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A.

SOAP
a.DEFINITION OF SOAP

 Soap is the salt formed when a fatty acid is neutralized by an alkali.

 Soaps are made from natural raw materials such as animals fats or plants
oil.

B.STRUCTURE OF SOAP(HYDROPHOBIC,HYDROPHILIC
PART)
Preparation of soap saponification
1.Soap is a cleansing agents produced by the reaction between sodium hydroxide and
potassium

hydroxide with animal fats or vegetable oils. This reaction is known as saponification.

2.Fats and vegetable oils are large, naturally occurring ester molecules. When fats or oils are
boiled

with concentrated alkalis, such as sodium hydroxide, saponification occurs and the ester

molecules are broken down into soap and glycerol.

Fats or vegetable oils + concentrated alkalis

soap +glycerol

3.Saponification is the alkaline hydrolysis of ester using alkali solutions. From the chemist
aspect,soaps are sodium salts or potassium salts of long chain carboxylic acids (with 12 to 18
carbonatoms per molecule).

4.Some examples of soaps are shown below.

a)Sodium palmitate, C15H31COONa


b)Sodium oleate, C17H33COONa
c)Sodium stearate, C17H35COONa

Additives such as perfume, colouring matter and sometimes antiseptics are added to soaps to

enhance their marketability.

5.Glyceryl tristearates are naturally occurring esters commonly found in animal fats and
vegetableoils. When the ester is boiled with concentrated sodium hydroxide solution,
saponification(alkaline hydrolysis) occurs and mixture of sodium stearate (soap) and glycerol is
obtained

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