Synthesis, chemistry and applications of 5-hydroxymethyl-furfural and its derivatives

J Lewkowski - 2001 - dspace.uni.lodz.pl
HMF is a good starting material for the synthesis of precursors of various pharmaceuticals,
thermo-resistant polymers and complex macrocycles. Among these precursors, one can find …

Critical evaluation of the dependence of 3JHH couplings on bond order and bond length in conjugated carbocyclic molecules. Evidence for a steric effect on 3JHH

MA Cooper, SL Manatt - Journal of the American Chemical …, 1969 - ACS Publications
Previously proposed linear correlationsbetween-bond orders and the magnitudes of nmr
ortho proton-proton spin-spin coupling constants (3/) in unsaturated systems have been …

Regioselectivity in the reactions of methoxydehydrobenzenes with furans. Part 1. Reactions of 3-methoxydehydrobenzene and 3-(methoxycarbonyl)-dehydrobenzene …

GF Robin - Journal of the Chemical Society, Perkin Transactions 1, 1991 - pubs.rsc.org
The isomer ratios for the cycloadducts obtained for the reaction of 3-
methoxydehydrobenzene, generated from 2-amino-6-methoxybenzoic acid by aprotic …

Conformation of nucleosides and nucleotides. Application of the nuclear Overhauser effect

PA Hart, JP Davis - Journal of the American Chemical Society, 1969 - ACS Publications
Conformational analysis of the glycosidic bond in the purine riboside series has been
difficult in view of the apparently low energy barriers to rotation about that bond. 2 …

Applications of the nuclear Overhauser effect in organic chemistry

PD Kennewell - Journal of Chemical Education, 1970 - ACS Publications
Applications of the Nuclear Overhauser Effect in organic chemistry Page 1 Peter D. Kennewell
Lehigh University Bethlehem, Pennsylvania 18015 Applications of the Nuclear Overhauser Effect …

Effect of steric compression on proton-proton, spin-spin coupling constants. Further evidence and mechanistic considerations

MA Cooper, SL Manatt - Journal of the American Chemical …, 1970 - ACS Publications
Analyses of the nmr spectra of 1, 4-dimethylnaphthalene, 1, 4-di-í-butylnaphthalene, and
benzo [c]-phenanthrene are presented. These results confirm earliersuggestions that nmr …

Identity of benzyne from various precursors

BH Klanderman, TR Criswell - Journal of the American Chemical …, 1969 - ACS Publications
(3) CD Campbell and CW Rees, Proc. Chem. Soc., 296 (1964).(4) CD Campbell and CW
Rees, Chem. Commun., 192 (1965).(5) The B-ring/A-ring ratios were not significantly …

Synthesis of 1,4‐, 1,5‐, 2,6‐ and 2,7‐di‐t‐butylnaphthalene and of 1,4‐, 1,5‐, 2,6‐ and 1,8‐diisopropylnaphthalene

H Van Bekkum, TJ Nieuwstad… - Recueil des Travaux …, 1969 - Wiley Online Library
Abstract Mixtures of 2, 6‐and 2, 7‐di‐t‐butylnaphthalene, obtained by the t‐butylation of
naphthalene, can be conveniently separated making use of the fact that only the 2, 6‐isomer …

Cyclotetramerization of 2-dimethylamino-4-tert-butylpyrrole. Tetra-tert-butylporphyrins

BJ Whitlock, HW Whitlock, H Alles - Journal of the American …, 1974 - ACS Publications
The acid-catalyzed cyclotetramerization of 2-dimethylaminomethyl-4-/erf-butylpyrrole was
examined. A mixture of all four isomeric tetra-Zerz-butylporphyrins was produced. Each …

Restricted rotation in biguanide dications

VJ Bauer, W Fulmor, GO Morton… - Journal of the American …, 1968 - ACS Publications
6846 trum to the 120 spectrum of II suggests that one bond (a) may be free to rotate, while
the restricted rotation about the others (ß, y) is essentially unchanged. The syntheses of …