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Balliranoite (Na, K) Ca (Si Al O) CL (CO)

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Balliranoite (Na,K)6Ca2(Si6Al6O24)Cl2(CO3)

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Crystal Data: Hexagonal. Point Group: 6. Crystals, prismatic on {101 0} and striated along
[0001], to 2 mm; as grains to 1 cm.
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Physical Properties: Cleavage: Perfect on {101 0}. Fracture: n.d.
Tenacity: Brittle. Hardness = 5 D(meas.) = 2.48(1) D(calc.) = 2.486(12)

Optical Properties: Transparent. Color: Colorless. Streak: n.d.


Luster: Vitreous.
Optical Class: Uniaxial (+). ω = 1.523(2) ε = 1.525(2)

Cell Data: Space Group: P63. a = 12.695(2) c = 5.325(1) Z=1

X-ray Powder Pattern: Monte Somma–Vesuvio volcanic complex, Campania, Italy.


4.797 (100), 3.281 (73), 2.662 (58), 3.669 (57), 2.446 (31), 2.120 (18), 2.754 (16)

Chemistry: (1)
SiO2 32.38
Al2O3 27.28
CaO 12.70
Na2O 13.05
K2O 3.08
Cl 7.43
SO3 1.96
CO2 3.24
H2O 0.19
-O=Cl2 1.68
Total 99.63

(1) Monte Somma–Vesuvio volcanic complex, Campania, Italy; average of 5 analyses, CO2 by
selective sorption, H2O by Penfield method and confirmed by IR, corresponding to
Na4.70Ca2.53K0.73(Si6.02Al 5.98O23.995)Cl2.34(CO3)0.82(SO4)0.27· 0.12 H2O.

Mineral Group: Cancrinite group.

Occurrence: A product of metasomatic reaction between alkaline magma and limestone.

Association: Orthoclase, phlogopite, clinohumite, calcite, diopside, pargasite, haüyne, apatite.

Distribution: Monte Somma–Vesuvio volcanic complex, Campania, Italy.

Name: Honors the Italian crystallographer Paolo Ballirano (b. 1964), Department of Earth Sciences,
University of Rome, for contributions to the crystal chemistry of cancrinite group minerals.

Type Material: A.E. Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow,
Russia (catalog no. 3756/1).

References: (1) Chukanov, N.V., N.V. Zubkova, I.V. Pekov, L.V. Olysych, E. Bonaccorsi, and
D.Y. Pushcharovski (2010) Balliranoite, (Na,K)6Ca2(Si6Al6O24)Cl2(CO3), a new cancrinite-group
mineral from Monte Somma–Vesuvio volcanic complex, Italy. Eur. J. Mineral., 22, 113–119. (2)
(2010) Amer. Mineral., 95, 1595-1596 (abs. ref. 1).

Mineralogical Society of America Handbook of Mineralogy Revised 1/14/2011

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