WO2018198564A1 - Hairdressing agent composition - Google Patents

Abstract

Provided is a hairdressing agent composition in which a reduction in viscosity over time is suppressed while containing an acrylic film-forming polymer and a thickening agent. This hair dressing agent composition contains the following components A, B, C, and D: component A, phytic acid; component B, an acrylic polymer obtained using monomer components B1 and B2 as monomer components (monomer component B1, an alkyl (meth)acrylate ester, and monomer component B2, an alkylacrylamide and/or diacetone acrylamide); component C, a thickening agent; and component D, water.

Description

Hairdressing composition

The present invention relates to a hairdressing composition. This application claims the priority of Japanese Patent Application No. 2017-088806 and Japanese Patent Application No. 2017-088807 for which it applied to Japan on April 27, 2017, and uses the content here.

In hair styling compositions represented by hair water, hair gel, hair spray, hair grease and the like, a film-forming polymer is generally used as a hair styling main functional base material. As the film forming polymer, an anionic film forming polymer, a cationic film forming polymer, an amphoteric film forming polymer, a nonionic film forming polymer, or the like is used. Moreover, in order to adjust the said hairdressing agent composition to desired viscosity, various thickeners, such as a carboxy vinyl polymer, are mix | blended (refer patent document 1 and 2).

Japanese Patent Laid-Open No. 3-48611 JP-A-10-87448

Among the above film-forming polymers, acrylic anionic film-forming polymers are useful in terms of improving hair styling retention because they have moisture resistance and moderate hardness. However, it has been found that when both the acrylic anionic film-forming polymer and a thickener (particularly anionic thickener) are blended into a hairdressing composition, the viscosity decreases over time.

Conventionally, there has been known a method for stabilizing the preparation by blending sodium edetate or the like to suppress a decrease in viscosity of the thickener. However, in a hairdressing composition containing an acrylic film-forming polymer and a thickener, even when sodium edetate is added, the effect of suppressing a decrease in viscosity over time is not sufficient.

Therefore, an object of the present invention is to provide a hair styling composition in which a decrease in viscosity over time is suppressed while an acrylic film-forming polymer and a thickener are blended.

That is, this invention provides the hairdressing composition containing the following component A, the following component B, the following component C, and the following component D.
Component A: Phytic acid Component B: Acrylic polymer obtained by using the following monomer component B1 and the following monomer component B2 as monomer components Monomer component B1: (meth) acrylic acid alkyl ester Monomer component B2: alkyl acrylamide and / or diacetone acrylamide Component C: Thickener Component D: Water

Component B includes (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP, and (acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer AMP. And (Acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide / hydroxyethyl acrylate) copolymer, preferably at least one selected from the group consisting of AMPs.

The component C preferably contains at least one selected from the group consisting of the following component C1, the following component C2, and the following component C3.
Component C1: Polymer obtained using at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester as the monomer component Component C2: (meth) acrylic acid as the monomer component And at least one monomer selected from the group consisting of (meth) acrylic acid alkyl esters, and a group selected from the group consisting of (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether, and vinyl neodecanoate Polymer obtained using at least one monomer selected from the above: Component C3: Carboxyvinyl polymer and / or alkyl-modified carboxyvinyl polymer

The content of component A is 0.01 to 2.0% by mass, the content of component B is 0.1 to 15.0% by mass, and the content of component C is 0.05 to 3%. It is preferably 0.0% by mass.

The hairdressing composition of the present invention preferably further contains the following component E.
Component E: sulfite and / or etidronic acid or a salt thereof

The hairdressing composition of the present invention preferably further contains the following component F.
Component F: Nonionic surfactant

The hairdressing composition of the present invention preferably further contains the following component G.
Component G: Tocopherol acetate and / or edetate

The hair styling composition of the present invention has the above-described configuration, thereby suppressing a decrease in viscosity over time. For this reason, it is excellent in formulation stability. Therefore, since the initial viscosity is hardly changed in the container from the time of manufacture to the end of use, a stable quality hairdressing composition can be provided.

The hairdressing composition of the present invention contains at least an acrylic polymer obtained by using phytic acid, (meth) acrylic acid alkyl ester, and alkylacrylamide and / or diacetoneacrylamide as monomer components, a thickener, and water. . In the present specification, an acrylic polymer obtained by using the above phytic acid as “component A”, the above (meth) acrylic acid alkyl ester, and alkyl acrylamide and / or diacetone acrylamide as monomer components is referred to as “component B”. The thickener may be referred to as “component C”, and the water may be referred to as “component D”. In addition, the (meth) acrylic acid alkyl ester may be referred to as “monomer component B1”, and the alkylacrylamide and / or diacetone acrylamide may be referred to as “monomer component B2”.

The hairdressing composition of the present invention preferably contains sulfite and / or etidronic acid or a salt thereof. Moreover, it is preferable that the hairdressing composition of this invention contains a nonionic surfactant. Moreover, it is preferable that the hairdressing composition of this invention contains tocopherol acetate and / or edetate. In the present specification, the above sulfite and / or etidronic acid or a salt thereof is referred to as “component E”, the nonionic surfactant is referred to as “component F”, and the tocopherol acetate and / or edetate is referred to as “component G”. Sometimes called.

That is, the hairdressing composition of the present invention includes at least Component A, Component B, Component C, and Component D. The hairdressing composition of the present invention preferably further contains Component E, Component F, and Component G. Other components may be included. In addition, each component contained in the hairdressing composition of the present invention, for example, component A, component B, component C, component D, component E, component F, component G, and other components, each has only one type. It may be used and 2 or more types may be used.

[Component A: Phytic acid]
Component A is phytic acid, which is a compound represented by “Physic Acid” under the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 16th edition, Volume 2, 2016, p. 2724).

Component A can be a commercially available product. As a commercial item of the component A, the brand name "Phytic acid" by the Tsukino Rice Fine Chemicals company is mentioned, for example.

The content of component A in 100% by mass of the hairdressing composition of the present invention is not particularly limited, but is preferably 0.01 to 2.0% by mass, more preferably 0.02 to 1.0% by mass. is there. It is preferable for the content to be 0.01% by mass or more because the effect of suppressing a decrease in viscosity over time is further improved. On the other hand, when the content exceeds 2.0% by mass, component A may inhibit the thickening effect of component C.

[Component B: Acrylic polymer obtained using monomer component B1 and monomer component B2 as monomer components]
Component B is an acrylic polymer obtained using (meth) acrylic acid alkyl ester (monomer component B1) and alkyl acrylamide and / or diacetone acrylamide (monomer component B2) as monomer components. That is, Component B is a polymer containing a structural unit derived from (meth) acrylic acid alkyl ester (monomer component B1) and a structural unit derived from alkylacrylamide and / or diacetone acrylamide (monomer component B2). Component B functions as a component that forms a film and imparts hair-styling power. Here, “(meth) acrylic acid” means one or both of acrylic acid and methacrylic acid. As for component B, only 1 type may be used and 2 or more types may be used. As component B, in the present invention, sodium salt of component B (hereinafter abbreviated as Na), ammonium salt, triethanolamine salt, 2-amino-2-methyl-1-propanol salt (hereinafter abbreviated as AMP) 2-amino-2-methyl-1,3-propanediol salt (hereinafter abbreviated as AMPD).

Preferred examples of component B include (alkyl acrylate / diacetone acrylamide) copolymer [INCI name: AMP-ACRYLATES / DIACETONACRYLAMIDE COPOLYMER], (acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer AMP. [INCI name: AMP-ACRYLATES / C1-18 ALKYL ACRYLATE / C1-8 ALKYL ACRYLAMIDE COPOLYMER], (alkyl acrylate / diacetone acrylamide) copolymer AMP [INCI name: AMP-ACRYLATES / DIACETONE ACRYLAMIDE® APOLYMATELAPOLY Alkyl (C1-18) / alkyl (C -8) acrylamide / acrylic acid hydroxyethyl) copolymer AMP [INCI name: AMP-ACRYLATES / C1-18 ALKYL ACRYLATE / C1-8 ALKYL ACRYLAMIDE / HYDROXYETHYLACRYLATE COPOLYMER], and the like.

Component B can be a commercially available product. Commercially available products of (alkyl acrylate / diacetone acrylamide) copolymers include, for example, trade name “Plus Size L-6345U”, trade name “Plus Size L-53”, (Acrylates / alkyl acrylate (C1-18) / Commercially available products of alkyl (C1-8) acrylamide) copolymer AMP include, for example, trade names “Plus Size L-9909U”, “Plus Size L-9909B”, Trade Name “Plus Size L-9715”, Trade Name “Plus”. Commercially available products of “Size L-6740B” (alkyl acrylate / diacetone acrylamide) copolymer AMP include, for example, trade name “Plus Size L-6330”, trade name “Plus Size L-6466”, (Acrylates / Acrylic Acid Alkyl (C1-18) / alkyl (C1-8) acrylic Examples of commercially available phagemid / hydroxyethyl acrylate) copolymer AMP, for example, trade name "Plus Size L-9700" (GOO CHEMICAL none Co., Ltd.).

The content of component B in 100% by mass of the hairdressing composition of the present invention is not particularly limited, but is preferably 0.1 to 15.0% by mass, more preferably 0.2 to 5.0% by mass. is there. It is preferable that the content is 0.1% by mass or more because the hair styling power is further improved. If the content exceeds 15.0% by mass, the stability of the preparation may be lowered, or flaking may occur after hair styling. Content of the said component B is content of the sum total of all the components B in the hairdressing composition of this invention.

[Component C: Thickener]
Component C is a thickener and has an effect of mainly thickening the system. For this reason, the hairdressing composition of the present invention is thickened, for example, when it is used by picking up the composition, it has a gel-like or grease-like property / dosage form that is difficult to sag and has excellent handleability. be able to. As for component C, only 1 type may be used and 2 or more types may be used.

Component C is not particularly limited as long as it is usually used in hairdressing composition, but for example, natural polymer thickeners such as xanthan gum, guar gum, carrageenan, locust bean gum; methylcellulose, ethylcellulose, hydroxymethylcellulose, hydroxy Examples thereof include cellulose thickeners such as ethyl cellulose, hydroxypropylmethylcellulose, carboxymethylcellulose; acrylic thickeners such as carboxyvinyl polymer. Among these, acrylic thickeners are preferable from the viewpoint of transparency and low luster.

Component C contains at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl esters as monomer components from the viewpoint of improving formulation stability and spreadability on hair. Polymer (component C1) obtained by using, as a monomer component, at least one monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, and polyoxyethylene alkyl (meth) acrylate A polymer (component C2) obtained using at least one monomer selected from the group consisting of ether, polyoxyethylene alkyl ethers of itaconic acid, and vinyl neodecanoate, and a carboxyvinyl polymer and / or an alkyl-modified carboxyvinyl polymer Selected from the group consisting of (component C3) Preferably contains at least one. In addition, as for component C1, component C2, and component C3, only 1 type may each be used, and 2 or more types may be used.

The monomer component used to obtain the polymer of component C1 includes at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl esters. That is, the component C1 is a polymer including at least two or more structural units selected from the group consisting of a structural unit derived from (meth) acrylic acid and a structural unit derived from (meth) acrylic acid alkyl ester. In the present specification, the polymer that can correspond to both the component C1 and the component C2 is not the component C1 but the component C2.

Although it does not specifically limit as said component C1, It describes with an INCI name (International Cosmetic Ingredient Dictionary and Handbook, 16th edition, the 1st volume, 2016, p.68-69) as "ACRYLATES COPOLYMER". Are preferred.

The component C1 may be a commercially available product. Examples of commercially available products of component C1 include trade name “Aculin 33”, trade name “Aculin 33A” (both manufactured by Dow Chemical Co.); trade name “SepiMAX ZEN” (manufactured by SEPPIC).

The monomer component used to obtain the polymer of component C2 is at least one monomer component C2a selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, and (meth) acrylic acid poly And at least one monomer component C2b selected from the group consisting of oxyethylene alkyl ether, polyoxyethylene alkyl ether itaconic acid, and vinyl neodecanoate. That is, the component C2 is a polymer including at least a structural unit derived from the monomer component C2a and a structural unit derived from the monomer component C2b. As for the monomer component C2a and the monomer component C2b, only one type may be used, or two or more types may be used.

Although it does not specifically limit as said component C2, INCI name (International Cosmetic Ingredient Dictionary and Handbook, the 16th edition, the 1st volume, 2016, p.76) "ACRYLATES / STEARETTH-20 METHACRYLATE COPOLY / (Acid Steareth-20) Copolymer)); “CIRYLATES / STEARETH-20 METHACRYLATEC (INCR) (INC) (International Cosmetic Ingredient Dictionary and Handbook, 16th Edition, Volume 1, 2016, p.76) Accel Relay / ACRYLATES / BEHENETH-25 METHACLA under the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 16th edition, Volume 1, 2016, p. 65). "POLYMERS / VINYL (methacrylic acid / Beheneth-25) copolymer" "; INCI name (International Cosmetic Ingredient Dictionary and Handbook, 16th edition, volume 1, 2016, p. 78)" ACRYLATES / VINYL " NEODECANOATE CROSSPOLYMER (Acrylates / Vinyl neodecanoate) cross-polymer); “CIRYLATES / STEARETH-” under the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 16th edition, Volume 1, 2016, p. 75-76) 20 ITACONATE COPOLYMER ((Acrylates / Itaconic Acid Steareth-20) Copolymer) ”; INCI name (International Cosmetic Ingredient Dictionary, 16th Edition, Volume 1, 2016, p. 68LA, ACR TE) / CETETH-20 ITACONATE COPOLYMER ( A compound represented by “(Acrylates / cetethate itaconate-20) copolymer” is preferred.

Component C2 may be a commercially available product. Examples of commercially available products of component C2 include, for example, trade name “Aculin 22”, trade name “Aculin 88”, trade name “Aculin 28”, trade name “Aculin 38” (all manufactured by Dow Chemical Co., Ltd.); trade name “STRUCTURE” 2001 ”, trade name“ STRUCTURE 3001 ”(all manufactured by Axon Nobel Co., Ltd.), and the like.

Component C3 is a carboxyvinyl polymer and / or an alkyl-modified carboxyvinyl polymer. The carboxyvinyl polymer is mainly a polymer of acrylic acid, and the alkyl-modified carboxyvinyl polymer is a copolymer of mainly acrylic acid and alkyl methacrylate (preferably alkyl has 10 to 30 carbon atoms). Examples of the alkyl-modified carboxyvinyl polymer include (acrylates / alkyl acrylate (C10-30)) crosspolymer. As for component C3, only 1 type may be used and 2 or more types may be used.

Component C3 may be a commercially available product. Examples of commercially available products of carboxyvinyl polymer include a trade name “Carbopol 934”, a trade name “Carbopol 940”, a trade name “Carbopol 941”, a trade name “Carbopol 980”, and a trade name “Carbopol 981”. , Product name “Carbopol 1342”, product name “Carbopol 2984”, product name “Carbopol Ultrez 10”, product name “Carbopol ETD 2050” (all manufactured by Nippon Lubrizol Corporation); product name “AQUPEC” HV-501 ”, product name“ AQUPEC HV-504 ”, product name“ AQUPEC HV-505 ”, product name“ Hibiswaco 104 ”, product name“ Hibiswaco 105 ”(all manufactured by Wako Pure Chemical Industries, Ltd.) Etc. Commercially available products of alkyl-modified carboxyvinyl polymer include, for example, trade name “PEMULEN TR-1”, trade name “PEMULEN TR-2”, trade name “Carbopol ETD 2020”, trade name “Carbopol ULTREZ 20” (any As well as Nippon Lubrizol Co., Ltd.).

The component C is not particularly limited, but is preferably neutralized with a basic substance or neutralized with a basic substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine; inorganic basic compounds such as ammonia, sodium hydroxide and potassium hydroxide; basic amino acids such as arginine. Moreover, the addition amount of the basic substance is an amount that becomes a sufficiently neutralized component C, or an amount sufficient to neutralize the component C, and the component C and the basic substance are added. What is necessary is just to mix | blend suitably according to the kind of this and the usage-amount of the said component C. FIG.

The content of Component C in 100% by mass of the hairdressing composition of the present invention is not particularly limited, but is preferably 0.05 to 3.0% by mass, more preferably 0.1 to 2.0% by mass. is there. It is preferable for the content to be 0.05% by mass or more because the hairdressing composition is sufficiently thickened and the storage stability and coatability are further improved. It is preferable for the content to be 3.0% by mass or less because the formulation stability and the stickiness-inhibiting effect are further improved. Content of the said component C is content of the sum total of all the components C in the hairdressing composition of this invention.

[Component D: Water]
The component D is water. Component D is not particularly limited, but purified water is preferred. Ingredient D has the effect of providing a refreshing feel with no oiliness when using the hairdressing composition of the present invention as an aqueous composition such as a gel or a grease, and improving the spreadability. The content of component D in 100% by mass of the hairdressing composition of the present invention is not particularly limited, but is preferably 20.0 to 95.0% by mass, more preferably 50.0 to 90.0% by mass. .

[Component E: Sulfite and / or Etidronic acid or salt thereof]
The component E is sulfite and / or etidronic acid or a salt thereof. In the present invention, Component E exhibits the effect of further improving the decrease in viscosity over time of the hairdressing composition. Furthermore, the effect of further suppressing changes in color tone and odor over time is exhibited. In particular, it is preferable because the effect of suppressing color tone change is high. Examples of the sulfite include sodium sulfite, sodium hydrogen sulfite, and anhydrous sodium sulfite. Examples of the salt of etidronic acid include sodium salt.

The content of component E in 100% by mass of the hairdressing composition of the present invention is not particularly limited, but is preferably 0.005 to 1.0% by mass, more preferably 0.01 to 0.5% by mass. is there. It is preferable for the content to be 0.005% by mass or more because the effect of suppressing the decrease in viscosity over time is further improved. Moreover, since the change of the color tone and odor of the hairdressing composition of this invention is suppressed further, it is preferable. When the said content exceeds 1.0 mass%, formulation stability may fall or an odor may arise. Content of the said component E is content of the sum total of all the components E in the hairdressing composition of this invention.

[Component F: Nonionic surfactant]
The component F is a nonionic surfactant. In the present invention, Component F functions as a hair styling component of the hair styling composition. It has been found that hairdressing composition containing component F generally tends to cause a decrease in viscosity over time. On the other hand, since the component A acts and suppresses the decrease in the viscosity, the effect of the present invention is more easily exhibited in the system including the component F. By blending component F in the hairdressing composition, the arranging power of the hairdressing composition (force to bend the hair in an arbitrary direction) and wash-off properties are improved. As for component F, only 1 type may be used and 2 or more types may be used.

Examples of component F include glycerin fatty acid ester, polyglycerin fatty acid ester, ethylene oxide condensate of glycerin fatty acid ester, polyethylene glycol fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, ethylene oxide condensate of sorbitan fatty acid ester, polyoxy Examples include alkylene alkyl ethers, polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene lanolin and the like.

More specifically, for example, glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehenate, glyceryl monooleate Glyceryl fatty acid esters such as glyceryl monoerucate, glyceryl sesquioleate, glyceryl distearate, glyceryl diisostearate, glyceryl diarachiate; diglyceryl monocaprylate, decaglyceryl monocaprylate, hexaglyceryl monocaprate, tetraglyceryl monolaurate, Hexaglyceryl monolaurate, decaglyceryl monolaurate, poly (4-10) glyceryl monolaurate, monomyris Decaglyceryl acid, decaglyceryl monostearate, decaglyceryl monoisostearate, poly (2-10) glyceryl monostearate, diglyceryl monooleate, hexaglyceryl monooleate, diglyceryl sesquioleate, poly (diisostearate poly ( 2-10) Polyglyceryl fatty acid esters such as glyceryl, poly (6-10) glyceryl distearate, diglyceryl triisostearate, poly (10) glyceryl tristearate; polyoxyethylene glyceryl monostearate, polyoxy monooleate Ethylene oxide condensates of glycerin fatty acid esters such as ethylene glyceryl; polyethylene glycol monooleate, polyethylene glycol monostearate, polyethylene glycol monolaurate Polyethylene glycol fatty acid esters such as propylene glycol; propylene glycol fatty acid esters such as propylene glycol monostearate, propylene glycol monolaurate, propylene glycol monooleate; sorbitan monooleate, sorbitan monostearate, sorbitan monoisostearate, sorbitan monopalmitate Sorbitan fatty acid esters such as sorbitan monolaurate, sorbitan trioleate, sorbitan tristearate, sorbitan sesquistearate, sorbitan sesquioleate, sorbitan sesquiisostearate, coconut oil fatty acid sorbitan; monolauric acid polyoxyethylene sorbitan monomonophosphate Polyoxyethylene sorbitan, polyoxyethylene sorbitan monostearate, Ethylene oxide condensates of sorbitan fatty acid esters such as polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monoisostearate, monococonut oil fatty acid polyoxyethylene sorbitan, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan trioleate; Polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene polyoxypropylene lauryl ether, polyoxypropylene cetyl ether, polyoxypropylene isocetyl ether, polyoxypropylene stearyl Polyoxyalkylene alkyl ethers such as ether and polyoxypropylene oleyl ether Le, and the like.

Component F is preferably polyoxyethylene hydrogenated castor oil or polyoxyalkylene alkyl ether (particularly polyoxyethylene alkyl ether) from the viewpoint of excellent effect of imparting hair-styling power. Particularly preferred is polyoxyethylene hydrogenated castor oil.

The hairdressing composition containing the component F is not particularly limited, and examples thereof include a polyoxyethylene hydrogenated castor oil component having an average addition mole number of oxyethylene of 45 to 65 (sometimes referred to as “component F1”) and A hair styling composition comprising polyoxyethylene hydrogenated castor oil (sometimes referred to as “component F2”) having an average addition mole number of oxyethylene of 75 to 125 (sometimes referred to as “hair conditioning composition of specific embodiment 1”). There is). The hair styling composition of the specific aspect 1 has the property of forming a hair bundle by the above-described configuration, raising the hair bundle from the roots while being able to be sufficiently eliminated, and maintaining the hairstyle for a long time. Have

Component F preferably contains polyoxyethylene hydrogenated castor oil (may be referred to as “Component F3”) having an average addition mole number of oxyethylene of 5 or more and less than 45, in addition to Component F1 and Component F2. When the hairdressing composition of the present invention contains the component F3 in addition to the components F1 and F2 as the component F, it is more excellent in facilitating the fading. Note that only one type of each of the components F1 to F3 may be used, or two or more types may be used.

The average number of moles of oxyethylene added in the component F1 is 45 to 65, preferably 50 to 60. Further, the average number of moles of oxyethylene added in the component F2 is 75 to 125, preferably 80 to 120. In addition, the average added mole number of oxyethylene in the component F3 is 5 or more and less than 45, preferably 10 to 40.

Commercially available products of component F1, for example, trade name “Brownon RCW-50”, trade name “Brownon RCW-60” (all manufactured by Aoki Oil & Fat Co., Ltd.), trade name “EMALEX HC-50”, trade name “EMALEX HC-60”, trade name “EMALEX RWIS-150”, trade name “EMALEX RWIS-350”, trade name “EMALEX RWIS-360” (all manufactured by Nippon Emulsion Co., Ltd.), and the like.

Commercially available products of component F2 include, for example, trade name “Brownon RCW-80”, trade name “Brownon RCW-100”, trade name “Brownon CW-100” (all manufactured by Aoki Oil & Fat Co., Ltd.), trade name “EMALEX HC-80”, trade name “EMALEX HC-100” (all manufactured by Nippon Emulsion Co., Ltd.) and the like can be mentioned.

Commercially available products of component F3 include, for example, trade name “Brownon RCW-20”, trade name “Brownon RCW-40”, trade name “Brownon CW-10”, trade name “Brownon CW-25”, trade name “Brownon”. CW-40 "(all manufactured by Aoki Oil & Fat Co., Ltd.), trade name" EMALEX HC-5 ", trade name" EMALEX HC-7 ", trade name" EMALEX HC-10 ", trade name" EMALEX HC-20 " ”, Product name“ EMALEX HC-30 ”, product name“ EMALEX HC-40 ”, product name“ EMALEX RWIS-105 ”, product name“ EMALEX RWIS-105EX ”, product name“ EMALEX RWIS-110 ”, product name“ EMALEX RWIS-110EX, product name “EMALEX RWIS-11” ”, Product name“ EMALEX RWIS-115EX ”, product name“ EMALEX RWIS-120 ”, product name“ EMALEX RWIS-130 ”, product name“ EMALEX RWIS-140 ”, product name“ EMALEX RWIS-305 ”, product name“ EMALEX RWIS-305 ” EMALEX RWIS-310, trade name “EMALEX RWIS-315”, trade name “EMALEX RWIS-315EX”, trade name “EMALEX RWIS-320”, trade name “EMALEX RWIS-320EX”, trade name “EMALEX RWIS-330” And trade name “EMALEX RWIS-340” (all manufactured by Nippon Emulsion Co., Ltd.).

In the hairdressing composition of the present invention, the mass ratio of the content of the component F1 to the total content of the component F1 and the component F2 [F1 / (F1 + F2)] From the viewpoint of the characteristics of starting up from the root, the formability of the hair bundle, and the characteristics of maintaining the hairstyle for a long time, 0.1 to 0.9 is preferable, more preferably 0.2 to 0.8, and still more preferably 0. .25 to 0.5. In the present specification, the content of the component F1 is the total content of all the components F1 in the hairdressing composition of the present invention, and the content of the component F2 is the hairdressing composition of the present invention. It is the total content of all the components F2 in the product.

The total content of the component F1 and the component F2 in the component F is not particularly limited, but it is easy to wear, the property of starting up the hair bundle from the root, the formability of the hair bundle, and maintaining the hairstyle for a long time. From the viewpoint of characteristics and the like, 50.0% by mass or more (for example, 50.0 to 100% by mass) is preferable with respect to 100% by mass of Component F, more preferably 70.0% by mass or more, and further preferably 80.0% by mass. % Or more.

The total content of the component F1 and the component F2 in the hairdressing composition of the present invention is not particularly limited, but is easy to apply, characteristics of starting up the hair bundle from the root, formability of the hair bundle, and hairstyle From the standpoint of the property of maintaining the hair for a long time, the amount is preferably 3.0 to 25.0% by weight, more preferably 5.0 to 20.0% by weight with respect to 100% by weight of the hairdressing composition of the present invention. More preferably, it is 6.0 to 15.0% by mass. When the content is within the above range, it is excellent in ease of squeezing, the property of raising the hair bundle from the root, the formability of a fine hair bundle, and the property of maintaining the hairstyle for a long time.

The total content of component F3 in the hairdressing composition of the present invention is not particularly limited, but from the viewpoint of further improving the ease of squeezing, it is based on 100% by mass of the hairdressing composition of the present invention. 0.5 to 10.0 mass% is preferable, and 0.8 to 5.0 mass% is more preferable. .

The content of component F in the hairdressing composition of the present invention is not particularly limited, but it is easy to wear, the property of starting up the hair bundle from the root, the formability of the hair bundle, and the hairstyle is maintained for a long time. From the viewpoint of properties and the like, the amount is preferably 3.0 to 30.0% by mass, more preferably 4.0 to 25.0% by mass, and still more preferably 6. It is 0 to 20.0% by mass. Content of the said component F is content of the sum total of all the components F in the hairdressing composition of this invention.

[Component G: Tocopherol acetate and / or edetate]
The component G is tocopherol acetate and / or edetate. In the present invention, Component G exerts an effect of further suppressing the decrease in viscosity over time of the hairdressing composition. In addition, it exhibits the effect of further suppressing changes in color tone and odor over time. Examples of the edetate include disodium edetate and tetrasodium edetate.

The content of component G in 100% by mass of the hairdressing composition of the present invention is not particularly limited, but is preferably 0.01 to 2.0% by mass, more preferably 0.05 to 1.0% by mass. is there. It is preferable for the content to be 0.01% by mass or more because the effect of suppressing a decrease in viscosity over time is further improved. Moreover, since the change of the color tone and odor of the hairdressing composition of this invention is suppressed further, it is preferable. When the content exceeds 2.0% by mass, the solubility may be lowered, or the thickening effect of Component C may be inhibited. Content of the said component G is content of the sum total of all the components E in the hairdressing composition of this invention.

[Other ingredients]
The hairdressing composition of the present invention may contain components other than components A to G (other components) within a range not impairing the effects of the present invention. The other components are not particularly limited, and examples include components usually used for cosmetics and quasi drugs. Specifically, for example, surfactants other than component F (anionic surfactants, cationic surfactants, amphoteric surfactants); lower alcohols such as ethanol; polyhydric alcohols, higher alcohols, silicone oils, esters Oil components such as oils, waxes, vegetable oils, hydrocarbon waxes, hydrocarbon oils, fats and oils, higher fatty acids, fragrances, ultraviolet absorbers, antioxidants, sequestering agents, powders such as silica, pigments, pigments, dyes; Vitamins; Amino acids; Astringents; Whitening agents; Animal and plant extracts; pH adjusters; Preservatives; Solvents;

[Other details of hairdressing composition]
The properties of the hairdressing composition of the present invention are not particularly limited, but gels and greases are preferred from the viewpoint of being easy to sag from the hand and excellent in handleability when picked up by hand and applied to hair. That is, the hair styling composition of the present invention is preferably a gel-like hair styling composition or a grease-like hair styling composition (referred to as hair grease, water grease, water-soluble pomade, etc.).

The method for producing the hairdressing composition of the present invention is not particularly limited, and a known method for producing a hairdressing composition can be used. Examples of the method for producing the hairdressing composition of the present invention include a method of stirring and homogenizing each component with a disper mixer, a paddle mixer or the like.

The hair styling composition of the present invention is not particularly limited, but can be used, for example, in a form filled in a container. Examples of the container include a bottle container, a jar container, and a tube container. Although not particularly limited, from the viewpoint of usability, when the hairdressing composition of the present invention is in a gel form, a bottle container, a tube container or a jar container is preferred, and when the hairdressing composition of the present invention is in a grease form A jar is preferred.

Although the viscosity and consistency of the hairdressing composition of the present invention are not particularly limited, for example, in the case of the hairdressing composition of the specific embodiment 1, when it is picked up and applied to the hair, it is difficult to sag from the hand. From the viewpoint of excellent properties, the viscosity (25 ° C.) is preferably 5000 mPa · s or more. The “viscosity (25 ° C.)” can be measured at 25 ° C. using a Brookfield rotary viscometer, for example. In addition, the consistency (25 ° C.) is preferably 50 gf or less, more preferably 30 gf or less, from the viewpoint of easy scooping and easy handling when the container is scooped with a finger. The “consistency (25 ° C.)” can be measured, for example, using a consistency meter equipped with a 17φ flat adapter at 25 ° C., a speed of 60 mm / min, and a stroke of 20 mm. Examples of the consistency meter include trade name “RHEO METER” manufactured by Sun Kagaku Co., Ltd.

The hairdressing composition of the present invention contains at least Component A, Component B, Component C, and Component D. The hair styling composition of the present invention is an aqueous hair styling composition containing component D, and solves the problem of a decrease in viscosity over time due to blending of both component B and component C by blending of component A. In addition, a stable viscosity is maintained. That is, formulation stabilization of a hairdressing composition containing component B, component C, and component D that could not be sufficiently suppressed with conventional sodium edetate alone can be achieved by blending component A. . Moreover, since the hair-styling composition of this invention is an aqueous hair-styling composition containing the component D, compared with an oil-based hair-styling composition, there is no oily feeling and the refreshing feeling of use is obtained.

The hair styling composition of the present invention preferably further contains Component E, Component F, and Component G. In particular, the combined use of component E and component G exhibits the effect of further improving the action of component A to suppress a decrease in viscosity over time. Moreover, the effect which further improves the effect | action which suppresses the change of a color tone or an odor is exhibited.

As described above, the hairdressing composition of the present invention can provide a stable quality hairdressing composition with excellent usability because the initial viscosity is hardly lowered in the container from the time of manufacture to the end of use. .

Hereinafter, the present invention will be specifically described with reference to examples and comparative examples. The present invention is not limited only to the following examples. The compounding amount shown in the table is the compounding amount of each component (that is, the compounding amount of the active ingredient (so-called pure component) in the raw material), and is expressed in “mass%” unless otherwise specified. *

In the examples and comparative examples, the following components were used.

[Component A]
Phytic acid: Product name “Phytic acid” manufactured by Tsukino Rice Fine Chemicals Co., Ltd.

[Component B]
(Alkyl acrylate / diacetone acrylamide) copolymer: manufactured by Kyoyo Chemical Industry Co., Ltd., trade name “Plus Size L-6345U”
(Acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer AMP: manufactured by Kyoyo Chemical Industry Co., Ltd., trade name “Plus Size L-9909B”
(Acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide / hydroxyethyl acrylate) copolymer AMP: manufactured by Kyoyo Chemical Industry Co., Ltd., trade name “Plus Size L-9700”

[Component C]
Carboxy vinyl polymer: Nippon Lubrizol Co., Ltd., trade name “Carbopol 940”
Alkyl-modified carboxyvinyl polymer: manufactured by Nippon Lubrizol Co., Ltd., trade name “Carbopol ETD 2020”, (acrylates / alkyl acrylate (C10-30)) crosspolymer (acrylates / Beheneth methacrylate-25) Copolymer: Dow Chemical Product name "Aculin 28"
(Acrylates / Stearless Methacrylate-20) Copolymer: manufactured by Dow Chemical Company, trade name “Aculin 22”
Hydroxypropyl methylcellulose: Shin-Etsu Chemical Co., Ltd., trade name “Metrozu 60SH-4000”
Xanthan gum: DSP Gokyo Food & Chemical Co., Ltd., trade name "Echo Gum T"

[Component D]
purified water

[Component E]
Anhydrous sodium sulfite: manufactured by Jinzu Chemical Co., Ltd., trade name “anhydrous sodium sulfite”
Etidronic acid: Product name “Tarpinal SL” manufactured by Ital Match Japan Co., Ltd.

[Component F]
Polyoxyethylene (20E.O.) hydrogenated castor oil: manufactured by Aoki Yushi Kogyo Co., Ltd., trade name “Brownon RCW-20”, average added mole number of oxyethylene 20, PEG-20 hydrogenated castor oil polyoxyethylene ( 50E.O.) Hardened castor oil: manufactured by Aoki Yushi Kogyo Co., Ltd., trade name “Brownon RCW-50”, average added mole number of oxyethylene 50, PEG-50 hydrogenated castor oil polyoxyethylene (100E.O. ) Hardened castor oil: Aoki Yushi Kogyo Co., Ltd., trade name “Brownon RCW-100”, average added mole number of oxyethylene 100, PEG-100 hydrogenated castor oil

[Component G]
Tocopherol acetate: manufactured by BASF Japan Ltd., trade name “tocopherol acetate”
Edetate disodium: Product name “Disorubin NA2-S” manufactured by Lion Akzo

[Other ingredients]
Silica: JGC Catalysts & Chemicals, trade name “SILICA PEARL P-4M”

Examples 1 to 12 and Comparative Examples 1 to 3
According to the composition described in Table 1, each hairdressing composition was prepared. The properties of the hairdressing composition obtained in Examples 1 to 12 and Comparative Examples 1 to 3 were all gel-like.

[Evaluation of viscosity reduction]
About 50 g of the hairdressing composition of each example and comparative example was filled in a white jar container (capacity 50 mL), and stored in a thermostat bath at 5 ° C. and 40 ° C. for 4 weeks. The consistency (25 ° C.) of a sample stored at 5 ° C. for 4 weeks (5 ° C. stored sample) and a sample stored at 40 ° C. for 4 weeks (40 ° C. stored sample) were measured. Consistency (25 ° C.) was measured using a consistency meter equipped with a 17φ flat adapter [trade name “RHEO METER” manufactured by Sun Kagaku Co., Ltd.] under the conditions of 25 ° C., speed 60 mm / min, and stroke 20 mm. did. As a result, the hair conditioner compositions of Examples 1 to 12 had a [Consistency at 40 ° C. storage sample (25 ° C.) / 5 ° C. storage sample consistency (25 ° C.)] of 0.87 or more. On the other hand, the hairdressing composition of Comparative Examples 1 to 3 had a [Consistency at 40 ° C. storage sample (25 ° C.) / 5 ° C. storage sample consistency (25 ° C.)] of 0.81 or less. Further, even in visual confirmation, the hairdressing composition of Examples 1 to 12 showed almost no decrease in the viscosity of the sample stored at 40 ° C. with respect to the sample stored at 5 ° C., whereas the hairdressing composition of Comparative Examples 1 to 3 had 40 The viscosity of the sample stored at 0C was clearly lower than the viscosity of the sample stored at 5C.

As described above, the hair styling composition containing component A (Examples 1 to 12) sufficiently suppressed the decrease in viscosity over time, whereas the hair styling composition containing no component A (Comparative Example) In 1 to 3), a decrease in viscosity was observed. In the above comparative example, component G and component E were blended instead of component A, but these components alone may not be sufficient to suppress the decrease in viscosity over time of the hairdressing composition of the present invention. Indicated.

[Evaluation of color and odor]
In addition to the evaluation of the above-described decrease in viscosity, the hair conditioner compositions of the examples and comparative examples were subjected to sensory evaluation of the color tone and odor of the 40 ° C. storage sample and the 5 ° C. storage sample by visual and olfactory senses. The evaluation was performed by three expert evaluators. As a result, in Examples 1 to 5 and 7 to 12 and Comparative Example 3, the color tone changes of the 40 ° C. storage sample and the 5 ° C. storage sample were indistinguishable by the separation evaluation. On the other hand, in Example 6 and Comparative Examples 1 and 2, yellowing was confirmed in the samples stored at 40 ° C. as compared with the samples stored at 5 ° C. by a distance evaluation. In Examples 1 to 12 and Comparative Example 3, the odor changes of the 40 ° C. storage sample and the 5 ° C. storage sample were indistinguishable by the separation evaluation. On the other hand, in Comparative Examples 1 and 2, it was confirmed that the 40 ° C. storage sample had a different odor that could be clearly identified by the separation evaluation compared to the 5 ° C. storage sample.

The following is a formulation example of the hairdressing composition of the present invention.

(Formulation example 1: hair grease)
Silica 3.0% by mass
Polyoxyethylene (50E.O.) hydrogenated castor oil 2.0% by mass
Polyoxyethylene (100E.O.) hydrogenated castor oil 3.0% by mass
(Acrylates / Beheneth-25 methacrylate) copolymer 0.6% by mass
Xanthan gum 0.5% by mass
(Hydroxyethyl acrylate / Methoxyethyl acrylate) copolymer
1.5% by mass
(Alkyl acrylate / diacetone acrylamide) copolymer
0.5% by mass
Triethanolamine 0.6% by mass
Tocophenol acetate 0.05% by mass
Edetate disodium 0.05 mass%
Phytic acid 0.05% by mass
Sodium sulfite 0.02% by mass
Soybean extract 0.1% by mass
Ethanol 5.0% by mass
Perfume Appropriate amount of purified water Remaining amount

(Formulation example 2: hair grease)
Silica 3.0% by mass
Polyoxyethylene (20E.O.) hydrogenated castor oil 1.0% by mass
Polyoxyethylene (50E.O.) hydrogenated castor oil 4.0% by mass
Polyoxyethylene (100E.O.) hydrogenated castor oil 7.0% by mass
(Acrylates / Beheneth-25 methacrylate) copolymer 0.6% by mass
Carboxyvinyl polymer 0.4% by mass
(Hydroxyethyl acrylate / Methoxyethyl acrylate) copolymer
1.5% by mass
(Alkyl acrylate / diacetone acrylamide) copolymer
0.5% by mass
Triethanolamine 1.0% by mass
Tocophenol acetate 0.05% by mass
Phytic acid 0.1% by mass
Etidronic acid 0.05% by mass
Sodium hyaluronate 0.01% by mass
Perfume Appropriate amount of purified water Remaining amount

(Prescription Example 3: Hair Gel)
Hydroxypropyl methylcellulose 0.6% by mass
(Acrylic acid / alkyl acrylate (C10-30)) copolymer
1.0% by mass
(Hydroxyethyl acrylate / Methoxyethyl acrylate) copolymer
1.0% by mass
(Alkyl acrylate / diacetone acrylamide) copolymer
0.5% by mass
Triethanolamine 1.0% by mass
Tocophenol acetate 0.05% by mass
Phytic acid 0.1% by mass
Sodium sulfite 0.02% by mass
Hydrolyzed collagen 0.01% by mass
Perfume Appropriate amount of purified water Remaining amount

(Prescription Example 4: Hair Gel)
Hydroxypropyl methylcellulose 0.6% by mass
(Acrylic acid / alkyl acrylate (C10-30)) copolymer
1.0% by mass
Polyvinylpyrrolidone 3.0% by mass
(Alkyl acrylate / diacetone acrylamide) copolymer
0.5% by mass
Triethanolamine 1.0% by mass
Tocophenol acetate 0.05% by mass
Phytic acid 0.1% by mass
Sodium sulfite 0.02% by mass
Hydrolyzed collagen 0.01% by mass
Perfume Appropriate amount of purified water Remaining amount

(Prescription Example 5: Hair Gel)
Hydroxypropyl methylcellulose 0.2% by mass
(Acrylates / Stearless Methacrylate-20) Copolymer 0.5% by mass
(Methacryloyloxyethylcarboxybetaine / methacryl
Alkyl sulfate) copolymer 1.0 mass%
(Alkyl acrylate / diacetone acrylamide) copolymer
1.0% by mass
Triethanolamine 0.5% by mass
Tocophenol acetate 0.05% by mass
Phytic acid 0.1% by mass
Sodium sulfite 0.02% by mass
Hydrolyzed collagen 0.01% by mass
Perfume Appropriate amount

(Formulation Example 6: Hair grease)
Silica 1.0% by mass
Talc 0.5% by mass
Polyoxyethylene (40E.O.) hydrogenated castor oil 2.0% by mass
Polyoxyethylene (50E.O.) hydrogenated castor oil 6.0% by mass
Polyoxyethylene (100E.O.) hydrogenated castor oil 3.0% by mass
(Acrylates / Beheneth methacrylate-25) copolymer 0.4% by mass
Carboxyvinyl polymer 0.4% by mass
(Hydroxyethyl acrylate / Methoxyethyl acrylate)
Copolymer 2.0% by mass
Triethanolamine 0.8% by mass
Tocophenol acetate 0.05% by mass
Phytic acid 0.05% by mass
Edetate disodium 0.05 mass%
Hydrolyzed collagen 0.1% by mass
Ethanol 10.0% by mass
Perfume Appropriate amount of purified water Remaining amount

(Prescription Example 7: Hair grease)
Mica 1.0% by mass
Titanium oxide 0.5% by mass
Polyoxyethylene (50E.O.) hydrogenated castor oil 5.0% by mass
Polyoxyethylene (100E.O.) hydrogenated castor oil 5.0% by mass
(Acrylates / Beheneth-25 methacrylate) copolymer 0.6% by mass
Carboxyvinyl polymer 0.4% by mass
(Hydroxyethyl acrylate / Methoxyethyl acrylate)
Copolymer 2.0% by mass
(Acrylates / Alkyl acrylate (C1-18) / Alky
(C1-8) acrylamide / hydroxyethyl acrylate)
Copolymer AMP 0.3% by mass
Triethanolamine 1.0% by mass
Tocophenol acetate 0.05% by mass
Edetate disodium 0.05 mass%
Phytic acid 0.05% by mass
Sodium sulfite 0.02% by mass
Sodium hyaluronate 0.01% by mass
Ethanol 5.0% by mass
Perfume Appropriate amount of purified water Remaining amount

(Formulation Example 8: Hair grease)
Silica 2.0% by mass
Polyoxyethylene (40E.O.) hydrogenated castor oil 2.0% by mass
Polyoxyethylene (50E.O.) hydrogenated castor oil 4.0% by mass
Polyoxyethylene (100E.O.) hydrogenated castor oil 4.0% by mass
(Acrylates / Beheneth-25 methacrylate) copolymer 0.8% by mass
Carboxyvinyl polymer 0.3% by mass
(Hydroxyethyl acrylate / Methoxyethyl acrylate)
Copolymer 1.5% by mass
(Alkyl acrylate / diacetone acrylamide) copolymer
0.5% by mass
Triethanolamine 1.1% by mass
Edetate disodium 0.05 mass%
Phytic acid 0.05% by mass
Sodium bisulfite 0.02% by mass
Soybean extract 0.01% by mass
Ethanol 5.0% by mass
Perfume Appropriate amount of purified water Remaining amount

(Formulation example 9: hair grease)
Silica 2.0% by mass
Polyoxyethylene (40E.O.) hydrogenated castor oil 2.0% by mass
Polyoxyethylene (50E.O.) hydrogenated castor oil 4.0% by mass
Polyoxyethylene (100E.O.) hydrogenated castor oil 4.0% by mass
(Acrylates / Beheneth-25 methacrylate) copolymer 0.8% by mass
(Acrylic acid / alkyl acrylate (C10-30)) copolymer
0.4% by mass
Triethanolamine 1.2% by mass
Edetate disodium 0.05 mass%
Tocopherol acetate 0.1% by mass
Phytic acid 0.1% by mass
Trimethylglycine 2.0% by mass
Perfume Appropriate amount of purified water Remaining amount

The present invention relates to a hair styling composition used for a hair styling agent for shaping hair. The hair styling composition of the present invention is preferably a gel-like hair styling composition or a grease-like hair styling composition (referred to as hair grease, water grease, water-soluble pomade, etc.).

Claims (7)

1. A hairdressing composition comprising the following component A, the following component B, the following component C, and the following component D.
   Component A: Phytic acid Component B: Acrylic polymer obtained by using the following monomer component B1 and the following monomer component B2 as monomer components Monomer component B1: (meth) acrylic acid alkyl ester Monomer component B2: alkyl acrylamide and / or diacetone acrylamide Component C: Thickener Component D: Water
2. Component B includes (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP, and (acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer AMP. The hair styling agent according to claim 1, wherein the hair styling agent is at least one selected from the group consisting of a copolymer AMP, and an (acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide / hydroxyethyl acrylate) copolymer. Composition.
3. The hairdressing composition according to claim 1 or 2, wherein the component C contains at least one selected from the group consisting of the following component C1, the following component C2, and the following component C3.
   Component C1: Polymer obtained using at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester as the monomer component Component C2: (meth) acrylic acid as the monomer component And at least one monomer selected from the group consisting of (meth) acrylic acid alkyl esters, and a group selected from the group consisting of (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether, and vinyl neodecanoate Polymer obtained using at least one monomer selected from the above: Component C3: Carboxyvinyl polymer and / or alkyl-modified carboxyvinyl polymer
4. The content of component A is 0.01 to 2.0% by mass,
   The content of component B is 0.1 to 15.0% by mass,
   The content of component C is 0.05 to 3.0% by mass;
   The hair styling composition according to any one of claims 1 to 3.
5. The hair styling composition according to any one of claims 1 to 4, further comprising the following component E:
   Component E: sulfite and / or etidronic acid or a salt thereof
6. The hair styling composition according to any one of claims 1 to 5, further comprising the following component F:
   Component F: Nonionic surfactant
7. The hair styling composition according to any one of claims 1 to 6, further comprising the following component G:
   Component G: Tocopherol acetate and / or edetate