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WO2004007356A3 - Verfahren zum starten eines gaserzeugungssystems - Google Patents

Verfahren zum starten eines gaserzeugungssystems Download PDF

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Publication number
WO2004007356A3
WO2004007356A3 PCT/DE2003/002199 DE0302199W WO2004007356A3 WO 2004007356 A3 WO2004007356 A3 WO 2004007356A3 DE 0302199 W DE0302199 W DE 0302199W WO 2004007356 A3 WO2004007356 A3 WO 2004007356A3
Authority
WO
WIPO (PCT)
Prior art keywords
starting
devices
starting materials
generating system
gas
Prior art date
Application number
PCT/DE2003/002199
Other languages
English (en)
French (fr)
Other versions
WO2004007356A2 (de
Inventor
Marc Sommer
Bernhard Vogel
Original Assignee
Daimler Chrysler Ag
Marc Sommer
Bernhard Vogel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daimler Chrysler Ag, Marc Sommer, Bernhard Vogel filed Critical Daimler Chrysler Ag
Priority to EP03763585A priority Critical patent/EP1519894A2/de
Priority to AU2003247248A priority patent/AU2003247248A1/en
Priority to JP2004520301A priority patent/JP2005538501A/ja
Priority to US10/520,900 priority patent/US7374591B2/en
Publication of WO2004007356A2 publication Critical patent/WO2004007356A2/de
Publication of WO2004007356A3 publication Critical patent/WO2004007356A3/de

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0687—Reactant purification by the use of membranes or filters
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435—Catalytic purification
    • C01B2203/044—Selective oxidation of carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288—Evaporation of one or more of the different feed components
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1604—Starting up the process
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Ein Verfahren dient zum Starten eines Gaserzeugungssystems (1) zum Erzeugen eines wasserstoffhaltigen Gases zum Betreiben einer Brennstoffzelle. Das Gaserzeugungssystems verfügt Einrichtungen zum Umsetzen von Ausgangsstoffen in das wasserstoffhaltige Gas, über Einrichtungen zum Konditionieren wenigstens eines Teils der Ausgangsstoffe, über Einrichtungen zum Reinigen des wasser­stoffhaltigen Gases von unerwünschten Gasbestandteilen und über einen Startbrenner (11). In einem ersten Verfahrensschritt werden gemäß der Erfindung in dem Startbrenner zumindest ein Brenn­stoff verbrannt. Die heissen Abgase dieser Verbrennung erwärmen zuerst die Einrichtungen zum Konditionieren wenigstens eines Teils der Ausgangssstoffe und anschließend mit der verbleiben­den Restwärme wenigstens eine weitere Komponente. Parallel dazu werden die Einrichtungen zum Umsetzen der Ausgangsstoffe durch eine elektrische Beheizung erwärmt. Nachfolgend werden in einem zweiten Verfahrensschritt die Ausgangsstoffe in die jeweiligen Komponenten der oben beschriebenen Einrichtungen zugegeben, wo­bei dies nach dem jeweiligen Erreichen einer Starttemperatur erfolgt. Anschließend werden in einem dritten Verfahrensschritt die Mengenverhältnisse der Ausgangsstoffe kontinuierlich in Richtung der für den bestimmungsgemäßen Betrieb des Gaserzeu­gungssystems vorgesehenen Mengenverhältnisse hin verändert.
PCT/DE2003/002199 2002-07-10 2003-07-02 Verfahren zum starten eines gaserzeugungssystems WO2004007356A2 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP03763585A EP1519894A2 (de) 2002-07-10 2003-07-02 Verfahren zum starten eines gaserzeugungssystems
AU2003247248A AU2003247248A1 (en) 2002-07-10 2003-07-02 Method for starting a gas generating system
JP2004520301A JP2005538501A (ja) 2002-07-10 2003-07-02 ガス発生システムの始動方法
US10/520,900 US7374591B2 (en) 2002-07-10 2003-07-02 Method for starting a gas generating system

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10231126.9 2002-07-10
DE10231126A DE10231126A1 (de) 2002-07-10 2002-07-10 Verfahren zum Starten eines Gaserzeugungssystems

Publications (2)

Publication Number Publication Date
WO2004007356A2 WO2004007356A2 (de) 2004-01-22
WO2004007356A3 true WO2004007356A3 (de) 2004-04-08

Family

ID=30009874

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2003/002199 WO2004007356A2 (de) 2002-07-10 2003-07-02 Verfahren zum starten eines gaserzeugungssystems

Country Status (6)

Country Link
US (1) US7374591B2 (de)
EP (1) EP1519894A2 (de)
JP (1) JP2005538501A (de)
AU (1) AU2003247248A1 (de)
DE (1) DE10231126A1 (de)
WO (1) WO2004007356A2 (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7082753B2 (en) * 2001-12-03 2006-08-01 Catalytica Energy Systems, Inc. System and methods for improved emission control of internal combustion engines using pulsed fuel flow
DE10349075B4 (de) * 2003-10-22 2016-01-07 Airbus Operations Gmbh Vorrichtung zur Zufuhr von Brennstoff zu einem Brenner in einem Brennstoffzellensystem mit einem Reformer
KR100560495B1 (ko) * 2004-01-28 2006-03-14 삼성에스디아이 주식회사 연료 전지 시스템의 개질기 및 이를 채용한 연료 전지시스템
AU2005295595C1 (en) 2004-10-15 2012-06-21 Seattle Genetics, Inc. Anti-CD70 antibody and its use for the treatment and prevention of cancer and immune disorders
US7641903B2 (en) 2004-10-15 2010-01-05 Seattle Genetics, Inc. Anti-CD70 antibody and its use for the treatment and prevention of cancer and immune disorders
DE102009037145B4 (de) 2009-08-06 2015-08-27 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Hochtemperaturbrennstoffzellensystem mit einem Startbrenner
WO2011124240A1 (en) * 2010-04-09 2011-10-13 Fraunhofer-Gesellschaft Zur Förderung Der Angewandten Forschung E.V. Angewandten Forschung E.V. System having high-temperature fuel cells
CN111864237B (zh) * 2020-06-17 2021-07-20 江苏大学 一种基于催化和微燃烧的氢燃料电池尾气后处理装置
DE102020127406A1 (de) 2020-10-19 2021-12-02 Diehl Aerospace Gmbh Katalytische Wärmeerzeugung für die Bordküche

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4033133A (en) * 1976-03-22 1977-07-05 California Institute Of Technology Start up system for hydrogen generator used with an internal combustion engine
DE19639150A1 (de) * 1996-09-24 1998-04-02 Daimler Benz Ag Zentrale Heizvorrichtung für ein Gaserzeugungssystem
WO1999031012A1 (de) * 1997-12-16 1999-06-24 Dbb Fuel Cell Engines Gesellschaft Mit Beschränkter Haftung Verfahren zum betrieb einer anlage zur wasserdampfreformierung eines kohlenwasserstoffs
EP1057780A2 (de) * 1999-06-03 2000-12-06 Toyota Jidosha Kabushiki Kaisha Brennstoffreformer zur Montage auf Fahrzeugen
US6231831B1 (en) * 1997-12-16 2001-05-15 Xcellsis Gmbh Hydrogen separating membrane, methanol reformation system equipped therewith, and operating method therefor
US6268075B1 (en) * 1997-12-16 2001-07-31 Xcellsis Gmbh Process for the water vapor reforming of a hydrocarbon or a hydrocarbon derivative, reforming system operable thereby, and fuel cell operating process
US6294149B1 (en) * 1997-12-16 2001-09-25 Xcellsis Gmbh Process for operating a water vapor reforming system, a reforming system operable thereby and a fuel cell system operating process
US20020064487A1 (en) * 2000-11-30 2002-05-30 Richard Sederquist Compact Multiple tube steam reformer

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2511866B2 (ja) 1986-02-07 1996-07-03 株式会社日立製作所 燃料電池発電システム及びその起動方法
JPH0217306A (ja) * 1988-07-04 1990-01-22 Fuji Electric Co Ltd 多孔体バーナ
US6221117B1 (en) * 1996-10-30 2001-04-24 Idatech, Llc Hydrogen producing fuel processing system
JP3678118B2 (ja) * 2000-06-01 2005-08-03 日産自動車株式会社 燃料改質システム
EP1316529A4 (de) * 2000-08-25 2006-03-08 Matsushita Electric Ind Co Ltd Wasserstoffgenerator

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4033133A (en) * 1976-03-22 1977-07-05 California Institute Of Technology Start up system for hydrogen generator used with an internal combustion engine
DE19639150A1 (de) * 1996-09-24 1998-04-02 Daimler Benz Ag Zentrale Heizvorrichtung für ein Gaserzeugungssystem
WO1999031012A1 (de) * 1997-12-16 1999-06-24 Dbb Fuel Cell Engines Gesellschaft Mit Beschränkter Haftung Verfahren zum betrieb einer anlage zur wasserdampfreformierung eines kohlenwasserstoffs
US6231831B1 (en) * 1997-12-16 2001-05-15 Xcellsis Gmbh Hydrogen separating membrane, methanol reformation system equipped therewith, and operating method therefor
US6268075B1 (en) * 1997-12-16 2001-07-31 Xcellsis Gmbh Process for the water vapor reforming of a hydrocarbon or a hydrocarbon derivative, reforming system operable thereby, and fuel cell operating process
US6294149B1 (en) * 1997-12-16 2001-09-25 Xcellsis Gmbh Process for operating a water vapor reforming system, a reforming system operable thereby and a fuel cell system operating process
EP1057780A2 (de) * 1999-06-03 2000-12-06 Toyota Jidosha Kabushiki Kaisha Brennstoffreformer zur Montage auf Fahrzeugen
US20020064487A1 (en) * 2000-11-30 2002-05-30 Richard Sederquist Compact Multiple tube steam reformer

Also Published As

Publication number Publication date
EP1519894A2 (de) 2005-04-06
AU2003247248A1 (en) 2004-02-02
US7374591B2 (en) 2008-05-20
DE10231126A1 (de) 2004-02-05
AU2003247248A8 (en) 2004-02-02
US20050260110A1 (en) 2005-11-24
WO2004007356A2 (de) 2004-01-22
JP2005538501A (ja) 2005-12-15

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