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Symmetry/Asymmetry: Feature Review Papers

A special issue of Symmetry (ISSN 2073-8994).

Deadline for manuscript submissions: closed (31 December 2023) | Viewed by 26512

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1. Institució Catalana de Recerca i Estudis Avançats (ICREA), Passeig Luis Companys, 23, 08010 Barcelona, Spain
2. Institute of Space Sciences (ICE-CSIC), C. Can Magrans s/n, 08193 Barcelona, Spain
Interests: cosmology; dark energy and inflation; quantum gravity; modified gravity and beyond general relativity; quantum fields at external fields
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Physics Department, Aristotle University of Thessaloniki, 541 24 Thessaloniki, Greece
Interests: cosmology; inflationary cosmology; modified theories of gravity; physics of the early universe; dark energy; dark matter; supersymmetry; mathematical physics; high energy physics; theoretical physics; epistemic game theory; game theory
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Department of Biology, Berry College, Mount Berry, GA 30149, USA
Interests: fluctuating asymmetry; developmental instability; evolutionary genetics; hybrid zones; community ecology
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

This Special Issue aims to publish high-quality long and complete review papers in Symmetry. The Issue will highlight a diverse set of topics related to symmetry/asymmetry phenomena wherever they occur in all aspects of natural sciences (e.g., physics, chemistry, biology, mathematics, materials, engineering science and computer science).

We are particularly interested in receiving manuscripts that review experimental and theoretical/computational studies as well as contributions from all disciplines.

All submissions should be explicitly related to symmetry studies and the related areas of symmetry already discussed in the journal Symmetry.

Prof. Dr. Sergei D. Odintsov
Prof. Dr. Juan Luis García Guirao
Prof. Dr. Vasilis Oikonomou
Prof. Dr. John H. Graham
Prof. Dr. György Keglevich
Guest Editors

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Related Special Issue

Published Papers (10 papers)

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Review

40 pages, 953 KiB  
Review
Recent Advances in Cosmological Singularities
by Oem Trivedi
Symmetry 2024, 16(3), 298; https://doi.org/10.3390/sym16030298 - 3 Mar 2024
Cited by 12 | Viewed by 1956
Abstract
The discovery of the Universe’s late-time acceleration and dark energy has led to a great deal of research into cosmological singularities, and in this brief review, we discuss all the prominent developments in this field for the best part of the last two [...] Read more.
The discovery of the Universe’s late-time acceleration and dark energy has led to a great deal of research into cosmological singularities, and in this brief review, we discuss all the prominent developments in this field for the best part of the last two decades. We discuss the fundamentals of spacetime singularities, after which we discuss in detail all the different forms of cosmological singularities that have been discovered in recent times. We then address methods and techniques to avoid or moderate these singularities in various theories and discuss how these singularities can also occur in non-conventional cosmologies. We then discuss a useful dynamical systems approach to deal with these singularities and finish up with some outlooks for the field. We hope that this work serves as a good resource to anyone who wants to update themselves with the developments in this very exciting area. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry: Feature Review Papers)
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<p>The classification of cosmological singularities summarized.</p>
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19 pages, 643 KiB  
Review
The Problem of Moments: A Bunch of Classical Results with Some Novelties
by Pier Luigi Novi Inverardi, Aldo Tagliani and Jordan M. Stoyanov
Symmetry 2023, 15(9), 1743; https://doi.org/10.3390/sym15091743 - 11 Sep 2023
Cited by 3 | Viewed by 1116
Abstract
We summarize significant classical results on (in)determinacy of measures in terms of their finite positive integer order moments. Well known is the role of the smallest eigenvalues of Hankel matrices, starting from Hamburger’s results a century ago and ending with the great progress [...] Read more.
We summarize significant classical results on (in)determinacy of measures in terms of their finite positive integer order moments. Well known is the role of the smallest eigenvalues of Hankel matrices, starting from Hamburger’s results a century ago and ending with the great progress made only in recent times by C. Berg and collaborators. We describe here known results containing necessary and sufficient conditions for moment (in)determinacy in both Hamburger and Stieltjes moment problems. In our exposition, we follow an approach different from that commonly used. There are novelties well complementing the existing theory. Among them are: (a) to emphasize on the geometric interpretation of the indeterminacy conditions; (b) to exploit fine properties of the eigenvalues of perturbed symmetric matrices allowing to derive new lower bounds for the smallest eigenvalues of Hankel matrices (these bounds are used for concluding indeterminacy); (c) to provide new arguments to confirm classical results; (d) to give new numerical illustrations involving commonly used probability distributions. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry: Feature Review Papers)
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<p>Parabolic region for H-indet case.</p>
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<p>Parabolic region for H-det case.</p>
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<p>Parabolic region for S-det—H-indet case.</p>
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<p>Parabolic region for S-det with H-det-(a).</p>
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<p>Parabolic region for S-det with H-det-(b).</p>
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27 pages, 12047 KiB  
Review
Symmetric Strange Attractors: A Review of Symmetry and Conditional Symmetry
by Chunbiao Li, Zhinan Li, Yicheng Jiang, Tengfei Lei and Xiong Wang
Symmetry 2023, 15(8), 1564; https://doi.org/10.3390/sym15081564 - 10 Aug 2023
Cited by 15 | Viewed by 3264
Abstract
A comprehensive review of symmetry and conditional symmetry is made from the core conception of symmetry and conditional symmetry. For a dynamical system, the structure of symmetry means its robustness against the polarity change of some of the system variables. Symmetric systems typically [...] Read more.
A comprehensive review of symmetry and conditional symmetry is made from the core conception of symmetry and conditional symmetry. For a dynamical system, the structure of symmetry means its robustness against the polarity change of some of the system variables. Symmetric systems typically show symmetrical dynamics, and even when the symmetry is broken, symmetric pairs of coexisting attractors are born, annotating the symmetry in another way. The polarity balance can be recovered through combinations of the polarity reversal of system variables, and furthermore, it can also be restored by the offset boosting of some of the system variables if the variables lead to the polarity reversal of their functions. In this case, conditional symmetry is constructed, giving a chance for a dynamical system outputting coexisting attractors. Symmetric strange attractors typically represent the flexible polarity reversal of some of the system variables, which brings more alternatives of chaotic signals and more convenience for chaos application. Symmetric and conditionally symmetric coexisting attractors can also be found in memristive systems and circuits. Therefore, symmetric chaotic systems and systems with conditional symmetry provide sufficient system options for chaos-based applications. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry: Feature Review Papers)
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Figure 1
<p>Symmetry, asymmetry and conditional symmetry in chaotic systems.</p>
Full article ">Figure 2
<p>Attractor of rotational symmetry in system (1) when <span class="html-italic">σ</span> = 0.279, <span class="html-italic">r</span> = 0, <span class="html-italic">b</span> = −0.3 and IC = (−0.1, 0.1, −2): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 3
<p>Symmetric solutions under the broken symmetry.</p>
Full article ">Figure 4
<p>Symmetric pair of attractors with rotational symmetry in system (1) under the parameters <span class="html-italic">σ</span> = 0.256, <span class="html-italic">r</span> = 0, <span class="html-italic">b</span> = −0.3 and IC<sub>1</sub> = (−0.1, 0.1, −2) (left), IC<sub>2</sub> = (0.1, −0.1, −2) (right): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 5
<p>Coexisting strange attractors of system (1) with rotational symmetry when <span class="html-italic">σ</span> = 0.279, <span class="html-italic">r</span> = 0, <span class="html-italic">b</span> = −0.3 and IC<sub>1</sub> = (−0.1, 0.1, −2) (blue), IC<sub>2</sub> = (−0.1, 0.1, −14) (cyan), IC<sub>3</sub> = (0.1, −0.1, −14) (purple): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 6
<p>Symmetric attractor of inversion symmetry in system (2) when <span class="html-italic">a</span> = 1.7, <span class="html-italic">b</span> = 2 and IC = (1, 0, 0): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 7
<p>A symmetric pair of coexisting attractors in system (2) when <span class="html-italic">a</span> = 2.1, <span class="html-italic">b</span> = 2 and IC<sub>1</sub> = (−1, 0, 0) (left), IC<sub>2</sub> = (1, 0, 0) (right): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 8
<p>Attractor of reflection invariant system (3) with <span class="html-italic">a</span> = 0.35 and IC = (−2, 2, 0): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 9
<p>A symmetric pair of attractors in a reflection invariant system (3) with <span class="html-italic">a</span> = 0.7 and IC<sub>1</sub> = (−2, 2, 0) (cyan), IC<sub>2</sub> = (2, 2, 0) (purple): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 10
<p>Quasi-periodic torus coexisting with a symmetric pair of chaotic attractors at <span class="html-italic">a</span> = 6, <span class="html-italic">b</span> = 0.1 (red and blue attractors correspond to two symmetric initial conditions under IC = (0, ±4, 0, ±5), cyan is for symmetric torus under IC = (1, −1, 1, −1)): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>, (<b>b</b>) <span class="html-italic">y</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 11
<p>Symmetric attractors of system (8) with <span class="html-italic">a</span> = <span class="html-italic">b</span> = 0.2, <span class="html-italic">c</span> = 6.5, <span class="html-italic">d</span> = 0 and IC<sub>1</sub> = (−9, 0, 2) (up), IC<sub>2</sub> = (−9, 0, −2) (down): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>, (<b>b</b>) <span class="html-italic">y</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 12
<p>Symmetric attractors of system (8) with <span class="html-italic">a</span> = <span class="html-italic">b</span> = 0.2, <span class="html-italic">c</span> = 6.5, <span class="html-italic">d</span> = 12 and IC<sub>1</sub> = (−9, 0, 12) (up), IC<sub>2</sub> = (−9, 0, −12) (down): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>, (<b>b</b>) <span class="html-italic">y</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 13
<p>Eight coexisting attractors of system (9) with <span class="html-italic">a</span> = <span class="html-italic">b</span> = 0.2, <span class="html-italic">c</span> = 6.5, <span class="html-italic">d</span><sub>1</sub> = 11, <span class="html-italic">d</span><sub>2</sub> = 13, <span class="html-italic">d</span><sub>3</sub> = 12.</p>
Full article ">Figure 14
<p>Polarity balance in a dynamical system.</p>
Full article ">Figure 15
<p>Coexisting conditional reflection symmetric attractors of system (10) with IC<sub>1</sub> = (3, −1.5, −2) (red), IC<sub>2</sub> = (3, −1.5, 1) (green): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>, (<b>b</b>) <span class="html-italic">y</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 16
<p>Coexisting conditional rotational symmetric attractors of system (11) with IC<sub>1</sub> = (3, 1, 0.5) (red), IC<sub>2</sub> = (−3, 1, 0.5) (green): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 17
<p>Coexisting attractors in system (12) by 2D offset boosting, when <span class="html-italic">a</span> = 0.22 and IC<sub>1</sub> = (2, 6, −1) (red), IC<sub>2</sub> = (−1, 1, −1) (green): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>, (<b>b</b>) <span class="html-italic">y</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 18
<p>Coexisting conditional rotational symmetric attractors of system (13) with <span class="html-italic">a</span> = 0.35, IC<sub>1</sub> = (0, 0.4, 6) (red), IC<sub>2</sub> = (0, 0.4, −5) (green): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>, (<b>b</b>) <span class="html-italic">y</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 19
<p>Coexisting attractors in conditional symmetric system (14) with <span class="html-italic">a</span> = 0.4, <span class="html-italic">b</span> = 1, IC<sub>1</sub> = (0, 14, 17) (red), IC<sub>2</sub> = (0, −6, −7) (green): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 20
<p>Coexisting attractors in symmetric system (15) with IC<sub>1</sub> = (1, 5, 5.5) (red), IC<sub>2</sub> = (1, −5, −4.5) (green): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>, (<b>b</b>) <span class="html-italic">y</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 21
<p>Coexisting repellors with conditional symmetry in system (16): (<b>a</b>) <span class="html-italic">y</span>–<span class="html-italic">x</span>, (<b>b</b>) <span class="html-italic">z</span>–<span class="html-italic">x</span>. (IC = (0, 0.96, 0) is red, IC = (6, 2, 2) is yellow, IC = (0, −0.96, 0) is green, IC = (−6, −2, −2) is blue).</p>
Full article ">Figure 22
<p>Coexisting attractors in system (17): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>. (IC = (1, 0, 0) is green, IC = (1 + 1.25π, 0, 0) is pink, IC = (1 + 2.5π, 0, 0) is red, IC = (1−1.25π, 0, 0) is cyan, IC = (1−2.5π, 0, 0) is blue).</p>
Full article ">Figure 23
<p>‘A square earth with a round sky above’ and two types of circuit constraints.</p>
Full article ">Figure 24
<p>A simple series chaotic circuit with a memristor, an inductor and a capacitor.</p>
Full article ">Figure 25
<p>Symmetric attractor in system (18) with <span class="html-italic">α</span> = 1, <span class="html-italic">ω</span> = 1 and IC = (4.1, 0.7, 5): (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">y</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 26
<p>Conditional symmetric chaotic attractors of system (19) with <span class="html-italic">a</span> = 0.6, <span class="html-italic">b</span> = 1, <span class="html-italic">c</span> = 2, (<b>a</b>) <span class="html-italic">z</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">z</span>–<span class="html-italic">x</span>. (IC = (2, 0, −1) is up, IC = (−2, 0, 1) is down).</p>
Full article ">Figure 27
<p>Meminductive parallel chaotic circuit for realizing system (19).</p>
Full article ">Figure 28
<p>Conditional symmetric chaotic attractors of system (19) with <span class="html-italic">a</span> = 0.6, <span class="html-italic">b</span> = 1, <span class="html-italic">c</span> = 2 observed in oscilloscope, (<b>a</b>) <span class="html-italic">z</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">z</span>–<span class="html-italic">x</span>. (IC = (2, 0, −1) is green, IC = (−2, 0, 1) is brown).</p>
Full article ">Figure 29
<p>Chaotic attractors in system (20) with <span class="html-italic">a</span> = 0.6, <span class="html-italic">b</span> = 1, <span class="html-italic">c</span> = 1, <span class="html-italic">d</span> = 4.11 and IC = (1, 1, −1). Here, two coexisting attractors close each other and bond to be a pseudo-double-scroll attractor: (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>.</p>
Full article ">Figure 30
<p>Coexisting attractors of system (20) with <span class="html-italic">a</span> = 0.6, <span class="html-italic">b</span> = 1, <span class="html-italic">c</span> = 1, <span class="html-italic">d</span> = 8: (<b>a</b>) <span class="html-italic">x</span>–<span class="html-italic">y</span>, (<b>b</b>) <span class="html-italic">x</span>–<span class="html-italic">z</span>. (IC = (−1, 1, −1) is left, IC = (1, 1, −1) is right).</p>
Full article ">Figure 31
<p>Simple circuit operation unit: (<b>a</b>) multiplier current constraint under external resistance, (<b>b</b>) the resistor-capacitor coupling realizes current control.</p>
Full article ">Figure 32
<p>Schematic circuit of the system (21).</p>
Full article ">
26 pages, 5945 KiB  
Review
Chiral Organophosphorus Pharmaceuticals: Properties and Application
by Anastasy O. Kolodiazhna and Oleg I. Kolodiazhnyi
Symmetry 2023, 15(8), 1550; https://doi.org/10.3390/sym15081550 - 7 Aug 2023
Cited by 12 | Viewed by 2121
Abstract
This review considers the chiral phosphorus-containing drugs used to treat patients in the clinic, as well as the promising and experimental drugs that are in the process of being researched. Natural and synthetic representatives of phosphorus-containing drugs, such as tenofovir (hepatitis B and [...] Read more.
This review considers the chiral phosphorus-containing drugs used to treat patients in the clinic, as well as the promising and experimental drugs that are in the process of being researched. Natural and synthetic representatives of phosphorus-containing drugs, such as tenofovir (hepatitis B and HIV treatment), fosfomycin (antibiotic), valinofos (antibiotic), phosphazinomycin A (antibiotic), (R)-phospholeucine, various antibacterial and antifungal agents, renin inhibitors, etc., have found practical applications as medicines and bioregulators and other medicines. The influence of the chirality of both carbon atoms and phosphorus atoms on the pharmacodynamics, pharmacokinetics, and toxicological properties of phosphorus drugs has been demonstrated. Therefore, the choice of enantiomers is critical since the wrong choice of a chiral drug can lead to undesirable consequences, carcinogenicity, and teratogenicity. New chiral technologies affecting drug development are discussed, such as the “chiral switch” of racemates already on the market, as well as phosphorus-containing prodrugs with a higher biological selectivity and low adverse effects. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry: Feature Review Papers)
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Figure 1
<p>Phosphoramide antibiotics.</p>
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<p>Phosphorus antibiotics of natural origin.</p>
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<p>Biologically active phosphonates of natural origin.</p>
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<p>Phosphoramide nucleotide antibiotics.</p>
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<p>Natural “Troyan Horse” antibiotics.</p>
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<p>Biologically active phosphonates.</p>
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<p>Typical examples of chiral phosphonocalixarenes.</p>
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<p>Synthesis of bisphosphonates, chiral in the side chain.</p>
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<p>Examples of chiral bisphosphonates.</p>
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<p>Synthesis of bisphosphonates, chiral in the side chain.</p>
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<p>Bisphosphonates—a derivative of amino acids.</p>
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<p>Aziridine analogues of presqualene diphosphates.</p>
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<p>Biochemical formation of vinylcyclopropylcarbinyl diphosphate.</p>
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<p>(<span class="html-italic">S</span>) and (<span class="html-italic">R</span>)–enantiomers of α-phosphonosulfonate effective against <span class="html-italic">Homo sapiens</span> SQS.</p>
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<p>Structures of phosphorus-containing compounds 1–3 targeting protein tyrosine phosphatase.</p>
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<p>Synthesis of chiral bisphosphonate synthon <b>4</b>.</p>
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<p>Aminophosphonate antibiotics: fosmidomycin and its derivatives, FR900098 and FR-33289.</p>
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<p>Phosphonopeptide antibiotics.</p>
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<p>Examples of phosphonopeptides.</p>
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<p>Some phosphorus prodrugs recently approved by the FDA.</p>
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<p>Structural formulas of the acyclic nucleoside phosphonate analogues PMPA and HPMPC.</p>
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<p>Synthesis of (<span class="html-italic">S</span>)-[3-hydroxy-2-(phosphonomethoxy)propyl] derivatives <b>9</b>.</p>
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<p>Synthesis of cidofovir <b>10</b>.</p>
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<p>The HepDirect strategy for phosph(on)ate prodrugs.</p>
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<p>Examples of adefovir analogs.</p>
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<p>Diastereomers of unsymmetrical phosphate prodrugs.</p>
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<p>Examples of HepDirect objects.</p>
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<p>Examples of lipid conjugate prodrugs.</p>
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<p>Structure of the SN-38 (<b>19</b>) methoxymethylphosphonate prodrugs and the naloxone prodrug <b>20</b>.</p>
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<p>Structures of Sofosbuvir and Tenofovir alafenamide.</p>
Full article ">Figure 31
<p>Examples of cycloSal phosphotriesters <b>21–24</b>.</p>
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<p>C-Nucleoside HCV polymerase inhibitor (GS6620) (<b>25</b>).</p>
Full article ">Figure 33
<p>Prodrug <b>26</b> analyzed as (<span class="html-italic">S</span><sub>P</sub>)-isomers.</p>
Full article ">Figure 34
<p>Synthesis of phosphorodiamidate derivatives (<span class="html-italic">R</span><sub>P</sub>)- or (<span class="html-italic">S</span><sub>P</sub>)-<b>30</b> and (<span class="html-italic">R</span><sub>P</sub>)- or (<span class="html-italic">S</span><sub>P</sub>)-<b>31</b> through (<span class="html-italic">R</span><sub>P</sub>)/(<span class="html-italic">S</span><sub>P</sub>)-phosphorochloridates.</p>
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38 pages, 11844 KiB  
Review
Azulene, Reactivity, and Scientific Interest Inversely Proportional to Ring Size; Part 2: The Seven-Membered Ring
by Alexandru C. Razus
Symmetry 2023, 15(7), 1391; https://doi.org/10.3390/sym15071391 - 10 Jul 2023
Cited by 3 | Viewed by 5439
Abstract
The second part of the article Azulene, Reactivity, and Scientific Interest Inversely Proportional to Ring Size deals with the chemical behavior of the seven-atom azulenic ring. As the title states, the ability of this system to react is lesser compared to [...] Read more.
The second part of the article Azulene, Reactivity, and Scientific Interest Inversely Proportional to Ring Size deals with the chemical behavior of the seven-atom azulenic ring. As the title states, the ability of this system to react is lesser compared to that of the five-atom ring; despite this, a large number of syntheses contain it as a participant in the molecules of starting compounds. This review is focused on certain more frequent syntheses such as nucleophilic substitution of the seven-atom ring or its substituents, vicarious nucleophilic substitutions, substitutions of azulene metallic compounds, or reactions catalyzed by complexes of certain transition metals. The syntheses of tricyclic compounds, porphyrinogenic systems, or azulenocyanines containing an azulenyl moiety are also presented. The adopted presentation is mainly based on reaction schemes that include the reaction conditions, as well as the yields of the products formed. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry: Feature Review Papers)
Show Figures

Scheme 1

Scheme 1
<p>Symmetry axes of naphthalene and HOMO of azulene.</p>
Full article ">Scheme 2
<p>Nucleophile addition to azulene and dehydrogenation of the Meisenheimer complex.</p>
Full article ">Scheme 3
<p>Difference between the vicarious nucleophilic substitution (VNS) and a classical one, S<sub>N</sub>Az.</p>
Full article ">Scheme 4
<p>Certain azulene seven ring substitutions, S<sub>N</sub>Az.</p>
Full article ">Scheme 5
<p>Hydroxylation of azulenes in Position 6.</p>
Full article ">Scheme 6
<p>Amination of azulenes in Position 6 (procedure for VSN).</p>
Full article ">Scheme 7
<p>Several nucleophilic early azulene substitutions, S<sub>N</sub>Az.</p>
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<p>Amination of azulenes in Position 6 (procedure for S<sub>N</sub>Az).</p>
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<p>S<sub>N</sub>Az of the MeO group in Position 6 with Et<sub>2</sub>N.</p>
Full article ">Scheme 10
<p>Electrophilic halogenation and acylation of the azulene seven ring, S<sub>E</sub>Az.</p>
Full article ">Scheme 11
<p>Vilsmeier reaction and azulene nitration.</p>
Full article ">Scheme 12
<p>Synthesis of N-containing heteroarylazulenes by electrophilic substitution.</p>
Full article ">Scheme 13
<p>Nucleophilic substitution of hydrogen belonging to the alkyl group in Position 4.</p>
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<p>Synthesis of 4-stirylazulenes.</p>
Full article ">Scheme 15
<p>Condensation of guaiazulene with thiophene-2-carbaldehyde.</p>
Full article ">Scheme 16
<p>Condensation of guaiazulene with thiophene 2- and 3-carbaldehyde.</p>
Full article ">Scheme 17
<p>Condensation of guaiazulene with certain aromatic and heteroaromatic aldehydes.</p>
Full article ">Scheme 18
<p>Synthesis of enamine intermediates and subsequent corresponding azulene carbaldehydes.</p>
Full article ">Scheme 19
<p>Reaction of azulenes with organomagnesium compounds.</p>
Full article ">Scheme 20
<p>Dimerization in the presence of a Grignard reagent.</p>
Full article ">Scheme 21
<p>Regioselective coupling of azulene at the double bond of α,β-unsaturated ketones.</p>
Full article ">Scheme 22
<p>Halogen–metal exchange reaction at Position 6 of azulene and subsequent replacement of metal.</p>
Full article ">Scheme 23
<p>Stille reaction at azulene Position 6.</p>
Full article ">Scheme 24
<p>Stille reaction of benzene with bromine atoms in different positions.</p>
Full article ">Scheme 25
<p>Stille reaction with organotin compounds.</p>
Full article ">Scheme 26
<p>Condensation of halogenozulene with various trimethylstannyl derivatives.</p>
Full article ">Scheme 27
<p>Heck–Negishi condensation.</p>
Full article ">Scheme 28
<p>Palladium catalyzed reaction between the 6-bromoazulene <b>28.1</b> and thiophene derivatives.</p>
Full article ">Scheme 29
<p>Borylation of azulenes.</p>
Full article ">Scheme 30
<p>Borylation at the azulene seven-membered ring.</p>
Full article ">Scheme 31
<p>Polyborylation and deborylation at the azulene seven-membered ring; Suzuki coupling.</p>
Full article ">Scheme 32
<p>Azulene dimerization by Suzuki condensation.</p>
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<p>Azulene oligomerization by Suzuki condensation.</p>
Full article ">Scheme 34
<p>Gao X. synthesis of cyclic diimide.</p>
Full article ">Scheme 35
<p>Suzuki cross-coupling syntheses.</p>
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<p>Suzuki reaction with thiophen-2-ylboronic acid.</p>
Full article ">Scheme 37
<p>Obtainment of “diarylethenes” 1 and 2 and their photochromic behavior.</p>
Full article ">Scheme 38
<p>Synthesis of bithyenyl-azulene, <b>38.1</b>.</p>
Full article ">Scheme 39
<p>Oligomers and polymers by Suzuki–Miyaura cross-coupling.</p>
Full article ">Scheme 40
<p>Buchwald–Hartwig procedure for obtaining dimeric aminoazulenes and poly [2(6)-aminoazulene.</p>
Full article ">Scheme 41
<p>Palladium-catalyzed reaction of phenylamines with 6-bromoazulene.</p>
Full article ">Scheme 42
<p>Dehydrogenative silylation of azulene.</p>
Full article ">Scheme 43
<p>Reaction of bromoazulenes with ethynylbenzene.</p>
Full article ">Scheme 44
<p>Reaction sequences starting from 6-bromoazulene, <b>44.1</b>, and ethynyltrimethylsilane or ethynylbenzene.</p>
Full article ">Scheme 45
<p>Sonogashira–Hagihara reaction for the generation of azulenylethynylbenzenes.</p>
Full article ">Scheme 46
<p>Synthesis of 9,10-anthracenediyl with azulene-substituted enediyne groups at Positions 9 and 10.</p>
Full article ">Scheme 47
<p>Sonogashira–Hagihara reaction based on reagents with thiophene in the molecule.</p>
Full article ">Scheme 48
<p>Sonogashira coupling of the haloazulene with 2-ethynylphenol.</p>
Full article ">Scheme 49
<p>Diels–Alder cycloaddition to build the product <b>49.2</b>.</p>
Full article ">Scheme 50
<p>Substitution with the simultaneous generation of a heteroaromatic substituent.</p>
Full article ">Scheme 51
<p>The synthesis of the tricyclic compound <b>51.3</b> and its subsequent reactions.</p>
Full article ">Scheme 52
<p>The synthesis of tricyclic compound <b>52.6</b> and its tautomerization.</p>
Full article ">Scheme 53
<p>Oxidation of benz[a]azulenes with pyridinium hydrobromide perbromide.</p>
Full article ">Scheme 54
<p>Synthesis of pyridazines and/or fulvenes starting from ethyl 4-ethoxy-3-formylazulene-1-carboxylate and hydrazines.</p>
Full article ">Scheme 55
<p>Tricyclic compounds obtained starting from 4-aminoguaiazulene and 1,2-dicarbonyl compounds.</p>
Full article ">Scheme 56
<p>Tricyclic azulenic systems containing a five-atom ring.</p>
Full article ">Scheme 57
<p>Synthesis of dicarboximides polycyclic aromatic hydrocarbons, terylene, and the azulenic isomer.</p>
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<p>Azulenyl moiety <span class="html-italic">meso</span>-linked to the porphyrin system.</p>
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<p>Ni<sup>II</sup>-porphyrin substituted with azulen-4-yl group(s).</p>
Full article ">Scheme 60
<p>Synthesis of azulenocyanine.</p>
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31 pages, 5754 KiB  
Review
Symmetry Perception and Psychedelic Experience
by Alexis D. J. Makin, Marco Roccato, Elena Karakashevska, John Tyson-Carr and Marco Bertamini
Symmetry 2023, 15(7), 1340; https://doi.org/10.3390/sym15071340 - 30 Jun 2023
Cited by 6 | Viewed by 4734
Abstract
This review of symmetry perception has six parts. Psychophysical studies have investigated symmetry perception for over 100 years (part 1). Neuroscientific studies on symmetry perception have accumulated in the last 20 years. Functional MRI and EEG experiments have conclusively shown that regular visual [...] Read more.
This review of symmetry perception has six parts. Psychophysical studies have investigated symmetry perception for over 100 years (part 1). Neuroscientific studies on symmetry perception have accumulated in the last 20 years. Functional MRI and EEG experiments have conclusively shown that regular visual arrangements, such as reflectional symmetry, Glass patterns, and the 17 wallpaper groups all activate the extrastriate visual cortex. This activation generates an event-related potential (ERP) called sustained posterior negativity (SPN). SPN amplitude scales with the degree of regularity in the display, and the SPN is generated whether participants attend to symmetry or not (part 2). It is likely that some forms of symmetry are detected automatically, unconsciously, and pre-attentively (part 3). It might be that the brain is hardwired to detect reflectional symmetry (part 4), and this could contribute to its aesthetic appeal (part 5). Visual symmetry and fractal geometry are prominent in hallucinations induced by the psychedelic drug N,N-dimethyltryptamine (DMT), and visual flicker (part 6). Integrating what we know about symmetry processing with features of induced hallucinations is a new frontier in neuroscience. We propose that the extrastriate cortex can generate aesthetically fascinating symmetrical representations spontaneously, in the absence of external symmetrical stimuli. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry: Feature Review Papers)
Show Figures

Figure 1

Figure 1
<p>(<b>A</b>) For most observers, reflectional symmetry is more salient than horizontal reflection, translation, or rotation. (<b>B</b>) Filtering images with reflectional symmetry produces mid-point collinear blobs, and the degree of reflectional symmetry is proportional to the degree of blob alignment (examples adapted from Mancini et al. [<a href="#B37-symmetry-15-01340" class="html-bibr">37</a>] and Rainville and Kingdom, [<a href="#B38-symmetry-15-01340" class="html-bibr">38</a>]). (<b>C</b>) When high and low spatial frequency filtered symmetrical images with orthogonal axes are superimposed, the low-resolution one dominates the percept (from Julesz and Chang, [<a href="#B39-symmetry-15-01340" class="html-bibr">39</a>]) (<b>D</b>) Figure 4 from Dakin and Hess [<a href="#B40-symmetry-15-01340" class="html-bibr">40</a>]. Phase disruption increases from top to bottom (a–d) 0 deg; (e–h) 60 deg; (i–l) 120 deg; (m–p) 360 deg. Axis orthogonal filtering is shown in the left two columns and axis parallel filtering is shown in the right two columns. Low-frequency filters are shown in columns 1 and 3. High-frequency filters are shown in columns 2 and 4. Axis orthogonal filtering is more robust to phase disruption (compare i and k for the clearest example). These experiments suggest orthogonal blobs that straddle the axis itself are fundamental for detecting reflectional symmetry. (<b>E</b>) Figure 1 from Dakin and Herbert [<a href="#B40-symmetry-15-01340" class="html-bibr">40</a>]. The original Figure legend reads: <span class="html-italic">“(a) Spatially band—limited symmetrical texture. (b) Same texture convolved with a low-frequency, horizontally orientated filter (inset), and ‘thresholded’ to remove values close to the mean grey level. Note the clustering of resulting blobs around the axis and the co-alignment of their centroids (crosses). (c) Symmetrical pattern where the contrast polarity of symmetrical features has been reversed across the axis. (d) Noise pattern containing a strip of symmetry around the axis; at brief presentation times, the entire pattern appears symmetrical.”</span> All examples from published work were reproduced with permission.</p>
Full article ">Figure 2
<p>(<b>A</b>) Anti-symmetry perception requires modification of filter models with front-end rectification of or second-order signals. (<b>B</b>) Reflection is more salient when it is the property of a single object. Translation is more salient when it is the property of a gap between two objects. This interaction between regularity type and objecthood is not explained by filter models. (<b>C</b>) Most experiments use symmetry in the frontoparallel plane. In the real world, symmetrical objects are often seen in perspective and do not project a symmetrical image onto the retina. This is a complication for filter models. (<b>D</b>) Symmetry in radial frequency patterns might be a special category (Adapted with permission from Wilson and Wilkinson, [<a href="#B93-symmetry-15-01340" class="html-bibr">93</a>]).</p>
Full article ">Figure 3
<p>(from Makin et al. [<a href="#B7-symmetry-15-01340" class="html-bibr">7</a>]) The grand-average ERPs are shown in the upper left panel and difference waves (reflection-random) are shown in the lower left panel. A large SPN is a difference wave that falls a long way below zero. Topographic difference maps are shown on the right, aligned with the representative stimuli (black background). The difference maps depict a head from above, and the SPN appears blue at the back. Purple labels indicate electrodes used for ERP waves [PO7, O1, O2, and PO8]. Note that SPN amplitude increases (that is, becomes more negative) with the proportion of symmetry in the image. In this experiment, the SPN increased from 0 to ~−3.5 microvolts as symmetry increased from 20% to 100%. Adapted from <a href="#symmetry-15-01340-f001" class="html-fig">Figure 1</a>, <a href="#symmetry-15-01340-f003" class="html-fig">Figure 3</a> and <a href="#symmetry-15-01340-f004" class="html-fig">Figure 4</a> in Makin et al. [<a href="#B141-symmetry-15-01340" class="html-bibr">141</a>].</p>
Full article ">Figure 4
<p>Parametric SPN responses in five different tasks. The default parametric response in the four non-regularity tasks (Color, Sound/color, Direction/color, and Distribution) was enhanced in the Regularity task (left panel). N = 26 in each task. Results from Makin et al. [<a href="#B141-symmetry-15-01340" class="html-bibr">141</a>].</p>
Full article ">Figure 5
<p>The left panel shows a ridge plot of all 249 SPNs currently in the complete Liverpool SPN catalog. Each distribution (ridge) shows the spread of participant-level SPNs around the grand average. Larger (more negative) SPNs are lower on the Y dimension. The right panel shows that variance in grand average SPN amplitude can be partly explained by W-load, and partly by task.</p>
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<p>Results from shifting occluder experiments of Rampone et al. [<a href="#B168-symmetry-15-01340" class="html-bibr">168</a>] (<b>A</b>) and Rampone et al. [<a href="#B169-symmetry-15-01340" class="html-bibr">169</a>] (<b>B</b>). An SPN is generated once the occluder shifts and reveals the second half of a symmetrical pattern.</p>
Full article ">Figure 7
<p>The SPN responses to reflectional symmetry and three types of Glass patterns. As with other SPNs, these waves are computed as a difference from a random condition (black square). These results from Rampone and Makin [<a href="#B181-symmetry-15-01340" class="html-bibr">181</a>] show that reflectional symmetry is not the only regularity that activates the extrastriate cortex and generates an SPN (All waves fall below the dashed black zero line).</p>
Full article ">Figure 8
<p>Results of Makin et al. [<a href="#B149-symmetry-15-01340" class="html-bibr">149</a>]. Amplitude is more negative for symmetrical than asymmetrical stimuli. However, negativity is even more strongly determined by abstraction (Patterns &lt; Floating Flowers &lt; Landscapes).</p>
Full article ">Figure 9
<p>Artistic representations of form constants, redrawn from [<a href="#B15-symmetry-15-01340" class="html-bibr">15</a>]. (<b>a</b>) tunnel/funnel; (<b>b</b>) spiral; (<b>c</b>) honeycomb; (<b>d</b>) cobweb.</p>
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41 pages, 496 KiB  
Review
Fluxbrane Polynomials and Melvin-like Solutions for Simple Lie Algebras
by Sergey V. Bolokhov and Vladimir D. Ivashchuk
Symmetry 2023, 15(6), 1199; https://doi.org/10.3390/sym15061199 - 3 Jun 2023
Cited by 1 | Viewed by 1066
Abstract
This review dealt with generalized Melvin solutions for simple finite-dimensional Lie algebras. Each solution appears in a model which includes a metric and n scalar fields coupled to n Abelian 2-forms with dilatonic coupling vectors determined by simple Lie algebra of rank n [...] Read more.
This review dealt with generalized Melvin solutions for simple finite-dimensional Lie algebras. Each solution appears in a model which includes a metric and n scalar fields coupled to n Abelian 2-forms with dilatonic coupling vectors determined by simple Lie algebra of rank n. The set of n moduli functions Hs(z) comply with n non-linear (ordinary) differential equations (of second order) with certain boundary conditions set. Earlier, it was hypothesized that these moduli functions should be polynomials in z (so-called “fluxbrane” polynomials) depending upon certain parameters ps>0, s=1,,n. Here, we presented explicit relations for the polynomials corresponding to Lie algebras of ranks n=1,2,3,4,5 and exceptional algebra E6. Certain relations for the polynomials (e.g., symmetry and duality ones) were outlined. In a general case where polynomial conjecture holds, 2-form flux integrals are finite. The use of fluxbrane polynomials to dilatonic black hole solutions was also explored. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry: Feature Review Papers)
Show Figures

Figure 1

Figure 1
<p>The Dynkin diagrams for the Lie algebras <inline-formula><mml:math id="mm959"><mml:semantics><mml:msub><mml:mi>A</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:semantics></mml:math></inline-formula>, <inline-formula><mml:math id="mm960"><mml:semantics><mml:msub><mml:mi>C</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:semantics></mml:math></inline-formula>, <inline-formula><mml:math id="mm961"><mml:semantics><mml:msub><mml:mi>G</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:semantics></mml:math></inline-formula>, respectively.</p>
Full article ">Figure 2
<p>The Dynkin diagrams for the Lie algebras <inline-formula><mml:math id="mm962"><mml:semantics><mml:msub><mml:mi>A</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:semantics></mml:math></inline-formula>, <inline-formula><mml:math id="mm963"><mml:semantics><mml:msub><mml:mi>B</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:semantics></mml:math></inline-formula>, <inline-formula><mml:math id="mm964"><mml:semantics><mml:msub><mml:mi>C</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:semantics></mml:math></inline-formula>, respectively.</p>
Full article ">Figure 3
<p>The Dynkin diagrams for the Lie algebras <inline-formula><mml:math id="mm965"><mml:semantics><mml:msub><mml:mi>A</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:semantics></mml:math></inline-formula>, <inline-formula><mml:math id="mm966"><mml:semantics><mml:msub><mml:mi>B</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:semantics></mml:math></inline-formula>, <inline-formula><mml:math id="mm967"><mml:semantics><mml:msub><mml:mi>C</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:semantics></mml:math></inline-formula>, <inline-formula><mml:math id="mm968"><mml:semantics><mml:msub><mml:mi>D</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:semantics></mml:math></inline-formula>, <inline-formula><mml:math id="mm969"><mml:semantics><mml:msub><mml:mi>F</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:semantics></mml:math></inline-formula>, respectively.</p>
Full article ">Figure 4
<p>Dynkin diagrams for the Lie algebras <inline-formula><mml:math id="mm970"><mml:semantics><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn>5</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:mspace width="0.166667em"/><mml:msub><mml:mi>B</mml:mi><mml:mn>5</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:mspace width="0.166667em"/><mml:msub><mml:mi>C</mml:mi><mml:mn>5</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:mspace width="0.166667em"/><mml:msub><mml:mi>D</mml:mi><mml:mn>5</mml:mn></mml:msub></mml:mrow></mml:semantics></mml:math></inline-formula>, respectively.</p>
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<p>The Dynkin diagram for the Lie algebra <inline-formula><mml:math id="mm971"><mml:semantics><mml:msub><mml:mi>E</mml:mi><mml:mn>6</mml:mn></mml:msub></mml:semantics></mml:math></inline-formula>.</p>
Full article ">Figure 6
<p>Dynkin diagram for semisimple Lie algebra <inline-formula><mml:math id="mm972"><mml:semantics><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:mo>⨁</mml:mo><mml:msub><mml:mi>A</mml:mi><mml:mn>1</mml:mn></mml:msub><mml:mo>⨁</mml:mo><mml:msub><mml:mi>A</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:mrow></mml:semantics></mml:math></inline-formula> describing the set of <inline-formula><mml:math id="mm973"><mml:semantics><mml:msub><mml:mi>A</mml:mi><mml:mn>5</mml:mn></mml:msub></mml:semantics></mml:math></inline-formula>-polynomials with <inline-formula><mml:math id="mm974"><mml:semantics><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:mo>=</mml:mo><mml:mn>0</mml:mn></mml:mrow></mml:semantics></mml:math></inline-formula> [<xref ref-type="bibr" rid="B28-symmetry-15-01199">28</xref>].</p>
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40 pages, 12642 KiB  
Review
Azulene, Reactivity, and Scientific Interest Inversely Proportional to Ring Size; Part 1: The Five-Membered Ring
by Alexandru C. Razus
Symmetry 2023, 15(2), 310; https://doi.org/10.3390/sym15020310 - 22 Jan 2023
Cited by 4 | Viewed by 2484
Abstract
The lack of azulene symmetry with respect to the axis perpendicular to a molecule creates an asymmetry of the electronic system, increasing the charge density of the five-atom ring and favoring its electrophilic substitutions. The increased reactivity of this ring has contributed to [...] Read more.
The lack of azulene symmetry with respect to the axis perpendicular to a molecule creates an asymmetry of the electronic system, increasing the charge density of the five-atom ring and favoring its electrophilic substitutions. The increased reactivity of this ring has contributed to ongoing interest about the syntheses in which it is involved. The aim of this review is to present briefly and mainly in the form of reaction schemes the behavior of this system. After a short chapter that includes the research until 1984, subsequent research is presented as generally accepted chapters and subchapters to describe the behavior of the azulene system: metal free catalyst reactions; reactions catalyzed by metals; various azulene five-ring substitutions. The author insists on reaction yields, and in some cases considers it useful to present the proposed reaction mechanisms. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry: Feature Review Papers)
Show Figures

Scheme 1

Scheme 1
<p>HOMO of azulene and its electrophile substitution.</p>
Full article ">Scheme 2
<p>Replacement of hydrogen at the five azulene ring.</p>
Full article ">Scheme 3
<p>The replacing of the substituent from positions 1 and 2 and the coupling of azulenes.</p>
Full article ">Scheme 4
<p>Leaving groups (or atoms) of azulenyl reagents.</p>
Full article ">Scheme 5
<p>Electrophile substitution of azulene with pyridinium salt.</p>
Full article ">Scheme 6
<p>Electrophile substitution of azulene with pyrylium salt.</p>
Full article ">Scheme 7
<p>S<sub>E</sub>Az at position 1 (and 3).</p>
Full article ">Scheme 8
<p>Synthesis of 1-(indol-2-yl)azulenes by Vilsmeier–Haack arylation.</p>
Full article ">Scheme 9
<p>Reissert–Henze reaction of azulenes with N-containing heteroaryl N-oxides.</p>
Full article ">Scheme 10
<p>Synthesis of azulenyl sulfides.</p>
Full article ">Scheme 11
<p>Substitution of azulenes with tetramethylenesulfoxide.</p>
Full article ">Scheme 12
<p>S<sub>E</sub>Az at position 2 activated by 6-NMe<sub>2</sub> group.</p>
Full article ">Scheme 13
<p>S<sub>N</sub>Az at position 2 in the presence of CO<sub>2</sub>Et in positions 1 and 3 (or without substituent).</p>
Full article ">Scheme 14
<p>S<sub>N</sub>Az at position 2 in azulene.</p>
Full article ">Scheme 15
<p>Synthesis of 2-azulene boronate.</p>
Full article ">Scheme 16
<p>Several routes for halogenation of azulene in position 2.</p>
Full article ">Scheme 17
<p>Synthesis of 1,1′-biazulenes without catalyst.</p>
Full article ">Scheme 18
<p>Radical dimerization of azulenes at the oxidation.</p>
Full article ">Scheme 19
<p>Aluminum chloride as catalyst of electrophile <span class="html-italic">ipso</span>-substitution.</p>
Full article ">Scheme 20
<p>Azulene arylation in the presence of Pd(OAc)<sub>2</sub>.</p>
Full article ">Scheme 21
<p>Substitution of 2-halogenoazulenes with thiophene derivatives.</p>
Full article ">Scheme 22
<p>Amination of 2-azulenols with <span class="html-italic">o</span>-benzoylhydroxylamines.</p>
Full article ">Scheme 23
<p>Proposed mechanism for the amination of 2-azulenols with 1-benzoylhydroxylamines.</p>
Full article ">Scheme 24
<p>Products of Stille coupling between halogenated azulene and different (tri-<span class="html-italic">n</span>-butyltin) substituted compounds.</p>
Full article ">Scheme 25
<p>Simplified representation of the Pd-catalyzed Stille reaction and additional copper participation.</p>
Full article ">Scheme 26
<p>Synthesis of 2,5-(diazulen-1-yl)phosphole <span class="html-italic">P</span>-oxide.</p>
Full article ">Scheme 27
<p>Attempting to generate 2-(tri-<span class="html-italic">n</span>-butylstannyl)azulene.</p>
Full article ">Scheme 28
<p>Polymers containing azulene.</p>
Full article ">Scheme 29
<p>Negishi cross-coupling.</p>
Full article ">Scheme 30
<p>Negishi cross-coupling with different organozinc compounds.</p>
Full article ">Scheme 31
<p>Negishi cross-coupling with azulenylzinc compounds.</p>
Full article ">Scheme 32
<p>The Kumada–Tamao–Corriu reaction.</p>
Full article ">Scheme 33
<p>Different behavior of borylation reagents.</p>
Full article ">Scheme 34
<p>Obtaining the photoswitch compounds <b>34.3</b>.</p>
Full article ">Scheme 35
<p>Reaction of 2-iodoazulene with pinacol esters <b>35.1</b> or <b>35.2</b>.</p>
Full article ">Scheme 36
<p>Coupling between azulenylboronates and bromopyridines.</p>
Full article ">Scheme 37
<p>Coupling between azulenylboronates with compound with furan moieties.</p>
Full article ">Scheme 38
<p>Coupling between azulen-2-yl boronate and halogenated compounds.</p>
Full article ">Scheme 39
<p>Synthesis of 2-aminoazulene.</p>
Full article ">Scheme 40
<p>Synthesis of azulene-embedded [n]helicenes.</p>
Full article ">Scheme 41
<p>Azulene-fused linear polycyclic aromatic hydrocarbons.</p>
Full article ">Scheme 42
<p>Synthesis of <span class="html-italic">meso</span>-azulenylporphyrins.</p>
Full article ">Scheme 43
<p>Simplified representation of Suzuki–Miyura reaction pathway.</p>
Full article ">Scheme 44
<p>Sonogashira–Hagihara reaction.</p>
Full article ">Scheme 45
<p>Obtaining of linear π-conjugated molecules.</p>
Full article ">Scheme 46
<p>Preparation of 1,3-bis(azulenylethynyl)azulenes.</p>
Full article ">Scheme 47
<p>Ethynylation procedure using TIPS-EBX, 2, <b>47.1</b>, as reagent.</p>
Full article ">Scheme 48
<p>Alkylation with propargylic alcohol <b>48.1</b>.</p>
Full article ">Scheme 49
<p>Acylation of azulenes.</p>
Full article ">Scheme 50
<p>Preparation of allyl-substituted azulenes catalyzed by a rhodium catalyst.</p>
Full article ">Scheme 51
<p>Guaiazulene alkylation using Ni(cod)<sub>2</sub> as catalyst.</p>
Full article ">Scheme 52
<p>Catalytic cycle proposed for carboxylic acid directed C−H arylation.</p>
Full article ">Scheme 53
<p>C−H bond functionalization by carbene–nitrene transfer.</p>
Full article ">Scheme 54
<p>Functionalized azulenes with cationic η<sup>5</sup>-iron carbonyl diene complexes.</p>
Full article ">Scheme 55
<p>2-(Azulenyl)benzo[b]furans syntheses.</p>
Full article ">Scheme 56
<p>Guaiazulene–heterocycle hybrid syntheses.</p>
Full article ">Scheme 57
<p>Three-component domino reaction: guaiazulene + methylglyoxal + enaminones.</p>
Full article ">Scheme 58
<p>Reaction of azulenes, aryl glyoxal and 1,3-dicarbonyl compounds.</p>
Full article ">Scheme 59
<p>2-Amino-3-cyano-4-aryl-10-ethoxycarbonylazuleno[2,1-b]pyrans synthesis.</p>
Full article ">Scheme 60
<p>1,2-Dihydro-1-oxabenz[a]azulen-2-one derivatives synthesis.</p>
Full article ">Scheme 61
<p>Proposed pathway for synthesis of tetra(substituted) benzoazulene.</p>
Full article ">Scheme 62
<p>Synthesis of tetra(substituted) benzoazulenes and di(substituted)azulenolactones.</p>
Full article ">Scheme 63
<p>The arylation of azulene and the synthesis of 3-arylazulenofuranones.</p>
Full article ">Scheme 64
<p>Synthesis of ethyl 2-phenyl-3H-azuleno[2,1-b]pyrrole-4-carboxylate, <b>64.2</b> [<a href="#B107-symmetry-15-00310" class="html-bibr">107</a>], azuleno[2,1-b]thiophenes, <b>64.3</b> [<a href="#B108-symmetry-15-00310" class="html-bibr">108</a>] and azulene[2,1-b]pyrrole-2,3-dione [<a href="#B109-symmetry-15-00310" class="html-bibr">109</a>].</p>
Full article ">Scheme 65
<p>Synthesis of azulenoisatine, <b>65.1</b> and azulenoisoindigo, <b>65.2</b>.</p>
Full article ">Scheme 66
<p>Synthesis of azulene-based BN-heteroaromatics.</p>
Full article ">Scheme 67
<p>Calixarene synthesis.</p>
Full article ">Scheme 68
<p>Azulenophane synthesis.</p>
Full article ">Scheme 69
<p>Lindsey−Rothemund Synthesis of azuliporphyrins.</p>
Full article ">
19 pages, 1050 KiB  
Review
Orbits of Particles and Photons around Regular Rotating Black Holes and Solitons
by Irina Dymnikova and Anna Dobosz
Symmetry 2023, 15(2), 273; https://doi.org/10.3390/sym15020273 - 18 Jan 2023
Cited by 2 | Viewed by 1830
Abstract
We briefly overview the basic properties and generic behavior of circular equatorial particle orbits and light rings around regular rotating compact objects with dark energy interiors, which are described by regular metrics of the Kerr–Schild class and include rotating black holes and self-gravitating [...] Read more.
We briefly overview the basic properties and generic behavior of circular equatorial particle orbits and light rings around regular rotating compact objects with dark energy interiors, which are described by regular metrics of the Kerr–Schild class and include rotating black holes and self-gravitating spinning solitons replacing naked singularities. These objects have an internal de Sitter vacuum disk and can have two types of dark interiors, depending on the energy conditions. The first type reduces to the de Sitter disk, the second contains a closed de Sitter surface and an S surface with the de Sitter disk as the bridge and an anisotropic phantom fluid in the regions between the S surface and the disk. In regular geometry, the potentials decrease from V(r) to their minima, which ensures the existence of the innermost stable photon and particle orbits that are essential for processes of energy extraction occurring within the ergoregions, which for the second type of interiors contain the phantom energy. The innermost orbits provide a diagnostic tool for investigation of dark interiors of de Sitter–Kerr objects. They include light rings which confine these objects and ensure the most informative observational signature for rotating black holes presented by their shadows. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry: Feature Review Papers)
Show Figures

Figure 1

Figure 1
<p>The first type of interior, horizons, and ergosphere (<b>left</b>) and second type of interior (<b>right</b>).</p>
Full article ">Figure 2
<p><math display="inline"><semantics> <mi mathvariant="script">S</mi> </semantics></math> surface, horizons, and ergospheres for <math display="inline"><semantics> <mrow> <mi>a</mi> <mo>=</mo> <mn>0.314</mn> </mrow> </semantics></math> (<b>left</b>) and <math display="inline"><semantics> <mrow> <mi>a</mi> <mo>=</mo> <mn>0.4</mn> </mrow> </semantics></math> (<b>right</b>).</p>
Full article ">Figure 3
<p>Dependence of radii on <span class="html-italic">a</span> for the marginally bound orbits (<b>left</b>) and for the marginally stable orbits (<b>right</b>), where <math display="inline"><semantics> <mrow> <msub> <mi>x</mi> <mi>g</mi> </msub> <mo>=</mo> <msub> <mi>r</mi> <mi>g</mi> </msub> <mo>/</mo> <msub> <mi>r</mi> <mn>0</mn> </msub> </mrow> </semantics></math>.</p>
Full article ">Figure 4
<p>Photon orbits, horizons, and ergospheres depending on <span class="html-italic">a</span> (<b>left</b>) and their enlarged image near the double horizon (<b>right</b>), where <math display="inline"><semantics> <mrow> <msub> <mi>x</mi> <mi>g</mi> </msub> <mo>=</mo> <msub> <mi>r</mi> <mi>g</mi> </msub> <mo>/</mo> <msub> <mi>r</mi> <mn>0</mn> </msub> </mrow> </semantics></math>.</p>
Full article ">Figure 5
<p>Limiting orbits in the de Sitter–Kerr geometry depending on <span class="html-italic">a</span> (<b>left</b>) and an enlarged image near the double horizon (<b>right</b>), where <math display="inline"><semantics> <mrow> <msub> <mi>x</mi> <mi>g</mi> </msub> <mo>=</mo> <msub> <mi>r</mi> <mi>g</mi> </msub> <mo>/</mo> <msub> <mi>r</mi> <mn>0</mn> </msub> </mrow> </semantics></math>.</p>
Full article ">Figure 6
<p>Impact parameters as celestial coordinates (<b>left</b>) and the asymmetry parameter <span class="html-italic">D</span> in the shadow contour (<b>right</b>).</p>
Full article ">Figure 7
<p>Comparison of shadows for the quickly decreasing density (Equation (<a href="#FD42-symmetry-15-00273" class="html-disp-formula">42</a>)) (<b>left</b>) and for the slowly decreasing density (Equation (<a href="#FD19-symmetry-15-00273" class="html-disp-formula">19</a>)) (<b>right</b>) for <math display="inline"><semantics> <mrow> <mi>a</mi> <mo>=</mo> <mn>0.3</mn> </mrow> </semantics></math>. The observer angular coordinate <math display="inline"><semantics> <mrow> <msub> <mi>θ</mi> <mi>i</mi> </msub> <mo>=</mo> <mi>π</mi> <mo>/</mo> <mn>2</mn> </mrow> </semantics></math>.</p>
Full article ">Figure 8
<p>Comparison of shadows for the quickly decreasing density (Equation (<a href="#FD42-symmetry-15-00273" class="html-disp-formula">42</a>)) (<b>left</b>) and for the slowly decreasing density (Equation (<a href="#FD19-symmetry-15-00273" class="html-disp-formula">19</a>)) (<b>right</b>) for <math display="inline"><semantics> <mrow> <mi>a</mi> <mo>=</mo> <mn>0.7</mn> </mrow> </semantics></math>. The observer angular coordinate <math display="inline"><semantics> <mrow> <msub> <mi>θ</mi> <mi>i</mi> </msub> <mo>=</mo> <mi>π</mi> <mo>/</mo> <mn>2</mn> </mrow> </semantics></math>.</p>
Full article ">
19 pages, 359 KiB  
Review
Some Applications of Affine in Velocities Lagrangians in Two-Dimensional Systems
by José F. Cariñena and José Fernández-Núñez
Symmetry 2022, 14(12), 2520; https://doi.org/10.3390/sym14122520 - 29 Nov 2022
Cited by 2 | Viewed by 1124
Abstract
The two-dimensional inverse problem for first-order systems is analysed and a method to construct an affine Lagrangian for such systems is developed. The determination of such Lagrangians is based on the theory of the Jacobi multiplier for the system of differential equations. We [...] Read more.
The two-dimensional inverse problem for first-order systems is analysed and a method to construct an affine Lagrangian for such systems is developed. The determination of such Lagrangians is based on the theory of the Jacobi multiplier for the system of differential equations. We illustrate our analysis with several examples of families of forces that are relevant in mechanics, on one side, and of some relevant biological systems, on the other. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry: Feature Review Papers)
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