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WO2014019038A1 - Emballage multicouche antimicrobien et atoxique pour aliments - Google Patents

Emballage multicouche antimicrobien et atoxique pour aliments Download PDF

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Publication number
WO2014019038A1
WO2014019038A1 PCT/BR2012/000291 BR2012000291W WO2014019038A1 WO 2014019038 A1 WO2014019038 A1 WO 2014019038A1 BR 2012000291 W BR2012000291 W BR 2012000291W WO 2014019038 A1 WO2014019038 A1 WO 2014019038A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
packaging
food
antimicrobian
atoxic
Prior art date
Application number
PCT/BR2012/000291
Other languages
English (en)
Portuguese (pt)
Inventor
Raquel PILETTI
Marcel FERRARI DOS SANTOS
Jair FIORI JUNIOR
Márcio Antônio FIORI
Paulo Eduardo MAREGA CARGNIN
Mateus VITAL COLONETTI
Carlos Alberto ARAUJO
Adailton CITADIN PEREIRA
Thiago TOFOLI
Original Assignee
Fundação Educacional De Criciúma
Plaszom Zomer Industria De Plasticos Ltda
Seara Alimentos Ltda
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fundação Educacional De Criciúma, Plaszom Zomer Industria De Plasticos Ltda, Seara Alimentos Ltda filed Critical Fundação Educacional De Criciúma
Priority to PCT/BR2012/000291 priority Critical patent/WO2014019038A1/fr
Publication of WO2014019038A1 publication Critical patent/WO2014019038A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514—Oriented
    • B32B2307/518—Oriented bi-axially
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/70—Food packaging

Definitions

  • the present invention belongs generally to the food packaging technology sector and more specifically relates to an antimicrobial and non-toxic multilayer packaging capable of packaging food and ensuring its physical, chemical and microbiological integrity.
  • the proposed packaging consists of layers made of special active materials and principles that make it active and capable of eliminating microorganisms such as bacteria and fungi that promote premature food spoilage.
  • the invention guarantees all the traditional protection conditions of a common packaging, however, due to its antimicrobial characteristic, it eliminates microorganisms such as bacteria and fungi inside. This differential makes the packaging object of the invention capable of extending shelf-life of products on the shelf and increasing consumer safety without compromising product quality.
  • the state of the art of this technology sector comprises packaging with antimicrobial principles, but these conventional packages are composed of only a single layer, ie monolayer packaging.
  • the monolayer linear extrusion technique is employed to manufacture these packages.
  • these packages are manufactured with silver and / or triclosan-based biocidal additives, ie commercial compounds.
  • the commercial line of Irgaguard® additives BASF / CIBA SPECIALTY CHEMICALS
  • NANOX silver and nanoprotein based compounds
  • a problem related to these monolayer packages relates to the fact that the single layer needs to be considerably thick as it assumes also the structural function of the package. This has a significant impact on the cost increase of a part because additives are too expensive and the high thickness implies the use of more additives. Many application possibilities are eliminated due to the high cost of packaging.
  • these conventional packages are subject to significant interactions with the external environment, which causes degradation of their active principle.
  • the active ingredients used are ionic or molecular species that easily oxidize in the presence of oxygen (or other free radicals). These reactions are accelerated by increased temperature and exposure to light. Thus, these packages have potentially short antimicrobial action time.
  • the present invention relates to an antimicrobial multilayer package produced with zinc based antimicrobial additive.
  • Zinc is an element present in the metabolic systems of humans and animals, so that in many situations of nutrition and medicines it is added in view of the vital need of humans and animals for this chemical element. Thus, it is not considered toxic and gives the packaging the great advantage and differential of being non-toxic. This feature will greatly facilitate their market acceptance and easy release by regulatory bodies such as ANVISA, Animal Health Bodies and others.
  • the proposed packaging is produced with the concept of functional multilayers.
  • the active (antimicrobial) layer is on the inside of the package and in contact with the food packaging medium.
  • This layer is protected from the external environment and its active principle isolated and absent from reactions with oxygen or other free radicals present in the atmosphere. It is Design ensures greater durability of antimicrobial principle and longer antimicrobial action time for packaging. It gives the food greater safety and longer time, and increases the shelf life of stored products.
  • the multilayer configuration guarantees on the outside of the packaging layers without the active principle, but with structural and finishing functions. Not being the antimicrobial outer layer the packaging can accept any visual finishing art. In this way it is possible to print images with traditional inks and varnishes without reacting with the active principle.
  • the active inner layer has no structural function, it is feasible to produce packages with small thicknesses. As a result, small thicknesses require smaller amounts of polymers and especially smaller amounts of active ingredients. Since active ingredients account for most of the cost of packaging, this differential certainly guarantees the economic viability of antimicrobial multilayer packaging over traditional single-layer packaging.
  • FIG. 1 perspective view of a three layer package manufactured in accordance with the principles of the invention.
  • FIG. 3 perspective view of a multilayer package manufactured in accordance with the principles of the invention.
  • the present invention relates to an antimicrobial and non-toxic food multilayer package comprising at least two layers having specific functions, wherein the inner layer (1) must have an antimicrobial function, preferably consisting of a polymeric material with any additive. zinc-based compound, which performs the antimicrobial function, associated with an outer layer (2).
  • the inner layer (1) is not restricted to just one additive or polymer, but any antimicrobial additive, preferably zinc based for the absence of toxicity, and any compatible polymer.
  • Suitable polymers for the inner layer constitution include, but are not limited to: LDPE, LLDPE, HDPE, EVOH, PET, NYLON, PVC, PP, BOPP or other non-toxic polymer compatible with the antimicrobial additive.
  • the package may consist of multiple layers in which each layer will have specific functions.
  • the other layers may be made of any polymer or any other material of interest, ie LDPE, LLDPE, HDPE, EVOH, PET, NYLON, PVC, PP, BOPP or other polymer, or aluminum films, or adhesives, or other materials. It depends on the functions they will perform and the physical and chemical properties that will be required of them according to the characteristics and properties required by the products to be packaged. At first there is no restriction on the number of layers that will make up the package. Packaging can be manufactured from two layers to the required quantity requested by the project.
  • Multilayer packaging should be produced with layers that perform important functions in the multilayer system as packaging.
  • Each layer has its own function and contributes to the fundamental performance of the multilayer packaging in its antimicrobial protection function.
  • the intermediate layers preferably perform the blocking / barrier function of undesirable compounds to the food or active ingredient. They thus contribute to the efficiency and durability of antimicrobial function.
  • the outer layers have structural and receiving function of the packaging art.
  • the structural layers are sized to prevent fractures from being generated during use of the packages, which would expose the active inner layers to the outer environment (which would decrease the efficiency and durability of the active principle). They also guarantee good weldability in their application, allowing the generation of vacuum and at the same time the tightness of the packaging medium (increases the efficiency and durability of the antimicrobial function).
  • two-layer film illustrated in Figure 1 is provided with an outer layer (2), which has the function of receiving the aesthetic finish (art) of the package, providing structural support to the package and acting as protection barrier of antimicrobial additive.
  • the inner layer (1) is a thermo sealable layer with antimicrobial additive, which has direct contact with the food, that is, the food packaging medium is surrounded by the inner layer (1).
  • the package consists of three layers: an inner layer (1) with antimicrobial additive, surrounding the food packaging medium; an outer layer (2) which receives the aesthetic finish of the package and provides structural support and; an intermediate layer (3) having barrier properties against moisture, gases and the antimicrobial additive.
  • Figure 3 shows an exemplary embodiment of a seven-layer package consisting of an inner layer with antimicrobial additive (1) and an outer layer with finishing functions (2), limiting a series of intermediate layers: a structural layer. (4), a gas barrier layer (5), another structural layer (6), a moisture barrier layer (7) and an antimicrobial additive barrier layer (8).

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Packages (AREA)
  • Wrappers (AREA)

Abstract

L'invention concerne un emballage multicouche antimicrobien et atoxique pour aliments, comprenant au moins deux couches dotées de fonctions spécifiques, soit une couche intérieure (1) dotée obligatoirement d'une fonction antimicrobienne et constituée de préférence d'une matière polymère additionnée d'un composé quelconque à base de zinc, associée à une couche extérieure (2) de support structural et de réception de revêtement de finition esthétique, pouvant inclure une multitude d'autres couches intermédiaires à fonctions spécifiques.
PCT/BR2012/000291 2012-08-02 2012-08-02 Emballage multicouche antimicrobien et atoxique pour aliments WO2014019038A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/BR2012/000291 WO2014019038A1 (fr) 2012-08-02 2012-08-02 Emballage multicouche antimicrobien et atoxique pour aliments

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/BR2012/000291 WO2014019038A1 (fr) 2012-08-02 2012-08-02 Emballage multicouche antimicrobien et atoxique pour aliments

Publications (1)

Publication Number Publication Date
WO2014019038A1 true WO2014019038A1 (fr) 2014-02-06

Family

ID=50026997

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/BR2012/000291 WO2014019038A1 (fr) 2012-08-02 2012-08-02 Emballage multicouche antimicrobien et atoxique pour aliments

Country Status (1)

Country Link
WO (1) WO2014019038A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104139566A (zh) * 2014-07-14 2014-11-12 湖北富思特材料科技集团有限公司 双面可印刷bopp镀铝膜
EP3802122B1 (fr) * 2018-05-25 2023-08-16 Cryovac, LLC Procédé de fabrication d'un film multicouche antimicrobien

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0722660B1 (fr) * 1995-01-12 2002-06-05 Hagiwara Research Corporation Composition polymère antimicrobienne
US20040110018A1 (en) * 2001-03-16 2004-06-10 Susanne Holzer Printable polypropylene film having anti-fog properties
US6838186B2 (en) * 2002-04-22 2005-01-04 Polinas Plastic Of America, Inc. Multilayer oriented antimicrobial and antifogging films
US20050019591A1 (en) * 2003-04-10 2005-01-27 Jean-Marc Francois Metallized films
US20100233326A1 (en) * 2006-05-17 2010-09-16 Ishida Co., Ltd. Antibacterial Laminate

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0722660B1 (fr) * 1995-01-12 2002-06-05 Hagiwara Research Corporation Composition polymère antimicrobienne
US20040110018A1 (en) * 2001-03-16 2004-06-10 Susanne Holzer Printable polypropylene film having anti-fog properties
US6838186B2 (en) * 2002-04-22 2005-01-04 Polinas Plastic Of America, Inc. Multilayer oriented antimicrobial and antifogging films
US20050019591A1 (en) * 2003-04-10 2005-01-27 Jean-Marc Francois Metallized films
US20100233326A1 (en) * 2006-05-17 2010-09-16 Ishida Co., Ltd. Antibacterial Laminate

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104139566A (zh) * 2014-07-14 2014-11-12 湖北富思特材料科技集团有限公司 双面可印刷bopp镀铝膜
EP3802122B1 (fr) * 2018-05-25 2023-08-16 Cryovac, LLC Procédé de fabrication d'un film multicouche antimicrobien

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