H2O2 50% GHS SDS Rev 6 PDF
H2O2 50% GHS SDS Rev 6 PDF
H2O2 50% GHS SDS Rev 6 PDF
Product Information
Product name HYDROGEN PEROXIDE 50wt%
Chemical name HYDROGEN PEROXIDE aqueous solution
Product use Used in bleaching textiles, paper, wood, rattan, and other material;
used in the manufacture of a wide range of chemicals, plastics,
cosmetics, etc; used in photography, electroplating, water treatment
and wastewater treatment
Company
Name PT. Peroksida Indonesia Pratama
Address Head Office: Graha Purna Bhakti Building, Jl. Jend. A. Yani No. 39,
PO BOX 53, Cikampek 41373, West Java, Indonesia
Customer Service Telephone Number (62) 264-313383, 264-313387, 264-318577
(Monday to Friday, 7.00 AM to 4.00 PM)
Customer Service Facsimile Number (62) 264-313386
(Monday to Friday, 7.00 AM to 4.00 PM)
Emergency Call (62) 264-313383, 264-313387, 264-318577
(Monday to Friday, 7.00 AM to 4.00 PM)
Please call the nearest fire department and hospital for spill, leak, fire,
and accident involving chemical. Within Indonesia area, call 113 for fire
department and 118/ 119 for medic (24 hrs. 7 days a week)
2. HAZARDS IDENTIFICATION
GHS Classification
Physical Hazards
Explosives Not classified
Flammable gasses Not applicable
Flammable aerosols Not applicable
Oxidizing gases Not applicable
Gases under pressure Not applicable
Flammable liquids Not classified
Flammable solids Not applicable
Self-reactive substances and mixtures Not classified
Pyrophoric liquids Not classified
Pyrophoric solids Not applicable
Self-heating substances and mixtures Not classified
Substances & mixtures which in contact Not applicable
with water emit flammable gases
Oxidizing liquids Category 2
Oxidizing solids Not applicable
Organic peroxides Not applicable
Corrosive to metals Classification not possible
Health Hazards
Acute toxicity - oral Category 4
Acute toxicity - dermal Not classified
Acute toxicity - inhalation: gas Not applicable
Acute toxicity - inhalation: vapor Category 4
Acute toxicity - inhalation: dust Not applicable
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Material Safety Data Sheet
GHS Labelling
Symbols/ Pictograms
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Material Safety Data Sheet
Protection of First-aiders
First-aiders should wear protective equipment such as rubber gloves, goggles to prevent the contact with this
product.
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Material Safety Data Sheet
Environmental Precautions
Harmful to aquatic life, etc. Prevent from discharging into rivers, etc.
Handling
For handling and storing, a notification must be made in accordance with the provisions of the Poisonous and
Deleterious Substance Control Law and the Industrial Safety and Health Law. (Refer to '15. Regulatory Information')
Technical Measures
- Provide emergency showers and eyewash stations in the workplace and show their locations.
- Use apparatus and machinery with fewer openings to the atmosphere or provide local exhaust ventilation.
- Do not confine pipes used for hydrogen peroxide.
- Take measures to prevent hydrogen peroxide from scattering, leaking, etc.
- Suitable material is required for containers, pipes, etc. used for hydrogen peroxide.
Precautions
- Avoid unnecessary flames in the workplace.
- Do not place combustibles and flammables in the workplace.
- Once this product has been taken out of its container, it must not be restored in the original one.
- Wash combustibles such as wood, cloth, paper contaminated with hydrogen peroxide thoroughly with water.
- Avoid foreign substances such as acid, alkali, heavy metal, organic matter, and garbage to get mixed.
- Handle so as not to generate unnecessary vapor and mist.
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Material Safety Data Sheet
Storage
Technical Measures
The outer walls, floor, and roof of storage facilities must be made of noncombustible material for fire spread
prevention.
Exposure Limits
Japan Society for Occupational Health (2008) Not established
ACGIH (2008) TLV-TWA: 1 ppm
TLV-STEL not established
Engineering Controls
- Provide emergency showers and eyewash stations in the workplace and show their locations.
- For handling, use apparatus and machinery with fewer openings to the atmosphere or provide local exhaust
ventilation.
- Control limit: not established
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Material Safety Data Sheet
Stability
- Very stable unless foreign substances such as heavy metal, alkali, readily oxidized organic matters get mixed.
- When hydrogen peroxide decomposes into water and oxygen gas, heat of 98.05kJ/mol is generated.
- Heating expedites decomposition. (When the temperature increases by 10°C, the decomposition speed will be
approximately 2.2 times faster.)
Condition to Avoid
Heating, getting mixed with foreign substances such as heavy metal, alkali, readily oxidized organic matters.
Incompatible Materials
- Heavy metal, alkali, readily oxidized organic matters, etc.
- Iron, copper, copper alloy, titanium, titanium alloy, alloys of Hastelloy series, polyamide (nylon), polybutadiene,
epoxy resin, natural rubber, asbestos molding material, etc.
Acute Toxicology
Oral Rat LD50: 1,518 mg - H2O2/ kg male rats (WISTAR-JCL) (When 9.6% H2O2 is used) *2
Oral Rat LDL0: 805 mg - 70%H2O2/ kg male & female rats (Crl:CD BR) (When 70% H2O2 is used) *11
Inhalation vapor rat LC50: 1,438 ppm *15
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Material Safety Data Sheet
Carcinogenicity
Mice (C57BL) were dosed with drinking water containing hydrogen peroxide for 740 days. There are cases of cancer
occurring in duodenum. *4, *5 (The concentrations of hydrogen peroxide in drinking water were 0.1% and 0.4%)
Rats (FISHER F344) administered with drinking water containing H2O2 for 78 weeks did not indicate carcinogenicity.
*4, *6 (H2O2 concentrations in drinking water were 0.3% and 0.6%)
IARC (2009): Group 3 (Classification not possible for human carcinogenicity) *12
ACGIH (2009): A3 (Animal carcinogen) *13
(The agent is carcinogenic in experimental animals at a relatively high dose, by route(s) of
administration, at site(s), of histological type(s), or by mechanism(s) that may not be relevant to
worker exposure. Available epidemiologic studies do not confirm an increased risk of cancer in
exposed humans. Available evidence does not suggest that the agent is likely to cause cancer in
humans except under uncommon or unlikely routes or levels of exposure.)
Reproductive Toxicity
In vitro experiments indicate effects on human sperm. Although no animal studies report general toxicity for parent
animals, the product is classified as Category 2, based on reports on effects on sperm motility, on estrous cycles of
females, on reduced numbers of dams giving birth, and lower birth weights. *14
Others
Sub-acute Toxicity
- When male rats (WISTAR) were orally dosed with hydrogen peroxide, 60mg/kg/day, growth restraint was
observed in 20 days or later. *3, *4 (when 0.6wt/vol% H2O2 was used)
- When male rats (WISTAR-JCL) were orally dosed with 56.2mg/kg hydrogen peroxides 6 days/week for 12
weeks, no effect was observed. *2 (when 5wt/vol% H2O2 was used)
Ecotoxicity
Fish Toxicity
Saltwater fish Siganus fuscescens LC50 H2O2 224 mg/L 24 hours *8, *9
Tridentiger bifasciatus LC50 H2O2 155 mg/L 24 hours *8, *9
Trachurus symmetricus LC50 H2O2 89 mg/L 24 hours *8, *9
Freshwater fish Carp LC50 H2O2 42 mg/L 24 hours *10
Bioaccumulative Potential
Not reported
Mobility in Soil
Not reported
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Material Safety Data Sheet
Residual Waste
- Follow the items mentioned in “7. Handling and Storage”. In addition, decompose unnecessary hydrogen peroxide
by reacting gradually with a reducing agent such as sodium sulfite or with metals, etc.
- Dispose of exhausted water in compliance with effluent standards (pH, COD, etc.).
- When hydrogen peroxide is discharged in activated sludge treatment facilities, micro-organisms (activated sludge)
may be annihilated and their function may weaken to result in disability or low treatment efficiency.
- After consulting the manufacturer for safe disposal, dispose of unused hydrogen peroxide.
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Material Safety Data Sheet
Indonesian Regulations
- Keputusan Menteri Tenaga Kerja RI (Indonesian Ministry of Manpower) No. Kep. 187/ Men/ 1999: Pengendalian
Bahan Kimia Berbahaya di Tempat Kerja (Hazardous Chemical Control in Workplace)
- Categorized as Oxidizing Agent
References
*1 Compilation of Guideline for Chemical Disaster Prevention (1996) by The Chemical Society of Japan
*2 Page 531, 5th and 6th, Volume 23 of Journal of the Medical Society of Toho University (1976)
*3 Page 68, Volume 10 of Shokuhin Eiseigaku Zasshi (1969)
*4 Instruction Manual of Official Formulary of Food Additives
*5 Page 315, Volume 73 of GANN (1982) [English]
*6 Page 956, Last Volume of Study Report by Cancer Research Grant from the Ministry of Welfare (1980)
*7 Page 211, Volume 9 of Teratogenesis, Carcinogenesis & Mutagenesis (1989)
*8 Page 117, 2nd, Volume 29 of Cultivation (1992)
*9 Page 221, Volume 37 of Aquaculture (1989)
*10 Page 165, 4th, The Bulletin of the Graduate School of Bioresources Mie University (1990)
*11 E. I. du Pont de Nemous and Company Haskell Laboratory Report (1996)
*12 IARC Monographs on the Evaluation of the Carcinogenic Risks to Humans (1987)
*13 American Conference of Governmental Industrial Hygienists 2001 TLVs and BEIs
*14 ECETOC JACC (1993)
*15 UE-RAR (2003)
Further Information
For further information, contact
Company Name: PT. PEROKSIDA INDONESIA PRATAMA
Telephone No: (62) 264-313383, 264-313387, 264-318577
Disclaimer
The contents herein are based on materials, information, and data available as of today. However, concentrations,
physicochemical properties, and hazards in this MSDS are not guaranteed. As precautions are described on the
subject of the normal use and handling, please take appropriate safety measures for special use and handling.
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