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WO2017215260A1 - Instant washing powder speckle and washing powder - Google Patents

Instant washing powder speckle and washing powder Download PDF

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Publication number
WO2017215260A1
WO2017215260A1 PCT/CN2017/070811 CN2017070811W WO2017215260A1 WO 2017215260 A1 WO2017215260 A1 WO 2017215260A1 CN 2017070811 W CN2017070811 W CN 2017070811W WO 2017215260 A1 WO2017215260 A1 WO 2017215260A1
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WO
WIPO (PCT)
Prior art keywords
parts
surfactant
laundry detergent
instant
embellishment
Prior art date
Application number
PCT/CN2017/070811
Other languages
French (fr)
Chinese (zh)
Inventor
郭庆春
阮勇
陈加祥
Original Assignee
四川省眉山市金庄新材料科技有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 四川省眉山市金庄新材料科技有限公司 filed Critical 四川省眉山市金庄新材料科技有限公司
Priority to GB1712932.1A priority Critical patent/GB2569938B/en
Publication of WO2017215260A1 publication Critical patent/WO2017215260A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds

Definitions

  • the present invention relates to the technical field of detergents, particularly laundry detergents.
  • Washing powder embellishments are generally colored particles added to the washing powder, some of which have the effect of assisting the washing effect, and some of which have only the embellishment function.
  • embellishments mixed with inorganic salts and pigments.
  • These embellishments only have an embellishment function and do not have washing and washing effects; the other is surface active.
  • the sodium salt of the fatty acid and the inorganic salt are pigmented and shaped into regular shaped embellishments.
  • the embellishments have regular shapes and washing and washing functions, they have poor low-temperature solubility and cannot satisfy normal temperature washing, and the washing effect is poor.
  • the object of the present invention is to provide an instant detergent powder garnish with regular shape, good low temperature solubility and good cleaning effect; another object is to provide a washing powder containing the garnish.
  • An instant detergent powder embellishment comprising the following components: 5 to 70 parts of the first surfactant, 5 to 20 parts of the second surfactant, 2 to 50 parts by mass of the bentonite, 2 to 50 parts by mass of the 4A zeolite, and pigment 0 ⁇ 10 parts by mass, wherein the second surfactant is a nonionic surfactant.
  • the bentonite in the invention has the effect of suspending the stain of the fabric, and the 4A zeolite has the effect of softening water, can replace the phosphate in the washing powder, and the disintegration of the bentonite and the 4A zeolite is good, and both have certain strength and flexibility. After compounding, it can complement and synergize in mechanical properties, and the embossing can be shaped into a regular shape, the particle size distribution is uniform, and the shape of the splicing object is stably maintained, and the washing effect is also promoted.
  • the second surfactant in the present invention can not only promote the washing effect, but also enhance the low-temperature solubility and molding plasticity of the embellishment, reduce the diffusion of the foreign matter molecules in the washing, and strengthen the connection between other components in the embellishment.
  • the inclusions containing bentonite and 4A zeolite can also be rapidly diffused and dissolved in water at a low temperature, and the washing effect is excellent.
  • the first surfactant is an anionic surfactant.
  • the first surfactant is one or more selected from the group consisting of sodium alkyl sulfate and sodium alkylsulfonate.
  • the sodium alkyl sulfate is a sodium alkylsulfonate-containing structure such as sodium lauryl sulfate or sodium cetyl sulfate.
  • the organic salt is an organic salt containing a sodium alkylsulfonate structure such as sodium dodecylsulfonate or sodium hexadecylsulfonate.
  • the first surfactant is one or more selected from the group consisting of sodium lauryl sulfate and sodium dodecyl sulfate.
  • the second surfactant is coconut oil fatty acid diethanolamide.
  • the surfactant is particularly preferred because: A. It can be combined with other materials in the formulation to improve the molding effect and release effect of the product during the manufacturing process; B. It can increase the moisturizing effect of the product during storage and transportation of the product. Improve the plasticity of the product to prevent breakage; C.
  • the surfactant also has an excellent washing function.
  • the patch has a particle diameter of 1.0 mm to 15.0 mm.
  • the embellishment needs to be formed into functional embellishments of uniform size, uniform shape, and regular shape.
  • the instant laundry detergent embedding comprises, by mass parts, 30 parts of sodium lauryl sulfate, 20 parts of 4A zeolite, 10 parts of coconut oil fatty acid diethanolamide, and 40 parts of bentonite.
  • the instant laundry detergent embedding comprises, by mass parts, the following components: 20 parts of sodium lauryl sulfate, 20 parts of sodium dodecyl sulfate, 10 parts of 4A zeolite, 5 parts of coconut oil Fatty acid diethanolamide, 45 parts bentonite.
  • the instant laundry detergent embedding comprises, in parts by mass, 10 parts of sodium lauryl sulfate, 30 parts of sodium dodecyl sulfate, 25 parts of 4A zeolite, and 5 parts of coconut oil. Fatty acid diethanolamide, 30 parts bentonite.
  • the above-mentioned ornament can be processed into a variety of fine and regular shapes, such as a ring shape, a star shape, a shield shape, a leaf shape, etc. Further, the characters and icons can be processed on the graphic, and the brand is enhanced while improving the detergent grade. Anti-counterfeiting effect.
  • the present invention further provides a laundry detergent comprising any of the above-described instant laundry detergent embellishments.
  • an inorganic salt-pigmented embellishment (abbreviated as the existing product 1) is an irregular spherical type; an additive formed by adding a surfactant fatty acid sodium and an inorganic salt to the pigment (abbreviation for the existing product 2) Due to the poor low-temperature solubility of sodium fatty acid, its washing and washing functions are poor, and it can not meet the normal temperature washing and washing effect.
  • the washing function is judged by the ability of suspension to resist redeposition and adsorption of stains of different embellishments.
  • the embellishment of the invention can be processed into a regular shape, such as a circle, a five-pointed star, a shield, a leaf, etc., and further, the text and the icon can be processed on the embellishment, the low-temperature solubility is good, the washing effect is excellent, and the washing effect is good.
  • the observation effect is good.
  • the washing powder containing the embellishment not only has excellent low-temperature washing effect, but also has a beautiful appearance and high grade, and at the same time, because the embellishment can be processed into a specific, fine and regular structure, it has an extremely high anti-counterfeiting effect.
  • Test items Test results shape Uniform size, shape rules Solubility (20 ° water temperature, dissolution 98%) 30 seconds Total activity (%) 38
  • Test items Test results shape Uniform size, shape rules Solubility (20 ° water temperature, dissolution 98%) 40 seconds Total activity (%) 42
  • Test items Test results shape Uniform size, shape rules Solubility (20 ° water temperature, dissolution 98%) 25 seconds Total activity (%) 43
  • Test items Test results shape Uniform size, shape rules Solubility (20 ° water temperature, dissolution 98%) 25 seconds Total activity (%) 43 colour Bright green
  • the total activity (%) in the table in each of the above examples is measured by the content of the active agent.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

An instant washing powder speckle and a washing powder, wherein the speckle comprises 5 to 70 parts of a first surfactant, 5 to 20 parts of a second surfactant, 2 to 50 parts by mass of bentonite, 2 to 50 parts by mass of 4A zeolite, and 0 to 10 parts by mass of pigment, wherein the second surfactant is a nonionic surfactant. The speckle can be processed to assume a regular shape, while having good low-temperature solubility and excellent washing effect; the speckle may be observed very well during washing, and is effective against counterfeiting.

Description

一种速溶洗衣粉点缀物及洗衣粉Instant detergent powder embellishment and washing powder 技术领域Technical field
本发明涉及洗涤用品，特别是洗衣粉的技术领域。The present invention relates to the technical field of detergents, particularly laundry detergents.
背景技术Background technique
洗衣粉点缀物一般为添加于洗衣粉内的彩色颗粒，其中部分具有辅助洗涤效果的作用，部分仅具有点缀功能。Washing powder embellishments are generally colored particles added to the washing powder, some of which have the effect of assisting the washing effect, and some of which have only the embellishment function.
目前的洗衣粉点缀物中常见的主要有两类，包括以无机盐加颜料混合成型的点缀物，该类点缀物只具有点缀功能，不具有洗涤和助洗效果；另一类是以表面活性剂脂肪酸钠与无机盐加颜料成型的规则形状的点缀物，该类点缀虽具有规则的形状及洗涤和助洗功能，但其低温溶解性差，不能满足常温洗涤，洗涤效果较差。At present, there are mainly two types of detergent powder embedding, including embellishments mixed with inorganic salts and pigments. These embellishments only have an embellishment function and do not have washing and washing effects; the other is surface active. The sodium salt of the fatty acid and the inorganic salt are pigmented and shaped into regular shaped embellishments. Although the embellishments have regular shapes and washing and washing functions, they have poor low-temperature solubility and cannot satisfy normal temperature washing, and the washing effect is poor.
发明内容Summary of the invention
本发明的目的在于提出一种形状规则、低温溶解性好、助洗效果好的速溶洗衣粉点缀物；另一目的在于提出一种含该点缀物的洗衣粉。The object of the present invention is to provide an instant detergent powder garnish with regular shape, good low temperature solubility and good cleaning effect; another object is to provide a washing powder containing the garnish.
本发明的技术方案如下：The technical solution of the present invention is as follows:
一种速溶洗衣粉点缀物，包括以下组分：第一表面活性剂5～70份，第二表面活性剂5～20份，膨润土2～50质量份、4A沸石2～50质量份、颜料0～10质量份，其中第二表面活性剂为非离子表面活性剂。An instant detergent powder embellishment comprising the following components: 5 to 70 parts of the first surfactant, 5 to 20 parts of the second surfactant, 2 to 50 parts by mass of the bentonite, 2 to 50 parts by mass of the 4A zeolite, and pigment 0 ～10 parts by mass, wherein the second surfactant is a nonionic surfactant.
本发明中的膨润土自身具有柔顺织物悬浮污渍的效果，4A沸石具有软化水的效果，可代替洗衣粉中的磷酸盐，同时膨润土与4A沸石的崩解性均较好，且均具有一定的强度与柔韧性，复配后更可以在力学性能上相互补充与协同，可使点缀物成型为规则的形状，粒径分布均一，并稳定地保持点缀物的形状，同时也具有促进洗涤的效果。The bentonite in the invention has the effect of suspending the stain of the fabric, and the 4A zeolite has the effect of softening water, can replace the phosphate in the washing powder, and the disintegration of the bentonite and the 4A zeolite is good, and both have certain strength and flexibility. After compounding, it can complement and synergize in mechanical properties, and the embossing can be shaped into a regular shape, the particle size distribution is uniform, and the shape of the splicing object is stably maintained, and the washing effect is also promoted.
本发明中的第二表面活性剂不仅能够促进洗涤效果，同时可增强该点缀物的低温溶解性和成型塑性，减少洗涤中杂物分子的扩散，加强点缀物中其它成分间的连接。The second surfactant in the present invention can not only promote the washing effect, but also enhance the low-temperature solubility and molding plasticity of the embellishment, reduce the diffusion of the foreign matter molecules in the washing, and strengthen the connection between other components in the embellishment.
通过不同表面活性剂的作用，也使得含有膨润土与4A沸石的点缀物可以在低温下快速地扩散溶解于水中，洗涤效果优良。By the action of different surfactants, the inclusions containing bentonite and 4A zeolite can also be rapidly diffused and dissolved in water at a low temperature, and the washing effect is excellent.
优选的是：所述第一表面活性剂为阴离子型表面活性剂。Preferably, the first surfactant is an anionic surfactant.
其进一步的优选为：所述第一表面活性剂为选自烷基硫酸钠、烷基磺酸钠的一种或多种。It is further preferred that the first surfactant is one or more selected from the group consisting of sodium alkyl sulfate and sodium alkylsulfonate.
其中所述烷基硫酸钠为如十二烷基硫酸钠、十六烷基硫酸钠这样含有烷基磺酸钠结构的 有机盐类，所述烷基磺酸钠为如十二烷基磺酸钠、十六烷基磺酸钠这样含有烷基磺酸钠结构的有机盐类。Wherein the sodium alkyl sulfate is a sodium alkylsulfonate-containing structure such as sodium lauryl sulfate or sodium cetyl sulfate. The organic salt is an organic salt containing a sodium alkylsulfonate structure such as sodium dodecylsulfonate or sodium hexadecylsulfonate.
进一步优选的是：所述第一表面活性剂为选自十二烷基硫酸钠、十二烷基磺酸钠的一种或多种。It is further preferred that the first surfactant is one or more selected from the group consisting of sodium lauryl sulfate and sodium dodecyl sulfate.
另外优选的是：所述第二表面活性剂为椰子油脂肪酸二乙醇酰胺。Further preferably, the second surfactant is coconut oil fatty acid diethanolamide.
特别优选该表面活性剂是因为：A.其能与配方中的其他材料配伍提高制造过程中产品的成型效果和脱模效果；B.在产品的储存运输过程中，其可以增加产品的保湿效果、提高产品的塑性，防止破碎；C.该表面活性剂同时具有优异的洗涤功能。The surfactant is particularly preferred because: A. It can be combined with other materials in the formulation to improve the molding effect and release effect of the product during the manufacturing process; B. It can increase the moisturizing effect of the product during storage and transportation of the product. Improve the plasticity of the product to prevent breakage; C. The surfactant also has an excellent washing function.
另外优选的是：所述点缀物的粒径为1.0mm～15.0mm。Further preferably, the patch has a particle diameter of 1.0 mm to 15.0 mm.
在本发明中，该点缀物需要成型为大小统一、形状统一、形状规则的功能性点缀物。In the present invention, the embellishment needs to be formed into functional embellishments of uniform size, uniform shape, and regular shape.
另外优选的是：所述速溶洗衣粉点缀物按质量份计，包括以下组分：30份十二烷基硫酸钠、20份4A沸石、10份椰子油脂肪酸二乙醇酰胺、40份膨润土。Further preferably, the instant laundry detergent embedding comprises, by mass parts, 30 parts of sodium lauryl sulfate, 20 parts of 4A zeolite, 10 parts of coconut oil fatty acid diethanolamide, and 40 parts of bentonite.
另外优选的是：所述速溶洗衣粉点缀物按质量份计，包括以下组分：20份十二烷基硫酸钠、20份十二烷基磺酸钠、10份4A沸石、5份椰子油脂肪酸二乙醇酰胺、45份膨润土。Further preferably, the instant laundry detergent embedding comprises, by mass parts, the following components: 20 parts of sodium lauryl sulfate, 20 parts of sodium dodecyl sulfate, 10 parts of 4A zeolite, 5 parts of coconut oil Fatty acid diethanolamide, 45 parts bentonite.
另外优选的是：所述速溶洗衣粉点缀物按质量份计，包括以下组分：将10份十二烷基硫酸钠、30份十二烷基磺酸钠25份4A沸石、5份椰子油脂肪酸二乙醇酰胺、30份膨润土。Further preferably, the instant laundry detergent embedding comprises, in parts by mass, 10 parts of sodium lauryl sulfate, 30 parts of sodium dodecyl sulfate, 25 parts of 4A zeolite, and 5 parts of coconut oil. Fatty acid diethanolamide, 30 parts bentonite.
上述点缀物可加工为多种精细、规则的形状，如圈状、星形、盾牌形、树叶形等等，进一步的，可在图形上加工文字、图标，在提高洗涤剂档次的同时具有品牌的防伪作用。The above-mentioned ornament can be processed into a variety of fine and regular shapes, such as a ring shape, a star shape, a shield shape, a leaf shape, etc. Further, the characters and icons can be processed on the graphic, and the brand is enhanced while improving the detergent grade. Anti-counterfeiting effect.
本发明进一步提出了一种洗衣粉，该洗衣粉包括上述任一种速溶洗衣粉点缀物。The present invention further provides a laundry detergent comprising any of the above-described instant laundry detergent embellishments.
现有点缀物中以无机盐加颜料成型的点缀物(简称现有产品1)，为不规则的类球状；以表面活性剂脂肪酸钠与无机盐加颜料成型的点缀物(简称现有产品2)由于脂肪酸钠的低温溶解性差，其洗涤和助洗功能均较差，不能满足常温洗涤和洗涤效果差。In the existing embellishment, an inorganic salt-pigmented embellishment (abbreviated as the existing product 1) is an irregular spherical type; an additive formed by adding a surfactant fatty acid sodium and an inorganic salt to the pigment (abbreviation for the existing product 2) Due to the poor low-temperature solubility of sodium fatty acid, its washing and washing functions are poor, and it can not meet the normal temperature washing and washing effect.
三者的对比效果如下：The comparison effect of the three is as follows:
Figure PCTCN2017070811-appb-000001
Figure PCTCN2017070811-appb-000001
Figure PCTCN2017070811-appb-000002
Figure PCTCN2017070811-appb-000002
其中助洗功能是通过不同点缀物的悬浮抗再沉积与吸附污渍的能力进行评判的。Among them, the washing function is judged by the ability of suspension to resist redeposition and adsorption of stains of different embellishments.
本发明的点缀物可加工为规则的形状，如圈、五角星、盾牌、树叶等等形状，更进一步可在点缀物上加工文字、图标，其低温溶解性好，洗涤效果优良，洗涤中的观察效果好。含有该点缀物的洗衣粉不仅低温洗涤效果优良，外观亮丽，档次高，同时因为其中的点缀物可加工为特定的、精细的、规则的结构，具有极高的防伪作用。The embellishment of the invention can be processed into a regular shape, such as a circle, a five-pointed star, a shield, a leaf, etc., and further, the text and the icon can be processed on the embellishment, the low-temperature solubility is good, the washing effect is excellent, and the washing effect is good. The observation effect is good. The washing powder containing the embellishment not only has excellent low-temperature washing effect, but also has a beautiful appearance and high grade, and at the same time, because the embellishment can be processed into a specific, fine and regular structure, it has an extremely high anti-counterfeiting effect.
具体实施方式detailed description
以下通过具体实施例对本发明作进一步的详细说明，但不应将此理解为本发明的范围仅限于以下的实例。在不脱离本发明上述方法思想的情况下,根据本领域普通技术知识和惯用手段做出的各种替换或变更,均应包含在本发明的范围内。The invention is further illustrated by the following examples, but it should be understood that the scope of the invention is limited to the following examples. Various alterations and modifications may be made without departing from the spirit and scope of the invention.
实施例1Example 1
将30份十二烷基硫酸钠、20份4A沸石、10份椰子油脂肪酸二乙醇酰胺、40份膨润土混合均匀后在成型机上成型成规则圈状，成型后点缀物形状规则，大小一致，粒径为5.0mm左右，检测情况如下：30 parts of sodium lauryl sulfate, 20 parts of 4A zeolite, 10 parts of coconut oil fatty acid diethanolamide, 40 parts of bentonite are uniformly mixed and formed into a regular ring shape on a molding machine. After molding, the shape of the ornament is regular and the size is uniform. The diameter is about 5.0mm, and the test situation is as follows:
检测项目Test items 检测结果Test results
形状shape 大小一致、形状规则Uniform size, shape rules
溶解性(20度水温，溶解98％)Solubility (20 ° water temperature, dissolution 98%) 30秒30 seconds
总活性(％)Total activity (%) 3838
实施例2Example 2
将20份十二烷基硫酸钠、20份十二烷基磺酸钠、10份4A沸石、5份椰子油脂肪酸二乙醇酰胺、45份膨润土混合均匀后在成型机上成型为五角星形状，成型后点缀物形状规则，大小一致，粒径为1.0mm左右，检测情况如下：20 parts of sodium lauryl sulfate, 20 parts of sodium dodecyl sulfate, 10 parts of 4A zeolite, 5 parts of coconut oil fatty acid diethanolamide, 45 parts of bentonite are uniformly mixed and formed into a pentagonal shape on a molding machine to form The shape of the posterior ornament is the same, the size is the same, and the particle size is about 1.0mm. The detection situation is as follows:
检测项目Test items 检测结果Test results
形状shape 大小一致、形状规则Uniform size, shape rules
溶解性(20度水温，溶解98％)Solubility (20 ° water temperature, dissolution 98%) 40秒40 seconds
总活性(％)Total activity (%) 4242
实施例3Example 3
将10份十二烷基硫酸钠、30份十二烷基磺酸钠25份4A沸石、5份椰子油脂肪酸二乙醇酰胺、30份膨润土混合均匀后在成型机上成型为盾牌状，成型后点缀物形状规则，大小一致，粒径为15.0mm左右，检测情况如下：10 parts of sodium lauryl sulfate, 30 parts of sodium dodecyl sulfate, 25 parts of 4A zeolite, 5 parts of coconut oil fatty acid diethanolamide, 30 parts of bentonite were uniformly mixed and formed into a shield shape on a molding machine, and embellished after molding. The shape of the object is regular and the size is the same. The particle size is about 15.0mm. The detection is as follows:
检测项目Test items 检测结果Test results
形状shape 大小一致、形状规则Uniform size, shape rules
溶解性(20度水温，溶解98％)Solubility (20 ° water temperature, dissolution 98%) 25秒25 seconds
总活性(％)Total activity (%) 4343
实施例4Example 4
将10份十二烷基硫酸钠、30份十二烷基磺酸钠25份4A沸石、5份椰子油脂肪酸二乙醇酰胺、29份膨润土、1份绿色颜料在混合均匀后在成型机上成型为树叶状，成型后点缀物形状规则，大小一致，粒径为10.0mm左右，检测情况如下：10 parts of sodium lauryl sulfate, 30 parts of sodium dodecyl sulfate, 25 parts of 4A zeolite, 5 parts of coconut oil fatty acid diethanolamide, 29 parts of bentonite, 1 part of green pigment are uniformly mixed and formed on a molding machine. The shape of the leaves is regular. The shape of the ornament is uniform and the size is about 10.0mm. The detection is as follows:
检测项目Test items 检测结果Test results
形状shape 大小一致、形状规则Uniform size, shape rules
溶解性(20度水温，溶解98％)Solubility (20 ° water temperature, dissolution 98%) 25秒25 seconds
总活性(％)Total activity (%) 4343
颜色colour 鲜亮的绿色Bright green
上述各实施例中表格内总活性(％)这一项目均以表明活性剂的含量进行衡量。The total activity (%) in the table in each of the above examples is measured by the content of the active agent.
尽管这里参照本发明的解释性实施例对本发明进行了描述，上述实施例仅为本发明较佳的实施方式，本发明的实施方式并不受上述实施例的限制，应该理解，本领域技术人员可以设计出很多其他的修改和实施方式，这些修改和实施方式将落在本申请公开的原则范围和精神之内。 Although the present invention has been described herein with reference to the preferred embodiments of the present invention, the embodiments of the present invention are only preferred embodiments of the present invention, and the embodiments of the present invention are not limited by the above embodiments, and it should be understood that those skilled in the art Many other modifications and embodiments can be devised which fall within the scope and spirit of the principles disclosed herein.

Claims (10)

  1. 一种速溶洗衣粉点缀物，其特征在于：包括以下组分：第一表面活性剂5～70份，第二表面活性剂5～20份，膨润土2～50质量份、4A沸石2～50质量份、颜料0～10质量份，其中第二表面活性剂为非离子型表面活性剂。An instant detergent powder embellen characterized by comprising the following components: 5 to 70 parts of the first surfactant, 5 to 20 parts of the second surfactant, 2 to 50 parts by mass of the bentonite, and 2 to 50 parts of the 4A zeolite. Parts, pigments 0 to 10 parts by mass, wherein the second surfactant is a nonionic surfactant.
  2. 根据权利要求1所述的速溶洗衣粉点缀物，其特征在于：所述第一表面活性剂为阴离子型表面活性剂。The instant laundry detergent embellishment according to claim 1, wherein the first surfactant is an anionic surfactant.
  3. 根据权利要求2所述的速溶洗衣粉点缀物，其特征在于：所述第一表面活性剂为选自烷基硫酸钠、烷基磺酸钠的一种或多种。The instant laundry detergent embellishment according to claim 2, wherein the first surfactant is one or more selected from the group consisting of sodium alkyl sulfate and sodium alkylsulfonate.
  4. 根据权利要求3所述的速溶洗衣粉点缀物，其特征在于：所述第一表面活性剂为选自十二烷基硫酸钠、十二烷基磺酸钠中的一种或多种。The instant laundry detergent embellishment according to claim 3, wherein the first surfactant is one or more selected from the group consisting of sodium lauryl sulfate and sodium dodecyl sulfate.
  5. 根据权利要求1所述的速溶洗衣粉点缀物，其特征在于：所述第二表面活性剂为椰子油脂肪酸二乙醇酰胺。The instant laundry detergent embellishment according to claim 1, wherein the second surfactant is coconut oil fatty acid diethanolamide.
  6. 根据权利要求1所述的速溶洗衣粉点缀物，其特征在于：所述点缀物的粒径为1.0mm～15.0mm。The instant laundry detergent embellishment according to claim 1, wherein the embellishment has a particle diameter of from 1.0 mm to 15.0 mm.
  7. 根据权利要求1所述的速溶洗衣粉点缀物，其特征在于：所述速溶洗衣粉点缀物按质量份计，包括以下组分：30份十二烷基硫酸钠、20份4A沸石、10份椰子油脂肪酸二乙醇酰胺、40份膨润土。The instant laundry detergent embellishment according to claim 1, wherein the instant laundry detergent embedding comprises, by mass parts, the following components: 30 parts of sodium lauryl sulfate, 20 parts of 4A zeolite, 10 parts. Coconut oil fatty acid diethanolamide, 40 parts bentonite.
  8. 根据权利要求1所述的速溶洗衣粉点缀物，其特征在于：所述速溶洗衣粉点缀物按质量份计，包括以下组分：20份十二烷基硫酸钠、20份十二烷基磺酸钠、10份4A沸石、5份椰子油脂肪酸二乙醇酰胺、45份膨润土。The instant laundry detergent embellishment according to claim 1, wherein the instant laundry detergent embedding comprises, by mass parts, the following components: 20 parts of sodium lauryl sulfate and 20 parts of dodecyl sulfonate. Sodium, 10 parts of 4A zeolite, 5 parts of coconut oil fatty acid diethanolamide, 45 parts of bentonite.
  9. 根据权利要求1所述的速溶洗衣粉点缀物，其特征在于：所述速溶洗衣粉点缀物按质量份计，包括以下组分：将10份十二烷基硫酸钠、30份十二烷基磺酸钠25份4A沸石、5份椰子油脂肪酸二乙醇酰胺、30份膨润土。The instant laundry detergent embellishment according to claim 1, wherein the instant laundry detergent embedding comprises, by mass part, the following components: 10 parts of sodium lauryl sulfate, 30 parts of dodecyl group Sodium sulfonate 25 parts of 4A zeolite, 5 parts of coconut oil fatty acid diethanolamide, 30 parts of bentonite.
  10. 一种洗衣粉，其特征在于：包括如权利要求1～9项中任一项所述的速溶洗衣粉点缀物。 A washing powder characterized by comprising the instant laundry detergent embellishment according to any one of claims 1-9.
PCT/CN2017/070811 2016-06-12 2017-01-11 Instant washing powder speckle and washing powder WO2017215260A1 (en)

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CN106085632A (en) * 2016-06-12 2016-11-09 四川省眉山市金庄新材料科技有限公司 A kind of instant detergent intersperses thing and detergent
GB2569938B (en) * 2016-06-12 2022-03-02 Sichuan Jinzhuang Tech Co Ltd Ornament of an instant detergent and detergent
CN107746755A (en) * 2017-11-17 2018-03-02 四川省眉山市金庄新材料科技有限公司 A kind of washing powder intersperses thing and washing powder

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