obtained from the
tangent construction are shown in Figure 8.18.
8-47
Figure 8.18. True fractional flow curve and its derivative for Example 8.1.
8-48
Figure 8.19. Water saturation profiles for Example 8.1.
1 1
t Dbt = = = 0.460 pore volume injected.
⎛ df w ⎞ 2.775
⎜ ⎟
⎝ dS w ⎠ Swf
1 1
Rbt = = = 0.450
⎛ df w ⎞ (1 − 0.20 )( 2.775 )
(1 − S wirr ) ⎜ ⎟
⎝ dS w ⎠ Swf
8-49
breakthrough, the oil recovery is calculated with Eq.(8.100) as
N pD
R= .
1 − S wirr
10. The producing water oil ratio is zero before water breakthrough. After
water breakthrough, the producing water oil water ratio is calculated
with Eq.(8.108). After breakthrough, the producing water oil ratio
increases rapidly as shown in Figure 8.21.
8-50
Figure 8.21. Producing water oil ratio for Example 8.1.
8-51
By measuring the produced fractions of the wetting and non-wetting
phases at the outlet end of the core and the pressure drop across the core
versus time, the relative permeability curves can be calculated from the
production and pressure data using the theory of immiscible displacement in
porous media. This method is much faster than the steady state method,
usually requiring a few hours to complete compared to several weeks for the
steady state method. If adequate precautions are taken, the dynamic
displacement method will give relative permeability curves that are
comparable to those obtained by the steady state method.
Figure 8.22 shows the experimental setup and the measured data.
Because the point of observation is the outlet end of the core, it is necessary
that capillary end effect be minimized otherwise the calculated relative
permeability-saturation relationship will be wrong. It should be noted that
relative permeability curves can only be obtained over the saturation range Swf
to 1-Snwr. Therefore, it is necessary to choose the fluid viscosities that will give
the widest possible saturation window. This is obtained by using performing
and adverse mobility ratio displacement. A favorable mobility ratio
displacement will be unsuitable because for such a displacement, Swf is equal
to (1-Snwr) and there is no saturation window for calculating the relative
permeability curves. The relative permeability to the wetting phase below Swf
can only be obtained by extrapolating the data above Swf.
1
f nw 2 = (8.115)
k μ
1 + rw nw
krnw μ w
8-52
Figure 8.22. Unsteady state method for determining two-phase relative
permeability curves; (a) coreflood; (b) measured data.
It should be noted that for saturations above Swf, Eq.(8.115) gives the true
fractional flow of the non-wetting phase because above Swf, the true fractional
flow and the approximate fractional curves are equal. Eq.(8.115) can be
rearranged to calculate the wetting-non-wetting phase relative permeability
ratio as
krw μ ⎛ 1 ⎞
= w ⎜ − 1⎟ (8.116)
krnw μ nw ⎝ f nw 2 ⎠
The fractional flow of the non-wetting phase at the outlet end of the core is
also given by
8-53
qnw dQnw ( t ) dN pD
f nw 2 = = = (8.117)
q dQi ( t ) dWi
where Qnw(t) and Qi(t) are the cumulative non-wetting phase produced and
the cumulative wetting phase injected and N pD and Wi are their dimensionless
S w 2 = S wirr + N pD − Wi f nw 2 (8.118)
krw
Using Eqs.(8.116) and (8.118), versus S w 2 can be computed.
krnw
8-54
L ∂P
ΔP = − ∫ dx (8.119)
0 ∂x
kkrnw A ∂P
qnw = − (8.120)
μnw ∂x
∂P ⎛ q μnw ⎞
= −⎜ ⎟ f nw (8.121)
∂x ⎝ kkrnw A ⎠
⎛ qμ ⎞ L f
ΔP = ⎜ nw ⎟ ∫ nw dx (8.122)
⎝ kA ⎠ 0 krnw
Qi ( t ) ⎛ df w ⎞
L= ⎜ ⎟ (8.90)
φ A ⎝ dS w ⎠ S
w2
x f'
= w' (8.123)
L f w2
where f w' and f w' 2 are the derivatives of the fractional flow functions at any
L
dx = '
df w' (8.124)
f w2
8-55
Substituting Eq.(8.124) into (8.122) and rearranging gives
Let
⎛ q ⎞ kA
⎜ ⎟ = = a constant (8.126)
⎝ ΔP ⎠ s μ nw L
⎛ q ⎞ '
⎜ ⎟ f w2
f w' 2 f nw ⎝ ΔP ⎠ s
∫ df w = (8.127)
'
0 krnw ⎛ q ⎞
⎜ ⎟
⎝ ΔP ⎠
⎛ q ⎞
⎜ ⎟
ΔP ⎠
Ir = ⎝ (8.128)
⎛ q ⎞
⎜ ⎟
⎝ ΔP ⎠ s
f nw 2 d ⎛ f' ⎞
= ' ⎜ w2 ⎟ (8.130)
krnw df w 2 ⎝ I r ⎠
f nw 2 d ⎛ 1 ⎞
= ⎜ ⎟ (8.131)
krnw ⎛ 1 ⎞ ⎝ Wi I r ⎠
d⎜ ⎟
⎝ Wi ⎠
8-56
Eq.(8.131) can be used to calculate the relative permeability of the non-
wetting phase as
f nw 2
krnw = (8.132)
d ⎛ 1 ⎞
⎜ ⎟
⎛ 1 ⎞ WI
d⎜ ⎟⎝ i r ⎠
⎝ Wi ⎠
μw ⎛ 1 ⎞
krw = ⎜ − 1⎟ krnw (8.133)
μnw ⎝ f nw 2 ⎠
The advantage of the unsteady method over the steady state method of
relative permeability measurement is that it is considerably faster. Because
the method is based on the Buckley-Leverett displacement model, the
unsteady state method can only be used to calculate relative permeability
curves between Swf and the wetting phase saturation at the residual
the case of a favorable mobility ratio displacement, then much of the relative
permeability curves cannot be obtained because one is limited to a very small
saturation observation window. To solve this problem, unfavorable mobility
ratio displacements are typically used to determine relative permeability
curves by the unsteady state method. Further, in order to minimize capillary
end effect, high displacement rates are also typically used. The combination
of high rate and adverse mobility ratio can lead to viscous instability that will
make the displacement performance to be rate sensitive. If this happens, the
relative permeability curves obtained by the unsteady state method will be
rate sensitive and can be quite different from the relative permeability curves
of the same porous medium obtained by the steady state method (Peters and
Khataniar, 1987).
8-57
Eqs.(8.117) and (8.132) call for differentiating the measured
experimental data. The challenge in calculating the relative permeability
curves from these equations is to ensure that the curves are smooth. Any type
of finite difference approximation of the derivatives will result in numerical
noise leading to noisy relative permeability curves. The best way to process
the experimental data is by fitting well behaved functions to the experimental
data and then differentiating the functions. Peters and Khataniar (1987) have
suggested the following curve fits, which they have shown to work well.
N pD = A1 + A2 ( ln Wi ) + A3 ( ln Wi )
2
(8.134)
2
⎛ 1 ⎞ ⎛ 1 ⎞ ⎡ ⎛ 1 ⎞⎤
ln ⎜ ⎟ = B1 + B2 ln ⎜ ⎟ + B3 ⎢ln ⎜ ⎟ ⎥ (8.135)
⎝ Wi I r ⎠ ⎝ Wi ⎠ ⎣ ⎝ Wi ⎠ ⎦
Example 8.2
Table 8.2 gives the experimental data for an unsteady state relative
permeability measurement for a sandpack. In the experiment, water was used
to displace a viscous oil at a constant injection rate. The pore volume of water
injected (Wi), the cumulative oil produced (Qo) and the pressure drop across
the sandpack (ΔP) were measured as functions of time.
Wi Qo ΔP
PV %IOIP psi
0.339 38.28 9.02
0.351 38.95 8.30
0.395 40.10 6.91
0.439 40.91 6.07
0.502 41.92 5.42
0.587 42.95 4.87
8-58
0.670 43.77 4.55
0.840 45.11 4.00
1.137 46.55 3.32
1.604 47.96 2.78
2.029 48.96 2.52
2.624 50.08 2.42
3.225 50.78 2.30
4.346 51.78 2.13
5.719 52.67 1.99
7.092 53.23 1.90
8.464 53.67 1.83
10.516 54.16 1.79
11.203 54.34 1.75
12.578 54.60 1.74
13.271 54.71 1.70
14.644 54.82 1.70
16.016 54.90 1.70
8-59
Effective permeability to oil at irreducible water saturation = 3.16
Darcies
Oil recovery at water breakthrough = 38.28 % IOIP
Final oil recovery at termination of experiment = 54.9 % IOIP
5. Plot the graph of the true fractional flow curve measured in the
experiment.
2. Figures 8.24 and 8.25 show the curve fits of N pD versus ln Wi and
⎛ 1 ⎞ ⎛ 1 ⎞
ln ⎜ ⎟ versus ln ⎜ ⎟ . The curve fit equations are
⎝ Wi I r ⎠ ⎝ Wi ⎠
2
⎛ 1 ⎞ ⎛ 1 ⎞ ⎡ ⎛ 1 ⎞⎤
ln ⎜ ⎟ = −2.3600 + 1.5798ln ⎜ ⎟ + 0.1130 ⎢ln ⎜ ⎟ ⎥
⎝ Wi I r ⎠ ⎝ Wi ⎠ ⎣ ⎝ Wi ⎠ ⎦
8-60
dN pD 0.0474 − ( 2 )( 0.0066 ) ln Wi
f nw 2 = =
dWi Wi
⎛ 1 ⎞ ⎡ ⎛ 1 ⎞⎤ ⎛
d⎜ ⎟ ⎢ ( 2 )( 0.1130 ) ln ⎜ 2⎞
⎟ ⎥ ⎜⎜ −2.3600+1.5798ln ⎛⎜ W1 ⎞⎟ + 0.1130 ⎡⎢ln ⎛⎜ W1 ⎞⎟⎤⎥ ⎟⎟
= ⎝ i r ⎠=⎢ ⎝ Wi ⎠ ⎥ e⎝
f nw 2 WI 1.5798 ⎝ i⎠ ⎢⎣ ⎝ i ⎠ ⎥⎦
+ ⎠
krnw ⎛ 1 ⎞ ⎢⎛ 1 ⎞ ⎛ 1 ⎞ ⎥
d⎜ ⎟ ⎢ ⎜ ⎟ ⎜ ⎟ ⎥
⎝ Wi ⎠ ⎢⎣ ⎝ Wi ⎠ ⎝ Wi ⎠ ⎦⎥
Wi NpD ΔP
PV PV psi ln(Wi) ⎛ 1⎞ fnw2 Sw2 Ir 1 ⎛ 1 ⎞ f nw 2 krnw krw
ln ⎜ ⎟ ln ⎜ ⎟
⎝ Wi ⎠ Wi I r ⎝ Wi I r ⎠ k rnw
0.339 0.337 9.02 -1.082 1.082 0.182 0.395 4.335 0.680 -0.385 0.368 0.494 0.021
0.351 0.343 8.30 -1.047 1.047 0.174 0.401 4.711 0.605 -0.503 0.356 0.490 0.022
0.395 0.353 6.91 -0.929 0.929 0.151 0.413 5.659 0.447 -0.804 0.319 0.473 0.025
0.439 0.360 6.07 -0.823 0.823 0.133 0.421 6.442 0.354 -1.040 0.290 0.457 0.028
0.502 0.369 5.42 -0.689 0.689 0.113 0.432 7.214 0.276 -1.287 0.258 0.436 0.032
0.587 0.378 4.87 -0.533 0.533 0.093 0.443 8.029 0.212 -1.550 0.226 0.411 0.037
0.67 0.386 4.55 -0.400 0.400 0.079 0.452 8.594 0.174 -1.751 0.203 0.388 0.042
0.84 0.397 4.00 -0.174 0.174 0.059 0.467 9.775 0.122 -2.106 0.170 0.349 0.052
1.137 0.410 3.32 0.128 -0.128 0.040 0.483 11.778 0.075 -2.595 0.136 0.295 0.066
1.604 0.423 2.78 0.473 -0.473 0.026 0.500 14.065 0.044 -3.116 0.108 0.237 0.084
2.029 0.431 2.52 0.708 -0.708 0.019 0.512 15.517 0.032 -3.449 0.094 0.199 0.097
2.624 0.441 2.42 0.965 -0.965 0.013 0.526 16.158 0.024 -3.747 0.082 0.162 0.113
3.225 0.447 2.30 1.171 -1.171 0.010 0.534 17.001 0.018 -4.004 0.074 0.135 0.125
4.346 0.456 2.13 1.469 -1.469 0.006 0.547 18.358 0.013 -4.379 0.064 0.100 0.144
5.719 0.464 1.99 1.744 -1.744 0.004 0.559 19.649 0.009 -4.722 0.057 0.074 0.162
7.092 0.469 1.90 1.959 -1.959 0.003 0.566 20.580 0.007 -4.983 0.053 0.057 0.175
8.464 0.473 1.83 2.136 -2.136 0.002 0.573 21.367 0.006 -5.198 0.050 0.045 0.185
10.516 0.477 1.79 2.353 -2.353 0.002 0.580 21.844 0.004 -5.437 0.047 0.033 0.197
11.203 0.479 1.75 2.416 -2.416 0.001 0.582 22.344 0.004 -5.523 0.047 0.030 0.200
12.578 0.481 1.74 2.532 -2.532 0.001 0.586 22.472 0.004 -5.644 0.045 0.025 0.206
8-61
13.271 0.482 1.70 2.586 -2.586 0.001 0.588 23.001 0.003 -5.721 0.045 0.022 0.208
14.644 0.483 1.70 2.684 -2.684 0.001 0.590 23.001 0.003 -5.820 0.044 0.019 0.213
16.016 0.484 1.70 2.774 -2.774 0.001 0.592 23.001 0.003 -5.909 0.043 0.016 0.217
Figure 8.23. Raw experimental data for the unsteady state relative
permeability measurements of Example 8.2.
8-62
Figure 8.24. Curve fit of N pD versus ln Wi for Example 8.2.
⎛ 1 ⎞ ⎛ 1 ⎞
Figure 8.25. Curve fit of ln ⎜ ⎟ versus ln ⎜ ⎟ for Example 8.2.
⎝ Wi I r ⎠ ⎝ Wi ⎠
4. Figure 8.26 shows the oil-water relative permeability curves from the
unsteady state experiment. It should be noted that the relative
permeability curves are obtained over the limited saturation range of
0.395 ≤ S w ≤ 0.592 . The relative permeability curves between S wirr = 0.119
and S wf = 0.395 cannot be obtained from the experiment. They can only
8-63
experiment predicts a residual oil saturation of 40% in this
homogeneous high permeability sand.
8-64
Figure 8.27. True fractional flow curve measured in the unsteady state
experiment of Example 8.2.
8-65
8.5.2 Saturation History
Like capillary pressure curves, relative permeability curves show
saturation hysteresis. Figure 8.28 shows typical relative permeability curves
for drainage and imbibition. The imbibition non-wetting phase relative
permeability curve is generally lower than the drainage curve at the same
saturations. The imbibition wetting phase relative permeability curve is
slightly greater than the drainage curve. These differences can easily be
explained. During drainage, the non-wetting phase flows through the large
pores displacing the wetting phase along the way. The thin film of wetting
phase that coats the grain surface acts as a lubricant for the flow of the non-
wetting phase. Therefore, the relative permeability to the non-wetting phase
will be high during drainage. That of the wetting phase also will be high
because it starts from 1 and decreases as the non-wetting phase begins to
occupy some of the pores that were previously occupied by the wetting phase.
During imbibition, some of the non-wetting phase will be trapped in the large
pores. This capillary trapping reduces the amount of non-wetting phase
available to flow during imbibition compared to during drainage. It also
reduces the cross-sectional area of the medium occupied by the connected
non-wetting phase. As a result, the imbibition relative permeability to the
non-wetting phase is reduced compared to that during drainage. Because of
capillary trapping of the non-wetting phase during imbibition, the wetting
phase is forced to occupy and flow through pore sizes that are larger than it
would otherwise have flowed if there was no trapping of the non-wetting
phase. This forcing of the wetting phase to flow through larger pores than it
would otherwise have done in the absence of trapping enhances the relative
permeability of the wetting phase on the imbibition cycle compared to the
drainage cycle. These observations are in accord with the experimental results
shown in Figure 8.28.
8-66
Figure 8.28. Relative permeability hysteresis (Osoba et al., 1951).
8.5.3 Wettability
Relative permeability curves are markedly affected by the wettability of
the medium. Jennings (1957) measured steady state oil water relative
permeability curves on a core that was initially strongly water wet. He then
treated the core with a surface active agent (organo chlorosilane) that
rendered the core oil wet and repeated the relative permeability
measurements. The results are shown Figure 8.29. In general, the relative
permeability to oil decreases while the relative permeability to water increases
as the medium changes from a strongly water wet to a strongly oil wet
8-67
medium. It is interesting to replot the relative permeability curves of Figure
8.29 as functions of wetting phase saturation instead of water saturation. The
replotted curves are shown in Figure 8.30. We see that when plotted against
the wetting phase saturation, the relative permeability curves for the oil wet
core and the water wet core are close to each other. They are not identical
because the degree of wettability preference in the two experiments may be
different. However, the relative permeability curves for the wetting phase and
the non-wetting phase from the two experiments are essentially the same.
8-68
Figure 8.29. Effect of strong preferential wettability on steady state relative
permeability curves (Jennings, 1957).
8-69
At a given saturation, the relative permeability for a phase is higher
when that phase is the non-wetting phase than when it is the wetting phase.
This is observation can be seen in Figure 8.29. At any water saturation, the
relative permeability to water is higher when the water was the non-wetting
phase than when it was the wetting phase. Similarly, at any water saturation,
the relative permeability to oil is higher when the oil was the non-wetting
phase than when it was the wetting phase.
8-70
increased. The water curve increases and the oil curve decreases away from
the steady state curves as the degree of instability of the displacement
experiment increases.
8-71
Figure 8.32. Effect of stability number on unsteady state relative permeability
curves for oil wet sandpacks (Peters and Khataniar, 1987).
8-72
Figure 8.33. Effect of stability number on unsteady state relative permeability
curves for water wet sandpacks (Peters and Khataniar, 1987).
8-73
Figure 8.34. Effect of viscosity ratio on relative permeability curves obtained
by the steady state method (Leverett, 1939).
8-74
increased as the interfacial tension decreased. The residual fluid saturations
decreased as the interfacial tension decreased as expected from the effect of
capillary number on residual fluid saturations. In the limit, at ultra-low
interfacial tensions, the relative permeability curves were approximately
straight lines. These general trends in the effect of interfacial tensions on
relative permeability curves have been confirmed by Amaefule and Handy
(1981).
8-75
space available for multiphase flow. Therefore, for such rocks, end point
relative permeabilities are high and a large saturation change may occur
during two phase flow. By contrast, rocks with small pores have larger
specific surface areas and larger irreducible water saturations that leave less
room for multiphase flow. As a result, the end point relative permeabilities
are lower and the saturation range for two phase flow is smaller than in rocks
with large pores. Finally, rocks having some relatively large pores connected
by small pores have a large surface area, resulting in high irreducible water
saturation and relative permeability behavior that is similar to rocks with
small pores only. These observations are summarized in Figure 8.36.
8.5.8 Temperature
There are data in the literature that suggest that relative permeability
curves are affected by temperature. Poston et al., (1970) found that
temperature causes residual oil saturation to decrease and irreducible water
saturation to increase, with corresponding increases in relative permeability
curves (Figure 8.37). On the other hand, there are data in the literature that
also show that relative permeabilities are not temperature dependent (Miller
and Ramey, 1985). Apparently, the effect of temperature on relative
permeabilities is still and open question. This situation is understandable
because temperature can affect rock and fluid properties which in turn can
affect relative permeability curves. For example, high temperature can change
the wettability of the rock which affects relative permeabilities. It can also
reduce interfacial tensions, which can affect relative permeabilities and the
irreducible saturations. Because of the effect of temperature on the other
properties of the system that can affect relative permeabilities, it is difficult to
categorically determine the effect of temperature on relative permeabilities.
8-76
Figure 8.36. Effect of pore structure on relative permeability curves; (a)
sandstone with large, well-connected pores with k = 1314 md; (b) sandstone
with small, well-connected pores with k = 20 md; (c) sandstone with a few
large pores connected with small pores with k = 36 md (Morgan and Gordon,
1970).
8-77
Figure 8.37. Effect of temperature on relative permeability curves (Poston et
al., 1970).
8.5.9 Heterogeneity
Relative permeabilities are typically measured on homogeneous core
samples. These curves are then used in numerical simulators to model the
performance of heterogeneous reservoirs. It is often necessary to adjust the
laboratory measured relative permeability curves in order to successfully
history match the performance of the heterogeneous reservoirs. Gharbi and
Peters (1993) simulated the waterflood performance of a heterogeneous
reservoir using a set of input relative permeability curves and then used the
simulated oil recovery versus pore volumes of water injected and the
simulated pressure drop to calculate the equivalent relative permeability
curves for the heterogeneous medium by the JBN method. Figure 8.38
8-78
compares the input relative permeabilities with the computed equivalent
relative permeabilities for the heterogeneous medium. The effect of the
heterogeneity is to shift the oil and water relative permeabilities to low water
saturations thereby increasing the water relative permeability curve and
decreasing the oil relative permeability curve. Thus, the relative
permeabilities for the heterogeneous medium are similar to the relative
permeabilities for a strongly oil wet medium.
8-79
saturation diagram, the approximate regions of single phase flow, two phase
flow and three phase flow in an oil, water and gas system ( Leverett and Lewis,
1941). It can be seen that the three phase flow region is small compared to
single phase and two phase flow regions. Figures 8.40, 8.41 and 8.42 show
the three phase water, oil and gas relative permeabilities measured by
Leverett and Lewis (1941). They found that the relative permeability to water
was only a function of the water saturation. However, the relative
permeabilities to oil and gas were functions of all three fluid saturations.
Figure 8.39. Approximate limits of saturations giving 5 per cent or more of all
components in flow stream for the flow of nitrogen, kerosene and brine.
Arrows point to increasing fraction of respective components in stream
(Leverett and Lewis, 1941).
8-80
Figure 8.40. Three phase relative permeability to water (Leverett and Lewis,
1941).
Figure 8.41. Three phase relative permeability to oil (Leverett and Lewis,
1941).
8-81
Figure 8.42. Three phase relative permeability to gas (Leverett and Lewis,
1941).
8-82
Sw
dS w
kw ∫ Pc 2
krw ( S w ) = = 0
1
(7.159)
k dS
∫0 Pc 2w
and
1
dS w
knw
∫ Pc 2
krnw ( S w ) = = (7.160)
Sw
1
k dS
∫0 Pc 2w
We found that these models were defective in two respects: (1) they do not
include trapped residual saturations and (2) the sum of the relative
permeabilities is equal to 1, which is contrary to experimental observations.
These deficiencies result from the fact that the models neglect certain facts
about the nature of two phase flow in porous media. First, the cross-sectional
area open to the flow of the wetting phase is not a constant as assumed in the
models but is a function of the wetting phase saturation. Second, the
tortuosity for the flow of the wetting phase, which was neglected in the
models, is also a function of the wetting phase saturation. Burdine (1953)
proposed the following normalized drainage relative permeability models,
which account for these saturation dependencies in the cross-sectional area
and the tortuosity for two phase flow:
S w*
1
* ∫P 2
dS w*
= ( S w* )
kw ( S ) 2
krw ( S w* ) = w 0 c
(8.136)
k w ( S w = 1)
* 1
1
∫0 Pc2 dSw
*
1
1
* ∫P 2
dS w*
= (1 − S w* )
knw ( S ) 2 S w* c
krnw ( S w* ) = w
(8.137)
knw ( S w = 0)
* 1
1
∫0 Pc2 dSw
*
8-83
where S w* is the normalized wetting phase saturation given by
S w − S wirr
S w* = (8.138)
1 − S wirr
In Eqs.(8.136) and (8.137), the ratios of the integrals on the right side
account for the cross-sectional area changes with saturations and the terms
(S )
* 2
w and (1 − S )
* 2
w account for the tortuosity changes with saturations. It
should be noted that the base permeability used in Eq.(8.136) to define the
normalized relative permeability to the wetting phase is equal to the absolute
permeability of the medium, whereas the base permeability used to define the
normalized relative permeability to the non-wetting phase in Eq.(8.137) is
equal to the effective permeability to the non-wetting phase at the irreducible
wetting phase saturation. Thus, the normalized wetting phase relative
permeability given by Eq.(8.136) is also the true relative permeability to the
wetting phase. However, the normalized non-wetting phase relative
permeability given by Eq.(8.137) must be multiplied by the end point relative
permeability to the non-wetting phase (knwr) in order to obtain the true non-
8-84
pressure curve and then integrate the resulting linear function. As discussed
in Section 7.13.1, the Brooks-Corey drainage capillary pressure model is given
by
ln S w* = −λ ln Pc + λ ln Pe (7.161)
or
1
ln Pc = − ln S w* + ln Pe (7.162)
λ
and
1
Pc = Pe ( S w* )
−
λ (7.164)
where λ is the pore size distribution index obtained from the straight line
given by Eq.(7.161) or (7.162). Substituting Eq.(7.164) into Eqs.(8.136) and
(8.137) and performing the integrations gives the normalized drainage relative
permeability curves as
2 + 3λ
krw ( S w ) = ( S w* ) λ (8.139)
and
2+λ
2 ⎡ ⎤
krnw ( S w ) = (1 − S w* ) ⎢1 − ( S w* ) λ ⎥ (8.140)
⎣ ⎦
A critical saturation can be introduced into the relative permeability model for
the non-wetting phase as
2
⎛ S − S wirr ⎞ ⎡ 2+ λ
⎤
krnw ( S w ) = ⎜ 1 − w ⎟ ⎢ ( w) λ ⎥
− (8.141)
*
1 S
⎝ Sm − S wirr ⎠ ⎣ ⎦
8-85
where Sm is the wetting phase saturation corresponding to the critical non-
wetting phase saturation. Finally, the true relative permeability curve for the
wetting and non-wetting phases are given by
2 + 3λ
krw ( S w ) = ( S w* ) λ (8.142)
2
⎛ S − S wi ⎞ ⎡ 2+λ
⎤
krnw ( S w ) = knwr ⎜ 1 − w ⎟ ⎢1 − ( S *
) λ
⎥ (8.143)
⎝ Sm − S wi ⎠ ⎣
w
⎦
Example 8.3
Use the air-water capillary pressure data of Table 8.4 to calculate the
drainage relative permeability curves by the method of Brooks and Corey for a
core sample.
8-86
0.300 54.691
0.278 78.408
ln Pc = −2.1443ln S w* + ln 2.2238
Therefore,
1
− = −2.1443
λ
λ = 0.4664
Pe = 2.2238
*
Figure 8.44 shows the graph of lnS w versus lnPc for Swi = 0.10. It also is
linear and could have been used for the subsequent calculations. The Brooks-
Corey drainage capillary pressure equation is given by
1
Pc = Pe ( S )
* −λ
= 2.2238 ( S w* )
−2.1443
w
relative permeability curves for Sm = 0.95 and knwr = 0.961. The results of the
8-87
*
Figure 8.43. Log-log graph of Pc versus S w for Example 8.3.
*
Figure 8.44. Log-log graph of S w versus Pc for Example 8.3.
8-88
Figure 8.45. Normalized drainage relative permeability curves for Example
8.3.
Figure 8.46. True drainage relative permeability curves for Example 8.3.
8-89
Table 8.5. Results of Drainage Relative Permeability Calculations for Example
8.3
Brooks-Corey
Original Data Model Drainage Relative Permeability Curves
Pc Pc
Sw psi S *
w psi krw ( S w ) krnw ( S w ) krw krnw
1.000 1.973 1.000 2.224 1.000 0.000 1.000 0.000
0.950 2.377 0.944 2.514 0.659 0.001 0.659 0.000
0.900 2.840 0.889 2.863 0.424 0.006 0.424 0.002
0.850 3.377 0.833 3.288 0.265 0.017 0.265 0.008
0.800 4.008 0.778 3.812 0.160 0.036 0.160 0.022
0.750 4.757 0.722 4.468 0.093 0.063 0.093 0.044
0.700 5.663 0.667 5.305 0.052 0.098 0.052 0.073
0.650 6.781 0.611 6.393 0.028 0.140 0.028 0.111
0.600 8.195 0.556 7.843 0.014 0.189 0.014 0.156
0.550 10.039 0.500 9.831 0.006 0.244 0.006 0.208
0.500 12.547 0.444 12.656 0.003 0.304 0.003 0.266
0.450 16.154 0.389 16.851 0.001 0.371 0.001 0.331
0.400 21.787 0.333 23.452 0.000 0.443 0.000 0.401
0.350 31.817 0.278 34.672 0.000 0.521 0.000 0.479
0.300 54.691 0.222 55.947 0.000 0.605 0.000 0.562
0.278 78.408 0.198 71.829 0.000 0.643 0.000 0.601
0.250 0.167 103.678 0.000 0.694 0.000 0.652
0.200 0.111 247.331 0.000 0.790 0.000 0.749
0.150 0.056 1093.394 0.000 0.892 0.000 0.852
0.100 0.000 0.000 1.000 0.000 0.962
8-90
NOMENCLATURE
A = cross sectional area in the flow direction
Bo = oil formation volume factor
Bw = water formation volume factor
fw = fractional flow of wetting phase
fw = fractional flow of water
fnw = fractional flow of non-wetting phase
fnw2 = fractional flow of non-wetting phase at the outlet end of porous
medium
fo = fractional flow of oil
Fw = approximate fractional flow of wetting phase
g = gravitational acceleration
Ir = relative injectivity
J = Leverett J-function
k = absolute permeability of the medium
ko = effective permeability to oil
kw = effective permeability to water
kwr = end-point relative permeability to wetting phase
kg = effective permeability to gas
kro = relative permeability to oil
krw = relative permeability to water
krg = relative permeability to gas
krw = relative permeability to wetting phase
krnw= relative permeability to non-wetting phase
knwr= end-point relative permeability to non-wetting phase
L = length
M = mobility ratio
ME = end-point mobility ratio
Ncap = dimensionless capillary to viscous force ratio
Ng = gravity number
NpD = dimensionless cumulative production
8-91
Nvcap = capillary number
P = pressure
Pc = capillary pressure
Pe = displacement pressure for Brooks-Corey model
Pg = pressure in the gas phase
Pnw= pressure in the non-wetting phase
Po = pressure in the oil phase
Pc/ow = oil-water capillary pressure curve
Pc/go = gas-oil capillary pressure curve
Pc/gw = gas-water capillary pressure curve
Pw = pressure in the water phase
Pw = pressure in the wetting phase
q = total volumetric injection rate
qo = volumetric flow rate of oil
qg = volumetric flow rate of gas
qnw= volumetric flow rate of non-wetting phase
qw = volumetric flow rate of water
qw = volumetric flow rate of wetting phase
Qi = cumulative injection
Qnw = cumulative non-wetting phase produced
Qo = cumulative oil produced
R = oil recovery as a fraction of initial oil in place
Se = effective wetting phase saturation
Sg = gas saturation
So = oil saturation
Sor = residual oil saturation
Sw = water saturation
Sw = wetting phase saturation
Swirr = irreducible wetting phase saturation
8-92
Swro= wetting phase saturation at which imbibition capillary pressure is
zero
Sw2 = wetting phase saturation at the outlet end of porous medium
Snw= non-wetting phase saturation
Snwr = residual non-wetting phase saturation
Swav = average wetting phase saturation
Swav = average water saturation
Swf = frontal saturation
S w* = normalized wetting phase saturation
t = time
tbt = breakthrough time
tD = dimensionless time
G
v = flux vector, Darcy velocity vector
vw = Darcy velocity for the wetting phase
vnw = Darcy velocity for the non-wetting phase
x = distance in the direction of flow
xf = distance to the displacement front
xD = dimensionless distance
xDf = dimensionless distance to the displacement front
ρo = density of oil
ρw = density of water
ρw = density of wetting phase
σ = interfacial tension
8-93
θ = contact angle
λ = pore size distribution index
μ = viscosity
μg = gas viscosity
μο = oil viscosity
μw = water viscosity
μw = wetting phase viscosity
μnw= non-wetting phase viscosity
φ = porosity, fraction
τ = tortuosity
γ = liquid specific gravity
ω = angular velocity of centrifuge
ΔP = pressure drop
ΔPw = pressure drop in the wetting phase
ΔPnw = pressure drop in the non-wetting phase
Γ = pore structure
8-94
Brutsaert, W. : "Some Methods of Calculating Unsaturated Permeability,"
Trans. of the Amer. Soc. of Agricultural Engineers, Vol. 10 (1967) 400-
404.
Buckley, S.E. and Leverett, M.C. : “Mechanism of Fluid Displacement in
Sands,” J. Pet. Tech. (May 1941) 107-116.
Burdine, N.T. : “Relative Permeability Calculations From Pore Size
Distribution Data,” Trans., AIME (1953) 71-78.
Campbell, G.S. : "A Simple Method for Determining Unsaturated Conductivity
from Moisture Retention Data," Soil Sci., Vol. 117, No. 6 (1974) 311-
314.
Charbeneau, R.J. and Daniel, D.E. : "Contaminant Transport in Unsaturated
Flow," Chapter 15, in Handbook of Hydrology, D.R. Maidment (Ed.),
McGraw-Hill Inc., New York, 1993.
Collins, R.E. : Flow of Fluids Through Porous Materials, Research &
Engineering Consultants Inc., 1990.
Corey, A.T. : Mechanics of Heterogeneous Fluids in Porous Media, Water
Resources Publications, Fort Collins, Colorado, 1977.
Craig, F.F., Jr. : The Reservoir Engineering Aspects of Waterflooding, SPE
Monograph Vol. 3, Society of Petroleum Engineers, Richardson, Texas,
1971.
Daniel, D.E. : "Permeability Test for Unconsolidated Soil," Geotechnical
Testing Journal., Vol. 6, No. 2 (1983) 81-86.
Daniel, D.E., Trautwein, S.J., Boyton, S.S. and Foreman, D.E. : "Permeability
Testing with Flexible-Wall Permeabilities for Unconsolidated Soil,"
Geotechnical Testing Journal., Vol. 7, No. 3 (1984) 113-122.
Delshad, M. and Pope, G.A. : “Comparison of the Three-Phase Oil Relative
Permeability Models,” Transport in Porous Media 4 (1989) 59-83.
Douglas, J., Jr., Blair, P.M. and Wagner, R.J. : “Calculation of Linear
Waterflood Behavior Including the Effects of Capillary Pressure,” Trans.,
AIME (1958) 213, 96-102.
Dullien, F.A.L. : Porous Media - Fluid Transport and Pore Structure, Academic
Press, New York, 1979.
Dykstra, H. and Parsons, R.L. : “The Prediction of Oil Recovery by Waterflood,”
Secondary Recovery of Oil in the United States, American Petroleum
Institute (1950) 160-175.
Gharbi, R. and Peters, E.J. : “Scaling Coreflood Experiments to Heterogeneous
Reservoirs,” Journal of Petroleum Science and Engineering, 10, (1993)
83-95.
8-95
Gharbi, R.: Numerical Modeling of Fluid Displacements in Porous Media
Assisted by Computed Tomography Imaging, PhD Dissertation, The
University of Texas at Austin, Austin, Texas, August 1993.
Graue, A., Kolltvelt, K., Lien, J.R. and Skauge, A. : "Imaging Fluid Saturation
Development in Long-Core Flood Displacements," SPE Formation
Evaluation (December 1990) 406-412.
Hardham, W. D.: Computerized Tomography Applied to the Visualization of
Fluid Displacements, MS Thesis, University of Texas at Austin,
December 1988.
Honarpour, M., Koederitz, L. and Harvey, A.H. : Relative Permeability of
Petroleum Reservoirs, CRC Press, Inc., Boca Raton, Florida, 1986.
Jennings, H.Y. : “Surface Properties of Natural and Synthetic Porous Media,”
Producers Monthly (March 1957) 20-24.
Jennings, H.J. : “How to Handle and Process Soft and Unconsolidated Cores,”
World Oil (June 1965) 116-119.
Johnson, E.F., Bossler, D.P. and Naumann, V.O. : “Calculation of Relative
Permeability from Displacement Experiments,” Trans., AIME (1959)
216, 370-372.
Jones, S.C. and Roszelle, W.O. : “Graphical Techniques for Determining
Relative Permeability from Displacement Experiments,” J. Pet. Tech.
(May 1978) 807-817.
Keelan, D.K. : "A Critical Review of Core Analysis Techniques” The Jour. Can.
Pet. Tech. (April-June 1972) 42-55.
Khataniar, S. and E. J. Peters: “The Effect of Heterogeneity on the
Performance of Unstable Displacements,” Journal of Petroleum Science
and Engineering, 7, No. 3/4 (May 1992) 263-81.
Khataniar, S. and E. J. Peters: “A Comparison of the Finite Difference and
Finite Element Methods for Simulating Unstable Displacements,”
Journal of Petroleum Science and Engineering, 5, (1991) 205-218.
Khataniar, S. : An Experimental Study of the Effect of Instability on Dynamic
Displacement Relative Permeability Measurements, MS Thesis,
University of Texas, Austin, Tx, August 1985.
Khataniar, S.: A Numerical Study of the Performance of Unstable
Displacements in Heterogeneous Media, Ph.D. Dissertation, University of
Texas at Austin, August 1991.
Killins, C.R., Nielsen, R.F. and Calhoun, J.C., Jr.: “Capillary Desaturation and
Imbibition in Rocks,” Producers Monthly (February 1953) 18, No. 2, 30-
39.
8-96
Klute, A. : "Water Retention: Laboratory Methods," Methods of Soil Analysis,
Part 1, A. Klute (Ed.), American Society of Agronomy, Madison, WI
(1986) 635-686.
Klute, A. : "Hydraulic Conductivity and Diffusivity: Laboratory Methods,"
Methods of Soil Analysis, Part 1, A. Klute (Ed.), American Society of
Agronomy, Madison, WI (1986) 687-734.
Kyte, J.R. and Rapoport, L.A. : “Linear Waterflood Behavior and End Effects in
Water-Wet Porous Media,” Trans., AIME (1958) 213, 423-426.
Lake, L.W. : Enhanced Oil Recovery, Prentice Hall, Englewood Cliffs, New
Jersey, 1989.
Land, C.S. : "Calculation of Imbibition Relative Permeability for Two- and
Three-Phase Flow From Rock Properties,” SPEJ (June 1968) 149-156.
Land, C.S. : "Comparison of Calculated with Experimental Imbibition Relative
Permeability,” SPEJ (Dec. 1971) 419-425.
Lefebvre du Prey, E.J. : “Factors Affecting Liquid-Liquid Relative
Permeabilities of a Consolidated Porous Medium,” Soc. Pet. Eng. J. (Feb.
1973) 39-47.
Leva, M., Weintraub, M., Grummer, M. Pollchick, M. and Storch, H.H. : "Fluid
Flow Through Packed and Packed and Fluidized Systems," US Bureau
of Mines Bull. No. 504, 1951.
Leverett, M.C. : “Flow of Oil-Water Mixtures through Unconsolidated Sands,”
Trans., AIME (1939) 140, xxx-xxx.
Leverett, M.C. : “Capillary Behavior in Porous Solids,” Trans., AIME (1941)
142, 152-169.
Li, Ping: Nuclear Magnetic Resonance Imaging of Fluid Displacements in
Porous Media, PhD Dissertation, The University of Texas at Austin,
Austin, Texas, August 1997.
Majors, P.D., Li, P. and Peters, E.J. :”NMR Imaging of Immiscible
Displacements in Porous Media,” Society of Petroleum Engineers
Formation Evaluation (September 1997) 164-169.
Marle, C.M. : Multiphase Flow in Porous Media, Gulf Publishing Company,
Houston, Texas, 1981.
Miller, M.A. and Ramey, H.J., Jr. : “Effect of Temperature on Oil/Water
Relative Permeability of Unconsolidated and Consolidated Sands,” Soc.
Pet. Eng. J. (Dec. 1985) 945-953.
Morrow, N.R., Cram, P.J. and McCaffery, F.G. : "Displacement Studies in
Dolomite With Wettability Control by Octanoic Acid," SPEJ (August
1973) 221-232.
8-97
Morgan, J.T. and Gordon, D.T. : “Influence of Pore Geometry on Water-Oil
Relative Permeability,” J. Pet. Tech. (October 1970) 1199-1208.
Mungan, N. : “Enhanced Oil Recovery Using Water as a Driving Fluid; Part 2 -
Interfacial Phenomena and Oil Recovery: Wettability,” World Oil (March
1981) 77-83.
Mungan, N. : “Enhanced Oil Recovery Using Water as a Driving Fluid; Part 3 -
Interfacial Phenomena and Oil Recovery: Capillarity,” World Oil (May
1981) 149-158.
Mungan, N. and Moore, E.J. : "Certain Wettability Effects on Electrical
Resisitivity in Porous Media," J. Cdn. Pet. Tech. (Jan.-March 1968) 7,
No.1, 20-25.
Muqeem, M.A., Bentsen, R.G. and Maini, B.B. : “Effect of Temperature on
Three-phase Water-oil-gas Relative Permeabilities of Unconsolidated
Sand,” J. Canadian Pet. Tech. (March 1995) 34-41.
Osoba, J.S., Richardson, J.G., Kerver, J.K., Hafford, J.A. and Blair, P.M. :
“Laboratory Measurements of Relative Permeability,” Trans., AIME
(1951) 192, 47-56.
Perkins, F.M. : "An Investigation of the Role of Capillary Forces in Laboratory
Water Floods," Trans. AIME (1957) Vol. 210, 409-411.
Peters, E.J. : Stability Theory and Viscous Fingering in Porous Media, PhD
Dissertation, University of Alberta, Edmonton, Alberta, Canada,
January 1979.
Peters, E.J. and Flock, D.L. : “The Onset of Instability During Two-Phase
Immiscible Displacement in Porous Media,” Soc. Pet. Eng. J. (April 1981)
249-258; Trans., AIME (1981) 271.
Peters, E. J., J. A. Broman and W. H. Broman, Jr.: “Computer Image
Processing: A New Tool for Studying Viscous Fingering in Corefloods,”
SPE Reservoir Engineering (November 1987) 720-28
Peters, E. J. and W. D. Hardham: “A Comparison of Unstable Miscible and
Immiscible Displacements,” SPE 19640, Proceedings of the 64th Annual
Technical Conference of the Society of Petroleum Engineers (October
1989) San Antonio.
Peters, E.J., Afzal, N. and Gharbi, R. : “On Scaling Immiscible Displacements
in Permeable Media,” Journal of Petroleum Science and Engineering, 9,
(1993) 183-205.
Peters, E.J. and Gharbi, R. : “Numerical Modeling of Laboratory Corefloods,”
Journal of Petroleum Science and Engineering, 9, (1993) 207-221.
8-98
Peters, E.J. and Hardham, W.D. : “Visualization of Fluid Displacements in
Porous Media Using Computed Tomography Imaging,” Journal of
Petroleum Science and Engineering, 4, No. 2, (May 1990) 155-168.
Peters, E.J. and Khataniar, S. : “The Effect of Instability on Relative
Permeability Curves Obtained by the Dynamic-Displacement Method,”
SPEFE (Dec. 1987) 469-474.
Pirson, S.J. : Oil Reservoir Engineering, McGraw-Hill Book Company, Inc., New
York, 1958.
Poston, S.W., Ysreal, S.C., Hossain, A.K.M.S., Montgomery, E.F., III, and
Ramey, H.J., Jr. : “The Effect of Temperature on Irreducible Water
Saturation and Relative Permeability of Unconsolidated Sands,” Soc.
Pet. Eng. J. (June 1970) 171-180; Trans., AIME (1970) 249.
Purcell, W.R. : “Capillary Pressures - Their Measurement Using Mercury and
the Calculation of Permeability There From,” Trans., AIME (1949) 186,
39-48.
Rapoport, L.A. and Leas, W.J. : “Properties of Linear Waterfloods,” Trans.,
AIME (1953) 198, 139-148.
Richardson, J.G. : “Flow Through Porous Media,” Section 16, Handbook of
Fluid Dynamics, Edited by V.I. Streeter, McGraw-Hill Book Company,
Inc., New York, 1961.
Richardson, J.G., Kerver, J.K., Hafford, J.A. and Osoba, J.S. : “Laboratory
Determination of Relative Permeability,” Trans., AIME (1952) 195, 187-
196.
Rose, H.E. : “ An Investigation into the the Laws of Flow of Fluids Through
Granular Material,” Proc. Inst. Mech. Eng. (1945) 153, 141-148.
Scheidegger, A.E. : The Physics of Flow Through Porous Media, University of
Toronto Press, Toronto, 1960.
Stiles, W.E : “Use of Permeability Distributions in Water Flood Calculations,”
Trans., AIME (1949) 186, 9-13.
van Genuchten, M.T. : "A Closed-Form Equation for Predicting the Hydraulic
Conductivity of Unsaturated Soils," Soil Sci. Soc. Am. J., Vol. 44 (1980)
892-898.
Vauclin, M. : "Flow of Water and Air: Theoretical and Experimental Aspects,"
in Unsaturated Flow in Hydrologic Modeling: Theory and Practice, H.J.
Morel-Seytoux (Ed.), NATO ASI Series C: Mathematical and Physical
Sciences, Vol. 275, 1989.
Welge, H.J. : “A Simplified Method for Computing Oil Recovery by Gas or
Water Drive,” Trans., AIME (1952) 195, 91-98.
8-99
Willhite, G. P. : Waterflooding, SPE Textbook Series Vol. 3, Society of
Petroleum Engineers, Richardson, Texas, 1986.
Wyllie, M.R.J. and Spangler, M.B. :”Application of Electrical Resistivity
Measurements to Problems of Fluid Flow in Porous Media,” AAPG Bull.,
Vol. 36, No. 2 (Feb. 1952) 359-403.
Wyllie, M.R.J. and Spangler, M.B. :”Application of Electrical Resistivity
Measurements to Problems of Fluid Flow in Porous Media,” AAPG Bull.,
Vol. 36, No. 2 (Feb. 1952) 359-403.
8-100