DERAKANECRGuide
DERAKANECRGuide
DERAKANECRGuide
C H E M I C A L R E S I S TA N C E G U I D E
Foreword
DERAKANE and DERAKANE MOMENTUM epoxy vinyl ester resins are designed and manufactured by Ashland. These resins possess outstanding corrosion-resistant properties and satisfy critical requirements in Fiber-Reinforced Plastic (FRP). Because they possess outstanding corrosion-resistant properties DERAKANE and DERAKANE MOMENTUM resins are particularly well suited for tough industrial applications. This guide briefly describes the various DERAKANE and DERAKANE MOMENTUM resins, and it presents detailed chemical resistance data needed to assist engineers in specifying and designing corrosion-resistant FRP applications. Recommendations given in this guide apply to state-of-the-art corrosion-resistant structures. Typically these structures have a corrosion barrier that is 2.5 to 6.3 mm (100 to 250 mils) thick and are designed for contact with a specific chemical environment. The first layer of the corrosion barrier usually is 0.3 to 0.8 mm (10 to 20 mils) thick and is 95% resin, reinforced by one or two surfacing veils. This layer is then backed with 2 to 6 mm (90 to 230 mils) of 75% resin, reinforced with chopped strand mat (powder binder only). Finally, the corrosion barrier is backed with a structural laminate that provides the strength and stiffness of the overall corrosion-resistant composite structure. Because many of the variables that affect the performance of a laminate are beyond Ashlands control, no warranty concerning the use of DERAKANE and DERAKANE MOMENTUM epoxy vinyl ester resins can be made. However, the service conditions shown in this bulletin are believed to be well within the capabilities of DERAKANE epoxy vinyl ester resins when laminates are properly designed, fabricated, and installed. For the design of FRP equipment, prospective users of DERAKANE resins should refer to the appropriate industry standards and design guidelines. For more information, contact Ashland at derakane@ashland.com or visit www.derakane.com.
DERAKANE and DERAKANE MOMENTUM 411 resins are the globally recognized standard for epoxy vinyl ester resins. They are based on bisphenol-A epoxy resin, and they provide resistance to a wide range of acids, alkalis, bleaches and solvents for use in many chemical processing applications. They offer excellent toughness and fatigue resistance. DERAKANE and DERAKANE MOMENTUM 441-400 resins are low styrene monomer bisphenol-A epoxy vinyl ester resins with mechanical, thermal and chemical resistance properties between DERAKANE 411 and DERAKANE 470 resins. Their unique combination of high HDT and elongation makes them resins of choice for applications with thermal cycling, e.g., for chemical reaction vessels. DERAKANE and DERAKANE MOMENTUM 470 resins are epoxy novolac-based vinyl ester resins designed to provide exceptional thermal and chemical resistance properties. They offer high resistance to solvents, acids and oxidizing substances such as chlorine. They also offer high retention of strength and toughness at elevated temperatures, making them the resins of choice for flue gas applications.
DERAKANE and DERAKANE MOMENTUM 510A/C resins are brominated epoxy vinyl ester resins that offer a high degree of fire retardance1. They are very resistant to chemical attack by chlorine and bleach environments. Their bromine content makes them tougher and more fatigue resistant than standard epoxy vinyl ester resins. DERAKANE 510N resin is brominated epoxy novolac vinyl ester resin that offers a high degree of fire retardance1. It is the most resistant resin in our portfolio against chlorine, bleach and hot, wet flue gas environments. DERAKANE 8084 resin is an elastomermodified bisphenol-A epoxy vinyl ester resin that offers very high toughness, impact- and fatigueresistance, and excellent adhesion. It is the resin of choice for demanding structural applications and as a primer for chemically resistant FRP linings.
The degree of retardance achieved in properly formulated cured products made of these resins is most frequently quantified by the ASTM E84 tunnel test. This is a controlled test that compares flammability characteristics of one material with another, but may not be predictive of behavior in a real fire situation. DERAKANE and DERAKANE MOMENTUM epoxy vinyl ester resins are organic materials and will burn under the right conditions of heat and oxygen supply.
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Table 1
Columns 411 series Valid for DERAKANE resins 411-350 411-45 411C-45 411C-50 441 series 441-400 470 series 470-300 470-30S 470-36 470-36S 470-45 470HT 470-300 510N series 510N 510A/C series 510A-40 510C-350
441-400
510A-40 510C-350
In the chemical resistance tables, a blank space simply indicates that no data was available at the time that temperature ratings were assigned. NR stands for not recommended at any temperature. LS stands for limited service (at least 3 days to 1 year at maximum 40C/100F). Generally in these cases, the respective resins can be used for FRP that is exposed accidentally, and where cleaning and inspection are possible after no more than 3 days.
This guide is updated on a regular basis in order to take into consideration all the new experiences and data (new products, other temperatures or concentrations, etc.).
Example
DERAKANE Resin Chemical Environment Hydrochloric Acid & Dissolved Organics 8,9,13
8
411 NR
not recommended
441
470 65/15015
510A/C
510N
8084 NR
Double surfacing veil and a 5 mm/200 mil CR barrier should be used Double C-veil should be used in the CR barrier. Acid resistant glass should be used in the corrosion liner and may be used in the structural wall
no data available
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FOOTNOTES
Information indicated in footnotes is essential in order to ensure a good service life of FRP equipment. It is strongly recommended that they are followed. 1. Double synthetic veil should be used in the CR barrier. 2. Postcure recommended to maximize service life. 3. Benzoyl Peroxide/Amine cure system with postcure recommended to increase service life. 4. Recommended provided that solvent used for dissolution is also recommended. 5. Satisfactory up to maximum stable temperature for product. 6. Check with corrosion technical service lab for specific recommendations. 7. Probably satisfactory at higher temperatures, but temperature shown is the highest for which information was available. 8. Double surfacing veil and a 5 mm/200 mil CR barrier should be used. 9. Double C-veil should be used in the CR barrier. 10. For reactors, use 441, 411 or 510A/C resins. 11. Within the solubility limits in aqueous solution. 12. Above 50C/120F, acid resistant glass should be used in the CR barrier and may be used in the structural wall. 13. Acid resistant glass should be used in the corrosion liner and may be used in the structural wall. 14. Chemical composition is unknown, obtain Safety Data Sheet from supplier.
15. Slight discoloration of high purity acid can occur during first exposures. 16. The use of the resin above the maximum allowable design temperature as limited by national design standards may require approval of the relevant authorities. NR: Not Recommended LS: Limited service, in general 3 days to 1 year lifetime at room temperature (max. 40C/100F), usually sufficient for secondary containment.
POSTCURE
For a service temperature below 100C/210F: A postcure may extend the service life if the operating temperature is within 20C/40F of the present CR guide maximum temperature for the service. This means that a postcure can be beneficial for solvent applications with a temperature limit of 25-40C/80-100F. For a service temperature above 100C/210F: Postcure in service may be sufficient, provided the resin specific minimum Barcol hardness values are reached before start up. For service in pure and neutral salt solutions: Postcure may, in general, not be required, provided the resin specific minimum Barcol hardness values are reached and no acetone sensibility is shown before start up. When using a BPO/Amine cure system, postcure is strongly recommended and should be done within two weeks of construction. The postcure conditions as detailed in DIN 18820 may be used: For 411, 441, 510A/C and 8084 resins: 80C/180F. For 470 and 510N resins: 100C/210F. This norm recommends 1 hour per mm thickness of the laminate (between 5 and 15 hours).
INSUFFICIENT INFORMATION
In cases where the environment or exposure conditions are outside the scope of this guide and if, therefore, no specific recommendations can be made, a test laminate should be exposed to the actual, or simulated, conditions proposed so that a final decision on resin suitability is made.
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Special Cases
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SAFETY PRECAUTIONS
DERAKANE and DERAKANE MOMENTUM epoxy vinyl ester resins and the materials (solvents, accelerators, catalysts, etc.) used with them can be hazardous unless simple but precise precautions are taken. The precautions necessary for handling DERAKANE and DERAKANE MOMENTUM resins are similar to those for unsaturated polyesters and will therefore be familiar to trained personnel. Safety Data Sheets on all DERAKANE and DERAKANE MOMENTUM resins are available to help customers satisfy their own handling and disposal needs.
NOTICE
Recommendations as to methods and use of material made in this publication are based on the experience of Ashland Inc. and knowledge of the characteristics of DERAKANE and DERAKANE MOMENTUM resins, and are given in good faith. However, since as a material supplier Ashland does not exercise any control over the use of DERAKANE and DERAKANE MOMENTUM resins, no legal responsibility is accepted for such recommendations. In particular, no responsibility is accepted by Ashland for any system or application in which DERAKANE and DERAKANE MOMENTUM resins are utilized. The legal obligations of Ashland Inc. with respect to any sale of DERAKANE and DERAKANE MOMENTUM resins shall be determined solely by the terms of its respective sales contract.
Anyone wishing to reproduce or publish any of the material in this publication, in whole or in part, should request permission from Ashland Inc.
Please fax this form to +1.614.790.5157 (America) or +49(0)7851 99478-30 (Europe) or your distributor.
Date: Number of Pages:
To
Name: Company: Fax:
From
Name: Company: Fax: Phone:
Equipment Type:
(Tank, Scrubber, Pipe/Duct, Lining)
Dimensions/Capacity:
(Height, Diameter, Flow Rate)
Operating Conditions
Chemical Environment 1) 2) 3) 4) 5) 6)
NOTE: Please show all major/minor components, concentrations including traces. (If insufficient space, please add extra sheet or include the respective Safety Data Sheet.)
Minimum
Concentrations Normal
Maximum
highs/lows min.
upsets max.
pH: typical
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Les rsines Epoxy Vinylester DERAKANE et DERAKANE MOMENTUM sont conues et produites par la division Epoxy Products and Intermediates de Ashland Inc. Elles rsistent exceptionnellement bien la corrosion et satisfont aux exigences les plus critiques des Stratifis Verre Rsine (SVR). Elles sont donc tout indiques pour les applications industrielles soumises des conditions de service extrmes. Ce guide donne une brve description des diverses rsines DERAKANE et DERAKANE MOMENTUM et prsente des donnes dtailles sur la rsistance chimique qui seront utiles aux ingnieurs lorsquils spcifient et conoivent des structures SVR rsistantes la corrosion. Les recommandations faites ici valent pour des structures anticorrosion fabriques dans les rgles de lart. Gnralement, ces structures ont une barrire anticorrosion dune paisseur de 2,5 6,3 mm (100 250 mils) et sont conues pour tre en contact avec un environnement chimique spcifique. La premire couche de la barrire a une paisseur denviron 0,3 0,8 mm (10 20 mils) et est constitue 95% de rsine, renforce dun ou deux voiles de surface. Derrire cette couche sajoute une autre couche de 2 6 mm (90 230 mils) constitue 75% de rsine, renforce dun mat fils coups ( liant poudre uniquement). Enfin, la barrire est renforce dun stratifi structural qui assure rsistance et rigidit lensemble de la structure composite.
Comme bien des facteurs qui influent sur la performance dun stratifi chappent son contrle, Ashland nest pas en mesure de garantir lutilisation qui est faite de ses rsines Epoxy Vinylester DERAKANE et DERAKANE MOMENTUM. Toutefois, les conditions de service exposes dans ce guide passent pour tre dans les limites des capacits des rsines DERAKANE lorsque les stratifis sont conus, produits et mis en uvre dans les rgles de lart. En ce qui concerne la conception dquipement en SVR, les utilisateurs des rsines DERAKANE et DERAKANE MOMENTUM sont invits consulter les normes de lindustrie et les directives de conception pertinentes. Pour obtenir plus d'informations, merci de nous envoyer un courriel l'adresse suivante derakane@ashland.com ou de visiter notre site internet www.derakane.com.
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Le degr dauto-extinguibilit atteint dans les produits durcis correctement et formuls partir de ces rsines est tabli le plus souvent au moyen de lessai en tunnel ASTM E84. Cet essai compare les caractristiques dinflammabilit dune matire avec une autre mais il ne peut prvoir le comportement de cette matire dans une situation relle dincendie. Les rsines Epoxy Vinylester DERAKANE et DERAKANE MOMENTUM sont des matires organiques susceptibles de senflammer dans des conditions favorables de chaleur et doxygne.
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Table 1
Colonnes 411 series Valide pour les rsines DERAKANE suivantes 411-350 411-45 411C-45 411C-50 441 series 441-400 470 series 470-300 470-30S 470-36 470-36S 470-45 470HT 470-300 510N series 510N 510A/C series 510A-40 510C-350
441-400
510A-40 510C-350
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Dans la table de rsistance chimique, un espace en blanc indique simplement quil ny a pas de donnes disponibles pour linstant. NR signifie Non recommand, indpendamment de la temprature. LS signifie Service Limit (dure dau moins 3 jours un an 40C/100F maximum). En gnral en pareils cas, les rsines mentionnes peuvent tre utilises pour fabriquer un SVR expos accidentellement un tel milieu. Il est recommand de raliser un nettoyage et une inspection aprs 3 jours de contact.
Ce guide est mis jour rgulirement pour tenir compte de toutes les nouvelles donnes et expriences (nouveaux produits, nouvelles tempratures ou concentrations, etc.). Il existe une version internet, ladresse www.derakane.com, o la recherche est des plus facile.
Exemple
DERAKANE Resin Chemical Environment Hydrochloric Acid & Dissolved Organics8,9,13
8
411 NR
non recommand
441
470 65/15015
510A/C
510N
8084 NR
Emploi impratif dun double voile de surface et une barrire anticorrosion de 5 mm (200 mils) Un double voile de type C dans la barrire anticorrosion est recommand. Emploi impratif dun verre rsistant aux acides dans le revtement anticorrosion et emploi facultatif dans la paroi structurale
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16. Lutilisation de la rsine au-del de la temprature maximale de calcul permise par la norme de conception choisie, peut ncessiter laval des autorits comptentes. NR: Non Recommand LS: Service Limit, en gnral dune dure de 3 jours 1 an temprature ambiante (max. 40C/ 100F). Normalement suffisant en confinement secondaire (bac de rtention ou autre).
POST-CUISSON
Temprature de service infrieure 100C (210F): une post-cuisson peut prolonger la dure de service si la temprature de service est comprise entre la temprature maximale indique dans ce guide et jusqu 20C en dessous de celle-ci. Cela signifie, par exemple, quune post-cuisson est toujours recommande pour les applications en contact avec des solvants dont la temprature maximale de service indique dans ce guide est comprise entre 25 et 40C (80 100F). Temprature de service suprieure 100C (210F): une post-cuisson en service peut tre suffisante, condition que les valeurs de duret Barcol minimales spcifiques de la rsine soient atteintes avant la mise en service. Service dans des solutions salines pures et neutres: une post-cuisson nest gnralement pas ncessaire, condition que les valeurs de duret Barcol minimales spcifiques de la rsine soient atteintes et que le SVR ne prsente pas de sensibilit au test lactone, avant la mise en service. Une post-cuisson est fortement recommande pour un SVR polymris au peroxyde de benzoyle (BPO)/Amine. La post-cuisson sera effectue de prfrence dans les deux semaines suivant la fabrication. Les conditions de post-cuisson numres dans la norme DIN 18820 peuvent tre considres: Pour les rsines 411, 441, 510 A/C et 8084: 80C (180F). Pour les rsines 470 et 510N: 100C (210F). Cette norme recommande 1 heure par mm dpaisseur du stratifi (entre 5 et 15 heures).
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Cas spciaux
MANQUE DINFORMATION
Il est des cas pour lesquels lenvironnement chimique et/ou les conditions dexposition ne sont pas traites dans ce guide. Des recommandations spcifiques ne peuvent alors pas tre formules, et il convient donc de raliser des tests sur des stratifis dans des conditions relles ou simules, avant de se prononcer sur la bonne tenue de la rsine.
Ces types de revtements ont des proprits particulires qui peuvent amener limiter les tempratures de service des installations en raison des diffrences de comportement thermique entre la rsine et le support (veuillez consulter les services techniques de Ashland pour plus dinformation ou une des compagnies locales spcialises dans ce type de dactivit). Un revtement stratifi peut donner une dure de service plus longue que dautres type de revtement au contact de fluides. Afin den garantir la qualit nous recommandons de les raliser par moulage au contact et non par projection simultane. En rgle gnrale, en raison du faible voire de labsence dexothermie lors de la polymrisation, ces revtements avec ou sans renfort devraient tre post-cuits chaque fois que cela est possible (voir le paragraphe concernant la postcuisson ci-dessus). Des prcautions particulires sont requises pour les milieux trs diffusants (HCl, HF, etc.). La rgle gnrale est la suivante ; plus le revtement est pais et mieux il a t rticul, plus sa rsistance la diffusion est leve et donc plus longue sera sa dure de service.
EXPOSITIONS INTERMITTENTES
Pour des expositions intermittentes, des fumes ou des dversements accidentels, il est possible doprer des tempratures de service parfois trs suprieures celles indiques dans le prsent guide. Cest ainsi que des structures telles que des canaux de dversement, revtements de sol, caillebotis, peuvent dans certains cas, tre exposes pour des courtes dures des produits jugs non recommands dans ce guide.
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COMMENT TRAVAILLER EN SCURIT AVEC LES RSINES DERAKANE ET DERAKANE MOMENTUM ET LES PRODUITS ASSOCIS
Les rsines Epoxy Vinylester DERAKANE et DERAKANE MOMENTUM ainsi que les produits associs (solvants, catalyseurs, acclrateurs, etc.) peuvent se rvler dangereux si des prcautions simples mais prcises ne sont pas observes. Les prcautions ncessaires la manipulation et la mise en uvre des rsines DERAKANE et DERAKANE MOMENTUM sont similaires celles des rsines polyesters insatures plus couramment utiliss dans lindustrie et seront de ce fait familires au personnel form ce dernier type de produits. Des fiches de scurit sur toutes les rsines DERAKANE et DERKANE MOMENTUM sont disponibles pour aider les clients les stocker ou les liminer (le cas chant).
AVERTISSEMENT
Les recommandations concernant les mthodes et lutilisation des produits contenus dans cette brochure, sont bases sur lexprience de Ashland Chemical et sur la connaissance des caractristiques des rsines Vinylester DERAKANE et DERAKANE MOMENTUM. Elles sont donnes de bonne foi. Ces informations sont toutefois donnes sans garantie et ne sauraient engager notre responsabilit. Elles nimpliquent aucune garantie du rsultat de lutilisation de notre produit ni de la libre exploitation de quelque brevet que ce soit. Ashland nexerant aucun contrle sur la bonne utilisation du produit, aucune responsabilit lie cette mise en uvre ne saurait, en consquence, lui tre impute. Ltendue des obligations de Ashland est exclusivement fixe par les termes de ses contrats de vente.
La reproduction ou la publication totale ou mme partielle du contenu de cette brochure est soumise lapprobation de Ashland.
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Date:
No de Pages:
Destinataire
Nom: Socit: Fax:
Expditeur
Nom: Socit: Fax: Tlphone:
Type dquipement:
(cuve, colonne, tuyau / conduit, revtement, etc.)
Dimensions/Capacit:
(hauteur, diamtre, dbit)
Conditions de service
Produits chimiques 1) 2) 3) 4) 5) 6)
NOTE:Veuillez galement indiquer les composs prsents faibles concentrations (traces). Si il manque de la place, veuillez rajouter une feuille.
Minimum
Concentrations Normal
Maximum
min./max. min.
accidentelles max.
pH: typique
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Vorwort
DERAKANE und DERAKANE MOMENTUM Epoxy-Vinylesterharze werden hergestellt von Ashland Inc. Zu HochleistungsGlasfaserverbundwerkstoffen (GFK) verarbeitet, bieten diese Reaktionsharze eine hervorragende Chemikalienbestndigkeit. Dies erlaubt einen Einsatz unter extremen industriellen Bedingungen. Diese Broschre umfat eine Einfhrung mit wichtigen Anwendungsdetails, sowie eine ausfhrliche Bestndigkeitstabelle. Zu den Zielgruppen gehren insbesondere GFKHersteller, Endanwender, Ingenieurfirmen und Anlagenbauer, technische Berater und Experten. Die Empfehlungen in dieser Broschre gelten fr korrosionsbestndige GFK-Laminate, hergestellt nach dem Stand der Technik. Im allgemeinen besitzen diese Laminate eine 2.5-6.3 mm starke Chemieschutzschicht (CSS), ausgelegt fr ein bestimmtes Medium. Die erste Schicht der CSS ist ca. 0.3-0.8 mm dick und enthlt ca. 95% Harz. Sie wird durch ein oder zwei Vlieslagen verstrkt. Auf diese Schicht werden mehrere Lagen (2-6 mm) harzgetrnkte, pulvergebundene Wirrfasermatten aufgebracht. Diese CSS wird dann mit dem sogenannten Traglaminat versehen, das fr die Festigkeit und die Steifigkeit des GFKBauteils sorgt. Die Einsatzgrenzen in dieser Broschre sind nach unserem besten Wissen und Gewissen mit GFK auf der Basis von DERAKANE Harzen zu erreichen, vorausgesetzt, die Bauteile wurden korrekt ausgelegt, hergestellt, und installiert. Da jedoch Ashland als Harzhersteller keinerlei Kontrolle ber die Verarbeitung der DERAKANE und DERAKANE MOMENTUM Harze sowie ber die vielen anderen Einflussgren hat, wird fr die Empfehlungen keine Haftung bernommen. Eine Auslegung von GFK Bauteilen ist nicht Gegenstand dieser Broschre. Wir verweisen hierzu auf die einschlgigen Regelwerke. Weitere Informationen finden Sie auf unserer Internetseite www.derakane.com, oder per E-mail-Anfrage bei derakane@ashland.com.
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Der Grad der Flammwidrigkeit, der mit korrekt formulierten und gehrteten Produkten auf der Basis dieser Harze erreicht wird, wird meistens durch einen Tunneltest nach ASTM E 84 bestimmt. Dies ist ein kontrolliertes Verfahren, welches das Brandverhalten mehrerer Materialien miteinander vergleicht, das jedoch mglicherweise keine Voraussagen des Verhaltens in echten Brandsituationen zult. DERAKANE und DERAKANE MOMENTUM Epoxy Vinylesterharze sind organische Materialien, die unter bestimmten Bedingungen (Wrme- und Sauerstoffzufuhr) brennen.
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Table 1
Columns 411 series Gltig fr DERAKANE Harze 411-350 411-45 411C-45 411C-50 441 series 441-400 470 series 470-300 470-30S 470-36 470-36S 470-45 470HT-400 470-300 510C-350 510N series 510N 510A/C series 510A-40 510C-350 510C-350FR
441-400
20
Eine Leerstelle in den Tabellen bedeutet, dass bis zur Drucklegung keine spezifischen Daten zur Verfgung standen. NR bedeutet nicht zu empfehlen, unabhngig von der Temperatur. LS bedeutet begrenzte Haltbarkeit (mindestens 3 Tage bis 1 Jahr bei maximal 40C/100F). In der Regel eignen sich die entsprechenden Harze in diesen Fllen fr Bauteile, die nur in Ausnahmefllen mit den Medien in Berhrung kommen, und wenn nach sptestens 3 Tagen eine Reinigung und Inspektion mglich sind.
Diese Broschre wird laufend berarbeitet. Neue Daten (neue Medien, Konzentrationen, Temperaturgrenzwerte usw.) sind damit schnell verfgbar. Eine Internetversion mit komfortablen Suchmglichkeiten finden Sie unter www.derakane.com.
Beispiel
DERAKANE Resin Chemical Environment Hydrochloric Acid & Dissolved Organics8,9,13
8
411 NR
nicht zu empfehlen
441
470 65/15015
510A/C
510N
8084 NR
Doppeltes Vlies und eine 5mm Chemieschutzschicht empfohlen Doppeltes C-Vlies in der Chemieschutzschicht empfohlen. Surebestndiges Glas sollte in der Chemieschutzschicht und kann im Traglaminat verwendet werden
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FUNOTEN
Die Funoten enthalten Informationen, die fr eine lange Standzeit der GFK-Bauteile von ausschlaggebender Bedeutung sind. Sie sollten daher unbedingt befolgt werden: 1. In der Chemieschutzschicht sollte ein doppeltes synthetisches Vlies verwendet werden. 2. Eine Nachhrtung wird zur Verlngerung der Standzeit empfohlen. 3. Maximale Standzeit wird durch die Verwendung eines Benzoylperoxid (BPO)/Amin-Hrtungssystems mit Nachhrtung erreicht. 4. Empfehlung gltig unter der Bedingung, dass das Harz gegenber dem Lsungsmittel ebenfalls bestndig ist. 5. Bestndig bis zur hchsten Temperatur, bei der das Medium noch stabil ist. 6. Es wird empfohlen, sich mit der Ashland Anwendungstechnik in Verbindung zu setzen. 7. Voraussichtlich auch bei hheren Temperaturen bestndig (Daten derzeit jedoch nur bis zur angegebenen Temperatur verfgbar). 8. Doppeltes Vlies und 5 mm Chemieschutzschicht empfohlen. 9. Doppeltes C-Vlies in der Chemieschutzschicht empfohlen. 10. Fr Reaktionsbehlter werden 441, 411, und 510A/C Harze empfohlen. 11. Innerhalb der Lslichkeitsgrenzen in wssriger Lsung. 12. Surebestndiges Glas sollte ber 50C in der Chemieschutzschicht und kann im Traglaminat verwendet werden. 13. Surebestndiges Glas sollte in der Chemieschutzschicht und kann im Traglaminat verwendet werden. 14. Wenn chemische Zusammensetzung unbekannt, ein Sicherheitsdatenblatt des Herstellers anfordern. 15. Eine leichte Verfrbung von reiner Sure kann whrend der ersten Expositionen auftreten. 22
16. Der Einsatz des Harzes oberhalb der in manchen Normen erlaubten Grenzen kann die Genehmigung durch die zustndigen Behrden erforderlich machen. NR: Nicht zu empfehlen LS: Begrenzte Haltbarkeit, im allgemeinen 3 Tage bis 1 Jahr bei Raumtemperatur (max. 40C), in der Regel geeignet fr Tanktassen, Auffangwannen, etc.
NACHHRTUNG
Fr eine Einsatztemperatur unter 100C: Eine Nachhrtung kann die Lebenserwartung verlngern, wenn die Einsatztemperatur innerhalb 20C unter den Temperaturgrenzen (Tmax 20C) in der Bestndigkeitstabelle liegt. Dies bedeutet, dass z.b. beim Einsatz in Lsungsmitteln mit einer Temperaturgrenze von 25 - 40C eine Nachhrtung immer empfehlenswert ist. Fr eine Einsatztemperatur ber 100C: Eine Nachhrtung im Betrieb kann ausreichend sein, vorausgesetzt, die Mindest-Barcolhrte des jeweiligen Harzes wird vor der Inbetriebnahme erreicht. Fr einen Einsatz in reinen und neutralen Salzlsungen: Eine Nachhrtung ist im allgemeinen nicht notwendig, vorausgesetzt, die Mindest-Barcolhrte des jeweiligen Harzes wird vor der Inbetriebnahme erreicht, und wenn der Acetontest eine klebfreie Oberflche ergibt. Eine Nachhrtung von Laminaten, die mit einem BPO/Amin-System gehrtet wurden, wird empfohlen. Die Nachhrtung sollte innerhalb von 2 Wochen nach der Fertigung erfolgen. Die folgenden in DIN 18820 vorgeschlagenen Nachhrtungsbedingungen sind empfehlenswert: Fr 411, 441, 510A/C, und 8084 Harze: 80C/180F. Fr 470 und 510N Harze: 100C/210F Diese Norm empfiehlt eine Nachhrtungsdauer von 1 Stunde pro mm Laminat-Wandstrke (zwischen mindestens 5 und maximal 15 Stunden).
Spezialflle
KEINE BESTNDIGKEITSDATEN VERFGBAR
Falls diese Broschre fr ein bestimmtes Medium oder fr bestimmte Einsatzbedingungen keine Daten enthlt, und wenn Ashland aufgrund fehlender Daten keine Empfehlungen aussprechen kann, sollte die Bestndigkeit von Testlaminaten unter Betriebs-oder Laborbedingungen untersucht werden. Solche Tests lassen im allgemeinen eine Abschtzung ber die zu erwartende Standzeit zu. Bei stark diffundierenden Medien (HCl, HF, etc.) ist besondere Vorsicht geboten. Generell gilt: Je dicker die Beschichtung, und je besser sie ausgehrtet ist, desto diffusionsdichter und haltbarer ist sie.
23
German
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
SICHERHEITSHINWEISE
DERAKANE und DERAKANE MOMENTUM Harze und Formulierungshilfsmittel knnen unter Befolgung blicher Vorschriften zur Arbeitsorganisation und -hygiene von ausgebildetem Fachpersonal sicher verarbeitet werden. Es gelten die gleichen Vorsichtsmanahmen wie fr styrolverdnnte Polyesterharze.
HINWEIS
Empfehlungen zu Endanwendung und Verarbeitung der DERAKANE und DERAKANE MOMENTUM Harze beruhen auf Erfahrungen der Ashland sowie auf anderen Leistungskennwerten und werden nach bestem Wissen und Gewissen gemacht. Da jedoch Ashland als Harzhersteller keinerlei Kontrolle ber die Verarbeitung der DERAKANE und DERAKANE MOMENTUM Harze hat, wird fr die Empfehlungen keine Haftung bernommen. Insbesondere bernimmt Ashland keine Haftung fr irgendwelche Systeme oder Anwendungen, in denen DERAKANE und DERAKANE MOMENTUM Harze verwendet werden. Pflichten und Haftung der Ashland in bezug auf den Verkauf von DERAKANE und DERAKANE MOMENTUM Harzen bestimmen sich ausschlielich nach dem jeweils zugrundeliegenden Kaufvertrag.
BESTNDIGKEITSANFRAGEN
Wird eine Harzempfehlung fr korrosive Medien gewnscht, so sollten die folgenden Daten zur Verfgung gestellt werden: Chemische Zusammensetzung aller Produkte eines Prozesses oder Ansatzes, mit den zugehrigen Konzentrationen (auch Spuren). Betriebstemperatur, sowie die Maximal- und Strfalltemperaturen (mit Zeitdauer). Aggregatzustand: Flssig, gasfrmig, fest (Risiko einer Phasentrennung oder Kondensation?). Art des Bauteils (GFK-Tank, -Rohr, Beschichtung usw.). Eine Kopie des umseitigen Vordrucks kann fr Bestndigkeitsanfragen verwendet werden (bitte per Fax an Ihren Hndler oder an die Ashland Anwendungstechnik schicken).
24
Datum:
Seitenzahl:
An
Name: Firma: Fax:
Von
Name: Firma: Fax: Tel:
Endkunde/Ingenieurfirma/Anlagenbauer/Projekt: Industriezweig/Prozess:
(Chemie, Papier, Erzaufbereitung, Rauchgas...)
Abmessungen/Leistung:
(Hhe, Durchmesser, Durchsatz...)
Betriebsbedingungen
Medien 1) 2) 3) 4) 5) 6)
HINWEIS: Bitte alle Komponenten angeben, auch solche in Spuren. Wenn der Platz nicht ausreicht, bitte ein separates Blatt oder ein Sicherheitsdatenblatt beifgen.
Minimum
Konzentrationen Normal
Maximum
Strfall min.
fr max.
pH: normal
25
German
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Prlogo
Las resinas epoxi vinil ster DERAKANE y DERAKANE MOMENTUM (EVER) son diseadas y producidas por el departamento Epoxy Products and Intermediates de Ashland Inc. Resisten exce cionalmente bien a la corrosin y satisfacen las exigencias ms difciles de los composites basados en laminados vidrio y resina (PRFV). As, estas resinas son muy adecuadas para las aplicaciones industriales sometidas a condiciones de uso extremado. Este gua propone una breve descripcin de las diversas resinas DERAKANE y DERAKANE MOMENTUM y presenta datos detallados sobre la resistencia qumica que sern tiles cuando los ingenieros tengan que especificar y concebir estructuras PRFV resistentes a la corrosin. Las recomendaciones siguientes valen para estructuras anticorrosivas producidas bajo todas las normas de la fabricacin. En general, estas estructuras tienen una barrera anticorrosiva de 2.5 a 6.3 mm (100 a 250 mils) de espesor y estn concebidas para estar en contacto con un medio qumico especfico. La primera capa de la barrera tiene de unos 0.3 a 0.8 mm (de 10 a 20 mils) de espesor y consta de un 95% de resina reforzada con uno o dos velos de superficie. Debajo de esta capa hay otra capa de 2 a 6 mm (de 90 a 230 mils) que consta de un 75% de resina reforzada con una malla de fibras cortadas (solamente con vnculo de polvo). Finalmente, se refuerza la barrera con un laminado que garantiza la resistencia y la rigidez del conjunto de la estructura composite.
Muchos factores que influyen en la elaboracin de un laminado estn fuera de nuestro control, por eso Ashland no est en condiciones de garantizar la utilizacin que se hace de sus resinas epoxi vinil ster DERAKANE. Sin embargo, se considera que todas las condiciones de uso presentadas en este gua estn dentro de los lmites de las capacidades de las resinas DERAKANE, siempre que los laminados se conciban, produzcan y utilicen siguiendo las correctas normas de fabricacin. En cuanto a la concepcin de la estructura de PRFV, aconsejamos a los usuarios de las resinas DERAKANE y DERAKANE MOMENTUM que consulten las normas de la industria y las directivas pertinentes de utilizacin. Para conseguir mas informaciones se puede mandarnos un mail con esta direccion derakane@ashland.com o visitar nuestro sitio internet www.derakane.com.
26
El grado de retardancia alcanzado en los productos endurecidos correctamente y formulados a partir de estas resinas se evala bajo el ensayo en tnel ASTM E84. Este ensayo compara las caractersticas de inflamabilidad de una materia con otra, pero no puede prever el comportamiento de esta materia en condiciones reales de incendio. Las resinas epoxi vinil ster DERAKANE y DERAKANE MOMENTUM son materias orgnicas que pueden inflamarse en condiciones propicias de calor y oxgeno.
27
Spanish
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Table 1
Columnas 411 series Vlido para las resinas DERAKANE siguientes 411-350 411-45 411C-45 411C-50 441 series 441-400 470 series 470-300 470-30S 470-36 470-36S 470-45 470HT 470-300 510N series 510N 510A/C series 510A-40 510C-350
441-400
510A-40 510C-350
28
En la tabla de resistencia qumica, un espacio blanco indica simplemente que no existen todava datos disponibles. NR significa No Recomendado cualquiera que sea la temperatura. LS significa Utilizacin Limitada (Limited Service). Duracin de 3 das a 1 ao a temperatura de ambiente (maximum de 40C/100F). En general, en los casos en que est indicado LS, las resinas citadas pueden utilizarse para fabricar un PRFV expuesto accidentalmente y momentneamente en semejante medio. Se recomienda realizar una limpieza y una inspeccin despus de 3 das de contacto.
Este gua se reactualiza regularmente para tener en cuenta todos los ltimos datos y nuevas experiencias (nuevos productos, nuevas temperaturas o concentraciones, etc.). Estos datos se pueden consultar y buscar fcilmente en la citada web www.derakane.com.
Ejemplo
DERAKANE Resin Chemical Environment Hydrochloric Acid & Dissolved Organics8,9,13
8
411 NR
NR No Recomendado
441
470 65/15015
510A/C
510N
8084 NR
Debe utilizarse un doble velo de superficie y una barrera anticorrosiva de 5 mm (200 mils). Se recomienda un doble velo de tipo C en la barrera anticorrosiva. Es necesario emplear un vidrio resistente a los cidos en la barrera anticorrosiva y es recomendable tambin su uso en la pared estructural.
13
29
Spanish
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
16. La utilizacin de la resina, por encima de la temperatura mxima de clculo permitida por la norma de diseo elegida, puede requerir la aprobacin de las autoridades competentes. NR: No Recomendado LS: Limited Service, Utilizacin limitada , en general a una duracin de 3 das a 1 ao a temperatura ambiente (max. de 40C, es decir 100F). Es normalmente suficiente en confinamiento secundario.
POSTCURADO
Temperatura de utilizacin inferior a 100C (210F): un postcurado del producto puede aumentar su tiempo de vida si la temperatura de utilizacin est comprendida entre la temperatura mxima indicada en este gua y 20C por debajo de dicha temperatura. Lo que significa, por ejemplo, que un postcurado puede ser beneficioso para las aplicaciones en contacto con disolventes dentro de una gama de temperaturas que van de 25 a 40C (de 80 a 100F). Temperatura de utilizacin superior a 100C (210F): un postcurado utilizado puede ser suficiente, si los valores mnimos de dureza Barcol especficos de la resina se alcanzan antes de la utilizacin del producto final. Utilizacin en soluciones de sales puras o neutras: un postcurado no suele ser necesario siempre que los valores mnimos de dureza Barcol especficos de la resina se alcanzan y que el PRFV no presenta sensibilidad a la prueba de la acetona, antes de la utilizacin del producto final. Se recomienda mucho un postcurado para un PRFV curado con Perxido de Benzoilo (BPO)/Amina. Se efectuar con preferencia el postcurado dentro de las dos semanas a partir de la fabricacin. Pueden utilizarse segn las condiciones de postcurado enumeradas en la norma DIN 18820: Resinas DERAKANE 411, 441, 510 A/C y 8084: 80C (180F ) Resinas DERAKANE 470 y 510N: 100C (210F ) La recomendacin es 1 hora /mm de espesor (entre 5 y 15 horas).
Casos Especficos
AUSENCIA DE INFORMACIN
En este gua no estn expuestos ni todos los casos, ni todos los productos quimicos, ni tampoco todas las condiciones de exposicin. En algunos casos no se puede dar recomendaciones (por falta de datos previos) y por eso es conveniente realizar ensayos de laminados en condiciones reales o simulaciones antes de decidir sobre la resistencia o el tipo de resina. Es necesario que se tomen precauciones particulares para los medios que difunden mucho (HCl, HF, etc.). En general cuanto ms espeso sea el revestimiento es y cuanto mejor curado est, tendr una mayor resistencia a la difusin y un tiempo de vida ms largo.
EXPOSICIONES INTERMITENTES
Para exposiciones intermitentes, humos o vertimientos accidentales, es posible actuar a temperaturas de utilizacin a veces superiores a las indicadas en este gua. Por eso, estructuras como canales de desage, revestimientos de suelo y entramados pueden en algunos casos exponerse durante breves momentos a productos considerados como no recomendados en este gua.
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Spanish
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
CMO TRABAJAR CON SEGURIDAD CON LAS RESINAS DERAKANE Y DERAKANE MOMENTUM Y LOS PRODUCTOS ASOCIADOS
Las resinas epoxi vinil ster DERAKANE y DERAKANE MOMENTUM as como los productos asociados (disolventes, catalizadores, aceleradores, etc.) podrn resultar peligrosos si no se toman precauciones tan simples como precisas. Las precauciones necesarias para la manipulacin y la utilizacin de las resinas DERAKANE y DERAKANE MOMENTUM son semejantes a las de las resinas polister insaturadas que suelen ser de uso ms comn en la industria y por eso sern ms familiares a los empleados formados para este tipo de producto. Las fichas de seguridad de todas las resinas DERAKANE y DERAKANE MOMENTUM estn disponibles para ayudar a los clientes a almacenarlas o destruirlas (si llega el caso).
AVISO
Las recomendaciones sobre los mtodos y la utilizacin de los productos presentes en este gua se dan de buena fe y estn basadas en la experiencia de Ashland y en su conocimiento de las caractersticas de las resinas vinil ster DERAKANE y DERAKANE MOMENTUM. Sin embargo, no se da garanta alguna para las mismas y no implican nuestra responsabilidad. Al no poder controlar el buen uso de nuestros productos, no se garantizan los resultados de uso ni la libre explotacin de cualquier patente, quedando Ashland libre de toda responsabilidad.
Las obligaciones de Ashland se limitan a los trminos de sus contratos de venta. La reproduccin o la publicacin total o parcial del contenido de este librito requiere la aprobacin de Ashland.
32
Fecha:
No de Pginas:
Destinatario
Nombre: Sociedad: Fax: 1.614.790.5157
Expedidor
Nombre: Sociedad: Fax: Telfono:
Aplicacin:
(cuba, columna, tubo, caera, revestimiento, etc.)
Dimensiones/Capacidad:
(altura, diametra, caudal)
Condiciones de Uso
Productos qumicos 1) 2) 3) 4) 5) 6)
NOTA : le pedimos tambin que precise los productos presentes con concentraciones dbiles (indicios). Si es necesario, se puede aada una hoja adicional).
Mnimo
Concentraciones Normal
Mximo
Presin/Vaco: Comentarios/notas:
(ej: procedimiento particular, ciclo de temperaturas, concentraciones variables, adicin & dilucin, diseo particular, etc.)
pH: (tpico)
min.
max.
33
Spanish
min./max.
accidenales
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins
Chemical Environment Concentration % 20 100 0.5 - 25 26 - 50 51 - 75 76 - 85 100 100 3/5/3 20/10 10 100 411 C/F 40/100 NR 100/210 80/180 65/150 45/110 NR NR 65/150 100/210 NR DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 40/100 NR 100/210 80/180 65/150 45/110 NR NR 80/180 100/210 80/180 NR 40/100 LS 100/210 80/180 65/150 45/110 40/100 40/100 80/180 100/210 80/180 LS 40/100 NR 100/210 80/180 65/150 45/110 NR NR 65/150 100/210 80/180 NR 40/100 100/210 80/180 65/150 45/110 NR NR 80/180 100/210 80/180 NR 8084 C/F 40/100 NR 65/150
Acetaldehyde Acetaldehyde Acetic Acid Acetic Acid Acetic Acid Acetic Acid Acetic Acid, Glacial Acetic Anhydride Acetic Acid/Nitric Acid/ Chromic Oxide Acetic Acid/Sulfuric Acid Acetone Acetone Acetone, Fumes, no condensation or coalescence Acetonitrile Acetonitrile Acetonitrile, Fumes, no condensation or coalescence Acetyl Acetone Acetyl Acetone Acid Cleaner - 31% hydrochloric acid2,8,9,13 Acrolein (Acrylaldehyde) Acrolein (Acrylaldehyde) Acrylamide Acrylic Acid7 Acrylic Acid Acrylic Latex Acrylonitrile Acrylonitrile Acrylonitrile Latex Dispersion7 Activated Carbon Beds, Water Treatment Adipic Acid (1.5 g sol. in water at 25C, sol. hot water) Adogen (see Quaternary Amine Salts) Air16 Alcohol, Amyl Alcohol, Butyl Alcohol, Ethyl
NR NR 65/150 65/150 NR
Fumes 20 100
40/100 NR
40/100 NR
80/180 40/100 LS
80/180 40/100 NR
80/180 40/100 NR
NR
40/100 NR 70/160 40/100 NR 40/100 40/100 NR 80/180 40/100 NR 25/80 100/210 80/180 210/410 60/140 50/120 25/80
80/180 50/120 LS 80/18015 40/100 LS 40/100 40/100 40/100 80/180 40/100 LS 25/80 100/210 80/180 230/450 65/150 65/150 40/100
80/180 40/100 NR 65/150 40/100 NR 40/100 40/100 NR 80/180 40/100 NR 25/80 80/180 80/180 195/380 50/120 50/120 25/80
80/180 50/120 NR 80/18015 40/100 NR 40/100 40/100 NR 80/180 40/100 NR 25/80 100/210 80/180 210/410 60/140 50/120 25/80
NR 25/80 65/150
23
100 100 95
50/120 NR NR
34
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 65/150 50/120 80/180 50/120 50/120 50/120 65/150 50/120
Alcohol, Isodecyl Alcohol, Propyl Alkaline Cleaner (see Sodium and Potassium Hydroxides) Alkaline Solutions (see Sodium, Potassium, and Ammonium Hydroxides, and Carbonates) Alkane Sulfonate (see Sodium Dodecylbenzene Sulfonate) Alkyl (C8-C10) Dimethyl Amine Alkyl (C8-C18) Chloride Alkyl Aryl Sulfonic Acid (see Alkyl Benzene Sulfonic Acid) Alkyl Benzene Sulfonic Acid6 Alkyl Tolyl Trimethyl Ammonium Chloride Allyl Alcohol Allyl Chloride Alpha-Oleum Sulfates Alpha-Methylstyrene Alum Alumina Hydrate Aluminum Chloride Aluminum Chlorohydrate Aluminum Chlorohydrate/ Hydrochloric Acid9,10,12 Aluminum Chlorohydroxide Aluminum Fluoride Aluminum Hydroxide Aluminum Nitrate Aluminum Potassium Sulfate Aluminum Sulfate Aluminum Sulfate Reactor10 AMBITROL* Ethylene Glycol Amine Salts Amino Acids Ammonia Ammonia Gas Ammonia Vapors (Wet) Ammonia, Aqueous (see Ammonium Hydroxide) Ammonium Acetate Ammonium Bicarbonate
* Dow Chemical
80/180 80/180
95/200 95/200
100/210 100/210
80/180 95/200
95/200 100/210
> 0.5
80/180 40/100 NR 25/80 50/120 25/80 100/210 80/180 100/210 100/210 80/180 100/210 25/80 80/180 100/210 100/210 100/210 100/210 100/210 50/120 40/100 NR 40/100 80/180
95/200 50/120 NR 25/80 50/120 40/100 120/250 80/180 120/250 100/210 100/210 100/210 25/80 80/180 100/210 120/250 120/250 100/210 100/210 65/150 40/100 NR 40/100 80/180
100/210 50/120 25/80 25/80 50/120 50/120 120/250 80/180 120/250 100/210 100/210 100/210 25/80 95/200 100/210 120/250 120/250 100/210 65/150 40/100 NR 40/100 80/180
95/200 40/100 NR 25/80 50/120 25/80 100/210 80/180 100/210 100/210 80/180 100/210 25/80 80/180 100/210 100/210 100/210 100/210 100/210 50/120 40/100 NR 40/100 80/180
100/210 50/120 NR 25/80 50/120 40/100 120/250 80/180 120/250 100/210 100/210 100/210 25/80 80/180 100/210 120/250 120/250 100/210 65/150 40/100 NR 40/100 80/180
100 100 100 100 Satd All Satd > 0.5 > 0.5/<15 50 All 100 > 0.5 Satd Satd > 0.5 > 0.5 All All Liquified Gas 100 40 vol %
NR NR NR 80/180 80/180 80/180 80/180 65/150 80/180 25/80 80/180 80/180 80/180 80/180
NR 40/100
25/80 70/160
25/80 70/160
40/100 70/160
25/80 70/160
25/80 70/160
NR 70/160
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
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COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % > 0.5 411 C/F 65/150 80/180 65/150 70/160 70/160 65/150 100/210 65/150 65/150 80/180 65/150 40/100 DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 65/150 80/180 65/150 70/160 70/160 65/150 100/210 65/150 65/150 80/180 65/150 40/100 65/150 80/180 65/150 70/160 70/160 65/150 100/210 65/150 65/150 65/150 40/100 40/100 8084 C/F 65/150 80/180 65/150 70/160 70/160 65/150 100/210 65/150 65/150 80/180 65/150 40/100 80/180 65/150 70/160 70/160 65/150 100/210 65/150 65/150 65/150 40/100 40/100
Ammonium Bifluoride1 Ammonium Bisulfite Black Liquor Ammonium Bisulfite Cooking Liquor Ammonium Bromate Ammonium Bromide Ammonium Carbonate Ammonium Chloride Ammonium Citrate Ammonium Fluoride1 Ammonium Hydroxide1 Ammonium Hydroxide1 Ammonium Hydroxide1 Ammonium Hydroxide/ Ammonium Chloride/ Ammonium Carbonate1 Ammonium Lauryl Sulfate Ammonium Ligno Sulfonate Ammonium Molybdate Ammonium Nitrate Ammonium Oxalate Ammonium Pentaborate Ammonium Perchlorate Ammonium Persulfate Ammonium Phosphate, dibasic Ammonium Phosphate, monobasic Ammonium Polysulfide Ammonium Sulfate Ammonium Sulfate/ Ethyl Alcohol/Ethoxylate Ammonium Sulfide (Bisulfide) Ammonium Sulfite Ammonium Thiocyanate Ammonium Thiocyanate Ammonium Thioglycolate Ammonium Thiosulfate Amyl Acetate Amyl Alcohol Amyl Alcohol, Vapor Amyl Chloride Aniline Aniline Aniline Hydrochloride Aniline Sulfate
0.5 - 43 0.5 - 43 > 0.5 > 0.5 > 0.5 > 0.5 0.5 - 5 6 - 20 30 (as NH3) 30 (as NH3) 35/5 0.5 - 30 0.5 - 50 > 0.5 Satd > 0.5 0.5 - 12 0.5 - 15 > 0.5 > 0.5 > 0.5 > 0.5 Satd 60/15/3 Satd Satd 0.5 - 20 Satd All All > 0.5 100 100 100 20 100 > 0.5 > 0.5
* Dow Chemical
40/100 50/120 80/180 65/150 100/210 65/150 50/120 75/170 100/210 100/210 100/210 50/120 100/210 40/100 50/120 65/150 100/210 50/120 40/100 60/140 20/70 50/120 50/120 50/120 40/100 NR 80/180 100/210
40/100 50/120 80/180 65/150 65/150 50/120 100/210 100/210 100/210 50/120 120/250 50/120 50/120 65/150 100/210 50/120 40/100 60/140 40/100 60/140 100/210 50/120 40/100 NR 80/180 100/210
100/210 100/210 100/210 65/150 120/250 65/150 50/120 65/150 100/210 50/120 40/100 60/140 50/120 65/150 100/210 50/120 40/100 20/70 80/180 100/210
100/210 100/210 100/210 105/220 40/100 65/150 100/210 50/120 40/100 60/140 50/120 50/120 50/120 40/100 NR 80/180 100/210
100/210 50/120 40/100 60/140 60/140 100/210 50/120 40/100 NR 80/180 100/210
50/120
NR
36
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 100/210 50/120
8084 C/F
Animal Fat Anionic Surfactant Anionic/Cationic Polymer Emulsions in Kerosene or Petroleum Distillates/Water Anodize (15% Sulfuric acid) Antimony Pentachloride, for aqueous solutions (see Hydrochloric Acid) Aqua Regia6 Armeen* H.T. Amines (C8-C18) Aromatic Naphtha/ Naphthalene/Isopropanol Arsenic Acid Arsenic Acid/Copper Sulfate/ Sodium Dichromate Arsenic Pentoxide/ Copper Oxide/Chromic Acid Arsenious Acid Barium Acetate Barium Bromide Barium Carbonate (slurry) Barium Chloride Barium Cyanide Barium Hydroxide Barium Sulfate Barium Sulfide Barley Solution Beer Beet Sugar Liquor o-Benzoyl Benzoic Acid Benzaldehyde Benzalkonium Chloride Benzene Benzene, 120F Benzene Sulfonic Acid6 Benzene, Vapor Benzene/Methyl Tertiary Butyl Ether Benzene/Ethylbenzene/ Toluene/Trimethylbenzene/ Xylene Benzene/Ethylbenzene Benzoic Acid Benzyl Alcohol
* Akyo Nobel
50/120
40/100
50/120
0 - 50
40/100 100/210
50/120 100/210
50/120 100/210
100/210
100/210
> 99 100 60/5/10 > 0.5 17/37/20 17/9/24 19Be > 0.5 > 0.5 All > 0.5 > 0.5 > 0.5 Satd > 0.5 > 0.5 > 0.5 > 0.5 All 100 Dilute 100 100 > 0.5
40/100 40/100
40/100 40/100 50/120 80/180 80/180 40/100 80/180 80/180 100/210 80/180 100/210 65/150 65/150 120/250 80/180 75/170 50/120 80/180 100/210 NR 40/100 NR NR 65/150 25/80 NR
40/100
40/100
40/100
40/100
80/180 80/180 40/100 80/180 80/180 100/210 80/180 100/210 65/150 65/150 100/210 80/180 75/170 50/120 80/180 100/210 NR 40/100 NR NR 65/150 25/80 NR
50/120 80/180 80/180 40/100 80/180 80/180 100/210 80/180 100/210 65/150 65/150 120/250 80/180 NR NR NR 100/210 20/70 40/100 50 LS/120 LS 65/150 50/120 40/100
80/180 80/180 40/100 80/180 100/210 80/180 100/210 65/150 65/150 100/210 80/180 NR NR NR 100/210 NR NR NR 65/150 NR NR
50/120 80/180 80/180 40/100 80/180 80/180 100/210 80/180 100/210 65/150 65/150 120/250 80/180 NR NR NR 100/210 NR LS 50 LS/120 LS 65/150 25/80 LS 40/100 65/150 80/180 80/180 80/180 65/150 65/150 80/180 NR NR NR 65/150 NR 40/100 NR NR 65/150 NR NR
80/20
NR NR 100/210 40/100
NR NR 100/210 40/100
NR NR 80/180 40/100
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
37
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 100 100 60 Thin 411 C/F NR NR 40/100 80/180 DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 25/80 NR 40/100 80/180 40/100 25/80 40/100 80/180 NR NR 40/100 80/180 25/80 NR 40/100 80/180 8084 C/F NR NR
Benzyl Alcohol Benzyl Chloride Benzyltrimethylammonium Chloride Black Liquor (Pulp & Kraft Mill)1,2 Black Liquor (Pulp & Kraft Mill) Thick, Heavy1,2 Black Liquor Recovery, Furnace Gases6,16 Blow Down (Non-Condensable Gases from Pulp Digester, i.e., Dimethyl Sulfide and Mercaptanes)8 Borax Boric Acid Boron Trichloride Scrubbing Brake Fluids Brass Plating Solution: 3% Copper, 1% Zinc, 5.6% Sodium Cyanides, 3.0% Sodium Carbonate1 Brine Mixture (0.4% MgSO4, 9.5% NaCl, 5.0% Na2SO4, 2.0% K2SO4, 7% CaSO4 /2H2O, 3% Na2SO3/9H2O, pH 7) Brine, Chlorinated (see Chlorinated Brine) Brine, Salt Brine, Salt Brominated Phosphate Ester Bromine, Dry Gas Bromine, Liquid Bromine, Wet Gas Brown Stock Bunker C Fuel Oil (heavy fraction) Butadiene (Gas)2 Butane Butanol 2,2-Butoxyethoxyethanol (DOWANOL* DB) 2-Butoxyethanol (DOWANOL EB) 2-Butoxyethanol (DOWANOL EB) Butyl Acetate Butyl Acrylate
Thick
95/200 165/325
105/220 175/350
105/220 205/400
105/220 165/325
105/220 175/350
80/180
80/180
80/180
80/180
80/180
80/180
100/210
100/210
100/210
100/210
100/210
80/180
> 0.5 Satd > 0.5 100 100 100 100 100 100 100 100 20 100 100 100
100/210 100/210 40/100 NR 40/100 95/200 100/210 45/110 60/140 50/120 40/100 40/100 40/100 NR NR
100/210 120/250 40/100 NR 40/100 95/200 105/220 45/110 60/140 50/120 40/100 50/120 40/100 25/80 NR
100/210 120/250 50/120 40/1007 NR 40/100 80/180 105/220 45/110 60/140 65/150 40/100 50/120 40/100 30/90 25/80
100/210 110/230 40/100 NR 40/100 95/200 100/210 45/110 60/140 50/120 40/100 40/100 40/100 NR NR
100/210 120/250 40/100 NR 40/100 80/180 105/220 45/110 60/140 50/120 40/100 50/120 40/100 25/80 NR
38
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
* Dow Chemical
Chemical Environment
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 50/120 40/100 NR 100/210 65/150 50/120 LS 40/100 100/210 50/120 NR NR 80/180 50/120 40/100 NR 100/210
8084 C/F NR NR NR
Butyl Alcohol Butyl Alcohol/Benzene Butyl Amine Butyl Benzoate Butyl Benzyl Phthalate Butyl Carbitol, Diethylene Glycol Butyl Ether (DOWANOL DB) Butyl CELLOSOLVE* Solvent (DOWANOL EB) Butyl Chloride Butyl Hypochlorite Butyl Stearate (5% in Mineral Spirits) Butylene Glycol Butylene Oxide Butyraldehyde Butyric Acid Butyric Acid Cadmium Chloride Cadmium Cyanide Plating Bath, (3% Cadmium Oxide, 10% Sodium Cyanide, 1.2% Sodium Hydroxide)1 Calcium Bisulfite Calcium Bromide Calcium Carbonate (slurry) Calcium Chlorate Calcium Chloride Calcium Chloride Calcium Hydroxide1 Calcium Hydroxide Slurry1 Calcium Hypochlorite1,2,3,5 Calcium Nitrate Calcium Sulfate Slurry Calcium Sulfite Calgon** (Product E) Sodium Hexametaphosphate Cane Sugar Liquor & Sweetwater Capric Acid (Decanoic Acid)4 Capric Acid/Lauric Acid/ Fatty Acids (C10-C18) Caproic Acid (Hexanoic Acid) Caprolactam
* Union Carbide ** Calgon Corporation
40/100 40/100 NR NR
40/100 40/100 LS NR
NR NR
NR NR
80/180
> 0.5 > 0.5 All > 0.5 > 0.5 Satd 100 0.5 - 25 All > 0.5 All > 0.5 All All > 0.5 70/15/15 100 0 - 50
80/180 100/210 100/210 80/180 100/210 100/210 100/210 100/210 80/180 80/180 100/210 100/210 100/210 50/120 80/180 80/180 80/180 25/80 40/100
80/180 100/210 100/210 80/180 100/210 100/210 120/250 100/210 65/150 80/180 100/210 100/210 100/210 50/120 80/180 80/180 80/180 50/120 40/100
80/180 100/210 100/210 80/180 100/210 100/210 120/250 100/210 40/100 40/100 100/210 100/210 100/210
80/180 100/210 100/210 80/180 100/210 100/210 105/220 100/210 80/180 80/180 100/210 100/210 100/210
80/180 100/210 100/210 80/180 100/210 100/210 120/250 100/210 65/150 80/180 100/210 100/210 100/210
80/180 80/180 80/180 80/180 80/180 80/180 80/180 80/180 65/150 80/180 80/180 80/180 80/180
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
39
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 100 100 100 All All 100 All All 100 All 100 10 All 100 100 411 C/F NR NR 80/180 50/120 165/325 NR 40/100 165/325 65/150 80/180 65/150 65/150 80/180 65/150 70/160 DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F NR NR 100/210 50/120 175/350 NR 65/150 175/350 80/180 95/200 80/180 65/150 80/180 65/150 70/160 LS LS 100/210 205/400 LS 65/150 205/400 80/180 95/200 80/180 65/150 80/180 70/160 NR NR 80/180 165/325 NR 40/100 165/325 65/150 80/180 65/150 65/150 80/180 70/160 NR NR 100/210 175/350 NR 65/150 175/350 80/180 95/200 80/180 65/150 80/180 70/160 8084 C/F NR NR
Caprolactam Caprolactone Caprylic Acid (Octanoic Acid) Caramel Carbon Dioxide Gas16 Carbon Disulfide Carbon Disulfide Fumes, no condensation or coalesence Carbon Monoxide Gas16 Carbon Tetrachloride Carbon Tetrachloride, Vapor CARBOWAX* Polyethylene Glycol Carboxyethyl Cellulose Cascade** Detergent in Solution Cashew Nut Oil Castor Oil (Ricinus Oil) Cationic/Anionic Polymer Emulsions in Kerosene or Petroleum Distillates/Water Caustic (see Sodium Hydroxide) Cetyl Alcohol (Hexadecanol) Chlordimeform (Galecron*** Insecticide) Chloric Acid Chlorinated Brine, pH < 2.5 Chlorinated Brine, pH > 9 (Hypochlorite)1,2,3 Chlorinated Brine, pH 2.5-9 6 Chlorinated Pulp6 Chlorinated Solvent Recovery (see Specific Solvents) Chlorinated Wax Chlorination Washer (Hoods & Vent Systems) Chlorine Dioxide Generator Effluent, R2 System Chlorine Dioxide Scrubber1,2,3 Chlorine Dioxide, Chlorine (Bleaching Solution, with or without Pulp)6
80/180 NR NR 80/180
0 - 50 100 100 All Satd Cl2 Satd Cl2 Satd Cl2 All
50/120 80/180 50/120 25/80 95/200 65/150 LS 95/200 65/150 25/80 25/80 80/180 80/180 LS 90/195 80/180 50/120 25/80 95/200 65/150 LS 95/200 50/120
25/80
LS
All
* Union Carbide ** Procter & Gamble ***Ciba-Geigy
80/180
90/195
95/200
90/195
95/200
40
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
Concentration %
411 C/F
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F
8084 C/F
Chlorine Dioxide, No Chlorine (Bleaching Solution, with or without Pulp)6 Chlorine Dioxide, Solution Storage Chlorine Water, pH < 2.5 Chlorine Water, pH > 9 (Hypochlorite)1,2,3 Chlorine Water, pH 2.5-96 Chlorine, Dry Gas2,8 Chlorine, Wet Gas2,8 Chlorine/Chlorine Dioxide/ Sulfur Dioxide Chlorine-Hydrogen Chloride, with Aqueous Condensate8,9,12,16 Chloroacetic Acid Chloroacetic Acid Chloroacetic Acid Chloroacetic Acid Chloroacetic Acid Chlorobenzene Chloroform Chloroform, Fumes, No Condensation or Coalescence Chloroform/Dichloroethane/ Methylene Chloride Chloropentane (1 to 5 Cl) Chloropicrin (Nitrochloroform) Chloropyridine (tetra) Chlorosulfonic Acid CHLOROTHENE* SM (1,1,1-Trichloroethane inhibited) Chlorotoluene N-Chloro-o-Tolyl (Insecticide Emulsion) Choline Chloride Chrome Bath, 19% Chromic Acid with Sodium Fluorosilicate and Sulfate1 Chrome Reduction Process6 Chromic Acid Chromic Acid
* Dow Chemical
All Satd Satd Cl2 Satd Cl2 Satd Cl2 100 100 0.8/2/0.7
80/180
NR NR NR
Fumes All 100 100 100 10 100 100 10 > 0.5 NR 40/100 NR 25/80 NR 40/100 25/80 50/120 50/120 NR 50/120 NR 50/120 NR 50/120 40/100 50/120 65/150
50/120
25 0.5 - 10 11 - 20
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
41
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 30 40 15/45 5/10 411 C/F LS NR 50/120 40/100 DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F LS NR 65/150 50/120 LS LS 65/150 65/150 LS NR 65/150 40/100 LS NR 65/150 40/100 50/120 40/100 8084 C/F
Chromic Acid Chromic Acid Chromic Acid/ Sodium Metabisulfite Chromic Acid/Nitric Acid Mixture Chromic Acid/Sulfuric Acid Mixture (Maximum Total Concentration 10%) Chromium Plate, Electroplating with a Salt Solution (with Sulfuric Acid: Not Recommended) Chromium Sulfate (water soluble forms) Citric Acid Clopidol (Coyden*)4 Cobalt Chloride Cobalt Chloride Reactor (Hydrochloric/Sulfuric Acid)10 Cobalt Citrate Cobalt Nitrate Coconut Oil Cod-liver Oil Copper Chloride Copper Chloride/Ammonium Chloride/Ammonium Hydroxide (see Ammonium Hydroxide) Copper Cyanide Copper Cyanide Plating Bath (10.5% Copper and 14% Sodium Cyanides; 6% Rochelle Salts) Copper Cyanide/ Potassium Cyanide/ Potassium Hydroxide1 Copper Matte Dipping Bath, (30% FeCl3, 19% Hydrochloric acid)8,9,13 Copper Nitrate Copper Plating Solution (45% Cu(BF4)2; 19% Copper Sulfate; 8% Sulfonic)1 Copper Sulfate Corn Oil Corn Starch Corn Sugar/Syrup (Glucose) Cottonseed Oil Crude Oil, Sweet, Sour Cumene
10
50/120
65/150
65/150
50/120
65/150
50/120
55/130 > 0.5 > 0.5 All > 0.5 40 12 > 0.5 100 100 Satd 100/210 100/210 100/210
55/130 100/210 100/210 100/210 95/200 80/180 100/210 95/200 40/100 120/250
100/210
100/210
100/210
100/210
100/210
80/180
70/160
70/160
70/160
70/160
70/160
70/160
7/2.5/2%
65/150
40/100
25/80
65/150
25/80
> 0.5
80/180 100/210
95/200 100/210
95/200 100/210
95/200 100/210
95/200 100/210
80/180 80/180
42
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
Concentration % All
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 40/100 50/120 25/80 50/120
8084 C/F NR
Cumene/Toluene/Xylene Curpric Chloride, (see Copper Chloride) Cyanide Disposal (Reaction with Hypo gives Sodium Thiosulfite) Cyanuric Acid Cyanuric Chloride4 Cyclohexane Cyclohexylamine Cyclopentane Dalapon Grass Killer (2,2-dichloropropionic acid and sodium salt) Decanoic Acid4 Decanol Deionized Water2 Demineralized Water2 Detergents, Organic De-waxed Paraffin Distillate Diacetone Alcohol Diacetone Alcohol Diallyl Phthalate Diammonium Phosphate Dibasic Acid (51-61% Glutaric Acid, 18-28% Succinic Acid, 15-25% Adipic Acid, 2% Nitric Acid) Dibromonitrilo-Proprionamide Dibromophenol Dibromopropane Dibromopropanol Dibutyl Carbitol (diethylene glycol dibutyl ether) Dibutyl Ether Dibutyl Sebacate Dibutyl Phthalate 2,4-Dichlorophenoxyacetic Acid (Acid, Salts, Esters and Formulations)4 Dichloroacetic Acid, (see Chloroacetic Acid) Dichlorobenzene (ortho and para) Dichloroethane Dichloroethylene Dichloromethane (Methylene Chloride) Dichloropropane
50/120
100 > 0.5 100 100 100 100 100 10 100 All > 0.5
25/80 80/180 65/150 80/180 80/180 80/180 80/180 40/100 NR 100/210 100/210
40/100 80/180 80/180 80/180 80/180 95/200 80/180 50/120 LS 100/210 100/210
25/80 80/180 65/150 80/180 80/180 80/180 80/180 50/120 NR 100/210 100/210
> 0.5 - 50 100 100 100 100 100 100 100 100
80/180 NR NR NR
80/180 NR NR NR
80/180 NR NR NR
25/80
50/120
50/120
50/120
50/120
50/120
NR NR NR NR NR
40/100 NR NR NR 25/80
NR NR NR NR NR
40/100 NR NR NR 25/80
NR NR NR NR NR
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
43
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 100 100 100 100 100 80/20 100 100 20 100 100 20 100 100 20 100 100 100 100 20 100 All 40 20 20 50 100 100 100 100 100 100 20 100 411 C/F NR NR 25/80 80/180 50/120 50/120 NR NR 40/100 NR NR 40/100 NR 40/100 40/100 NR 50/120 40/100 80/180 40/100 NR 40/100 40/100 80/180 40/100 40/100 NR NR 65/150 40/100 65/150 50/120 40/100 NR DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F NR 25/80 50/120 100/210 50/120 50/120 25/80 NR 40/100 LS NR 45/110 NR 50/120 40/100 NR 50/120 65/150 100/210 40/100 NR 50/120 50/120 80/180 50/120 40/100 NR 50/120 65/150 40/100 100/210 50/120 40/100 NR 25/80 40/100 50/120 100/210 65/150 50/120 40/100 NR 40/100 40/100 LS 50/120 25/80 50/120 40/100 LS 50/120 65/150 100/210 40/100 25/80 50/120 50/120 80/180 50/120 40/100 LS 50/120 65/150 40/100 100/210 65/150 40/100 LS NR NR 25/80 80/180 50/120 50/120 NR NR 40/100 NR NR 40/100 NR 40/100 40/100 NR 50/120 40/100 80/180 40/100 NR 50/120 50/120 80/180 40/100 40/100 NR NR 65/150 40/100 65/150 50/120 40/100 NR NR 25/80 50/120 100/210 50/120 50/120 25/80 NR 40/100 LS NR 40/100 NR 50/120 40/100 NR 50/120 65/150 100/210 40/100 NR 50/120 50/120 80/180 50/120 40/100 NR 50/120 65/150 40/100 100/210 50/120 40/100 NR 40/100 40/100 NR NR 25/80 65/150 40/100 NR NR 8084 C/F NR NR NR 65/150
Dichloropropene Dichloropropionic Acid (see also Dalapon) Dichlorotoluene Diesel Fuel Diethanolamine Diethanolamine/Ethanolamine Diethyl Carbonate Diethyl Ether Diethyl Formamide Diethyl Formamide Diethyl Hydroxylamine Diethyl Ketone Diethyl Ketone Diethyl Sulfate Diethylamine Diethylamine Diethylaminoethanol Diethylbenzene Diethylene Glycol Diethylene Glycol Dimethylether Diethylene Glycol Dimethylether Diethylenetriaminepentaacetic Acid Diethylenetriaminepentaacetic Acid, sodium salt Di-2-Ethylhexyl Phosphoric Acid (DEHPA) in Kerosene Diglycolamine (Aminoethoxyethanol) Diglycolamine (Aminoethoxyethanol) Diglycolamine (Aminoethoxyethanol) Diisobutyl Ketone Diisobutyl Phthalate Diisobutylene Diisonoyl Phthalate Diisopropanolamine Dimethyl Acetamide Dimethyl Acetamide Dimethyl Acetamide, Fumes, no condensation or coalescence
Fumes
80/180
80/180
80/180
44
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
Concentration % 20 40
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 40/100 LS 40/100 LS 40/100 LS 40/100 LS
Dimethyl Amine Dimethyl Amine Dimethylammonium Hydrochloride (Dimethylamine HCl, DMA-HCl) Dimethyl Aniline Dimethyl Formamide Dimethyl Formamide Dimethyl Formamide, Fumes, no condensation or coalescence Dimethyl Morpholine Dimethyl Phthalate Dimethyl Sulfate Dimethyl Sulfate Dimethyl Sulfide Dimethyl Sulfoxide Dimethyl Sulfoxide Dimethyl Sulfoxide (DMSO) Water Solution 2,2-Dimethyl Thiazolidine Dimethylcarbonate Dimethylformamide/ Acetonitrile/Methanol Dioctyl Phthalate Diphenyl Oxide (Diphenyl Ether, Phenyl Ether) Dipotassium Phosphate Dipropylene Glycol Dipropylene Glycol Monomethyl Ether (DOWANOL DPM) Dipropylene Glycol Monomethyl Ether (DOWANOL DPM) Distilled Water2 Divinylbenzene DMA 4 Weed Killer 2,4-D DMA 6 Weed Killer Dodecanol (Lauryl Alcohol) Dodecene Dodecyl Benzene Sulfonic Acid6 Dodecyl Benzene Sulfonic Acid/ Sulfuric Acid/Water/Oil Dodecyldimethylamine Dodecylmercaptan DOWANOL DB Glycol Ether
70 100 20 100 Fumes 100 100 20 100 100 20 100 20 1 100 26/9/7 100 100 > 0.5 100 20 100 100 100 100 100 100 100 100 85/10/4/1 100 100 100
40/100 NR 40/100 NR
40/100 LS 40/100 NR
50/1207 40/100 40/100 LS 80/180 50/120 80/180 50/120 LS 25/80 40/100 LS 20/70 80/180 NR LS 100/210 50/120 100/210 100/210 65/150 20/70 80/180 50/120 50/120 50/120 80/180 80/180 100/210 65/150 100/210 100/210 40/100
40/100 LS NR
NR 40/100 NR NR 40/100 NR
65/150 NR NR 65/150 25/80 100/210 80/180 40/100 NR 80/180 40/100 50/120 50/120 65/150 65/150 80/180 65/150 80/180 80/180 40/100
80/180 NR NR 100/210 40/100 100/210 100/210 50/120 LS 80/180 50/120 50/120 50/120 80/180 80/180 95/200 65/150 95/200 95/200 40/100
65/150 NR NR 65/150 25/80 100/210 80/180 50/120 NR 80/180 40/100 50/120 50/120 65/150 65/150 95/200 65/150 80/180 80/180 40/100
80/180 NR NR 100/210 50/120 100/210 100/210 65/150 NR 80/180 50/120 50/120 50/120 80/180 80/180 100/210 65/150 95/200 95/200 40/100
50/120 50/120
65/150
NR
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
45
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 411 C/F DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 8084 C/F
DOWANOL EB Glycol Ether (Ethylene Glycol n-butyl ether) DOWANOL PM Glycol Ether DOWANOL DPM (Dipropylene Glycol Monomethyl Ether) DOWANOL DB Diethylene Glycol n-Butyl Ether (see also Butyl CARBITOL*) DOWCLENE* EC Solvent DOWCLENE Solvent DOWEX* 50WX4 Ion Exchange Resin DOWFAX* 2A1 Surfactant DOWFAX 2AO Solution Surfactant DOWICIDE* Antimicrobial DOWTHERM* Heat Transfer Agent Electrosol Antistatic Agent (Petroleum naphtha, heavy alkylate) Epichlorohydrin Epoxidized Castor Oil Epoxidized Soybean Oil Esters, Fatty Acid Ethanol (Ethyl Alcohol) Ethanol (Ethyl Alcohol) Ethanol (Ethyl Alcohol) Ethanol (Ethyl Alcohol) Ethanol, Fumes, no condensation or coalescence Ethanol/Ethylacetate/ Methanol/DMF Ethanolamine Ethanolamine Ethephon Ethoxy Acetic Acid Ethoxy Acetic Acid Ethoxylated Alcohol, C12-C14 Ethoxylated Nonyl Phenol Ethyl Acetate
40/100 NR NR
40/100 LS LS
40/100 NR NR
40/100 NR NR
NR NR NR
100 100
40/100 50/120
NR
All 100 100 100 100 10 50 90 - 95 100 Fumes 35/29/10/10 20 100 100 10 100 100 100 100
* Dow Chemical
65/150 LS 40/100 65/150 80/180 50/120 40/100 25/80 NR 65/150 NR 40/100 25/80
65/150 LS 40/100 65/150 80/180 50/120 40/100 25/80 LS 65/150 NR 45/110 30/90 40/100 40/100 NR 40/100 LS LS
65/150 25/80 65/150 80/180 65/150 65/150 40/100 40/100 80/180 LS 50/120 40/100 40/100 40/100 LS 50/120 40/100 25/80
65/150 NR 65/150 80/180 50/120 40/100 25/80 25/80 80/180 NR 50/120 30/90 40/100 NR 40/100 LS LS
NR 25/80 NR NR
NR 25/80 NR NR
NR NR NR
46
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
Concentration %
411 C/F
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F
8084 C/F
Ethyl Acetate, Fumes, no condensation or coalescence Ethyl Acetate/Sodium Hydroxide1,2 Ethyl Acrylate Ethyl Amine Ethyl Amine Ethyl Bromide Ethyl Chloride Ethyl Ether Ethyl Sulfate 2-Ethylhexyl Alcohol Ethyl-3-Ethoxy Propionate Ethylbenzene Ethylbenzene/Benzene Ethylene Chloride (see Dichloroethane) Ethylene Chlorohydrin Ethylene Chlorohydrin Ethylene Diamine Ethylene Diamine Ethylene Dibromide Ethylene Dichloride (see Dichloroethane) Ethylene Dichloride/ Ethylene Dibromide/Tetra Ethyl Lead (above water solubility) Ethylene Glycol Ethylene Glycol Monobutyl Ether (DOWANOL EB) Ethylene Glycol Monobutyl Ether (DOWANOL EB) Ethylene Glycol/Sulfuric Acid Ethylene Oxide Ethylenediaminetetraacetic Acid (EDTA), (see VERSENE* 100 Chelating agent for the Tetrasodium Salt of EDTA) Ethylenesulfonic Acid, Sodium Salt6 Eucalyptus Oil Fatty Acid/Sterol/Triglyceride
* Dow Chemical
Fumes 4/0 - 50 100 20 70 100 100 100 100 100 100 100 67/33 100 20 100 20 100 100 100 50/120 NR 40/100 NR NR NR NR 40/100 65/150 NR 25/80 NR NR 40/100 40/100 40/100 NR NR NR 50/120 LS 40/100 NR LS LS NR 40/100 70/160 LS 40/100 25/80 NR 50/120 40/100 40/100 NR NR NR
80/180 40/100 25/80 40/100 LS LS 25/80 NR 40/100 80/180 25/80 50/120 40/100 25/80 65/150 40/100 40/100 LS NR 25/80
80/180 40/100 20/70 40/100 NR LS 25/80 NR 40/100 80/180 LS 40/100 25/80 NR 65/150 40/100 40/100 NR NR NR
NR 65/150 40/100 NR NR
80/180
65/150
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
47
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 5/2 All All > 0.5 5/20 48/0.2/0.2 0 - 29/1 - 20 0 - 40/0 - 25 > 0.5 > 0.5 0 - 29/1 - 20 411 C/F 100/210 100/210 80/180 100/210 100/210 100/210 80/180 100/210 100/210 100/210 80/180 DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 100/210 120/250 80/180 100/210 100/210 105/220 105/220 100/210 100/210 100/210 100/210 100/210 120/250 80/180 100/210 100/210 105/220 105/220 100/210 100/210 100/210 100/210 100/210 100/210 80/180 100/210 100/210 100/210 80/180 100/210 100/210 100/210 80/180 100/210 120/250 80/180 100/210 100/210 105/220 105/220 100/210 100/210 100/210 100/210 8084 C/F
Fatty Acid/Sulfuric Acid10 Fatty Acids Ferric Acetate Ferric Chloride Ferric Chloride/Ferrous Chloride Ferric Chloride/FerrousChloride/ Hydrochloric Acid Ferric Chloride/ Hydrochloric Acid8,9,12 Ferric or Ferrous Sulfate/ Sulfuric Acid Ferric Sulfate Ferrous Chloride Ferrous Chloride/ Hydrochloric Acid8,9,12 Ferrous Chloride+Manganese Chloride+Ferric Chloride/ Hydrochloric Acid8,9,12 Ferrous Nitrate Ferrous Sulfate Fertilizer, Uran*; Urea ammonium nitrate composition: 43.4% Ammonium Nitrate, 35.4% Urea, 20.3% Water 8-8-8 Fertilizer Composition: (Parts by wt. 30 Phosphoric Acid, 29 Ammonia, 104.3 Water, 10.4 Uran, 26.0 Potash, 3.0 Borax pH 8.2) Flue Gas, Dry16 Flue Gas, Wet Fluoboric Acid1,2 Fluoride Salts/Hydrochloric Acid1,2,5 Fluorine in Flue Gas, Wet1 Fluosilicic Acid1,2 Fluosilicic Acid1,2 Fluosilicic Acid Fumes1,2 Fluosilicic/Hydrofluoric/ Phosphoric Acids1,2 Fluozirconic Acid, Fluotitanic Acid, Ammonium Hydroxide1,2 Fly Ash Slurry Formaldehyde Formaldehyde/Methanol Formamide
65/150
65/150
65/150
65/150
65/150
65/150
65/150 165/325 80/180 100/210 50/120 80/180 80/180 40/100 80/180 40/100 40/100 80/180 50/120 50/120 40/100
65/150 175/350 100/210 100/210 50/120 100/210 80/180 40/100 80/180 40/100 40/100 80/180 65/150 65/150 50/120
65/150 205/400 100/210 100/210 50/120 100/210 80/180 40/100 80/180 40/100 40/100 80/180 65/150 65/150 65/150
65/150 165/325 80/180 100/210 50/120 80/180 80/180 40/100 80/180 40/100 40/100 80/180 50/120 50/120 50/120
65/150 80/180 65/150 50/120 80/180 65/150 40/100 65/150 40/100 40/100 80/180
40/100
* Arcadian Corporation
48
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 20/70 80/180 65/150 50/120 25/80 40/100 40/100 20/70 80/180 65/150 50/120 40/100 40/100 40/100 40/100 50/120 20/70 80/180 50/120 50/120 25/80 25/80 40/100 20/70 80/180 65/150 50/120 25/80 40/100 40/100
8084 C/F
Formamide Formic Acid Formic Acid Formic Acid Formic Acid Formic Acid Freon* 11 and 12 Refrigerant Freon 113 Refrigerant Fuel C (50/50 Isooctane/Toluene) Fuel C/Methyl t-Butyl Ether (MTBE) Note: Fuel C is 50% toluene and 50% isooctane) Fuel Oil Furfural11 Furfural Furfural in Organic Solvent4 Furfural/Acetic Acid/Methanol Furfuryl Alcohol2 Furfuryl Alcohol2 Galecron (Chlordimeform) Insecticide 100 Gallic Acid Gasohol (5% Methanol) Gasohol (Up to 10% Alcohol) Gasohol (10-100% Alcohol) Gasoline, Aviation Gasoline, Leaded Gasoline, No Lead, No Methanol Gasoline/MTBE Glucose Glutamic Acid Glutaraldehyde Glutaric Acid Glycerine Glycine and Derivatives Glycol Glycolic Acid (Hydroxyacetic acid) Glyconic Acid
* E. I. DuPont de Nemours & Co., Inc.
65/150 50/120
NR
80/180 40/100 NR NR NR 40/100 NR 25/80 80/180 50/120 40/100 NR 80/180 80/180 50/120 40/100 80/180 50/120 50/120 50/120 100/210 40/100 100/210 40/100 80/180
100/210 50/120 NR 25/80 NR 50/120 NR 50/120 80/180 50/120 40/100 NR 80/180 80/180 65/150 40/100 80/180 50/120 50/120 50/120 100/210 40/100 100/210 40/100 80/180
50/120 100/210 50/120 LS 40/100 LS 65/150 25/80 50/120 80/180 50/120 50/120 40/100 80/180 80/180 65/150 50/120 50/120 50/120 50/120 100/210 40/100 100/210 40/100 80/180
100/210 50/120 NR 40/100 NR 50/120 NR 50/120 80/180 50/120 40/100 NR 80/180 80/180 65/150
65/150 NR NR 40/100 NR
Satd
65/150
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
49
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 40 All 411 C/F 40/100 DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 40/100 40/100 40/100 40/100 40/100 40/100 40/100 8084 C/F
Glyoxal Glyphosate Gold Plating Solution (23% Potassium Ferrocyanide with Potassium Gold Cyanide and Sodium Cyanide) Goodrite K702/732 Product (Sodium Polyacrylate Disperants) Green Liquor1,2 Gypsum Slurry (see also Calcium Sulfate) Hard Chrome Plating Baths (with Sulfuric Acid: Not Recommended) Heptane Heptane, Fumes, no condensation or coalescence Herbicides14 Hexachloroethane Hexadecanol Hexamethylenetetramine Hexane Hexanoic Acid Hot Stack Gas (see Flue Gas) Hydraulic Fluid (Glycols)14 Hydrazine Hydrazine Hydrazine/Sodium Phosphate Hydriodic Acid Hydriodic Acid Hydrobromic Acid Hydrobromic Acid Hydrobromic Acid Hydrobromic Acid/Bromine Hydrochloric Acid9,12 Hydrochloric Acid8,9,12 Hydrochloric Acid8,9,12 Hydrochloric Acid8,9,12 Hydrochloric Acid8,9,13 Hydrochloric Acid8,9,13 Hydrochloric Acid8,9,13 Hydrochloric Acid8,9,13 Hydrochloric Acid & Dissolved Organics8,9,13
80/180
All All
80/180 80/180
100 Fumes 100 100 40 100 100 100 20 100 5/10 40 57 0 - 25 48 62 40/2 1 - 15 16 - 20 21 - 25 26 - 30 31 - 32 33 - 34 35 - 36 37 0 - 33% HCl
60/140 100/210 80/180 50/120 LS 65/150 40/100 70/160 25/80 80/180 NR 65/150 80/180 65/150 40/100 80/180 80/180 65/150 65/150 65/150 50/125 50/125 40/100 NR
60/140 100/210 80/180 50/120 40/100 80/180 50/120 70/160 50/120 80/180 LS NR LS 65/150 40/100 80/180 65/150 40/100 40/100 105/220 105/220 80/180 80/180 70/160 50/125 50/125 45/110
100/210 80/180 50/120 50/120 80/180 50/120 70/160 50/120 80/180 LS LS LS 65/150 40/100 80/180 65/150 40/100 40/100 110/230 110/230 100/210 95/200 80/18015 70/16015 60/14015 50/12515 65/15015
100/210 80/180 50/120 LS 65/150 40/100 70/160 25/80 80/180 LS NR LS 65/150 40/100 80/180 65/150 40/100 40/100 100/210 100/210 80/180 80/180 65/150 50/125 50/125 40/100
100/210 80/180 50/120 40/100 80/180 50/120 70/160 50/120 80/180 LS NR LS 65/150 40/100 80/180 65/150 40/100 40/100 105/220 105/220 80/180 80/180 80/18015 70/16015 60/14015 50/12015
25/80
NR 65/150 80/180 65/150 40/100 80/180 80/180 80/180 80/180 65/150 50/125 50/125
NR
50
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
Concentration %
411 C/F
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F
8084 C/F
Hydrochloric Acid + Aluminum + Aluminum chloride9,10,12 Hydrochloric Acid/Aluminum Chloride8,9,12 Hydrochloric Acid + Chlorine9,12 Hydrochloric Acid, Fumes + Free Chlorine, dry above 210F/100C8,9,12,16 Hydrochloric Acid, Fumes9,16 Hydrochloric Acid/Bromine/ Chlorine8,9,12 Hydrochloric Acid/Calcium Chloride8,9,12 Hydrochloric Acid/Diethylene Triamine (as Hydrochloride)/ Ammonium Chloride8,9,13 Hydrochloric Acid/ Ferric Chloride8,9,12 Hydrochloric Acid/ Ferric Chloride/Organics2,8,9,13 Hydrochloric Acid/ Ferrous Chloride8,9,12 Hydrochloric Acid/ Formaldehyde2,8,9,13 Hydrochloric/ Hydrofluoric Acid1,2,8,13 Hydrochloric Acid/ Hydrofluoric Acid1,2,8,13 Hydrochloric/ Hydrofluoric Acid1,2,13 Hydrochloric/ Hydrofluoric Acid1,2,8,13 Hydrochloric/Hydrofluoric/ Phosphoric Acid, Nitrobenzene1,2 Hydrochloric/Hydrofluoric/ Xylene Hydrochloric/Hydrofluoric Acid1,2,8,13 Hydrochloric/Hydrofluoric Acid1,2,8,13 Hydrocyanic Acid Hydrofluoric Acid1,2 Hydrofluoric Acid1,2 Hydrofluoric/Nitric Acid1,2 Hydrofluoric/Nitric Acid1,2
< 33/>10/10 1 - 20/0 - 29 28/35/1 1 - 20/0 - 29 25/3 36/1 Max. Total 20 15/0.1 - 1 25/6 40/100 80/180 40/100 80/180 NR 80/180 NR 105/220 NR 100/210 NR 40/100 40/100 100/210 45/110
65/150 105/220 65/150 100/210 65/150 40/10015 40/100 100/210 50/125 40/100 100/210 40/100 80/180 NR 80/180 NR 105/220 NR 100/210 NR 40/10015 40/100 100/210 50/120 40/100 80/180 80/180 NR 80/180 NR
NR
LS
40/100 NR
NR
LS
NR
65/150
80/180
65/150
80/180
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
51
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 3 - 5/30 - 35 8/20/2 411 C/F NR DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F NR LS 60/140 NR LS 60/140 8084 C/F NR
Hydrofluoric/Nitric Acid1 Hydrofluoric/Nitric/ Sulfuric Acid1,2 Hydrofluosilicic Acid/ Polyaluminum Hydroxychloride (or Polyaluminum Chloride, PAC)1,2 Hydrofluosilicic Acid1 (see Fluosilicic Acid) Hydrofluosilicic Acid1 (see Fluosilicic Acid) Hydrofluosilicic Acid/ Zinc Chloride1 Hydrogen Bromide, Dry Gas Hydrogen Bromide, Wet Gas Hydrogen Chloride, Dry Gas6,16 Hydrogen Chloride, Wet Gas Hydrogen Fluoride, Dry Gas/Vapor (if wet max. 40C/100F)1,2,6 Hydrogen Peroxide2,3,6 Hydrogen Peroxide2,3,6 Hydrogen Peroxide2,3,6 Hydrogen Peroxide/ Caustic1,2,3 (See individual listing for details) Hydrogen Peroxide/Caustic Bleach - Aqueous Solution with up to 0.56 wt. % Hydrogen Peroxide, pH = 10.7, 2% Sodium Silicate Pentahydrate, 0.2% Chelating Agent, 0.2% Chelant1,2,3 Hydrogen Sulfide6,16 Hydrogen Sulfide, Aqueous Hydrogen Sulfide, Dry Gas Hydrosulfite Bleach, Aqueous Solution containing 5% Zinc Hydrosulfite and 2.5% Tripolyphosphate5
40/100 80/180 40/100 40/100 80/180 80/180 100/210 100/210 80/180 65/150 25/80 NR
40/100 80/180 40/100 40/100 80/180 80/180 175/350 110/230 80/180 65/150 30/90 NR
40/100 80/180 40/100 40/100 100/210 80/180 175/350 110/230 80/180 65/150 40/100 LS
40/100 80/180 40/100 40/100 80/180 80/180 100/210 100/210 80/180 65/150 30/90 NR
40/100 80/180 40/100 40/100 100/210 80/180 175/350 110/230 80/180 65/150 40/100 NR
40/100 65/150 40/100 40/100 80/180 80/180 80/180 80/180 80/180 65/150 NR NR
0 - 30 35 50
85/185
85/185
85/185
85/185
80/180
5 All 100
80/180
80/180
80/180
80/180
80/180
80/180
52
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
Concentration %
411 C/F
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F
8084 C/F
J K
Hydroxyacetic Acid (Glycolic Acid) Hydroxyacetic Acid (Glycolic Acid) Hydroxylamine Acid Sulfate (Hydroxylammonium Acid Sulfate, HSA), Reaction of Hydroxylamine Acid Disulfate with steam to form HAS, Sulfuric Acid, Ammonium Sulfate Hypochlorous Acid2,3 Hypophosphorous Acid Imidazoline Acetate/Solvent2,4 Imidazoline Acetate/Solvent2,4 Incinerator Gases (see Flue Gas) Insecticide Emulsions Iodine, Crystals Iodine, Vapor Iron and Steel Cleaning Bath, 9% Hydrochloric, 23% Sulfuric acid Iron Plating Solution 45% FeCl2; 15% CaCl2; 20% FeSO4; 11% (NH4)2SO4 Isoamyl Alcohol Isoamyl Alcohol Isobutyl Alcohol Isobutyl Alcohol Isodecanol Isononyl Alcohol Isooctyl Adipate Isooctyl Alcohol Isopropanol Amine Isopropyl Alcohol (Isopropanol) Isopropyl Amine Isopropyl Amine Isopropyl Myristate Isopropyl Palmitate Itaconic Acid Jet Fuel, General Kerosene
20 70
40/100 40/100
50/120 40/100
65/150 40/100
40/100 40/100
50/120 40/100
40/100
40/100 50/120 NR NR
65/150 65/150
80/180
100/210
100/210
80/180
100/210
80/180
20 100 20 100 100 100 100 100 100 100 0.5 - 50 100 100 100 0.5 - 40 100 100
80/180 65/150 50/120 65/150 50/120 50/120 65/150 50/120 65/150 50/120 50/120 40/100 NR 100/210 100/210 60/140 60/140 80/180
120/250 65/150 60/140 65/150 50/120 65/150 65/150 50/120 65/150 50/120 50/120 40/100 NR 110/230 110/230 60/140 60/140 80/180
120/250 80/180 65/150 80/180 65/150 80/180 65/150 65/150 65/150 50/120 50/120 40/100 LS 110/230 110/230 60/140 60/140 80/180
80/180 65/150 50/120 65/150 50/120 50/120 65/150 50/120 65/150 50/120 50/120 40/100 NR 100/210 60/140 60/140 80/180
120/250 65/150 60/140 65/150 50/120 65/150 65/150 65/150 50/120 50/120 40/100 NR 110/230 110/230 60/140 60/140 80/180
80/180 65/150 50/120 40/100 NR 50/120 40/100 40/100 50/120 NR NR NR 65/150 65/150 60/140 60/140 65/150
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
53
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 411 C/F DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 8084 C/F
Kraft Recovery Boiler Breeching (see Flue Gas) Lactic Acid Lasso* Herbicide4 Latex (Emulsion in Water) (for specific latices see under chemical/polymer name) Lauroyl Chloride Lauryl Alcohol Lauryl Chloride Lauryl Mercaptan Lead Acetate Levulinic Acid Lignin Sulfonate Lime Slurry (see Calcium Hydroxide) Limestone Slurry (see Calcium Carbonate) Linseed Oil Liquid Petroleum Gas (LPG) Lithium Bromide Lithium Carbonate1 Lithium Chloride Lithium Chloride Lithium Hydroxide1 Lithium Hypochlorite1,2,3,5 Magnesium Bisulfite Magnesium Carbonate Magnesium Chloride Magnesium Fluosilicate1 Magnesium Hydroxide Magnesium Nitrate Magnesium Phosphate Magnesium Sulfate Magnesium Sulfate, Phosphoric Acid Magnifloc** 500 Series Products Magnifloc 837A Products Maleic Acid Manganese Chloride (Manganous Chloride) Manganese Nitrate (Manganous)
All All
100/210
100/210
100/210 50/120
100/210
100/210
65/150
65/150
All 100 100 Satd All > 0.5 Satd (35 - 40) All All > 0.5 All Satd All > 0.5 All > 0.5 Satd 1 - 40/0 - 36 All All > 0.5 > 0.5 > 0.5
* Monsanto ** Cytec
80/180 100/210 60/140 100/210 80/180 100/210 100/210 80/180 80/180 100/210 80/180 100/210 80/180 100/210 100/210 100/210 100/210 100/210 60/140 65/150 80/180 100/210 100/210
80/180 110/230 60/140 120/250 80/180 100/210 120/250 80/180 80/180 100/210 80/180 120/250 80/180 100/210 100/210 100/210 120/250 100/210 60/140 65/150 100/210 100/210 100/210
80/180 110/230 60/140 120/250 80/180 100/210 120/250 40/100 40/100 100/210 80/180 120/250 80/180 100/210 100/210 100/210 120/250 100/210 60/140 65/150 100/210 100/210 100/210
80/180 100/210 60/140 100/210 80/180 100/210 100/210 80/180 80/180 100/210 80/180 100/210 100/210 100/210 100/210 100/210 100/210 60/140 65/150 80/180 100/210 100/210
80/180 110/230 60/140 80/180 100/210 120/250 80/180 80/180 100/210 80/180 120/250 80/180 100/210 100/210 100/210 120/250 100/210 60/140 65/150 100/210 100/210 100/210
80/180 65/150 60/140 80/180 80/180 80/180 80/180 80/180 80/180 80/180 80/180 80/180 80/180 80/180 80/180 80/180 80/180 100/210 60/140 65/150 80/180 80/180 80/180
54
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
Concentration %
411 C/F
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F
8084 C/F
Manganese Sulfate (Manganous Sulfate) Melamine Formaldehyde Resin Mercaptoacetic Acid Mercaptoethanol Mercuric Chloride Mercurous Chloride Mercury Metal Pickling Solutions (Sulfuric-, Hydrochloric-, and/or Phosphoric Acids)9 Methacrylic Acid7 Methacrylic Acid Methane/Nitrogen Methane Sulfonic Acid6 Methanol (Methyl Alcohol) Methanol (Methyl Alcohol) Methanol (Methyl Alcohol) Methanol, Fumes, no condensation or coalescence Methanol/Ethanolamine Methanol/Formaldehyde/Sulfuric Methanol/Formaldehyde Methanol/Formaldehyde 1-Methoxy-2-Propanol Methyl Acetate Methyl Acetate Methyl Bromide Methyl Bromide Methyl Butyl Ketone (MBK), includes Methyl t-Butyl Ketone (MTBK) and other Isomers Methyl Chloride, Gas Methyl Chloride, Fumes, no condensation or coalescence Methyl Distearyl Ammonium Chloride/Isopropanol Methyl Ethyl Ketone Methyl Ethyl Ketone Methyl Ethyl Ketone, 2-Butanol, Triethylamine, 2-Butoxy Ethanol Methyl Formate Methyl Isobutyl Ketone (MIBK) Methyl Mercaptan (Gas)
0.5 - 15 Total 25 100 70/30 20 - 100 5 20 40 - 100 Fumes 0 - 60/0 - 20 60/20/2 0 - 15/0 - 37 35/4 100 20 100 10 100
100/210 50/120 40/100 95/200 40/100 50/120 40/100 40/100 80/180 40/100 40/100 65/150 40/100 20/70 40/100 LS 25/80 LS
100/210 40/100 40/100 95/200 NR 50/120 40/100 NR 80/180 NR NR 65/150 NR NR 40/100 LS 25/80 NR
NR NR
NR 40/100 NR NR NR
25/80 40/100
40/100 65/150
NR NR
40/100 NR NR NR NR
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
55
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % All 10 100 100 411 C/F NR NR NR DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F LS NR 25/80 25/80 LS LS 25/80 NR NR NR 20/70 NR 25/80 8084 C/F NR NR NR
Methyl Methacrylate N-methyl-2-pyrrolidone N-methyl-2-pyrrolidone Methyl t-Butyl Ether Methyl t-Butyl Ether (MTBE)/ Fuel C (Fuel C is 50% toluene and 50% isooctane) Methyl t-Butyl Ether, Fumes, no condensation or coalescence 2-Methyl-3-butenenitrile Methylamine Methylamine Methylamine Methyldiethanolamine Methyldiethanolamine Methylene Chloride Methylene Chloride, Fumes, no condensation or coalescence Methylene Chloride/Methanol/ Water Methylstyrene (alpha) Mineral Oils, Aliphatic Molasses Monochloroacetic Acid (see Chloroacetic Acid) Monochlorobenzene Monoethanolamine (see Ethanolamine) Monomethylhydrazine Morpholine2 Morpholine2 Morpholine/Cyclohexylamine Motor Oil Muriatic Acid (see Hydrochloric Acid) Myristic Acid Naphtha Naphtha, Heavy Aromatic
15/85 Fumes All 20 40 100 20 100 100 Fumes 1/4/95 100 100 100
40/100
50/120
40/100 80/180 25/80 40/100 LS NR 50/120 50/120 NR 80/180 40/100 25/80 100/210
50/120 80/180 40/100 40/100 LS NR 65/150 50/120 NR 80/180 40/100 40/100 120/250
NR
40/100 NR NR 40/100 NR
40/100 NR 65/150
100
NR
25/80
40/100
NR
25/80
NR
NR 40/100 NR NR 100/210
NR 45/110 NR NR 120/250
NR 45/110 NR NR 100/210
NR 50/120 NR NR 120/250
NR 40/100 NR NR 65/150
100/210 80/180
100/210 80/180
65/150 80/180
56
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 100/210 65/150 100/210 100/210 100/210 65/150 100/210 100/210 100/210 65/150 100/210 100/210 100/210 65/150 100/210 100/210
Naphthalene Neutralizer & Desmut Nickel Chloride Nickel Nitrate Nickel Plating Solution #1 (11% Nickel Sulfate/ 2% Nickel Chloride/ 1% Boric Acid) Nickel Plating Solution #2 (44% Nickel Sulfate/ 4% Ammonium Chloride/ 4% Boric Acid) Nickel Plating Solution #3 (15% Nickel Sulfate/5% Nickel Chloride/3% Boric Acid) Nickel Sulfamate Nickel Sulfate Nitric Acid Nitric Acid Nitric Acid Nitric Acid2 Nitric Acid2 Nitric Acid2 Nitric Acid Nitric Acid Fumes2 Nitric Acid Fumes, no condensation2 Nitric Acid/Hexavalent Chrome (Chromic Acid) Nitric Acid/Hydrogen Peroxide/ Hydrofluoric Acid1,2,3 Nitric/Hydrofluoric Acid1,2 Nitric/Hydrofluoric Acid Nitric/Hydrofluoric Acid1,2 Nitric/Hydrofluoric Acid1,2 Nitric/Hydrofluoric/ Sulfuric Acid1,2 Nitric/Phosphoric Acid2 Nitric/Sulfuric Acid2 Nitric/Sulfuric/Phosphoric Acid Nitric/Phosphoric Acid2 Nitrobenzene
80/180
80/180
80/180
80/180
80/180
80/180
80/180
80/180
80/180
80/180
80/180
80/180
All > 0.5 0-5 6 - 10 11 - 20 21 - 29 30 - 35 36 - 40 70 < 60 (soln.) > 60 (soln.) 10/5 30/5/0.5 25/3 30 - 35/3 - 5 15/15 20/6 20/8/2 24/23 20/20 20/5/2 5&5 100
100/210 80/180 100/210 65/150 65/150 50/120 40/100 25/80 NR NR 80/180 80/180 40/100 25/80 40/100 NR 50/120
100/210 80/180 100/210 80/180 65/150 50/120 40/100 30/90 NR NR 80/180 80/180 50/120 30/90 40/100 NR 50/120
100/210 80/180 100/210 80/180 65/150 65/150 50/120 40/100 40/100 LS 80/180 80/180 65/150 40/100 50/120 LS 40/100 60/140 60/140 50/120 50/120 50/120 80/180 40/100
100/210 80/180 100/210 65/150 65/150 50/120 40/100 30/90 NR NR 80/180 80/180 40/100 30/90 40/100 NR 55/130
100/210 80/180 100/210 80/180 65/150 65/150 50/120 40/100 25/80 NR 80/180 80/180 40/100 40/100 50/120 LS 40/100 60/140 60/140 50/120 50/120 50/120 80/180 25/80
80/180 80/180 80/180 65/150 50/120 50/120 40/100 NR NR NR 80/180 80/180 40/100 NR 40/100 NR 40/100
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
57
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration %
11
411 C/F NR NR
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 25/80 NR 40/100 LS LS NR NR 25/80 NR
8084 C/F NR NR
Nitrophenol11 N-methyl-2-pyrrolidone N-methyl-2-pyrrolidone Noncondensable Blow Down Gases (see Flue Gas or Blow Down) Octanoic Acid Oil, Sweet and Sour, Crude Oleic Acid Oleum (Fuming Sulfuric) Olive Oils Ortho-Dichlorobenzene (see Dichlorobenzene) Oxalic Acid Ozone in solution6 Palladium Suspensions in Ammonium Hydroxide, (see Ammonium Hydroxide) Palladium Suspensions in Hydrochloric Acid (see Hydrochloric Acid) Palmitic Acid Paper Mill Effluent (see Sulfite/ Sulfate Liquors (Pulp Mill)) Para-Dichlorobenzene (see Dichlorobenzene) Peanut Oil Pentabromo Diphenyl Oxide Pentachlorophenol4 Pentanedioic Acid (see Glutaric Acid) Peracetic Acid1,2,3,6 Peracetic Acid Perchloric Acid Perchloric Acid Perchloroethylene Phenol (Carbolic Acid)2 Phenol (Carbolic Acid)2 Phenol (Carbolic Acid)2 Phenol (Carbolic Acid)2 Phenol (Carbolic Acid)2 Phenol Formaldehyde Resin Phenol Sulfonic Acid6 Phenol/Methanol/ Anionic Detergent Phenolic Resin/Phenol2
10 100
100/210 120/250 LS
80/180 100/210 NR
100/210 120/250 NR
65/150 NR
Satd 2 mg/L
50/120 40/100
50/120 40/100
50/120 40/100
50/120 40/100
50/120 40/100
40/100
100
100/210
120/250
50/120 50/120
25/80 50/120
50/120 50/120
NR 50/120
40/100 LS 65/150 40/100 50/120 50/120 50/120 50/120 30/90 20/70 50/120 25/80 LS 25/80
NR
58
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
411 C/F
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 50/120 100/210 105/220 105/220
8084 C/F
Phenolic Resin/Phenol2 Phosphoric Acid Phosphoric Acid Phosphoric Acid (Polyphosphoric Acid) Phosphoric Acid (Superphosphoric Acid 76% P2O5) Phosphoric Acid/Tributyl Phosphate (Vapor Phase, Condensation) Phosphoric Acid with Phosphorous Pentoxide, Hydrochloric Acid and Sulfuric Dioxide Phosphoric Acid, Vapor6 Phosphoric Acid/Gypsum Phosphoric Acid/Sulfuric Acid Phosphoric Acid/Tributyl Phosphate/Hydrofluoric Acid (no condensation of TBP) Phosphoric Acid/Zinc Chloride Phosphoric Acid/Hydrochloric Acid, satd with Cl29,12 Phosphoric/Sulfuric Acid Phosphoric/Sulfuric/ Hydrofluoric1,2 Phosphorous Acid Phosphorous Acid 70%/ Hydrochloric Acid 37%9,15 Phosphorous Acid 70%/ Hydrochloric Acid 37%8,9,15 Phosphorus Oxychloride Phosphorus Trichloride Phthalic Acid4 Picric Acid (Alcoholic)4 Pine Oil Plating Chemicals6 Polyacrylamide Polyacrylic Acid Polyethylene Glycol methyl ether6 Polyethyleneimine Polyphosphoric Acid H3PO4 Polyvinyl Acetate Adhesives
105
100/210
100/210
105/220
100/210
100/210
80/180
85/0.5
50/120
60/140
60/140
50/120
60/140
40/100
88/0.1/0.03 0 - 100/0.5 - 70 15/9 0 - 45/0.5 - 40 0 - 75/1/0 - 3 70 0 - 100/1 - 10 0 - 100/11 - 20 100 100 All 10 100 All All 100 All 115% All
80/180 100/210 100/210 100/210 65/150 80/180 100/210 65/150 NR NR 100/210 NR 90/190 80/180 80/180
80/180 100/210 100/210 100/210 65/150 80/180 100/210 65/150 NR NR 100/210 LS 90/190 80/180 80/180
100/210 100/210 100/210 100/210 65/150 80/180 100/210 80/180 LS LS 100/210 40/100 90/190 80/180 80/180
80/180 100/210 100/210 100/210 65/150 80/180 100/210 65/150 NR NR 100/210 NR 90/190 80/180 80/180
80/180 100/210 100/210 100/210 65/150 80/180 100/210 65/150 NR NR 100/210 NR 90/190 80/180 80/180
80/180
NR NR NR
80/180 80/180
80/180
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
59
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 100 All Satd > 0.5 > 0.5 0 - 50 20/4/1 > 0.5 > 0.5 > 0.5 > 0.5 All 12 0 - 45 2/3/8 oz/gal, 2/2.5/7% 411 C/F 80/180 50/120 100/210 80/180 100/210 80/180 80/180 100/210 100/210 100/210 100/210 80/180 100/210 65/150 65/150 DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 80/180 50/120 120/250 80/180 100/210 80/180 80/180 100/210 100/210 100/210 100/210 80/180 100/210 40/100 40/100 80/180 50/120 120/250 80/180 100/210 65/150 65/150 100/210 100/210 100/210 100/210 80/180 100/210 25/80 25/80 80/180 50/120 100/210 80/180 100/210 80/180 80/180 100/210 100/210 100/210 100/210 80/180 100/210 65/150 65/150 80/180 50/120 120/250 80/180 100/210 65/150 65/150 100/210 100/210 100/210 100/210 80/180 100/210 25/80 25/80 8084 C/F
Polyvinyl Alcohol Polyvinyl Chloride Latex with 35 parts Dioctylphthalate Potassium Aluminum Sulfate Potassium Bicarbonate Potassium Bromide Potassium Carbonate1 Potassium Carbonate/Boric Acid/ Potassium Metavanadate1 Potassium Chloride Potassium Dichromate Potassium Ferricyanide Potassium Ferrocyanide Potassium Fluoride Potassium Gold Cyanide Potassium Hydroxide1,2 Potassium Hydroxide/Potassium Cyanide/Copper Cyanide1 Potassium Hypochlorite, Potassium Hydroxide, Potassium Metasilicate1,2,3 Potassium Iodide Potassium Nitrate Potassium Oxalate Potassium Permanganate Potassium Persulfate Potassium Pyrophosphate Potassium Silicofluoride1 Potassium Sulfate Propane Propanol (n-) Propanol (n-), Fumes, no condensation or coalescence Propionic Acid Propionic Acid Propionyl Chloride Propyl Acetate Propyl Bromide Propyl Chloride Propylene Glycol Propylene Glycol Monomethyl Ether Acetate (DOWANOL PMA)2
80/180 80/180 80/180 80/180 80/180 80/180 80/180 80/180 80/180 80/180 80/180
50/40/10 All > 0.5 All > 0.5 All 60 All > 0.5 100 100 Fumes 0 - 50 100 100 100 100 100 100
50/120 65/150 100/210 65/150 100/210 100/210 55/130 40/100 100/210 60/140 50/120 80/180 80/180 NR NR NR NR NR 100/210
65/150 100/210 65/150 100/210 100/210 65/150 40/100 100/210 60/140 50/120 80/180 80/180 25/80 NR LS LS LS 100/210
65/150 100/210 65/150 100/210 100/210 65/150 40/100 100/210 60/140 50/120 80/180 80/180 40/100 LS 25/80 25/80 25/80 100/210
65/150 100/210 65/150 100/210 100/210 55/130 40/100 100/210 60/140 50/120 80/180 80/180 NR NR NR NR NR 100/210
65/150 100/210 65/150 100/210 100/210 65/150 40/100 100/210 60/140 50/120 80/180 80/180 25/80 NR NR LS LS 100/210
65/150 80/180 65/150 80/180 80/180 55/130 40/100 80/180 60/140 NR 80/180 80/180 NR NR NR NR NR
20
40/100
50/120
50/120
40/100
50/120
40/100
60
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
Concentration %
411 C/F
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F
8084 C/F
Q R S
Propylene Glycol Monomethyl Ether Acetate (DOWANOL PMA)2 Propylene Glycol Monomethyl Ether (see DOWANOL PM) Propylene Glycol/ Ethoxylated Fatty Alcohols/ Diethylene Glycol Monobutyl Ether (DOWANOL DB) Propylene Glycol/ Monoethanolamine Propylene Oxide Propylene Oxide, Fumes, no condensation or coalescence Pulp Paper Mill Blow Down (Noncondensable Gases, see also Blow Down) Pyridine Pyridine Quaternary Amine Salts Quinoline Quinoline Radiation Resistance6 Rayon Spin Bath Rayon Spinning Recovery Boiler Gases (see Flue Gas) Red Liquor Salicylic Acid Salt Brine Scrubbing Low MW Amines with 10% Sulfuric Acid, (see Amine Salts) Sea Water Selenious Acid Silicon Tetrafluoride/Hydrofluoric/ Sulfuric Acid1,2 Silver Nitrate Silver Plating Solution, 4% Silver; 7% Potassium and 5% Sodium Cyanides; 2% Potassium Carbonate1 Sodium Acetate Sodium Alkyd Aryl Sulfonates Sodium Aluminate1 Sodium Benzoate Sodium Bicarbonate
100
NR
LS
20/70
NR
NR
NR
40/100 25/80 NR
45/110 30/90 NR
NR NR NR
NR NR
Fumes
60/140
60/140
60/140
60/140
80/180 120/250
80/180 100/210
80/180 120/250
65/150 80/180
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
61
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 411 C/F DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 8084 C/F
Sodium Bicarbonate/ Sodium Carbonate1 15/20 Sodium Bifluoride1 All Sodium Bisulfate > 0.5 Sodium Bisulfide (Hydrosulfide) All Sodium Bisulfite > 0.5 Sodium Borate > 0.5 Sodium Borohydride SWS (Stabilized Water Solution) All Sodium Bromate > 0.5 Sodium Bromide > 0.5 Sodium Carbonate1 All Sodium Carbonate/ Sodium Bicarbonate1 20/15 Sodium Chlorate, Stable > 0.5 Sodium Chlorate/ Phosphoric Acid6 1 - 20/1 - 20 Sodium Chlorate/ Sulfuric Acid6 1 - 20/1 - 20 Sodium Chlorate/Sodium Chloride 34/20 Sodium Chloride > 0.5 Sodium Chloride (see Salt Brine) Satd Sodium Chloride with Chlorine, pH > 9 (see Chlorinated Brine) Sodium Chloride with Chlorine, pH 2.5 - 96 Sodium Chloride, pH < 2.5, Cl2 Satd (see Chlorinated Brine) Sodium Chloride/Ethyl Vanillin 0.1 - 25/1 Sodium Chloride/ 0.5 - 26/0.1 - 20/ Magnesium Oxide/Lime 0.1 - 10 Sodium Chloride/Sodium Hydroxide1,2 0.5 - 10/0.1 - 2 Sodium Chloride/Sodium Chlorate 20/34 Sodium Chlorite, pH < 6, (see Chlorine Dioxide) Sodium Chlorite, pH > 65 All Sodium Chlorite/Sodium Hypochlorite pH>111,2,3 0.1 - 25/0.1 - 15 Sodium Chromate > 0.5 Sodium Cyanide > 0.5 Sodium Dichromate > 0.5
80/180 50/120 100/210 80/180 100/210 100/210 40/100 100/210 100/210 80/180 80/180 100/210
80/180 50/120 100/210 80/180 100/210 100/210 40/100 100/210 100/210 80/180 80/180 100/210
LS
LS
LS
LS
LS
LS
50/120 100/210 65/150 100/210 100/210 40/100 100/210 100/210 80/180 100/210 100/210 65/150 100/210 80/180 50/120
62
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
Concentration %
411 C/F
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F
8084 C/F
Sodium Dimethyldithiocarbamate/ Disodium Ethylene Bisdithiocarbamate Sodium Diphosphate Sodium Dodecylbenzene Sulfonate Sodium Ferricyanide Sodium Ferrocyanide Sodium Fluoride Sodium Fluoroborate1 Sodium Fluorosilicate1 Sodium Gluconate Sodium Glycolate Sodium Hexametaphosphate Sodium Hydrosulfide (Sodium Bisulfide) Sodium Hydroxide1,2 Sodium Hydroxide/ Sodium Bisulfite1,2 Sodium Hydroxide/Sodium Chloride/Sodium Sulfate/ Sodium Hypochlorite (active Chlorine)1,2,3,5 Sodium Hydroxide/Organics (within solubility limits, i.e., no phase separation or coalescence) Sodium Hydroxide/Sodium Hypochlorite1,2 Sodium Hypochlorite, pH>11 (active Chlorine)1,2,3,5 Sodium Hypochlorite, pH>11 (active Chlorine)1,2,3,5 Sodium Hypochlorite, pH>11 (active Chlorine)1,2,3,5 Sodium Lauryl Sulfate Sodium Metabisulfite Sodium Methyldithiocarbamate Sodium Monophosphate Sodium Myristyl Sulfate Sodium Nitrate Sodium Nitrite Sodium Oxalate Sodium Perchlorate Sodium Persulfate
0.1 - 15/0.1 - 15 > 0.5 All > 0.5 > 0.5 All > 0.5 All > 0.5 > 0.5 All All All All
40/100 100/210 70/160 100/210 100/210 80/180 95/200 50/120 80/180 80/180 80/180 80/180 80/180 80/180
40/100 100/210 70/160 100/210 100/210 80/180 95/200 50/120 95/200 95/20 80/180 80/180 65/150 65/150
50/120 100/210 70/160 100/210 100/210 80/180 95/200 50/120 100/210 100/210 80/180 80/180 40/100 40/100
40/100 100/210 70/160 100/210 100/210 80/180 50/120 95/200 80/180 80/180 80/180 80/180 80/180
50/120 100/210 70/160 100/210 100/210 80/180 50/120 100/210 95/200 80/180 80/180 65/150 65/150
40/100 80/180
80/180
65/150
40/100
80/180
65/150
8/trace 0 - 20/0 - 0.1 0 - 18 21 24 All > 0.5 All > 0.5 All > 0.5 > 0.5 > 0.5 60 All
65/150
80/180 40/100
50/120
80/180 40/100
65/150
65/150
LS 70/160 100/210 80/180 100/210 70/160 100/210 100/210 100/210 40/100 100/210
LS 70/160 100/210 80/180 100/210 70/160 100/210 100/210 100/210 40/100 100/210
LS 70/160 100/210 80/180 100/210 70/160 100/210 100/210 100/210 40/100 100/210
LS 70/160 100/210 80/180 100/210 70/160 100/210 100/210 100/210 40/100 100/210
LS 70/160 100/210 80/180 100/210 70/160 100/210 100/210 100/210 40/100 100/210
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
63
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 411 C/F DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 8084 C/F
Sodium Phosphate, mono-, di-, tribasic Sodium Polyacrylate, pH 9 - 10.5 Sodium Sarcosinate Sodium Silicate Sodium Sulfate Sodium Sulfate/Sodium Sulfite Sodium Sulfhydrate (see Sodium Hydrosulfide) Sodium Sulfide Sodium Sulfite Sodium Sulphite/Sodium Hydroxide/Toluene Sodium Tartrate Sodium Tetraborate Sodium Thiocyanate Sodium Thiosulfate Sodium Tripolyphosphate Sodium Xylene Sulfonate Solder Plate (see Plating Chemicals) Solvent Extraction Solutions: 3% Isodecanol, 6% Alamine* 336, 91% Kerosene Solvent Extraction Solutions: 4% Trioctylphosphine Oxide (TOPO), 4% Di 2-Ethylhexyl Phosphoric Acid (DEHPA), 92% Kerosene Sorbitol Solutions Sour Crude Oil (see Crude Oil) Soy (Soya) Sauce Soya Oil Spearmint Oil Stannic Chloride Stannous Chloride Steam, Dry, No Condensation Steam, Wet, Condensation Stearic Acid Styrene Styrene Acrylic Emulsion Styrene-Butadiene Latex Succinonitrile, Aqueous Sugar/Sucrose Sugar Beet, Liquor
80/180
> 0.5 > 0.5 22/10/5 > 0.5 All All All > 0.5 All
80/180
80/180
80/180
80/180
80/180
65/150
All
80/180 70/160 70/160 100/210 40/100 100/210 100/210 100/210 80/180 100/210 NR 50/120 60/140 25/80 100/210 80/180
80/180 70/160 70/160 100/210 40/100 100/210 100/210 105/220 80/180 100/210 40/100 50/120 60/140 40/100 100/210 80/180
80/180 80/180
80/180 70/160
80/180 70/160
100/210 100/210 100/210 105/220 80/180 100/210 50/120 50/120 60/140 40/100
100/210 100/210 100/210 105/220 80/180 100/210 40/100 50/120 60/140 40/100
64
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
Concentration % All 0.5 - 10 11 - 15 16 - 25 0.5 - 25/0.5 - 30/ 0.5 - 10 > 0.5 All
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 80/180 100/210 80/180 65/150 65/150 100/210 100/210
8084 C/F
Sugar Cane, Liquor & Sweetwater Sulfamic Acid Sulfamic Acid Sulfamic Acid Sulfamic/Boric/ Glycolic Acid Sulfanilic Acid (meta) Sulfanilic Acid (para)4 Sulfate Process Noncondensable Gases (see Flue Gas) Sulfated Detergents (see Sulfonated Detergents) Sulfated Tall Oil Fatty Acid (see Tall Oil) Sulfides Scrubbing with Caustic (see Sodium Hydroxide) Sulfite/Sulfate Liquors (Pulp Mill) Sulfonated Detergents Sulfur Chloride Sulfur Chloride Sulfur Dioxide (see Flue Gas) Sulfur Trioxide, Dry16 Sulfur Trioxide, Wet (see Sulfuric Acid) Sulfur, Molten (Dry)16 Sulfur, Wettable, Fungicide4 Sulfuric/Nitric/ Phosphoric Acids Sulfuric Acid Sulfuric Acid Sulfuric Acid Sulfuric Acid15 Sulfuric Acid2,15 Sulfuric Acid15 Sulfuric Acid/ Ammonium Bifluoride1 Sulfuric Acid/Copper Sulfate Sulfuric Acid/Copper Sulfate/ Sodium Persulfate/EDTA
80/180 80/180
1 - 70
80/180 65/150 100/210 100/210 80/180 40/100 40/100 NR 40/100 100/210 55/130
120/250 80/180 65/150 105/220 100/210 80/180 50/120 40/100 NR 50/120 100/210 55/130
150/300 80/180 65/150 105/220 100/210 80/180 80/180 50/120 LS 65/150 100/210 55/130
80/180 65/150 100/210 100/210 80/180 40/100 40/100 NR 40/100 100/210 55/130
120/250 80/180 65/150 105/220 100/210 80/180 50/120 40/100 LS 50/120 100/210 55/130
80/180
55/130
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
65
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 60/20 25/10 10/10 1 - 20/1 - 10 411 C/F 40/100 40/100 40/100 65/150 DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 40/100 45/110 50/120 65/150 50/120 50/120 65/150 65/150 40/100 40/100 40/100 65/150 40/100 40/100 40/100 65/150 8084 C/F
Sulfuric Acid/Hydriodic Acid Sulfuric Acid/ Hydrofluoric Acid1,2 Sulfuric Acid/ Hydrofluoric Acid1,2 Sulfuric Acid/ Hydrogen Peroxide3 Sulfuric Acid/Hydrogen Peroxide/ Ammonium Sulfate/ Copper Sulfate3 Sulfuric Acid/Hydrogen Sulfide Sulfuric Acid/Methanol Sulfuric Acid/Nitric Acid Sulfuric Acid/Phosphoric Acid Sulfuric Acid/Sodium Chromate6 Sulfuric Acid/Sodium Dichromate, (see Sulfuric Acid/ Chromic Acid Mixture) Sulfuric Acid/ Hydrochloric Acid8,9,13 Sulfuric Acid/ Hydrochloric Acid9,12 Sulfuric Acid/ Hydrofluoric Acid1,2 Sulfuric Acid/Hydrofluoric Acid Sulfuric Acid/Inorganic Salts Sulfuric Acid/Inorganic Salts Sulfuric Acid/Sulfate Salts, Max. Total Concentration 80%, (see Sulfuric Acid) Sulfuric Acid/Chromic Acid Mixture (Maximum Total Concentration 10%) Sulfuric/Hydrochloric/ Hydrofluoric/Phosphoric Acids/ Chlorinated Solvents Sulfuric/Hydrofluosilicic Acids/MIBK1,2 Sulfuric/Lactic Acids/ Sodium Sulfate Sulfurous Acid Superphosphoric Acid (76% P2O5) Surfactant, Anionic
50/120
65/150
65/150
50/120
65/150
50/120
NR
66
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
Concentration %
411 C/F
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F
8084 C/F
Surfactant (see under chemical name) Tall Oil (Storage) Tall Oil Reactor6 Tallow/Sulfuric Acid Tannic Acid Tap Water, Hard2 Tap Water, Soft2 Tartaric Acid t-Butyl Methyl Ether (MTBE) t-Butyl Methyl Ether (MTBE) Tetrabutyltin Tetrachloroethane Tetrachloroethylene (Perchloroethylene) Tetrachloropyridine Tetrahydrofuran Tetrahydrofuran Tetrahydrofuran, Fumes, no condensation or coalescence Tetramethyl Ammonium Hydroxide1 Tetra-n-Butylammonium Hydroxide1,2 Tetra-n-Butylphosphonium Hydroxide1,2 Tetrapotassium Pyrophospate Tetrasodium Ethylenediaminetetraacetic Acid (Tetrasodium Salt of EDTA) Textone Liquid Product (50% Aqueous Solution of Sodium Chlorite, see there) Thermal Oxidizer (HCl Absorption) (see Flue Gas, Wet) Thioglycolic Acid (see Mercaptoacetic Acid) Thionyl Chloride Thiourea Tin Fluoborate Plating Bath: 18% Stannous Fluoborate, 7% Tin, 9% Fluoboric Acid, 2% Boric Acid1 Titanium Dioxide
100 99/1 > 0.5 All All > 0.5 20 100 100 100 100 100 0-5 10-100 Fumes 0 - 10 40 40 0 - 60
95/200 100/210 80/180 100/210 100/210 80/180 100/210 40/100 NR 50/120 40/100 25/80 25/80 40/100 NR
105/220 105/220 80/180 100/210 100/210 80/180 100/210 50/120 25/80 50/120 50/120 40/100 50/120 40/100 NR
105/220 105/220 100/210 100/210 80/180 100/210 50/120 25/80 50/120 55/130 50/120 50/120 50/120 LS 80/180
95/200 100/210 100/210 100/210 80/180 100/210 40/100 NR 50/120 40/100 25/80 25/80 40/100 NR 80/180 50/120 40/100 40/100 55/130
105/220 105/220 100/210 100/210 80/180 100/210 50/120 25/80 50/120 50/120 50/120 50/120 50/120 NR 80/180 40/100 40/100 40/100 65/150 65/150 80/180 80/180 65/150 30/80 NR NR NR NR NR
65/150
55/130
All
80/180
80/180
65/150
80/180
65/150
80/180
100 0 - 50
NR 65/150
NR 65/150
LS 65/150
NR 65/150
NR 65/150
NR 65/150
All
100/210 80/180
100/210 80/180
100/210 80/180
100/210 80/180
100/210 80/180
80/180 80/180
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
67
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % 0 - 30/30 All 100 100 > 0.5 Fumes 100 All 100 100 100 411 C/F 100/210 65/150 100/210 25/80 80/180 DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 100/210 80/180 100/210 40/100 95/200 65/150 NR 90/190 65/150 120/250 60/140 100/210 80/180 100/210 50/120 100/210 80/180 20/70 65/150 150/300 60/140 110/230 50/120 100/210 65/150 100/210 25/80 95/200 80/180 NR 100/210 80/180 100/210 40/100 100/210 80/180 NR 65/150 120/250 60/140 8084 C/F 80/180
Titanium Dioxide/Sulfuric Acid Titanium Tetrachloride Tobias Acid (2-Naphthylamine1-Sulfonic)6 Toluene Toluene Sulfonic Acid6 Toluene, Fumes, no condensation or coalescence Toluidine (o-, p-, m-) Tomato Sauce Transformer Oils (Ester types) Transformer Oils (Silicone and Mineral Oils)16 Tributyl Phosphate Trichloroacetic Acid (see Chloroacetic Acid) Trichloroethane Trichloroethylene Trichloromonofluoromethane (see Freon 11) Tricresyl Phosphate Triethanolamine Triethylamine Triethylamine/Triethylamine Hydrochloride/ Hydrochloric Acid9 Triethylene Glycol (see Ethylene Glycol) Trifluoroacetic Acid (see Chloroacetic Acid) Trimethyl Ammonium Chloride (Trimethylamine HCl, TMA-HCl) Trimethyl Benzene Trimethylamine Trimethylamine Trimethylamine, Fumes, no condensation or coalescence Trimethylene Chlorobromide Trioctyl Phosphine Oxide/ Di 2-Ethylhexyl Phosphoric Acid (DEHPA)/Kerosene Trioctylphosphate Tripropylene Glycol (see Ethylene Glycol)
NR
NR
40/100
100 100
40/100 NR
50/120 NR
50/120 LS
40/100 NR
50/120 NR
NR NR
NR NR
50/20/5
50/120
50/120
50/120
50/120
50/120
NR
40/100 NR NR
NR
25/80
NR
4/4/92 100
80/180 70/160
80/180 70/160
80/180 80/180
80/180 70/160
80/180 70/160
40/100
68
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Chemical Environment
Concentration % Satd
DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 120/250 120/250 100/210 120/250
Trisodium Phosphate TRITON X-100 Wetting Agent (see Ethylene Glycol) Turpentine Tween Surfactant (see Ethylene Glycol) Ultrawet* Surfactant (see Sodium Dodecylbenzenesulfonate) Uran Fertilizer Urea Ammonium Nitrate Composition: 44.3% Ammonium Nitrate, 35.4% Urea, 20.3% Water Uranium Extraction (see Kerosene) Urea Urea Formaldehyde Resin Urea/Ammonium Nitrate/Water Urine (see Urea) Vanillin Black Liquor VERSENE 100 Chelating Agent (see also Tetrasodium Ethylenediaminetetraacetic Acid) VERSENE Chelating Agents (others) Vetran 6501 (16.7 Vol. % VERSENE 100 Aqueous Solution, pH 9.5 - 10) Vidden** D Fumigant (see Dichloropropane) Vinegar Vinyl Acetate Vinyl Acetate Vinyl Chloride Vinyl Chloride Fumes, no condensation Vinyltoluene VORANOL** P-400 Polyol (see Ethylene Glycol) Water Deionized2 Water Vapor, no condensation (see Flue Gas, Dry)
* Mach I ** Dow Chemical
100
65/150
100/210
100/210
65/150
100/210
40/100
All All
80/180 50/120
80/180 50/120
65/150 50/120
80/180 50/120
65/150 50/120
80/180
80/180
80/180
65/150
80/180
65/150
80/180
100/210 40/100 NR NR
100/210 40/100 NR NR
65/150 NR NR NR
25/80
50/120
NR
100
80/180
80/180
80/180
80/180
80/180
80/180
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
69
COMPOSITE POLYMERS
C H E M I C A L R E S I S TA N C E G U I D E
Chemical Resistance Table: Maximum Service Temperatures for DERAKANE and DERAKANE MOMENTUM Resins continued
Chemical Environment Concentration % Satd 100 All 100 100 100 All All 100 Fumes 50/20/20/10 Satd NR 100/210 411 C/F 80/180 80/180 80/180 80/180 100/210 80/180 65/150 80/180 25/80 DERAKANE or DERAKANE MOMENTUM Resin 441 470 510A/C 510N C/F C/F C/F C/F 80/180 80/180 80/180 80/180 100/210 80/180 65/150 80/180 40/100 65/150 NR 120/250 80/180 80/180 80/180 80/180 100/210 80/180 40/100 50/120 80/180 LS 120/250 80/180 80/180 80/180 80/180 100/210 80/180 80/180 25/80 80/180 NR 100/210 80/180 80/180 80/180 80/180 100/210 80/180 80/180 50/120 80/180 NR 120/250 NR 80/180 8084 C/F 80/180 80/180 80/180 80/180 80/180 80/180 80/180 NR
X Z
Water Vapor, Wet2 Water, Distilled2 Water, Phenol (see Phenol) Water, Sea, Desalination Water, Steam Condensate2 Water, Tap, Hard2 Water, Tap, Soft2 Whey White Liquor (Pulp Mill)1,2 Xylene Xylene, Fumes, No Condensation or Coalescence Xylene/Methyl Ethyl Ketone/ Butyl Acetate/Methyl Acetate Zinc Chloride Zinc Cyanide Plating Bath, 9% Zinc and 4% Sodium Cyanides, 9% Sodium Hydroxide1,2 Zinc Electrolyte (Zinc Sulfate, 35 g/L Sulfuric Acid), see Sulfuric Acid Zinc Fluoborate Plating Bath, 49% Zinc Fluoborate; 5% Ammonium Chloride, 6% Ammonium Fluoborate1 Zinc Nitrate Zinc Phosphate (slurry) Zinc Sulfate
80/180
80/180
40/100
80/180
80/180
80/180
70
For notes in English, see page 6; French, see page 14, German, see page 22; Spanish, see page 30.
Notes
71
COMPOSITE POLYMERS
C H E M I C A L
Notes
R E S I S TA N C E
G U I D E
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COMPOSITE POLYMERS
Customer Service North America: 1.614.790.4191 Europe: +34 93 206 5120 Latin America: +55 11 4136 1900 Asia: +86 512 5787 6290
Registered Trademark, Ashland Inc. In Canada, Ashland Canada, Inc. A Division of Ashland Inc. Registered user of Trademark
Trademark, Ashland Inc. Service mark Ashland Inc. Copyright 2005, Ashland Inc.
SM
TM
Printed in U.S.A
Bulletin #2899