We demonstrate both theoretically and experimentally beam-dependent photonic spin-orbit coupling in a two-wave mixing process described by an equivalent of the Pauli equation in quantum mechanics. The considered structured light in the system is comprising a superposition of two orthogonal spin-orbit-coupled states defined as spin-up and -down equivalents. The spin-orbit coupling is manifested by prominent pseudospin precession as well as spin-transport-induced orbital angular momentum generation in a photonic crystal film of wavelength thickness. The coupling effect is significantly enhanced by using a deep-subwavelength carrier envelope, different from previous studies which depend on materials. The beam-dependent coupling effect can find intriguing applications; for instance, it is used in precisely measuring variation of light with spatial resolution up to 15 nm.