Search Results (1,709)

Sustainable wastewater management is essential for conserving water resources and reducing environmental pollution. Traditional wastewater treatment methods primarily aim to purify water for reuse, yet they often involve high energy consumption, extensive chemical use, and loss of potentially recoverable resources, which pose sustainability challenges. With approximately 2.2 billion people worldwide currently lacking access to clean water—a number projected to exceed 3 billion by 2025—water scarcity has become an urgent issue. Traditional wastewater treatment processes handle around 330 billion cubic meters of water annually; however, they account for 3–4% of global energy consumption and produce 300 million tons of carbon emissions. This situation underscores the need for more sustainable treatment methods. Innovative wastewater treatment technologies have the potential to facilitate the reuse of approximately 50 billion cubic meters of water each year, helping to alleviate water scarcity. Additionally, energy recovery from these processes aims to achieve an annual energy savings of 20 TWh, in contrast to conventional treatment methods. This article examines recent advances in sustainable wastewater management technologies, specifically focusing on biological, physicochemical, and membrane-based processes. It discusses strategies for optimizing these processes to minimize environmental impact. Furthermore, innovative approaches, such as advanced oxidation processes and energy recovery, are explored for their potential to harness energy and recover nutrients from wastewater. The article concludes that implementing innovative strategies in sustainable wastewater management can significantly contribute to water conservation, energy savings, and a reduction in carbon footprint. Full article

The construction, demolition, and renovation industries are among the largest contributors to global carbon emissions and waste. With decreased landfill capacities, increased waste diversion targets, resource shortages, and the recognition that material waste is critical to climate change, diverting demolition waste is now a significant priority in waste management. Deconstructing a structure and reusing its building components can significantly reduce the environmental burdens imposed. However, to optimize the reuse of building materials and components for their environmental, societal, and economical benefits, the reclamation procedure must be undertaken in a more rational and robust manner. There are currently gaps in frameworks and tools that involve the assessment of reusable building components in demolition projects. This paper develops a reclamation framework to assess the viability of recovering and reusing building components. The framework first describes a process for conducting a technical audit and uses an assessment tool to suggest a level of deconstruction based on the physical parameters of the building circumstances. The framework complements this initial outcome by then assessing additional comprehensive parameters, such as the cost, the heritage value, and the available timeframe to arrive at a suggested outcome of actions, which can range from complete demolition and basic material recovery to deliberately removing salvageable items. The framework is then applied to an older, detached office building as a conceptual case study for demonstration. The recommended level of deconstruction appears appropriate based on the visual assessment of the structure. The result of this paper promotes the circular economy and supports the United Nations Sustainable Development Goals (UN SDGs) by presenting a notably more insightful and guided approach to capturing deconstruction waste. Full article

Mining activities generate large volumes of waste, posing environmental and economic challenges, particularly in Brazil’s Quadrilátero Ferrífero region. This study assesses the potential reuse of iron ore waste from Samarco Mineração S.A. in road pavement layers by blending it with phyllite residual soil (PRS) and lateritic clayey soil (LCS). The addition of 50% waste to PRS led to substantial improvements, increasing the resilient modulus (RM) by up to 130% under medium stress and reducing expansibility from 6.1% to 1%, meeting Brazilian standards for sub-base applications. These enhancements make the PRS-waste blend a viable and sustainable option for reinforcing subgrade and sub-base layers. In contrast, the LCS with 20% waste showed moderate RM improvements under high-stress conditions, while higher waste contents reduced stiffness, indicating that higher dosages may adversely affect performance. This study highlights the potential of inert, non-hazardous mining waste as a safe and efficient solution for pavement applications, promoting the sustainable use of discarded materials. Full article

In the current study, pyromellitimide benzoyl thiourea cross-linked chitosan (PIBTU-CS) hydrogel, was evaluated as a green biocatalyst for the efficient synthesis of novel thiazole derivatives. The PIBTU-CS hydrogel showcased key advantages, such as an expanded surface area and superior thermal stability, establishing it as a potent eco-friendly catalyst. By employing PIBTU-CS alongside ultrasonic irradiation, we successfully synthesized a series of novel thiazoles through the reaction of 2-(4-((2-carbamothioylhydrazineylidene)methyl)phenoxy)-N-(4-chlorophenyl)acetamide with a variety of hydrazonoyl halides (6a–f) and α-haloketones (8a–c or 10a,b). A comparative analysis with TEA revealed that PIBTU-CS hydrogel consistently delivered significantly higher yields. This synthetic strategy provided several benefits, including mild reaction conditions, reduced reaction times, and consistently high yields. The robustness of PIBTU-CS was further underscored by its ability to be reused multiple times without a substantial reduction in catalytic efficiency. The structures of the synthesized thiazole derivatives were meticulously characterized using a range of analytical techniques, including IR, ¹H-NMR, ¹³C-NMR, and mass spectrometry (MS), confirming their successful formation. These results underscore the potential of PIBTU-CS hydrogel as a sustainable and recyclable catalyst for the synthesis of heterocyclic compounds. Additionally, all synthesized products were tested for their anticancer activity against HepG2-1 cells, with several new compounds exhibiting good anticancer effects. Full article

Amid South Africa’s shift towards electric vehicles (EVs), building a lithium-ion battery (LIB) recycling sector is essential for promoting sustainable development and generating employment opportunities. This study employs qualitative methodologies to collect insights from 12 critical stakeholders in the automotive, mining, and recycling sectors and academia to examine the feasibility and advantages of establishing such an industry. We implemented purposeful and snowball sampling to guarantee an exhaustive array of viewpoints. Thematic analysis of the interview data reveals that LIB recycling has substantial social, environmental, and economic implications. The results emphasize the pressing necessity of recycling infrastructure to mitigate environmental impacts and attract investment. The economic feasibility and employment potential of LIB recycling is promising despite the early stage of the EV industry in South Africa. These potentials are influenced by EV adoption rates, technological advancements, regulatory frameworks, and industry growth. In this sector, employment opportunities are available in various phases: battery collection, transportation, disassembly, testing, mechanical crushing, hydrometallurgical processes, valuable metal recovery, manufacturing, reuse, research and development, and administrative roles. Each of these roles necessitates a unique set of skills. This interdisciplinary research investigates vital elements of economic growth, employment creation, environmental sustainability, policymaking, technological innovation, and global collaboration. The study offers valuable guidance to policymakers and industry stakeholders trying to establish a sustainable and robust LIB recycling industry in South Africa by utilizing Transition Management Theory to develop a framework for improving the sustainability and circularity of the EV LIB recycling sector. Full article

The increasing environmental pollution resulting from plastic waste and the need to reuse agro-industrial wastes as a source of discarding has led to the development of innovative biobased products. In the frame of this context, the use of neat polylactic acid (PLA) and its blend with polybutylene succinate (PBS) with or without cellulose nanocrystals (CNCs) extracted from hemp fibers is explored here. This study aimed to assess the biogas production of different biopolymeric films. In parallel, life cycle assessment (LCA) analysis was performed on the same films, focusing on their production phase and potential end-of-life scenarios, regardless of film durability (i.e., single-use packaging) and barrier performance, to counteract possible soil health threats. Specifically, this study considered three specific systems: PLA, PLA_PBS (PLA/PBS blend 80:20 w/w), and PLA_PBS_3CNC (PLA/PBS blend + 3% CNCs) films. The assessment involved a batch anaerobic digestion (AD) process at 52 °C, using digestate obtained from the anaerobic treatment of municipal waste as the inoculum and cellulose as a reference material. The AD process was monitored over about 30 days, revealing that reactors containing cellulose showed inherent biodegradability and enhanced biogas production. On the other hand, biopolymeric films based on PLA and its blends with PBS and CNCs exhibited an inhibitory effect, likely due to their recalcitrant nature, which can limit or delay microbial activity toward biomass degradation and methanogenesis. LCA analysis was performed taking into consideration the complex environmental implications of both including biopolymers in the production of renewable energy and the use of post-composting digestate as an organic fertilizer. Remarkably, the PLA_PBS_3CNC formulation revealed slightly superior performance in terms of biodegradability and biogas production, mainly correlated to the presence of CNCs in the blend. The observed enhanced biodegradability and biogas yield, coupled with the reduced environmental impact, confirm the key role of optimized biopolymeric formulations in mitigating inhibitory effects on AD processes while maximizing, at the same time, the utilization of naturally derived energy sources. Full article

Due to the restrictions of strong acids in some regions, the reuse process of rare earth (RE) precipitation mother liquor is difficult to carry out. To achieve the straightforward and efficient reuse of precipitation mother liquor in such areas, the potential for directly reusing this liquor for rare earth (RE) leaching was explored. The results showed that when the RE concentration in the leachate ranged from 0.1 to 1.5 g/dm³ and the RE precipitation rate exceeded 96%, the residual total carbonate content in precipitation mother liquor was less than 0.01 mol/L, and the solution pH was 7–8. Furthermore, when the total carbonate content in leaching liquor was lower than 0.01 mol/L, the presence of carbonate had a minimal impact on the RE leaching efficiency, which was observed to exceed 93%. Additionally, the process of mother liquor leaching was analyzed using dynamic models and chromatography tray theory. It was found that the leaching results were well fitted with the shrinking core model, and the apparent activation energy of RE was 5.77 kJ/mol, indicating that the reaction was controlled by diffusion, and the reaction order was 0.672 for RE. This confirms that a total carbonate content below 0.01 mol/L in the precipitation mother liquor can be directly used for the RE leaching process. Full article

The catalytic reduction of organic pollutants in water is a critical environmental challenge due to the persistent and hazardous nature of compounds like azo dyes and nitrophenols. In this study, we synthesized nanostructured CuO/TiO₂ catalysts via a combustion technique, followed by calcination at 700 °C to achieve a rutile-phase TiO₂ structure with varying copper loadings (5–40 wt.%). The catalysts were characterized using X-ray diffraction (XRD), attenuated total reflectance-Fourier transform infrared (ATR–FTIR) spectroscopy, thermogravimetric analysis-differential thermal analysis (TGA–DTA), UV-visible diffuse reflectance spectroscopy (DRS), and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM–EDS). The XRD results confirmed the presence of the crystalline rutile phase in the CuO/TiO₂ catalysts, with additional peaks indicating successful copper oxide loading onto TiO₂. The FTIR spectra confirmed the presence of all the functional groups in the prepared samples. SEM images revealed irregularly shaped copper oxide and agglomerated TiO₂ particles. The DRS results revealed improved optical properties and a decreased bandgap with increased Cu content, and 4-Nitrophenol (4-NP) and methyl orange (MO), which were chosen for their carcinogenic, mutagenic, and nonbiodegradable properties, were used as model organic pollutants. Catalytic activities were tested by reducing 4-NP and MO with sodium borohydride (NaBH₄) in the presence of a CuO/TiO₂ catalyst. Following the in situ reduction of CuO/TiO₂, Cu (NPs)/TiO₂ was formed, achieving 98% reduction of 4-NP in 480 s and 98% reduction of MO in 420 s. The effects of the NaBH₄ concentration and catalyst mass were investigated. The catalysts exhibited high stability over 10 reuse cycles, maintaining over 96% efficiency for MO and 94% efficiency for 4-NP. These findings demonstrate the potential of nanostructured CuO/TiO₂ catalysts for environmental remediation through efficient catalytic reduction of organic pollutants. Full article

Recyclable construction waste can be used as a low-cost material to reduce stormwater pollution caused by various pollutants. In recent years, studies have reported increased water contamination from chlorine and chlorine compounds and its negative impact on aquatic ecosystems. When assessing the need for waste recycling, circularity, and stormwater reuse, it is worth evaluating the capacities of construction waste materials to reduce stormwater pollution from residual chlorine. Laboratory experiments using bentonite waste material (bentonite clay) and sodium hypochlorite solutions were carried out to analyze the potential of bentonite clay to retain residual chlorine in stormwater and evaluate its capacity to be applied as filtration media in green infrastructure. In the first stage, the particle size distribution and texture of bentonite clay were assessed using laboratory sieve analysis and microscopy. The results of the experiments indicated that the optimal grain size to retain pollutants was 0.8–2.0 mm. The microstructure analysis showed the capacity of bentonite to retain residual chlorine. The results of the static and dynamic experiments (leaching and filtration tests) show that the bentonite clay retained up to 44% of the residual chlorine. The obtained results indicate that bentonite clay might be suitable for application as filtration media in green infrastructure to reduce stormwater contamination. Full article

Fly ash (FA) is the main solid waste emitted from coal-fired power plants. Due to its high yield, low utilization rate, and occupation of a large amount of land, it exerts enormous pressure on the Earth’s environment. With the deepening of the concept of sustainable development, exploring the reuse of industrial waste such as FA has become a key strategy. If FA can be combined with commonly used jewelry in people’s lives, it will be of great significance to promote the high-net-worth utilization of FA. Therefore, this study synthesized a fly-ash-based composite material with color-changing function and combined it with necklaces as the main material. In the first stage, after blending fly ash and slag, an alkaline activator with a total mass of 10% was added. When the proportion of fly ash was 60%, the compressive strength of the prepared fly-ash-based composite material reached 10.1 MPa. This was attributed to the reaction between sodium silicate in the alkaline activator and free CaO, MgO, and other substances in the fly ash to form hydrated silicate colloids, which solidify the fly ash and transform it into a complex three-dimensional network skeleton. In the second stage, a UV resistant coating with thermochromic function was obtained by blending acrylic resin, TiO₂, and a thermosensitive color-changing agent. It was applied to the surface of fly-ash-based composite materials, and the results showed that as the content of the color-changing agent increased, the number of pores on the surface of the coating gradually decreased. When the content of color-changing agent was 10%, the prepared 10%FAB not only had good surface color but also had good thermal stability, UV absorption ability, superhydrophobicity, and mechanical properties. Therefore, 10%FAB was selected as the basic material for jewelry design. In the third stage, the traditional Chinese technique of “gold inlaid with jade” was utilized to develop jewelry applications for the FA composites. As such, 10%FAB was processed into necklaces, which not only had modern design aesthetics but also had good color-changing effects above 30 °C. And after a long period of UV aging experiments, the necklace did not show any wrinkles, bubbles, or other phenomena. Due to the excitation of TiO₂ hole–electron pairs, the necklace’s UV absorption ability was further improved. This study demonstrates the potential application of industrial waste in decorative products, expands the high-end utilization of fly ash as a low-cost material, and provides new ideas for building a low-carbon lifestyle. Full article

Airborne microplastics are emerging pollutants originating from disposable tableware, packaging materials, textiles, and other consumer goods. Microplastics vary in shape and size and exposed to external factors break down into even smaller fractions. Airborne microplastics are abundant in both urban and natural environments, including water bodies and glaciers, as particles can travel long distances. The potential toxicity of airborne microplastics cannot be underestimated. Microparticles, especially those < 10 µm, entering the human body through inhalation or ingestion have been shown to cause serious adverse health effects, such as chronic inflammation, oxidation stress, physical damage to tissues, etc. Microplastics adsorb toxic chemicals and biopolymers, forming a polymer corona on their surface, affecting their overall toxicity. In addition, microplastics can also affect carbon dynamics in ecosystems and have a serious impact on biochemical cycles. The approaches to improve sampling techniques and develop standardized methods to assess airborne microplastics are still far from being perfect. The mechanisms of microplastic intracellular and tissue transport are still not clear, and the impact of airborne microplastics on human health is not understood well. Reduced consumption followed by collection, reuse, and recycling of microplastics can contribute to solving the microplastic problem. Combinations of different filtration techniques and membrane bioreactors can be used to optimize the removal of microplastic contaminants from wastewater. In this review we critically summarize the existing body of literature on airborne microplastics, including their distribution, identification, and safety assessment. Full article

As the climate crisis progresses, droughts and the seasonal availability of fresh water are becoming increasingly common in different regions of the world. One solution to tackle this problem is the reuse of treated wastewater in agriculture. This study was carried out in two significant hydrographic regions located in the southeast of Brazil (Mogi Guaçu River Water Management Unit—UGRHI-09 and Piracicaba River Basin—PRB) that have notable differences in terms of land use and land cover. The aim of this study was to carry out a multi-criteria analysis of a set of environmental attributes in order to classify the areas under study according to their levels of soil suitability and runoff potential. The integrated analysis made it possible to geospatialize prospective regions for reuse, under two specified conditions. In the UGRHI-09, condition 1 corresponds to 3373.24 km², while condition 2 comprises 286.07 km², located mainly in the north-western and central-eastern portions of the unit. In the PRB, condition 1 was also more expressive in occupational terms, corresponding to 1447.83 km²; and condition 2 was perceptible in 53.11 km², predominantly in the central region of the basin. The physical characteristics of the areas studied were decisive in delimiting the areas suitable for the reuse of treated wastewater. Full article

Over the past 50 years, global plastic production has surged exponentially. Around 40% of this plastic is used for packaging, most of which is single-use, while 20% is used in construction. Despite the vast quantities produced, only about 6% of discarded plastics are properly recycled, 10% are incinerated, and the majority are disposed of without proper management. With low recycling rates and some plastics being non-recyclable or with limited recycling cycles, it is important to explore new ways of reusing this waste as secondary raw materials. This study explores the potential of incorporating non-recyclable plastic waste into bituminous mixtures. The objective is to develop a sustainable solution for surface courses with similar or better performance than traditional bituminous mixtures by incorporating plastic waste using the dry method. A bituminous mixture containing 10% non-recyclable plastic was formulated and tested for water sensitivity, wheel tracking, and stiffness modulus. Additionally, environmental and economic comparisons were performed with a standard surface mixture. Results showed increased water resistance, high resistance to permanent deformation, reduced stiffness, lower susceptibility to frequency and temperature variations, and greater flexibility. These findings suggest that adding plastic not only enhances mechanical properties but also reduces costs, offering a sustainable alternative for non-recyclable plastics in road construction. Full article

This study investigated treatment methods for urban wastewater sludge, specifically examining natural drying over five years, accelerated freeze–thaw–drying cycles, and composting with and without a zeolite additive. The findings reveal that composting effectively stabilized the sludge while retaining essential nutrients crucial for agriculture. Notably, with the addition of 2% zeolite by total mass, approximately 40% of the total nitrogen was preserved. Adequate aeration during composting maintained acceptable levels of phosphorus compounds, with the phosphorus content expressed as P₂O₅ showing significant retention compared with the natural drying methods. Composting also demonstrated a substantial reduction in petroleum hydrocarbon concentrations, which decreased from 30 mg/kg to 3 mg/kg, thereby showcasing its potential for processing contaminated sludge. The inclusion of zeolite enhanced the nitrogen retention by an additional 10–20% compared with the composting without zeolite, aligning with previous studies on its effectiveness. While composting and thermal treatments, like accelerated freeze–thaw cycles, influenced the physical properties of the sludge—such as reducing the moisture content and altering the volatile substance concentrations—they did not significantly affect the heavy metal levels. Natural drying over five years resulted in reduced metal quantities, which possibly reflected changes in the wastewater characteristics over time. Given that the heavy metal concentrations remained largely unchanged, additional treatment methods are recommended when the initial sludge contains high levels of these contaminants to ensure the safe use of the final product as fertilizer. This study underscored the significant role of biochemical and microbiological processes during composting and natural drying in transforming sludge properties. Future research should focus on establishing upper contamination thresholds and exploring microbiological safety measures to enhance the viability of sludge reuse in agriculture, balancing nutrient preservation with environmental safety. Full article

Maximizing energy efficiency (EE) in massive multiple-input multiple-output (MIMO) systems, while supporting the rapid expansion of Internet of Things (IoT) devices, is a critical challenge. In this paper, we delve into the intricate operations geared toward enhancing EE in such complex environments. To effectively support a multitude of IoT devices, we adopt a strategy of heavy reference signal (RS) reuse, and in this circumstance, we formulate the EE metrics and their corresponding inverses to determine pivotal operational parameters. These EE-centric parameters encompass factors such as the number of service antennas in the base station (BS), the number of IoT devices, and permissible coverage extents. Our objective is to calibrate these parameters to meet a predefined EE threshold, ensuring optimal system performance. Additionally, we recognize the indispensable role of Peak-to-Average Power Ratio (PAPR) reduction techniques, particularly in multicarrier systems, to further enhance EE. As such, we employ clipping-based PAPR reduction methods to mitigate signal distortions and bolster overall efficiency. Theoretical EE metrics are derived based on formulated signal-to-interference-plus-noise ratios (SINRs), yielding insightful closed-form expressions for the operational parameters. Leveraging two distinct EE metric models, we undertake parameter determinations, accounting for the levels of approximation. Intriguingly, our analysis reveals that even simplified models exhibit remarkable applicability in real-world scenarios, with a minimal margin of error. The results not only underscore the practical applicability of our theoretical constructs but also highlight the potential for significant EE enhancements in massive MIMO systems, thereby contributing to sustainable evolution in the IoT era. Full article