Search Results (11,361)

Based on the photocatalytic activity and magnetic nature of magnetite and goethite, as well as the oxygen storage characteristic of cerianite, a magnetic ternary hybrid composite including cubic CeO₂, cubic Fe₃O₄ and orthorhombic FeOOH, designated as Fe₃O₄/FeOOH/CeO₂, was successfully synthesized with different Ce:Fe molar ratios using a simple hydrothermal route without subsequent calcination process, and employed as photocatalysts for the degradation of Acid Orange 7 (AO7) dye. The absorption range of light by the Fe₃O₄/FeOOH/CeO₂ composites was broadened, and the intensity was enhanced. Furthermore, there existed a possibility of hybridization and doping among the three crystalline structures, with the elements Ce, Fe and O exhibiting a uniform distribution, significantly enhancing the photocatalytic efficiency of the Fe₃O₄/FeOOH/CeO₂ composites in promoting the photodegradation of AO7. The magnetic response behaviors of hybrid composites synthesized with different Ce:Fe molar ratios were investigated. The adsorptive degradation of AO7 in darkness and the photocatalytic degradation of AO7 under UV light illumination were evaluated. Moreover, ten cycling runs of the photocatalytic degradation of AO7 under simulated UV illumination of Fe₃O₄/FeOOH/CeO₂ synthesized with a Ce:Fe molar ratio of 1:15 were performed. The hybrid ternary composites were proved to have excellent magnetic sensitivity, exhibited outstanding photocatalytic activities and demonstrated remarkable stability. It is anticipated that magnetic Fe₃O₄/FeOOH/CeO₂ ternary hybrid composites may have potential applications in the treatment of organic dye sewage. Full article

Papaya seeds (Carica papaya L.), a by-product of the food industry, contain primary metabolites and offer secondary health benefits, but are often considered a waste with no value. Therefore, the aim of this research was to optimize the extraction process of polyphenols from papaya seeds (Carica papaya L.) to maximize their antioxidant activity using the response surface methodology (RSM). A design of experiment (DOE) approach was applied to produce the optimum conditions of factors such as solvent concentration (0–100%), temperature (30–60 °C), time (1–6 h), and exhaustion (1–6 times) to improve the extraction process. The response variables were the number of phenols and flavonoids, and the inhibition capacity of the DPPH and ABTS radicals. The main findings indicated that optimal conditions—100% solvent concentration, a temperature of 30 °C, an extraction time of 6 h, and 6 depletion cycles—maximized the yield of total polyphenols, total flavonoids, and antioxidant capacity, as evaluated using ABTS and DPPH assays. The extracts presented values of 2.521 to 6.168 mg AGE/g DW for total polyphenols and 30.830 to 68.599 mg QE/g DW for total flavonoids. Likewise, they presented an antioxidant capacity using DPPH and ABTS methods with values of around 15.151 to 72.389 and 29.434 to 165.393 μM TE/g DW, respectively. Identification was also performed using liquid chromatography to determine the presence of sugars (glucose, fructose, and sucrose) and organic acids (oxalic, citric, tartaric, malic, quinic, and succinic). However, optimal values were presented outside the study area, which indicates the maximum point of the surface was at intervals higher than those studied in this investigation. The papaya seed can be applied in future research for the optimization of bioactive compounds extracted from vegetable waste and it represents a matrix with potential in the area of technological development and health. Full article

Understanding the balance between robustness and evolvability is crucial in evolutionary dynamics. This study aims to determine how varying mutation rates and valley depths affect this interplay during adaptation. Using a two-peak fitness landscape model requiring populations to cross a fitness valley to reach a higher peak, we investigate how mutation rates and valley depths influence both evolvability—the capacity to generate beneficial mutations—and mutational robustness, which stabilizes populations at the highest peak. Our experiments reveal that at low mutation rates, populations struggle to cross fitness valleys, reducing the occurrence of pioneers. As mutation rates increase, valley crossing becomes more frequent, but organisms forming a majority at the highest peak are less common and tend to arise at intermediate mutation rates. Although pioneers reach the highest peak, they are often replaced by more mutationally robust organisms that later form a majority. This suggests that while evolvability aids in valley crossing, long-term stability at the highest peak requires greater mutational robustness. Our findings highlight that adaptations in epistasis and pleiotropy facilitate the trade-off between evolvability and robustness, providing insights into how organisms navigate complex fitness landscapes. These results can also inform the design of genetic algorithms that balance evolvability with robustness to optimize outcomes. Full article

The sustainable management of aquaculture by-products is crucial for advancing circular economy practices. Mediterranean mussel shell waste, rich in calcium carbonate, presents a sustainable alternative to conventional liming materials, especially for mitigating soil acidification, a very important and common issue that limits crop productivity. This study evaluated the effectiveness of processed mussel shell waste in enhancing soil pH, organic matter, and nutrient availability. A 180-day pot experiment using highly acidic soil (pH < 4.5) collected from a local field was conducted in a Completely Randomized Design. Treatments involved two grain sizes of mussel shell powder (Fine: <1 mm; Coarse: 1–2 mm) at rates between 0.1 and 6%. Treated soil pH was measured monthly, whereas organic matter, available phosphorus (P), and exchangeable potassium (K) were measured at the beginning and the end of the experiment. The results revealed significant improvements in pH, organic matter, available phosphorus (P), and exchangeable potassium (K), particularly in the Fine Powder treatments. However, total nitrogen (N) remained unaffected. These findings highlight the potential of mussel shells as an eco-friendly and cost-effective amendment, advancing sustainable agriculture and waste recycling, thus contributing to broader conservation efforts by reducing the environmental footprint of aquaculture waste and supporting biodiversity and ecosystem resilience through sustainable resource management. Full article

Background/Objectives: Understanding speech in background noise is a challenging task for listeners with normal hearing and even more so for individuals with hearing impairments. The primary objective of this study was to develop Romanian speech material in noise to assess speech perception in diverse auditory populations, including individuals with normal hearing and those with various types of hearing loss. The goal was to create a versatile tool that can be used in different configurations and expanded for future studies examining auditory performance across various populations and rehabilitation methods. Methods: This study outlines the development of Romanian speech material for speech-in-noise testing, initially presented to normal-hearing listeners to establish baseline data. The material consisted of unpredictable sentences, each with a fixed syntactic structure, generated using speech synthesis from all Romanian phonemes. A total of 50 words were selected and organized into 15 lists, each containing 10 sentences, with five words per sentence. Two evaluation methods were applied in two sessions to 20 normal-hearing volunteers. The first method was an adaptive speech-in-noise recognition test designed to assess the speech recognition threshold (SRT) by adjusting the signal-to-noise ratio (SNR) based on individual performance. The intelligibility of the lists was further assessed at the sentence level to evaluate the training effect. The second method was used to obtain normative data for the SRT, defined as the SNR at which a subject correctly recognizes 50% of the speech material, as well as for the slope, which refers to the steepness of the psychometric function derived from threshold recognition scores measured at three fixed SNRs (−10 dB, −7 dB, and −4 dB) during the measurement phase. Results: The adaptive method showed that the training effect was established after two lists and remained consistent across both sessions. During the measurement phase, the fixed SNR method yielded a mean SRT50 of −7.38 dB with a slope of 11.39%. These results provide reliable and comparable data, supporting the validity of the material for both general population testing and future clinical applications. Conclusions: This study demonstrates that the newly developed Romanian speech material is effective for evaluating speech recognition abilities in noise. The training phase successfully mitigated initial unfamiliarity with the material, ensuring that the results reflect realistic auditory performance. The obtained SRT and slope values provide valuable normative data for future auditory assessments. Due to its flexible design, the material can be further developed and extended to accommodate various auditory rehabilitation methods and diverse populations in future studies. Full article

Three-dimensional bioprinting (3DP) is transforming the field of regenerative medicine by enabling the precise fabrication of complex tissues, including the retina, a highly specialized and anatomically complex tissue. This review provides an overview of 3DP’s principles, its multi-step process, and various bioprinting techniques, such as extrusion-, droplet-, and laser-based methods. Within the scope of biomimicry and biomimetics, emphasis is placed on how 3DP potentially enables the recreation of the retina’s natural cellular environment, structural complexity, and biomechanical properties. Focusing on retinal tissue engineering, we discuss the unique challenges posed by the retina’s layered structure, vascularization needs, and the complex interplay between its numerous cell types. Emphasis is placed on recent advancements in bioink formulations, designed to emulate retinal characteristics and improve cell viability, printability, and mechanical stability. In-depth analyses of bioinks, scaffold materials, and emerging technologies, such as microfluidics and organ-on-a-chip, highlight the potential of bioprinted models to replicate retinal disease states, facilitating drug development and testing. While challenges remain in achieving clinical translation—particularly in immune compatibility and long-term integration—continued innovations in bioinks and scaffolding are paving the way toward functional retinal constructs. We conclude with insights into future research directions, aiming to refine 3DP for personalized therapies and transformative applications in vision restoration. Full article

Abstract: Fine particulate matter (PM_2.5) poses significant health risks, prompting public health organizations to recommend the use of respirators and facemasks (RFMs) to mitigate exposure. Consequently, interest in their usage has increased, leading to several studies assessing the efficiency of these personal-level interventions against various fractions of ambient particulate matter (PM). We conducted a comprehensive literature search across PubMed, Web of Science, and Scopus to identify relevant studies and address the following objectives: (1) explore the efficiency of RFMs in reducing ambient PM; (2) discuss discrepancies in efficiencies reported; (3) critique the experimental setups used to evaluate the efficiency of RFMs; and (4) propose recommendations for future research. Five relevant studies we reviewed reported significantly lower RFM effectiveness against ambient PM, with a size-dependent efficiency that decreases for smaller PM fractions. Variations in the reported efficiencies were primarily attributed to design-related factors, resulting in poor facial fit. Therefore, it is crucial to consider standardizing and properly designing these products. These studies overlooked essential factors, such as using dummy heads with flexible textures that mimic human skin. The use of rigid-textured dummy heads, as seen in previous studies, may fail to accurately represent real-world conditions. We recommend researchers take into account diverse facial profiles in their experiments. Moreover, it is essential to consider facial characteristics in the design of RFMs. We believe the evidence supports the increasing need for the adoption of appropriate guidelines and regulations to govern RFM suppliers at both national and international levels. Full article

The purpose of this study is to solve the problem of low load factor and profit margin in the point-to-point transportation of international freight trains through the assembly transportation organization mode. A bi-objective location-routing optimization model is constructed to optimize problems, such as the location of the assembly center, route of freight assembly, frequency of international freight trains, and number of formations. The objectives are to minimize the total comprehensive cost and maximize the average satisfaction of the shippers. Considering the impact of blockchain technology, the proportion of customs clearance time reduction after blockchain implementation, the proportion of customs clearance fee reduction after blockchain implementation, and the cost of blockchain technology are introduced into the model. The case study is based on railroad transportation data for 2022. In this case, 43 stations in the Indo-China Peninsula are selected as origin stations, and two Chinese stations are designated terminal stations. An improved NSGA-II algorithm (ANSGAII-OD) is proposed to resolve the location-routing optimization model. This algorithm is based on opposition-based learning and its dominant strength. The case study indicates that assembly transportation is advantageous compared with direct transportation. Moreover, the comprehensive cost is reduced by 19.77%. Furthermore, blockchain technology can effectively reduce costs and improve transportation efficiency. After the implementation of blockchain technology, the comprehensive cost is reduced by 8.10%, whereas the average satisfaction of shippers is increased by 10.35%. Full article

Maritime navigation safety relies on preventing accidents, such as collisions and groundings. However, several factors can exacerbate these risks, including inexistent or inadequate buoyage systems and nautical charts with outdated bathymetry. The International Hydrographic Organization (IHO) highlights high costs and traditional methods as obstacles to updating bathymetric information, impacting both safety and socio-economic factors. Navigation in inland and coastal waters is particularly complex due to the presence of shallow intertidal zones that are not signaled, where navigation depends on tidal height, vessel draw, and local knowledge. To address this, recreational vessels can use electronic maritime sensors to share critical data with nearby vessels. This article introduces a low-cost maritime data sharing system using IoT technologies for both inland (e.g., Ria de Aveiro) and coastal waters. The system enables the collection and sharing of meteorological and oceanographic data, including depth, tide height, wind direction, and speed. Using a case study in the Ria de Aveiro lagoon, known for its navigational difficulties, the system was developed with a Contextual Design approach focusing on sailors’ needs. It allows for the real-time sharing of data, helping vessels to anticipate maneuvers for safer navigation. The results demonstrate the system’s potential to improve maritime safety in both inland and coastal areas. Full article

The hospitality industry, particularly hotels, is increasingly emphasizing the dual goals of sustainability and cost optimization to align with global environmental objectives and enhance operational efficiency. The current study comprehensively explores sustainable energy solutions tailored for hotel buildings, utilizing insights drawn from a review of the relevant literature, analysis of industry data, and an examination of real-world case studies. The study begins by assessing the energy consumption patterns of hotels and the environmental implications of reliance on conventional energy sources. It then delves into various sustainable energy systems designed to mitigate these impacts, including solar photovoltaic panels, geothermal heating and cooling technologies, energy-efficient lighting solutions, and advanced smart building management systems. These interventions demonstrate significant potential to reduce energy expenses and carbon emissions while simultaneously enhancing guest satisfaction through improved comfort and environmentally friendly practices. Furthermore, the research highlights critical factors that facilitate the adoption of sustainable energy systems in the hotel industry. These include active stakeholder participation, adherence to regulatory frameworks, and the availability of financial incentives, such as subsidies or tax benefits. This study also identifies substantial barriers to implementation, such as the high initial investment costs, technological challenges in retrofitting existing infrastructures, and cultural resistance to adopting new practices within organizations. The findings underscore the importance of a holistic approach to energy sustainability in hotels, advocating for a collaborative effort among industry stakeholders, policymakers, and technology providers. By addressing these challenges and leveraging the identified opportunities, hotels can transition toward more energy-efficient operations, contributing meaningfully to environmental preservation and achieving long-term economic benefits. Full article

In recent years, passenger holiday travel momentum continues to increase, which proposes a challenge to the refined transportation organization of China’s high-speed railway. In order to save the cost of transportation organization, this paper proposes a collaborative optimization method using a high-speed railway train diagram and Electric Multiple Unit (EMU) routing considering the coordination of weekdays and holidays. Based on the characteristics of the train diagram and EMU routing, this method optimizes the EMU routing synchronously when compiling the train diagram. By constructing a space–time–state network, considering the constraints of train headway, operation conflict, and EMU maintenance, a collaborative optimization model of the train diagram and EMU routing considering the coordination of weekdays and holidays is established. This research combines the actual operation data to verify the model and algorithm. Based on five consecutive days of holidays, a seven-day transportation plan covering before and after the holidays and during the holidays is designed, and a case study is carried out. The results show that the proposed collaborative optimization theory has practical significance in the application scenarios of high-speed railway holidays. Full article

Aqueous zinc-ion batteries (AZIBs) have emerged as highly promising options for large-scale energy storage systems due to their cost-effectiveness, substantial energy capacity, and improved safety features. However, the Zn anode faces challenges such as self-corrosion and dendrite formation, which limit its practical use in AZIB applications. In this work, a simple blade-coating method was used to successfully coat poly (vinylidene fluoride–hexafluoro propylene) (PVDF-HFP) on the Zn anode. The coated Zn anode (P-Zn) displayed a stable cycling performance (700 h) at 1 mA cm⁻² current density in the symmetric cell. In addition, the full cell using MnO₂ as the cathode and P-Zn as the anode retained almost full capacity even after 1400 cycles at 2C, far outperforming the full cell using the unmodified Zn anode with only 50% capacity retention after 600 cycles. In situ optical observations of Zn deposition demonstrate that the special organic coating significantly enhances the uniform deposition of Zn²⁺, thus effectively mitigating corrosion and hydrogen evolution. Density Functional Theory (DFT) calculations show that the PVDF-HFP coating effectively narrows the adsorption energy gap between the P-Zn (002) and (101) planes, leading to the homogeneous deposition of Zn²⁺ with fewer Zn dendrites. A simple and feasible strategy for designing ultra-stable AZIBs by coating an organic protective layer on the Zn surface is provided by this work. Full article

Since biochemists and biologists have progressed in understanding the mechanisms involved in living organisms, biological systems have become a source of inspiration for chemists. In this context, the concept of colloidal tectonics, describing the spontaneous formation of colloidal particles or supracolloidal structures in which the building blocks are called “tectons”, has emerged. Therefore, a bottom-up edification of tectons towards (supra) colloidal structures is allowed. Each (supra) colloidal system has at least one of the following properties: amphiphilicity, predictability, versatility, commutability, and reversibility. However, for these systems to perform even more interesting functions, it is necessary for tectons to have very precise chemical and physical properties so that new properties emerge in (supra) colloidal systems. In this way, colloidal tectonics enables engineering at the nano- and micrometric level and contributes to the development of smart bioinspired systems with applications in catalysis, drug delivery, etc. In this review, an overview of the concept of colloidal tectonics is illustrated by some biotic systems. The design of abiotic (supra) colloidal systems and their applications in various fields are also addressed (notably Pickering emulsions for catalysis or drug delivery). Finally, theoretical directions for the design of novel self-assembled (supra) colloidal systems are discussed. Full article

7,7′,8,8′-tetracyanoquinodimethane (TCNQ) is one of the most widely used effective surface electron acceptors in organic electronics and sensors, which opens up a very interesting field in electrochemical applications. In this review article, we outline the historical context of electrochemically stable selective electrode materials based on TCNQ and its derivatives and their development, their electrochemical characteristics, and the experimental aspects of their electrochemical applications. TCNQ-modified electrodes are characterized by long-term stability, reproducibility, and a low detection limit compared to other sensors; thus, their use can increase determination speed and flexibility and reduce investigation costs. TCNQ and its derivatives can also be successfully combined with other detector materials for cancer-related clinical diagnostic testing. Examples of simple, rapid, and sensitive detection procedures for various analytes are provided. Applications of new electrochemically stable TCNQ-based metal/covalent–organic hybrid frameworks, with exceptionally large surface areas, tunable pore sizes, diverse functionality, and high electrical conductivity, are also presented. As a result, they also offer enormous potential as revolutionary catalysts, drug carrier systems, and smart materials, as well as for use in gas storage. The use of TCNQ compounds as promising active electrode materials in high-power organic batteries/energy storage devices is discussed. We hope that the information featured in this review will provide readers with a good understanding of the chemistry of TCNQ and, more importantly, help to find good ways to prepare new micro-/nanoelectrode materials for rational sensor design. Full article

Photodetectors based on selenium (Se) have attracted significant attention because of their outstanding optoelectronic characteristics, including their rapid reactivity and high photoconductivity. However, the poor responsivity of pure Se limits their further development. In this study, a novel Se-P/P3HT:G photodetector was designed and fabricated by combining an organic semiconductor made of poly-3-hexylthiophene mixed with graphene (P3HT:G) with self-supporting Se paper (Se-P) via spin-coating process. The device possesses a dark current of around 4.23 × 10⁻¹² A and self-powered characteristics at 300–900 nm. At zero bias voltage and 548 nm illumination, the Se-P/P3HT:G photodetector demonstrates a maximum photocurrent of 1.35 × 10⁻⁹ A (745% higher than that of Se-P at 0.1 V), a quick response time (16.2/27.6 ms), an on/off ratio of 292, and a maximum detectivity and responsivity of 6.47 × 10¹¹ Jones and 34 mA W⁻¹, respectively. Moreover, Se-P/P3HT:G exhibits superior environmental stability. After one month, the photocurrent value of the Se-P/P3HT:G device held steady at 91.4% of its initial value, and even following pre-treatment at 140 °C, the on/off ratio still remained 17 (at a retention rate of about 5.9%). The excellent thermal stability, environmental reliability, and optoelectronic performance of this heterojunction structure offer a useful pathway for the future advancement of high-performance optoelectronic devices. Full article