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13 pages, 3941 KiB  
Article
Effects of Low Temperature, Freeze–Thaw Cycles, and Healing Conditions on Viability of Non-Ureolytic Bacteria in Biological Self-Healing Concrete
by Augusta Ivaškė, Ronaldas Jakubovskis, Renata Boris and Jaunius Urbonavičius
Materials 2024, 17(23), 5797; https://doi.org/10.3390/ma17235797 - 26 Nov 2024
Abstract
The capacity of biological self-healing concrete (BSHC) to repair cracks relies on the sustained viability and metabolic function of bacteria embedded within the concrete. BSHC structures face significant risk in cold climates due to low temperatures and freeze–thaw (FT) cycles, during which freezing [...] Read more.
The capacity of biological self-healing concrete (BSHC) to repair cracks relies on the sustained viability and metabolic function of bacteria embedded within the concrete. BSHC structures face significant risk in cold climates due to low temperatures and freeze–thaw (FT) cycles, during which freezing water can generate internal pressure that damages bacterial cells and diminishes their activity. A special feature of this study is the incorporation of bacterial spores within expanded clay aggregates, tested under varying environmental conditions. The viability of bacterial spores was measured under cold and freeze–thaw cycles by counting colony-forming units, and a specific methodology was developed to assess the efficiency of self-healing under rain-simulated conditions. It was demonstrated that bacteria embedded in concrete could endure fluctuations in low temperatures and freeze–thaw cycles, compromising approximately 50% of viable spores. Also, it was found that water immersion during concrete curing can trigger early germination, decreasing viable spore counts by nearly tenfold. Ultimately, it was demonstrated that the healing of cracks in BSHC components is influenced by the conditions under which the specimens are incubated. The results suggest that BSHC can be employed in cold climate areas, given that suitable curing conditions and adequate bacterial protection within the concrete are ensured. Full article
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Figure 1

Figure 1
<p>Preparation of structural biological concrete specimens: (<b>A</b>) placement of reinforcement; (<b>B</b>) dry components in a rotating pan mixer; (<b>C</b>) specimens after casting.</p>
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<p>Preparation of BSHC samples: (<b>A</b>) specimens of Test Series 1; (<b>B</b>) specimens of Test Series 2.</p>
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<p>Evaluation of healing: (<b>A</b>) crack measurement scheme; (<b>B</b>) healing conditions.</p>
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<p>Bacterial viability tests: (<b>A</b>) specimens used for FT and temperature fluctuation tests; (<b>B</b>) schematic illustration of viability tests.</p>
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<p>Survival of bacteria in concrete from Test Series 1: (<b>A</b>) changes in CFU due to low-temperature cycles; (<b>B</b>) changes in CFU due to FT cycles. Continuous lines represent the average values of the calculated CFU/g, whereas the shaded areas show the 95% confidence intervals.</p>
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<p>Bacterial viability in early-age concrete. Solid lines depict the mean values of the determined CFU/g, while the shaded regions indicate the 95% confidence intervals.</p>
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<p>Variation in the healing ratio over time: (<b>A</b>) results of Test Series 1; (<b>B</b>) results of Test Series 2.</p>
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51 pages, 6848 KiB  
Review
Potential Reuse of Ladle Furnace Slag as Cementitious Material: A Literature Review of Generation, Characterization, and Processing Methods
by Noureddine Ouffa, Mostafa Benzaazoua, Romain Trauchessec, Tikou Belem, Yassine Taha and Cécile Diliberto
Minerals 2024, 14(12), 1204; https://doi.org/10.3390/min14121204 - 26 Nov 2024
Abstract
Ladle furnace slag (LFS), a by-product of steel refining, shows a promising reuse pathway as an alternative additive or substitute for Portland cement due to its high alkalinity and similar chemical composition to clinkers. However, LFS is often stored in large, open surface [...] Read more.
Ladle furnace slag (LFS), a by-product of steel refining, shows a promising reuse pathway as an alternative additive or substitute for Portland cement due to its high alkalinity and similar chemical composition to clinkers. However, LFS is often stored in large, open surface areas, leading to many environmental issues. To tackle waste management challenges, LFS can be recycled as supplementary cementitious material (SCM) in many cementitious composites. However, LFS contains some mineral phases that hinder its reactivity (dicalcium silicate (γ-C2S)) and pose long-term durability issues in the cured cemented final product (free lime (f-CaO) and free magnesia (f-MgO)). Therefore, LFS needs to be adequately treated to enhance its reactivity and ensure long-term durability in the structures of the cementitious materials. This literature review assesses possible LFS treatments to enhance its suitability for valorization. Traditional reviews are often multidisciplinary and explore all types of iron and steel slags, sometimes including the recycling of LFS in the steel industry. As the reuse of industrial by-products requires a knowledge of their characteristics, this paper focuses first on LFS characterization, then on the obstacles to its use, and finally compiles an exhaustive inventory of previously investigated treatments. The main parameters for treatment evaluation are the mineralogical composition of treated LFS and the unconfined compressive strength (UCS) of the final geo-composite in the short and long term. This review indicates that the treatment of LFS using rapid air/water quenching at the end-of-refining process is most appropriate, allowing a nearly amorphous slag to be obtained, which is therefore suitable for use as a SCM. Moreover, the open-air watering treatment leads to an optimal content of treated LFS. Recycling LFS in this manner can reduce OPC consumption, solve the problem of limited availability of blast furnace slag (GGBFS) by partially replacing this material, conserve natural resources, and reduce the carbon footprint of cementitious material operations. Full article
(This article belongs to the Special Issue Metallurgy Waste Used for Backfilling Materials)
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Figure 1
<p>Summary diagram illustrating the iron slag typologies.</p>
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<p>Principle of steel refining in a ladle furnace, modified from Yuasa et al. [<a href="#B53-minerals-14-01204" class="html-bibr">53</a>].</p>
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<p>Secondary electron microscope (SEM) images with different scales of ladle furnace slag (LFS) (in polished section) from ArcelorMittal operation in Contrecoeur, Quebec, Canada.</p>
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<p>Visual appearance of an as-received ladle furnace slag (LFS) from ArcelorMittal’s operations in Contrecoeur, Quebec, Canada (with an index finger as a means of comparison).</p>
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<p>Average chemical composition of ladle furnace slag (LFS) with variation margins of main oxides; data from Table 6.</p>
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<p>Representation of ladle furnace slag (LFS) samples in a ternary diagram.</p>
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<p>X-ray diffractogram of a ground air-cooled ladle furnace slag (LFS) from ArcelorMittal operation at Contrecœur, Quebec, Canada (from the authors’ works).</p>
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<p>Proposed classification of reported ladle furnace slag (LFS) treatments.</p>
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<p>Classification of ladle furnace slag (LFS).</p>
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19 pages, 1387 KiB  
Article
An Assessment of the Construction and Hydrographic Conditions of Bukhtarma and Ust-Kamenogorsk Reservoirs in the East Kazakhstan Region for 2017–2021
by Nazgul Zhensikbayeva, Kuat Saparov, Nazym Kabdrakhmanova, Emin Atasoy, Aigul Yeginbayeva, Kamila Abzeleeva, Serik Bakin, Valeryi Sedelev and Nazerke Amangeldy
Sustainability 2024, 16(23), 10348; https://doi.org/10.3390/su162310348 - 26 Nov 2024
Abstract
The article defines the morphometric, hydrochemical, and hydrobiological parameters of the Ust-Kamenogorsk reservoir, located on the territory of Ablaketka and the Bukhtarma reservoir, formed in the zone of narrowing of the mountain valley (1960), 12 km below the confluence of the Bukhtarma River [...] Read more.
The article defines the morphometric, hydrochemical, and hydrobiological parameters of the Ust-Kamenogorsk reservoir, located on the territory of Ablaketka and the Bukhtarma reservoir, formed in the zone of narrowing of the mountain valley (1960), 12 km below the confluence of the Bukhtarma River with the Irtysh River. When determining deviations in indicators of the reservoirs, data from gauging stations have been taken into account. The purpose of the article is to conduct a comprehensive assessment of the current state of two large reservoirs in the East Kazakhstan region during the specified time period. The novelty of this topic lies in its comprehensive approach to assessing various aspects of the reservoirs’ condition in a specific region over a defined period. This approach enables the identification of current trends and issues and facilitates the proposal of practical measures to address them and enhance water resource management. As a result of this research work, after analyzing changes in indicators, the condition of the reservoirs was determined. During the research work, according to the results of hydrochemical studies, the Bukhtarma reservoir is favorable for the habitat of aquatic organisms, and in the Ust-Kamenogorsk reservoir, a positive change in hydrochemical parameters has been noted compared with 2020. In addition, after analyzing the research indicators, it was proposed to form specially protected areas in the Bukhtarma reservoir, suitable for use in connection with the distribution of valuable fish listed in the Red Book of the Republic of Kazakhstan. When demonstrating the location of gauging stations, methods of remote sensing of the earth and the method of geoinformation mapping were used. Full article
(This article belongs to the Special Issue Hydrosystems Engineering and Water Resource Management)
16 pages, 2870 KiB  
Article
Characteristics of Pervious Concrete with Activated-Sludge Biological Fermentation
by Yongsheng Zhang, Xuechen Jia, Bingqi Li, Weilong Zhao, Wenyan Pan, Jianfei Liu and Pengfei Yuan
Appl. Sci. 2024, 14(23), 10988; https://doi.org/10.3390/app142310988 - 26 Nov 2024
Abstract
This study investigates the performance of sludge-added pervious concrete (SPC) at different curing temperatures by replacing some of the cement with activated sludge (AS). The results reveal that the incorporation of AS into pervious concrete had a favorable impact. At a curing temperature [...] Read more.
This study investigates the performance of sludge-added pervious concrete (SPC) at different curing temperatures by replacing some of the cement with activated sludge (AS). The results reveal that the incorporation of AS into pervious concrete had a favorable impact. At a curing temperature of 30 °C, the 28-day compressive strength and specific surface area reached 20.8 MPa and 9.14 m2/g, respectively, representing a 60% and 98.7% increase, in comparison to conventional concrete. Furthermore, the addition of AS to the concrete results in a notable reduction in the concentration of chemical oxygen demand (COD) in surface runoff water. The maximum rate of COD removal observed was 55.6%. A mechanism study revealed that the strength of concrete increased due to the reaction between reactive SiO2 in AS and CaO in the aggregate. At a temperature of 30 °C, the microorganisms in the activated sludge fermentation process exhibit a higher production rate of fermentation gas, resulting in a greater escape of gas and an increase in the number of micropores in the permeable concrete. This leads to an enhanced specific surface area, which in turn exhibits a superior adsorption effect on COD. Full article
19 pages, 1305 KiB  
Article
From an Ideal Village to a Cultural Landscape: Rediscovering People’s Commune Heritage
by Fei Yu, Yue Yu, Rui Wang and Chaoran Shen
Land 2024, 13(12), 2017; https://doi.org/10.3390/land13122017 - 26 Nov 2024
Abstract
As an important ideal social practice in world history, the people’s commune system and its organized architectural activities took the first step in promoting rural modernization in modern China and had a significant impact on the built environment of urban and rural areas. [...] Read more.
As an important ideal social practice in world history, the people’s commune system and its organized architectural activities took the first step in promoting rural modernization in modern China and had a significant impact on the built environment of urban and rural areas. This study aims to discuss how to view the legacy of rural people’s communes in service of contemporary society. Taking the Weixing Commune, which was the earliest established commune in China in 1958, as an example, through a comparative study of relevant planning and construction archives and the literature, combined with onsite investigations and through the perspective of the cultural landscape, this study delves into the history of local rural construction and sorts out the types, specific compositions, and value elements of the commune’s remains from four dimensions: environment, industry, architecture, and memory. The heritage of the people’s commune is unique. It was a comprehensive transformation of land to farmland, water conservancy, and other natural environmental patterns carried out by residents and related professionals to realize the ideal life of socialism and ultimately resulted in the shaping of a unique type of cultural landscape, presenting the coexistence of political landscapes that hold ideals and vernacular landscapes that carry life. Full article
25 pages, 2590 KiB  
Article
Predictive Modeling of Water Level in the San Juan River Using Hybrid Neural Networks Integrated with Kalman Smoothing Methods
by Jackson B. Renteria-Mena and Eduardo Giraldo
Information 2024, 15(12), 754; https://doi.org/10.3390/info15120754 - 26 Nov 2024
Abstract
This study presents an innovative approach to predicting the water level in the San Juan River, Chocó, Colombia, by implementing two hybrid models: nonlinear auto-regressive with exogenous inputs (NARX) and long short-term memory (LSTM). These models combine artificial neural networks with smoothing techniques, [...] Read more.
This study presents an innovative approach to predicting the water level in the San Juan River, Chocó, Colombia, by implementing two hybrid models: nonlinear auto-regressive with exogenous inputs (NARX) and long short-term memory (LSTM). These models combine artificial neural networks with smoothing techniques, including the exponential, Savitzky–Golay, and Rauch–Tung–Striebel (RTS) smoothing filters, with the aim of improving the accuracy of hydrological predictions. Given the high rainfall in the region, the San Juan River experiences significant fluctuations in its water levels, which presents a challenge for accurate prediction. The models were trained using historical data, and various smoothing techniques were applied to optimize data quality and reduce noise. The effectiveness of the models was evaluated using standard regression metrics, such as Nash–Sutcliffe efficiency (NSE), mean square error (MSE), and mean absolute error (MAE), in addition to Kling–Gupta efficiency (KGE). The results show that the combination of neural networks with smoothing filters, especially the RTS filter and smoothed Kalman filter, provided the most accurate predictions, outperforming traditional methods. This research has important implications for water resource management and flood prevention in vulnerable areas such as Chocó. The implementation of these hybrid models will allow local authorities to anticipate changes in water levels and plan preventive measures more effectively, thus reducing the risk of damage from extreme events. In summary, this study establishes a solid foundation for future research in water level prediction, highlighting the importance of integrating advanced technologies in water resources management. Full article
(This article belongs to the Special Issue Real-World Applications of Machine Learning Techniques)
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Graphical abstract

Graphical abstract
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<p>Geographical location of the San Juan River and the hydrological stations.</p>
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<p>NARX-based neural network structure.</p>
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<p>Measurements of the level data samples at the two hydrological stations.</p>
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<p>Measurements of the flow data samples at the two hydrological stations.</p>
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<p>Measurements of the precipitation data samples at the two hydrological stations.</p>
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<p>NARX-EnKF model validation: (<b>a</b>) NARX-EnKF Feedforward model response; (<b>b</b>) NARXEnKF model performance response.</p>
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<p>NARX-EnKF model validation: (<b>a</b>) NARX-EnKF visual representation of the model fitted to the data; (<b>b</b>) NARX-EnKF response train state.</p>
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<p>Short-term estimation response of the two water level outputs of the NARX model for the hydrological stations. Y-Real corresponds to the real data of the study sample, and Y-Estim NARX corresponds to the estimation of this real data by the NARX model. (<b>a</b>) Short-term estimation of the water level at Tadó at hydrological station 1 using a NARX model. (<b>b</b>) Short-term estimation of the water level at Santa Rita Iró at hydrological station 2 using a NARX model.</p>
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<p>The exponential smoothing method applied to two water level outputs shows how the predicted values of both outputs are smoothed and adjusted. In this case, the plot presents the observed water level variations together with their corresponding smoothed values, eliminating minor fluctuations or noise. This allows for the clear visualization of the overall water level trend at both outlets, facilitating the prediction and analysis of patterns over time, which is useful for identifying potential flooding or significant changes in levels. (<b>a</b>) Short-term estimation of the water level at Tadó at hydrological station 1 using a NARX model with the exponential Kalman smoothing technique. (<b>b</b>) Short-term estimation of the water level at Santa Rita Iró at hydrological station 2 using a NARX model with the exponential Kalman smoothing technique.</p>
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<p>The Savitzky–Golay smoothing filter (applied to two water level outputs) shows how the predicted values of both outputs are smoothed and adjusted. This case indicates how the filter reduces noise in both time series without significantly altering key features such as peaks or abrupt transitions. The smoothed lines allow for the underlying trends to be identified more clearly, making it easier to detect important patterns and behaviors, such as gradual changes or sharp increases in water level. This approach is especially useful when you need to analyze the evolution of data with natural fluctuations, but these are affected by noise. (<b>a</b>) Short-term estimation of the water level at Tadó at hydrological station 1 using a NARX model with the Savitzky–Golay smoothing filter technique. (<b>b</b>) Short-term estimation of the water level at Santa Rita Iró at hydrological station 2 using a NARX model with the Savitzky–Golay smoothing filter technique.</p>
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<p>The smoothed Kalman filter using the Rauch–Tung–Striebel (RTS) algorithm for the two water level outputs provides a clear view of the effectiveness of the model by comparing the estimates to the actual measurements over time. By observing how the estimation curves align with the actual values, the ability of the filter to capture the fluctuations and noise present in the data can be assessed. A close match between the estimates and measurements indicates that the model is achieving an accurate prediction, which is crucial for anticipating changes in water levels. This type of visualization not only allows for an analysis of system performance but is also essential for identifying patterns and making informed decisions in water resource management, especially in situations of flood risk. (<b>a</b>) Short-term estimation of the water level at Tadó at hydrological station 1 using a NARX model with the Rauch–Tung–Striebel (RTS) smoothing filter technique. (<b>b</b>) Short-term estimation of the water level at Santa Rita Iró at hydrological station 2 using a NARX model with the Rauch–Tung–Striebel (RTS) smoothing filter technique.</p>
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<p>Short-term estimation response of the two water level outputs of the LSTM model for the hydrological stations. Y-real corresponds to the actual data from the study sample, and Y-Estim LSTM corresponds to the estimation of these actual data using the LSTM model. (<b>a</b>) Short-term estimation of Tadó water level at hydrologic station 1 using the LSTM model. (<b>b</b>) Short-term estimation of Santa Rita Iró water level at hydrologic station 2 using the LSTM model.</p>
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<p>The exponential smoothing method applied to two water level outputs on a neural network recurrent LSTM illustrates how the predicted values of both outputs are smoothly adjusted, reducing the impact of minor fluctuations or noise in the data. The plot compares the observed variations in water level with their smoothed values, allowing the overall trend in both outflows to be identified. This approach facilitates a clearer understanding of patterns over time, improving the ability to predict potential floods or detect major changes in water levels. (<b>a</b>) The short-term water level estimation at Tadó, hydrological station 1, was performed using an LSTM model and exponential Kalman smoothing. This combination improves accuracy by capturing nonlinear dynamics and reducing noise, allowing for more accurate river level predictions and facilitating early warnings of possible flooding. (<b>b</b>) The short-term estimation of the water level in Santa Rita Iró, hydrological station 2, was carried out using an LSTM model combined with the Kalman exponential smoothing technique. This methodology allows for obtaining more accurate predictions by reducing noise in the data, providing an effective tool for the monitoring and prevention of possible river floods.</p>
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<p>The Savitzky–Golay smoothing filter, applied to two water level outputs, demonstrates its ability to smooth and adjust the estimated values of both outputs. This method is effective at reducing noise in the time series while keeping essential features such as peaks and abrupt transitions intact. Smoothed lines facilitate the identification of underlying trends, allowing clearer analysis of critical patterns and behaviors, such as sudden increases or gradual changes in water level. This approach is particularly useful for examining the evolution of data that exhibit natural fluctuations but are affected by noise. (<b>a</b>) Short-term estimation of the water level at Tadó at hydrological station 1 using an LSTM model with the Savitzky–Golay smoothing filter technique. (<b>b</b>) Short-term estimation of the water level at Santa Rita Iró at hydrological station 2 using an LSTM model with the Savitzky–Golay smoothing filter technique.</p>
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<p>The smoothed Kalman Filter using the Rauch–Tung–Striebel (RTS) algorithm applied to an LSTM for the two water level outputs provides a clear view of the effectiveness of the model by comparing the estimates with the actual short-term measurements. Alignment between the estimation curves and the observed values allows for the LSTM to capture the inherent fluctuations and noise in the data to be assessed. A close match between estimates and measurements indicates that the model is achieving accurate predictions, which is critical for anticipating changes in water levels. This type of visualization not only allows for an analysis of system performance but is also essential for identifying patterns and facilitating informed decision making in water resource management, especially in situations of flood risk. (<b>a</b>) The short-term estimation of the water level at Tadó, corresponding to hydrological station 1, is presented using an LSTM model with the Rauch–Tung–Striebel smoothing filter (RTS) technique. (<b>b</b>) The short-term estimation of the water level at Santa Rita Iró, from hydrological station 2, using the same technique is shown.</p>
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18 pages, 1256 KiB  
Article
Experimental and Numerical Simulation Studies on the Synergistic Design of Gas Injection and Extraction Reservoirs of Condensate Gas Reservoir-Based Underground Gas Storage
by Jie Geng, Hu Zhang, Ping Yue, Simin Qu, Mutong Wang and Baoxin Chen
Processes 2024, 12(12), 2668; https://doi.org/10.3390/pr12122668 - 26 Nov 2024
Abstract
The natural gas industry has developed rapidly in recent years, with gas storage playing an important role in regulating winter and summer gas consumption and ensuring energy security. The Ke7010 sand body is a typical edge water condensate gas reservoir with an oil [...] Read more.
The natural gas industry has developed rapidly in recent years, with gas storage playing an important role in regulating winter and summer gas consumption and ensuring energy security. The Ke7010 sand body is a typical edge water condensate gas reservoir with an oil ring, and the construction of gas storage has been started. In order to clarify the feasibility of synergistic storage building for gas injection and production, the fluid characteristics during the synergistic reservoir building process were investigated through several rounds of drive-by experiments. The results show that the oil-phase flow capacity is improved by increasing the number of oil–water interdrives, and the injection and recovery capacity is improved by increasing the number of oil–gas interdrives; the reservoir capacities of the high-permeability and low-permeability rock samples increase by about 4.84% and 7.26%, respectively, after multiple rounds of driving. Meanwhile, a numerical model of the study area was established to simulate the synergistic storage construction scheme of gas injection and extraction, and the reservoir capacity was increased by 7.02% at the end of the simulation period, which was in line with the experimental results. This study may provide a reference for gas storage construction in the study area. Full article
(This article belongs to the Special Issue Numerical Simulation of Oil and Gas Storage and Transportation)
32 pages, 5232 KiB  
Review
Spatiotemporal Distribution, Bioaccumulation, and Ecological and Human Health Risks of Polycyclic Aromatic Hydrocarbons in Surface Water: A Comprehensive Review
by Zijian Wang, Qingling Meng, Kaicheng Sun and Zhao Wen
Sustainability 2024, 16(23), 10346; https://doi.org/10.3390/su162310346 - 26 Nov 2024
Abstract
The release of polycyclic aromatic hydrocarbons (PAHs) by human energy exploitation and excessive environmental use has caused substantial environmental contamination. These compounds bioaccumulate in aquatic environments and translocate through the food chain, posing risks to health and environmental safety. To better understand the [...] Read more.
The release of polycyclic aromatic hydrocarbons (PAHs) by human energy exploitation and excessive environmental use has caused substantial environmental contamination. These compounds bioaccumulate in aquatic environments and translocate through the food chain, posing risks to health and environmental safety. To better understand the risks of PAHs in surface water and food chains, this review summarizes their distribution, concentration levels, sources, and toxicity in various surface water environments. It also examines how PAH bioaccumulation affects aquatic organisms and human health. Globally, PAHs have been detected in both aquatic environments and organisms with an increasing trend. Human activity is the main cause of PAH contamination. The results revealed a distinct geographical distribution of PAH risk influenced by population density, industrial development, climate, and seasonal variations. PAHs are found in remote areas, indicating their medium- and long-range transport by atmospheric dispersion. PAHs bioaccumulate in aquatic organisms and cause direct and indirect toxic effects via biomagnification. PAH bioaccumulation is directly correlated with aquatic pollution. This study also emphasizes the carcinogenicity of compounds such as benzo[a]pyrene, identifying occupational and environmental exposure frequencies as key risk factors. This study enhances our understanding of the dynamics of multiple PAHs in aquatic ecosystems and their health effects, thereby contributing to environmental sustainability. Full article
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Figure 1

Figure 1
<p>Molecular structure of 16 PAHs prioritized for control by the United States Environmental Protection Agency.</p>
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<p>Dispersion of polycyclic aromatic hydrocarbons in the air and terrestrial and aquatic environments.</p>
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<p>Major sources of PAHs in the environment.</p>
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<p>Transmission of PAHs in the aquatic food chain.</p>
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<p>The composition of PAHs in ports. (<b>a</b>) Average concentrations of PAHs of various rings across continents and media. (<b>b</b>) Average concentrations of the dominant PAH isomers across media. (<b>c</b>) Temporal changes in the average concentration of PAHs at different ports across the selected media [<a href="#B119-sustainability-16-10346" class="html-bibr">119</a>]; see <a href="#app1-sustainability-16-10346" class="html-app">Table S1</a> for detailed data.</p>
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<p>The composition of PAHs in ports. (<b>a</b>) Average concentrations of PAHs of various rings across continents and media. (<b>b</b>) Average concentrations of the dominant PAH isomers across media. (<b>c</b>) Temporal changes in the average concentration of PAHs at different ports across the selected media [<a href="#B119-sustainability-16-10346" class="html-bibr">119</a>]; see <a href="#app1-sustainability-16-10346" class="html-app">Table S1</a> for detailed data.</p>
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<p>PAHs pose a toxicity hazard to human health.</p>
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23 pages, 2770 KiB  
Article
Enhancing Bird Diversity in Urban Parks: Insights from the Futian Mangrove Ecological Park, Shenzhen
by Xiangyi Li, Zhaojun Li, Yu Chen and Qing Wang
Forests 2024, 15(12), 2088; https://doi.org/10.3390/f15122088 - 26 Nov 2024
Abstract
Small urban parks and green spaces, serving as essential recreational venues for city residents, also play a vital and irreplaceable role in maintaining urban biodiversity. It is of great importance to design and plan these areas in a way that integrates multiple habitats [...] Read more.
Small urban parks and green spaces, serving as essential recreational venues for city residents, also play a vital and irreplaceable role in maintaining urban biodiversity. It is of great importance to design and plan these areas in a way that integrates multiple habitats for various species while accommodating residents’ usage. This study, carried out at the Futian Mangrove Ecological Park located in Shenzhen, Guangdong Province, China, chose birds as indicator species to assess biodiversity within the park. Site inventory was undertaken from May to September 2022 and from October 2022 to April 2023. We quantitatively described the park’s habitats by examining primary environmental factors, along with 3 primary environmental factors and 11 secondary factors. A correlation analysis was then performed between these factors and bird diversity to gain insights into birds’ habitat preferences across different habitat types and at a finer scale of plant communities. Furthermore, bird clusters in the study case were categorized by foraging guilds and foraging patterns, and their distributions were studied at both the habitat patch scale and the plant community scale. Our findings reveal that, at the habitat patch scale, water surface area and grass coverage significantly positively impact bird diversity. At the plant community scale, plant communities with different structural characteristics vary in their importance to bird clusters with distinct characteristics. In areas with high human disturbance, shrub coverage is crucial for bird habitat protection. Additionally, we discovered that the impact of anthropogenic sound differs among bird species, highlighting the complexity of human disturbance factors on bird habitat preferences. Accordingly, we proposed several design recommendations aimed at enhancing bird diversity in parks, including increasing water body areas, reducing the distance between habitats and water surfaces, enhancing herbaceous plant coverage, and controlling anthropogenic sound. Full article
(This article belongs to the Section Urban Forestry)
15 pages, 3164 KiB  
Article
Polystyrene Nanomicroplastics Aggravate Ammonia-Induced Neurotoxic Effects in Zebrafish Embryos
by Dan Xing, Wenting Zheng, Huiming Zhou, Guangyu Li, Yan Li, Jingwen Jia, Haoling Liu, Ning Luan and Xiaolin Liu
Toxics 2024, 12(12), 853; https://doi.org/10.3390/toxics12120853 - 26 Nov 2024
Abstract
The highly hazardous chemical ammonia has been proven to be absorbed by nanoparticles, thereby exerting highly toxic effects on aquatic organisms. As a ubiquitous pollutant in aquatic environments, polystyrene nanomicroplastics (PSNPs) have shown strong adsorption capacity due to their large surface area. Therefore, [...] Read more.
The highly hazardous chemical ammonia has been proven to be absorbed by nanoparticles, thereby exerting highly toxic effects on aquatic organisms. As a ubiquitous pollutant in aquatic environments, polystyrene nanomicroplastics (PSNPs) have shown strong adsorption capacity due to their large surface area. Therefore, the potential joint effects of ammonia and PSNPs need to be clarified. In this study, zebrafish embryos were exposed to a water solution with ammonia concentrations (0, 0.1, 1, and 10 mg/L) with or without PSNP (100 μg/L) treatment up to 120 hpf. The results showed that combined exposure increased the accumulation of ammonia and obviously reduced the locomotor speed of zebrafish larvae compared with exposure to ammonia alone. Further studies indicated that PSNPs can aggravate ammonia-induced neurotoxicity by altering the cholinergic system, dopaminergic neurons, and the retinal structure in zebrafish larvae. In addition, our results revealed that ammonia caused significant alterations in the expression of genes related to neurodevelopment and retinal development, and PSNPs exacerbated this adverse effect. In conclusion, PSNPs can aggravate ammonia-induced neurotoxicity in the early stage of zebrafish and their associated health risk to aquatic animals should not be underestimated. The main contribution of this article lies in revealing the synergistic neurotoxicity of ammonia and PSNPs in the early stage of zebrafish. Moreover; it emphasizes that the associated health risks to aquatic animals should not be underestimated. Full article
(This article belongs to the Section Neurotoxicity)
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<p>(<b>a</b>) Particle size distribution of suspension of PSNPs; (<b>b</b>) zeta potential of PSNPs; (<b>c</b>) TEM image of PSNPs. Scale bars, 200 μm.</p>
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<p>Adsorption analysis of ammonia (10 mg/L) by PSNPs (100 μg/L). The data show the changes in ammonia concentration over 24 h for ammonia alone and ammonia combined with PSNPs.</p>
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<p>Indicators of developmental endpoints of zebrafish embryos (mean ± SEM, n = 3). (<b>a</b>) Mortality rate; (<b>b</b>) malformation rate; (<b>c</b>) heart rate; (<b>d</b>) hatching rate; * indicates a significant difference between the control and exposure groups (<span class="html-italic">p</span> &lt; 0.05); # indicates a significant difference between the treatment groups of ammonia and PSNPs + ammonia (<span class="html-italic">p</span> &lt; 0.05).</p>
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<p>Locomotor behavior of 120 hpf zebrafish larvae (mean ± SEM, n = 3). (<b>a</b>) Movement patterns of zebrafish larvae; (<b>b</b>) mean velocity (5 min) of zebrafish larvae; (<b>c</b>) movement trajectories of zebrafish larvae under dark conditions. * indicates significant difference between control and exposed groups (<span class="html-italic">p</span> &lt; 0.05).</p>
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<p>Ammonia content in zebrafish larvae was determined after 120 hpf (mean ± SEM, n = 3). * indicates a significant difference between the control and exposed groups (<span class="html-italic">p</span> &lt; 0.05). # indicates a significant difference between the treatment groups of ammonia and PSNPs + ammonia (<span class="html-italic">p</span> &lt; 0.05).</p>
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<p>Histopathological analysis of retinal structures in zebrafish larvae. (<b>a</b>) Control group; (<b>b</b>) 0.1 mg/L ammonia exposure group; (<b>c</b>) 1 mg/L ammonia exposure group; (<b>d</b>) 10 mg/L ammonia exposure group; (<b>e</b>) PSNPs exposure group; (<b>f</b>) 0.1 mg/L ammonia + PSNPs exposure group; (<b>g</b>) 1 mg/L ammonia + PSNPs exposure group (<b>h</b>) 10 mg/L ammonia + PSNPs exposure group. GCL: ganglion cell layer; IPL: inner plexiform layer; INL: inner nuclear layer, ONL: outer nuclear layer; RPE: retinal pigment epithelium (scale bar is 100 μm; n = 10). Black arrows: disorganized nuclei. Red arrow: vacuolization.</p>
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<p>(<b>a</b>) Activity of AChE (U/mgprot) and (<b>b</b>) DA content (ng/mL) in 120 h zebrafish larvae (mean ± SEM, n = 3). # indicates a significant difference between the treatment groups of ammonia and PSNPs + ammonia (<span class="html-italic">p</span> &lt; 0.05), * indicates significant difference between control and exposed groups (<span class="html-italic">p</span> &lt; 0.05).</p>
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<p>Heatmaps of the expression of neurodevelopment- and retinal development-related genes in zebrafish larvae at 120 hpf (mean ± SEM, n = 3). Values in the heatmaps are derived from log base 2-transformed fold change in gene expression.</p>
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17 pages, 3922 KiB  
Article
Effects of ECMF Isolated from Mining Areas on Water Status, Photosynthesis Capacity, and Lead Ion Transport of Populus alba Under Pb Stress
by Na Wu, Zhen Li, Fei Wu and Jing Tan
J. Fungi 2024, 10(12), 822; https://doi.org/10.3390/jof10120822 - 26 Nov 2024
Abstract
Native ectomycorrhizal fungi (ECMF) are generally more effective than non-native ECMF in facilitating the phytoremediation of heavy metal (HM) ions from contaminated soils. This study aimed to investigate the contributions of four ECMF species—Suillus luteus, Suillus flavidus, Suillus variegatus, and [...] Read more.
Native ectomycorrhizal fungi (ECMF) are generally more effective than non-native ECMF in facilitating the phytoremediation of heavy metal (HM) ions from contaminated soils. This study aimed to investigate the contributions of four ECMF species—Suillus luteus, Suillus flavidus, Suillus variegatus, and Gomphidius glutinosus—that were isolated from mining areas to the growth, water status, photosynthesis, and metallothionein gene expression of Populus alba exposed to varying concentrations of lead (Pb). The experiment lasted two months and involved P. alba cuttings subjected to Pb concentrations of 0, 200, and 400 mg kg−1, representing no Pb stress, moderate Pb stress, and severe Pb stress, respectively. Results indicated that S. flavidus significantly enhanced the growth, water status, photosynthesis parameters, and metallothionein gene expression of P. alba under Pb stress, whereas S. luteus only exhibited positive effects under severe Pb stress. S. variegatus negatively affected the growth, water status, photosynthesis, and metallothionein gene expression of P. alba under Pb stress, while no significant difference was observed between the control treatment and G. glutinosus symbiosis. Therefore, S. flavidus and S. luteus are promising ECMF species for ecological restoration in mining areas, especially in P. alba woodlands. Full article
(This article belongs to the Special Issue Soil Fungi and Their Role in Plant Growth)
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<p>Effects of ECMF inoculation on height under different Pb treatments. NM, non-inoculation. Different letters indicate significant difference at <span class="html-italic">p</span> ≤ 0.05; the data are means ± SD (n = 6).</p>
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<p>Effects of ECMF inoculation on biomass of shoots (<b>A</b>) and roots (<b>B</b>) accumulation and root/shoot ratio (<b>C</b>) under different Pb treatments. NM, non-inoculation. Different letters indicate significant difference at <span class="html-italic">p</span> ≤ 0.05; the data are means ± SD (n = 6).</p>
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<p>Effects of ECMF inoculation on RWC (<b>A</b>) and REL (<b>B</b>) under different Pb treatments. NM, non-inoculation. Different letters indicate significant difference at <span class="html-italic">p</span> ≤ 0.05; the data are means ± SD (n = 6).</p>
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<p>Effects of ECMF inoculation on gas exchange parameters ((<b>A</b>), net photosynthesis; (<b>B</b>), stomatal conductance; (<b>C</b>), intercellular CO<sub>2</sub> concentration; (<b>D</b>), transpiration rates.) under different Pb treatments. NM, non-inoculation. Different letters indicate significant difference at <span class="html-italic">p</span> ≤ 0.05; the data are means ± SD (n = 6).</p>
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<p>Effects of ECMF inoculation on chlorophyll fluorescence parameters ((<b>A</b>), nonphotochemical quenching; (<b>B</b>), photochemical quenching; (<b>C</b>), maximum quantum yield of photosystem II; (<b>D</b>), actual quantum yield of photosystem II) under different Pb treatments. NM, non-inoculation. Different letters indicate significant difference at <span class="html-italic">p</span> ≤ 0.05; the data are means ± SD (n = 6).</p>
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<p>Effects of ECMF inoculation on Pb contents in shoots (<b>A</b>) and roots (<b>B</b>), and translocation factor (<b>C</b>) under different Pb treatments. NM, non-inoculation. Different letters indicate significant difference at <span class="html-italic">p</span> ≤ 0.05; the data are means ± SD (n = 6).</p>
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<p>Effects of ECMF inoculation on <span class="html-italic">PaMT</span>s ((<b>A</b>), <span class="html-italic">PaMT1</span> in leaves; (<b>B</b>), <span class="html-italic">PaMT2</span> in leaves; (<b>C</b>), <span class="html-italic">PaMT3</span> in leaves; (<b>D</b>), <span class="html-italic">PaMT1</span> in roots; (<b>E</b>), <span class="html-italic">PaMT2</span> in roots; (<b>F</b>), <span class="html-italic">PaMT3</span> in roots) expression under different Pb treatments. NM, non-inoculation. Different letters indicate significant difference at <span class="html-italic">p</span> ≤ 0.05; the data are means ± SD (n = 6).</p>
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<p>PCA results. NM, non-inoculation.</p>
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13 pages, 1089 KiB  
Article
Households’ Willingness to Use Water from a Solar Water Disinfection Treatment System for Household Purposes
by Abdul-Rahaman Afitiri and Ernest Kofi Amankwa Afrifa
World 2024, 5(4), 1181-1193; https://doi.org/10.3390/world5040060 - 26 Nov 2024
Abstract
The consumption of contaminated water contributes to the global burden of diarrhea and other water-borne diseases, especially among young children. While decentralized solar water disinfection treatment systems (hereafter SODIS) remain a viable option to have safe drinking water, our understanding of the effects [...] Read more.
The consumption of contaminated water contributes to the global burden of diarrhea and other water-borne diseases, especially among young children. While decentralized solar water disinfection treatment systems (hereafter SODIS) remain a viable option to have safe drinking water, our understanding of the effects of household water treatment before use on willingness to accept and adopt a SODIS is limited. In this study, a complementary log-log regression analysis of the compositional and contextual factors that systematically vary with willingness to accept and adopt a SODIS in the Sawla-Tuna-Kalba (STK) district of Ghana was carried out. Based on our findings, a greater proportion of households (97%) are willing to accept and adopt a SODIS. Compositional and contextual factors such as age, marital status, education, religion, and geographical location significantly contribute to households’ willingness to accept and adopt a SODIS in the STK district of Ghana. Households that treat their water before use (66%, p < 0.05) are more likely to accept and adopt a SODIS compared to those that do not treat their water before use. The findings, therefore, suggest that scaling up SODIS in the STK district is sacrosanct and highlight the necessity to analyse compositional and contextual factors influencing willingness to accept and adopt SODIS. Our findings will inform policies and programs aimed at implementing SODIS in the study area to improve the health of communities that rely on poor-quality drinking water sources. Full article
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<p>Map of the study area.</p>
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30 pages, 7606 KiB  
Article
Soybean Yield Losses Related to Drought Events in Brazil: Spatial–Temporal Trends over Five Decades and Management Strategies
by Rodrigo Cornacini Ferreira, Rubson Natal Ribeiro Sibaldelli, Luis Guilherme Teixeira Crusiol, Norman Neumaier and José Renato Bouças Farias
Agriculture 2024, 14(12), 2144; https://doi.org/10.3390/agriculture14122144 - 26 Nov 2024
Abstract
By the end of the decade, the world population is expected to increase by nearly one billion people, posing challenges to meeting global food demand. In this scenario, soybean production is projected to increase by 18% within this decade. Despite being the largest [...] Read more.
By the end of the decade, the world population is expected to increase by nearly one billion people, posing challenges to meeting global food demand. In this scenario, soybean production is projected to increase by 18% within this decade. Despite being the largest soybean producer, responsible for over 40% of soybeans produced worldwide, drought events often impair Brazilian production. The goals of the present research were to quantify soybean yield losses related to drought in Brazil from 1973 to 2023 at national, state, and municipal levels and to assess the spatial distribution of losses across the production areas. The hypothesis investigated is that year-to-year variations in soybean yield are closely related to water availability, considering that crop management practices are constant from year to year, while increments in soybean yield across time (more than five years) relate tightly to better crop management practices and breeding improvements. Thus, quantifying year-to-year yield losses might demonstrate the effects of water availability on soybean yield. Yield data from the 1976/1977 to 2022/2023 crop seasons from the 26 states and the Federal District came from the National Supply Company, while the Brazilian Institute of Geography and Statistics supplied yield data for the 1973/1974 to 2020/2021 crop seasons from 1998 municipalities with more than 14 crop seasons. Soybean drought yield losses were calculated for each cropping season individually at the municipal, state, and national levels, based on the deviation in the observed yield to the corresponding maximum yield in the five-year window, considering that crop management practices and genetics represent a regular increment in soybean yield, which means that production practices improved over time and deviations from year to year are mainly related to drought occurrence. Annual soybean yield loss (expressed in tons, USD, and percentage), frequency of yield loss, and severity of yield loss were calculated at national, state, and municipal levels for each cropping season. The Standardized Precipitation Index (SPI), acquired from the Brazilian Weather Forecast and Climate Studies Center at the National Space Research Institute, was used as a qualitative indicator to corroborate the assessed soybean yield losses related to drought. The results demonstrate yield losses in more than 50% of crop seasons at the national level, with a similar frequency across the five decades, albeit with lower severities in the last 30 years. The Central–West region was more stable than the South region, with yield losses of up to 74%. In five decades, yield losses related to drought events stand at 11.65%, corresponding to 280 million tons or USD 152 billion (considering the average soybean price in 2022 at the Chicago Board of Trade). At the municipal level, analogous behavior was observed across time and space. The outcomes from the present research might subsidize public and corporative policies related to agricultural zoning, farm loan programs, crop insurance contracts, and food security, contributing to higher agricultural, environmental, economic, and social sustainability. Full article
(This article belongs to the Section Crop Production)
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<p>Annual mean temperature (<b>a</b>), rainfall (<b>b</b>), and climate according to Köppen classification (<b>c</b>) for Brazil and municipalities with soybean crops in 2020/2021 crop season (<b>d</b>). Subparts a, b, and c were adapted from Alvares et al. [<a href="#B24-agriculture-14-02144" class="html-bibr">24</a>], and the soybean record from subpart d came from the Brazilian Institute of Geography and Statistics (IBGE).</p>
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<p>Administrative regions of Brazil, municipalities with soybean crops in 2020/2021 crop seasons, and official data at the national level of soybean area, production, and yield from the 1976/1977 to 2022/2023 crop seasons.</p>
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<p>Flowchart of the methodological process.</p>
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<p>Correlation between SPI and soybean yield in the field experiment located at Embrapa Soja, assuming the reference yield based on the yield under no water restrictions (<b>a</b>) and based on genotype performances under no water restrictions (<b>b</b>).</p>
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<p>Frequency of soybean yield losses at the state level (<b>a</b>) and severity of losses: 0–10% (<b>b</b>), 10–20% (<b>c</b>), 20–30% (<b>d</b>), 30–40% (<b>e</b>), and more than 40% (<b>f</b>).</p>
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<p>Soybean production and yield losses in Brazil from the 1976/1977 to 2022/2023 crop seasons and the percentage of yield losses in relation to the Yield<sub>Reference</sub> (Equation (1)) for the corresponding crop season.</p>
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<p>Observed minimum and maximum soybean yields from 1976/1977 to 2022/2023 in five-year windows in the states of GO (<b>a</b>), MS (<b>b</b>), MT (<b>c</b>), PR (<b>d</b>), and RS (<b>e</b>).</p>
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<p>Monthly SPI maps from November, December, and January in the 1990/1991, 2003/2004, 2004/2005, and 2021/2022 crop seasons.</p>
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<p>Monthly SPI maps from September, October, November, December, January, and February in the 2022/2023 crop season.</p>
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<p>Drought occurrence based on SPI in the mesoregions of soybean production in Brazil from 2003/2004 to 2022/23 (<b>a</b>), from 2003/2004 to 2012/2013 (<b>b</b>), and from 2013/2014 to 2022/23 (<b>c</b>).</p>
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<p>Occurrence of yield loss at the municipal level from 1974/1975 to 2020/2021 (<b>a</b>), from 1973/1974 to 1982/1983 (<b>b</b>), from 1983/1984 to 1992/1993 (<b>c</b>), from 1993/1994 to 2002/2003 (<b>d</b>), from 2003/2004 to 2013/2014 (<b>e</b>), and from 2014/2015 to 2020/2021 (<b>f</b>).</p>
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<p>Severity of yield loss at the Municipal level expressed as a percentage of occurrence within severity levels: from 0 to 10% (<b>a</b>), from 10 to 20% (<b>b</b>), from 20 to 30% (<b>c</b>), from 30 to 40% (<b>d</b>), and above 40% (<b>e</b>).</p>
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19 pages, 2662 KiB  
Article
Deep Reinforcement Learning for Multi-Objective Real-Time Pump Operation in Rainwater Pumping Stations
by Jin-Gul Joo, In-Seon Jeong and Seung-Ho Kang
Water 2024, 16(23), 3398; https://doi.org/10.3390/w16233398 - 26 Nov 2024
Abstract
Rainwater pumping stations located near urban centers or agricultural areas help prevent flooding by activating an appropriate number of pumps with varying capacities based on real-time rainwater inflow. However, relying solely on rule-based pump operations that monitor only basin water levels is often [...] Read more.
Rainwater pumping stations located near urban centers or agricultural areas help prevent flooding by activating an appropriate number of pumps with varying capacities based on real-time rainwater inflow. However, relying solely on rule-based pump operations that monitor only basin water levels is often insufficient for effective control. In addition to maintaining a low maximum water level to prevent flooding, pump operation at rainwater stations also requires minimizing the number of pump on/off switches. Reducing pump switch frequency lowers the likelihood of mechanical failure and thus decreases maintenance costs. This paper proposes a real-time pump operation method for rainwater pumping stations using Deep Reinforcement Learning (DRL) to meet these operational requirements simultaneously, based only on currently observable information such as rainfall, inflow, storage volume, basin water level, and outflow. Simulated rainfall data with various return periods and durations were generated using the Huff method to train the model. The Storm Water Management Model (SWMM), configured to simulate the Gasan rainwater pumping station located in Geumcheon-gu, Seoul, South Korea, was used to conduct experiments. The performance of the proposed DRL model was then compared with that of the rule-based pump operation currently used at the station. Full article
(This article belongs to the Section Urban Water Management)
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<p>Gasan pumping station located in Korea.</p>
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<p>(<b>a</b>) Cumulative rainfall over time for a 60 min duration sample generated with a 30-year return period. (<b>b</b>) Inflow variation into the detention basin over time, as obtained from the SWMM simulation of rainfall data.</p>
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<p>Simulation result of the DDQN model using a 30-year, 60 min test sample as input: (<b>a</b>) inflow to the detention basin and (<b>b</b>) outflow from the detention basin at 2 min intervals.</p>
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<p>Simulation result of the rule-based pump operation method using a 30-year, 60 min test sample as input: (<b>a</b>) inflow to the detention basin and (<b>b</b>) outflow from the detention basin at 2 min intervals.</p>
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<p>(<b>a</b>) Maximum water level and (<b>b</b>) number of pump changes for three models based on rainfall data for all durations with a 30-year return period.</p>
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<p>(<b>a</b>,<b>b</b>) The maximum water level for the DDQN model without the weight <span class="html-italic">w<sub>p</sub></span> for minimizing pump changes and for the DDQN model with the weight <span class="html-italic">w<sub>p</sub></span>, respectively, based on the input sequence size. (<b>c</b>,<b>d</b>) The number of pump changes in both models according to the input sequence size.</p>
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12 pages, 2253 KiB  
Article
Effect of Incorporating Natural Zeolitic Tuffs in Concrete Mixed and Cured Using Seawater
by Ansam Qsymah, Hasan Alqawasmeh, Mo’men Ayasrah and Buthainah Al-kharabsheh
Eng 2024, 5(4), 3080-3091; https://doi.org/10.3390/eng5040160 - 26 Nov 2024
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Abstract
Concrete production has increasingly used seawater to overcome the challenge of freshwater scarcity. Although the use of seawater in concrete still has a controversial reputation, it is a promising application, particularly when combined with mineral admixtures such as natural zeolitic tuffs (ZT). This [...] Read more.
Concrete production has increasingly used seawater to overcome the challenge of freshwater scarcity. Although the use of seawater in concrete still has a controversial reputation, it is a promising application, particularly when combined with mineral admixtures such as natural zeolitic tuffs (ZT). This paper aims to investigate the effect of using locally quarried ZT on the strength of unreinforced concrete mixed and/or cured using seawater. The mix proportions of the concrete were selected to obtain the optimum combination for the M20 grade of concrete with a water-to-cement ratio of 0.69. Moreover, 150mm-cubes and cylinders of 100 mm diameter by 200mm height were cast from the concrete mixtures, which contain 0%, 5%, 7.5%, 10%, and 25% of ZT as a partial replacement of silica sand. Splitting tensile tests and compressive strength tests were conducted on these specimens at 7, 28, and 90 days. The results show the harmful effect of seawater on the strength of plain concrete (without ZT) at 7, 28, and 90 days of curing, especially when seawater is used in both mixing and curing of the concrete. However, adding ZT in seawater-based concrete improved its strength apparently, especially at early curing ages. For example, using 10% of ZT as a partial replacement of silica sand increased the compressive strength of seawater based-concrete by 105.4%, 28.3%, and 34.6% after 7, 28, and 90 days of curing, compared with concrete without ZT and produced using seawater. These results contribute to the enhancement of the sustainability of both freshwater and concrete material through the use of ZT in producing concrete, particularly in areas where freshwater is scarce or expensive. Full article
(This article belongs to the Section Chemical, Civil and Environmental Engineering)
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<p>Ground zeolitic tuffs.</p>
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<p>(<b>a</b>) Molded concrete specimens. (<b>b</b>) Compressive strength test. (<b>c</b>) Splitting tensile test.</p>
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<p>Compressive strength of concrete specimens cured and/or mixed with fresh and seawater incorporating ZT at age of 7 days.</p>
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<p>Compressive strength of concrete specimens cured and/or mixed with fresh and seawater incorporating ZT at age of 28 days.</p>
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<p>Compressive strength of concrete specimens cured and/or mixed with fresh and sea water incorporating ZT at age of 90 days.</p>
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<p>Splitting tensile strength of concrete specimens cured and/or mixed with fresh and seawater incorporating ZT at age of 7 days.</p>
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<p>Splitting tensile strength of concrete specimens cured and/or mixed with fresh and seawater incorporating ZT at age of 28 days.</p>
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