WO2001081065A1 - Method of molding a panel - Google Patents
Method of molding a panel Download PDFInfo
- Publication number
- WO2001081065A1 WO2001081065A1 PCT/CA2001/000534 CA0100534W WO0181065A1 WO 2001081065 A1 WO2001081065 A1 WO 2001081065A1 CA 0100534 W CA0100534 W CA 0100534W WO 0181065 A1 WO0181065 A1 WO 0181065A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mold
- rib
- mold half
- series
- extending
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 34
- 238000000465 moulding Methods 0.000 title claims description 17
- 239000000463 material Substances 0.000 claims abstract description 47
- 239000012768 molten material Substances 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 230000004888 barrier function Effects 0.000 claims abstract description 4
- 239000012815 thermoplastic material Substances 0.000 claims description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
- -1 polypropylene Polymers 0.000 claims description 6
- 239000004677 Nylon Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 239000012764 mineral filler Substances 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 claims description 3
- 229920001778 nylon Polymers 0.000 claims description 3
- 239000004417 polycarbonate Substances 0.000 claims description 3
- 229920000515 polycarbonate Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920001187 thermosetting polymer Polymers 0.000 claims description 3
- 239000012779 reinforcing material Substances 0.000 claims 2
- 239000011347 resin Substances 0.000 claims 2
- 229920005989 resin Polymers 0.000 claims 2
- 239000007924 injection Substances 0.000 description 7
- 238000002347 injection Methods 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000012899 standard injection Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
- B29C45/1679—Making multilayered or multicoloured articles applying surface layers onto injection-moulded substrates inside the mould cavity, e.g. in-mould coating [IMC]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
- B29C2045/1687—Making multilayered or multicoloured articles preventing leakage of second injected material from the mould cavity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
- B29C37/0028—In-mould coating, e.g. by introducing the coating material into the mould after forming the article
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
- B29C45/1635—Making multilayered or multicoloured articles using displaceable mould parts, e.g. retractable partition between adjacent mould cavities
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/722—Decorative or ornamental articles
Definitions
- the subject invention relates to a method of manufacturing an automotive panel that has an exterior class-A finish.
- Injection molding is well known in many industries for manufacturing a wide variety of products.
- the automotive industry utilizes plastic injection molding to create a number of interior and exterior trim components and other like parts, such as tonneau covers and body panels, which require an aesthetically pleasing exterior surface.
- the desired exterior surface is typically known as an exterior class-A finish.
- United States Patent no. 4,910,067 can produce structurally rigid panels.
- the quality of the surface finish is usually slightly less than class-A.
- a separate skin, paint or coating must then be applied to the panel after removing the panel from the mold to create the class-A finish.
- the disadvantages of the prior art may be overcome by providing a method of manufacturing a panel utilizing a first mold half having a peripherally extending rib and a second mold half.
- the first mold half is moved relative to the second mold half to define a first mold cavity with the rib extending into the first mold cavity.
- a first molten material is injected into the first mold cavity and allowed to solidify to thereby form a notch within the first solidified material corresponding to the shape of the rib.
- a second mold cavity is formed which has a flow path between the first solidified material and the first mold half comprising a series of sharp turns which present a barrier to material flow.
- a second material is injected into the second mold cavity and allowed to cure on the first solidified material.
- Figure 1 is a cross-sectional side view of a molding assembly having an upper mold half and a lower mold half in accordance with the subject invention
- Figure 2 is an enlarged fragmentary cross-sectional side view of the molding assembly with the upper and lower mold half in a completely closed position before a first inj ection of a first material
- Figure 3 is an enlarged fragmentary cross-sectional side view of the molding assembly after the first injection with the upper mold half in a partially raised position
- Figure 4 is an enlarged fragmentary cross-sectional side view of the molding assembly after a second inj ection of a second material
- Figure 5 is an enlarged fragmentary cross-sectional side view of an alternative embodiment of the upper mold half
- Figure 6 is a perspective view of a second embodiment of a molding formed utilizing the present invention.
- Figure 7 is a top plan view of the molding of Figure 6;
- Figure 8 is a sectional view of the molding of Figure 6 along the lines A- A; and
- Figure 9 is a sectional view of the molding of Figure 6 along the lines B-B .
- the molding assembly 10 includes a first mold half 12 and a second mold half 14.
- Both the first 12 and second 14 mold halves include an inner surface 16, 17 having a desired contour which correlates to the shape of a final molded product having a generally convex outer class-A surface (not shown).
- the inner surfaces 16, 17 are configured to form an automotive panel.
- the contour of the inner surfaces 16, 17 may be of any suitable design to create a desired automotive or non-automotive molded product generally having a large planar surface.
- a center plug 19 extends from the second mold half 14 that aligns with the center recess of the first mold half 12.
- Center plug 19 has walls that are slightly tapered to accommodate demolding.
- the center plug 19 has a flange 21 extending about the perimeter of the plug 19. Flange 21 extends about and is spaced from the inner surface 17.
- the first mold half 12 has a recess 23 sized to receive center plug 19. Recess 23 is slightly larger than the center plug 19 such that when the mold halves 12, 14 are closed a desired gap will be maintained between surfaces 16, 17. Rib 24 extends around the recess 23. Rib 24 is spaced from the outer periphery of the first mold half 12. Abutment 25 extends about the outer periphery of the first mold half 12. Abutment 25 has a thickness which corresponds to the thickness of the desire gap between the surfaces 16, 17. Rib 24 has a thickness that is less than that of abutment 25.
- the mold halves 12, 14 are first moved to a closed position. Abutment 25 abuts against mold half 14 forming a seal.
- a first molten material 20 is then injected through a plurality of apertures or gates 22, preferably in the upper mold half 12, into the first mold cavity 18 until completely filled.
- gates 22 could be located in mold half 14 in accordance with standard injection molding practice.
- a plurality of gates are used and the flow of material is controlled by a technique known as sequential valve gating, which is more particularly described in United States patent no. 5,762,855.
- the gates are preferably positioned relative to the part to be molded in inconspicuous regions so that if a mark is created by the gate, this mark can be later covered or removed.
- the first material 20 is preferably any thermoplastic material. Suitable non-limiting examples include polypropylene, polyethylene terephthalate (PET), NYLON, polycarbonate, and PCABS.
- reinforcement materials such as a glass fibre, mineral filler or nanoparticle may be added to the thermoplastic.
- the molten material 20 solidifies or "freezes" to a rigid or semi-rigid base or substrate for the panel.
- Rib 24 forms a corresponding notch 26 within the solidified first material 20 that forms flange 27 extending about the periphery of the molded part.
- the rib 24 has a substantially rectangular configuration.
- the rib 24 preferably has a trapezoidal configuration as shown in Figure 5 (slightly exaggerated for illustration purposes) or any other suitable shape which allows the flange 27 to demold from the rib 24.
- the notch 26 formed in the flange 27 will directly correspond to the configuration of the rib 24.
- the first mold half 12 is opened slightly to create a second desired gap between the first 12 and second 14 mold halves.
- This gap defines a second mold cavity 28 disposed above the first material 20 for receiving a second material 30.
- the rib 24 and corresponding notch 26 have sharpened edges which creates a narrow channel or flow path having a series of sharp turns between the flange 27 and rib 24.
- the series of sharp turns presents a barrier to the flow of viscous liquids, preventing the viscous liquid from being expelled from the second mold cavity 28.
- the second material 30 forms a thin skin or coating that adheres to the solidified part.
- the second material 30 is preferably a light stable coating such as thermosetting poryurethane or polyester, either aliphatic or aromatic.
- a preferred polyurethane coating is commercially available from O nova Solutions Inc. under the trademark GENGLAZE or STYLECOAT.
- the second material 30 fills the second mold cavity 28 and extends through the narrow channel and partially spills into the notch 26 of the first material 20 as is illustrated in Figure 4.
- the flow of the uncured second material is terminated and does not escape from between the mold halves 12, 14 during the second injection process.
- the gap formed between the upper 12 and lower 14 mold halves and the narrow channels are exaggerated.
- the preferred thickness of the skin 30 is about 3-5 thousands of an inch or approximately .125 mm.
- the mold halves 12, 14 can be maintained at about 250°F to enhance cross linking.
- the first mold half 12 is completely opened.
- the molded part now has a skin defining the desired class-A finish for the panel.
- the panel does not require an additional painting step.
- first mold half 12 is not raised above the second mold half 14.
- the upper 12 and lower 14 mold halves remain in the completely closed position during the molding process.
- the injecting of the first material 20, along with the forming of the notch 26, occurs in the same manner as above.
- the second material 30 is injected while the mold halves 12, 14 remain closed.
- the first material 20 may shrink slightly during solidification and has some compressible characteristics.
- the injection pressure of the second material 30 will at least partially compress the first material 20 and create a small gap between the first material 20 and the first mold half 12.
- the small gap is analogous to the second mold cavity 28 discussed above.
- the rib 24 and notch 26 of the first material 20 still operate to retain the second material 30 within the upper 12 and lower 14 mold halves during the injection thereof. This method may be preferred when using a first material 20 that is compressible after an initial solidification.
- Molded part 100 generally has a convex class-A outer surface having a generally planar section 40 and a flange 27 extending about a periphery of the parent part 100.
- Flange 27 is preferably spaced from and extends about planar section 40.
- the flange 27 has a series of circumferentially extending apertures 42 separated by a series of filling webs 44.
- the series of apertures 42 separate the inner region of flange 27 from an outer racetrack 46.
- First and second mold halves 12, 14 are modified in a known manner to mold the apertures 42 by inserting walls onto either of mold half 12 or mold half 14.
- the portions of rib 24 are configured to extend between the walls that form apertures 42.
- the molded part is formed in the manner described above. Once the formed part is removed from the mold halves 12, 14, the racetrack 46 may be removed from the parent part by cutting or shearing the webs 44. The webs 44 should have a minimal amount of the second material 30. This material can be easily removed or alternatively the webs 44 can be cut from the racetrack 46 whereupon the racetrack may be ground up into a regrind and fed back into the molding process as part of first material 20 as is known in the art.
- the invention has been described in an illustrative manner, and it is to be understood that the terminology that has been used is intended to be in the nature of words of description rather than of limitation. It is now apparent to those skilled in the art that many modifications and variations of the present invention are possible in light of the above teachings. It is, therefore, to be understood that the invention may be practiced otherwise than as specifically described.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001578190A JP2003531039A (en) | 2000-04-20 | 2001-04-20 | Panel molding method |
AU2001250213A AU2001250213A1 (en) | 2000-04-20 | 2001-04-20 | Method of molding a panel |
US10/258,096 US20030090035A1 (en) | 2000-04-20 | 2001-04-20 | Method of molding a panel |
MXPA02010360A MXPA02010360A (en) | 2000-04-20 | 2001-04-20 | Method of molding a panel. |
EP01923440A EP1274556A1 (en) | 2000-04-20 | 2001-04-20 | Method and mold for molding a panel |
BR0110155-2A BR0110155A (en) | 2000-04-20 | 2001-04-20 | Method for making a molded part, and, mold for making a molded part |
CA002406453A CA2406453A1 (en) | 2000-04-20 | 2001-04-20 | Method of molding a panel |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US19869100P | 2000-04-20 | 2000-04-20 | |
US60/198,691 | 2000-04-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001081065A1 true WO2001081065A1 (en) | 2001-11-01 |
Family
ID=22734395
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CA2001/000534 WO2001081065A1 (en) | 2000-04-20 | 2001-04-20 | Method of molding a panel |
Country Status (9)
Country | Link |
---|---|
US (1) | US20030090035A1 (en) |
EP (1) | EP1274556A1 (en) |
JP (1) | JP2003531039A (en) |
KR (1) | KR20030007539A (en) |
AU (1) | AU2001250213A1 (en) |
BR (1) | BR0110155A (en) |
CA (1) | CA2406453A1 (en) |
MX (1) | MXPA02010360A (en) |
WO (1) | WO2001081065A1 (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6676877B2 (en) | 2002-04-03 | 2004-01-13 | Omnova Solutions Inc. | Mold runner for prevention of in-mold coating flow |
WO2004096520A1 (en) * | 2003-04-29 | 2004-11-11 | Omnova Solutions Inc. | ISOLATING MOULD MECHANICAL FUNCTIONS DURING IN-mOULD COATING OPERATION |
US6875389B2 (en) | 2000-07-12 | 2005-04-05 | Omnova Solutions Inc. | Method for in-mold coating a polyolefin article |
US6887550B2 (en) | 2001-10-22 | 2005-05-03 | Omnova Solutions Inc. | Removable defined flange for in-mold coating containment |
US6890469B2 (en) | 2001-10-22 | 2005-05-10 | Omnova Solutions Inc. | Selectively controlling in-mold coating flow |
US7045213B2 (en) | 2001-10-22 | 2006-05-16 | Omnova Solutions Inc. | In-mold coating injection inlet flow control |
US7105231B2 (en) | 2001-10-22 | 2006-09-12 | Omnova Solutions Inc. | In-mold coating barrier for a substrate injection orifice |
DE102020200071A1 (en) * | 2020-01-07 | 2021-07-08 | Volkswagen Aktiengesellschaft | Injection molding process for the production of a structurally optimized plastic component |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6793861B2 (en) | 2000-07-12 | 2004-09-21 | Omnova Solutions Inc. | Optimization of in-mold coating injection molded thermoplastic substrates |
RU2323106C2 (en) * | 2001-08-15 | 2008-04-27 | Дау Глобал Текнолоджиз Инк. | Improved system of vehicle seats |
DE60324026D1 (en) * | 2002-12-12 | 2008-11-20 | Omnova Solutions Inc | METHOD FOR MANUFACTURING AND USE OF A TOOL |
RU2340503C2 (en) * | 2003-02-13 | 2008-12-10 | Дау Глобал Текнолоджиз Инк. | Improved instrument cluster unit and method for its manufacturing |
US20040188885A1 (en) * | 2003-03-31 | 2004-09-30 | Luis Lorenzo | Instrument panel assembly and method of forming same |
JP4430898B2 (en) * | 2003-07-24 | 2010-03-10 | パナソニック株式会社 | Partition transfer mold, plasma display panel, and transfer partition formation method |
US7291378B2 (en) * | 2004-05-24 | 2007-11-06 | International Automotive Components Group North America, Inc. | Trim panel assembly having integrated energy management characteristics and method of manufacture |
FR2893528B1 (en) * | 2005-11-21 | 2009-07-17 | Visteon Global Tech Inc | METHOD OF LOCALIZED OVERMOLDING BY INJECTION, MOLD IMPLEMENTED IN SAID METHOD AND MULTIMATERIC PART THUS OBTAINED |
US20070184273A1 (en) * | 2006-02-09 | 2007-08-09 | Husky Injection Molding Systems Ltd. | Overmolding of Inserts |
US20080080204A1 (en) * | 2006-06-23 | 2008-04-03 | Faurecia Interior Systems U.S.A., Inc. | Molded panel and method of manufacture |
JP5169780B2 (en) * | 2008-12-05 | 2013-03-27 | 宇部興産機械株式会社 | In-mold coating mold |
ES2715451T3 (en) | 2015-06-03 | 2019-06-04 | Weidplas Gmbh | Component |
JP7175749B2 (en) * | 2018-12-26 | 2022-11-21 | ダイハツ工業株式会社 | injection molding method |
JP7173863B2 (en) * | 2018-12-27 | 2022-11-16 | ダイハツ工業株式会社 | injection molded product, injection molding method, injection mold |
FR3117060B1 (en) * | 2020-12-08 | 2023-10-27 | Faurecia Automotive Ind | Part of motor vehicle equipment and associated manufacturing process |
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- 2001-04-20 AU AU2001250213A patent/AU2001250213A1/en not_active Abandoned
- 2001-04-20 EP EP01923440A patent/EP1274556A1/en not_active Withdrawn
- 2001-04-20 WO PCT/CA2001/000534 patent/WO2001081065A1/en not_active Application Discontinuation
- 2001-04-20 MX MXPA02010360A patent/MXPA02010360A/en unknown
- 2001-04-20 KR KR1020027014061A patent/KR20030007539A/en not_active Application Discontinuation
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- 2001-04-20 JP JP2001578190A patent/JP2003531039A/en active Pending
- 2001-04-20 US US10/258,096 patent/US20030090035A1/en not_active Abandoned
- 2001-04-20 BR BR0110155-2A patent/BR0110155A/en not_active IP Right Cessation
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
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US6875389B2 (en) | 2000-07-12 | 2005-04-05 | Omnova Solutions Inc. | Method for in-mold coating a polyolefin article |
US6887550B2 (en) | 2001-10-22 | 2005-05-03 | Omnova Solutions Inc. | Removable defined flange for in-mold coating containment |
US6890469B2 (en) | 2001-10-22 | 2005-05-10 | Omnova Solutions Inc. | Selectively controlling in-mold coating flow |
US7045213B2 (en) | 2001-10-22 | 2006-05-16 | Omnova Solutions Inc. | In-mold coating injection inlet flow control |
US7105231B2 (en) | 2001-10-22 | 2006-09-12 | Omnova Solutions Inc. | In-mold coating barrier for a substrate injection orifice |
EP1441888B1 (en) * | 2001-10-22 | 2008-07-30 | Omnova Solutions Inc. | Method for applying an in-mold coating on a surface area of an injection molded substrate |
US6676877B2 (en) | 2002-04-03 | 2004-01-13 | Omnova Solutions Inc. | Mold runner for prevention of in-mold coating flow |
US6884056B2 (en) | 2002-04-03 | 2005-04-26 | Omnova Solutions Inc. | Mold runner for prevention of in-mold coating flow |
WO2004096520A1 (en) * | 2003-04-29 | 2004-11-11 | Omnova Solutions Inc. | ISOLATING MOULD MECHANICAL FUNCTIONS DURING IN-mOULD COATING OPERATION |
DE102020200071A1 (en) * | 2020-01-07 | 2021-07-08 | Volkswagen Aktiengesellschaft | Injection molding process for the production of a structurally optimized plastic component |
Also Published As
Publication number | Publication date |
---|---|
AU2001250213A1 (en) | 2001-11-07 |
MXPA02010360A (en) | 2004-09-10 |
CA2406453A1 (en) | 2001-11-01 |
JP2003531039A (en) | 2003-10-21 |
BR0110155A (en) | 2002-12-31 |
KR20030007539A (en) | 2003-01-23 |
EP1274556A1 (en) | 2003-01-15 |
US20030090035A1 (en) | 2003-05-15 |
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