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Search Results (10,254)

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19 pages, 2383 KiB  
Article
Masonry and Pictorial Surfaces Study by Laser Diagnostics: The Case of the Diana’s House in Ostia Antica
by Valeria Spizzichino, Luisa Caneve, Antonella Docci, Massimo Francucci, Massimiliano Guarneri, Daniela Tarica and Claudia Tempesta
Appl. Sci. 2025, 15(4), 2172; https://doi.org/10.3390/app15042172 - 18 Feb 2025
Abstract
The aim of the present research is to validate the combined use, through data fusion, of a Laser Induced Fluorescence (LIF) scanning system and a radar scanner (RGB-ITR, Red Green Blue Imaging Topological Radar system), as a unique tool to address the need [...] Read more.
The aim of the present research is to validate the combined use, through data fusion, of a Laser Induced Fluorescence (LIF) scanning system and a radar scanner (RGB-ITR, Red Green Blue Imaging Topological Radar system), as a unique tool to address the need for non-invasive, rapid, and low-cost techniques for both diagnostic and operational needs. The integrated system has been applied to the House of Diana complex in Ostia Antica. The main diagnostic objective of this research was to trace the materials used in different phases of restoration, from antiquity to modernity, on both masonry and pictorial surfaces, to reconstruct the history of the building. Due to the significant interest in this insula, other studies have been recently carried out on the House of Diana, but they once again highlighted the necessity of multiple approaches and non-invasive methods capable of providing quasi-real-time answers, delivering point-by-point information on very large surfaces to overcome the limits related to representativeness of sampling. The data acquired by the RGB-ITR system are quantitative, allowing for morphological and 3-colour analysis of the investigated artwork. In this work, the sensor has been used to create coloured 3D models useful for structural assessments and for locating different classes of materials. In fact, the LIF maps, which integrate knowledge about the original constituent materials and previous conservation interventions, have been used as additional layers of the tridimensional models. Therefore, the method can direct possible new investigations and restoration actions, piecing together the history of the House of Diana to build for it a safer future. Full article
15 pages, 5877 KiB  
Article
Impact of Surfactants on Silk Fibroin Self-Assembly at the Air–Water Interface
by O. Yu. Milyaeva, R. Miller, G. Loglio, A. R. Rafikova, Z. Wan and B. A. Noskov
Polymers 2025, 17(4), 529; https://doi.org/10.3390/polym17040529 - 18 Feb 2025
Abstract
Silk fibroin (SF)-based materials attract significant interest because of their biocompability and great diversity of possible morphologies. One of the approaches to obtain SF materials is the use of an air–water or oil–water interface as a template for protein self-assembly. Surfactants can change [...] Read more.
Silk fibroin (SF)-based materials attract significant interest because of their biocompability and great diversity of possible morphologies. One of the approaches to obtain SF materials is the use of an air–water or oil–water interface as a template for protein self-assembly. Surfactants can change the surface properties of adsorbed SF layers by promoting or preventing the formation of SF fiber networks. This study focuses on the influence of two typical ionic surfactants, cationic cetyltrimethylammonium bromide (CTAB) and anionic sodium dodecyl sulfate (SDS), on the dynamic properties of SF layers adsorbed at the air–water interface. The dynamic surface elasticity, surface tension, ellipsometric angle Δ, and the film thickness were measured as a function of the surface age and surfactant concentration. The morphology of the layers was evaluated by atomic force microscopy (AFM). For the adsorption layers of globular proteins, the main effect of the surfactants consists in the protein unfolding at high concentrations and in a decrease in the electrostatic adsorption barrier. In the case of SF layers, CTAB and SDS strongly influence the protein aggregation at the air–water interface. Regardless of the sign of the surfactant charge, its addition to SF solutions results in a decrease in the surface elasticity and the destruction of the ordered structure of protein fibers at concentrations higher than 1 × 10−4 M. With the further increase in the surfactant concentration, the thread-like aggregates disappear, the packing of thin fibers becomes less tight, a uniform layer disintegrates into separate islands, and finally, the protein is displaced from the interface. Full article
(This article belongs to the Collection Feature Papers in Polymer Processing and Engineering)
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Figure 1
<p>Kinetic dependencies of the dynamic surface tension (<b>a</b>,<b>c</b>) and the modulus of the dynamic surface elasticity (<b>b</b>,<b>d</b>) of 0.02 mg/mL SF solutions with addition of CTAB (<b>a</b>,<b>b</b>) and SDS (<b>c</b>,<b>d</b>), respectively, at surfactant concentrations of 0 M (black squares), 1 × 10<sup>−6</sup> M (red circles), 1 × 10<sup>−5</sup> M (green triangles), 1 × 10<sup>−4</sup> M (blue diamonds), 1.5 × 10<sup>−4</sup> M (cyan stars), 2 × 10<sup>−4</sup> M (pink snowflakes), 1 × 10<sup>−3</sup> M (orange circles), 1.5 × 10<sup>−3</sup> M (violet crossed circles), and 1 × 10<sup>−2</sup> M (brown crossed diamonds).</p>
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<p>Modulus of the dynamic surface elasticity as a function of the surface pressure of SF solutions with addition of CTAB (<b>a</b>) and SDS (<b>b</b>), respectively, at surfactant concentrations of 0 M (black squares), 1 × 10<sup>−6</sup> M (red circles), 1 × 10<sup>−5</sup> M (green triangles), 1 × 10<sup>−4</sup> M (blue diamonds), 1.5 × 10<sup>−4</sup> M (cyan stars), 2 × 10<sup>−4</sup> M (pink snowflakes), 1 × 10<sup>−3</sup> M (orange circles), 1.5 × 10<sup>−3</sup> M (violet crossed circles), and 1 × 10<sup>−2</sup> M (brown crossed diamonds).</p>
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<p>Compression isotherm of SF layers formed from SF solutions with the addition of CTAB (<b>a</b>) and SDS (<b>b</b>), respectively. Concentrations of the surfactants are as follows: 0 M (black squares), 1 × 10<sup>−6</sup> M (red circles), 5 × 10<sup>−5</sup> M (green triangles), 1 × 10<sup>−4</sup> M (blue diamonds), 5 × 10<sup>−4</sup> M (cyan stars), 1 × 10<sup>−3</sup> M (pink snowflakes), and 1 × 10<sup>−2</sup> M (orange circles).</p>
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<p>Kinetic dependencies of the ellipsometric angle Δ<sub>surf</sub><sup>0</sup> (<b>a</b>,<b>d</b>), film thickness (<b>b</b>,<b>e</b>), and adsorption (<b>c</b>,<b>f</b>) for 0.02 mg/mL SF solutions with addition of CTAB (<b>a</b>–<b>c</b>) and SDS (<b>d</b>–<b>f</b>), respectively. Concentrations of the surfactants are as follows: 0 M (black squares), 1 × 10<sup>−6</sup> M (red circles), 1 × 10<sup>−4</sup> M (green triangles), 1.5 × 10<sup>−4</sup> M (blue diamonds), 1 × 10<sup>−3</sup> M (cyan stars), 1.5 × 10<sup>−3</sup> M (pink snowflakes), and 1 × 10<sup>−2</sup> M (orange circles).</p>
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<p>AFM images of surface layers formed in pure SF solutions (<b>A</b>) and SF solutions with addition of CTAB (<b>B</b>–<b>D</b>) and SDS (<b>E</b>–<b>G</b>) and transferred from the air–water interface onto a mica surface. Concentrations of the surfactants are as follows: 0 M (<b>A</b>), 1 × 10<sup>−5</sup> M (<b>B</b>,<b>E</b>), 1.5 × 10<sup>−4</sup> M (<b>C</b>,<b>F</b>), 1 × 10<sup>−3</sup> M (<b>D</b>,<b>F</b>).</p>
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<p>Scheme of SF surface layer structure transitions under the action of the surfactant.</p>
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20 pages, 7295 KiB  
Article
Treating White Spot Lesions and Non-Carious Cervical Lesions with Amelogenin Peptide-Based Hydrogel
by Erika Bauza Nowotny, Salony Jassar, Jin-Ho Phark and Janet Moradian-Oldak
Biomimetics 2025, 10(2), 120; https://doi.org/10.3390/biomimetics10020120 - 18 Feb 2025
Abstract
Peptide-based biomimetic treatments have gained increased attention in the dental field due to their biocompatibility and minimally invasive qualities. These biomimetic approaches can replicate the native architecture of dental tissues, thus contributing to higher success rates and improved longevity of restorations. The aim [...] Read more.
Peptide-based biomimetic treatments have gained increased attention in the dental field due to their biocompatibility and minimally invasive qualities. These biomimetic approaches can replicate the native architecture of dental tissues, thus contributing to higher success rates and improved longevity of restorations. The aim of this study was first to examine the biocompatibility and stability of an amelogenin peptide-based chitosan hydrogel (P26-CS) against salivary enzymes. Second, we aimed to evaluate its efficacy in biomimetically repairing human dental lesions in situ. White spot lesions (WSLs) in enamel and non-carious cervical lesions (NCCLs) in dentin were artificially created. Chitosan (CS) improved peptide stability, while remineralization of enamel sections with P26-CS was not impeded by salivary enzymes. The peptide was not cytotoxic, irritating, or sensitizing. Fluorescently labeled P26-CS penetrated ~300 μm into the enamel of WSLs and ~100 μm into the dentin of NCCLs. After peptide treatment, quantitative light-induced fluorescence (QLF) and microcomputed tomography (μCT) indicated a gain in mineral density of WSLs. In NCCLs, scanning electron microscopy showed that the dentin was covered by a mineral layer of needle-shaped crystals. Our results show that the repair of artificial WSLs and NCCLs was achieved by P26 peptide-guided remineralization and demonstrate its potential to repair dental lesions. Full article
(This article belongs to the Special Issue Biomimetic Bonded Restorations for Dental Applications)
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<p>Peptide stability after incubation in artificial saliva with salivary enzymes. (<b>A</b>,<b>B</b>) HPLC spectra of P26 and P26-CS after incubation in artificial saliva with MMP1, MMP8, α-amylase, and lysozyme. Peptide stability was measured as the change in area of peptide peak (eluting at 30 min). Incubations for each sample were performed in triplicates (<span class="html-italic">n</span> = 3). (<b>C</b>,<b>D</b>) Peptide stability (as % of initial peptide peak area) of P26 and P26-CS (0.2 mg/mL) after incubation with individual enzymes for 30 min (<b>C</b>) and 5 h (<b>D</b>) at 37 °C. Enzymes were used at their native concentrations in humans. Ratios indicate amount of enzyme relative to peptide. (<b>E</b>) Peptide stability after incubation with all enzymes (native concentrations) at 37 °C (<span class="html-italic">n</span> = 3 per group).</p>
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<p>Evaluation of mineral density of demineralized enamel by QLF analysis after remineralization in the presence and absence of salivary enzymes. (<b>A1</b>–<b>A4</b>) Representative QLF images used to calculate ΔΔF<sub>remin</sub>, before treatment (<b>A1</b>,<b>A3</b>) and after treatment with P26-CS (<b>A2</b>,<b>A4</b>). Remineralization was carried out either in the presence (<b>A3</b>,<b>A4</b>) or absence (<b>A1</b>,<b>A2</b>) of salivary enzymes. (<b>B</b>) Statistical analysis of ΔΔF<sub>remin</sub> values of samples remineralized with P26-CS with and without enzymes. No difference was observed between the ΔΔF<sub>remin</sub> in groups with enzymes vs. the non-enzyme groups (dotted) (<span class="html-italic">p</span> &gt; 0.05; One-Way ANOVA; <span class="html-italic">n</span> = 7/group). Additionally, treatment with P26-CS resulted in mineral density gain compared to controls both in the presence and absence of enzymes (<span class="html-italic">p</span> &gt; 0.05).</p>
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<p>Penetration of Cy5-P26-CS on WSLs. After treatment, the specimens were remineralized in artificial saliva for 2 h with and without salivary enzymes (<b>A</b>,<b>B</b>, respectively). Insets in (<b>A</b>,<b>B</b>) show the white-light pictures of the block with the WSLs. Fluorescence was detected through a depth of ~390 μm. Fluorescence after 7-day remineralization at 37 °C from A (<b>C</b>) and B (<b>D</b>), respectively. Three-dimensional overlay front view (<b>E</b>–<b>H</b>) and lateral (<b>I</b>–<b>L</b>) from the z-stack showing peptide penetration (red) and enamel autofluorescence (green) from corresponding (<b>A</b>–<b>D</b>). White arrows indicate areas of peptide penetration.</p>
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<p>Cy5-P26 treated in situ NCCL. (<b>A</b>) Two-dimensional sectioning of in situ lesion after 2 h remineralization. Inset: white-light picture of the lesion. (<b>B</b>) Three-dimensional volume rendering of lateral view of lesion showing peptide penetration along the YZ plane. (<b>C</b>–<b>F</b>) Representative images of peptide penetration along the XZ plane after 1.5 h (<b>C</b>) and 7 days remin. (<b>E</b>) along with the point where it was measured in the lesion (<b>D</b>,<b>F</b>), respectively. En: enamel; D: dentin.</p>
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<p>Cy5-P26 treated in natural NCCL. (<b>A</b>) Lesion after 1.5 h remineralization showing peptide presence in enamel and dentin. Inset: white-light picture of lesion. (<b>B</b>) Lateral view of lesion showing peptide penetration along YZ plane. (<b>C</b>–<b>F</b>) Representative images of peptide penetration along the XZ plane in dentin (<b>C</b>) and enamel (<b>E</b>) along with the point where it was measured in the lesion (<b>D</b>,<b>F</b>), respectively. En: enamel; D: dentin.</p>
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<p>Assessment of mineral density of WSLs after a 21-day remineralization cycle. (<b>A1–A8</b>) Representative QLF images used to calculate ΔΔF<sub>remin</sub> showing the fluorescence of the lesion pre- and post-treatment. (<b>B</b>) Quantitative analysis of the QLF images. Treatment with P26-CS resulted in the highest ΔΔF<sub>remin</sub>. Application of P26-CS for 30 min, 2× per week (blue) or 6 h, 1× a week (red) had an almost identical effect in the ΔΔF<sub>remin</sub>. <span class="html-italic">p &gt;</span> 0.05 (<span class="html-italic">p</span> = 0.17 by One-Way ANOVA; <span class="html-italic">n</span> = 8 per group. Error bars represent standard error of the mean). FV = Fluoride Varnish (positive control).</p>
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<p>Assessment of mineral density and bone mineral density. (<b>A</b>–<b>C</b>) Representative microcomputed tomography cross section images of a block after remineralization and treatment with P26-CS (30 min, 2× a week). The ROI function (in red) was used to circumscribe the area of interest and calculate the bone mineral density (BMD) of the lesion area (<b>B</b>) as well as healthy enamel (En) above the lesion (<b>C</b>). (<b>D</b>) BMD recovery (as %) of the demineralized enamel after 21-day remineralization (<span class="html-italic">p</span> &lt; 0.0001, Chi-Square test, <span class="html-italic">n</span> = 4/ group) Multiple comparisons test, after Bonferroni’s correction, showed a significant difference between control and P26-CS, and control and FV (*** <span class="html-italic">p</span> &lt; 0.001). (<b>E</b>) Quantitative analysis by QLF showed a significant difference in ΔΔF<sub>remin</sub> amongst the groups (<span class="html-italic">p</span> = 0.015, Brown–Forsythe and Welch ANOVA, <span class="html-italic">n</span> = 4/ group), and by pairwise comparison, a significant difference between the mean ΔΔF<sub>remin</sub> of control and P26-CS (Dunette’s pairwise comparison, ** <span class="html-italic">p</span> = 0.002) was observed.</p>
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<p>Surface morphology of enamel. (<b>A</b>,<b>B</b>) Enamel of NCCLs after etching and subsequent remineralization in artificial saliva for 7 days displayed tiny crystals. (<b>C</b>,<b>D</b>). Enamel of NCCLs after etching and P26-CS treatment showed bigger crystals, with bundles of longer crystals (arrows) scattered around the surface.</p>
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<p>Dentin morphology along the surface and cross section orientations. (<b>A</b>–<b>C</b>) Dentin surface after etching (<b>A</b>), remineralization in AS (<b>B</b>), and P26-CS treatment (<b>C</b>) with corresponding elemental analysis of carbon (C), Calcium (Ca), and phosphorous (P). Etching resulted in an almost complete removal of Ca and P minerals from the surface (<b>A</b>). Remineralization in AS deposited a few minerals on the surface (<b>B</b>). Mineral content was the highest in the P26-CS-treated sample <b>(C)</b>, which also exhibited a layer of crystals that covered the tubular orifices. White arrows in (<b>C</b>) point to needle-shaped crystals. (<b>D</b>–<b>F</b>) Dentin morphology along the cross-sectional orientation. (<b>D</b>) Etch only was characterized by an absence of a superficial layer, empty tubules (orange arrow) and exposed collagen fibrils (inset, yellow arrow). (<b>E</b>) AS group presented a mostly organic superficial layer, which was narrow and characterized by exposed collagen fibrils (yellow arrow) and empty tubules (orange arrow). (<b>F</b>) After P26-CS treatment, a thicker superficial layer with markedly decreased organic content was observed, in addition to abundant deposits within the tubules (pink arrows). Insets (white boxes) show area where the EDS maps were taken.</p>
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21 pages, 783 KiB  
Article
Robust Beamfocusing for Secure NFC with Imperfect CSI
by Weijian Chen, Zhiqiang Wei and Zai Yang
Sensors 2025, 25(4), 1240; https://doi.org/10.3390/s25041240 - 18 Feb 2025
Abstract
In this paper, we consider the issue of the physical layer security (PLS) problem between two nodes, i.e., transmitter (Alice) and receiver (Bob), in the presence of an eavesdropper (Eve) in a near-field communication (NFC) system. Notably, massive multiple-input multiple-output (MIMO) arrays significantly [...] Read more.
In this paper, we consider the issue of the physical layer security (PLS) problem between two nodes, i.e., transmitter (Alice) and receiver (Bob), in the presence of an eavesdropper (Eve) in a near-field communication (NFC) system. Notably, massive multiple-input multiple-output (MIMO) arrays significantly increase array aperture, thereby rendering the eavesdroppers more inclined to lurk near the transmission end. This situation necessitates using near-field channel models to more accurately describe channel characteristics. We consider two schemes with imperfect channel estimation information (CSI). The first scheme involves a conventional multiple-input multiple-output multiple-antenna eavesdropper (MIMOME) setup, where Alice simultaneously transmits information signal and artificial noise (AN). In the second scheme, Bob operates in a full-duplex (FD) mode, with Alice transmitting information signal while Bob emits AN. We then jointly design beamforming and AN vectors to degrade the reception signal quality at Eve, based on the signal-to-interference-plus-noise ratio (SINR) of each node. To tackle the power minimization problem, we propose an iterative algorithm that includes an additional constraint to ensure adherence to specified quality-of-service (QoS) metrics. Additionally, we decompose the robust optimization problem of the two schemes into two sub-problems, with one that can be solved using generalized Rayleigh quotient methods and the other that can be addressed through semi-definite programming (SDP). Finally, our simulation results confirm the viability of the proposed approach and demonstrate the effectiveness of the protection zone for NFC systems operating with CSI. Full article
(This article belongs to the Special Issue Secure Communication for Next-Generation Wireless Networks)
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<p>The near-field secure wireless communication system.</p>
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<p>Convergence behavior of the proposed algorithm for both schemes. (<b>a</b>) When Eve is within the near-field region of Alice. (<b>b</b>) When Eve is within the near-field region of Bob.</p>
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<p>The average transmit power versus minimum required SINR <math display="inline"><semantics> <msub> <mo>Γ</mo> <mi>Req</mi> </msub> </semantics></math>.</p>
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<p>(<b>a</b>) The average transmit power versus number of Alice’s antennas <math display="inline"><semantics> <msub> <mi>N</mi> <mi mathvariant="normal">A</mi> </msub> </semantics></math>. (<b>b</b>) The average transmit power versus number of Eve’s antennas <math display="inline"><semantics> <msub> <mi>N</mi> <mi mathvariant="normal">E</mi> </msub> </semantics></math>.</p>
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<p>The average transmit power versus the distance between Alice and Eve.</p>
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<p>Normalized power heat maps for Scheme I. (<b>a</b>) Desired signal power. (<b>b</b>) Interference-plus-noise power.</p>
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<p>Normalized power heat maps for scheme II. (<b>a</b>) Desired signal power. (<b>b</b>) Interference-plus-noise power.</p>
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26 pages, 660 KiB  
Review
Understanding Young Adolescent Identity and Experiences Through Internal Dimensions: A Scoping Review
by Dezeré J. Martin, Stacie K. Pettit, Sandra L. Stacki, Kristie W. Smith and Micki M. Caskey
Educ. Sci. 2025, 15(2), 253; https://doi.org/10.3390/educsci15020253 - 18 Feb 2025
Abstract
The purpose of this study was to explore multiple facets of young adolescent identity and related experiences through a scoping literature review. Based on Gardenswartz and Rowe’s Four Layers of Diversity Model, we specifically examined extant literature around five of the internal dimensions: [...] Read more.
The purpose of this study was to explore multiple facets of young adolescent identity and related experiences through a scoping literature review. Based on Gardenswartz and Rowe’s Four Layers of Diversity Model, we specifically examined extant literature around five of the internal dimensions: gender, sexuality, race, ethnicity, and physical ability. Two overarching research questions guided this investigation: What is the range and nature of current findings on young adolescent identity and experience? What gaps exist in research on young adolescent identity and experiences? To address these research questions, our research group conducted a scoping literature review using predetermined search strings related to young adolescents, identity, and experiences. We organized and presented our results in three sections: (a) gender and sexuality, (b) race and ethnicity, and (c) physical ability and disability. For each section, we specified the relevant research details, summarized the nature and characteristics of articles reviewed in a table, and described the themes derived from the reviews of literature. An overall finding was the dearth of research on young adolescent identity and experiences. Our research highlights the importance of an intersectional approach for understanding and studying the totality of young adolescent identity and experiences. Full article
(This article belongs to the Special Issue Moving Forward: Research to Guide Middle Level Education)
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<p>The Four Layers of Diversity Model (<a href="#B26-education-15-00253" class="html-bibr">Gardenswartz &amp; Rowe, 2008</a>) * Refers to the integrative dimensions of an individual person.</p>
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16 pages, 3838 KiB  
Review
Anatomical-Based Diagnosis and Filler Injection Techniques: Lips and Philtrum
by Gi-Woong Hong, Wonseok Choi, Song-Eun Yoon, Jovian Wan and Kyu-Ho Yi
Life 2025, 15(2), 315; https://doi.org/10.3390/life15020315 - 18 Feb 2025
Abstract
Lip augmentation has become increasingly popular in aesthetic medicine, driven by advancements in dermal filler technologies and injection techniques. This review provides a comprehensive overview of lip anatomy, age-related changes, and current best practices in lip augmentation using dermal fillers. The complex structure [...] Read more.
Lip augmentation has become increasingly popular in aesthetic medicine, driven by advancements in dermal filler technologies and injection techniques. This review provides a comprehensive overview of lip anatomy, age-related changes, and current best practices in lip augmentation using dermal fillers. The complex structure of the lips, including multiple layers of skin, muscle, and mucosa, contributes to their unique appearance and function. Age-related changes, such as volume loss, thinning of the vermilion border, and flattening of the philtrum, significantly impact lip aesthetics. Understanding these changes is crucial for developing effective treatment strategies. The review discusses the importance of tailoring treatments to individual patient needs, considering factors such as ethnic variations in lip structure and cultural preferences. It emphasizes the significance of proper filler selection, with hyaluronic acid-based products being the gold standard due to their biocompatibility and reversibility. Injection techniques, including needle and cannula approaches, are described in detail, with a focus on safety and optimal aesthetic outcomes. Anatomical considerations, particularly the vascular supply to the lips, are highlighted as critical for avoiding complications during filler injections. The review also addresses the evolving approach to lip augmentation, which now focuses on restoring natural contours and addressing age-related changes in the perioral region rather than simply increasing volume. Finally, the importance of managing patient expectations and the potential for future advancements in the field are discussed, including the development of more targeted filler products and refined injection techniques. Full article
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<p>Anatomical structures of the lips.</p>
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<p>Dry and wet mucosa of the vermilion.</p>
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<p>Anatomical layers of the lips.</p>
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<p>Age-related changes in the lip and philtrum region: thinning and elongation of upper and lower lips, loss of cupid’s bow definition, equalization of lip projection, reduction in vermilion-cutaneous pout, flattening of philtral columns, down-turning of oral commissures, lengthening of the upper white lip, and volume loss in the red lips.</p>
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<p>Positioning of the suborbicularis oris fat.</p>
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<p>Course of the superior and inferior labial arteries.</p>
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<p>Topography of major perioral vessels.</p>
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<p>Lip filler injection: before (<b>A</b>) and after (<b>B</b>) treatment comparison.</p>
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<p>Lip injection techniques. Needle technique: Entry point 2–3 mm medial to oral commissures; vermilion–cutaneous border and cupid’s bow treated with linear threading and serial puncture; lip mucosa treated with retrograde fanning in the submucosal layer. Cannula technique: Entry point in skin lateral to cheilion; vermilion–cutaneous border and cupid’s bow treated with linear threading; lip mucosa treated with retrograde fanning in the submucosal layer.</p>
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<p>Philtrum injection technique: Entry point at vermilion line towards philtrum; retrograde linear threading or tiny serial punctures in the subdermal layer including deep dermis.</p>
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<p>Filler injection for thin lips before (<b>A</b>) and after (<b>B</b>) treatment comparison.</p>
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26 pages, 7794 KiB  
Article
Advancing Water Hyacinth Recognition: Integration of Deep Learning and Multispectral Imaging for Precise Identification
by Diego Alberto Herrera Ollachica, Bismark Kweku Asiedu Asante and Hiroki Imamura
Remote Sens. 2025, 17(4), 689; https://doi.org/10.3390/rs17040689 - 18 Feb 2025
Abstract
The aquatic plant species Eichhornia crassipes, commonly known as water hyacinth, is indigenous to South America and is considered an invasive species. The invasive water hyacinth has caused significant economic and ecological damage by preventing sunlight from penetrating the surface of the water, [...] Read more.
The aquatic plant species Eichhornia crassipes, commonly known as water hyacinth, is indigenous to South America and is considered an invasive species. The invasive water hyacinth has caused significant economic and ecological damage by preventing sunlight from penetrating the surface of the water, resulting in the loss of aquatic life. To quantify the invasiveness and address the issue of accurately identifying plant species, water hyacinths have prompted numerous researchers to propose approaches to detect regions occupied by water hyacinths. One such solution involves the utilization of multispectral imaging which obtain detailed information about plant species based on the surface reflectance index. This is achieved by analyzing the intensity of light spectra at different wavelengths emitted by each plant. However, the use of multispectral imagery presents a potential challenge since there are various spectral indices that can be used to capture different information. Despite the high accuracy of these multispectral images, there remains a possibility that plants similar to water hyacinths may be misclassified if the right spectral index is not chosen. Considering this challenge, the objective of this research is to develop a low-cost multispectral camera capable of capturing multispectral images. The camera will be equipped with two infrared light spectrum filters with wavelengths of 720 and 850 nanometers, respectively, as well as red, blue, and green light spectrum filters. Additionally, the implementation of the U-Net architecture is proposed for semantic segmentation to accurately identify water hyacinths, as well as other classes such as lakes and land. An accuracy rate of 96% was obtained for the identification of water hyacinths using data captured by an autonomous drone constructed in the laboratory flying at an altitude of 10 m. We also analyzed the contribution each of the infrared layers to the camera’s spectrum setup. Full article
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<p>An illustration by Assman et al. [<a href="#B36-remotesensing-17-00689" class="html-bibr">36</a>] depicting the reflectance maps obtained by a multispectral camera on vegetation.</p>
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<p>Custom multispectral camera with labeled channels: top-left NIR 850 nm (#133), top-right NIR 720 nm (#67), center RGB (#17), and bottom NoIR (#249).</p>
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<p>Captured images from the custom-built multispectral camera system: (<b>a</b>) RGB camera, (<b>b</b>) 720 nm infrared camera, (<b>c</b>) 850 nm infrared camera, and (<b>d</b>) NoIR camera.</p>
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<p>Intersection over union of the four images: (<b>a</b>) RGB camera, (<b>b</b>) 720 nm infrared camera, (<b>c</b>) 850 nm infrared camera, and (<b>d</b>) NoIR camera.</p>
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<p>Cropped images using the IOU generated after the image processing described in Algorithm 1. (<b>a</b>) RGB camera, (<b>b</b>) 720 nm infrared camera, (<b>c</b>) 850 nm infrared camera, and (<b>d</b>) NoIR camera.</p>
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<p>Dataset distribution across train, validation, and test subsets for each spectral band.</p>
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<p>Pixel-wise class distribution in the ground truth masks.</p>
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<p>U-Net architecture based on a base model with dimensions and parameters per block.</p>
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<p>NDVI-derived masks.</p>
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<p>Predicted masks.</p>
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<p>RGB image.</p>
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27 pages, 9816 KiB  
Article
Investigation of Geotechnical Seismic Isolation Systems Based on Recycled Tire Rubber–Sand Mixtures
by Doğan Sağlam and Murat Tonaroğlu
Appl. Sci. 2025, 15(4), 2133; https://doi.org/10.3390/app15042133 - 18 Feb 2025
Viewed by 173
Abstract
In geotechnical earthquake engineering, enhancing the seismic properties of foundation soil to modify the characteristics of earthquake waves transmitted to structures presents a viable solution. This study investigates the effect of placing an isolation layer, composed of a mixture of recycled tire rubber [...] Read more.
In geotechnical earthquake engineering, enhancing the seismic properties of foundation soil to modify the characteristics of earthquake waves transmitted to structures presents a viable solution. This study investigates the effect of placing an isolation layer, composed of a mixture of recycled tire rubber and sand, beneath structures to mitigate seismic forces acting on buildings situated on soil layers with high amplification potential. In other words, the role of a soil layer functioning as a seismic isolator is examined. To achieve this objective, the seismic behavior of building-type structures is analyzed through numerical simulations, supplemented by laboratory experiments available in the literature. The numerical analyses are performed in the frequency domain using the finite element method within a one-dimensional (1D) framework. To validate the feasibility of the proposed isolation layer based on parametric analysis results, comparisons are made with laboratory tests available. In the literature, seismic isolation applications with thicknesses ranging from 1 to 3 m resulted in reductions of 6.8% to 16.17% in response spectral accelerations measured at the surface, while improvements in Fourier amplitude ratios ranged between 12.03% and 13.98%. This approach aims to provide an economical and efficient solution for earthquake-resistant structures while simultaneously promoting sustainability by recycling waste tires, contributing both to environmental conservation and economic benefits. Full article
(This article belongs to the Special Issue Soil-Structure Interaction in Structural and Geotechnical Engineering)
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<p>Changes in damping ratio, shear stress amplitude, and confining pressures for 0.0%, 8%, 10% and 14% granulated rubber obtained from the three-axis compression test based on from [<a href="#B12-applsci-15-02133" class="html-bibr">12</a>].</p>
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<p>Evaluation of the variation in shear modulus with shear strain amplitude under 50 and 100 kPa confining pressures for different percentages of granular rubber.</p>
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<p>Evaluation of the variation in damping ratio and shear modulus with shear strain amplitude for granular rubber contents of 0.0%, 5%, and 10% and different confining pressures.</p>
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<p>The relationship between normalized shear modulus and shear strain amplitude for 0% granular rubber and varying confining pressures.</p>
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<p>The relationship between normalized shear modulus and shear strain amplitude for 5% granular rubber and varying confining pressures.</p>
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<p>The relationship between normalized shear modulus and shear strain amplitude for 10% granular rubber and varying confining pressures.</p>
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<p>The process of creating the DeepSoil model.</p>
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<p>Model geometry for sand with 10%, 5%, and 0% rubber content under 100 kPa confining pressure.</p>
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<p>Model geometry for sand with 10%, 5%, and 0% rubber content under 50 kPa confining pressure.</p>
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<p>Ground response spectrum for the ChiChi, Coyote, Imperial Valley, and Kocaeli earthquakes with the isolation layer composed of sand containing 10% rubber content and subjected to a confining pressure of 100 kPa.</p>
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<p>Ground response spectrum for the ChiChi, Coyote, Imperial Valley, and Kocaeli earthquakes with the isolation layer composed of sand containing 10% rubber content and subjected to a confining pressure of 50 kPa.</p>
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<p>Ground response spectrum for the ChiChi, Coyote, Imperial Valley, and Kocaeli earthquakes with the isolation layer composed of sand containing 5% rubber content and subjected to a confining pressure of 100 kPa.</p>
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<p>Ground response spectrum for the ChiChi, Coyote, Imperial Valley, and Kocaeli earthquakes with the isolation layer composed of sand containing 5% rubber content and subjected to a confining pressure of 50 kPa.</p>
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<p>Ground response spectrum for the ChiChi, Coyote, Imperial Valley, and Kocaeli earthquakes with the isolation layer composed of sand containing 0% rubber content and subjected to a confining pressure of 100 kPa.</p>
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<p>Ground response spectrum for the ChiChi, Coyote, Imperial Valley, and Kocaeli earthquakes with the isolation layer composed of sand containing 0% rubber content and subjected to a confining pressure of 50 kPa.</p>
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<p>Fourier amplitude ratio for the ChiChi, Coyote, Imperial Valley, and Kocaeli earthquakes with the isolation layer composed of sand containing 10% rubber content and subjected to a confining pressure of 100 kPa.</p>
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<p>Fourier amplitude ratio for the ChiChi, Coyote, Imperial Valley, and Kocaeli earthquakes with the isolation layer composed of sand containing 10% rubber content and subjected to a confining pressure of 50 kPa.</p>
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<p>Fourier amplitude ratio for the ChiChi, Coyote, Imperial Valley, and Kocaeli earthquakes with the isolation layer composed of sand containing 5% rubber content and subjected to a confining pressure of 100 kPa.</p>
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<p>Fourier amplitude ratio for the ChiChi, Coyote, Imperial Valley, and Kocaeli earthquakes with the isolation layer composed of sand containing 5% rubber content and subjected to a confining pressure of 50 kPa.</p>
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<p>Fourier amplitude ratio for the ChiChi, Coyote, Imperial Valley, and Kocaeli earthquakes with the isolation layer composed of sand containing 0% rubber content and subjected to a confining pressure of 100 kPa.</p>
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<p>Fourier amplitude ratio for the ChiChi, Coyote, Imperial Valley, and Kocaeli earthquakes with the isolation layer composed of sand containing 0% rubber content and subjected to a confining pressure of 50 kPa.</p>
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13 pages, 6068 KiB  
Article
Fabrication and Characterization of a Flexible Polyurethane-Based Triboelectric Nanogenerator for a Harvesting Energy System
by Saba Ejaz, Imran Shah, Shahid Aziz, Gul Hassan, Ahmed Shuja, Muhammad Asif Khan and Dong-Won Jung
Micromachines 2025, 16(2), 230; https://doi.org/10.3390/mi16020230 - 17 Feb 2025
Viewed by 183
Abstract
Powering wearable and portable devices, triboelectric nanogenerators (TENGs) are a considerably promising technology. Low-cost production, ease of fabrication, optimal efficiency, and high output performance are always key concerns in developing energy harvesting technologies. Optimum efficiency and high output are always key concerns. This [...] Read more.
Powering wearable and portable devices, triboelectric nanogenerators (TENGs) are a considerably promising technology. Low-cost production, ease of fabrication, optimal efficiency, and high output performance are always key concerns in developing energy harvesting technologies. Optimum efficiency and high output are always key concerns. This research addresses the ongoing challenge of raising efficient, flexible, and lightweight energy harvesting systems for recent wearable technologies. In this research, a triboelectric nanogenerator is proposed for harvesting the triboelectric effect. Using polyurethane (PU), a bendable TENG that is in the vertical contact separation mode was developed. UV-curable PU forms the basis of TENGs. A sponge, repurposed from landfill waste, acts by means of a spacer to maintain a consistent air gap between the tribo-layers for enhanced triboelectrification. The triboelectric nanogenerators formed a Voc approaching 500 V and a current of ~2 µA and also showed high performance with a power density of 8.53 W/m2. In addition, the triboelectric nanogenerator can light LEDs and charge capacitors, making it a self-powered energy source for portable devices, Wi-Fi, and monitoring systems. The proposed TENG provides a capable solution for sustainable, self-powered wearable electronics and has the potential for further development in energy-efficient and eco-friendly applications. Full article
(This article belongs to the Special Issue Piezoelectric Devices and System in Micromachines)
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<p>(<b>a</b>) Structure of the proposed TENG. (<b>b</b>) Zoomed-in structure of the TENG.</p>
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<p>(<b>a</b>) Complete mechanism process of the proposed TENG. (<b>b</b>) Generated Output voltage.</p>
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<p>Design principle of the TENG.</p>
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<p>(<b>a</b>) Schematic Design. (<b>b</b>) Fabrication Process of the TENG.</p>
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<p>(<b>a</b>) Schematic Design. (<b>b</b>) Fabrication Process of the TENG.</p>
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<p>(<b>a</b>) SEM image of PU. (<b>b</b>) X-ray Diffraction (XRD) Results.</p>
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<p>(<b>a</b>) Variation of the V<sub>teng</sub> by the varied x(t). (<b>b</b>) Variation of the V<sub>teng</sub> by the varied d.</p>
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<p>(<b>a</b>,<b>b</b>) TENG Voltage (V) and Current (µA) graphs with respect to time (s). (<b>c</b>) Voltage output response with varying applied forces. (<b>d</b>) Frequency-dependent output response of the TENG device.</p>
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<p>(<b>a</b>) Output voltage at 0 h and after 2 h of continuous operation. (<b>b</b>) Power Density vs. Resistance.</p>
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<p>(<b>a</b>) Full image of the fabricated TENG. (<b>b</b>) Capacitor charging by the TENG device. (<b>c</b>) LED’s glow after capacitor charging.</p>
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13 pages, 33523 KiB  
Article
Mapping Sulphide Mineralization in the Hawiah Area Using Transient Electromagnetic Methods
by Panagiotis Kirmizakis, Abid Khogali, Konstantinos Chavanidis, Timothy Eatwell, Tomos Bryan and Pantelis Soupios
Minerals 2025, 15(2), 186; https://doi.org/10.3390/min15020186 - 17 Feb 2025
Viewed by 151
Abstract
The Arabian–Nubian Shield (ANS) hosts numerous volcanogenic massive sulphide (VMS) deposits formed in submarine volcanic settings and enriched by hydrothermal processes, making it a critical region for mineral exploration due to the types of deposits it hosts and its geological complexity. The Wadi [...] Read more.
The Arabian–Nubian Shield (ANS) hosts numerous volcanogenic massive sulphide (VMS) deposits formed in submarine volcanic settings and enriched by hydrothermal processes, making it a critical region for mineral exploration due to the types of deposits it hosts and its geological complexity. The Wadi Bidah Mineral Belt (WBMB), located within the Arabian Shield, contains over 30 polymetallic VMS occurrences associated with an island arc system active between 950 and 800 million years ago. Despite its mineral potential, the WBMB still needs to be explored, with limited geophysical studies to support resource evaluation. This study focuses on the Hawiah area, a prominent VMS site within the WBMB, to delineate subsurface mineralization using transient electromagnetic (TEM) methods. TEM surveys were conducted to characterize the conductivity structure and identify potential zones of sulphide mineralization. Data were processed and inverted to generate 1D, 2D, and 3D resistivity models, providing critical insights into the depth, geometry, and continuity of the mineralized zones based on the final 3D resistivity distribution. The results revealed distinct conductive (very low resistivity) anomalies, correlating with known surface gossans and inferred sulphide-rich layers, and extended these features into the subsurface. The integration of TEM results with geological and geochemical data highlights the effectiveness of this approach in detecting and mapping concealed mineral deposits in complex geological environments. This study advances the understanding of VMS systems in the WBMB and demonstrates the potential of TEM surveys as a key tool for mineral exploration in the Arabian Shield. Full article
(This article belongs to the Special Issue Novel Methods and Applications for Mineral Exploration, Volume III)
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<p>(<b>a</b>) The location of the Hawiah VMS deposit within the Arabian Peninsula, (<b>b</b>) geological map of WBMB depicting the location of Hawiah VMS deposits (modified from Beziat and Donzeau [<a href="#B20-minerals-15-00186" class="html-bibr">20</a>]), and (<b>c</b>) the study area, including key features such as the Crossroads Lode, Central Area, and Camp Lode.</p>
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<p>Generalized cross-section of the main oxidation state zones (oxide, transitional, and fresh) in the Hawiah VMS deposit, based on Eatwell [<a href="#B21-minerals-15-00186" class="html-bibr">21</a>] and Ashley [<a href="#B22-minerals-15-00186" class="html-bibr">22</a>].</p>
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<p>(<b>a</b>) Extended area of interest around the Hawiah deposit, (<b>b</b>) survey area with TEM stations marked by green squares, and (<b>c</b>) acquisition setup for each TEM station showing the arrangements of the transmitter (100 × 100 m) and receiver (10 × 10 m) loops for data collection.</p>
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<p>Geological cross-section shows the lithological unit distribution and mineralization within the Hawiah VMS deposit. The TEM profile (red line) highlights resistivity variations associated with the mineralized zones.</p>
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<p>Resistivity depth slices from the TEM survey show variations within depth intervals ranging from 0-300 m. Each panel (<b>a</b>–<b>f</b>) represents a specific depth interval, highlighting the resistivity’s lateral and vertical distribution. The color scale reflects resistivity values in ohm-meters (Ohm.m), where lower values (blue color) indicate conductive zones and higher values (red/orange colors) represent resistive zones.</p>
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<p>Petrographic images of core samples showing various lithological and mineralogical features under plane-polarized transmitted light. All fields of view are 0.5 to 2 mm across.</p>
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24 pages, 24136 KiB  
Review
Innovation in Metal Casting Processes: A Review of Metal Matrix Nanocomposites in Metal and Bimetal Castings
by Tayyab Subhani, Mohamed Ramadan, Naglaa Fathy, Abdel Khaliq and K. S. Abdel Halim
Crystals 2025, 15(2), 191; https://doi.org/10.3390/cryst15020191 - 17 Feb 2025
Viewed by 170
Abstract
The arrival of nanotechnology in the field of metal castings is considered a promising approach to significantly improve the quality, performance and lifetime of castings. A better understanding of the implementation of nanotechnology in the metal casting process and its dynamics is essential [...] Read more.
The arrival of nanotechnology in the field of metal castings is considered a promising approach to significantly improve the quality, performance and lifetime of castings. A better understanding of the implementation of nanotechnology in the metal casting process and its dynamics is essential for the successful production of metal matrix nanocomposite castings. This review focuses on past and present techniques for metal matrix nanocomposite castings to facilitate future fabrication processes and improve the performance of casting products. The advantages, limitations, difficulties and optimal processing conditions of nanocomposite castings are presented and thoroughly discussed. Both types of metal matrix nanocomposites (i.e., ferrous and nonferrous metallic matrices, are discussed in the present review), as well as nanocomposites in the working surface layer and interlayer of bimetallic materials. Significant improvements in the surface microstructure and shear strength of bimetallic bearings are achieved using nanoparticles as additions to the surface working layer and interlayer areas. Special emphasis is given to the factors affecting these fabrication processes in achieving high-quality products. The dispersion of nanoparticles in the metallic matrix is another critical issue, which is discussed comprehensively. Moreover, the strengthening mechanisms that evolve due to the incorporation of nanoparticles in the metallic matrices, which deserve separate attention, are discussed. The economic and political factors that simultaneously lead to evolutionary and drastic changes in metal matrix nanocomposite castings are also considered. Finally, the present article indicates future fabrication routes and describes the development of metal matrix nanocomposite castings under the influence of nanotechnology after incorporating the novel casting opportunities presented by nanotechnology. Full article
(This article belongs to the Section Crystalline Metals and Alloys)
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<p>Engine block cast from aluminium alloy [<a href="#B2-crystals-15-00191" class="html-bibr">2</a>].</p>
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<p>History of the metal casting process (<b>a</b>); pouring liquid metal in mold fabricated by gravity metallic mold casting (<b>b</b>).</p>
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<p>Solidification structure of pure metal (<b>a</b>); alloy (<b>b</b>); nucleating agent’s structure (<b>c</b>).</p>
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<p>Relationship between the mismatch and supercooling (logarithm) [<a href="#B26-crystals-15-00191" class="html-bibr">26</a>,<a href="#B27-crystals-15-00191" class="html-bibr">27</a>].</p>
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<p>Schematic of the (<b>a</b>) element regional supply technique along with (<b>b</b>) casting and (<b>c</b>) tempering [<a href="#B42-crystals-15-00191" class="html-bibr">42</a>].</p>
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<p>Schematic of the experimental process for SLM (<b>a</b>); horizontal view of the domain cross-section (<b>b</b>); longitudinal view of the domain cross-section (<b>c</b>) [<a href="#B48-crystals-15-00191" class="html-bibr">48</a>].</p>
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<p>Interaction between the dendritic growth and nanoparticles during the solidification [<a href="#B54-crystals-15-00191" class="html-bibr">54</a>].</p>
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<p>Setup for the stir-casting technique (<b>a</b>) addition the reinforcing phase; stir casting process (<b>b</b>) [<a href="#B66-crystals-15-00191" class="html-bibr">66</a>].</p>
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<p>Ultrasonic processing of nanocomposites showing the stirring conducted outside (<b>a</b>) and inside the furnace (<b>b</b>) [<a href="#B68-crystals-15-00191" class="html-bibr">68</a>].</p>
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<p>Stress–strain curves of AZ31 alloy and AC-UST samples (<b>a</b>) and AZ31 alloy and Iso-UST specimens (<b>b</b>) [<a href="#B68-crystals-15-00191" class="html-bibr">68</a>].</p>
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<p>Setup for the disintegrated melt deposition technique [<a href="#B70-crystals-15-00191" class="html-bibr">70</a>].</p>
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<p>Mechanical properties of liquid AC43A cast alloy without and with the SiC nanocomposite [<a href="#B71-crystals-15-00191" class="html-bibr">71</a>].</p>
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<p>Ultrasonic nanoparticle clusters’ deagglomeration for the collapse of the cavitation (<b>a</b>); bubble and acoustic streaming (<b>b</b>) [<a href="#B77-crystals-15-00191" class="html-bibr">77</a>].</p>
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<p>Microstructure of AM60 with (<b>a</b>) and without (<b>b</b>) the addition of AlN [<a href="#B79-crystals-15-00191" class="html-bibr">79</a>].</p>
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<p>Primary Si particle size with graphene additions [<a href="#B80-crystals-15-00191" class="html-bibr">80</a>].</p>
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<p>Primary Si SF with graphene nanosheets affects [<a href="#B80-crystals-15-00191" class="html-bibr">80</a>].</p>
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<p>(<b>a</b>) Mold and (<b>b</b>) furnace employed for manufacturing nanocomposites containing tin-based Babbitt alloy while (<b>c</b>) steel after grinding and tinning, and (<b>d</b>) mold are also shown. [<a href="#B86-crystals-15-00191" class="html-bibr">86</a>].</p>
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<p>SEM images showing the morphologies of the Cu<sub>6</sub>Sn<sub>5</sub> phase in tin-based Babbitt alloy (<b>a</b>) without the addition of nanoparticles; (<b>b</b>) 0.5 wt% iron oxide nanoparticles; (<b>c</b>) 0.5 wt% silica nanoparticles; (<b>d</b>) 0.25 wt% iron oxide and 0.25 wt% silica nanoparticles [<a href="#B102-crystals-15-00191" class="html-bibr">102</a>].</p>
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16 pages, 5216 KiB  
Article
A New Approach Using Multi-Layer Films from Food Waste as a Shrink Film
by Kateřina Plevová, Michael Feuchter, Nadine Wild and Katharina Resch-Fauster
Processes 2025, 13(2), 560; https://doi.org/10.3390/pr13020560 - 17 Feb 2025
Viewed by 149
Abstract
Multi-layer films are one of the most challenging classes of polymer waste for recycling, as they consist of a mixture of constituent materials like polyethylene (PE), polyamide 6 (PA6), and ethylene vinyl alcohol (EVOH). This study investigates the characterization, washing, and mechanical properties [...] Read more.
Multi-layer films are one of the most challenging classes of polymer waste for recycling, as they consist of a mixture of constituent materials like polyethylene (PE), polyamide 6 (PA6), and ethylene vinyl alcohol (EVOH). This study investigates the characterization, washing, and mechanical properties of recycled blends derived from such multi-layer films. Raman spectroscopy and Differential Scanning Calorimetry (DSC) were used to characterize the individual components in single- and multi-layer films, and distinct properties of LDPE, LLDPE, PA6, and EVOH were observed. Mechanical properties enhanced by proper shredding, washing procedures, and multiple combinations of polyethylene blends were investigated to optimize the mechanical characteristics of the recycled materials, especially strain at break. Additionally, the shrinkage behavior of the recycled films was compared to commercial shrink films, demonstrating their potential for use in industry packaging applications. These results highlight a more sustainable possibility for multi-layer packaging applications. Full article
(This article belongs to the Special Issue Advances in Value-Added Products from Waste)
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<p>Drawing of washing device. The steel cage is filled with plastic stones and attached to the rotor, and it can be immersed in the water.</p>
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<p>(<b>a</b>) The whole spectra of SF1, SF2, and MF1 are shown; and (<b>b</b>) shows only the range of 500–2000 cm<sup>−1</sup>. Spectra are stacked for clarity.</p>
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<p>Tensile strength of washed and unwashed blends.</p>
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<p>Strain at break and tensile strength of blends with different ratios of polymers.</p>
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<p>Strain at break of blends with different LLDPE content. The percentages of SF1 and SF2 used in each blend are stated above bars.</p>
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<p>Strain at break of LLDPE_0 blends with different compatibilizers. The dashline represents strain at break of the LLDPE_0 that was used as a base for compatibilized blends.</p>
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<p>Shrinkage of the recycled material and the commercial shrink film in an oven at 180 °C.</p>
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30 pages, 17875 KiB  
Article
Development and Characterization of Novel Hybrid Particleboard Made from Several Non-Wood Lignocellulosic Materials
by Fazilla Oktaviani Tarigan, Luthfi Hakim, Agus Purwoko, Tito Sucipto, Halimatuddahliana Nasution, Widya Fatriasari, Muhammad Adly Rahandi Lubis, Jajang Sutiawan, Mohammad Irfan Bakhsi, Nam-Hun Kim, Petar Antov, Seng Hua Lee, Rangabhashiyam Selvasembian, Mohd Hazwan Hussin, Manggar Arum Aristri and Apri Heri Iswanto
Polymers 2025, 17(4), 512; https://doi.org/10.3390/polym17040512 - 16 Feb 2025
Viewed by 178
Abstract
The green transition trend in the wood-based panel industry aims to reduce environmental impact and waste production, and it is a viable approach to meet the increasing global demand for wood and wood-based materials as roundwood availability decreases, necessitating the development of composite [...] Read more.
The green transition trend in the wood-based panel industry aims to reduce environmental impact and waste production, and it is a viable approach to meet the increasing global demand for wood and wood-based materials as roundwood availability decreases, necessitating the development of composite products as alternatives to non-wood lignocellulosic raw materials. As a result, the purpose of this study is to examine and assess the physical, mechanical, and acoustic properties of particleboard manufactured from non-wood lignocellulosic biomass. The core layer was composed of non-wood lignocelluloses (banana stem, rice straw, coconut fiber, sugarcane bagasse, and fibrous vascular bundles (FVB) from snakefruit fronds), whereas the surface was made of belangke bamboo (Gigantochloa pruriens) and wood. The chemical characteristics, fiber dimensions and derivatives, and contact angles of non-wood lignocellulosic materials were investigated. The contact angle, which ranged from 44.57 to 62.37 degrees, was measured to determine the wettability of these materials toward adhesives. Hybrid particleboard (HPb) or sandwich particleboard (SPb) samples of 25 cm × 25 cm with a target density of 0.75 g/cm3 and a thickness of 1 cm were manufactured using 7% isocyanate adhesive (based on raw material oven dry weight). The physical parameters of the particleboard, including density, water content, water absorption (WA), and thickness swelling (TS), ranged from 0.47 to 0.79 g/cm3, 6.57 to 13.78%, 16.46 to 103.51%, and 3.38 to 39.91%, respectively. Furthermore, the mechanical properties of the particleboard, including the modulus of elasticity (MOE), bending strength (MOR), and internal bond strength (IB), varied from 0.39 to 7.34 GPa, 6.52 to 87.79 MPa, and 0.03 to 0.69 MPa, respectively. On the basis of these findings, the use of non-wood lignocellulosic raw materials represents a viable alternative for the production of high-performance particleboard. Full article
(This article belongs to the Special Issue New Challenges in Wood and Wood-Based Materials III)
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<p>Non-wood lignocellulosic materials.</p>
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<p>Raw materials used for the surface layers of the hybrid particleboard produced in this work.</p>
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<p>Calculation of contact angle. Description: a: liquid (adhesive), b: fiber diameter, c: distance between fibers, d: contact angle of water with fiber, e: depression from the meniscus formed by water.</p>
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<p>Three-layer particleboard.</p>
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<p>Alpha-cellulose content in non-wood lignocellulosic materials. L1: banana stem; L2: rice straw; L3: coconut husk; L4: bagasse; L5: snakefruit palm frond FVB.</p>
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<p>Hemicellulose content in non-wood lignocellulosic materials. L1: banana stem; L2: rice straw; L3: coconut husk; L4: bagasse; L5: snakefruit palm frond FVB.</p>
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<p>Holocellulose content in non-wood lignocellulosic materials. L1: banana stem; L2: rice straw; L3: coconut husk; L4: bagasse; L5: snakefruit palm frond FVB.</p>
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<p>Lignin content in non-wood lignocellulosic materials. L1: banana stem; L2: rice straw; L3: coconut husk; L4: bagasse; L5: snakefruit palm frond FVB.</p>
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<p>Extractive substance contents in non-wood lignocellulosic materials. L1: banana stem; L2: rice straw; L3: coconut husk; L4: bagasse; L5: snakefruit palm frond FVB.</p>
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<p>Ash content of non-wood lignocellulosic materials. L1: banana stem; L2: rice straw; L3: coconut husk; L4: bagasse; L5: snakefruit palm frond FVB.</p>
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<p>Fiber images of banana stems and coconut husks.</p>
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<p>Banana stem and rice straw lumens.</p>
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<p>Contact angle values for the non-wood lignocellulosic materials: L1: banana stem, L2: rice straw, L3: coconut husk, L4: bagasse, L5: snakefruit palm frond FVB.</p>
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<p>Density of SPb fabricated from non-wood lignocellulosic materials and various types of surface layers. P0: without surface layers, P1: 1 mm bamboo strand, P2: 3 mm bamboo strand, P3: 1 mm wood strand, P4: 3 mm wood strand, P5: veneer, L1: banana stem, L2: rice straw, L3: coconut husk, L4: bagasse, L5: snakefruit palm fronds FVB.</p>
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<p>Moisture content of SPb fabricated from non-wood lignocellulosic materials and various types of surface layers. P0: without surface layers, P1: 1 mm bamboo strand, P2: 3 mm bamboo strand, P3: 1 mm wood strand, P4: 3 mm wood strand, P5: veneer, L1: banana stem, L2: rice straw, L3: coconut husk, L4: bagasse, L5: snakefruit palm fronds FVB.</p>
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<p>Water absorption of SPb fabricated from non-wood lignocellulosic materials and various types of surface layers. P0: without surface layers, P1: 1 mm bamboo strand, P2: 3 mm bamboo strand, P3: 1 mm wood strand, P4: 3 mm wood strand, P5: veneer, L1: banana stem, L2: rice straw, L3: coconut husk, L4: bagasse, L5: snakefruit palm fronds FVB.</p>
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<p>Thickness swelling of SPb fabricated from non-wood lignocellulosic materials and various types of surface layers. P0: without surface layers, P1: 1 mm bamboo strand, P2: 3 mm bamboo strand, P3: 1 mm wood strand, P4: 3 mm wood strand, P5: veneer, L1: banana stem, L2: rice straw, L3: coconut husk, L4: bagasse, L5: snakefruit palm fronds FVB.</p>
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<p>MOE of SPb fabricated from non-wood lignocellulosic materials and various surface layers. P0: without surface layers, P1: 1 mm bamboo strand, P2: 3 mm bamboo strand, P3: 1 mm wood strand, P4: 3 mm wood strand, P5: veneer, L1: banana stem, L2: rice straw, L3: coconut husk, L4: bagasse, L5: snakefruit palm fronds FVB.</p>
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<p>MORs of SPb fabricated from non-wood lignocellulosic materials and various surface layers. P0: without surface layers, P1: 1 mm bamboo strand, P2: 3 mm bamboo strand, P3: 1 mm wood strand, P4: 3 mm wood strand, P5: veneer, L1: banana stem, L2: rice straw, L3: coconut husk, L4: bagasse, L5: snakefruit palm fronds FVB.</p>
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<p>Internal bonds of SPb fabricated from non-wood lignocellulosic materials and various types of surface layers. P0: without surface layers, P1: 1 mm bamboo strand, P2: 3 mm bamboo strand, P3: 1 mm wood strand, P4: 3 mm wood strand, P5: veneer, L1: banana stem, L2: rice straw, L3: coconut husk, L4: bagasse, L5: snakefruit palm fronds FVB.</p>
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<p>Sound absorption coefficient values for the particleboard samples fabricated from non-wood lignocellulosic materials without surface layers. L1P0 (banana stem board without a surface layer), L1P0 (rice straw board without surface layers), L3P0 (coconut husk board without surface layers), L4P0 (bagasse board without a surface layer), and L5P0 (FVB snakefruit palm frond board without surface layers).</p>
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<p>Sound absorption coefficient values for the surface layers of snakefruit palm fronds.</p>
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16 pages, 3047 KiB  
Article
Two-Dimensional Chromatographic Isolation of High Purity Erinacine A from Hericium erinaceus
by Katerina Naumoska, Andrej Gregori and Alen Albreht
J. Fungi 2025, 11(2), 150; https://doi.org/10.3390/jof11020150 - 15 Feb 2025
Viewed by 237
Abstract
A simple and robust two-dimensional chromatographic fractionation protocol for the isolation of the neuroprotective compound erinacine A from Hericium erinaceus is proposed. This production platform yielded 19.4 mg of erinacine A from approximately 130 g of mushroom material, with a chromatographic purity of [...] Read more.
A simple and robust two-dimensional chromatographic fractionation protocol for the isolation of the neuroprotective compound erinacine A from Hericium erinaceus is proposed. This production platform yielded 19.4 mg of erinacine A from approximately 130 g of mushroom material, with a chromatographic purity of 97.4%. The procedure includes extraction, concentration, fractionation, purification, and characterisation of the bioactive compound. The crude H. erinaceus extract was fractionated in the first dimension by normal-phase flash chromatography, and the fraction containing erinacine A was further purified in the second dimension by semi-preparative reversed-phase chromatography. This strategy utilises the orthogonality of the two chromatographic modes to effectively eliminate difficult impurities, including structural isomers and analogues of erinacine A. Complementary analytical approaches such as high-performance thin-layer chromatography (HPTLC) and high-performance liquid chromatography with ultraviolet and tandem mass spectrometric detection (HPLC–UV–MS/MS) were employed to unambiguously confirm erinacine A in the isolated fractions, while HPLC with a charged aerosol detector (CAD) was used to determine its purity. Given the limited commercial availability and the high price of erinacine A, the described method offers a straightforward and cost-effective alternative to obtain this valuable compound for further research and applications. Full article
(This article belongs to the Section Fungi in Agriculture and Biotechnology)
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<p>Schematic representation of the fractionation workflow: preliminary stage (orange), supporting analyses for isolation guidance and isolate characterisation (green), and the optimised isolation protocol (blue). The dashed blue frame highlights the key iterative steps that enabled the successful isolation of erinacine A.</p>
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<p>Flash–UV chromatogram at 340 nm showing fractions #1–4 (<b>A</b>) and UV–VIS spectrum of the erinacine A-containing fraction #3 (<b>B</b>).</p>
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<p>Chromatograms of fractions #1–4 (bands 1–4) and a custom-made erinacine A standard (band 5) using a HPTLC silica gel 60 plate. The images were acquired before (<b>A</b>) and after derivatization (<b>B</b>) with an anisaldehyde detection reagent at 366 nm (<b>A</b>) and under visible light (WhiteT) (<b>B</b>). A magnified view of track 3 (white dashed frame) reveals two partially co-eluting bands: a purple band with a lower retention factor (<b>a</b>) and a brownish band with a higher retention factor (<b>b</b>). The brownish band matched the colour of erinacine A.</p>
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<p>Total ion chromatogram (TIC) of the isolated fraction #3 from 1<sup>st</sup>D of fractionation (<b>top</b>); MS spectra of the closely eluting isobaric compounds (<b>middle</b>); and their MS/MS spectra (<b>bottom</b>). Data for the custom-made erinacine A standard are provided at the bottom of each section for reference.</p>
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<p>HPLC–UV chromatogram of fraction #3 at 340 nm (<b>A</b>) and a magnified view of the chromatogram at 340 nm (<b>B</b>) and 280 nm (<b>C</b>). The collection interval is indicated, with the green line marking the start and the red line marking the end of the collection.</p>
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<p>TIC (<b>top</b>), MS (<b>middle</b>), and MS/MS (<b>bottom</b>) spectra of the isolated erinacine A. Data for the custom-made erinacine A standard are provided at the top of each section for reference.</p>
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<p>HPLC–CAD chromatograms of erinacine A standard (black), procedural blank (filtered 70% ethanol; blue), and the erinacine A isolate (pink).</p>
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15 pages, 11855 KiB  
Article
Multi-Angle Crack Detection in CFRP Based on Line Laser Infrared Thermography Scanning Technology
by Guangyu Zhou, Zhijie Zhang, Wuliang Yin, Yu Fu and Ding’erkai Wang
Polymers 2025, 17(4), 508; https://doi.org/10.3390/polym17040508 - 15 Feb 2025
Viewed by 241
Abstract
Infrared thermography is a real-time and efficient method for defect detection. This study utilizes line laser scanning infrared thermography to detect cracks in manually laid-up unidirectional CFRP, 3D-printed CFRP cracks, and naturally occurring microcracks in CFRP deflectors. In manually layered unidirectional CFRP, detection [...] Read more.
Infrared thermography is a real-time and efficient method for defect detection. This study utilizes line laser scanning infrared thermography to detect cracks in manually laid-up unidirectional CFRP, 3D-printed CFRP cracks, and naturally occurring microcracks in CFRP deflectors. In manually layered unidirectional CFRP, detection performance is influenced by the layup direction, with cracks aligned to the layup exhibiting minimal hindrance to heat conduction, resulting in weaker high-frequency components in thermal images and poorer detection accuracy. In contrast, the composite structure of 3D-printed CFRP minimizes the impact of crack orientation. By analyzing the temperature characteristics of the crack center and thermal drag tail for cracks with varying opening angles, the study establishes a relationship between the crack opening angle, crack depth, and thermal features. Fitted curves of the ratio between crack opening angle and absolute temperature difference yielded an average R2 of 0.9828 and MSE of 0.1287, validating the effectiveness of the proposed approach. Finally, the features of microcracks in CFRP deflector plates were effectively extracted through high-frequency filtering, which demonstrated the broad applicability and robustness of this study. Full article
(This article belongs to the Special Issue Polymers for Imaging and Detection)
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<p>Line laser scanning infrared thermography detection system.</p>
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<p>Specimen A: manually layered CFRP multi-angle crack specimen.</p>
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<p>Specimen B: 3D printed CFRP multi-angle opening crack specimen.</p>
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<p>Specimen C: naturally occurring scratches in CFRP deflectors.</p>
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<p>Infrared image of a crack in specimen A swept by a line laser for 1 s.</p>
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<p>Infrared image of a crack in specimen A swept by a line laser for 1 s.</p>
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<p>Ratio of crack center to regional mean temperature boxed in <a href="#polymers-17-00508-f005" class="html-fig">Figure 5</a>.</p>
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<p>Before and after processing images of three cracks detected by a line laser.</p>
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<p>Differential images of cracks with depths of 1.5 mm and different opening angles.</p>
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<p>Schematic illustration of the phenomenon of obstruction of heat conduction by oblique opening crack.</p>
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<p>Line temperature response of the crack in <a href="#polymers-17-00508-f008" class="html-fig">Figure 8</a>.</p>
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<p>Trend of regional temperature with crack opening angle.</p>
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<p>Fitted curves of crack absolute temperature difference ratio versus crack opening angle for cracks of different depths.</p>
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<p>Raw infrared images of natural scratches detected by line laser scanning.</p>
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<p>High-frequency filtering results for differential images of natural scratches.</p>
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