US3609089A - Process for cleaning road vehicles and composition - Google Patents
Process for cleaning road vehicles and composition Download PDFInfo
- Publication number
- US3609089A US3609089A US662300A US3609089DA US3609089A US 3609089 A US3609089 A US 3609089A US 662300 A US662300 A US 662300A US 3609089D A US3609089D A US 3609089DA US 3609089 A US3609089 A US 3609089A
- Authority
- US
- United States
- Prior art keywords
- parts
- weight
- cleaning
- composition
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 56
- 238000004140 cleaning Methods 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 23
- 230000008569 process Effects 0.000 title claims abstract description 21
- -1 alkylbenzene sulfonate Chemical class 0.000 claims abstract description 25
- 230000003165 hydrotropic effect Effects 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 5
- 235000011180 diphosphates Nutrition 0.000 claims description 4
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 abstract description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 6
- 239000010452 phosphate Substances 0.000 abstract description 6
- 229910001514 alkali metal chloride Inorganic materials 0.000 abstract description 5
- 239000007864 aqueous solution Substances 0.000 abstract description 5
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 150000002191 fatty alcohols Chemical class 0.000 abstract description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 15
- 239000011734 sodium Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 229910052708 sodium Inorganic materials 0.000 description 11
- 229910052783 alkali metal Inorganic materials 0.000 description 9
- 150000001340 alkali metals Chemical class 0.000 description 6
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 230000009471 action Effects 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Inorganic materials [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- IVSZLXZYQVIEFR-UHFFFAOYSA-N 1,3-Dimethylbenzene Natural products CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 2
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000002274 desiccant Substances 0.000 description 2
- 125000001924 fatty-acyl group Chemical group 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 229910052913 potassium silicate Inorganic materials 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 235000019795 sodium metasilicate Nutrition 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 2
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical class [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- ZQCUDFIHJAXGTP-KVVVOXFISA-N (z)-octadec-9-enoic acid;sodium Chemical compound [Na].CCCCCCCC\C=C/CCCCCCCC(O)=O ZQCUDFIHJAXGTP-KVVVOXFISA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000013175 Crataegus laevigata Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- XDRMBCMMABGNMM-UHFFFAOYSA-N ethyl benzenesulfonate Chemical compound CCOS(=O)(=O)C1=CC=CC=C1 XDRMBCMMABGNMM-UHFFFAOYSA-N 0.000 description 1
- 125000005313 fatty acid group Chemical group 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229940005740 hexametaphosphate Drugs 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- URLKBWYHVLBVBO-UHFFFAOYSA-N p-dimethylbenzene Natural products CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003109 potassium Chemical class 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 235000013966 potassium salts of fatty acid Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- YQZZXXKFKTWDPY-UHFFFAOYSA-N propan-2-yl benzenesulfonate Chemical class CC(C)OS(=O)(=O)C1=CC=CC=C1 YQZZXXKFKTWDPY-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000013875 sodium salts of fatty acid Nutrition 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- FODHIQQNHOPUKH-UHFFFAOYSA-N tetrapropylene-benzenesulfonic acid Chemical compound CC1CC11C2=C3S(=O)(=O)OC(C)CC3=C3C(C)CC3=C2C1C FODHIQQNHOPUKH-UHFFFAOYSA-N 0.000 description 1
- 235000019798 tripotassium phosphate Nutrition 0.000 description 1
- 229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- GDJZZWYLFXAGFH-UHFFFAOYSA-M xylenesulfonate group Chemical group C1(C(C=CC=C1)C)(C)S(=O)(=O)[O-] GDJZZWYLFXAGFH-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines
Definitions
- This invention relates to a process for cleaning road film from automobiles, trucks, buses and the like with a dilute aqueous solution of a cleaning composition and to the cleaning composition.
- the process of this invention is a method for cleaning road film from road vehicles comprising the steps of applying an aqueous solution of from 0.1 to 2 oz./gal. of an inventive cleaning composition per gallon of water to the surface to be cleaned, and rinsing this surface with water.
- the cleaning composition comprises from 15-90 parts by weight of an alkali metal condensed phosphate; from 2-40 parts by weight of an alkaline builder selected from the group consisting of alkali metal phosphates, silicates, carbonates, and mixtures thereof; from 5-60 parts by weight of an alkali metal chloride; from 1-25 parts by weight of an alkylbenzene sulfonate having from 8-18 carbons in the alkyl group; from lparts by weight of a member selected from the group consisting of fatty amido amine complex salts, fatty lower alkanolamides, and mixtures thereof; from 1-10 parts by weight of a member selected from a group consisting of polyethoxylated fatty alcohols having from 1-30 ethoxy groups, polyethoxylated alkylphenols having from 8-9 carbons in the alkyl group and from 1-30 ethoxy groups, and mixtures thereof; and from l-30 parts by weight of hydrotropic agent selected from the group consisting of alkali
- the object of this invention is to provide a method for effectively cleaning road films from the surfaces of road vehicles, and to provide a more effective composition for this process. It is another object of this invention to provide a process for cleaning road vehicle surfaces with a composition containing components which cooperate to effect a greatly improved cleaning action.
- the process of this invention comprises applying an aqueous cleaning solution containing from 0.1 to 2 oz. per gallon of water and preferably from 0.05 to 0.5 oz. per gallon of water of a cleaning composition to dirty surfaces of road vehicles and trucks, and rinsing these surfaces with water.
- the cleaning solution can be applied to the vehicle surfaces by hand, with or without a rubbing action, but is preferably applied with a pressurized spray apparatus.
- a concentrated aqueous solution of the cleaning composition can be mixed with water sprayed from a pressure hose system using conventional and well-known equipment. In such equipment, the liquid cleaner concentrate can be siphoned or pumped into the water stream immediately before it leaves the spray nozzle.
- High-pressure spraying is preferred because the impact of the liquid on the surface to be cleaned assists in removing film materials from the surfaces.
- Rinsing is also preferably accomplished with a water spray.
- the process of this invention can also be accomplished in automatic vehicle-cleaning systems such as car or bus wash systems and the like.
- the cleaning composition of this invention contains from 15-90 and preferably -40 parts by weight of an alkali-metal.
- Suitable phosphates include' the sodium and potassium tripolyphosphates, tetrasodium and tetrapotassium pyrophosphates, and sodium and potassium hexametaphosphates.
- the cleaning composition preferably contains from 20-40 parts by weight of an alkali metal pyrophosphate and from l-30 parts by weight of an alkali metal tripolyphosphate.
- the cleaning composition also contains from 2-40 and preferably from 5-30 parts by weight of an alkaline builder such as alkali metal phosphates, silicates, carbonates, and the like. Suitable builders are trisodium and tripotassium phosphate, sodium and potassium silicates and in particular sodium or potassium metasilicate, sodium or potassium carbonate, and mixtures thereof.
- the cleaning composition contains from 5-20 percent sodium phosphate, and up to 15 percent sodium carbonate for optimum cleaning action.
- These alkaline builders provide the pH conditions in the cleaning solution at which the other components provide the increased cleaning action characteristic of the process and composition of this invention.
- the composition of this invention contains from 5-60 and preferably from 10-30 parts by weight of an alkali metal chloride such as sodium or potassium chloride.
- alkali metal chlorides are not ordinarily considered to have any significant cleaning activity, it has been found that in the unique composition of this invention, they function to provide a greatly increased overall cleaning activity.
- composition of this invention also contains from l-25 and preferably from 5-15 parts by weight of an alkyl benzene sulfonate having from 8-18 carbons in the alkyl group.
- alkylbenzene sulfonates include the tetrapropylene benzene sulfonate and linear alkylbenzene sulfonates having about 12 carbons in the alkyl group, the latter being preferred because they are biodegradable and do not create disposal problems.
- the composition also contains from 1-15 and preferably from l-5 parts per weight of a surfactant such as fatty amido amine complexes, alkali metal and preferably potassium salts, sold under the trade name Carbon Detergent K Modified, by Textilana Corp. of Hawthorne, California, and fatty lower alkanolamides having from 8-18 carbons, preferably from 12 to 16 carbons, in the fatty acyl group and from l-3, preferably 2, carbons in the lower alkanol group.
- a surfactant such as fatty amido amine complexes, alkali metal and preferably potassium salts, sold under the trade name Carbon Detergent K Modified, by Textilana Corp. of Hawthorne, California
- fatty lower alkanolamides having from 8-18 carbons, preferably from 12 to 16 carbons, in the fatty acyl group and from l-3, preferably 2, carbons in the lower alkanol group.
- the preferred fatty lower alkanol amide is
- the composition of this invention contains from l-lO and preferably from l-5 parts by weight of a polyethoxylated compound such as polyethoxylated fatty alcohols having from 8-18 carbons in the fatty alkyl group and having from l-30 ethoxy groups and polyethoxylated alkylphenols having from 8-9 carbons in the alkyl group and from l-30 ethoxy groups.
- a polyethoxylated compound such as polyethoxylated fatty alcohols having from 8-18 carbons in the fatty alkyl group and having from l-30 ethoxy groups and polyethoxylated alkylphenols having from 8-9 carbons in the alkyl group and from l-30 ethoxy groups.
- the cleaning composition also contains from 1-30 and preferably from l-lO parts by weight of a hydrotropic agent which functions, notonly as a coupling agent to maintain the components in solution, but also to provide additional wetting activity and reduction of surface tension in the cleaning compositions.
- Suitable hydrotropic agents include the alkali metal (sodium and potassium) salts of fatty acid sulfonates having from 8-18 carbons in the fatty acid group, and lower alkylbenzene sulfonate having from l-3 carbons in a lower alkyl group.
- the preferred fatty acid sulfonate is the sodium salt of oleic acid sulfonate or myristic acid sulfonate.
- the preferred lower alkylbenzene sulfonates include xylene, toluene, ethylbenzene, and isopropylbenzene sulfonates.
- Sulfonates made from xylene include orthoxylene sulfonate, metaxylene sulfonate, paraxylene sulfonate, and ethylbenzene sulfonate.
- Commercial xylene sulfonates usually contain metaxylene sulfonate as the main ingredient.
- the cleaning composition of this invention is preferably for- .mulated as a dry, anhydrous composition. Therefore, fillers such as sodium sulfate and desiccants. such as calcium silicate, silica gel, and the like can be added in sufficient concentrations to provide a noncaking powder composition. Desiccant concentrations of from l-3 parts by weight are usually sufficient to prevent caking.
- composition of this invention may conveniently be phosphate selected from the group consisting of sodium or potassium tripolyphosphate: tetrasodium or tetrapotassium pyrophosphate, and sodium or potassium hexametaphosphate;
- Solution concentrates containthe group consisting of trisodium or tripotassium ing from 0.5 to 40 oz. per gallon of water can be easily phosphate; sodium or potassium metasilicate; and sodium prepared from the composition of this invention. or potassium carbonate;
- the process and composition of this invention are effective c. 5-60 parts by weight of an alkali metal chloride, selected to remove road film from automobiles, trucks, buses and other from the group consisting of sodium or potassium road vehicles by conventional cleaning processes.
- an alkali metal chloride selected to remove road film from automobiles, trucks, buses and other from the group consisting of sodium or potassium road vehicles by conventional cleaning processes.
- a very parchloride; ticular cooperation of the ingredients in the composition of d. l-25 parts by weight of an alkylbenzene sulfonate having this invention exists at the pH level provided by the alkaline from 8-18 carbons in the alkyl group; builders. With the essential cooperation of the alkali metal e.
- the invention is further illustrated by the following specific g, 1-30 art by weight of a hydrotropic agent selected from but nonlimiting example. the group consisting of sodium or potassium salts of fatty acid sulfonates; and lower alkylbenzene sulfonates having EXAMPLE from l-3 carbons in the lower alkyl group; and rinsing the
- a hydrotropic agent selected from but nonlimiting example. the group consisting of sodium or potassium salts of fatty acid sulfonates; and lower alkylbenzene sulfonates having EXAMPLE from l-3 carbons in the lower alkyl group; and rinsing the
- the following cleaning compositions in concentrations of vehlcle Surfaces water' from 0.25 to 0.5 oz. per gallon of water have been found to 2.
- the process of claim 1 wherein the cleaning composition provide exceptional cleaning of road films from outer surfaces contains from 20-40 parts by weight of said pyrophosphate of road vehicles when sprayed against these surfaces. These and
- a process for cleaning road film from road vehicles which comprises the steps of applying to the surfaces to be cleaned an aqueous solution of from 0.1 to 2 oz. per gallon of water of a cleaning composition consisting of:
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Process for cleaning road film from road vehicles with a dilute aqueous solution of a cleaning composition. The cleaning composition is a mixture of 15-90 parts condensed phosphate, 2-40 parts alkaline builder, 5-60 parts alkali metal chloride, 1-25 parts higher alkylbenzene sulfonate, 1-15 parts of fatty lower alkanolamides, 1-10 parts polyethyoxylated fatty alcohols or alkylphenols, and 1-30 parts of a hydrotropic agent.
Description
United States Patent [72] Inventors Clifford M. Cantrell Cincinnati, Ohio; David P. MacDonald, Ludlow, Ky.; Millard J. Laugle, Cincinnati, Ohio [2]] Appl. No. 662,300 [22] Filed Aug. 22, 1967 [45) Patented Sept. 28,1971 [73] Auulgnea W. R. Grace 8: Co.
New York, N.Y.
[54] PROCESS FOR CLEANING ROAD VEHICLES AND COMPOSITION 5 Claims, No Drawings [52] [1.8. CI 252/137, 252/152, 134/2, 134/6, 134/32, 134/36, 134/42 [51] 1nt.(l Cllcl H22 50 Field 6: Search 252/137; 134/2, 6, 29, 32, 36
[56] References Cited UNITED STATES PATENTS 2,044,246 6/1936 Johnson 252/89 2,846,402 8/1958 Lew 252/152 2,920,045 1/ 1960 l-learn et a1. 252/137 2,956,026 10/1960 Lew 252/137 X 3,075,922 1/1963 Wixon 252/137 X 3,122,508 2/1964 Grifo et al 252/137 X 3,151,084 9/1964 Schiltz et a1. 252/152 X 3,232,880 l/l966 Mausner et al.. 252/137 3,393,154 7/1968 Treitlcr 252/152 X OTHER REFERENCES Soap 8: Chemical Specialties 1 July 1962-p. 159 Soap & Chemical Specialties (2) January 1965-p. 163
Primary Examiner--Leon D. Rosdol Assistant Examiner-M. Halpem Attorneys-William B. Walker and Kenneth E. Prince PROCESS FOR CLEANING ROAD VEHICLES AND COMPOSITION This invention relates to a process for cleaning road film from automobiles, trucks, buses and the like with a dilute aqueous solution of a cleaning composition and to the cleaning composition.
In summary, the process of this invention is a method for cleaning road film from road vehicles comprising the steps of applying an aqueous solution of from 0.1 to 2 oz./gal. of an inventive cleaning composition per gallon of water to the surface to be cleaned, and rinsing this surface with water. The cleaning composition comprises from 15-90 parts by weight of an alkali metal condensed phosphate; from 2-40 parts by weight of an alkaline builder selected from the group consisting of alkali metal phosphates, silicates, carbonates, and mixtures thereof; from 5-60 parts by weight of an alkali metal chloride; from 1-25 parts by weight of an alkylbenzene sulfonate having from 8-18 carbons in the alkyl group; from lparts by weight of a member selected from the group consisting of fatty amido amine complex salts, fatty lower alkanolamides, and mixtures thereof; from 1-10 parts by weight of a member selected from a group consisting of polyethoxylated fatty alcohols having from 1-30 ethoxy groups, polyethoxylated alkylphenols having from 8-9 carbons in the alkyl group and from 1-30 ethoxy groups, and mixtures thereof; and from l-30 parts by weight of hydrotropic agent selected from the group consisting of alkali metal salts of fatty acid sulfonates, lower alkylbenzene sulfonates having 1-3 carbons in the lower alkyl group, and mixtures thereof.
Much effort has been made in recent years to develop cleaning compositions which, by spray application or the like to automobile, bus, or truck surfaces, would effectively remove road film from these vehicles. The road film is a diverse mixture of dirt, fuel and lubricant residues, soot and other materials which settle on the vehicle from the air or are picked up from roads; it resists the cleaning action of many detergent compositions. Because the detergent composition must not deteriorate the paint surface on the trucks and automobiles or corrode exposed metal components thereof, the highly alkaline or acidic detergent compositions normally used to remove greases and the like from metal parts cannot be safely used.
The object of this invention is to provide a method for effectively cleaning road films from the surfaces of road vehicles, and to provide a more effective composition for this process. It is another object of this invention to provide a process for cleaning road vehicle surfaces with a composition containing components which cooperate to effect a greatly improved cleaning action.
The process of this invention comprises applying an aqueous cleaning solution containing from 0.1 to 2 oz. per gallon of water and preferably from 0.05 to 0.5 oz. per gallon of water of a cleaning composition to dirty surfaces of road vehicles and trucks, and rinsing these surfaces with water. The cleaning solution can be applied to the vehicle surfaces by hand, with or without a rubbing action, but is preferably applied with a pressurized spray apparatus. For example, a concentrated aqueous solution of the cleaning composition can be mixed with water sprayed from a pressure hose system using conventional and well-known equipment. In such equipment, the liquid cleaner concentrate can be siphoned or pumped into the water stream immediately before it leaves the spray nozzle. High-pressure spraying is preferred because the impact of the liquid on the surface to be cleaned assists in removing film materials from the surfaces. Rinsing is also preferably accomplished with a water spray. The process of this invention can also be accomplished in automatic vehicle-cleaning systems such as car or bus wash systems and the like.
All concentrations are herein given as parts by weight or weight percents unless otherwise indicated.
The cleaning composition of this invention contains from 15-90 and preferably -40 parts by weight of an alkali-metal.
condensed phosphate. Suitable phosphates include' the sodium and potassium tripolyphosphates, tetrasodium and tetrapotassium pyrophosphates, and sodium and potassium hexametaphosphates. The cleaning composition preferably contains from 20-40 parts by weight of an alkali metal pyrophosphate and from l-30 parts by weight of an alkali metal tripolyphosphate.
The cleaning composition also contains from 2-40 and preferably from 5-30 parts by weight of an alkaline builder such as alkali metal phosphates, silicates, carbonates, and the like. Suitable builders are trisodium and tripotassium phosphate, sodium and potassium silicates and in particular sodium or potassium metasilicate, sodium or potassium carbonate, and mixtures thereof. The cleaning composition contains from 5-20 percent sodium phosphate, and up to 15 percent sodium carbonate for optimum cleaning action. These alkaline builders provide the pH conditions in the cleaning solution at which the other components provide the increased cleaning action characteristic of the process and composition of this invention.
As a critical ingredient, the composition of this invention contains from 5-60 and preferably from 10-30 parts by weight of an alkali metal chloride such as sodium or potassium chloride. Although alkali metal chlorides are not ordinarily considered to have any significant cleaning activity, it has been found that in the unique composition of this invention, they function to provide a greatly increased overall cleaning activity.
The composition of this invention also contains from l-25 and preferably from 5-15 parts by weight of an alkyl benzene sulfonate having from 8-18 carbons in the alkyl group. Suitable alkylbenzene sulfonates include the tetrapropylene benzene sulfonate and linear alkylbenzene sulfonates having about 12 carbons in the alkyl group, the latter being preferred because they are biodegradable and do not create disposal problems.
The composition also contains from 1-15 and preferably from l-5 parts per weight of a surfactant such as fatty amido amine complexes, alkali metal and preferably potassium salts, sold under the trade name Carbon Detergent K Modified, by Textilana Corp. of Hawthorne, California, and fatty lower alkanolamides having from 8-18 carbons, preferably from 12 to 16 carbons, in the fatty acyl group and from l-3, preferably 2, carbons in the lower alkanol group. The preferred fatty lower alkanol amide is the fatty ethanol amide.
As an auxiliary surfactant which cooperates with the other surfactants in the composition of this invention to provide increased cleaning, the composition of this invention contains from l-lO and preferably from l-5 parts by weight of a polyethoxylated compound such as polyethoxylated fatty alcohols having from 8-18 carbons in the fatty alkyl group and having from l-30 ethoxy groups and polyethoxylated alkylphenols having from 8-9 carbons in the alkyl group and from l-30 ethoxy groups.
The cleaning composition also contains from 1-30 and preferably from l-lO parts by weight of a hydrotropic agent which functions, notonly as a coupling agent to maintain the components in solution, but also to provide additional wetting activity and reduction of surface tension in the cleaning compositions. Suitable hydrotropic agents include the alkali metal (sodium and potassium) salts of fatty acid sulfonates having from 8-18 carbons in the fatty acid group, and lower alkylbenzene sulfonate having from l-3 carbons in a lower alkyl group. The preferred fatty acid sulfonate is the sodium salt of oleic acid sulfonate or myristic acid sulfonate. The preferred lower alkylbenzene sulfonates include xylene, toluene, ethylbenzene, and isopropylbenzene sulfonates. Sulfonates made from xylene include orthoxylene sulfonate, metaxylene sulfonate, paraxylene sulfonate, and ethylbenzene sulfonate. Commercial xylene sulfonates usually contain metaxylene sulfonate as the main ingredient.
The cleaning composition of this invention is preferably for- .mulated as a dry, anhydrous composition. Therefore, fillers such as sodium sulfate and desiccants. such as calcium silicate, silica gel, and the like can be added in sufficient concentrations to provide a noncaking powder composition. Desiccant concentrations of from l-3 parts by weight are usually sufficient to prevent caking.
The composition of this invention may conveniently be phosphate selected from the group consisting of sodium or potassium tripolyphosphate: tetrasodium or tetrapotassium pyrophosphate, and sodium or potassium hexametaphosphate;
mixed with water to form a solution concentrate for liquid b. 2-40 parts by weight of an alkaline builder selected from feeding in cleaning equipment. Solution concentrates containthe group consisting of trisodium or tripotassium ing from 0.5 to 40 oz. per gallon of water can be easily phosphate; sodium or potassium metasilicate; and sodium prepared from the composition of this invention. or potassium carbonate;
The process and composition of this invention are effective c. 5-60 parts by weight of an alkali metal chloride, selected to remove road film from automobiles, trucks, buses and other from the group consisting of sodium or potassium road vehicles by conventional cleaning processes. A very parchloride; ticular cooperation of the ingredients in the composition of d. l-25 parts by weight of an alkylbenzene sulfonate having this invention exists at the pH level provided by the alkaline from 8-18 carbons in the alkyl group; builders. With the essential cooperation of the alkali metal e. l-l5 parts by weight of fatty acid lower alkanol amides chloride, higher alkylbenzene sulfonate, and the combinations having from 8-18 carbons in the fatty acyl group and l-3 of surfactants disclosed above, a far more effective removal of carbons in the lower alkanol group, road film is obtained than has heretofore been obtained with f, 1-10 arts by weight of a member selected from the group cleaning compositions for road vehicles. The process of this on isting of polyethoxylated higher fatty alcohols having invention, because of the particular cleaning composition infrom 1-30 ethoxy groups polyethoxylated alkylphenols gredients, does not harm painted surfaces or cause corrosion having from 8-9 carbons in the alkyl group and from of the metal surfaces being cleaned. l-30 ethoxy groups; and
The invention is further illustrated by the following specific g, 1-30 art by weight of a hydrotropic agent selected from but nonlimiting example. the group consisting of sodium or potassium salts of fatty acid sulfonates; and lower alkylbenzene sulfonates having EXAMPLE from l-3 carbons in the lower alkyl group; and rinsing the The following cleaning compositions in concentrations of vehlcle Surfaces water' from 0.25 to 0.5 oz. per gallon of water have been found to 2. The process of claim 1 wherein the cleaning composition provide exceptional cleaning of road films from outer surfaces contains from 20-40 parts by weight of said pyrophosphate of road vehicles when sprayed against these surfaces. These and from lparts by weight of said tripolyphosphate. superior compositions are shown in table A. 30 3. The process of claim 1 wherein the cleaning composition TABLE A Weight percent Composition No l 2 3 4 5 6 7 5 9 'li-trusodium pyrophosphate 35, 0 34. 0 25. 0 25. 0 25. O 37.0 0. 0 5 1m 0 Sodium earb0natn l 10.0 9.0 5.0 5. 0 15.9 (lui'hon detergent K modified. 3. 0 2.0 2. 0 4 0 5 0 0 Sodium tripolyphosphato A H 20. 0 20. O 20. O 20. 0 -0 0 90. 0 0 0 Tenor-55cc sulionato 0A-5, sodium oleic acid sulfonate sa]t 2.0 4. 5 4. 5 4. 5 0 Z 0 34 0 U Ti'isodlum phosphate, anhydrous v 10. 0 10. 0 10. 0 l0. 0 0 r 0 Higher fatty othanolamide l .4 3.0 U. 5 (.Zm'boxano 'IW-lOO, fatty alcohol ethoxylate t t 2 0 l. 5 2 0 1 0 4 5 0 l repal L0 730, polycthoxylated nonyl phenol 1 v t t t t 1.5 5 Sodium chloride 18,5 18,5 17.0 17. 5 20.0 20. 0 5 5 Linear sodlium dotlecyl benzene sulfonato S. 0 8.0 8. 0 8.0 0 94 0 0 5 Silent: EF, calcium silicate 1. 5 l. 5 1. 5 1. 5 0 0r 5 5 I N onylphcnol plus 15 moles ethylene oxide.
Obviously many modifications and variations of the invention as hereinabove set forth can be made without departing from the essence and scope thereof, and only such limitations should be applied as are indicated in the claims.
The invention claimed is: l. A process for cleaning road film from road vehicles which comprises the steps of applying to the surfaces to be cleaned an aqueous solution of from 0.1 to 2 oz. per gallon of water of a cleaning composition consisting of:
a. 15-90 parts by weight of an alkali metal condensed
Claims (3)
- 2. The process of claim 1 wherein the cleaning composition contains from 20-40 parts by weight of said pyrophosphate and from 1-30 parts by weight of said tripolyphosphate. 3. The process of claim 1 wherein the cleaning composition contains from 5-30 percent by weight of said alkaline builder.
- 4. The process of claim 1 wherein the cleaning composition contains from 10-30 parts by weight of said chloride.
- 5. The process of claim 1 wherein the cleaning composition contains from 5-15 parts by weight of said alkylbenzene sulfonate having from 8-18 carbons in the alkyl group; from 1-5 parts by weight of said (e) member; from 1-5 parts by weight of said (f) member; and from 1-10 parts by weight of said hydrotropic agent.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US66230067A | 1967-08-22 | 1967-08-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3609089A true US3609089A (en) | 1971-09-28 |
Family
ID=24657183
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US662300A Expired - Lifetime US3609089A (en) | 1967-08-22 | 1967-08-22 | Process for cleaning road vehicles and composition |
Country Status (1)
Country | Link |
---|---|
US (1) | US3609089A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4040989A (en) * | 1973-05-25 | 1977-08-09 | Colgate-Palmolive Company | Liquid detergent |
US4670171A (en) * | 1985-02-26 | 1987-06-02 | Pennzoil Company | Surface cleaner composition |
US4683008A (en) * | 1985-07-12 | 1987-07-28 | Sparkle Wash, Inc. | Method for cleaning hard surfaces |
WO1992015660A1 (en) * | 1991-03-08 | 1992-09-17 | Henkel Kommanditgesellschaft Auf Aktien | Liquid detergent containing di-salts of sulfo-oleic acid |
US5391325A (en) * | 1993-09-29 | 1995-02-21 | Exxon Chemical Patents Inc. | Non-toxic biodegradable emulsion compositions for use in automatic car washes |
US5865851A (en) * | 1996-03-07 | 1999-02-02 | Reckitt & Colman Inc. | Home dry cleaning compositions |
US20040261887A1 (en) * | 2003-06-26 | 2004-12-30 | William Lewis | Mixing apparatus and methods using the same |
US20040266658A1 (en) * | 2003-06-26 | 2004-12-30 | Lenhart John G. | Cleaning formulations and methods for manufacturing the same |
US20050176608A1 (en) * | 2002-06-07 | 2005-08-11 | Coley Paul S. | Compositions for use in vehicle wash |
US20060223736A1 (en) * | 2005-03-30 | 2006-10-05 | R. Lewis Technologies, Inc. | Dye and scent pouches and methods of making the same |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2044246A (en) * | 1932-11-23 | 1936-06-16 | Frank R Johnson | Cleaning composition |
US2846402A (en) * | 1958-08-05 | Alkyl sulfate detergent compositions | ||
US2920045A (en) * | 1955-09-06 | 1960-01-05 | Colgate Palmolive Co | Heavy duty liquid detergent compositions |
US2956026A (en) * | 1955-03-22 | 1960-10-11 | California Research Corp | Sulfonate detergent compositions |
US3075922A (en) * | 1957-08-01 | 1963-01-29 | Colgate Palmolive Co | Prepartion of liquid detergent compositions |
US3122508A (en) * | 1960-07-28 | 1964-02-25 | Gen Aniline & Film Corp | Heavy duty detergent compositions |
US3151084A (en) * | 1961-03-13 | 1964-09-29 | Swift & Co | Solubilizer for synthetic detergent |
US3232880A (en) * | 1961-04-10 | 1966-02-01 | Ultra Chemical Works Inc | Liquid detergent composition |
US3393154A (en) * | 1965-10-23 | 1968-07-16 | Colgate Palmolive Co | Pearlescent liquid detergent compositions |
-
1967
- 1967-08-22 US US662300A patent/US3609089A/en not_active Expired - Lifetime
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2846402A (en) * | 1958-08-05 | Alkyl sulfate detergent compositions | ||
US2044246A (en) * | 1932-11-23 | 1936-06-16 | Frank R Johnson | Cleaning composition |
US2956026A (en) * | 1955-03-22 | 1960-10-11 | California Research Corp | Sulfonate detergent compositions |
US2920045A (en) * | 1955-09-06 | 1960-01-05 | Colgate Palmolive Co | Heavy duty liquid detergent compositions |
US3075922A (en) * | 1957-08-01 | 1963-01-29 | Colgate Palmolive Co | Prepartion of liquid detergent compositions |
US3122508A (en) * | 1960-07-28 | 1964-02-25 | Gen Aniline & Film Corp | Heavy duty detergent compositions |
US3151084A (en) * | 1961-03-13 | 1964-09-29 | Swift & Co | Solubilizer for synthetic detergent |
US3232880A (en) * | 1961-04-10 | 1966-02-01 | Ultra Chemical Works Inc | Liquid detergent composition |
US3393154A (en) * | 1965-10-23 | 1968-07-16 | Colgate Palmolive Co | Pearlescent liquid detergent compositions |
Non-Patent Citations (2)
Title |
---|
Soap & Chemical Specialties (1) July 1962-p. 159 * |
Soap & Chemical Specialties (2) January 1965-p. 163 * |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4040989A (en) * | 1973-05-25 | 1977-08-09 | Colgate-Palmolive Company | Liquid detergent |
US4670171A (en) * | 1985-02-26 | 1987-06-02 | Pennzoil Company | Surface cleaner composition |
US4683008A (en) * | 1985-07-12 | 1987-07-28 | Sparkle Wash, Inc. | Method for cleaning hard surfaces |
WO1992015660A1 (en) * | 1991-03-08 | 1992-09-17 | Henkel Kommanditgesellschaft Auf Aktien | Liquid detergent containing di-salts of sulfo-oleic acid |
US5391325A (en) * | 1993-09-29 | 1995-02-21 | Exxon Chemical Patents Inc. | Non-toxic biodegradable emulsion compositions for use in automatic car washes |
WO1995009223A1 (en) * | 1993-09-29 | 1995-04-06 | Tomah Products, Inc. | Non-toxic biodegradable emulsion compositions for use in automatic car washes |
US5865851A (en) * | 1996-03-07 | 1999-02-02 | Reckitt & Colman Inc. | Home dry cleaning compositions |
US20050176608A1 (en) * | 2002-06-07 | 2005-08-11 | Coley Paul S. | Compositions for use in vehicle wash |
US7524802B2 (en) * | 2002-06-07 | 2009-04-28 | Autoglym | Compositions for use in vehicle wash comprising a micro-organism |
US20040266658A1 (en) * | 2003-06-26 | 2004-12-30 | Lenhart John G. | Cleaning formulations and methods for manufacturing the same |
US20040264295A1 (en) * | 2003-06-26 | 2004-12-30 | William Lewis | Mixing apparatus |
US7140405B2 (en) | 2003-06-26 | 2006-11-28 | Relevant Engineering Development | Mixing apparatus |
US20040261887A1 (en) * | 2003-06-26 | 2004-12-30 | William Lewis | Mixing apparatus and methods using the same |
US7530373B2 (en) | 2003-06-26 | 2009-05-12 | R. Lewis Technologies, Inc. | Mixing apparatus and methods using the same |
US8210215B2 (en) | 2003-06-26 | 2012-07-03 | R. Lewis Technologies, Inc. | Mixing apparatus and methods of using the same |
US8905088B2 (en) | 2003-06-26 | 2014-12-09 | R. Lewis Technologies, Inc. | Mixing apparatus and methods of using the same |
US20060223736A1 (en) * | 2005-03-30 | 2006-10-05 | R. Lewis Technologies, Inc. | Dye and scent pouches and methods of making the same |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA1149255A (en) | Spray cleaner for transportation vehicle bodies | |
US3993575A (en) | Hard surface acid cleaner and brightener | |
AU707778B2 (en) | Wheel cleaning composition containing acid fluoride salts | |
US3609089A (en) | Process for cleaning road vehicles and composition | |
CN102703248B (en) | Wipe-free environment-friendly vehicle cleanser and preparation and use methods | |
US4032466A (en) | Acid cleaner and process for disposal thereof | |
US2802788A (en) | Cleaning composition for automotive | |
US3634338A (en) | Method and composition for cleaning aluminum magnesiumand alloys thereof | |
US4670171A (en) | Surface cleaner composition | |
EP0479888B1 (en) | Improved builder-containing aqueous cleaner/degreaser microemulsion compositions | |
US4472205A (en) | Method for cleaning various surfaces of a single article | |
DE2000069A1 (en) | Process for the production of enzyme and perborate detergents | |
US20120208735A1 (en) | Hydrophobic and Particulate Soil Removal Composition | |
US3816351A (en) | Industrial car wash composition | |
US3985922A (en) | Process for washing paint overspray from air | |
US8808464B2 (en) | Method for removal of a hydrophobic and particulate soil composition | |
US4517025A (en) | Method for removing sealant contamination | |
US3010907A (en) | Alkaline cleaning compositions | |
US3870560A (en) | Silicate-and Hydroxide-containing cleaning compositions, and liquid concentrates for the preparation thereof | |
US4152306A (en) | Windshield cleaning solvent | |
US3723148A (en) | Process for recovering coating materials | |
KR100254533B1 (en) | Composition and process for cleaning tinplate stock | |
FI95151C (en) | Method of cleaning and degreasing, premix used in the method and cleaning agents | |
GB2134132A (en) | Vehicle cleaning compositions | |
JPS58191800A (en) | Detergent highly swellable by gas generation |