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WO2000028374A1 - Electrochromic glass component - Google Patents

Electrochromic glass component Download PDF

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Publication number
WO2000028374A1
WO2000028374A1 PCT/EP1999/008572 EP9908572W WO0028374A1 WO 2000028374 A1 WO2000028374 A1 WO 2000028374A1 EP 9908572 W EP9908572 W EP 9908572W WO 0028374 A1 WO0028374 A1 WO 0028374A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
glass component
component according
electrochromic
ion
Prior art date
Application number
PCT/EP1999/008572
Other languages
French (fr)
Inventor
Wolfgang Athenstaedt
David Macher
Heinz Zorn
Thomas Soczka-Guth
Original Assignee
Magna Auteca Zweigniederlassung Der Magna Holding Ag
Celanese Ventures Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BR9915189-8A priority Critical patent/BR9915189A/en
Application filed by Magna Auteca Zweigniederlassung Der Magna Holding Ag, Celanese Ventures Gmbh filed Critical Magna Auteca Zweigniederlassung Der Magna Holding Ag
Priority to AU12697/00A priority patent/AU1269700A/en
Priority to SK598-2001A priority patent/SK5982001A3/en
Priority to AT99955960T priority patent/ATE232989T1/en
Priority to EP99955960A priority patent/EP1129387B1/en
Priority to JP2000581499A priority patent/JP2002529794A/en
Priority to CA002350144A priority patent/CA2350144A1/en
Priority to US09/831,535 priority patent/US6563625B1/en
Priority to PL99348203A priority patent/PL348203A1/en
Priority to KR1020017005927A priority patent/KR20010092729A/en
Priority to DE69905486T priority patent/DE69905486T2/en
Publication of WO2000028374A1 publication Critical patent/WO2000028374A1/en
Priority to NO20012267A priority patent/NO20012267L/en

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Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
    • G02F1/1523—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material
    • G02F1/1525—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material characterised by a particular ion transporting layer, e.g. electrolyte
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R1/00—Optical viewing arrangements; Real-time viewing arrangements for drivers or passengers using optical image capturing systems, e.g. cameras or video systems specially adapted for use in or on vehicles
    • B60R1/02—Rear-view mirror arrangements
    • B60R1/08—Rear-view mirror arrangements involving special optical features, e.g. avoiding blind spots, e.g. convex mirrors; Side-by-side associations of rear-view and other mirrors
    • B60R1/083—Anti-glare mirrors, e.g. "day-night" mirrors
    • B60R1/088—Anti-glare mirrors, e.g. "day-night" mirrors using a cell of electrically changeable optical characteristic, e.g. liquid-crystal or electrochromic mirrors
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/153—Constructional details
    • G02F1/155—Electrodes
    • G02F2001/1552—Inner electrode, e.g. the electrochromic layer being sandwiched between the inner electrode and the support substrate

Definitions

  • the invention relates to an electrochromic glass component, particularly for motor vehicle mirrors, which contains a doped ion-conducting basic polymer as the ion-conducting layer.
  • Electrochromic mirrors particularly for motor vehicles, are known in the state of the art.
  • the essential element of these electrochromic mirrors is a layer of electrochromic material.
  • a material is termed electrochromic when it changes its optical constants (n, k ) and hence its optical properties on application of an electric field.
  • Typical examples of such electrochromic materials are 0 3 and Mo0 3 , which are virtually colourless when applied to a substrate in thin layers.
  • An electrochromic layer may change its optical properties by oxidation or reduction processes. If protons move in such a layer, in the case of tungsten oxide there is a reduction to blue tungsten bronze. The intensity o£ colouration is determined by the quantity of charge which has flowed in the layer.
  • electrochromic mirrors particularly for motor vehicles, are now know from the state of the art and have electrochromic layers of this type in different layered structures.
  • German 3 008 768 describes an electrochromic mirror which essentially consists of a layer system built on a glass substrate at least one electrochromic layer, at least two electrodes, at least one proton-conducting layer and at least one proton-delivering and one proton-storing layer being present.
  • the optical change properties of a mirror of this type are determined, inter alia, by the proton conductivity of the proton-conducting layer.
  • proton-conducting glass plates which were soaked with sulphuric acid, have been used hitherto as proton-conducting layers (for example in German Offenlegungsschrift 2 504 905) or as in German 3 008 768 so-called solid ion-conducting layers.
  • the object of the present invention is therefore, starting from the electrochromic mirror as described in german 3 008 768, to indicate a significantly improved embodiment which is characterised particularly by an ion-conducting layer which is favourable to apply as regard to manufacture and processing and furthermore has a high ion conductivity, with which it is possible to change the electrochromic layer quickly.
  • a doped ion-conducting basic polymer as the ion-co - ducting layer. It has been shown that these doped ion-conduction basic polymers are particularly well suited.
  • the doped ion-conducting basic polymer is preferably selected from polybenzimidazoles (PBI) , polypyridines, polyimidazoles, polybenzthiazoles, polybenzoxazoles, polyquinolines, polythiazoles, polyoxadiazoles and polytetrapyrenes .
  • the ion-conduc ing layer is thus a layer which preferably conducts protons. However, in principle the layer is also suitable for other ions, such as for example lithium.
  • Figure 1 shows an electrochromic glass component of the invention, here as a motor vehicle mirror.
  • Figure 2 shows the concrete structure of a mirror.
  • the electrochromic glass component which is used as a motor vehicle mirror, consists of a glass substrate 1 having a thickness of 2 mm. A layer system which has the following successive layers is applied to this substrate 1.
  • Figures 2a and 2b show the electrochromic glass component according to Figure 1, but the function of a glass component of this type becomes visible here.
  • a primer 10 for better adhesion promotion is also applied between the electrochromic layer 2 and the mirror layer 3.
  • Figure 2a thus shows the light position and Figure 2b the dark position.
  • the electrochromic glass component of the invention if the doped ion- conducting polymer is present in the form of a polymer membrane.
  • a proton-conduction polymer membrane particulate preferred. It should be emphasised in particular for the ion-conducting layer according to the invention that it may be applied easily using all conventional techniques. Examples of these are screen printing, immersion, spraying, blade coating or also application of a gel.
  • the polymer membrane is a polybenzimidazole .
  • the doped ion-conducting layer has particularly good properties with regard to its ion conductivity if the ion-conducing layer is doped with an acid, in par- ticular with a strong acid. It is preferable if the pKa value of the doping acid ⁇ 4.5, preferably ⁇ 3.5 for the first dissociation stage at 25 °C. For acid it has proved to be particularly advantageous if the acid is a phosphoric acid, in particular a poly- phosphoric acid. Acid treatment of polybenzimidazoles is described in United States 5 599 639, to which reference is made expressly here.
  • the electrochromic glass component of the invention contains a proton-conducting polymer membrane of polybenzimidazole .
  • Polymer membranes of this type which are composed of polybenzimidazoles and are proton-conducting, are known from the state of the art, for example from United States 5 017 681. All named polybenzimidazoles in the above-mentioned United States patent specification may be used in principle for the proton-con- ducting layer of the invention. It is particularly preferable if the polymer consists of a polybenzimidazole having a molecular weight between 1,000 and 500,000 which consists of repeating units of the following structural formula:
  • the electrochromic glass component if the ion-conducting layer described in more detail above is used at a layer thickness of 1 ⁇ m to 1 mm, preferably 5 ⁇ m to 100 ⁇ m .
  • Application of the layer, in particular the polymer membrane, may thus be effected by screen. printing, immersion, spraying, blade coating or even as a gel . Provision is thus made according to the invention in that the layer is applied either as a finished film or is even produced directly on the substrate or a layer lying underneath. These applica- tion procedures may also be used in combination.
  • the electrochromic layer which preferably has a layer thickness of 300 n to 8,000 nm, preferably 300 nm to 8,000 nm, preferably consists of 0 3 , Mo0 3 , Ir0 2 or mixed oxides thereof.
  • the electrochromic layer is applied by sputtering, sol-gel or by vapour deposition.
  • the electrodes which are necessary for constructing the layer system of the invention, are preferably metallic layers having a layer thickness of 50 nm to 10 ⁇ m.
  • layers of this type are those which contain rhodium, palladium, platinum or alloys thereo .
  • a metallic electrode layer at the same time forms a reflector which may accept protons.
  • This reflector preferably consists of a layer having a layer thickness of 30 nm to 500 nm, which contains rhodium, palladium, platinum or alloys thereof.
  • the electrochromic glass component of the invention if the ion-delivering layer and the ion-storing layer at the same time form a layer or a composite.
  • a W0 3 layer thus functions at the same time as a hydrogen ion-storing layer and as an electrochromic layer.
  • the composite consists of the proton-storing and at the same time proton-delivering layer on a film, preferably a polyester film with metallisation which is the counter-electrode.
  • the film of polyester, glass, metal or other plastics are suitable as substrate materials for the composite.
  • the glass component of the invention ith regard to the possible layered structure variants of the electrochromic glass component of the invention, reference is made to German 3 008 76S and the layered structure described therein. However, it is preferable for the glass component of the invention if the glass component has been constructed from two layered composites. Hence, in the manufacture of the electrochromic glass component according to a preferred embodiment, a first layer system is constructed on a glass substrate, an electrochromic layer applied thereto and metallisation as a reflector. These layers are produced by means of sputtering processes.
  • the second part of the layer system is then a composite which consists of a proton-storing layer, metallisation and a film arranged thereabove, in particular a polyester film.
  • This composite is manufac- tured in a separate process step and then joined to the above-mentioned first layered composite of the layer system. This procedure facilitates cost-effective and simple manufacture of the electrochromic glass component .
  • a further favourable embodiment of the invention makes provision, if it is necessary, in that adhesion-promoting layers for better bonding are applied between the individual layers .
  • adhesion-promoting layers for better bonding are applied between the individual layers .
  • adhesion-promoting layers for better bonding are applied between the individual layers .
  • these are chromium, titanium or even silicon oxides SiO ⁇ .
  • the layer system is tightly sealed externally.
  • the layer system may be sealed at the and-faces and a final layer, that is a layer opposite the glass substrate seen in the viewing direction, may be provided with a protective layer, for example a diffusion barrier.
  • Diffusion barriers of this type have a water permeability ⁇ 1,000, preferably ⁇ 100 cm 3 .
  • the glass substrate is a reflection-reducing thin glass having a layer thickness of 0,1 to 3 mm.
  • a transparent conductive layer for heating the mirror is applied in front of the substrate, seen in the viewing direction.

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Nonlinear Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Multimedia (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Laminated Bodies (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)
  • Rear-View Mirror Devices That Are Mounted On The Exterior Of The Vehicle (AREA)
  • Surface Treatment Of Glass (AREA)
  • Liquid Crystal Substances (AREA)

Abstract

The invention relates to an electrochromic glass component, particularly for motor vehicle mirrors, which contains a doped ion-conducting basic polymer (4) as the ion-conducting layer. The electrochromic glass component consists, for example of a glass substrate (1) as well as a layer system having an electrochromic layer (2), a mirror layer (3), a doped polymer membrane (4), for example of polybenzimidazole polymer, a proton store (5), a rear electrode (6) and a polyester film (7). The layer system is sealed by a seal (8) which closes the coating system towards the glass substrate (1).

Description

ElβcfcroehroπiiG glass component
FIΞLD OF IIWEN ION
The invention relates to an electrochromic glass component, particularly for motor vehicle mirrors, which contains a doped ion-conducting basic polymer as the ion-conducting layer.
B&CKGROUHD OF IHVEM ION
Electrochromic mirrors, particularly for motor vehicles, are known in the state of the art. The essential element of these electrochromic mirrors is a layer of electrochromic material. A material is termed electrochromic when it changes its optical constants (n, k ) and hence its optical properties on application of an electric field. Typical examples of such electrochromic materials are 03 and Mo03 , which are virtually colourless when applied to a substrate in thin layers. An electrochromic layer may change its optical properties by oxidation or reduction processes. If protons move in such a layer, in the case of tungsten oxide there is a reduction to blue tungsten bronze. The intensity o£ colouration is determined by the quantity of charge which has flowed in the layer.
Numerous electrochromic mirrors, particularly for motor vehicles, are now know from the state of the art and have electrochromic layers of this type in different layered structures.
German 3 008 768 describes an electrochromic mirror which essentially consists of a layer system built on a glass substrate at least one electrochromic layer, at least two electrodes, at least one proton-conducting layer and at least one proton-delivering and one proton-storing layer being present.
The optical change properties of a mirror of this type are determined, inter alia, by the proton conductivity of the proton-conducting layer. The higher the proton conductivity, the higher also the rate of change of reflection. In the mirrors of the state of the art, proton-conducting glass plates, which were soaked with sulphuric acid, have been used hitherto as proton-conducting layers (for example in German Offenlegungsschrift 2 504 905) or as in German 3 008 768 so-called solid ion-conducting layers.
It has been shown all these ion-conducting layers from the state of the art used hitherto for the electrochromic glass components still do not have satisfactory results with regard to ion conductivity.
Furthermore, it is disadvantageous for the mirrors of the state of the art, that the ion-conducting layers described there are either too thick or are too complex and expensive as regards their mode of manufac- ture.
SUMBfi&EY OF INVEHrriON
The object of the present invention is therefore, starting from the electrochromic mirror as described in german 3 008 768, to indicate a significantly improved embodiment which is characterised particularly by an ion-conducting layer which is favourable to apply as regard to manufacture and processing and furthermore has a high ion conductivity, with which it is possible to change the electrochromic layer quickly.
The invention is achieved by the characterising fea- tures of patent claim 1. The sub-claims show advantageous further developments.
According to the invention it is thus proposed to use a doped ion-conducting basic polymer as the ion-co - ducting layer. It has been shown that these doped ion-conduction basic polymers are particularly well suited. The doped ion-conducting basic polymer is preferably selected from polybenzimidazoles (PBI) , polypyridines, polyimidazoles, polybenzthiazoles, polybenzoxazoles, polyquinolines, polythiazoles, polyoxadiazoles and polytetrapyrenes . The ion-conduc ing layer is thus a layer which preferably conducts protons. However, in principle the layer is also suitable for other ions, such as for example lithium.
DESCRIPTION OF THE DRAWINGS
The invention is illustrated in more detail below using Figure 1 and Figure 2.
Figure 1 shows an electrochromic glass component of the invention, here as a motor vehicle mirror.
Figure 2 shows the concrete structure of a mirror.
DESCRIPTION OF THE INVENTION
The electrochromic glass component, which is used as a motor vehicle mirror, consists of a glass substrate 1 having a thickness of 2 mm. A layer system which has the following successive layers is applied to this substrate 1.
An electrochromic layer 2 of tungsten oxide having a thickness of - 700 n , a mirror layer 3 of palladium having a thickness of - 70 nm, a polymer membrane 4 of polybenzimidazols polymer having a thickness of 30 /-.m, a proton store 5 of tungsten trioxide having a thickness of 700 nm, a rear electrode 6 of gold having a thickness of 100 n , a polyester film 7 having a thickness of about 175 μm as well as a sealing layer 8 of traditional plastics, which wraps around the entire coating system including the glass substrate 1 and thus seals the coating system comprising layers 2 to 7. Seal 8 is only interrupted by copper wires 5, which contact the mirror layer 3 on the one side and the rear electrode 6 on the other side to apply a voltage to the latter.
Figures 2a and 2b show the electrochromic glass component according to Figure 1, but the function of a glass component of this type becomes visible here. In the exemplary embodiment according to Figure 2, a primer 10 for better adhesion promotion is also applied between the electrochromic layer 2 and the mirror layer 3. Figure 2a thus shows the light position and Figure 2b the dark position.
It is particularly preferable for the electrochromic glass component of the invention if the doped ion- conducting polymer is present in the form of a polymer membrane. A proton-conduction polymer membrane particulate preferred. It should be emphasised in particular for the ion-conducting layer according to the invention that it may be applied easily using all conventional techniques. Examples of these are screen printing, immersion, spraying, blade coating or also application of a gel.
According to the present invention it is particularly preferable if the polymer membrane is a polybenzimidazole .
It should be emphasised in particular for the electrochromic glass component of the invention that the doped ion-conducting layer has particularly good properties with regard to its ion conductivity if the ion-conduc ing layer is doped with an acid, in par- ticular with a strong acid. It is preferable if the pKa value of the doping acid ≤ 4.5, preferably ≤ 3.5 for the first dissociation stage at 25 °C. For acid it has proved to be particularly advantageous if the acid is a phosphoric acid, in particular a poly- phosphoric acid. Acid treatment of polybenzimidazoles is described in United States 5 599 639, to which reference is made expressly here.
It is particularly preferable for the electrochromic glass component of the invention if it contains a proton-conducting polymer membrane of polybenzimidazole .
Polymer membranes of this type, which are composed of polybenzimidazoles and are proton-conducting, are known from the state of the art, for example from United States 5 017 681. All named polybenzimidazoles in the above-mentioned United States patent specification may be used in principle for the proton-con- ducting layer of the invention. It is particularly preferable if the polymer consists of a polybenzimidazole having a molecular weight between 1,000 and 500,000 which consists of repeating units of the following structural formula:
Figure imgf000008_0001
It has proved to be particularly favourable for the electrochromic glass component if the ion-conducting layer described in more detail above is used at a layer thickness of 1 μm to 1 mm, preferably 5 μm to 100 μm . Application of the layer, in particular the polymer membrane, may thus be effected by screen. printing, immersion, spraying, blade coating or even as a gel . Provision is thus made according to the invention in that the layer is applied either as a finished film or is even produced directly on the substrate or a layer lying underneath. These applica- tion procedures may also be used in combination.
The electrochromic layer, which preferably has a layer thickness of 300 n to 8,000 nm, preferably 300 nm to 8,000 nm, preferably consists of 03 , Mo03, Ir02 or mixed oxides thereof. The electrochromic layer is applied by sputtering, sol-gel or by vapour deposition.
The electrodes, which are necessary for constructing the layer system of the invention, are preferably metallic layers having a layer thickness of 50 nm to 10 μm. Examples of layers of this type are those which contain rhodium, palladium, platinum or alloys thereo .
According to a preferred embodiment, provision is made in that a metallic electrode layer at the same time forms a reflector which may accept protons. This reflector preferably consists of a layer having a layer thickness of 30 nm to 500 nm, which contains rhodium, palladium, platinum or alloys thereof.
As already described in German 3 008 768, it is also preferable for the electrochromic glass component of the invention if the ion-delivering layer and the ion-storing layer at the same time form a layer or a composite. According to a preferred embodiment of the invention, provision ia thus made in that the proton- storing layer is the electrochromic layer at the same time. In this case, for example a W03 layer, thus functions at the same time as a hydrogen ion-storing layer and as an electrochromic layer. According to a preferred embodiment, the composite consists of the proton-storing and at the same time proton-delivering layer on a film, preferably a polyester film with metallisation which is the counter-electrode. Instead of the film of polyester, glass, metal or other plastics are suitable as substrate materials for the composite.
ith regard to the possible layered structure variants of the electrochromic glass component of the invention, reference is made to German 3 008 76S and the layered structure described therein. However, it is preferable for the glass component of the invention if the glass component has been constructed from two layered composites. Hence, in the manufacture of the electrochromic glass component according to a preferred embodiment, a first layer system is constructed on a glass substrate, an electrochromic layer applied thereto and metallisation as a reflector. These layers are produced by means of sputtering processes.
The second part of the layer system is then a composite which consists of a proton-storing layer, metallisation and a film arranged thereabove, in particular a polyester film. This composite is manufac- tured in a separate process step and then joined to the above-mentioned first layered composite of the layer system. This procedure facilitates cost-effective and simple manufacture of the electrochromic glass component .
A further favourable embodiment of the invention makes provision, if it is necessary, in that adhesion-promoting layers for better bonding are applied between the individual layers . Examples of this are chromium, titanium or even silicon oxides SiO^. For application as motor vehicle mirrors, provision is also made in that the layer system is tightly sealed externally. Hence the layer system may be sealed at the and-faces and a final layer, that is a layer opposite the glass substrate seen in the viewing direction, may be provided with a protective layer, for example a diffusion barrier. Diffusion barriers of this type have a water permeability < 1,000, preferably < 100 cm3. For motor vehicle mir- rors it has proved to be particularly favourable if the glass substrate is a reflection-reducing thin glass having a layer thickness of 0,1 to 3 mm. For motor vehicle mirrors it is also advisable if a transparent conductive layer for heating the mirror is applied in front of the substrate, seen in the viewing direction.

Claims

Patent claims
1. Electrochromic glass component, particularly for motor vehicle mirrors, having a layer system arranged on a glass substrate containing at least one electrochromic layer, at least two electrodes, at least one ion- conducting layer, at least one ion-delivering layer and at least one ion-storing layer, wherein the two las -mentioned layers may also form a layer at the same time, characterised in that the ion-conduction layer contains a doped ion-conducting basic polymer.
2. Electrochromic glass component according to claim 1, characterised in that the doped ion-conducting polymer is selected from polybenzimidazoles,
(PBI) , polypyridin.es, polyimidazoles, polybenzthiazoles , polybenzoxazoles , polyquinolines, polythiazoles, polyoxadiasoles and polytetrapyrenes .
Electrochromic glass components according to claim l or 2, characterised in that the doped ion-conducting polymer is a polymer membrane.
Electrochromic glass component according to claim 3 , characterised in that the polymer membrane consists of a polyben≥i idazole polymer.
. Electrochromic glass component according to at least one of claims 1 to 4, characterised in that the ion-conducting layer is doped with acid.
6. Electrochromic glass component according to claim 5, characterised in that the layer has been doped with phosphoric acid.
7. Electrochromic glass component according to at least one of claims 1 to 5, characterised in that the pKa value of the free acid is ≤ 4.5 at 25 °C for the first diεεocia- tion stage.
8. Electrochromic glass component according to at least one of claims 1 to 7, characterised in that the ion-conducting layer has a layer thick- ness of 1 μ to 1 mm.
9. Electrochromic glass component according to at least one of claims 1 to 8, characterised in that the ion-conducting layer is applied to the substrate or a different layer of the layer system or is produced thereon.
10. Electrochromic glass component according to at least one of claims 1 to 9, characterised in that the ion-conducting layer is applied or produced by screen printing, immersion, blade coating, spraying or as a gel, or by a combination thereof .
11. Electrochromic glass component according to at leastone of claims 1 to 10, characterised in that the electrochromic layer is an oxidation-reduction layer consisting of metal oxides.
12. Electrochromic glass component according to claim 11, characterised in that the electrochromic layer is a W03 layer having a layer thickness of
100 nm to 3, 000 nm.
13. Electrochromic glass component according to at least one of claims l to 12, characterised in that at least one electrode is designed in the form of metallic layers having a layer thickness of 100 n to 10 μm.
1 . Electrochromic glass component according to claim 13, characterised in that a metallic electrode layer forms a reflector which may accept and conduct protons at the same time.
15. Electrochromic glass component according to at least one of claims 1 to 14, characterised in that the ion-delivering and ion-storing layer is present in the form of a composite.
16. Electrochromic glass component according to claim 15, characterised in that the composite consists of a substrate, for example of glass, metal or plastic, for example a polyester film, to which a proto -storing layer, for example a metal oxide layer, is applied.
17. Electrochromic glass component according to claim 16, characterised in that the composite additionally has an electrode layer in the form of metallisation.
18. Electrochromic glass component according to at least one of claims 1 to 17, characterised in that an electrochromic layer, metallisation as a reflector, a proton-conducting membrane and a composite of a proton-storing layer, metallisation and a film arranged thereon, in particular of polyester, is applied to a glass substrate one after another, seen in the viewing direction.
19. Electrochromic glass component according to claim 18, characterised in that the layer system is sealed at the end-faces,
20. Electrochromic glass component according to claim 18 or 19, layer characterised in that the final opposite the glass substrate is provided with a protective layer.
21. Electrochromic glass component according to one of claims 19 or 20, characterised in that a reflection-reducing thin glass having a layer thickness of 0.3 to 3 mm is used as the glass substrate.
2. Electrochromic glass component according to one of claims 19 to 21, characterised in that a conductive layer for heating the mirror is applied in front of the substrate, seen in the viewing direction.
PCT/EP1999/008572 1998-11-10 1999-11-09 Electrochromic glass component WO2000028374A1 (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
JP2000581499A JP2002529794A (en) 1998-11-10 1999-11-09 Electrochromic glass components
AU12697/00A AU1269700A (en) 1998-11-10 1999-11-09 Electrochromic glass component
SK598-2001A SK5982001A3 (en) 1998-11-10 1999-11-09 Electrochromic glass component
AT99955960T ATE232989T1 (en) 1998-11-10 1999-11-09 ELECTROCHROMIC GLASS PART
EP99955960A EP1129387B1 (en) 1998-11-10 1999-11-09 Electrochromic glass component
BR9915189-8A BR9915189A (en) 1998-11-10 1999-11-09 Electrochromic glass component
CA002350144A CA2350144A1 (en) 1998-11-10 1999-11-09 Electrochromic glass component
KR1020017005927A KR20010092729A (en) 1998-11-10 1999-11-09 Electrochromic glass component
PL99348203A PL348203A1 (en) 1998-11-10 1999-11-09 Electrochromic glass component
US09/831,535 US6563625B1 (en) 1998-11-10 1999-11-09 Electrochromic glass component
DE69905486T DE69905486T2 (en) 1998-11-10 1999-11-09 ELECTROCHROMIC GLASS PART
NO20012267A NO20012267L (en) 1998-11-10 2001-05-08 Electrochromatic glass component

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DE19851717A DE19851717A1 (en) 1998-11-10 1998-11-10 Electrochromic glass assembly
DE19851717.3 1998-11-10

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BR9915189A (en) 2001-10-30
PL348203A1 (en) 2002-05-06
CN1326561A (en) 2001-12-12
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NO20012267D0 (en) 2001-05-08
AU1269700A (en) 2000-05-29
DE69905486D1 (en) 2003-03-27
CA2350144A1 (en) 2000-05-18
US6563625B1 (en) 2003-05-13
DE19851717A1 (en) 2000-06-15
DE69905486T2 (en) 2003-09-11
NO20012267L (en) 2001-07-10
JP2002529794A (en) 2002-09-10
ES2192869T3 (en) 2003-10-16
ATE232989T1 (en) 2003-03-15
SK5982001A3 (en) 2001-12-03
TR200101274T2 (en) 2001-10-22
CZ20011636A3 (en) 2001-09-12
EP1129387B1 (en) 2003-02-19
EP1129387A1 (en) 2001-09-05
KR20010092729A (en) 2001-10-26

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