US20080142754A1

US20080142754A1 - 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone refrigerant compositions and uses thereof

Info

Publication number: US20080142754A1
Application number: US11/961,519
Authority: US
Inventors: Barbara Haviland Minor; Thomas J. Leck
Original assignee: Individual
Current assignee: Individual
Priority date: 2004-05-26
Filing date: 2007-12-20
Publication date: 2008-06-19
Also published as: US7094356B2; US7332103B2; US20060202155A1; US20050263738A1

Abstract

The present invention relates to compositions for use in refrigeration and air conditioning systems comprising 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and at least one chlorocarbon, alcohol, ketone, ether, ester, N-(difluoromethyl)-N,N-dimethylamine, 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane or mixtures thereof, and which are also useful in systems employing a centrifugal compressor The compositions of the present invention may be azeotropic or near azeotropic and are useful in processes for producing refrigeration or heat or as heat transfer fluids.

Description

CROSS REFERENCE(S) TO RELATED APPLICATION(S)

This application is a divisional application of pending application Ser. No. 11/437,051 filed May 19, 2006, which is a divisional of U.S. application Ser. No. 11/062,975 filed Feb. 22, 2005 now U.S. Pat. No. 7,094,356 issued Aug. 22, 2006, which claims the priority benefit of U.S. Provisional Application 60/575,037, filed May 26, 2004, and U.S. Provisional Application 60/584,785, filed Jun. 29, 2004.

BACKGROUND OF THE INVENTION

1. Field of the Invention
The present invention relates to compositions for use in refrigeration and air conditioning systems comprising 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone (PEIK) and at least one chlorocarbon, alcohol, ketone, ether, ester, N-(difluoromethyl)-N,N-dimethylamine, 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane or mixtures thereof. Further, the present invention relates to compositions for use in refrigeration and air-conditioning systems employing a centrifugal compressor comprising 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone (PEIK) and at least one chlorocarbon, alcohol, ketone, ether, ester, N-(difluoromethyl)-N,N-dimethylamine, perfluoro-N-methylmorpholine, 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane or combinations thereof. The compositions of the present invention may be azeotropic or near azeotropic and are useful in processes for producing refrigeration or heat or as heat transfer fluids.
2. Description of Related Art
The refrigeration industry has been working for the past few decades to find replacement refrigerants for the ozone depleting chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCS) being phased out as a result of the Montreal Protocol. The solution for most refrigerant producers has been the commercialization of hydrofluorocarbon (HFC) refrigerants. The new HFC refrigerants, HFC-134a being the most widely used at this time, have zero ozone depletion potential and thus are not affected by the current regulatory phase out as a result of the Montreal Protocol.
Further environmental regulations may ultimately cause global phase out of certain HFC refrigerants as well. Currently, the automobile industry is facing regulations relating to global warming potential for refrigerants used in mobile air-conditioning. Therefore, there is a great current need to identify new refrigerants with reduced global warming potential for the automobile air-conditioning market. Should the regulations be more broadly applied in the future, an even greater need will be felt for refrigerants that can be used in all areas of the refrigeration and air-conditioning industry.
Currently proposed replacement refrigerants for HFC-134a include HFC-152a, pure hydrocarbons such as butane or propane, or “natural” refrigerants such as CO₂or ammonia. Many of these suggested replacements are toxic, flammable, and/or have low energy efficiency. Therefore, new alternatives are constantly being sought.
The object of the present invention is to provide novel refrigerant compositions and heat transfer fluids that provide unique characteristics to meet the demands of low or zero ozone depletion potential and lower global warming potential as compared to current refrigerants.

BRIEF SUMMARY OF THE INVENTION

The present invention relates to compositions selected from the group consisting of:

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1-dichloroethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and trans-1,2-dichloroethylene;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and N-(difluoromethyl)-N,N-dimethylamine;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and acetone;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and diisopropyl ether;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,2-dimethoxyethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and dimethoxymethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1-dimethoxyethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and tert-butylmethyl ether;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methanol;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and ethanol;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and isopropanol;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and n-propanol;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and ethyl formate;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methyl acetate; and
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methyl formate.

The present invention further relates to the above listed compositions specifically for use in refrigeration or air conditioning systems including employing a centrifugal compressor.
The present invention further relates to the above listed compositions specifically for use in refrigeration or air conditioning systems employing a multistage or 2-stage centrifugal compressor.
The present invention further relates to the above listed compositions specifically for use in refrigeration or air conditioning systems employing a single pass/single slab heat exchanger.
The present invention further relates to azeotropic or near azeotropic refrigerant compositions. These compositions are useful in refrigeration or air conditioning systems. The compositions are also useful in refrigeration or air conditioning systems employing a centrifugal compressor.
The present invention further relates to processes for producing refrigeration, heat, and transfer of heat from a heat source to a heat sink using the present inventive compositions.

DETAILED DESCRIPTION OF THE INVENTION

Applicants specifically incorporate the entire contents of all cited references in this disclosure. Further, when an amount, concentration, or other value or parameter is given as either a range, preferred range, or a list of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. Where a range of numerical values is recited herein, unless otherwise stated, the range is intended to include the endpoints thereof, and all integers and fractions within the range. It is not intended that the scope of the invention be limited to the specific values recited when defining a range.
The refrigerant compositions of the present invention comprising 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone (PEIK) and at least one chlorocarbon, alcohol, ketone, ether, ester, N-(difluoromethyl)-N,N-dimethylamine, 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane or mixtures thereof. The refrigerant compositions of the present invention may comprise a mixture of PEIK with combinations of any of the listed components.
The refrigerant compositions of the present invention comprise compounds selected from chlorocarbons, alcohols, ethers, ketones, esters, N-(difluoromethyl)-N,N-dimethylamine, or 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane. Representative chlorocarbons, alcohols, ethers, ketones, and esters are listed in Table 1.
Representative compounds that may be components of the compositions of the present invention are listed in Table 1.

TABLE 1

			CAS Reg.
Compound	Chemical Formula	Chemical Name	No.

PEIK	CF₃CF₂C(O)CF(CF₃)₂	1,1,1,2,2,4,5,5,5-nonafluoro-4-	756-13-8
		(trifluoromethyl)-3-pentanone (or
		perfluoroethylisopropyl ketone)
	(CF₃)₃COH	Nonafluoro-tert-butanol	2378-02-1
	CH₃CHCl₂	1,1-dichloroethane	75-34-3
t-DCE	CHCl═CHCl	Trans-1,2-dichloroethylene	156-60-5
	(CH₃)₂C═O	acetone	67-64-1
	CH₃OC(CH₃)₃	tert-butyl methyl ether	1634-04-4
	(CH₃)₂CHOCH(CH₃)₂	diisopropyl ether	108-20-3
	CH₃OCH₂CH₂OCH₃	1,2-dimethoxyethane	110-71-9
	CH₃OCH₂OCH₃	dimethoxymethane	109-87-5
	(CH₃O)₂CHCH₃	1,1-dimethoxyethane	534-15-6
	CH₃OH	methanol	67-56-1
	CH₃CH₂OH	ethanol	64-17-5
	CH₃CH₂CH₂OH	n-propanol	71-23-8
	CH₃CHOHCH₃	isopropanol	67-63-0
	CH₃COOCH₂CH₃	ethyl acetate	141-78-6
	HCOOCH₂CH₃	ethyl formate	109-94-4
	CH₃COOCH₃	methyl acetate	79-20-9
	HCOOCH₃	methyl formate	107-31-3
	N(CH₃)₂(CHF₂)	N-(difluoromethyl)-N,N-dimethylamine	683-81-8
	CF₃CF₂SCF₂CF₃	1,1,1,2,2-pentafluoro-2-	155953-22-3
		[(pentafluoroethyl)thio]ethane

The compounds listed in Table 1 are available commercially (from chemical supply houses such as Aldrich, Milwaukee, Wis.) or may be prepared by processes known in the art. 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone (PEIK) is commercially available from 3M™ (St. Paul, Minn.).
Compositions of the present invention have low or zero ozone depletion potential and low global warming potential. For example, PEIK and the other compounds of the present invention, alone or in mixtures will have global warming potentials lower than many HFC refrigerants currently in use.
The compositions of the present invention that are mixtures may be prepared by any convenient method to combine the desired amounts of the individual components. A preferred method is to weigh the desired component amounts and thereafter combine the components in an appropriate vessel. Agitation may be used, if desired.
The refrigerant or heat transfer compositions of the present invention include:

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and N-(difluoromethyl)-N,N-dimethylamine;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1-dichloroethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and trans-1,2-dichloroethylene;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and acetone;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and diisopropyl ether;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,2-dimethoxyethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and dimethoxymethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1-dimethoxyethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and ethanol;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and ethyl formate;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and isopropanol;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methanol;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methyl acetate;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methyl formate;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and tert-butylmethyl ether; and
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and n-propanol.

The refrigerant or heat transfer compositions of the present invention may be azeotropic or near azeotropic compositions. An azeotropic composition is a liquid admixture of two or more substances that has a constant boiling point that may be above or below the boiling points of the individual components. As such an azeotropic composition will not fractionate within the refrigeration or air conditioning system during operation, which may reduce efficiency of the system. Additionally, an azeotropic composition will not fractionate upon leakage from the refrigeration or air conditioning system. In the situation where one component of a mixture is flammable, fractionation during leakage could lead to a flammable composition either within the system or outside of the system.
A near azeotropic composition is a substantially constant boiling, liquid admixture of two or more substances that behaves essentially as a single substance. One way to characterize a near azeotropic composition is that the vapor produced by partial evaporation or distillation of the liquid has substantially the same composition as the liquid from which it was evaporated or distilled, that is, the admixture distills/refluxes without substantial composition change. Another way to characterize a near azeotropic composition is that the bubble point vapor pressure and the dew point vapor pressure of the composition at a particular temperature are substantially the same. Herein, a composition is near azeotropic if, after 50 weight percent of the composition is removed, such as by evaporation or boiling off, the difference in vapor pressure between the original composition and the composition remaining after 50 weight percent of the original composition has been removed is less than about 10 percent.
The azeotropic refrigerant compositions of the present invention are listed in Table 2.

	TABLE 2

	Azeotrope
	Concentration	Azeotrope

Component A	Component B	Wt % A	Wt % B	BP (° C.)

PEIK	N(CH₃)₂(CHF₂)	70.2	29.8	38.1
PEIK	1,1-dichloroethane	78.7	21.3	38.2
PEIK	t-DCE	72.0	28.0	31.8
PEIK	diisopropyl ether	85.3	14.7	40.3
PEIK	1,2-dimethoxyethane	92.6	7.4	42.0
PEIK	dimethoxymethane	79.5	20.5	29.6
PEIK	1,1-dimethoxyethane	85.5	14.5	44.4
PEIK	ethanol	96.8	3.2	44.7
PEIK	ethyl formate	82.3	17.7	34.1
PEIK	isopropanol	96.7	3.3	45.6
PEIK	methanol	97.0	3.0	43.5
PEIK	methyl acetate	84.4	15.6	35.4
PEIK	methyl formate	73.2	26.8	22.6
PEIK	tert-butyl methyl ether	83.3	16.7	35.3
PEIK	n-propanol	98.4	1.6	47.6

The near azeotropic refrigerant compositions and concentration ranges of the present invention are listed in Table 3.

	TABLE 3

		Near Azeotropic Concentration
		Range
	Compounds (A/B)	wt % A/wt % B

	PEIK/N(CH₃)₂(CHF₂)	43-91/57-9
	PEIK/CF₃CF₂SCF₂CF₃	1-99/99-1
	PEIK/1,1-dichloroethane	55-91/45-9
	PEIK/t-DCE	48-87/52-12
	PEIK/acetone	1-99/99-1
	PEIK/diisopropyl ether	63-94/37-6
	PEIK/1,2-dimethoxyethane	73-96/27-4
	PEIK/dimethoxymethane	60-92/40-8
	PEIK/1,1-dimethoxyethane	61-99/39-1
	PEIK/ethanol	87-99/13-1
	PEIK/ethyl formate	61-92/39-8
	PEIK/isopropanol	85-99/15-1
	PEIK/methanol	91-99/9-1
	PEIK/methyl acetate	63-93/37-7
	PEIK/methyl formate	53-90/47-10
	PEIK/tert-butyl methyl ether	63-92/37-8
	PEIK/n-propanol	87-99/13-1

The compositions of the present invention may further comprise about 0.01 weight percent to about 5 weight percent of a stabilizer, free radical scavenger or antioxidant. Such additives include but are not limited to, nitromethane, hindered phenols, hydroxylamines, thiols, phosphites, or lactones. Single additives or combinations may be used.
The compositions of the present invention may further comprise about 0.01 weight percent to about 5 weight percent of a water scavenger (drying compound). Such water scavengers may comprise ortho esters such as trimethyl-, triethyl-, or tripropylortho formate.
The compositions of the present invention may further comprise an ultra-violet (UV) dye and optionally a solubilizing agent. The UV dye is a useful component for detecting leaks of the refrigerant composition by permitting one to observe the fluorescence of the dye in the refrigerant or heat transfer fluid composition at a leak point in or the vicinity of refrigeration or air-conditioning apparatus. One may observe the fluorosence of the dye under an ultra-violet light. Solubilizing agents may be needed due to poor solubility of such UV dyes in some refrigerants.
By “ultra-violet” dye is meant a UV fluorescent composition that absorbs light in the ultra-violet or “near” ultra-violet region of the electromagnetic spectrum. The fluorescence produced by the UV fluorescent dye under illumination by a UV light that emits radiation with wavelength anywhere from 10 nanometer to 750 nanometer may be detected. Therefore, if refrigerant containing such a UV fluorescent dye is leaking from a given point in a refrigeration or air conditioning apparatus, the fluorescence can be detected at the leak point. Such UV fluorescent dyes include but are not limited to naphthalimides, perylenes, coumarins, anthracenes, phenanthracenes, xanthenes, thioxanthenes, naphthoxanthenes, fluoresceins, and derivatives or combinations thereof.
Solubilizing agents of the present invention comprise at least one compound selected from the group consisting of hydrocarbons, hydrocarbon ethers, polyoxyalkylene glycol ethers, amides, nitriles, ketones, chlorocarbons, esters, lactones, aryl ethers, fluoroethers and 1,1,1-trifluoroalkanes.
Hydrocarbon solubilizing agents of the present invention comprise hydrocarbons including straight chained, branched chain or cyclic alkanes or alkenes containing 5 or fewer carbon atoms and only hydrogen with no other functional groups. Representative hydrocarbon solubilizing agents comprise propane, propylene, cyclopropane, n-butane, isobutane, and n-pentane. It should be noted that if the refrigerant is a hydrocarbon, then the solubilizing agent may not be the same hydrocarbon.
Hydrocarbon ether solubilizing agents of the present invention comprise ethers containing only carbon, hydrogen and oxygen, such as dimethyl ether (DME).
Polyoxyalkylene glycol ether solubilizing agents of the present invention are represented by the formula R¹-[(OR²)_xOR³]Y, wherein: x is an integer from 1-3; y is an integer from 1-4; R¹is selected from hydrogen and aliphatic hydrocarbon radicals having 1 to 6 carbon atoms and y bonding sites; R²is selected from aliphatic hydrocarbylene radicals having from 2 to 4 carbon atoms; R³is selected from hydrogen and aliphatic and alicyclic hydrocarbon radicals having from 1 to 6 carbon atoms; at least one of R¹and R³is said hydrocarbon radical; and wherein said polyoxyalkylene glycol ethers have a molecular weight of from about 100 to about 300 atomic mass units. In the present polyoxyalkylene glycol ether solubilizing agents represented by R¹-[(OR²)_xOR³]_y: x is preferably 1-2; y is preferably 1; R¹and R³are preferably independently selected from hydrogen and aliphatic hydrocarbon radicals having 1 to 4 carbon atoms; R²is preferably selected from aliphatic hydrocarbylene radicals having from 2 or 3 carbon atoms, most preferably 3 carbon atoms; the polyoxyalkylene glycol ether molecular weight is preferably from about 100 to about 250 atomic mass units, most preferably from about 125 to about 250 atomic mass units. The R¹and R³hydrocarbon radicals having 1 to 6 carbon atoms may be linear, branched or cyclic. Representative R¹and R³hydrocarbon radicals include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, pentyl, isopentyl, neopentyl, tert-pentyl, cyclopentyl, and cyclohexyl. Where free hydroxyl radicals on the present polyoxyalkylene glycol ether solubilizing agents may be incompatible with certain compression refrigeration apparatus materials of construction (e.g. Mylar®), R¹and R³are preferably aliphatic hydrocarbon radicals having 1 to 4 carbon atoms, most preferably 1 carbon atom. The R²aliphatic hydrocarbylene radicals having from 2 to 4 carbon atoms form repeating oxyalkylene radicals—(OR²)_x— that include oxyethylene radicals, oxypropylene radicals, and oxybutylene radicals. The oxyalkylene radical comprising R²in one polyoxyalkylene glycol ether solubilizing agent molecule may be the same, or one molecule may contain different R²oxyalkylene groups. The present polyoxyalkylene glycol ether solubilizing agents preferably comprise at least one oxypropylene radical. Where R¹is an aliphatic or alicyclic hydrocarbon radical having 1 to 6 carbon atoms and y bonding sites, the radical may be linear, branched or cyclic. Representative R¹aliphatic hydrocarbon radicals having two bonding sites include, for example, an ethylene radical, a propylene radical, a butylene radical, a pentylene radical, a hexylene radical, a cyclopentylene radical and a cyclohexylene radical. Representative R¹aliphatic hydrocarbon radicals having three or four bonding sites include residues derived from polyalcohols, such as trimethylolpropane, glycerin, pentaerythritol, 1,2,3-trihydroxycyclohexane and 1,3,5-trihydroxycyclohexane, by removing their hydroxyl radicals.
Representative polyoxyalkylene glycol ether solubilizing agents include but are not limited to: CH₃OCH₂CH(CH₃)O(H or CH₃) (propylene glycol methyl (or dimethyl)ether), CH₃O[CH₂CH(CH₃)O]₂(H or CH₃) (dipropylene glycol methyl (or dimethyl)ether), CH₃O[CH₂CH(CH₃)O]₃(H or CH₃) (tripropylene glycol methyl (or dimethyl)ether), C₂H₅OCH₂CH(CH₃)O(H or C₂H₅) (propylene glycol ethyl (or diethyl)ether), C₂H₅O[CH₂CH(CH₃)O]₂(H or C₂H₅) (dipropylene glycol ethyl (or diethyl)ether), C₂H₅O[CH₂CH(CH₃)O]₃(H or C₂H₅) (tripropylene glycol ethyl (or diethyl)ether), C₃H₇OCH₂CH(CH₃)O(H or C₃H₇) (propylene glycol n-propyl (or di-n-propyl)ether), C₃H₇O[CH₂CH(CH₃)O]₂(H or C₃H₇) (dipropylene glycol n-propyl (or di-n-propyl)ether), C₃H₇O[CH₂CH(CH₃)O]₃(H or C₃H₇) (tripropylene glycol n-propyl (or di-n-propyl)ether), C₄H₉OCH₂CH(CH₃)OH (propylene glycol n-butyl ether), C₄H₉O[CH₂CH(CH₃)O]₂(H or C₄H₉)(dipropylene glycol n-butyl (or di-n-butyl)ether), C₄H₉O[CH₂CH(CH₃)O]₃(H or C₄H₉) (tripropylene glycol n-butyl (or di-n-butyl)ether), (CH₃)₃COCH₂CH(CH₃)OH (propylene glycol t-butyl ether), (CH₃)₃CO[CH₂CH(CH₃)O]₂(H or (CH₃)₃) (dipropylene glycol t-butyl (or di-t-butyl)ether), (CH₃)₃CO[CH₂CH(CH₃)O]₃(H or (CH₃)₃) (tripropylene glycol t-butyl (or di-t-butyl)ether), C₅H₁₁OCH₂CH(CH₃)OH (propylene glycol n-pentyl ether), C₄H₉OCH₂CH(C₂H₅)OH (butylene glycol n-butyl ether), C₄H₉O[CH₂CH(C₂H₅)O]₂H (dibutylene glycol n-butyl ether), trimethylolpropane tri-n-butyl ether (C₂H₅C(CH₂—O—(CH₂)₃CH₃)₃) and trimethylolpropane di-n-butyl ether (C₂H₅C(CH₂OC(CH₂)₃CH₃)₂CH₂OH).
Amide solubilizing agents of the present invention comprise those represented by the formulae R¹CONR²R³and cyclo-[R⁴CON(R⁵)—], wherein R¹, R², R³and R⁵are independently selected from aliphatic and alicyclic hydrocarbon radicals having from 1 to 12 carbon atoms; R⁴is selected from aliphatic hydrocarbylene radicals having from 3 to 12 carbon atoms; and wherein said amides have a molecular weight of from about 100 to about 300 atomic mass units. The molecular weight of said amides is preferably from about 160 to about 250 atomic mass units. R¹, R², R³and R⁵may optionally include substituted hydrocarbon radicals, that is, radicals containing non-hydrocarbon substituents selected from halogens (e.g., fluorine, chlorine) and alkoxides (e.g. methoxy). R¹, R², R³and R⁵may optionally include heteroatom-substituted hydrocarbon radicals, that is, radicals, which contain the atoms nitrogen (aza-), oxygen (oxa-) or sulfur (thia-) in a radical chain otherwise composed of carbon atoms. In general, no more than three non-hydrocarbon substituents and heteroatoms, and preferably no more than one, will be present for each 10 carbon atoms in R^1-3, and the presence of any such non-hydrocarbon substituents and heteroatoms must be considered in applying the aforementioned molecular weight limitations. Preferred amide solubilizing agents consist of carbon, hydrogen, nitrogen and oxygen. Representative R¹, R², R³and R⁵aliphatic and alicyclic hydrocarbon radicals include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, pentyl, isopentyl, neopentyl, tert-pentyl, cyclopentyl, cyclohexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl and their configurational isomers. A preferred embodiment of amide solubilizing agents are those wherein R⁴in the aforementioned formula cyclo-[R⁴CON(R⁵)—] may be represented by the hydrocarbylene radical (CR⁶R⁷)_n, in other words, the formula: cyclo-[(CR⁶R⁷)NCON(R⁵)—] wherein: the previously-stated values for molecular weight apply; n is an integer from 3 to 5; R⁵is a saturated hydrocarbon radical containing 1 to 12 carbon atoms; R⁶and R⁷are independently selected (for each n) by the rules previously offered defining R^1-3. In the lactams represented by the formula: cyclo-[(CR⁶R⁷)NCON(R⁵)—], all R⁶and R⁷are preferably hydrogen, or contain a single saturated hydrocarbon radical among the n methylene units, and R⁵is a saturated hydrocarbon radical containing 3 to 12 carbon atoms. For example, 1-(saturated hydrocarbon radical)-5-methylpyrrolidin-2-ones.
Representative amide solubilizing agents include but are not limited to: 1-octylpyrrolidin-2-one, 1-decylpyrrolidin-2-one, 1-octyl-5-methylpyrrolidin-2-one, 1-butylcaprolactam, 1-cyclohexylpyrrolidin-2-one, 1-butyl-5-methylpiperid-2-one, 1-pentyl-5-methylpiperid-2-one, 1-hexylcaprolactam, 1-hexyl-5-methylpyrrolidin-2-one, 5-methyl-1-pentylpiperid-2-one, 1,3-dimethylpiperid-2-one, 1-methylcaprolactam, 1-butyl-pyrrolidin-2-one, 1,5-dimethylpiperid-2-one, 1-decyl-5-methylpyrrolidin-2-one, 1-dodecylpyrrolid-2-one, N,N-dibutylformamide and N,N-diisopropylacetamide.
Ketone solubilizing agents of the present invention comprise ketones represented by the formula R¹COR², wherein R¹and R²are independently selected from aliphatic, alicyclic and aryl hydrocarbon radicals having from 1 to 12 carbon atoms, and wherein said ketones have a molecular weight of from about 70 to about 300 atomic mass units. R¹and R²in said ketones are preferably independently selected from aliphatic and alicyclic hydrocarbon radicals having 1 to 9 carbon atoms. The molecular weight of said ketones is preferably from about 100 to 200 atomic mass units. R¹and R²may together form a hydrocarbylene radical connected and forming a five, six, or seven-membered ring cyclic ketone, for example, cyclopentanone, cyclohexanone, and cycloheptanone. R¹and R²may optionally include substituted hydrocarbon radicals, that is, radicals containing non-hydrocarbon substituents selected from halogens (e.g., fluorine, chlorine) and alkoxides (e.g. methoxy). R¹and R²may optionally include heteroatom-substituted hydrocarbon radicals, that is, radicals, which contain the atoms nitrogen (aza-), oxygen (keto-, oxa-) or sulfur (thia-) in a radical chain otherwise composed of carbon atoms. In general, no more than three non-hydrocarbon substituents and heteroatoms, and preferably no more than one, will be present for each 10 carbon atoms in R¹and R², and the presence of any such non-hydrocarbon substituents and heteroatoms must be considered in applying the aforementioned molecular weight limitations. Representative R¹and R²aliphatic, alicyclic and aryl hydrocarbon radicals in the general formula R¹COR²include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, pentyl, isopentyl, neopentyl, tert-pentyl, cyclopentyl, cyclohexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl and their configurational isomers, as well as phenyl, benzyl, cumenyl, mesityl, tolyl, xylyl and phenethyl.
Representative ketone solubilizing agents include but are not limited to: 2-butanone, 2-pentanone, acetophenone, butyrophenone, hexanophenone, cyclohexanone, cycloheptanone, 2-heptanone, 3-heptanone, 5-methyl-2-hexanone, 2-octanone, 3-octanone, diisobutyl ketone, 4-ethylcyclohexanone, 2-nonanone, 5-nonanone, 2-decanone, 4-decanone, 2-decalone, 2-tridecanone, dihexyl ketone and dicyclohexyl ketone.
Nitrile solubilizing agents of the present invention comprise nitriles represented by the formula R¹CN, wherein R¹is selected from aliphatic, alicyclic or aryl hydrocarbon radicals having from 5 to 12 carbon atoms, and wherein said nitriles have a molecular weight of from about 90 to about 200 atomic mass units. R¹in said nitrile solubilizing agents is preferably selected from aliphatic and alicyclic hydrocarbon radicals having 8 to 10 carbon atoms. The molecular weight of said nitrile solubilizing agents is preferably from about 120 to about 140 atomic mass units. R¹may optionally include substituted hydrocarbon radicals, that is, radicals containing non-hydrocarbon substituents selected from halogens (e.g., fluorine, chlorine) and alkoxides (e.g. methoxy). R¹may optionally include heteroatom-substituted hydrocarbon radicals, that is, radicals, which contain the atoms nitrogen (aza-), oxygen (keto-, oxa-) or sulfur (thia-) in a radical chain otherwise composed of carbon atoms. In general, no more than three non-hydrocarbon substituents and heteroatoms, and preferably no more than one, will be present for each 10 carbon atoms in R¹, and the presence of any such non-hydrocarbon substituents and heteroatoms must be considered in applying the aforementioned molecular weight limitations. Representative R¹aliphatic, alicyclic and aryl hydrocarbon radicals in the general formula R¹CN include pentyl, isopentyl, neopentyl, tert-pentyl, cyclopentyl, cyclohexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl and their configurational isomers, as well as phenyl, benzyl, cumenyl, mesityl, tolyl, xylyl and phenethyl. Representative nitrile solubilizing agents include but are not limited to: 1-cyanopentane, 2,2-dimethyl-4-cyanopentane, 1-cyanohexane, 1-cyanoheptane, 1-cyanooctane, 2-cyanooctane, 1-cyanononane, 1-cyanodecane, 2-cyanodecane, 1-cyanoundecane and 1-cyanododecane.
Chlorocarbon solubilizing agents of the present invention comprise chlorocarbons represented by the formula RCl_x, wherein; x is selected from the integers 1 or 2; R is selected from aliphatic and alicyclic hydrocarbon radicals having 1 to 12 carbon atoms; and wherein said chlorocarbons have a molecular weight of from about 100 to about 200 atomic mass units. The molecular weight of said chlorocarbon solubilizing agents is preferably from about 120 to 150 atomic mass units. Representative R aliphatic and alicyclic hydrocarbon radicals in the general formula RCl_xinclude methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, pentyl, isopentyl, neopentyl, tert-pentyl, cyclopentyl, cyclohexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl and their configurational isomers.
Representative chlorocarbon solubilizing agents include but are not limited to: 3-(chloromethyl)pentane, 3-chloro-3-methylpentane, 1-chlorohexane, 1,6-dichlorohexane, 1-chloroheptane, 1-chlorooctane, 1-chlorononane, 1-chlorodecane, and 1,1,1-trichlorodecane.
Ester solubilizing agents of the present invention comprise esters represented by the general formula R¹CO₂R², wherein R¹and R²are independently selected from linear and cyclic, saturated and unsaturated, alkyl and aryl radicals. Preferred esters consist essentially of the elements C, H and O, have a molecular weight of from about 80 to about 550 atomic mass units.
Representative esters include but are not limited to: (CH₃)₂CHCH₂OOC(CH₂)_2-4OCOCH₂CH(CH₃)₂(diisobutyl dibasic ester), ethyl hexanoate, ethyl heptanoate, n-butyl propionate, n-propyl propionate, ethyl benzoate, di-n-propyl phthalate, benzoic acid ethoxyethyl ester, dipropyl carbonate, “Exxate 700” (a commercial C₇alkyl acetate), “Exxate 800” (a commercial C₈alkyl acetate), dibutyl phthalate, and tert-butyl acetate.
Lactone solubilizing agents of the present invention comprise lactones represented by structures [A], [B], and [C]:
These lactones contain the functional group —CO₂— in a ring of six (A), or preferably five atoms (B), wherein for structures [A] and [B], R₁through R₈are independently selected from hydrogen or linear, branched, cyclic, bicyclic, saturated and unsaturated hydrocarbyl radicals. Each R₁though R₈may be connected forming a ring with another R₁through R₈. The lactone may have an exocyclic alkylidene group as in structure [C], wherein R₁through R₆are independently selected from hydrogen or linear, branched, cyclic, bicyclic, saturated and unsaturated hydrocarbyl radicals. Each R₁though R₆may be connected forming a ring with another R₁through R₆. The lactone solubilizing agents have a molecular weight range of from about 80 to about 300 atomic mass units, preferred from about 80 to about 200 atomic mass units.
Representative lactone solubilizing agents include but are not limited to the compounds listed in Table 4.

TABLE 4

			Molecular
		Molecular	Weight
Additive	Molecular Structure	Formula	(amu)

(E,Z)-3-ethylidene-5-methyl-dihydro-furan-2-one		C₇H₁₀O₂	126

(E,Z)-3-propylidene-5-methyl-dihydro-furan-2-one		C₈H₁₂O₂	140

(E,Z)-3-butylidene-5-methyl-dihydro-furan-2-one		C₉H₁₄O₂	154

(E,Z)-3-pentylidene-5-methyl-dihydro-furan-2-one		C₁₀H₁₆O₂	168

(E,Z)-3-Hexylidene-5-methyl-dihydro-furan-2-one		C₁₁H₁₈O₂	182

(E,Z)-3-Heptylidene-5-methyl-dihydro-furan-2-one		C₁₂H₂₀O₂	196

(E,Z)-3-octylidene-5-methyl-dihydro-furan-2-one		C₁₃H₂₂O₂	210

(E,Z)-3-nonylidene-5-methyl-dihydro-furan-2-one		C₁₄H₂₄O₂	224

(E,Z)-3-decylidene-5-methyl-dihydro-furan-2-one		C₁₅H₂₆O₂	238

(E,Z)-3-(3,5,5-trimethylhexylidene)-5-methyl-dihydrofuran-2-one		C₁₄H₂₄O₂	224

(E,Z)-3-cyclohexylmethylidene-5-methyl-dihydrofuran-2-one		C₁₂H₁₈O₂	194

gamma-octalactone		C₈H₁₄O₂	142

gamma-nonalactone		C₉H₁₆O₂	156

gamma-decalactone		C₁₀H₁₈O₂	170

gamma-undecalactone		C₁₁H₂₀O₂	184

gamma-dodecalactone		C₁₂H₂₂O₂	198

3-hexyldihydro-furan-2-one		C₁₀H₁₈O₂	170

3-heptyldihydro-furan-2-one		C₁₁H₂₀O₂	184

cis-3-ethyl-5-methyl-dihydro-furan-2-one		C₇H₁₂O₂	128

cis-(3-propyl-5-methyl)-dihydro-furan-2-one		C₈H₁₄O₂	142

cis-(3-butyl-5-methyl)-dihydro-furan-2-one		C₉H₁₆O₂	156

cis-(3-pentyl-5-methyl)-dihydro-furan-2-one		C₁₀H₁₈O₂	170

cis-3-hexyl-5-methyl-dihydro-furan-2-one		C₁₁H₂₀O₂	184

cis-3-heptyl-5-methyl-dihydro-furan-2-one		C₁₂H₂₂O₂	198

cis-3-octyl-5-methyl-dihydro-furan-2-one		C₁₃H₂₄O₂	212

cis-3-(3,5,5-trimethylhexyl)-5-methyl-dihydro-furan-2-one		C₁₄H₂₆O₂	226

cis-3-cyclohexylmethyl-5-methyl-dihydro-furan-2-one		C₁₂H₂₀O₂	196

5-methyl-5-hexyl-dihydro-furan-2-one		C₁₁H₂₀O₂	184

5-methyl-5-octyl-dihydro-furan-2-one		C₁₃H₂₄O₂	212

Hexahydro-isobenzofuran-1-one		C₈H₁₂O₂	140

delta-decalactone		C₁₀H₁₈O₂	170

delta-undecalactone		C₁₁H₂₀O₂	184

delta-dodecalactone		C₁₂H₂₂O₂	198

mixture of 4-hexyl-dihydrofuran-2-one and 3-hexyl-dihydro-furan-2-one		C₁₀H₁₈O₂	170

Lactone solubilizing agents generally have a kinematic viscosity of less than about 7 centistokes at 40° C. For instance, gamma-undecalactone has kinematic viscosity of 5.4 centistokes and cis-(3-hexyl-5-methyl)dihydrofuran-2-one has viscosity of 4.5 centistokes both at 40° C. Lactone solubilizing agents may be available commercially or prepared by methods as described in U.S. provisional patent application Ser. No. 10/910,495 (inventors being P. J. Fagan and C. J. Brandenburg), filed Aug. 3, 2004, incorporated herein by reference.
Aryl ether solubilizing agents of the present invention further comprise aryl ethers represented by the formula R¹OR², wherein: R¹is selected from aryl hydrocarbon radicals having from 6 to 12 carbon atoms; R²is selected from aliphatic hydrocarbon radicals having from 1 to 4 carbon atoms; and wherein said aryl ethers have a molecular weight of from about 100 to about 150 atomic mass units. Representative R¹aryl radicals in the general formula R¹OR²include phenyl, biphenyl, cumenyl, mesityl, tolyl, xylyl, naphthyl and pyridyl. Representative R²aliphatic hydrocarbon radicals in the general formula R¹OR²include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl and tert-butyl. Representative aromatic ether solubilizing agents include but are not limited to: methyl phenyl ether (anisole), 1,3-dimethyoxybenzene, ethyl phenyl ether and butyl phenyl ether.
Fluoroether solubilizing agents of the present invention comprise those represented by the general formula R¹OCF₂CF₂H, wherein R¹is selected from aliphatic and alicyclic hydrocarbon radicals having from about 5 to about 15 carbon atoms, preferably primary, linear, saturated, alkyl radicals. Representative fluoroether solubilizing agents include but are not limited to: C₈H₁₇OCF₂CF₂H and C₆H₁₃OCF₂CF₂H. It should be noted that if the refrigerant is a fluoroether, then the solubilizing agent may not be the same fluoroether.
Fluoroether solubilizing agents may further comprise ethers derived from fluoro-olefins and polyols. The fluoro-olefins may be of the type CF₂═CXY, wherein X is hydrogen, chlorine or fluorine, and Y is chlorine, fluorine, CF₃or OR_f, wherein R_fis CF₃, C₂F₅, or C₃F₇. Representative fluoro-olefins are tetrafluoroethylene, chlorotrifluoroethylene, hexafluoropropylene, and perfluoromethylvinyl ether. The polyols may be of the type HOCH₂CRR′(C H₂)_z(CHOH)_xCH₂(CH₂OH)_y, wherein R and R′ are hydrogen or CH₃or C₂H₅and wherein x is an integer from 0-4, y is an integer from 0-3 and z is either zero or 1. Representative polyols are trimethylol propane, pentaerythritol, butane diol, and ethylene glycol.
1,1,1-Trifluoroalkane solubilizing agents of the present invention comprise 1,1,1-trifluoroalkanes represented by the general formula CF₃R¹, wherein R¹is selected from aliphatic and alicyclic hydrocarbon radicals having from about 5 to about 15 carbon atoms, preferably primary, linear, saturated, alkyl radicals. Representative 1,1,1-trifluoroalkane solubilizing agents include but are not limited to: 1,1,1-trifluorohexane and 1,1,1-trifluorododecane.
Solubilizing agents of the present invention may be present as a single compound, or may be present as a mixture of more than one solubilizing agent. Mixtures of solubilizing agents may contain two solubilizing agents from the same class of compounds, say two lactones, or two solubilizing agents from two different classes, such as a lactone and a polyoxyalkylene glycol ether.
In the present compositions comprising refrigerant and UV fluorescent dye, from about 0.001 weight percent to about 1.0 weight percent of the composition is UV dye, preferably from about 0.005 weight percent to about 0.5 weight percent, and most preferably from 0.01 weight percent to about 0.25 weight percent.
Solubility of these UV fluorescent dyes in refrigerants may be poor. Therefore, methods for introducing these dyes into the refrigeration or air conditioning apparatus have been awkward, costly and time consuming. U.S. Pat. No. RE 36,951 describes a method, which utilizes a dye powder, solid pellet or slurry of dye that may be inserted into a component of the refrigeration or air conditioning apparatus. As refrigerant and lubricant are circulated through the apparatus, the dye is dissolved or dispersed and carried throughout the apparatus. Numerous other methods for introducing dye into a refrigeration or air conditioning apparatus are described in the literature.
Ideally, the UV fluorescent dye could be dissolved in the refrigerant itself thereby not requiring any specialized method for introduction to the refrigeration or air conditioning apparatus. The present invention relates to compositions including UV fluorescent dye, which may be introduced into the system in the refrigerant. The inventive compositions will allow the storage and transport of dye-containing refrigerant even at low temperatures while maintaining the dye in solution.
In the present compositions comprising refrigerant, UV fluorescent dye and solubilizing agent, from about 1 to about 50 weight percent, preferably from about 2 to about 25 weight percent, and most preferably from about 5 to about 15 weight percent of the combined composition is solubilizing agent in the refrigerant. In the compositions of the present invention the UV fluorescent dye is present in a concentration from about 0.001 weight percent to about 1.0 weight percent in the refrigerant, preferably from 0.005 weight percent to about 0.5 weight percent, and most preferably from 0.01 weight percent to about 0.25 weight percent.
Optionally, commonly used refrigeration system additives may be added, as desired, to compositions of the present invention in order to enhance performance and system stability. These additives are known within the field of refrigeration, and include, but are not limited to, anti wear agents, extreme pressure lubricants, corrosion and oxidation inhibitors, metal surface deactivators, free radical scavengers, and foam control agents. In general, these additives are present in the inventive compositions in small amounts relative to the overall composition. Typically concentrations of from less than about 0.1 weight percent to as much as about 3 weight percent of each additive are used. These additives are selected on the basis of the individual system requirements. These additives include members of the triaryl phosphate family of EP (extreme pressure) lubricity additives, such as butylated triphenyl phosphates (BTPP), or other alkylated triaryl phosphate esters, e.g. Syn-0-Ad 8478 from Akzo Chemicals, tricresyl phosphates and related compounds. Additionally, the metal dialkyl dithiophosphates (e.g. zinc dialkyl dithiophosphate (or ZDDP), Lubrizol 1375 and other members of this family of chemicals may be used in compositions of the present invention. Other antiwear additives include natural product oils and asymmetrical polyhydroxyl lubrication additives, such as Synergol TMS (International Lubricants). Similarly, stabilizers such as anti oxidants, free radical scavengers, and water scavengers may be employed. Compounds in this category can include, but are not limited to, butylated hydroxy toluene (BHT) and epoxides.
Solubilizing agents such as ketones may have an objectionable odor, which can be masked by addition of an odor masking agent or fragrance. Typical examples of odor masking agents or fragrances may include Evergreen, Fresh Lemon, Chemy, Cinnamon, Peppermint, Floral or Orange Peel, all available commercially, as well as d-limonene and pinene. Such odor masking agents may be used at concentrations of from about 0.001% to as much as about 15% by weight based on the combined weight of odor masking agent and solubilizing agent.
The present invention further relates to a method of using the refrigerant or heat transfer fluid compositions further comprising ultraviolet fluorescent dye, and optionally, solubilizing agent, in refrigeration or air conditioning apparatus. The method comprises introducing the refrigerant or heat transfer fluid composition into the refrigeration or air conditioning apparatus. This may be done by dissolving the UV fluorescent dye in the refrigerant or heat transfer fluid composition in the presence of a solubilizing agent and introducing the combination into the apparatus. Alternatively, this may be done by combining solubilizing agent and UV fluorescent dye and introducing said combination into refrigeration or air conditioning apparatus containing refrigerant and/or heat transfer fluid. The resulting composition may be used in the refrigeration or air conditioning apparatus.
The present invention further relates to a method of using the refrigerant or heat transfer fluid compositions comprising ultraviolet fluorescent dye to detect leaks. The presence of the dye in the compositions allows for detection of leaking refrigerant in the refrigeration or air conditioning apparatus. Leak detection helps to address, resolve or prevent inefficient operation of the apparatus or system or equipment failure. Leak detection also helps one contain chemicals used in the operation of the apparatus.
The method comprises providing the composition comprising refrigerant, ultra-violet fluorescent dye as described herein, and optionally, a solubilizing agent as described herein, to refrigeration and air conditioning apparatus and employing a suitable means for detecting the UV fluorescent dye-containing refrigerant. Suitable means for detecting the dye include, but are not limited to, ultra-violet lamp, often referred to as a “black light” or “blue light”. Such ultra-violet lamps are commercially available from numerous sources specifically designed for this purpose. Once the ultra-violet fluorescent dye containing composition has been introduced to the refrigeration or air conditioning apparatus and has been allowed to circulate throughout the system, a leak can be found by shining said ultra-violet lamp on the apparatus and observing the fluorescence of the dye in the vicinity of any leak point.
The present invention further relates to a method of using the compositions of the present invention for producing refrigeration or heat, wherein the method comprises producing refrigeration by evaporating said composition in the vicinity of a body to be cooled and thereafter condensing said composition; or producing heat by condensing said composition in the vicinity of the body to be heated and thereafter evaporating said composition.
Mechanical refrigeration is primarily an application of thermodynamics wherein a cooling medium, such as a refrigerant, goes through a cycle so that it can be recovered for reuse. Commonly used cycles include vapor-compression, absorption, steam-jet or steam-ejector, and air.
Vapor-compression refrigeration systems include an evaporator, a compressor, a condenser, and an expansion device. A vapor-compression cycle re-uses refrigerant in multiple steps producing a cooling effect in one step and a heating effect in a different step. The cycle can be described simply as follows. Liquid refrigerant enters an evaporator through an expansion device, and the liquid refrigerant boils in the evaporator at a low temperature to form a gas and produce cooling. The low-pressure gas enters a compressor where the gas is compressed to raise its pressure and temperature. The higher-pressure (compressed) gaseous refrigerant then enters the condenser in which the refrigerant condenses and discharges its heat to the environment. The refrigerant returns to the expansion device through which the liquid expands from the higher-pressure level in the condenser to the low-pressure level in the evaporator, thus repeating the cycle.
There are various types of compressors that may be used in refrigeration applications. Compressors can be generally classified as reciprocating, rotary, jet, centrifugal, scroll, screw or axial-flow, depending on the mechanical means to compress the fluid, or as positive-displacement (e.g., reciprocating, scroll or screw) or dynamic (e.g., centrifugal or jet), depending on how the mechanical elements act on the fluid to be compressed.
Either positive displacement or dynamic compressors may be used in the present inventive process. A centrifugal type compressor is the preferred equipment for the present refrigerant compositions.
A centrifugal compressor uses rotating elements to accelerate the refrigerant radially, and typically includes an impeller and diffuser housed in a casing. Centrifugal compressors usually take fluid in at an impeller eye, or central inlet of a circulating impeller, and accelerate it radially outward. Some static pressure rise occurs in the impeller, but most of the pressure rise occurs in the diffuser section of the casing, where velocity is converted to static pressure. Each impeller-diffuser set is a stage of the compressor. Centrifugal compressors are built with from 1 to 12 or more stages, depending on the final pressure desired and the volume of refrigerant to be handled.
The pressure ratio, or compression ratio, of a compressor is the ratio of absolute discharge pressure to the absolute inlet pressure. Pressure delivered by a centrifugal compressor is practically constant over a relatively wide range of capacities.
Positive displacement compressors draw vapor into a chamber, and the chamber decreases in volume to compress the vapor. After being compressed, the vapor is forced from the chamber by further decreasing the volume of the chamber to zero or nearly zero. A positive displacement compressor can build up a pressure, which is limited only by the volumetric efficiency and the strength of the parts to withstand the pressure.
Unlike a positive displacement compressor, a centrifugal compressor depends entirely on the centrifugal force of the high-speed impeller to compress the vapor passing through the impeller. There is no positive displacement, but rather what is called dynamic-compression.
The pressure a centrifugal compressor can develop depends on the tip speed of the impeller. Tip speed is the speed of the impeller measured at its tip and is related to the diameter of the impeller and its revolutions per minute. The capacity of the centrifugal compressor is determined by the size of the passages through the impeller. This makes the size of the compressor more dependent on the pressure required than the capacity.
Because of its high-speed operation, a centrifugal compressor is fundamentally a high volume, low-pressure machine. A centrifugal compressor works best with a low-pressure refrigerant, such as trichlorofluoromethane (CFC-11) or 1,2,2-trichlorotrifluoroethane (CFC-113).
Large centrifugal compressors typically operate at 3000 to 7000 revolutions per minute (rpm). Small turbine centrifugal compressors are designed for high speeds, from about 40,000 to about 70,000 (rpm), and have small impeller sizes, typically less than 0.15 meters.
A multi-stage impeller may be used in a centrifugal compressor to improve compressor efficiency thus requiring less power in use. For a two-stage system, in operation, the discharge of the first stage impeller goes to the suction intake of a second impeller. Both impellers may operate by use of a single shaft (or axle). Each stage can build up a compression ratio of about 4 to 1; that is, the absolute discharge pressure can be four times the absolute suction pressure. An example of a two-stage centrifugal compressor system, in this case for automotive applications, is described in U.S. Pat. No. 5,065,990, incorporated herein by reference.
The compositions of the present invention suitable for use in a refrigeration or air conditioning systems employing a centrifugal compressor comprise at least one of:

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and N-(difluoromethyl)-N,N-dimethylamine;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1-dichloroethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and trans-1,2-dichloroethylene;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and acetone;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and diisopropyl ether;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,2-dimethoxyethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and dimethoxymethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1-dimethoxyethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and ethanol;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and ethyl formate;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and isopropanol;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methanol;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methyl acetate;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methyl formate;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and tert-butylmethyl ether; or
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and n-propanol.

These above-listed compositions are also suitable for use in a multi-stage centrifugal compressor, preferably a two-stage centrifugal compressor apparatus.
The compositions of the present invention may be used in stationary air-conditioning, heat pumps or mobile air-conditioning and refrigeration systems. Stationary air conditioning and heat pump applications include window, ductless, ducted, packaged terminal, chillers and commercial, including packaged rooftop. Refrigeration applications include domestic or home refrigerators and freezers, ice machines, self-contained coolers and freezers, walk-in coolers and freezers and transport refrigeration systems.
The compositions of the present invention may additionally be used in air-conditioning, heating and refrigeration systems that employ fin and tube heat exchangers, microchannel heat exchangers and vertical or horizontal single pass tube or plate type heat exchangers.
Conventional microchannel heat exchangers may not be ideal for the low pressure refrigerant compositions of the present invention. The low operating pressure and density result in high flow velocities and high frictional losses in all components. In these cases, the evaporator design may be modified. Rather than several microchannel slabs connected in series (with respect to the refrigerant path) a single slab/single pass heat exchanger arrangement may be used. Therefore, a preferred heat exchanger for the low pressure refrigerants of the present invention is a single slab/single pass heat exchanger.
In addition to two-stage compressor systems, the following compositions of the present invention are suitable for use in refrigeration or air conditioning systems employing a single slab/single pass heat exchanger:

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and N-(difluoromethyl)-N,N-dimethylamine;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1-dichloroethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and trans-1,2-dichloroethylene;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and acetone;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and diisopropyl ether;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,2-dimethoxyethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and dimethoxymethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1-dimethoxyethane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and ethanol;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and ethyl formate;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and n-heptane;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and isopropanol;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methanol;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methyl acetate;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methyl formate;
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and tert-butylmethyl ether; and
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and n-propanol.

The compositions of the present invention are particularly useful in small turbine centrifugal compressors, which can be used in auto and window air conditioning or heat pumps as well as other applications. These high efficiency miniature centrifugal compressors may be driven by an electric motor and can therefore be operated independently of the engine speed. A constant compressor speed allows the system to provide a relatively constant cooling capacity at all engine speeds. This provides an opportunity for efficiency improvements especially at higher engine speeds as compared to a conventional R-134a automobile air-conditioning system. When the cycling operation of conventional systems at high driving speeds is taken into account, the advantage of these low pressure systems becomes even greater.
Some of the low pressure refrigerant fluids of the present invention may be suitable as drop-in replacements for CFC-113 in existing centrifugal equipment.
The present invention relates to a process for producing refrigeration comprising evaporating the compositions of the present invention in the vicinity of a body to be cooled, and thereafter condensing said compositions.
The present invention further relates to a process for producing heat comprising condensing the compositions of the present invention in the vicinity of a body to be heated, and thereafter evaporating said compositions.
The present invention further relates to a process for transfer of heat from a heat source to a heat sink wherein the compositions of the present invention serve as heat transfer fluids. Said process for heat transfer comprises transferring the compositions of the present invention from a heat source to a heat sink.
Heat transfer fluids are utilized to transfer, move or remove heat from one space, location, object or body to a different space, location, object or body by radiation, conduction, or convection. A heat transfer fluid may function as a secondary coolant by providing means of transfer for cooling (or heating) from a remote refrigeration (or heating) system. In some systems, the heat transfer fluid may remain in a constant state throughout the transfer process (i.e., not evaporate or condense). Alternatively, evaporative cooling processes may utilize heat transfer fluids as well.
A heat source may be defined as any space, location, object or body from which it is desirable to transfer, move or remove heat. Examples of heat sources may be spaces (open or enclosed) requiring refrigeration or cooling, such as refrigerator or freezer cases in a supermarket, building spaces requiring air conditioning, or the passenger compartment of an automobile requiring air conditioning. A heat sink may be defined as any space, location, object or body capable of absorbing heat. A vapor compression refrigeration system is one example of such a heat sink.

EXAMPLES

Example 1

Impact of Vapor Leakage

A vessel is charged with an initial composition at a specified temperature, and the initial vapor pressure of the composition is measured. The composition is allowed to leak from the vessel, while the temperature is held constant, until 50 weight percent of the initial composition is removed, at which time the vapor pressure of the composition remaining in the vessel is measured. The results are summarized in Table 5 below.

TABLE 5

			After 50%	After 50%
Compounds	Initial	Initial	Leak	Leak	Delta
wt % A/wt % B	Psia	kPa	Psia	kPa	P %

PEIK/CF₃CF₂SCF₂CF₃(50.0° C.)

0/100	22.71	156.58	22.71	156.58	0.0%
1/99	22.65	156.17	22.64	156.10	0.0%
20/80	21.44	147.82	21.16	145.89	1.3%
40/60	20.06	138.31	19.59	135.07	2.3%
60/40	18.57	128.04	18.04	124.38	2.9%
80/20	16.96	116.94	16.57	114.25	2.3%
99/1	15.32	105.63	15.29	105.42	0.2%
100/0	15.23	105.01	15.23	105.01	0.0%

PEIK/N(CH₃)₂(CHF₂) (38.1° C.)

70.2/29.8	14.68	101.22	14.68	101.22	0.0%
90/10	13.76	94.87	12.60	86.87	8.4%
91/9	13.60	93.77	12.31	84.87	9.5%
92/8	13.40	92.39	12.01	82.81	10.4%
100/0	9.92	68.40	9.92	68.40	0.0%
43/57	14.33	98.80	13.00	89.63	9.3%
42/58	14.31	98.66	12.80	88.25	10.6%
0/100	10.17	70.12	10.17	70.12	0.0%
54/46	14.54	100.25	12.91	89.01	11.2%
0/100	7.47	51.50	7.47	51.50	0.0%

PEIK/t-DCE (31.8° C.)

72.0/28.0	14.72	101.49	14.72	101.49	0.0%
85/15	14.62	100.80	14.03	96.73	4.0%
87/13	14.56	100.39	13.36	92.11	8.2%
88/12	14.52	100.11	12.82	88.39	11.7%
100/0	7.79	53.71	7.79	53.71	0.0%
60/40	14.70	101.35	14.67	101.15	0.2%
50/50	14.68	101.22	14.61	100.73	0.5%
48/52	14.68	101.22	14.28	98.46	2.7%
0/100	8.34	57.50	8.34	57.50	0.0%

PEIK/acetone (50° C.)

0/100	11.85	81.70	11.85	81.70	0.0%
1/99	11.85	81.70	11.85	81.70	0.0%
20/80	11.90	82.05	11.90	82.05	0.0%
40/60	12.00	82.74	11.99	82.67	0.1%
60/40	12.21	84.19	12.17	83.91	0.3%
80/20	12.76	87.98	12.64	87.15	0.9%
99/1	15.02	103.56	14.97	103.22	0.3%
100/0	15.23	105.01	15.23	105.01	0.0%

PEIK/diisopropyl ether (40.3° C.)

85.3/14.7	14.69	101.28	14.69	101.28	0.0%
90/10	14.66	101.08	14.53	100.18	0.9%
95/5	14.38	99.15	12.23	84.32	15.0%
94/6	14.49	99.91	13.06	90.05	9.9%
100/0	10.77	74.26	10.77	74.26	0.0%
63/37	14.58	100.53	13.17	90.8	9.7%
62/38	14.57	100.46	12.64	87.15	13.2%
0/100	5.68	39.16	5.68	39.16	0.0%

PEIK/1,2-dimethoxyethane (42.0° C.)

92.6/7.4	14.69	101.28	14.69	101.28	0.0%
95/5	14.69	101.28	14.69	101.28	0.0%
96/4	14.69	101.28	14.69	101.28	0.0%
100/0	14.47	99.77	14.47	99.77	0.0%
80/20	14.69	101.28	14.60	100.66	0.6%
73/27	14.67	101.15	13.66	94.18	6.9%
72/28	14.67	101.15	13.06	90.05	11.0%
0/100	3.43	23.65	3.43	23.65	0.0%

PEIK/dimethoxymethane (29.6° C.)

79.5/20.5	14.72	101.49	14.72	101.49	0.0%
90/10	14.71	101.42	14.69	101.28	0.1%
92/8	14.70	101.35	14.69	101.28	0.1%
100/0	7.13	49.16	7.13	49.16	0.0%
60/40	14.66	101.08	13.42	92.53	8.5%
59/41	14.65	101.01	13.04	89.91	11.0%
0/100	8.26	56.95	8.26	56.95	0.0%

PEIK/1,1-dimethoxyethane (44.4° C.)

85.5/14.5	14.67	101.15	14.67	101.15	0.0%
95/5	14.14	97.49	13.76	94.87	2.7%
99/1	13.02	89.77	12.75	87.91	2.1%
100/0	12.51	86.25	12.51	86.25	0.0%
60/40	14.10	97.22	12.67	87.36	10.1%
61/39	14.13	97.42	12.89	88.87	8.8%
0/100	7.49	51.64	7.49	51.64	0.0%

PEIK/ethanol (44.7° C.)

96.8/3.2	14.72	101.49	14.72	101.49	0.0%
99/1	14.55	100.32	13.15	90.67	9.6%
100/0	12.64	87.15	12.64	87.15	0.0%
87/13	14.59	100.60	13.39	92.32	8.2%
86/14	14.57	100.46	12.78	88.12	12.3%
0/100	3.28	22.61	3.28	22.61	0.0%

PEIK/ethyl formate (34.1° C.)

82.3/17.7	14.72	101.49	14.72	101.49	0.0%
90/10	14.69	101.28	14.41	99.35	1.9%
92/8	14.64	100.94	13.55	93.42	7.4%
93/7	14.60	100.66	12.35	85.15	15.4%
100/0	8.52	58.74	8.52	58.74	0.0%
60/40	14.70	101.35	12.95	89.29	11.9%
61/39	14.70	101.35	14.66	101.08	0.3%
0/100	7.11	49.02	7.11	49.02	0.0%

PEIK/isopropanol (45.6° C.)

96.7/3.3	14.72	101.49	14.72	101.49	0.0%
99/1	14.55	100.32	13.45	92.74	7.6%
100/0	13.06	90.05	13.06	90.05	0.0%
85/15	14.59	100.60	13.56	93.49	7.1%
84/16	14.58	100.53	13.10	90.32	10.2%
0/100	2.72	18.75	2.72	18.75	0.0%

PEIK/methanol (43.5° C.)

97.0/3.0	14.72	101.49	14.72	101.49	0.0%
99/1	14.51	100.04	13.07	90.12	9.9%
100/0	12.11	83.50	12.11	83.50	0.0%
90/10	14.24	98.18	12.62	87.01	11.4%
91/9	14.35	98.94	13.14	90.60	8.4%
0/100	5.77	39.78	5.77	39.78	0.0%

PEIK/methyl acetate (35.4° C.)

84.4/15.6	14.70	101.35	14.70	101.35	0.0%
90/10	14.69	101.28	14.59	100.60	0.7%
93/7	14.64	100.94	13.55	93.42	7.4%
94/6	14.60	100.66	11.93	82.25	18.3%
100/0	8.96	61.78	8.96	61.78	0.0%
70/30	14.69	101.28	14.67	101.15	0.1%
63/37	14.68	101.22	14.65	101.01	0.2%
0/100	6.52	44.95	6.52	44.95	0.0%

PEIK/methyl formate (22.6° C.)

73.2/26.8	14.72	101.49	14.72	101.49	0.0%
90/10	14.70	101.35	13.77	94.94	6.3%
91/9	14.69	101.28	11.87	81.84	19.2%
100/0	5.35	36.89	5.35	36.89	0.0%
60/40	14.72	101.49	14.72	101.49	0.0%
54/46	14.72	101.49	14.71	101.42	0.1%
53/47	14.72	101.49	14.71	101.42	0.1%
0/100	9.69	66.81	9.69	66.81	0.0%

PEIK/tert-butyl methyl ether (35.3° C.)

83.3/16.7	14.71	101.42	14.71	101.42	0.0%
90/10	14.71	101.42	14.64	100.94	0.5%
92/8	14.69	101.28	14.22	98.04	3.2%
93/7	14.68	101.22	12.70	87.56	13.5%
100/0	8.92	61.50	8.92	61.50	0.0%
70/30	14.69	101.28	14.52	100.11	1.2%
62/38	14.66	101.08	12.87	88.74	12.2%
63/37	14.66	101.08	13.35	92.05	8.9%
0/100	6.70	46.20	6.7	46.20	0.0%

PEIK/n-propanol (47.6° C.)

98.4/1.6	14.69	101.28	14.69	101.28	0.0%
99/1	14.67	101.15	14.61	100.73	0.4%
100/0	14.01	96.60	14.01	96.60	0.0%
86/14	14.48	99.84	12.91	89.01	10.8%
87/13	14.49	99.91	13.42	92.53	7.4%
0/100	1.55	10.69	1.55	10.69	0.0%

The results show the difference in vapor pressure between the original composition and the composition remaining after 50 weight percent has been removed is less then about 10 percent for compositions of the present invention. This indicates compositions of the present invention are azeotropic or azeotrope-like. Where an azeotrope is present, the data show compositions of the present invention have an initial vapor pressure higher than the vapor pressure of either pure component.

Example 2

Tip Speed to Develop Pressure

Tip speed can be estimated by making some fundamental relationships for refrigeration equipment that use centrifugal compressors. The torque an impeller ideally imparts to a gas is defined as
T=m*(v ₂ *r ₂ −v ₁ *r ₁) Equation 1
where
T=torque, N*m
m=mass rate of flow, kg/s
v2=tangential velocity of refrigerant leaving impeller (tip speed), m/s
r₂=radius of exit impeller, m
v₁=tangential velocity of refrigerant entering impeller, m/s
r₁=radius of inlet of impeller, m
Assuming the refrigerant enters the impeller in an essentially radial direction, the tangential component of the velocity v1=0, therefore
T=m*v ₂ *r ₂ Equation 2
The power required at the shaft is the product of the torque and the rotative speed
P=T*w Equation 3
where
P=power, W
w=rotative speed, rez/s
therefore,
P=T*w=m*v2*r2*w Equation 4
At low refrigerant flow rates, the tip speed of the impeller and the tangential velocity of the refrigerant are nearly identical; therefore
r ₂ *w=v2 Equation 5
and
P=m*v ₂ *v ₂ Equation 6
Another expression for ideal power is the product of the mass rate of flow and the isentropic work of compression,
P=m*H _i*(1000 J/kJ) Equation 7
where
H_i=Difference in enthalpy of the refrigerant from a saturated vapor at the evaporating conditions to saturated condensing conditions, kJ/kg.
Combining the two expressions Equation 6 and 7 produces,
v2*v2=1000*H _i Equation 8
Although Equation 8 is based on some fundamental assumptions, it provides a good estimate of the tip speed of the impeller and provides an important way to compare tip speeds of refrigerants.
Table 6 below shows theoretical tip speeds that are calculated for 1,2,2-trichlorotrifluoroethane (CFC-113) and compositions of the present invention. The conditions assumed for this comparison are:


	Evaporator temperature	40.0° F. (4.4° C.)
	Condenser temperature	110.0° F. (43.3° C.)
	Liquid subcool temperature	10.0° F. (5.5° C.)
	Return gas temperature	75.0° F. (23.8° C.)
	Compressor efficiency is	70%

These are typical conditions under which small turbine centrifugal compressors perform.

TABLE 6

Refrigerant	Wt %		Hi	Hi*0.7	Hi*0.7	V2	V2 rel
Composition	PEIK	Wt % B	Btu/lb	Btu/lb	KJ/Kg	m/s	to CFC-113

CFC-113	100		10.92	7.6	17.8	133.3	n/a
PEIK plus (B):
1,1-dichloroethane	78.7	21.3	11.41	8.0	18.6	136.3	102%
t-DCE	72.0	28.0	10.86	7.6	17.7	133.0	100%
acetone	50.0	50.0	11.53	8.1	18.8	137.0	103%
diisopropyl ether	85.3	14.6	10.31	7.2	16.8	129.6	97%
dimethoxyethane	92.6	7.4	9.65	6.8	15.7	125.3	94%
dimethoxymethane	79.5	20.5	12.87	9.0	21.0	144.8	109%
dimethyl acetal	85.5	14.5	11.08	7.8	18.0	134.3	101%
ethanol	96.8	3.2	10.02	7.0	16.3	127.7	96%
ethyl formate	82.3	17.7	12.59	8.8	20.5	143.2	107%
isopropanol	96.7	3.3	9.59	6.7	15.6	125.0	94%
methanol	97.0	3.0	10.74	7.5	17.5	132.2	99%
methyl acetate	84.4	15.6	11.92	8.3	19.4	139.3	105%
methyl formate	73.2	26.8	16.72	11.7	27.2	165.0	124%
methy-tert-butyl	83.3	16.7	11.09	7.8	18.1	134.4	101%
ether
n-propanol	98.4	1.6	9.03	6.3	14.7	121.3	91%

The example shows that compounds of the present invention have tip speeds within about +/−20 percent of CFC-113 and would be effective replacements for CFC-113 with minimal compressor design changes. Most preferred compositions have tip speeds within about +/−10 percent of CFC-113.

Example 3

Performance Data

Table 7 shows the performance of various refrigerants compared to CFC-113. The data are based on the following conditions.


	Evaporator temperature	40.0° F. (4.4° C.)
	Condenser temperature	110.0° F. (43.3° C.)
	Subcool temperature	10.0° F. (5.5° C.)
	Return gas temperature	75.0° F. (23.8° C.)
	Compressor efficiency is	70%

TABLE 7

			Evap	Evap	Cond	Cond	Compr	Compr
Refrigerant	wt %	wt %	Pres	Pres	Pres	Pres	Disch	Disch		Capacity	Capacity
composition	PEIK	B	(Psia)	(kPa)	(Psia)	(kPa)	Temp (F.)	Temp (C.)	COP	(Btu/min)	(kW)

CFC-113			2.7	19	12.8	88	156.3	69.1	4.18	14.8	0.26
PEIK plus (B):
1,1-dichloroethane	78.7	21.3	3.5	24	17.4	120	141.3	60.7	3.97	21.2	0.37
t-DCE	72.0	28.0	4.4	30	21.6	149	150.4	65.8	3.99	26.8	0.47
acetone	50.0	50.0	3.6	25	18.4	127	137.1	58.4	3.94	21.9	0.38
diisopropyl ether	85.3	14.6	3.2	22	16.3	112	127.3	52.9	3.73	18.1	0.32
dimethoxyethane	92.6	7.4	2.8	19	15.1	104	128.2	53.4	3.8	16.8	0.29
dimethoxymethane	79.5	20.5	4.5	31	22.7	156	139.0	59.4	3.86	26.6	0.47
dimethyl acetal	85.5	14.5	2.7	18	14.1	97	131.9	55.5	3.89	16.3	0.29
ethanol	96.8	3.2	2.4	17	13.8	95	131.2	55.1	3.87	15.4	0.27
ethyl formate	82.3	17.7	3.9	27	19.9	137	140.4	60.2	3.92	23.6	0.41
isopropanol	96.7	3.3	2.4	16	13.4	93	129.0	53.9	3.83	14.8	0.26
methanol	97.0	3.0	2.5	17	14.1	97	135.2	57.3	3.94	16.1	0.28
methyl acetate	84.4	15.6	3.7	26	18.8	130	139.6	59.8	3.94	22.5	0.39
methyl formate	73.2	26.8	6.0	41	29.4	203	159.2	70.7	3.99	36.5	0.64
methy-tert-butyl	83.3	16.7	3.7	26	18.5	128	129.8	54.3	3.76	21.1	0.37
ether

Data show the compositions of the present invention have evaporator and condenser pressures similar to CFC-113. Some compositions also have higher capacity and/or energy efficiency (COP) than CFC-113.

Claims

1. A composition selected from the group consisting of:

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1-dichloroethane;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and N-(difluoromethyl)-N,N-dimethylamine;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and acetone;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and diisopropyl ether;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,2-dimethoxyethane;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and dimethoxymethane;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1,1-dimethoxyethane;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and tert-butylmethyl ether;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and ethanol;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and isopropanol;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and n-propanol;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and ethyl formate;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methyl acetate; and

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and methyl formate.

2. A composition as in claim 1 wherein the composition is a refrigerant or heat transfer fluid composition suitable for use in refrigeration or air conditioning apparatus employing (i) centrifugal compressor, or (ii) multi-stage centrifugal compressor, or (iii) a single slab/single pass heat exchanger, and said composition is selected from the group consisting of:

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and acetone;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and ethanol;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and isopropanol;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and n-propanol;

1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and ethyl formate;

3. A composition as in claim 1, wherein the composition is an azeotropic or near-azeotropic composition selected from the group consisting of:

about 55 to about 91 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 45 to about 9 weight percent 1,1-dichloroethane;

about 43 to about 91 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 57 to about 9 weight percent N-(difluoromethyl)-N,N-dimethylamine;

about 1 to about 99 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 99 to about 1 weight percent 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane;

about 1 to about 99 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 99 to about 1 weight percent acetone;

about 63 to about 94 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 37 to about 6 weight percent diisopropyl ether;

about 73 to about 96 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 27 to about 4 weight percent 1,2-dimethoxyethane;

about 60 to about 92 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 40 to about 8 weight percent dimethoxymethane;

about 61 to about 99 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 39 to about 1 weight percent 1,1-dimethoxyethane;

about 63 to about 92 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 37 to about 8 weight percent tert-butyl methyl ether; and

about 87 to about 99 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 13 to about 1 weight percent ethanol;

about 85 to about 99 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 15 to about 1 weight percent isopropanol;

about 87 to about 99 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 13 to about 1 weight percent n-propanol;

about 61 to about 92 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 39 to about 8 weight percent ethyl formate;

about 63 to about 93 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 37 to about 7 weight percent methyl acetate; and

about 53 to about 90 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and about 47 to about 10 weight percent methyl formate.

4. A composition as in claim 1 wherein the composition is an azeotropic composition selected from the group consisting of:

78.7 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 21.3 weight percent 1,1-dichloroethane having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 38.2° C.;

70.2 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 29.8 weight percent N-(difluoromethyl)-N,N-dimethylamine having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 38.1° C.;

85.3 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 14.7 weight percent diisopropyl ether having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 40.3° C.;

92.6 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 7.4 weight percent 1,2-dimethoxyethane having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 42.0° C.;

79.5 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 20.5 weight percent dimethoxymethane having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 29.6° C.;

85.5 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 14.5 weight percent 1,1-dimethoxyethane having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 44.4° C.;

83.3 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 16.7 weight percent tert-butyl methyl ether having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 35.3° C.; and

96.8 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 3.2 weight percent ethanol having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 44.7° C.;

96.7 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 3.3 weight percent isopropanol having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 45.6° C.;

98.4 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 1.6 weight percent n-propanol having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 47.6° C.;

82.3 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 17.7 weight percent ethyl formate having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 34.1° C.;

84.4 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 15.6 weight percent methyl acetate having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 35.4° C.; and

73.2 weight percent 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and 26.8 weight percent methyl formate having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 22.6° C.

5. A process for producing refrigeration, said process comprising evaporating the refrigerant composition of claim 2, in the vicinity of a body to be cooled, and thereafter condensing said composition.

6. A process for producing heat, said process comprising condensing the heat transfer composition of claim 2 in the vicinity of a body to be heated, and thereafter evaporating said composition.

7. A process for transferring heat, said process comprising transferring the composition of claim 1 from the vicinity of a heat source to a heat sink.

8. The composition of claim 1, further comprising at least one ultra-violet fluorescent dye selected from the group consisting of naphthalimides, perylenes, coumarins, anthracenes, phenanthracenes, xanthenes, thioxanthenes, naphthoxanthenes, fluoresceins, derivatives of said dye and combinations thereof.

9. The composition of claim 8, further comprising at least one solubilizing agent selected from the group consisting of hydrocarbons, dimethylether, polyoxyalkylene glycol ethers, amides, ketones, nitriles, chlorocarbons, esters, lactones, aryl ethers, hydrofluoroethers, and 1,1,1-trifluoroalkanes; and wherein the refrigerant and solubilizing agent are not the same compound.

10. The composition of claim 9, wherein said solubilizing agent is selected from the group consisting of:

a) polyoxyalkylene glycol ethers represented by the formula R¹[(OR²)_xOR³]_y, wherein: x is an integer from 1 to 3; y is an integer from 1 to 4; R¹is selected from hydrogen and aliphatic hydrocarbon radicals having 1 to 6 carbon atoms and y bonding sites; R²is selected from aliphatic hydrocarbylene radicals having from 2 to 4 carbon atoms; R³is selected from hydrogen, and aliphatic and alicyclic hydrocarbon radicals having from 1 to 6 carbon atoms; at least one of R¹and R³is selected from said hydrocarbon radicals; and wherein said polyoxyalkylene glycol ethers have a molecular weight of from about 100 to about 300 atomic mass units;

b) amides represented by the formulae R¹CONR²R³and cyclo-[R⁴CON(R⁵)—], wherein R¹, R², R³and R⁵are independently selected from aliphatic and alicyclic hydrocarbon radicals having from 1 to 12 carbon atoms, and at most one aromatic radical having from 6 to 12 carbon atoms; R⁴is selected from aliphatic hydrocarbylene radicals having from 3 to 12 carbon atoms; and wherein said amides have a molecular weight of from about 100 to about 300 atomic mass units;

c) ketones represented by the formula R¹COR², wherein R¹and R²are independently selected from aliphatic, alicyclic and aryl hydrocarbon radicals having from 1 to 12 carbon atoms, and wherein said ketones have a molecular weight of from about 70 to about 300 atomic mass units;

d) nitriles represented by the formula R¹CN, wherein R¹is selected from aliphatic, alicyclic or aryl hydrocarbon radicals having from 5 to 12 carbon atoms, and wherein said nitriles have a molecular weight of from about 90 to about 200 atomic mass units;

e) chlorocarbons represented by the formula RCl_x, wherein; x is selected from the integers 1 or 2; R is selected from aliphatic and alicyclic hydrocarbon radicals having from 1 to 12 carbon atoms; and wherein said chlorocarbons have a molecular weight of from about 100 to about 200 atomic mass units;

f) aryl ethers represented by the formula R¹OR², wherein: R¹is selected from aryl hydrocarbon radicals having from 6 to 12 carbon atoms; R²is selected from aliphatic hydrocarbon radicals having from 1 to 4 carbon atoms; and wherein said aryl ethers have a molecular weight of from about 100 to about 150 atomic mass units;

g) 1,1,1-trifluoroalkanes represented by the formula CF₃R¹, wherein R¹is selected from aliphatic and alicyclic hydrocarbon radicals having from about 5 to about 15 carbon atoms;

i) fluoroethers represented by the formula R¹OCF₂CF₂H, wherein R¹is selected from aliphatic and alicyclic hydrocarbon radicals having from about 5 to about 15 carbon atoms; or wherein said fluoroethers are derived from fluoro-olefins and polyols, wherein said fluoro-olefins are of the type CF₂═CXY, wherein X is hydrogen, chlorine or fluorine, and Y is chlorine, fluorine, CF₃or OR_f, wherein R_fis CF₃, C₂F₅, or C₃F₇; and said polyols are of the type HOCH₂CRR′(CH₂)_z(CHOH)_xCH₂(CH₂OH)_y, wherein R and R′ are hydrogen, CH₃or C₂H₅, x is an integer from 0-4, y is an integer from 0-3 and z is either zero or 1; and

j) lactones represented by structures [B], [C], and [D]:

wherein, R₁through R₈are independently selected from hydrogen, linear, branched, cyclic, bicyclic, saturated and unsaturated hydrocarbyl radicals; and the molecular weight is from about 100 to about 300 atomic mass units; and

k) esters represented by the general formula R¹CO₂R², wherein R¹and R²are independently selected from linear and cyclic, saturated and unsaturated, alkyl and aryl radicals; and wherein said esters have a molecular weight of from about 80 to about 550 atomic mass units.

11. A process for detecting a leak at or in the vicinity of a refrigeration or air conditioning apparatus, said process comprising: providing a composition of claim 8 into said apparatus, and providing a suitable means for detecting said composition at a leak point or in the vicinity of said apparatus.

12. A method as in claim 5 wherein the refrigerant composition further comprises at least one ultra-violet fluorescent dye selected from the group consisting of naphthalimides, perylenes, coumarins, anthracenes, phenanthracenes, xanthenes, thioxanthenes, naphthoxanthenes, fluoresceins, derivatives of said dye and combinations thereof.

13. A method as in claim 6 wherein the heat transfer composition further comprises at least one ultra-violet fluorescent dye selected from the group consisting of naphthalimides, perylenes, coumarins, anthracenes, phenanthracenes, xanthenes, thioxanthenes, naphthoxanthenes, fluoresceins, derivatives of said dye and combinations thereof.

14. A method as in claim 12, wherein the refrigerant composition further comprises at least one solubilizing agent selected from the group consisting of hydrocarbons, dimethylether, polyoxyalkylene glycol ethers, amides, ketones, nitriles, chlorocarbons, esters, lactones, aryl ethers, hydrofluoroethers, and 1,1,1-trifluoroalkanes; and wherein the refrigerant and solubilizing agent are not the same compound.

15. A method as in claim 14 wherein the refrigerant composition is introduced into a compression refrigeration or air conditioning apparatus by (i) dissolving the ultraviolet fluorescent dye in the refrigerant composition or heat transfer fluid in the presence of the solubilizing agent, and introducing the combination into said compression refrigeration or air conditioning apparatus or (ii), combining solubilizing agent and UV fluorescent dye and introducing said combination into said compression refrigeration or air conditioning apparatus containing refrigerant and/or heat transfer fluid.

16. The composition of claim 1 further comprising a stabilizer, water scavenger, or odor masking agent.

17. The composition of claim 16 wherein said stabilizer is selected from the group consisting of nitromethane, hindered phenols, hydroxylamines, thiols, phosphites and lactones.

18. The composition of claim 16 wherein said water scavenger is an ortho ester.