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Search Results (7,589)

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22 pages, 4633 KiB  
Review
Typical Case Studies and Classification with Evaluation of Carbon Dioxide Geological Sequestration in Saline Aquifers
by Lihua Ping, Huijun Wang, Yuchen Tian, Helong Zhang, Xiuping Wu, Shiheng Chen, Yinghai Liu, Yanzhi Liu, Shiqi Liu, Shuxun Sang and Sijian Zheng
Processes 2024, 12(11), 2562; https://doi.org/10.3390/pr12112562 (registering DOI) - 16 Nov 2024
Viewed by 85
Abstract
To achieve carbon neutrality in China’s fossil energy sector, saline aquifer CO2 geological storage has become a critical strategy. As research into carbon reduction and storage potential evaluation advances across various geological scales, the need arises for consolidating key CO2 storage [...] Read more.
To achieve carbon neutrality in China’s fossil energy sector, saline aquifer CO2 geological storage has become a critical strategy. As research into carbon reduction and storage potential evaluation advances across various geological scales, the need arises for consolidating key CO2 storage cases and establishing a standardized classification system and evaluation methodology. This paper provides a comprehensive review of notable CO2 storage projects in saline aquifers, covering aspects such as project overviews, structural and reservoir characteristics, caprock integrity, and seismic monitoring protocols. Drawing on insights from mineral and oil and gas exploration, as well as international methods, this paper outlines the stages and potential levels of saline aquifer storage in China. It proposes an evaluation framework with formulas and reference values for key coefficients. The study includes successful global projects, such as Sleipner and Snøhvit in Norway, In Salah in Algeria, and Shenhua in China’s Ordos Basin, which provide valuable insights for long-term carbon capture and storage (CCS). By examining geological characteristics, injection, and monitoring protocols in these projects, this paper analyzes how geological features impact CO2 storage outcomes. For example, the Sleipner project’s success is linked to its straightforward structure, favorable reservoir properties, and stable caprock, while Snøhvit illustrates diverse structural suitability, and In Salah demonstrates the influence of fractures on storage efficacy. CO2 storage activities are segmented into four stages—survey, investigation, exploration, and injection—and are further categorized by storage potential: geological, technical, techno-economic, and engineering capacities. This study also presents evaluation levels (prediction, control, technically recoverable, and engineering) that support effective reservoir selection, potential classification, and calculations considering factors like reservoir stability and sealing efficacy. Depending on application needs, volumetric or mechanistic methods are recommended, with precise determination of geological, displacement, and cost coefficients. For China, a dynamic evaluation mechanism characterized by multi-scale, tiered approaches and increasing precision over time is essential for robust storage potential assessment. The levels and methods outlined here serve as a scientific foundation for regional and stage-based comparisons, guiding engineering approvals and underground space management. To align with practical engineering demands, ongoing innovation through laboratory experiments, simulations, and field practice is crucial, supporting continual refinement of formulas and key parameter determinations. Full article
18 pages, 922 KiB  
Article
Do Environmental Tax and Energy Matter for Environmental Degradation in the UK? Evidence from Novel Fourier-Based Estimators
by Kwaku Addai, Souha Hanna Al Geitany, Seyed Alireza Athari, Panteha Farmanesh, Dervis Kirikkaleli and Chafic Saliba
Energies 2024, 17(22), 5732; https://doi.org/10.3390/en17225732 (registering DOI) - 15 Nov 2024
Viewed by 359
Abstract
Currently, the UK has ambitious plans to reach net zero by 2050, despite other countries such as Russia and India targeting 2060 and 2070, respectively. Assuming that the UK emissions unceasingly decline at a given rate annually towards achieving net zero by 2050, [...] Read more.
Currently, the UK has ambitious plans to reach net zero by 2050, despite other countries such as Russia and India targeting 2060 and 2070, respectively. Assuming that the UK emissions unceasingly decline at a given rate annually towards achieving net zero by 2050, its economy would need to ensure a reduction of 105 MtCO2 per year of its emissions from the current 2021 levels. Given that global greenhouse gas emissions have not peaked and continue to rise, the UK seeks to implement costly and aggressive emission reduction policies towards fulfilling commitments under the 2021 Glasgow Climate Pact. This paper investigates the effect of environmental taxes on environmental degradation in the UK between 2000Q1 and 2019Q4 using novel Fourier approaches. Using the novel Fourier ARDL estimator, the long-run equilibrium estimates indicate that gross domestic product and environmental tax cause a fall in carbon emissions. However, in trade and primary energy use, a unit change caused rising carbon emissions in the UK. Especially, the results indicate that environmental taxes have a negative effect on environmental degradation in the UK, and ecological tax policy could be considered as an effective channel to attain environmental sustainability. The outcome provides the following policy insights: (i) The government of the UK should support international environmental tax coordination mechanisms, especially on carbon pricing, to avoid relocation of carbon-intensive investments. (ii) The UK government must note that imposing more taxes to encourage emissions reductions could bring complexity to the tax system and unnecessarily bring costly ways to deal with climate change. Higher domestic electricity prices could disproportionately hit low-income households and create distributional cost concerns, which require benefit payouts or compensation schemes. (iii) Switching to electric vehicles simultaneously requires investments in charging infrastructure and battery technologies. To avoid this chicken-and-egg problem, the government of the UK could play a coordinating role, including deploying targeted subsidies, regulations, direct government involvement, or setting higher carbon prices in special cases. Full article
(This article belongs to the Special Issue Energy Economics, Finance and Policy Towards Sustainable Energy)
19 pages, 3200 KiB  
Article
High-Resolution Remotely Sensed Evidence Shows Solar Thermal Power Plant Increases Grassland Growth on the Tibetan Plateau
by Naijing Liu, Huaiwu Peng, Zhenshi Zhang, Yujin Li, Kai Zhang, Yuehan Guo, Yuzheng Cui, Yingsha Jiang, Wenxiang Gao and Donghai Wu
Remote Sens. 2024, 16(22), 4266; https://doi.org/10.3390/rs16224266 (registering DOI) - 15 Nov 2024
Viewed by 178
Abstract
Solar energy plays a crucial role in mitigating greenhouse gas emissions in the context of global climate change. However, its deployment for green electricity generation can significantly influence regional climate and vegetation dynamics. While prior studies have examined the impacts of solar power [...] Read more.
Solar energy plays a crucial role in mitigating greenhouse gas emissions in the context of global climate change. However, its deployment for green electricity generation can significantly influence regional climate and vegetation dynamics. While prior studies have examined the impacts of solar power plants on vegetation, the accuracy of these assessments has often been constrained by the availability of publicly accessible multispectral, high-resolution remotely sensed imagery. Given the abundant solar energy resources and the ecological significance of the Tibetan Plateau, a thorough evaluation of the vegetation effects associated with solar power installations is warranted. In this study, we utilize sub-meter resolution imagery from the GF-2 satellite to reconstruct the fractional vegetation cover (FVC) at the Gonghe solar thermal power plant through image classification, in situ sampling, and sliding window techniques. We then quantify the plant’s impact on FVC by comparing data from the pre-installation and post-installation periods. Our findings indicate that the Gonghe solar thermal power plant is associated with a 0.02 increase in FVC compared to a surrounding control region (p < 0.05), representing a 12.5% increase relative to the pre-installation period. Notably, the enhancement in FVC is more pronounced in the outer ring areas than near the central tower. The observed enhancement in vegetation growth at the Gonghe plant suggests potential ecological and carbon storage benefits resulting from solar power plant establishment on the Tibetan Plateau. These findings underscore the necessity of evaluating the climate and ecological impacts of renewable energy facilities during the planning and design phases to ensure a harmonious balance between clean energy development and local ecological integrity. Full article
(This article belongs to the Special Issue Remote Sensing of Mountain and Plateau Vegetation)
23 pages, 906 KiB  
Article
Energy Solutions for Decarbonization of Industrial Heat Processes
by Danieli Veronezi, Marcel Soulier and Tímea Kocsis
Energies 2024, 17(22), 5728; https://doi.org/10.3390/en17225728 (registering DOI) - 15 Nov 2024
Viewed by 245
Abstract
The global rise in population and advancement in civilization have led to a substantial increase in energy demand, particularly in the industrial sector. This sector accounts for a considerable proportion of total energy consumption, with approximately three-quarters of its energy consumption being used [...] Read more.
The global rise in population and advancement in civilization have led to a substantial increase in energy demand, particularly in the industrial sector. This sector accounts for a considerable proportion of total energy consumption, with approximately three-quarters of its energy consumption being used for heat processes. To meet the Paris Agreement goals, countries are aligning policies with international agreements, and companies are setting net-zero targets. Upstream emissions of the Scope 3 category refer to activities in the company’s supply chain, being crucial for achieving its net-zero ambitions. This study analyzes heating solutions for the supply chain of certain globally operating companies, contributing to their 2030 carbon-neutral ambition. The objective is to identify current and emerging heating solutions from carbon dioxide equivalent (CO2e) impact, economic, and technical perspectives, considering regional aspects. The methodology includes qualitative and quantitative surveys to identify heating solutions and gather regional CO2e emission factors and energy prices. Calculations estimate the CO2e emissions and energy costs for each technology or fuel, considering each solution’s efficiency. The study focuses on Europe, the United States, Brazil, China, and Saudi Arabia, regions or countries representative of companies’ global supply chain setups. Results indicate that heat pumps are the optimal solution for low temperatures, while biomass is the second most prevalent solution, except in Saudi Arabia where natural gas is more feasible. For medium and high temperatures, natural gas is viable in the short term for Saudi Arabia and China, while biomass and electrification are beneficial for other regions. The proportion of electricity in the energy mix is expected to increase, but achieving decarbonization targets requires cleaner energy mixes or competitive Power Purchase Agreement (PPA) projects. Brazil, with its high proportion of renewable energy sources, offers favorable conditions for using green electricity to reduce emissions. The utilization of biomethane is promising if costs and incentives align with those in the EU. Although not the objective of this study, a comprehensive analysis of CAPEX and lifecycle costs associated with equipment is necessary when migrating technologies. Policies and economic incentives can also make these solutions more or less favorable. Full article
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<p>Overview of GHG Protocol scopes and emissions across the value chain [<a href="#B13-energies-17-05728" class="html-bibr">13</a>].</p>
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<p>Industry drives global energy consumption [<a href="#B11-energies-17-05728" class="html-bibr">11</a>].</p>
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13 pages, 2125 KiB  
Article
Catalytic Methane Decomposition on In Situ Reduced FeCo Alloy Catalysts Derived from Layered Double Hydroxides
by Dianfeng Cao, Yuwen Li, Chao Lv, Yongtao An, Jiangfeng Song, Mingcan Li and Xin Zhang
Nanomaterials 2024, 14(22), 1831; https://doi.org/10.3390/nano14221831 (registering DOI) - 15 Nov 2024
Viewed by 187
Abstract
Catalytic methane decomposition (CMD) reaction is considered a promising process for converting greenhouse gas CH4 into hydrogen and high-value-added carbon materials. In this work, a series of Al2O3-supported FeCo alloy catalysts were successfully prepared in the CMD process. [...] Read more.
Catalytic methane decomposition (CMD) reaction is considered a promising process for converting greenhouse gas CH4 into hydrogen and high-value-added carbon materials. In this work, a series of Al2O3-supported FeCo alloy catalysts were successfully prepared in the CMD process. Compared to the pre-reduced catalysts, the in situ reduced FeCo alloy catalysts showed higher methane conversion rates, with the highest reaching 83% at 700 °C, due to the finer active nanoparticle size and greater exposure of active site. Furthermore, the time-on-stream tests demonstrated that the catalytic activity of in situ reduced FeCo alloy catalysts could remain above 92.3% of the highest catalytic activity after 10 h. In addition, TEM analyses of the carbon products from the CMD in situ reduced catalysts revealed the production of carbon nanofibers and nanotubes several microns in length after the reaction. This indicates that the in situ reduced FeCo alloy catalysts more effectively promoted the growth of carbon nanofibers. These results could provide a viable strategy for future methane decomposition development aimed at producing hydrogen and high-value carbon. Full article
(This article belongs to the Special Issue Nanomaterials for Sustainable Green Energy)
16 pages, 3980 KiB  
Article
Planting Ages Inhibited Soil Respiration and CO2-C Emissions Attribute to Soil Degradation in Gravel-Mulched Land in Arid Areas
by Bingyao Wang, Yunfei Li, Zhixian Liu, Peiyuan Wang, Zhanjun Wang, Xudong Wu, Yongping Gao, Lichao Liu and Haotian Yang
Land 2024, 13(11), 1923; https://doi.org/10.3390/land13111923 (registering DOI) - 15 Nov 2024
Viewed by 213
Abstract
Gravel mulching is a widely employed strategy for water conservation in arid agricultural regions, with potential implications for soil carbon (C) sequestration and greenhouse gas emissions. However, soil respiration and CO2-C emissions remain uncertain owing to less consideration of the influence [...] Read more.
Gravel mulching is a widely employed strategy for water conservation in arid agricultural regions, with potential implications for soil carbon (C) sequestration and greenhouse gas emissions. However, soil respiration and CO2-C emissions remain uncertain owing to less consideration of the influence of precipitation patterns and planting age. In this study, we investigated the soil respiration rate (Rsoil) and cumulative CO2-C emission (Ccum), both measured over a period of 72 h, along with soil properties and enzyme activities under different precipitation conditions based on gravel mulching with different planting ages. We analyzed the effects of planting ages on Rsoil and Ccum and revealed the underlying mechanisms driving changes in environmental factors on Rsoil and Ccum. The results demonstrated that the Rsoil reached the maximum value at about 1 h, 0.5 h, and 0.25 h after rewetting in 1, 10, and 20 years of gravel mulching under the condition with 1 mm, 5 mm, and 10 mm of precipitation, respectively, whereas the Rsoil exhibited its maximum at about 8 h after soil rewetting under precipitation of 30 mm. The Ccum induced by precipitation pulses tends to decrease with increasing years of gravel mulching. The Ccum was 0.0061 t ha−1 in the 20-year gravel-mulched soil, representing a 53.79% reduction compared to the 1-year gravel-mulched soil. Soil organic matter (SOM), planting ages, and alkaline phosphatase (ALP) were the primary factors influencing the Rsoil and Ccum in 0–20 cm, while SOM, planting ages, and soil porosity (AirP) were the key factors affecting the Rsoil and Ccum in 20–40 cm. The Rsoil and Ccum in the 0–20 cm soil were regulated by soil enzyme activities, while those of 20–40 cm soil were controlled by soil properties. This indicates that the decrease in Rsoil and Ccum is caused by soil degradation, characterized by a decrease in SOM and ALP. This study offers a novel insight into the long-term environmental impact of gravel mulching measures in arid areas, which is helpful in providing a theoretical basis for dryland agricultural management. It is imperative to consider the duration of gravel mulching when predicting the potential for C sequestration in arid agricultural areas. Full article
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<p>Elevation map of the study areas and sampling site: (<b>a</b>) provincial administrative (Ningxia Hui Autonomous Region, China) elevation map of the study areas; (<b>b</b>) general view of the research sites; (<b>c</b>) samples gravel-mulched for 1 year; (<b>d</b>) samples gravel-mulched for 10 years; (<b>e</b>) samples gravel-mulched for 20 years.</p>
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<p>Dynamic variation characteristics of soil respiration under different precipitation conditions. Note: Y<sub>1</sub>, gravel-mulched land with 1 year; Y<sub>10</sub>, gravel-mulched land with 10 years; Y<sub>20</sub>, gravel-mulched land with 20 years.</p>
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<p>Cumulative CO<sub>2</sub>-C emission of soil respirable C within 72 h after precipitation. Note: The presence of prominent capital letters indicates statistically significant differences in CO<sub>2</sub>-C emissions across various precipitation conditions, with a significance level of <span class="html-italic">p</span> &lt; 0.05. Similarly, the occurrence of a distinct lowercase letter signifies a statistically significant difference in CO<sub>2</sub>-C emissions between different years of gravel-mulched tillage.</p>
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<p>Correlation of precipitation, planting ages, soil physicochemical properties, and enzyme activities in 0–20 cm (<b>a</b>) and 20–40 cm (<b>b</b>) soils. P, precipitation; PA, planting age; BD, bulk density; Pro, soil porosity; AirP, soil air permeability; SOM, soil organic matter; AN, available nitrogen; AK, available potassium; AP, Available phosphorus; ALP, alkaline phosphatase; CAT, catalase; URE, urease; <span class="html-italic">R<sub>max</sub></span>, maximum rate of CO<sub>2</sub>-C emission; <span class="html-italic">C<sub>cum,</sub></span> the cumulative CO<sub>2</sub>-C emission. Note: * <span class="html-italic">p</span> &lt; 0.05, ** <span class="html-italic">p</span> &lt; 0.01, *** <span class="html-italic">p</span> &lt; 0.001.</p>
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<p>RDA ordination plots of precipitation, planting ages, soil physicochemical properties, and enzyme activities for 0–20 cm (<b>a</b>) and 20–40 cm (<b>b</b>) soils. Note: PA, planting age; BD, bulk density; Pro, soil porosity; AirP, soil air permeability; SOM, soil organic matter; AN, available nitrogen; AK, available potassium; AP, Available phosphorus; ALP, alkaline phosphatase; CAT, catalase; URE, urease; <span class="html-italic">R<sub>max</sub></span>, the maximum rate of CO<sub>2</sub>-C emission; <span class="html-italic">C<sub>cum</sub></span>, the cumulative CO<sub>2</sub>-C emission.</p>
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<p>Structural equation modeling of soil respiration as a function of planting ages and precipitation variability: (<b>a</b>,<b>b</b>) the 0–20 cm soil layer; (<b>c</b>,<b>d</b>) the 20–40 cm soil layer. Note: Numbers adjoining the arrows indicate standardized path coefficients, and the arrow width is proportional to the strength of the association. The red arrow represents the positive correlation, and the blue arrow is the negative correlation. Asterisks indicate significance (* <span class="html-italic">p</span> &lt; 0.05, ** <span class="html-italic">p</span> &lt; 0.01, *** <span class="html-italic">p</span> &lt; 0.001), and the absence of any marker shows no significance. Variance inflation factors (VIF), coefficient of determination (R<sup>2</sup>), common factor variance (Q<sup>2</sup>), and goodness of fit (GOF) are shown. PA, planting ages; P, precipitation; ALP, alkaline phosphatase; CAT, catalase; Pro, soil porosity; SOM, soil organic matter; CS, clay and silt; AN, available nitrogen; <span class="html-italic">R<sub>ave</sub></span>, average rate of soil respiration; <span class="html-italic">R<sub>cum</sub></span>, cumulative of maximum rate of soil respiration.</p>
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<p>Standardized total effects of environmental factors, soil properties, and enzyme activity in PLS-PM. Note: <span class="html-italic">R<sub>ave</sub></span>, average rate of soil respiration; <span class="html-italic">C<sub>cum</sub></span>, the cumulative CO<sub>2</sub>-C emission.</p>
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16 pages, 1455 KiB  
Article
Evaluating the Effects of Fertilizer Deep Placement on Greenhouse Gas Emissions and Nutrient Use Efficiency in Wet Direct-Seeded Rice During the Wet Season in Assam, India
by Jami Naveen, Khagen Kurmi, Mrinal Saikia, Kalyan Pathak, Virendar Kumar, Rupam Borgohain, Ashish K. Srivastava, Suryakanta Khandai, Panneerselvam Peramaiyan, Vivek Kumar, Mintu Sarmah, Bhabesh Gogoi, Kanwar Singh, Sudhanshu Singh, Sumanta Kundu, Kandapu Sai Teja and Guntamukkala Sekhar
Agriculture 2024, 14(11), 2061; https://doi.org/10.3390/agriculture14112061 (registering DOI) - 15 Nov 2024
Viewed by 236
Abstract
Mitigation of greenhouse gases (GHGs), improving nutrient-use efficiency (NUE), and maximizing yield in rainfed lowland rice cultivation poses significant challenges. To address this, a two-year field experiment (2020 and 2021) was conducted in Assam, India, to examine the impact of different fertilizer-management practices [...] Read more.
Mitigation of greenhouse gases (GHGs), improving nutrient-use efficiency (NUE), and maximizing yield in rainfed lowland rice cultivation poses significant challenges. To address this, a two-year field experiment (2020 and 2021) was conducted in Assam, India, to examine the impact of different fertilizer-management practices on grain yield, NUE, and GHGs in wet direct-seeded rice (Wet-DSR) during the kharif season. The experiment included eight treatments: control; farmer’s practice (30-18.4-36 kg N-P2O5-K2O ha−1); state recommended dose of fertilizer (RDF) @ 60-20-40 kg N-P2O5-K2O ha−1 with N applied in three splits @ 30-15-15 kg ha−1 as basal, at active tillering (AT), and panicle initiation (PI); best fertilizer management practices (BMPs): 60-20-40 kg N-P2O5-K2O ha−1 with N applied in three equal splits as basal, at AT, and PI; and fertilizer deep placement (FDP) of 120%, 100%, 80%, and 60% N combined with 100% PK of RDF. The experiment was arranged out in a randomized complete block design with three replications for each treatment. The highest grain yield (4933 kg ha−1) and straw yield (6520 kg ha−1) were achieved with the deep placement of 120% N + 100% PK of RDF. FDP with 80% N + 100% PK reduced 38% N2O emissions compared to AAU’s RDF and BMPs, where fertilizer was broadcasted. This is mainly due to the lower dose of nitrogen fertilizer and the application of fertilizer in a reduced zone of soil. When considering both productivity and environmental impact, applying 80% N with 100% PK through FDP was identified as the most effective practice. Full article
(This article belongs to the Section Crop Production)
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<p>Graphical representation of the weekly air temperature and precipitation observed during the crop growth period.</p>
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<p>Effect of fertilizer management practices on CH<sub>4</sub> emission, and N<sub>2</sub>O flux in wet direct-seeded <span class="html-italic">Sali</span> rice (pooled).</p>
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<p>Effect of fertilizer management practices on available N, available P<sub>2</sub>O<sub>5,</sub> and available K<sub>2</sub>O in wet direct-seeded <span class="html-italic">kharif</span> rice.</p>
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<p>Effect of fertilizer management practices on available N, available P<sub>2</sub>O<sub>5,</sub> and available K<sub>2</sub>O in wet direct-seeded <span class="html-italic">kharif</span> rice.</p>
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<p>Effect of fertilizer management practices on the economic indicator in wet direct-seeded <span class="html-italic">Sali</span> rice.</p>
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8 pages, 6735 KiB  
Proceeding Paper
Silicon Nanowire-Supported Catalysts for the Photocatalytic Reduction of Carbon Dioxide
by Feysal M. Ali, Doug Perovic, Geoffrey A. Ozin and Hussameldin Ibrahim
Eng. Proc. 2024, 76(1), 81; https://doi.org/10.3390/engproc2024076081 - 15 Nov 2024
Viewed by 104
Abstract
The conversion of carbon dioxide, a greenhouse gas, into valuable chemicals using sunlight is highly significant technologically and holds the promise of providing a more sustainable alternative to fossil fuels. To effectively utilize the abundant solar irradiation, it is essential to develop catalysts [...] Read more.
The conversion of carbon dioxide, a greenhouse gas, into valuable chemicals using sunlight is highly significant technologically and holds the promise of providing a more sustainable alternative to fossil fuels. To effectively utilize the abundant solar irradiation, it is essential to develop catalysts that can absorb a significant portion of the solar spectrum, particularly in the UV, visible, and infrared regions. Silicon nanowire arrays grown on silicon substrates meet this criterion, as they can absorb over 85% of solar irradiation and show minimal reflective losses across the UV, visible, and infrared portions of the solar spectrum. Herein, we report the deposition of various catalysts, including iron oxyhydroxides, copper, nickel, and ruthenium, on silicon nanowires using different catalyst deposition techniques. The photocatalytic reduction of carbon dioxide was evaluated using these catalysts. The results show that silicon nanowires coated with nickel and ruthenium oxide had the highest activity towards the photocatalytic reduction of carbon dioxide, with photomethanation rates reaching 546 μmolgcat−1h−1 for RuO2@SiNWs and 278 μmolgcat−1h−1 for Ni/NiO@SiNWs. Continued improvement of photocatalysts using nanostructured silicon supports could enable the development of solar refineries for converting gas-phase CO2 into value-added chemicals and fuels. Full article
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<p>(<b>a</b>,<b>b</b>) SEM images of the α-FeOOH@SiNWs catalyst and those of the (<b>c</b>,<b>d</b>) β-FeOOH@SiNWs catalyst.</p>
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<p>(<b>a</b>,<b>b</b>) SEM images of the Cu@SiNWs catalyst.</p>
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<p>(<b>a</b>,<b>b</b>) SEM images of the Ni@SiNWs catalyst and that of (<b>c</b>,<b>d</b>) Ni/NiO@SiNWs catalyst.</p>
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<p>(<b>a</b>) Band structure of silicon nanowires with respect to fermi energy level of the nickel catalyst; (<b>b</b>) band structure of silicon nanowires with respect to that of nickel oxide; (<b>c</b>) valence and conduction band positions of silicon and nickel oxide with respect to the fermi position of metallic nickel.</p>
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<p>(<b>a</b>) SEM image of the RuO<sub>2</sub>@SiNWs catalyst; (<b>b</b>) TEM image of the RuO<sub>2</sub>@SiNWs catalyst. XPS showing (<b>c</b>) the 3d and (<b>d</b>) the O1s spectrum of the RuO<sub>2</sub>@SiNWs catalyst.</p>
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<p>The photocatalytic performance comparisons of α-FeOOH@SiNWs, β-FeOOH@SiNWs, Cu@SiNWs, Ni/NiO@SiNWs, and RuO<sub>2</sub>@SiNWs catalysts towards CO<sub>2</sub> reduction.</p>
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15 pages, 5664 KiB  
Article
A Trend Analysis of Changes in Cooling Degree Days in West Africa Under Global Warming
by Kagou Dicko, Emmanuel Tanko Umaru, Souleymane Sanogo, Appollonia Aimiosino Okhimamhe and Ralf Loewner
Atmosphere 2024, 15(11), 1376; https://doi.org/10.3390/atmos15111376 - 15 Nov 2024
Viewed by 211
Abstract
Monitoring energy consumption in response to rising temperatures has become extremely important in all regions of the globe. The energy required for cooling is a major challenge in West Africa, where the climate is predominantly tropical. Among the various methods for evaluating energy [...] Read more.
Monitoring energy consumption in response to rising temperatures has become extremely important in all regions of the globe. The energy required for cooling is a major challenge in West Africa, where the climate is predominantly tropical. Among the various methods for evaluating energy requirements, the degree-day method is best known for its ability to estimate the heating, ventilation, and air-conditioning (HVAC) requirements of buildings. This study used three decades of weather station data to assess the cooling degree days (CDD) in two major West African cities, Kano and Bamako, across a range of base temperatures from 22 °C to 30 °C. The results indicate an increase in cooling degree days for Kano, whereas Bamako experienced a decrease in these parameters over the same period. Nonetheless, Bamako required a relatively higher cooling demand for all base temperatures. Furthermore, the study showed that the years 1998 and 2015 had the most significant impact on Kano and Bamako, with CDD values ranging from 2220 °C-day to 218 °C-day for Kano and from 2425 °C-day to 276 °C-day for Bamako. The study also found that a lower base temperature leads to higher energy consumption, while a higher base temperature leads to lower energy consumption. This information provides a useful reference for governments and policymakers to achieve energy efficiency and reduce greenhouse gas emissions. Full article
(This article belongs to the Section Climatology)
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<p>Location of the study area in West Africa.</p>
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<p>Interannual variation in CDD for Kano at different base temperatures.</p>
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<p>Interannual variation in CDD for Bamako at different base temperatures.</p>
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<p>Annual average CDD at different base temperatures for Kano and Bamako.</p>
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<p>Correlation between annual CDD and mean temperature for Kano.</p>
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<p>Correlation between annual CDD and mean temperature for Bamako.</p>
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13 pages, 2559 KiB  
Article
Precipitation Patterns and Their Role in Modulating Nitrous Oxide Emissions from Arid Desert Soil
by Chunming Xin, Huijun Qin, Yuanshang Guo and Mingzhu He
Land 2024, 13(11), 1920; https://doi.org/10.3390/land13111920 - 15 Nov 2024
Viewed by 198
Abstract
Nitrous oxide (N2O) ranks as the third most significant greenhouse gas, capable of depleting the ozone layer and posing threats to terrestrial ecosystems. Climate change alters precipitation variability, notably in terms of frequency and magnitude. However, the implications of precipitation variability [...] Read more.
Nitrous oxide (N2O) ranks as the third most significant greenhouse gas, capable of depleting the ozone layer and posing threats to terrestrial ecosystems. Climate change alters precipitation variability, notably in terms of frequency and magnitude. However, the implications of precipitation variability on N2O emissions and the underlying mechanisms remain inadequately understood. In this study, employing laboratory incubation methods on three representative sandy soil types (sandy soil, shrub soil, and crust soil), we examined the impacts of diverse precipitation levels (5 mm and 10 mm) and frequencies (7 days and 14 days) on N2O emissions from these soil types. This study aims to clarify the complex connections between soil N2O emission fluxes and soil physicochemical properties in the soil environment. Our findings reveal that the N2O emission flux exhibits heightened responsiveness to 5 mm precipitation events and a 14-day precipitation frequency, and compared to other treatments, the 5 mm precipitation and 14-day precipitation frequency treatment resulted in a 20% increase in cumulative nitrous oxide emissions. Consequently, cumulative N2O emissions were notably elevated under the 5 mm precipitation and 14-day precipitation frequency treatments compared to the other experimental conditions. The N2O emission flux in sandy soil displayed a positive correlation with available phosphorus (AP) and a negative correlation with pH, primarily attributed to the exceedingly low AP content in sandy soil. In shrub soil, the soil N2O emission flux exhibited a significant positive correlation with NH4+-N and a negative correlation with NO3-N. Conversely, no significant correlations were observed between soil N2O emission flux and soil physicochemical properties in crust soil, underscoring the importance of considering plant–soil microbial interactions. Our findings suggest that soil nitrous oxide emissions in arid and semi-arid regions will be particularly responsive to small and frequent rainfall events as precipitation patterns change in the future, primarily due to their soil physicochemical characteristics. Full article
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<p>Variations in mass water content under different experimental conditions. The experimental treatments consisted of a precipitation frequency of 7 days with either 5 mm (F7P5) or 10 mm (F7P10) of precipitation (<b>a</b>), as well as a precipitation frequency of 14 days with either 5 mm (F14P5) or 10 mm (F14P10) of precipitation (<b>b</b>).</p>
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<p>The emission fluxes of N<sub>2</sub>O for each experimental treatment. The experimental treatments comprised F7P5 (<b>a</b>), F7P10 (<b>b</b>), F14P5 (<b>c</b>), and F14P10 (<b>d</b>). The data for each point is represented as the mean value plus or minus the standard error (mean ± SE).</p>
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<p>The total cumulative N<sub>2</sub>O emission across various experimental treatments. Lowercase letters indicate significant differences in N<sub>2</sub>O cumulative emissions between the three soil types, while uppercase letters indicate significant differences between experimental treatments. The identical letter indicates no statistically significant variance, while distinct letters indicate a significant difference.</p>
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<p>The relationships between species N<sub>2</sub>O emission fluxes and soil physicochemical properties in sandy soil (<b>a</b>), shrub soil (<b>b</b>), and crust soil (<b>c</b>).</p>
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<p>The correlation between AP (<b>a</b>) and pH (<b>b</b>) levels and the emission fluxes of soil N<sub>2</sub>O in sandy soil. The red area denotes the 95% confidence interval.</p>
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<p>The correlation between NH<sub>4</sub><sup>+</sup>-N (<b>a</b>) and NO<sub>3</sub><sup>−</sup>-N (<b>b</b>) levels and N<sub>2</sub>O emission fluxes from shrub soil. The red area denotes the 95% confidence interval.</p>
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31 pages, 839 KiB  
Review
Using Ionic Liquids to Improve CO2 Capture
by Francisco Jose Alguacil and Jose Ignacio Robla
Molecules 2024, 29(22), 5388; https://doi.org/10.3390/molecules29225388 - 15 Nov 2024
Viewed by 221
Abstract
Most of our energy consumption proceeds from the use of fossil fuels and the production of natural gas. However, the presence of impurities in this gas, like CO2, makes treatment necessary to avoid further concerns, such as greenhouse gas emissions, the [...] Read more.
Most of our energy consumption proceeds from the use of fossil fuels and the production of natural gas. However, the presence of impurities in this gas, like CO2, makes treatment necessary to avoid further concerns, such as greenhouse gas emissions, the corrosion of industrial equipment, etc.; thus, the development of CO2 capture and storage procedures is of the utmost importance in order to decrease CO2 production and mitigate its contribution to global warming. Among the CO2 capture processes available, three separation technologies are being used to achieve this goal: absorption, adsorption and membranes. To overcome some limitations of these methodologies, the joint use of these technologies with ionic liquids is gaining interest. The present work reviewed the most recent developments (for 2024) in CO2 capture using ionic liquids coupled to absorption-, adsorption- or membrane-based processes. Full article
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<p>Commercial hollow fiber membrane module to investigate CO<sub>2</sub> permeation phenomena. Phases entering the module in counter-current operational form (co-current form is also possible, and the way (tube or shell sides) in which the phases feed the module). Module length: 28 cm. Fiber length: 15 cm. Effective membrane area: 1.4 m<sup>2</sup>.</p>
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<p>Scheme of different types of carbon dioxide capture/separation processes.</p>
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25 pages, 1077 KiB  
Review
Environmental Policy vs. the Reality of Greenhouse Gas Emissions from Top Emitting Countries
by Nerea Portillo Juan, Vicente Negro Valdecantos, Javier Olalde Rodríguez and Gregorio Iglesias
Energies 2024, 17(22), 5705; https://doi.org/10.3390/en17225705 - 14 Nov 2024
Viewed by 379
Abstract
The 21st century climate crisis has been compounded by the COVID-19 health crisis and the Russian war. What at first appeared to be an opportunity to move towards sustainable growth and development has turned into the opposite. In this context, it seems necessary [...] Read more.
The 21st century climate crisis has been compounded by the COVID-19 health crisis and the Russian war. What at first appeared to be an opportunity to move towards sustainable growth and development has turned into the opposite. In this context, it seems necessary to pause and analyze what countries are doing and where they are heading in order to ensure that their environmental efforts are not in vain. This article analyzes the environmental policies of the seven countries emitting the most GHGs from 1990 to the present day and compares them with the reality of their emissions. These behaviors are extrapolated into the future and, finally, conclusions are drawn as to which countries are not fully living up to their commitments, which have implemented the most effective measures, and where particular attention needs to be directed for maximum efficiency in decarbonizing the energy mix. Full article
(This article belongs to the Collection Feature Papers in Energy, Environment and Well-Being)
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<p>Historic evolution of the emissions of the 7 top emitting countries.</p>
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<p>Historic evolution of emissions intensity of the 7 top emitting countries.</p>
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28 pages, 9113 KiB  
Article
A Multi Source Data-Based Method for Assessing Carbon Sequestration of Urban Parks from a Spatial–Temporal Perspective: A Case Study of Shanghai Century Park
by Yiqi Wang, Jiao Yu, Weixuan Wei and Nannan Dong
Land 2024, 13(11), 1914; https://doi.org/10.3390/land13111914 - 14 Nov 2024
Viewed by 258
Abstract
As urbanization accelerates globally, urban areas have become major sources of greenhouse gas emissions. In this context, urban parks are crucial as significant components of carbon sinks. Using Shanghai Century Park as a case study, this study aims to develop an applicable and [...] Read more.
As urbanization accelerates globally, urban areas have become major sources of greenhouse gas emissions. In this context, urban parks are crucial as significant components of carbon sinks. Using Shanghai Century Park as a case study, this study aims to develop an applicable and reliable workflow to accurately assess the carbon sequestration capacity of urban parks from a spatial–temporal perspective. Firstly, the random forest model is employed for biotope classification and mapping in the park based on multi-source data, including raw spectral bands, vegetation indices, and texture features. Subsequently, the Net Primary Productivity and biomass of different biotope types are calculated, enabling dynamic monitoring of the park’s carbon sequestration capacity from 2018 to 2023. Moreover, the study explores the main factors influencing changes in carbon sequestration capacity from the management perspective. The findings reveal: (1) The application of multi-source imagery data enhances the accuracy of biotope mapping, with winter imagery proving more precise in classification. (2) From 2018 to 2023, Century Park’s carbon sequestration capacity showed a fluctuating upward trend, with significant variations in the carbon sequestration abilities of different biotope types within the park. (3) Renovation and construction work related to biotope types significantly impacted the park’s carbon sequestration capacity. Finally, the study proposes optimization strategies focused on species selection and layout, planting density, and park management. Full article
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<p>Location of the study area: (<b>a</b>) China; (<b>b</b>) Pudong New District, Shanghai; (<b>c</b>) Century Park.</p>
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<p>Flowchart of methodology.</p>
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<p>Schematic diagram of Random Forest model for image classification.</p>
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<p>Accuracy assessment of classification results from four RF models ((<b>top</b>): overall accuracy; (<b>bottom</b>): Kappa coefficient).</p>
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<p>Schematic diagram of biotope type transitions in Century Park from 2018 to 2020.</p>
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<p>Schematic diagram of biotope type transitions in Century Park from 2020 to 2023.</p>
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<p>NPP (<b>top</b>) and biomass (<b>bottom</b>) map of Century Park in 2023.</p>
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<p>Variation in CS capacity of Century Park from 2018 to 2023.</p>
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<p>Variation in NPP per unit area for landscape zones in Century Park from 2018 to 2023.</p>
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<p>Variation in biomass per unit area for landscape zones in Century Park from 2018 to 2023.</p>
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<p>Spatial distribution of renovation and construction work in Century Park.</p>
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<p>Variation in area of 5 biotopes and CS capacity in Lakeside Scenic Zone.</p>
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<p>Variation in area of 5 biotopes and CS capacity in Scenic Forest Zone.</p>
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<p>Variation in area of 5 biotopes and CS capacity in Golf Course Zone.</p>
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<p>Biotope maps of Century Park from 2018 to 2023.</p>
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26 pages, 8262 KiB  
Article
Wind–Photovoltaic–Electrolyzer-Underground Hydrogen Storage System for Cost-Effective Seasonal Energy Storage
by Torsten Clemens, Martin Hunyadi-Gall, Andreas Lunzer, Vladislav Arekhov, Martin Datler and Albert Gauer
Energies 2024, 17(22), 5696; https://doi.org/10.3390/en17225696 - 14 Nov 2024
Viewed by 399
Abstract
Photovoltaic (PV) and wind energy generation result in low greenhouse gas footprints and can supply electricity to the grid or generate hydrogen for various applications, including seasonal energy storage. Designing integrated wind–PV–electrolyzer underground hydrogen storage (UHS) projects is complex due to the interactions [...] Read more.
Photovoltaic (PV) and wind energy generation result in low greenhouse gas footprints and can supply electricity to the grid or generate hydrogen for various applications, including seasonal energy storage. Designing integrated wind–PV–electrolyzer underground hydrogen storage (UHS) projects is complex due to the interactions between components. Additionally, the capacities of PV and wind relative to the electrolyzer capacity and fluctuating electricity prices must be considered in the project design. To address these challenges, process modelling was applied using cost components and parameters from a project in Austria. The hydrogen storage part was derived from an Austrian hydrocarbon gas field considered for UHS. The results highlight the impact of the renewable energy source (RES) sizing relative to the electrolyzer capacity, the influence of different wind-to-PV ratios, and the benefits of selling electricity and hydrogen. For the case study, the levelized cost of hydrogen (LCOH) is EUR 6.26/kg for a RES-to-electrolyzer capacity ratio of 0.88. Oversizing reduces the LCOH to 2.61 €/kg when including electricity sales revenues, or EUR 4.40/kg when excluding them. Introducing annually fluctuating electricity prices linked to RES generation results in an optimal RES-to-electrolyzer capacity ratio. The RES-to-electrolyzer capacity can be dynamically adjusted in response to market developments. UHS provides seasonal energy storage in areas with mismatches between RES production and consumption. The main cost components are compression, gas conditioning, wells, and cushion gas. For the Austrian project, the levelized cost of underground hydrogen storage (LCHS) is 0.80 €/kg, with facilities contributing EUR 0.33/kg, wells EUR 0.09/kg, cushion gas EUR 0.23/kg, and OPEX EUR 0.16/kg. Overall, the analysis demonstrates the feasibility of integrated RES–hydrogen generation-seasonal energy storage projects in regions like Austria, with systems that can be dynamically adjusted to market conditions. Full article
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<p>Overview of renewable energy generation using wind and PV, hydrogen generation, and supply to underground hydrogen storage. The energy generation section supplies electricity by transmission via the communal grid (grid supply/return) to a proton-exchange membrane (PEM) electrolyzer to generate hydrogen. Hydrogen is afterwards supplied to a pipeline or underground hydrogen storage (UHS). After the UHS, due to mixing effects in the storage, the gas stream is conditioned and separated to be supplied to a hydrogen and a natural gas (NG) pipeline, respectively.</p>
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<p>Comparison of vertical and horizontal panels of a project on a sunny winter day (20 December 2019). i-South, inclined south 20°; v-E/W, vertical east/west. The blue curve shows the resulting power generation from PV cells facing south. The result is a single peak while the bi-facial agrivoltaic installation in east-west direction leads to two peaks (orange curves).</p>
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<p>Overview of the underground hydrogen storage process. Gases produced from the underground hydrogen storage (UHS) are compressed and then treated in a pressure swing adsorption unit (PSA). The pure hydrogen is produced into the hydrogen pipeline, whereas the gas that is not meeting pipeline specifications is further separated using membranes. The permeate is back-circulated to the PSA.</p>
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<p>Overview of the AVEVA model components for sustainable energy and hydrogen generation. Here, a system of equal installed capacity for PV and wind is depicted. The simulation model also includes energetic losses at each modelled piece of equipment.</p>
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<p>Simulated PV, PV and wind power output, and electrolyzer power input for Case 2 (power ratio, 0.5; RES ratio, 1:1). The diagram shows that during summertime PV and wind generated power exceeds the electrolyzer capacity for this case.</p>
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<p>Simulated PV and wind power output and electrolyzer power required versus operating hours in a year for Case 2.</p>
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<p>Sankey diagram for Case 2. About 84% of the generated energy is used for conversion into hydrogen (RES installed capacity: 265 MW<sub>p</sub> PV and 265 MW wind turbines).</p>
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<p>LCOH versus electricity sales prices for various power ratios (numbers at the lines). Cases 1–4 are comparable, because they have a RES ratio PV:wind of 1:1. Case 5 refers to a PV-only case and Case 6 to wind only. The electricity price refers to the price at which excess electricity produced is sold. For electricity prices above the LCOE, the required LCOH is decreasing, while for electricity price below the LCOE, the required LCOH is increasing. The red area indicates that no economic cases can be realized. Within the area above the red area, projects with positive NPV can be generated.</p>
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<p>Electricity price cumulative function over the year hours.</p>
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<p>LCOH versus power ratio (<b>top</b>) for varying electricity prices within a year and present value cost as well as hydrogen production per year versus power ratio (<b>bottom</b>).</p>
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<p>Wind velocity versus power curve. Below a velocity ratio of 0.2, there is insufficient wind energy to generate power. Between the cut-in and rated velocities, the output power increases proportionally with wind velocity. Beyond the rated velocity, the controller limits the output power. Above the cut-out wind velocity, the blades are pitched and stopped to prevent turbine damage.</p>
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<p>Normalized renewable energy production over a year. Monthly cumulative function of power generation for PV (orange) and wind (blue).</p>
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<p>Total electricity demand in a year.</p>
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<p>Residual electricity demand in a year (<b>top</b>) and cumulative function of residual electricity demand (<b>bottom</b>).</p>
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<p>Electricity price versus residual electricity demand function.</p>
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24 pages, 5857 KiB  
Article
Simulation-Based Tool for Strategic and Technical Planning of Truck Charging Parks at Highway Sites
by Florian Klausmann and Felix Otteny
World Electr. Veh. J. 2024, 15(11), 521; https://doi.org/10.3390/wevj15110521 - 14 Nov 2024
Viewed by 285
Abstract
In the forthcoming years, it is expected that there will be a notable increase in the market penetration of electrically powered trucks with the objective of reducing greenhouse gas emissions in the transport sector. It is therefore essential to implement a comprehensive public [...] Read more.
In the forthcoming years, it is expected that there will be a notable increase in the market penetration of electrically powered trucks with the objective of reducing greenhouse gas emissions in the transport sector. It is therefore essential to implement a comprehensive public charging infrastructure along highways in the medium term, enabling vehicles to be charged overnight or during driving breaks, particularly in the context of long-distance transportation. This paper presents a simulation model that supports the planning and technical design of truck charging parks at German highway rest areas. It also presents a transferable mobility model for the volume of trucks and the parking times of long-distance trucks at rest areas. Subsequently, a simulation is offered for the purpose of designing the charging infrastructure and analysing peak loads in the local energy system. The potential of the models is demonstrated using various charging infrastructure scenarios for an exemplary reference site. Subsequently, the extent to which the charging infrastructure requirements and the service quality at the location depend on external conditions is explained. In addition, the influence of the range of offers and the business models on the efficiency of infrastructure use is established. Based on the findings, general recommendations for the design of truck charging parks at rest areas are then given and discussed. Full article
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Graphical abstract
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<p>Parking occupancy of 20 German rest areas over the course of a week.</p>
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<p>Probability for the break type/parking time for arriving trucks.</p>
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<p>Overview of the simulation model.</p>
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<p>MCS charging curve.</p>
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<p>Willingness to wait before charging process.</p>
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<p>Average truck park occupancy and road utilisation at the rest area.</p>
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<p>Distribution of trucks present at the same time: (<b>a</b>) truck utilisation of the rest area (maximum: 150 trucks, red line: 93 regular parking spaces at the rest area); (<b>b</b>) BET utilisation of the rest area with an electrification share of 20 percent (maximum: 36 BETs, red line: 20 percent of the regular parking spaces).</p>
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<p>Potential trip distances for the trucks at the rest area. Distances from (<b>a</b>) origin to destination, (<b>b</b>) origin to rest area, (<b>c</b>) rest area to destination.</p>
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<p>Average utilisation of the charging infrastructure over the course of the week in scenario 1.</p>
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<p>Peak load analysis for the charging park in Scenario 1.</p>
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<p>Development of service quality at the rest area with increasing electrification of vehicles and 7 MCS CP in Scenario 1a.</p>
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<p>Peak load analysis of the charging park in scenario 3.</p>
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