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Search Results (9,673)

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26 pages, 41998 KiB  
Article
Spatial Prediction of Soil Continuous and Categorical Properties Using Deep Learning Approaches for Tamil Nadu, India
by Thamizh Vendan Tarun Kshatriya, Ramalingam Kumaraperumal, Sellaperumal Pazhanivelan, Nivas Raj Moorthi, Dhanaraju Muthumanickam, Kaliaperumal Ragunath and Jagadeeswaran Ramasamy
Agronomy 2024, 14(11), 2707; https://doi.org/10.3390/agronomy14112707 (registering DOI) - 17 Nov 2024
Viewed by 143
Abstract
Large-scale mapping of soil resources can be crucial and indispensable for several of the managerial applications and policy implications. With machine learning models being the most utilized modeling technique for digital soil mapping (DSM), the implementation of model-based deep learning methods for spatial [...] Read more.
Large-scale mapping of soil resources can be crucial and indispensable for several of the managerial applications and policy implications. With machine learning models being the most utilized modeling technique for digital soil mapping (DSM), the implementation of model-based deep learning methods for spatial soil predictions is still under scrutiny. In this study, soil continuous (pH and OC) and categorical variables (order and suborder) were predicted using deep learning–multi layer perceptron (DL-MLP) and one-dimensional convolutional neural networks (1D-CNN) for the entire state of Tamil Nadu, India. For training the deep learning models, 27,098 profile observations (0–30 cm) were extracted from the generated soil database, considering soil series as the distinctive stratum. A total of 43 SCORPAN-based environmental covariates were considered, of which 37 covariates were retained after the recursive feature elimination (RFE) process. The validation and test results obtained for each of the soil attributes for both the algorithms were most comparable with the DL-MLP algorithm depicting the attributes’ most intricate spatial organization details, compared to the 1D-CNN model. Irrespective of the algorithms and datasets, the R2 and RMSE values of the pH attribute ranged from 0.15 to 0.30 and 0.97 to 1.15, respectively. Similarly, the R2 and RMSE of the OC attribute ranged from 0.20 to 0.39 and 0.38 to 0.42, respectively. Further, the overall accuracy (OA) of the order and suborder classification ranged from 39% to 67% and 35% to 64%, respectively. The explicit quantification of the covariate importance derived from the permutation feature importance implied that both the models tried to incorporate the covariate importance with respect to the genesis of the soil attribute under study. Such approaches of the deep learning models integrating soil–environmental relationships under limited parameterization and computing costs can serve as a baseline study, emphasizing opportunities in increasing the transferability and generalizability of the model while accounting for the associated environmental dependencies. Full article
(This article belongs to the Section Precision and Digital Agriculture)
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<p>(<b>a</b>) Locational information of the study area, illustrated using the true color composite (TCC) derived from a three-month composite of Landsat 8 (March to May). (<b>b</b>) Elevation map represented using SRTM DEM datasets.</p>
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<p>Graphical representation of the DL-MLP model architecture.</p>
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<p>Graphical representation of the 1D-CNN model architecture.</p>
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<p>The frequency chart of the lowest-ranked covariates occurring in the soil properties to be predicted.</p>
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<p>Predicted soil pH maps derived from (<b>a</b>) DL-MLP, (<b>b</b>) 1D-CNN, and (<b>c</b>) the legacy soil pH map.</p>
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<p>Predicted soil organic carbon maps derived from (<b>a</b>) DL-MLP, (<b>b</b>) 1D-CNN, and (<b>c</b>) the legacy soil pH map.</p>
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<p>Predicted soil order maps derived from (<b>a</b>) DL-MLP, (<b>b</b>) 1D-CNN, and (<b>c</b>) the legacy soil order map.</p>
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<p>Predicted soil suborder maps derived from (<b>a</b>) DL-MLP, (<b>b</b>) 1D-CNN, and (<b>c</b>) the legacy soil suborder map.</p>
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17 pages, 4011 KiB  
Article
High-Performance Ammonia QCM Sensor Based on SnO2 Quantum Dots/Ti3C2Tx MXene Composites at Room Temperature
by Chong Li, Ran Tao, Jinqiao Hou, Huanming Wang, Chen Fu and Jingting Luo
Nanomaterials 2024, 14(22), 1835; https://doi.org/10.3390/nano14221835 (registering DOI) - 16 Nov 2024
Viewed by 331
Abstract
Ammonia (NH3) gas is prevalent in industrial production as a health hazardous gas. Consequently, it is essential to develop a straightforward, reliable, and stable NH3 sensor capable of operating at room temperature. This paper presents an innovative approach to modifying [...] Read more.
Ammonia (NH3) gas is prevalent in industrial production as a health hazardous gas. Consequently, it is essential to develop a straightforward, reliable, and stable NH3 sensor capable of operating at room temperature. This paper presents an innovative approach to modifying SnO2 colloidal quantum dots (CQDs) on the surface of Ti3C2Tx MXene to form a heterojunction, which introduces a significant number of adsorption sites and enhances the response of the sensor. Zero-dimensional (0D) SnO2 quantum dots and two-dimensional (2D) Ti3C2Tx MXene were prepared by solvothermal and in situ etching methods, respectively. The impact of the mass ratio between two materials on the performance was assessed. The sensor based on 12 wt% Ti3C2Tx MXene/SnO2 composites demonstrates excellent performance in terms of sensitivity and response/recovery speed. Upon exposure to 50 ppm NH3, the frequency shift in the sensor is −1140 Hz, which is 5.6 times larger than that of pure Ti3C2Tx MXene and 2.8 times higher than that of SnO2 CQDs. The response/recovery time of the sensor for 10 ppm NH3 was 36/54 s, respectively. The sensor exhibited a theoretical detection limit of 73 ppb and good repeatability. Furthermore, a stable sensing performance can be maintained after 30 days. The enhanced sensor performance can be attributed to the abundant active sites provided by the accumulation/depletion layer in the Ti3C2Tx/SnO2 heterojunction, which facilitates the adsorption of oxygen molecules. This work promotes the gas sensing application of MXenes and provides a way to improve gas sensing performance. Full article
16 pages, 4235 KiB  
Article
Mobile Accelerometer Applications in Core Muscle Rehabilitation and Pre-Operative Assessment
by Aleš Procházka, Daniel Martynek, Marie Vitujová, Daniela Janáková, Hana Charvátová and Oldřich Vyšata
Sensors 2024, 24(22), 7330; https://doi.org/10.3390/s24227330 (registering DOI) - 16 Nov 2024
Viewed by 380
Abstract
Individual physiotherapy is crucial in treating patients with various pain and health issues, and significantly impacts abdominal surgical outcomes and further medical problems. Recent technological and artificial intelligent advancements have equipped healthcare professionals with innovative tools, such as sensor systems and telemedicine equipment, [...] Read more.
Individual physiotherapy is crucial in treating patients with various pain and health issues, and significantly impacts abdominal surgical outcomes and further medical problems. Recent technological and artificial intelligent advancements have equipped healthcare professionals with innovative tools, such as sensor systems and telemedicine equipment, offering groundbreaking opportunities to monitor and analyze patients’ physical activity. This paper investigates the potential applications of mobile accelerometers in evaluating the symmetry of specific rehabilitation exercises using a dataset of 1280 tests on 16 individuals in the age range between 8 and 75 years. A comprehensive computational methodology is introduced, incorporating traditional digital signal processing, feature extraction in both time and transform domains, and advanced classification techniques. The study employs a range of machine learning methods, including support vector machines, Bayesian analysis, and neural networks, to evaluate the balance of various physical activities. The proposed approach achieved a high classification accuracy of 90.6% in distinguishing between left- and right-side motion patterns by employing features from both the time and frequency domains using a two-layer neural network. These findings demonstrate promising applications of precise monitoring of rehabilitation exercises to increase the probability of successful surgical recovery, highlighting the potential to significantly enhance patient care and treatment outcomes. Full article
(This article belongs to the Special Issue Robust Motion Recognition Based on Sensor Technology)
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<p>Principle of data processing during rehabilitation exercises presenting (<b>a</b>) mobile Matlab initialization, (<b>b</b>) data acquisition using accelerometric sensors inside the smartphone, (<b>c</b>) export of recorded signals to the remote drive, and (<b>d</b>) processing of data on the remote drive in time and frequency domains to extract motion features and evaluate the coefficient of symmetry.</p>
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<p>Selected rehabilitation exercises used for accelerometric data acquisition recorded by wearable sensors (red squares) located on the left and right sides of the body used for data acquisition and processing in the computational and visualization environment of the mobile Matlab system.</p>
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<p>Principle of data processing during rehabilitation exercises presenting (<b>a</b>) animation of motion exercises to train individuals and data acquisition using a smartphone, (<b>b</b>) data import into the proposed web-page, (<b>c</b>) frequency domain remote signal processing including symmetry coefficient estimation, and (<b>d</b>) extraction and analysis of motion features.</p>
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<p>Symmetry criteria for 8 rehabilitation exercises evaluated by (<b>a</b>) time domain and (<b>b</b>) mixed-domain features presenting mean values by 16 tests of different individuals with 10 repetitions of each rehabilitation exercise.</p>
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<p>Comparison of symmetry criteria for 16 tests involving different individuals and eight rehabilitation exercises, evaluated using time domain and spectral domain features.</p>
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<p>Comparison of distribution of the time and spectral domain features for selected exercises of (<b>a</b>) prevailing asymmetric motion (individual 6, exercise 6) and (<b>b</b>) prevailing symmetric motion (individual 10, exercise 5) with centers of the right and left side positions and <span class="html-italic">c</span> multiples of standard deviations for <math display="inline"><semantics> <mrow> <mi>c</mi> <mo>=</mo> <mn>0.2</mn> <mo>,</mo> <mn>0.5</mn> <mo>,</mo> <mn>1</mn> </mrow> </semantics></math>.</p>
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<p>Classification of symmetry features of the body cross-motion by mixed features using (<b>a</b>) support vector machine, (<b>b</b>) the Bayes method, and (<b>c</b>) the two-layer neural network for a selected individual 6-DH.</p>
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20 pages, 17929 KiB  
Article
Experimental Identification of a New Secondary Wave Pattern in Transonic Cascades with Porous Walls
by Valeriu Drăgan, Oana Dumitrescu, Mihnea Gall, Emilia Georgiana Prisăcariu and Bogdan Gherman
Aerospace 2024, 11(11), 946; https://doi.org/10.3390/aerospace11110946 (registering DOI) - 16 Nov 2024
Viewed by 188
Abstract
Turbomachinery shock wave patterns occur as a natural result of operating at off-design points and are accountable for some of the loss in performance. In some cases, shock wave–boundary layer (SW-BLIs) interactions may even lead to map restrictions. The current paper refers to [...] Read more.
Turbomachinery shock wave patterns occur as a natural result of operating at off-design points and are accountable for some of the loss in performance. In some cases, shock wave–boundary layer (SW-BLIs) interactions may even lead to map restrictions. The current paper refers to experimental findings on a transonic linear cascade specifically designed to mitigate shock waves using porous walls on the blades. Schlieren visualization reveals two phenomena: Firstly, the shock waves were dissipated in all bladed passages, as predicted by the CFD studies. Secondly, a lower-pressure wave pattern was observed upstream of the blades. It is this phenomenon that the paper reports and attempts to describe. Attempts to replicate this pattern using Reynolds-averaged Navier–Stokes (RANS) calculations indicate that the numerical method may be too dissipative to accurately capture it. The experimental campaign demonstrated a 4% increase in flow rate, accompanied by minimal variations in pressure and temperature, highlighting the potential of this approach for enhancing turbomachinery performance. Full article
(This article belongs to the Section Aeronautics)
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<p>Vanes after surface finishing: (<b>a</b>) porous walls; (<b>b</b>) reference case, with no flow control.</p>
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<p>Linear cascade facility overview.</p>
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<p>P&amp;ID diagram for linear cascade facility.</p>
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<p>Schlieren system for flow visualization with knife edge.</p>
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<p>Mesh convergence study.</p>
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<p>Linear cascade computational grid with channel details. (<b>a</b>) test area; (<b>b</b>) zoomed-in view of the second channel.</p>
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<p>Computational grid, with blade details: (<b>a</b>) leading edge; (<b>b</b>) trailing edge.</p>
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<p>Distribution of the dimensionless distance to the wall (y+): (<b>a</b>) vanes surface; (<b>b</b>) perforated plate.</p>
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<p>Computational domain and boundary conditions.</p>
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<p>Schlieren images: (<b>a</b>) no control and no filter, with knife edge [<a href="#B28-aerospace-11-00946" class="html-bibr">28</a>]; (<b>b</b>) passive control and gradual color filter (upper corner, right). Inlet static pressure of 70,000 Pa gauge.</p>
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<p>Schlieren images: (<b>a</b>) no control and no filter, with knife edge [<a href="#B28-aerospace-11-00946" class="html-bibr">28</a>]; (<b>b</b>) passive control and color filter. Inlet static pressure of 80,000 Pa gauge.</p>
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<p>Schlieren images: (<b>a</b>) no control and no filter [<a href="#B28-aerospace-11-00946" class="html-bibr">28</a>]; (<b>b</b>) passive control. Inlet static pressure of 90,000 Pa gauge.</p>
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<p>Pressure distribution in the linear cascade, median plane: (<b>a</b>) no control [<a href="#B28-aerospace-11-00946" class="html-bibr">28</a>]; (<b>b</b>) passive control.</p>
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<p>Density gradient distribution, median plane: (<b>a</b>) no control [<a href="#B28-aerospace-11-00946" class="html-bibr">28</a>]; (<b>b</b>) passive control.</p>
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<p>Velocity vectors in Channel 3 of the linear cascade: (<b>a</b>) Channel 3 top view; (<b>b</b>) perforated plate and cavity detail.</p>
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<p>Reference lines, upstream and downstream of the test area.</p>
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<p>Pressure profile along the mid-height measurement line upstream and downstream of the blades, with a 0.013 m distance.</p>
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<p>Velocity profile along the mid-height measurement line upstream and downstream of the blades, with a 0.013 m distance.</p>
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<p>Effect of passive control on key operating parameters: (<b>a</b>) mass flow rate, (<b>b</b>) total inlet temperature variation, and (<b>c</b>) inlet static pressure variation.</p>
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<p>Influence of porous wall on overall flow rate and flow structure: (<b>a</b>) no control; (<b>b</b>) passive control.</p>
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<p>Impact of passive control on the splitter: (<b>a</b>) first splitter with passive control; (<b>b</b>) second splitter no control.</p>
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<p>Influence of passive control on the main blade: (<b>a</b>) second main blade with passive control; (<b>b</b>) first main blade with no control.</p>
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12 pages, 877 KiB  
Article
Students and Clinical Teachers’ Experiences About Productive Feedback Practices in the Clinical Workplace from a Sociocultural Perspective
by Javiera Fuentes-Cimma, Dominique Sluijsmans, Javiera Ortega-Bastidas, Ignacio Villagran, Arnoldo Riquelme-Perez and Sylvia Heeneman
Int. Med. Educ. 2024, 3(4), 461-472; https://doi.org/10.3390/ime3040035 (registering DOI) - 16 Nov 2024
Viewed by 147
Abstract
For feedback to be productive, it relies on the interactions of participants, design elements, and resources. Yet, complexities in clinical education pose challenges for feedback practices in students and teachers, and efforts to improve feedback often ignore the influence of culture and context. [...] Read more.
For feedback to be productive, it relies on the interactions of participants, design elements, and resources. Yet, complexities in clinical education pose challenges for feedback practices in students and teachers, and efforts to improve feedback often ignore the influence of culture and context. A recent sociocultural approach to feedback practices recognized three layers to understand the complexity of productive feedback: the encounter layer, the design layer, and the knowledge layer. This study explores the sociocultural factors that influence productive feedback practices in clinical settings from the clinical teacher–student dyad perspective. A cross-sectional qualitative study in a physiotherapy clerkship involved semi-structured interviews with ten students and eight clinical educators. Convenience sampling was used, and participation was voluntary. Employing thematic analysis from a sociocultural perspective, this study examined feedback practices across the three layers of feedback practices. The analysis yielded different elements along the three layers that enable productive feedback practices in the clinical workplace: (1) the feedback encounter layer: dyadic relationships, mutual trust, continuity of supervision, and dialogue; (2) the feedback design layer: enabled learning opportunities and feedback scaffolding; (3) the knowledge domain layer in the clinical culture: Growing clinical experience and accountability. In the context of undergraduate clinical education, productive feedback practices are shaped by social–cultural factors. Designing feedback practices should consciously integrate these components, such as cultivating relationships, fostering guidance, enhancing feedback agency, and enabling supervised autonomy to promote productive feedback. Full article
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<p>The three-layer descriptive model of the constitutive relations of productive feedback practices. Reproduced with permission [<a href="#B10-ime-03-00035" class="html-bibr">10</a>].</p>
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<p>The three layers that are involved in feedback practices in clinical education.</p>
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12 pages, 675 KiB  
Article
Interpretable Embeddings for Next Point-of-Interest Recommendation via Large Language Model Question–Answering
by Jiubing Chen, Haoyu Wang, Jianxin Shang and Chaomurilige
Mathematics 2024, 12(22), 3592; https://doi.org/10.3390/math12223592 (registering DOI) - 16 Nov 2024
Viewed by 251
Abstract
Next point-of-interest (POI) recommendation provides users with location suggestions that they may be interested in, allowing them to explore their surroundings. Existing sequence-based or graph-based POI recommendation methods have matured in capturing spatiotemporal information; however, POI recommendation methods based on large language models [...] Read more.
Next point-of-interest (POI) recommendation provides users with location suggestions that they may be interested in, allowing them to explore their surroundings. Existing sequence-based or graph-based POI recommendation methods have matured in capturing spatiotemporal information; however, POI recommendation methods based on large language models (LLMs) focus more on capturing sequential transition relationships. This raises an unexplored challenge: how to leverage LLMs to better capture geographic contextual information. To address this, we propose interpretable embeddings for next point-of-interest recommendation via large language model question–answering, named QA-POI, which transforms the POI recommendation task into obtaining interpretable embeddings via LLM prompts, followed by lightweight MLP fine-tuning. We introduce question–answer embeddings, which are generated by asking LLMs yes/no questions about the user’s trajectory sequence. By asking spatiotemporal questions about the trajectory sequence, we aim to extract as much spatiotemporal information from the LLM as possible. During training, QA-POI iteratively selects the most valuable subset of potential questions from a set of questions to prompt the LLM for the next POI recommendation. It is then fine-tuned for the next POI recommendation task using a lightweight Multi-Layer Perceptron (MLP). Extensive experiments on two datasets demonstrate the effectiveness of our approach. Full article
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<p>An example of a check-in sequence in a trajectory where the selection of candidate POIs is influenced by multiple factors, with geographical factors playing a significant role. Note that the dashed arrows denote the historical trajectory while the dotted ones stand for the potential visit of the next check-in. The numbers denote the order of check-ins.</p>
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<p>It illustrates the architecture of our proposed model. It consists of (1) a prompt template for generating input text modules, (2) a module for learning to answer yes/no question sets, (3) an MLP fine-tuning module, and (4) a prediction module. In particular, (1) is our proposed prompt template that incorporates various comprehensive factors to prompt the LLM to automatically generate questions; (2) continues to input these questions into the LLM to produce representation vectors and trims the question set based on the prediction results; (3) uses an MLP to further fine-tune the model parameters; and (4) the prediction module outputs a top-k set of potential target candidates.</p>
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<p>The performance comparison about the dimension <span class="html-italic">d</span>, the number of question <span class="html-italic">P</span>. The circles and squares denote the scores on Foursquare and Gowalla, respectively.</p>
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15 pages, 4958 KiB  
Article
Chondrogenic Cancer Grading by Combining Machine and Deep Learning with Raman Spectra of Histopathological Tissues
by Gianmarco Lazzini and Mario D’Acunto
Appl. Sci. 2024, 14(22), 10555; https://doi.org/10.3390/app142210555 (registering DOI) - 15 Nov 2024
Viewed by 275
Abstract
Raman spectroscopy (RS) is a promising tool for cancer diagnosis. In particular, in the last years several studies have demonstrated how the diagnostic performances of RS can be significantly improved by employing machine learning (ML) algorithms for the interpretation of Raman-based data. Recently, [...] Read more.
Raman spectroscopy (RS) is a promising tool for cancer diagnosis. In particular, in the last years several studies have demonstrated how the diagnostic performances of RS can be significantly improved by employing machine learning (ML) algorithms for the interpretation of Raman-based data. Recently, it has been demonstrated that RS can perform an accurate classification of chondrosarcoma tissues. Chondrosarcoma is a cancer of bones, that can occur in the soft tissues near the bones. It is normally characterized by three different malignant degrees and a benign counterpart, knows as enchondroma. In line with these findings, in this paper, we exploited ML algorithms to distinguish, as well as possible, between the three grades of chondrosarcoma and to distinguish between chondrosarcoma and enchondroma. We obtained a high level of accuracy of classification by analyzing a dataset composed of a relatively small number of Raman spectra, collected in a previous study by one of the authors of this paper. Such spectra were acquired from micrometric tissue sections with a confocal Raman microscope. We tested the classification performances of a support vector machine (SVM) and a random forest classifier (RFC), as representatives of ML algorithms, and two versions of the multi-layer perceptron (MLPC) as representatives of deep learning (DL). These models, especially RFC and MLPC, showed excellent classification performances, with accuracy reaching 99.7%. This outcome makes the aforementioned models a promising route for future improvements of diagnostic devices focused on detecting cancerous bone tissues. Alongside the diagnostic purpose, the aforementioned approach allowed us to identify characteristic molecules, i.e., amino acids, nucleic acids, and bioapatites, relevant for obtaining the final diagnostic response, through the use of a tool named by us Raman Band Identification (RBI). The method to evaluate RBI is the most important contribution of this paper, because RBI could represent a relevant parameter for the identification of biochemical processes on the basis of the tumor progression and associated malignant degree. In turn, the spectral bands highlighted by RBI could provide precious indicators in an attempt to restrict the spectral acquisition to specific Raman bands. This last objective could help to reduce the amount of experimental data needed to obtain an accurate final grading outcome, with a consequent reduction in the computational cost. Full article
20 pages, 6407 KiB  
Article
Prediction of Breakdown Pressure Using a Multi-Layer Neural Network Based on Supercritical CO2 Fracturing Data
by Xiufeng Zhang, Min Zhang, Shuyuan Liu and Heyang Liu
Appl. Sci. 2024, 14(22), 10545; https://doi.org/10.3390/app142210545 - 15 Nov 2024
Viewed by 282
Abstract
Hydraulic fracturing is a widely employed technique for stimulating unconventional shale gas reservoirs. Supercritical CO2 (SC-CO2) has emerged as a promising fracturing fluid due to its unique physicochemical properties. Existing theoretical models for calculating breakdown pressure often fail to accurately [...] Read more.
Hydraulic fracturing is a widely employed technique for stimulating unconventional shale gas reservoirs. Supercritical CO2 (SC-CO2) has emerged as a promising fracturing fluid due to its unique physicochemical properties. Existing theoretical models for calculating breakdown pressure often fail to accurately predict the outcomes of SC-CO2 fracturing due to the complex, nonlinear interactions among multiple influencing factors. In this study, we conducted fracturing experiments considering parameters such as fluid type, flow rate, temperature, and confining pressure. A fully connected neural network was then employed to predict breakdown pressure, integrating both our experimental data and published datasets. This approach facilitated the identification of key influencing factors and allowed us to quantify their relative importance. The results demonstrate that SC-CO2 significantly reduces breakdown pressure compared to traditional water-based fluids. Additionally, breakdown pressure increases with higher confining pressures and elevated flow rates, while it decreases with increasing temperatures. The multi-layer neural network achieved high predictive accuracy, with R, RMSE, and MAE values of 0.9482 (0.9123), 3.424 (4.421), and 2.283 (3.188) for training (testing) sets, respectively. Sensitivity analysis identified fracturing fluid type and tensile strength as the most influential factors, contributing 28.31% and 21.39%, respectively, followed by flow rate at 12.34%. Our findings provide valuable insights into the optimization of fracturing parameters, offering a promising approach to better predict breakdown pressure in SC-CO2 fracturing operations. Full article
(This article belongs to the Special Issue Development and Production of Oil Reservoirs)
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<p>Flow chart of the shale specimen preparation for the experiments. UCS denotes uniaxial compressive strength. <math display="inline"><semantics> <mrow> <mi mathvariant="sans-serif">ϕ</mi> <mn>50</mn> <mo> </mo> <mo>*</mo> <mo> </mo> <mn>100</mn> </mrow> </semantics></math> and <math display="inline"><semantics> <mrow> <mi mathvariant="sans-serif">ϕ</mi> <mn>50</mn> <mo> </mo> <mo>*</mo> <mo> </mo> <mn>25</mn> </mrow> </semantics></math> denote cylindrical specimens with a diameter of 50 mm and heights of 100 mm and 25 mm, respectively. “<math display="inline"><semantics> <mrow> <mi mathvariant="sans-serif">ϕ</mi> </mrow> </semantics></math>” is the symbol that typically represents diameter, and “<math display="inline"><semantics> <mrow> <mo>*</mo> </mrow> </semantics></math>” is a notation for the dimension.</p>
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<p>Experimental apparatus used for hydraulic fracturing tests. AE refers to acoustic emission, while FPC stands for flexible printed circuit.</p>
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<p>Fracturing experiment schemes.</p>
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<p>Injection pressure versus time under various flow rates.</p>
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<p>Breakdown pressure under different fracturing schemes.</p>
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<p>Comparison between theoretical and experimental results. The areas shaded in green, blue, yellow, and red represent the scheme of fracturing fluid type, flow rate, temperature, and confining pressure, respectively. Black circle means the value of the breakdown pressure.</p>
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<p>Schematic diagram of a multi-layer neural network model.</p>
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<p>Performance of the neural network model on the training set: (<b>a</b>) Training loss curve, illustrating the model’s reduction in prediction error across epochs, which demonstrates the model’s learning process and its convergence toward minimizing error on known data; (<b>b</b>) training accuracy curve, showing the model’s predictive accuracy on the training set over epochs, indicating the model’s capacity to accurately capture the relationships between variables affecting breakdown pressure.</p>
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<p>Performance of the neural network model on the testing set: (<b>a</b>) Testing loss curve, showing the reduction in prediction error across epochs, which indicates the model’ ability to generalize and converge toward minimizing prediction error on unseen data; (<b>b</b>) testing accuracy curve, representing the model’s predictive accuracy on the testing set over epochs, reflecting its capability to generalize and correctly predict breakdown pressure under various experimental conditions.</p>
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<p>Correlation between actual values and predictive values: (<b>a</b>) Training dataset; (<b>b</b>) predicting dataset.</p>
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<p>Comparison of actual values and predictive values.</p>
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<p>The relative importance of influencing variables.</p>
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<p>Stress distribution leading to rock formation breakdown: (<b>a</b>) In situ circumferential stress field resulting from the maximum and minimum horizontal stresses; (<b>b</b>) circumferential stress induced by the injection pressure of the fracturing fluid within the wellbore; (<b>c</b>) circumferential stress attributed to pore pressure distribution throughout the rock mass; (<b>d</b>) total circumferential stress distribution after the superimposition of all three components [<a href="#B28-applsci-14-10545" class="html-bibr">28</a>].</p>
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20 pages, 5794 KiB  
Article
Advanced Bearing-Fault Diagnosis and Classification Using Mel-Scalograms and FOX-Optimized ANN
by Muhammad Farooq Siddique, Wasim Zaman, Saif Ullah, Muhammad Umar, Faisal Saleem, Dongkoo Shon, Tae Hyun Yoon, Dae-Seung Yoo and Jong-Myon Kim
Sensors 2024, 24(22), 7303; https://doi.org/10.3390/s24227303 - 15 Nov 2024
Viewed by 248
Abstract
Accurate and reliable bearing-fault diagnosis is important for ensuring the efficiency and safety of industrial machinery. This paper presents a novel method for bearing-fault diagnosis using Mel-transformed scalograms obtained from vibrational signals (VS). The signals are windowed and pass through a Mel filter [...] Read more.
Accurate and reliable bearing-fault diagnosis is important for ensuring the efficiency and safety of industrial machinery. This paper presents a novel method for bearing-fault diagnosis using Mel-transformed scalograms obtained from vibrational signals (VS). The signals are windowed and pass through a Mel filter bank, converting them into a Mel spectrum. These scalograms are subsequently fed into an autoencoder comprising convolutional and pooling layers to extract robust features. The classification is performed using an artificial neural network (ANN) optimized with the FOX optimizer, which replaces traditional backpropagation. The FOX optimizer enhances synaptic weight adjustments, leading to superior classification accuracy, minimal loss, improved generalization, and increased interpretability. The proposed model was validated on a laboratory dataset obtained from a bearing testbed with multiple fault conditions. Experimental results demonstrate that the model achieves perfect precision, recall, F1-scores, and an AUC of 1.00 across all fault categories, significantly outperforming comparison models. The t-SNE plots illustrate clear separability between different fault classes, confirming the model’s robustness and reliability. This approach offers an efficient and highly accurate solution for real-time predictive maintenance in industrial applications. Full article
(This article belongs to the Special Issue Feature Papers in Fault Diagnosis & Sensors 2024)
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<p>The complete workflow of the proposed model for bearing-fault detection.</p>
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<p>Mel-transformed scalograms of bearing faults: (<b>a</b>) IRF (<b>b</b>) NC (<b>c</b>) ORF (<b>d</b>) RF.</p>
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<p>Architecture of ANN.</p>
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<p>Working of FOX–ANN.</p>
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<p>Experimental setup for bearing dataset.</p>
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<p>Schematic diagram of experimental setup for bearing-fault diagnosis.</p>
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<p>Vibration time-domain signals for different bearing-fault conditions: (<b>a</b>) IRF, (<b>b</b>) NC, (<b>c</b>) ORF, (<b>d</b>) RF.</p>
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<p>Vibration time-domain signals for different bearing-fault conditions: (<b>a</b>) IRF, (<b>b</b>) NC, (<b>c</b>) ORF, (<b>d</b>) RF.</p>
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<p>Fault components used during the experiment: (<b>a</b>) IRF, (<b>b</b>) ORF, (<b>c</b>) RF.</p>
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<p>Proposed model: (<b>a</b>) accuracy vs. number of epochs and (<b>b</b>) losses vs. number of epochs.</p>
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<p>Performance metrics comparison of the (<b>a</b>) proposed model, (<b>b</b>) Zhang et al., and (<b>c</b>) Fu et al.</p>
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<p>Confusion matrices comparison of the (<b>a</b>) proposed model with (<b>b</b>) Zhang et al. and (<b>c</b>) Fu et al.</p>
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<p>t-SNE comparison of the (<b>a</b>) proposed model with (<b>b</b>) Zhang et al. and (<b>c</b>) Fu et al.</p>
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<p>ROC curves comparison of the (<b>a</b>) proposed model with (<b>b</b>) Zhang et al. and (<b>c</b>) Fu et al.</p>
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38 pages, 1147 KiB  
Article
Seamless Transition to Post-Quantum TLS 1.3: A Hybrid Approach Using Identity-Based Encryption
by Thiago Leucz Astrizi  and Ricardo Custódio 
Sensors 2024, 24(22), 7300; https://doi.org/10.3390/s24227300 - 15 Nov 2024
Viewed by 319
Abstract
We propose a novel solution to streamline the migration of existing Transport Layer Security (TLS) protocol implementations to a post-quantum Key Encapsulation Mechanism for Transport Layer Security (KEMTLS). By leveraging Identity-Based Encryption (IBE), our solution minimizes the necessary modifications to the surrounding infrastructure, [...] Read more.
We propose a novel solution to streamline the migration of existing Transport Layer Security (TLS) protocol implementations to a post-quantum Key Encapsulation Mechanism for Transport Layer Security (KEMTLS). By leveraging Identity-Based Encryption (IBE), our solution minimizes the necessary modifications to the surrounding infrastructure, enabling the reuse of existing keys and certificates. We provide a proof-of-concept implementation and performance analysis, demonstrating the practical feasibility and effectiveness of our proposed approach. Full article
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<p>Diagram illustrating the usage of TLS 1.3. The server must first obtain a certificate from a Certificate Authority before initiating the protocol issuing a Certificate Signing Request (CSR) to authenticate itself, presenting the public key to be certificated and proving that it has the corresponding secret key (proof of knowledge). The Transmission Control Protocol (TCP) handshake, typically managed by the operating system, establishes the connection between the client and server. TLS 1.3 then secures the connection, enabling secret sharing between the client and server, which allows encryption of application data.</p>
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<p>This diagram compares the necessary steps to migrate from TLS 1.3 to a typical KEMTLS or PQ-TLS proposal (the red arrows) with the steps necessary to migrate from TLS 1.3 to our proposal (blue arrows).</p>
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<p>Side-by-side comparison between KEMTLS (<b>left</b>) and our proposal (<b>right</b>). Our approach does not require changes in the certificate authority or new post-quantum certificates. If new keys are needed, we can use the same CSRs as in TLS 1.3, whereas typical KEMTLS needs to adapt.</p>
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<p>A more detailed view of our proposal mixing KEMTLS and IBE. The yellow boxes represent the messages sent between the client and server over the network. The gray boxes indicate computations performed locally by both the client and server. The red boxes provide additional comments on key aspects of the protocol and emphasize the differences between this proposal and a typical hybrid construction using KEMTLS.</p>
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<p>Setup for our local tests in a simulated environment. Since our tests were integrated into the Go standard library, both the client and server were Go executables, each running a different test function. By modifying a configuration structure in the source code, we were able to use various protocols over the local TCP connection, including TLS 1.3, KEMTLS, and different variations of our proposed KEMTLS-IBE. To simulate a high-bandwidth channel with different latencies, we invoked the “tc qdisc” command with different parameters before running our tests, configuring the network emulator in the Linux kernel.</p>
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<p>Comparison of our proposal with TLS 1.3. All timings are in milliseconds. (<b>a</b>) Running the protocols over a local connection without introducing any artificial latency using NetEM. (<b>b</b>) Introducing a latency of 1 ms with NetEM. (<b>c</b>) Latency of 5 ms introduced with NetEM. (<b>d</b>) Latency of 50 ms. (<b>e</b>) Latency of 150 ms. (<b>f</b>) Measuring timings over a real internet connection.</p>
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<p>Setup for remote experiments over a real network. We used the same client and server configuration as in the simulated environment and ran the same tests. However, the client and server were deployed on different rented machines across different continents. Instead of configuring the Linux network emulator, we connected them over a real internet connection using different TLS protocols.</p>
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<p>Comparison of our proposal with other hybrid algorithms. All timings are in milliseconds. (<b>a</b>) Running the protocols over a local connection without introducing any artificial latency with NetEM. (<b>b</b>) Introducing a latency of 1 ms with NetEM. (<b>c</b>) Latency of 5 ms introduced with NetEM. (<b>d</b>) Latency of 50 ms introduced. (<b>e</b>) Latency of 150 ms. (<b>f</b>) Measuring the timings over a real Internet connection.</p>
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<p>Comparison of our proposal with other hybrid algorithms using pre-distributed keys. All timings are in milliseconds. (<b>a</b>) Running the protocols over a local connection without introducing any artificial latency using NetEM. (<b>b</b>) Introducing a latency of 1 ms with NetEM. (<b>c</b>) Latency of 5 ms introduced with NetEM. (<b>d</b>) Latency of 50 ms introduced. (<b>e</b>) Latency of 150 ms. (<b>f</b>) Measuring timings over a real Internet connection.</p>
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12 pages, 6849 KiB  
Article
Deformation Characteristics of Surrounding Rock of Marine Soft Soil Tunnel Under Cyclic Loading
by Wenbin Xu, Yajun Liu, Ke Wu, Heng Zhang, Yindong Sun and Wenbin Xiao
Buildings 2024, 14(11), 3631; https://doi.org/10.3390/buildings14113631 - 15 Nov 2024
Viewed by 330
Abstract
Soft marine soil exhibits unique mechanical properties that can lead to significant deformation and instability in the surrounding rock of urban subway tunnels. This presents a critical challenge for tunnel engineering researchers and designers. This thesis investigates the stability characteristics of surrounding rock [...] Read more.
Soft marine soil exhibits unique mechanical properties that can lead to significant deformation and instability in the surrounding rock of urban subway tunnels. This presents a critical challenge for tunnel engineering researchers and designers. This thesis investigates the stability characteristics of surrounding rock in marine soft soil tunnels under cyclic loading conditions. Focusing on the shield tunnel segment between Left Fortress Station and Taiziwan Station of Shenzhen Urban Rail Transit Line 12, a discrete–continuous coupled numerical analysis method is employed to examine the deformation characteristics of the surrounding rock. This analysis takes into account the effects of dynamic loads resulting from train operations on the arch bottom’s surrounding rock. The findings indicate that damage to the surrounding rock occurs gradually, with the marine soft soil layer, particularly at higher water content, being prone to substantial plastic deformation. Additionally, under the influence of train vibration loads, the degree of vertical fluctuation in the internal marine soft soil diminishes with increasing depth from the bottom of the tunnel arch. This coupled numerical analysis approach offers valuable insights and methodologies for assessing the structural safety of tunnel projects throughout their operational periods. Full article
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<p>Schematic diagram of the distribution of geotechnical strata.</p>
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<p>Coupling model.</p>
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<p>Distribution of surrounding rock instability zone in unsupported state of coupled model.</p>
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<p>Height change curve of the destabilization zone.</p>
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<p>Force chain diagram for discrete particles after tunnel excavation.</p>
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<p>Comparison of cumulative deformation of different models.</p>
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<p>Schematic diagram of measuring point.</p>
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<p>Settlement deformation of arch bottom under different moisture content conditions.</p>
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<p>Settlement deformation of arch bottom under different moisture content conditions.</p>
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<p>Settlement deformation of arch bottom under different moisture content conditions.</p>
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19 pages, 3906 KiB  
Article
Adaptive Enhancement of Thermal Infrared Images for High-Voltage Cable Buffer Layer Ablation
by Hao Zhan, Jing Zhang, Yuhao Lan, Fan Zhang, Qinqing Huang, Kai Zhou and Chengde Wan
Processes 2024, 12(11), 2543; https://doi.org/10.3390/pr12112543 - 14 Nov 2024
Viewed by 329
Abstract
In recent years, ablation of the buffer layer in high-voltage cables has become a prevalent issue compromising the reliability of power transmission systems. Given the internal location of these faults, direct monitoring and assessment are challenging, resulting in numerous undetected ablation hazards. Previous [...] Read more.
In recent years, ablation of the buffer layer in high-voltage cables has become a prevalent issue compromising the reliability of power transmission systems. Given the internal location of these faults, direct monitoring and assessment are challenging, resulting in numerous undetected ablation hazards. Previous practice has demonstrated that detecting buffer layer ablation through surface temperature distribution changes is feasible, offering a convenient, efficient, and non-destructive approach. However, the variability in heat generation and the subtle temperature differences in thermal infrared images, compounded by noise interference, can impair the accuracy and timeliness of fault detection. To overcome these challenges, this paper introduces an adaptive enhancement method for the thermal infrared imaging of high-voltage cable buffer layer ablation. The method involves an Average Gradient Weighted Guided Filtering (AGWGF) technique to decompose the image into background and detail layers, preventing noise amplification during enhancement. The background layer, containing the primary information, is enhanced using an improved Contrast Limited Adaptive Histogram Equalization (CLAHE) to accentuate temperature differences. The detail layer, rich in high-frequency content, undergoes improved Adaptive Bilateral Filtering (ABF) for noise reduction. The enhanced background and detail layers are then fused and stretched to produce the final enhanced thermal image. To vividly depict temperature variations in the buffer layer, pseudo-color processing is applied to generate color-infrared thermal images. The results indicate that the proposed method’s enhanced images and pseudo-colored infrared thermal images provide a clearer and more intuitive representation of temperature differences compared to the original images, with an average increase of 2.17 in information entropy and 8.38 in average gradient. This enhancement facilitates the detection and assessment of buffer layer ablation faults, enabling the prompt identification of faults. Full article
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<p>High-voltage cable longitudinal cross-sectional view.</p>
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<p>Buffer layer ablation fault cable dissection diagram.</p>
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<p>The images captured by an HIKMICRO infrared thermal imager. From <b>left</b> to <b>right</b>, from <b>top</b> to <b>bottom</b>, they are respectively referred to as Image 1 to Image 9.</p>
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<p>Flow chart of the proposed adaptive thermal infrared image enhancement method.</p>
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<p>Visual quality comparison. The images in the first column are the original and enhanced thermal infrared images, and the corresponding pseudo-colored infrared images are shown in the second column.</p>
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<p>Visual quality comparison. The images in the first column are the original and enhanced thermal infrared images, and the corresponding pseudo-colored infrared images are shown in the second column.</p>
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<p>Visual quality comparison. The images in the first column are the original and enhanced thermal infrared images, and the corresponding pseudo-colored infrared images are shown in the second column.</p>
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<p>Visual quality comparison. The images in the first column are the original and enhanced thermal infrared images, and the corresponding pseudo-colored infrared images are shown in the second column.</p>
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<p>Visual quality comparison. The images in the first column are the original and enhanced thermal infrared images, and the corresponding pseudo-colored infrared images are shown in the second column.</p>
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17 pages, 19605 KiB  
Article
TOLGAN: An End-To-End Framework for Producing Traditional Orient Landscape
by Booyong Kim, Heekyung Yang and Kyungha Min
Electronics 2024, 13(22), 4468; https://doi.org/10.3390/electronics13224468 - 14 Nov 2024
Viewed by 251
Abstract
We present TOLGAN that generates traditional oriental landscape (TOL) image from a map that specifies the locations and shapes of the elements composing TOL. Users can create a TOL map by using a user interface or a segmentation scheme from a photograph. We [...] Read more.
We present TOLGAN that generates traditional oriental landscape (TOL) image from a map that specifies the locations and shapes of the elements composing TOL. Users can create a TOL map by using a user interface or a segmentation scheme from a photograph. We design the generator of TOLGAN as a series of decoding layers where the map is applied between the layers. The generated TOL image is further enhanced through an AdaIN architecture. The discriminator of TOLGAN processes a generated image and its groundtruth TOL artwork image. TOLGAN is trained through a dataset composed of paired TOL artwork images and their TOL maps. We present a tool through which users can produce a TOL map by specifying and organizing the elements of TOL artworks. TOLGAN successfully generates a series of TOL images from the TOL map. We evaluate our approach using a quantitative way by estimating FID and ArtFID scores and a qualitative way by executing two user studies. Through these studies, we prove the excellence of our approach by comparing our results with those from several important existing works. Full article
(This article belongs to the Special Issue Feature Papers in Computer Science & Engineering, 2nd Edition)
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<p>An overview of our TOL generation framework.</p>
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<p>The architecture of our generator. *n indicates that the same structure consists of n components.</p>
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<p>The structure of our discriminator. *n indicates that the same structure consists of n components.</p>
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<p>The structure of our model. *n indicates that the same structure consists of n components.</p>
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<p>TOL image dataset: (<b>a</b>) The images belong to 18K TOL artwork images, (<b>b</b>) The selected TOL images.</p>
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<p>The process of building dataset.</p>
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<p>The loss curves of our model.</p>
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<p>The user interface of our model.</p>
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<p>Twelve different input TOL maps (<b>a</b>–<b>l</b>) drawn by the user for TOL generation.</p>
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<p>Twelve generated TOL images (<b>a</b>–<b>l</b>), corresponding to each of the twelve input TOL maps in <a href="#electronics-13-04468-f009" class="html-fig">Figure 9</a>.</p>
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<p>Comparison of our results with those from existing works.</p>
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<p>Ablation study of our results: generated TOL images based on six different TOL maps. (<b>a</b>) The images in the upper row are generated without the AdaIN module, which enhances the generated TOL images. (<b>b</b>) The images in the lower row are produced by processing the images in the upper row through the AdaIN module.</p>
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<p>Various TOL images generated from similar TOL maps.</p>
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<p>Failed TOL images generated: (<b>a</b>) shows TOL images generated from improper user-initiated TOL map, (<b>b</b>) shows TOL images generated from unreal TOL map.</p>
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21 pages, 526 KiB  
Article
Collaborative Caching for Implementing a Location-Privacy Aware LBS on a MANET
by Rudyard Fuster, Patricio Galdames and Claudio Gutierréz-Soto
Appl. Sci. 2024, 14(22), 10480; https://doi.org/10.3390/app142210480 - 14 Nov 2024
Viewed by 236
Abstract
This paper addresses the challenge of preserving user privacy in location-based services (LBSs) by proposing a novel, complementary approach to existing privacy-preserving techniques such as k-anonymity and l-diversity. Our approach implements collaborative caching strategies within a mobile ad hoc network (MANET), exploiting [...] Read more.
This paper addresses the challenge of preserving user privacy in location-based services (LBSs) by proposing a novel, complementary approach to existing privacy-preserving techniques such as k-anonymity and l-diversity. Our approach implements collaborative caching strategies within a mobile ad hoc network (MANET), exploiting the geographic of location-based queries (LBQs) to reduce data exposure to untrusted LBS servers. Unlike existing approaches that rely on centralized servers or stationary infrastructure, our solution facilitates direct data exchange between users’ devices, providing an additional layer of privacy protection. We introduce a new privacy entropy-based metric called accumulated privacy loss (APL) to quantify the privacy loss incurred when accessing either the LBS or our proposed system. Our approach implements a two-tier caching strategy: local caching maintained by each user and neighbor caching based on proximity. This strategy not only reduces the number of queries to the LBS server but also significantly enhances user privacy by minimizing the exposure of location data to centralized entities. Empirical results demonstrate that while our collaborative caching system incurs some communication costs, it significantly mitigates redundant data among user caches and reduces the need to access potentially privacy-compromising LBS servers. Our findings show a 40% reduction in LBS queries, a 64% decrease in data redundancy within cells, and a 31% reduction in accumulated privacy loss compared to baseline methods. In addition, we analyze the impact of data obsolescence on cache performance and privacy loss, proposing mechanisms for maintaining the relevance and accuracy of cached data. This work contributes to the field of privacy-preserving LBSs by providing a decentralized, user-centric approach that improves both cache redundancy and privacy protection, particularly in scenarios where central infrastructure is unreachable or untrusted. Full article
(This article belongs to the Special Issue New Advances in Computer Security and Cybersecurity)
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<p>M-LBS system.</p>
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<p>Network partition with the red circle indicating a user’s coverage area.</p>
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<p>Number of LBS accesses when the cache size is varied.</p>
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<p>Number of LBS accesses when the speed of the nodes is varied.</p>
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<p>Privacy loss for different k-anonymity values across three approaches.</p>
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<p>Number of queries sent to LBSs and number of query responses from MANET vs. expiration time. Solid lines represent queries sent to LBSs; dashed lines represent query responses from MANET.</p>
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9 pages, 6360 KiB  
Article
The Study of the Etching Resistance of YOF Coating Deposited by Atmospheric Plasma Spraying in HBr/O2 Plasma
by Zaifeng Tang, Bing Wang, Kaiqu Ang, Xiaojun Jiang, Yuwei Wang, Jin Xu, Hua Meng, Hongli Chen, Ying Shi and Linjun Wang
Coatings 2024, 14(11), 1442; https://doi.org/10.3390/coatings14111442 - 13 Nov 2024
Viewed by 333
Abstract
Yttrium oxyfluoride (YOF) coatings with different oxygen content were prepared using atmospheric plasma spraying (APS) technology. The etching resistance of the coatings in HBr/O2 plasma was investigated. Shifts in diffraction peaks of the X-ray diffraction, along with XPS analysis conducted before and [...] Read more.
Yttrium oxyfluoride (YOF) coatings with different oxygen content were prepared using atmospheric plasma spraying (APS) technology. The etching resistance of the coatings in HBr/O2 plasma was investigated. Shifts in diffraction peaks of the X-ray diffraction, along with XPS analysis conducted before and after etching, demonstrated that Br ions could replace O and F ions and fill the oxygen vacancies after exposure to HBr/O2 plasma, which is supported by the first-principles calculations. Br ions formed a protective layer on the surface of the YOF coating, slowing down further etching by Br ions. By adjusting the oxygen mass fraction in YOF powder, the oxygen vacancy concentration and Br ion filling were regulated to enhance etching resistance. YOF coatings with 6% oxygen content exhibited improved etching resistance compared to YOF coatings with 3% and 9% oxygen content. This improvement was primarily due to the increased Br ion concentration. These findings provide a new approach for developing coatings with enhanced etching resistance. Full article
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<p>Simple schematic illustration of the etching chamber system.</p>
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<p>SEM images of (<b>a</b>) YOF 3%, (<b>b</b>) YOF 6%, and (<b>c</b>) YOF 9% powders.</p>
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<p>XRD spectra of (<b>a</b>) YOF powders, (<b>b</b>) YOF 3% coatings as deposited and after plasma exposure, (<b>c</b>) YOF 6% coatings as deposited and after plasma exposure, and (<b>d</b>) YOF 9% coatings as deposited and after plasma exposure.</p>
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<p>SEM images of (<b>a</b>) YOF 3%, (<b>b</b>) YOF 6% and (<b>c</b>) YOF 9% coating before etching, and SEM images of (<b>d</b>) YOF 3%, (<b>e</b>) YOF 6% and (<b>f</b>) YOF 9% coating after etching.</p>
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<p>SEM images for etching depth of (<b>a</b>) YOF 3%, (<b>b</b>) YOF 6%, and (<b>c</b>) YOF 9% coatings.</p>
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<p>The XPS images of YOF 3%, YOF 6%, and YOF 9% coatings before (<b>a</b>–<b>c</b>) and after (<b>d</b>–<b>f</b>) HBr/O<sub>2</sub> plasma exposure.</p>
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<p>Oxygen vacancy concentration of YOF 3%, YOF 6%, and YOF 9% fitting by XPS (<b>a</b>) before and (<b>b</b>) after etching.</p>
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<p>(<b>a</b>) the Y<sub>5</sub>O<sub>4</sub>F<sub>7</sub> unit cell; (<b>b</b>) the filling of Br atoms for oxygen vacancy within the Y<sub>5</sub>O<sub>4</sub>F<sub>7</sub> unit cell; (<b>c</b>) the substitution of Br atoms for F atoms in the Y<sub>5</sub>O<sub>4</sub>F<sub>7</sub> unit cell; and (<b>d</b>) the substitution of Br atoms for O atoms in the Y<sub>5</sub>O<sub>4</sub>F<sub>7</sub> unit cell.</p>
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