TWI600097B - Manufacturing method of package substrate for mounting semiconductor device, package substrate for mounting semiconductor device, and semiconductor package - Google Patents
Manufacturing method of package substrate for mounting semiconductor device, package substrate for mounting semiconductor device, and semiconductor package Download PDFInfo
- Publication number
- TWI600097B TWI600097B TW101108124A TW101108124A TWI600097B TW I600097 B TWI600097 B TW I600097B TW 101108124 A TW101108124 A TW 101108124A TW 101108124 A TW101108124 A TW 101108124A TW I600097 B TWI600097 B TW I600097B
- Authority
- TW
- Taiwan
- Prior art keywords
- metal foil
- carrier metal
- flip chip
- circuit
- package substrate
- Prior art date
Links
- 239000000758 substrate Substances 0.000 title claims description 190
- 239000004065 semiconductor Substances 0.000 title claims description 124
- 238000004519 manufacturing process Methods 0.000 title claims description 31
- 239000011888 foil Substances 0.000 claims description 349
- 229910052751 metal Inorganic materials 0.000 claims description 293
- 239000002184 metal Substances 0.000 claims description 293
- 239000010410 layer Substances 0.000 claims description 213
- 229910000679 solder Inorganic materials 0.000 claims description 168
- 238000007747 plating Methods 0.000 claims description 142
- 238000000034 method Methods 0.000 claims description 78
- 239000010953 base metal Substances 0.000 claims description 57
- 230000008569 process Effects 0.000 claims description 50
- 238000005530 etching Methods 0.000 claims description 38
- 239000011229 interlayer Substances 0.000 claims description 29
- 239000004020 conductor Substances 0.000 claims description 22
- 238000010030 laminating Methods 0.000 claims description 13
- 238000000576 coating method Methods 0.000 claims description 9
- 238000009413 insulation Methods 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 239000012212 insulator Substances 0.000 claims description 2
- 239000010408 film Substances 0.000 description 90
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 51
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 26
- 229910052759 nickel Inorganic materials 0.000 description 23
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 21
- 229910044991 metal oxide Inorganic materials 0.000 description 18
- 150000004706 metal oxides Chemical class 0.000 description 18
- 239000010949 copper Substances 0.000 description 17
- 239000000463 material Substances 0.000 description 17
- 239000011889 copper foil Substances 0.000 description 14
- 229910052802 copper Inorganic materials 0.000 description 13
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 13
- 229910052737 gold Inorganic materials 0.000 description 13
- 239000010931 gold Substances 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 11
- 239000011521 glass Substances 0.000 description 9
- 229910052750 molybdenum Inorganic materials 0.000 description 9
- 239000004593 Epoxy Substances 0.000 description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 239000011733 molybdenum Substances 0.000 description 8
- 230000001681 protective effect Effects 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000004744 fabric Substances 0.000 description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 229920001721 polyimide Polymers 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 229910052709 silver Inorganic materials 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229910000365 copper sulfate Inorganic materials 0.000 description 5
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- 239000004642 Polyimide Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000005476 soldering Methods 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 239000009719 polyimide resin Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229910020816 Sn Pb Inorganic materials 0.000 description 1
- 229910020922 Sn-Pb Inorganic materials 0.000 description 1
- 229910008783 Sn—Pb Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- -1 bismuth imide Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- LQBJWKCYZGMFEV-UHFFFAOYSA-N lead tin Chemical compound [Sn].[Pb] LQBJWKCYZGMFEV-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 235000015393 sodium molybdate Nutrition 0.000 description 1
- 239000011684 sodium molybdate Substances 0.000 description 1
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 1
- WZWGGYFEOBVNLA-UHFFFAOYSA-N sodium;dihydrate Chemical compound O.O.[Na] WZWGGYFEOBVNLA-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/12—Mountings, e.g. non-detachable insulating substrates
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4644—Manufacturing multilayer circuits by building the multilayer layer by layer, i.e. build-up multilayer circuits
- H05K3/4682—Manufacture of core-less build-up multilayer circuits on a temporary carrier or on a metal foil
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/48—Manufacture or treatment of parts, e.g. containers, prior to assembly of the devices, using processes not provided for in a single one of the subgroups H01L21/06 - H01L21/326
- H01L21/4814—Conductive parts
- H01L21/4846—Leads on or in insulating or insulated substrates, e.g. metallisation
- H01L21/4857—Multilayer substrates
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/48—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor
- H01L23/488—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor consisting of soldered or bonded constructions
- H01L23/498—Leads, i.e. metallisations or lead-frames on insulating substrates, e.g. chip carriers
- H01L23/49822—Multilayer substrates
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/10—Bump connectors; Manufacturing methods related thereto
- H01L2224/15—Structure, shape, material or disposition of the bump connectors after the connecting process
- H01L2224/16—Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
- H01L2224/161—Disposition
- H01L2224/16151—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/16221—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/16225—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
- H01L2224/31—Structure, shape, material or disposition of the layer connectors after the connecting process
- H01L2224/32—Structure, shape, material or disposition of the layer connectors after the connecting process of an individual layer connector
- H01L2224/321—Disposition
- H01L2224/32135—Disposition the layer connector connecting between different semiconductor or solid-state bodies, i.e. chip-to-chip
- H01L2224/32145—Disposition the layer connector connecting between different semiconductor or solid-state bodies, i.e. chip-to-chip the bodies being stacked
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/4805—Shape
- H01L2224/4809—Loop shape
- H01L2224/48091—Arched
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/481—Disposition
- H01L2224/48151—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/48221—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/48225—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
- H01L2224/48227—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation connecting the wire to a bond pad of the item
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/73—Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
- H01L2224/732—Location after the connecting process
- H01L2224/73251—Location after the connecting process on different surfaces
- H01L2224/73265—Layer and wire connectors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/80—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
- H01L2224/81—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a bump connector
- H01L2224/8138—Bonding interfaces outside the semiconductor or solid-state body
- H01L2224/81385—Shape, e.g. interlocking features
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2225/00—Details relating to assemblies covered by the group H01L25/00 but not provided for in its subgroups
- H01L2225/03—All the devices being of a type provided for in the same subgroup of groups H01L27/00 - H01L33/648 and H10K99/00
- H01L2225/04—All the devices being of a type provided for in the same subgroup of groups H01L27/00 - H01L33/648 and H10K99/00 the devices not having separate containers
- H01L2225/065—All the devices being of a type provided for in the same subgroup of groups H01L27/00 - H01L33/648 and H10K99/00 the devices not having separate containers the devices being of a type provided for in group H01L27/00
- H01L2225/06503—Stacked arrangements of devices
- H01L2225/06555—Geometry of the stack, e.g. form of the devices, geometry to facilitate stacking
- H01L2225/06568—Geometry of the stack, e.g. form of the devices, geometry to facilitate stacking the devices decreasing in size, e.g. pyramidical stack
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/73—Means for bonding being of different types provided for in two or more of groups H01L24/10, H01L24/18, H01L24/26, H01L24/34, H01L24/42, H01L24/50, H01L24/63, H01L24/71
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/151—Die mounting substrate
- H01L2924/153—Connection portion
- H01L2924/1531—Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface
- H01L2924/15311—Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface being a ball array, e.g. BGA
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/151—Die mounting substrate
- H01L2924/153—Connection portion
- H01L2924/1532—Connection portion the connection portion being formed on the die mounting surface of the substrate
- H01L2924/1533—Connection portion the connection portion being formed on the die mounting surface of the substrate the connection portion being formed both on the die mounting surface of the substrate and outside the die mounting surface of the substrate
- H01L2924/15331—Connection portion the connection portion being formed on the die mounting surface of the substrate the connection portion being formed both on the die mounting surface of the substrate and outside the die mounting surface of the substrate being a ball array, e.g. BGA
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/10—Details of components or other objects attached to or integrated in a printed circuit board
- H05K2201/10613—Details of electrical connections of non-printed components, e.g. special leads
- H05K2201/10621—Components characterised by their electrical contacts
- H05K2201/10674—Flip chip
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/15—Position of the PCB during processing
- H05K2203/1536—Temporarily stacked PCBs
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/0097—Processing two or more printed circuits simultaneously, e.g. made from a common substrate, or temporarily stacked circuit boards
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/30—Assembling printed circuits with electric components, e.g. with resistor
- H05K3/32—Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
- H05K3/34—Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by soldering
- H05K3/341—Surface mounted components
- H05K3/3431—Leadless components
- H05K3/3436—Leadless components having an array of bottom contacts, e.g. pad grid array or ball grid array components
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Wire Bonding (AREA)
- Production Of Multi-Layered Print Wiring Board (AREA)
Description
本發明係有關於能夠高密度化之半導體元件搭載用封裝基板之製造方法、半導體元件搭載用封裝基板及半導體封裝,更詳細而言,係有關於具備倒裝晶片連接端子的半導體元件搭載用封裝基板之製造方法、半導體元件搭載用封裝基板及半導體封裝,該倒裝晶片連接端子係與具有凸塊之半導體元件作連接。 The present invention relates to a method of manufacturing a semiconductor device mounting package substrate, a semiconductor device mounting package substrate, and a semiconductor package, and more particularly to a semiconductor device mounting package including a flip chip connection terminal. A method of manufacturing a substrate, a package substrate for mounting a semiconductor element, and a semiconductor package, wherein the flip chip connection terminal is connected to a semiconductor element having bumps.
作為將半導體元件與半導體元件搭載用封裝基板(以下,亦有將「半導體元件搭載用封裝基板」稱作「封裝基板」的情況)之連接端子作電性連接的方法,係使用有倒裝晶片連接法(flip chip connection)。在此倒裝晶片連接中,由於要與半導體元件的凸塊形成良好之焊料圓角(solder fillet)之目的,多半會使用下述方法:在封裝基板之倒裝晶片連接端子上形成預焊料,藉由此預焊料與形成於半導體元件之凸塊處之焊料兩者確保焊料量,來與設置在半導體元件之凸塊作連接。另一方面,伴隨著電子零件之小型化和高密度化,產生了將與半導體元件連接之連接端子高密度地作配置的必要,而對於倒裝晶片連接端子之細微化有所要求。 A flip-chip is used as a method of electrically connecting a connection terminal between a semiconductor element and a package substrate for mounting a semiconductor element (hereinafter, a case where the "semiconductor element mounting package substrate" is referred to as a "package substrate"). Flip chip connection. In this flip chip connection, since a good solder fillet is formed with the bump of the semiconductor element, most of the following methods are used: a pre-solder is formed on the flip-chip connection terminal of the package substrate, The amount of solder is ensured by both the pre-solder and the solder formed at the bump of the semiconductor element to be connected to the bump provided on the semiconductor element. On the other hand, with the miniaturization and high density of electronic components, it is necessary to arrange the connection terminals connected to the semiconductor elements with high density, and the miniaturization of the flip chip connection terminals is required.
若是將倒裝晶片連接端子細微化,則因為會形成有預焊料之連接端子的面積減少,故被形成在倒裝晶片連接端 子上的預焊料之量亦會減少,其結果,與半導體元件之凸塊所形成的焊料圓角,其形成會變得不充分,而有著連接可靠性降低的問題。又,若是想要在細微之倒裝晶片連接端子上形成預焊料並使此預焊料對於與半導體元件之連接為充分之量,則如圖1所示,由於在一般之製法中,倒裝晶片連接端子26係相對於封裝基板之表面形成為凸狀,故預焊料19會繞流至倒裝晶片連接端子26的側面,而有著在相鄰倒裝晶片連接端子26之間會產生預焊料19之橋接的問題。亦即,即使為了要在倒裝晶片連接端子26上形成預焊料19而供給焊料,亦會有相當比例之焊料被耗用於覆蓋倒裝晶片連接端子26之側面,對於可用以形成連接所需的焊料圓角之預焊料19的比例會減少,不僅如此,相鄰倒裝晶片連接端子26還會產生橋接。 If the flip chip connection terminal is made fine, the area of the connection terminal where the pre-solder is formed is reduced, so that it is formed on the flip chip connection end. The amount of pre-solder on the sub-solder is also reduced, and as a result, the solder fillet formed by the bumps of the semiconductor element is insufficiently formed, and the connection reliability is lowered. Further, if it is desired to form a pre-solder on the fine flip chip connection terminal and to make the pre-solder a sufficient amount for connection with the semiconductor element, as shown in FIG. 1, since the flip chip is used in a general method. The connection terminal 26 is formed in a convex shape with respect to the surface of the package substrate, so that the pre-solder 19 will flow to the side of the flip-chip connection terminal 26, and the pre-solder 19 will be generated between the adjacent flip-chip connection terminals 26. The problem of bridging. That is, even if solder is supplied to form the pre-solder 19 on the flip-chip connecting terminal 26, a considerable proportion of solder is consumed to cover the side of the flip-chip connecting terminal 26, which is required for forming a connection. The proportion of the pre-solder 19 of the solder fillet is reduced, and not only the adjacent flip chip connection terminals 26 but also bridging.
作為改善此種問題之方法,揭示有:將封裝基板上成為倒裝晶片連接端子之區域的配線圖案形成為相對較長,以使此區域之焊料量增加的方法(專利文獻1),或藉由將成為倒裝晶片連接端子之區域的配線圖案的寬度相較於其他區域來部分地加寬,以使倒裝晶片連接端子上之預焊料量增加的方法(專利文獻2)。 As a method for improving such a problem, a method of forming a wiring pattern in a region of a package substrate as a flip chip connection terminal to be relatively long to increase the amount of solder in this region is disclosed (Patent Document 1), or A method of partially widening the width of the wiring pattern in the region to be the flip-chip connecting terminal to increase the amount of pre-solder on the flip-chip connecting terminal (Patent Document 2).
〔專利文獻1〕日本特開2002-329744號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2002-329744
〔專利文獻2〕日本特開2005-101137號公報 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2005-101137
若依據上述專利文獻1、2的方法,則能夠某種程度地確保用以與半導體元件作連接之倒裝晶片連接端子上的預焊料的量。但是,如圖1所示,形成倒裝晶片連接端子26之電路圖案,其係形成為從封裝基板1的表面形成為凸狀之電路圖案(以下,亦有稱作「凸狀電路」之情況),與封裝基板1之絕緣層3的表面密著者僅有此凸狀電路32之底面。並且,由於此凸狀電路32一般係利用半加成法(semi-additive method)等伴隨有蝕刻的方法來形成,因此會產生所謂的底切現象(undercut),其結果,電路圖案之寬度在厚度方向之中間處和底部(底面側)處會變得比在頂部(表面側)處狹窄。因此,若將倒裝晶片連接端子26細微化,則因倒裝晶片連接端子26與其下方的絕緣層3之間的密著面積減少和電路圖案的寬度減少,密著力會降低,在倒裝晶片連接時僅需施加些許外力,倒裝晶片連接端子26即會有發生剝離的可能性。 According to the methods of Patent Documents 1 and 2 described above, the amount of pre-solder on the flip chip connection terminal to be connected to the semiconductor element can be secured to some extent. However, as shown in FIG. 1, the circuit pattern of the flip-chip connecting terminal 26 is formed as a circuit pattern which is formed in a convex shape from the surface of the package substrate 1 (hereinafter, also referred to as a "convex circuit"). The surface of the insulating layer 3 of the package substrate 1 is only the bottom surface of the convex circuit 32. Further, since the convex circuit 32 is generally formed by a method such as a semi-additive method accompanied by etching, a so-called undercut phenomenon occurs, and as a result, the width of the circuit pattern is The middle portion and the bottom portion (bottom side) in the thickness direction become narrower than at the top (surface side). Therefore, if the flip chip connection terminal 26 is made fine, the adhesion area between the flip chip connection terminal 26 and the insulating layer 3 under it and the width of the circuit pattern are reduced, and the adhesion is lowered, and the flip chip is flipped. Only a small amount of external force needs to be applied during the connection, and the flip chip connection terminal 26 may have a possibility of peeling.
本發明係有鑑於上述問題點而完成者,其目的在於:提供一種半導體元件搭載用封裝基板之製造方法、半導體元件搭載用封裝基板、以及半導體封裝,其能夠形成即使細微也會確保密著力之倒裝晶片連接端子,並且藉由具備有倒裝晶片連接端子,其會確保對於與半導體元件的凸塊之倒裝晶片連接為必要之預焊料的量,而能夠對應高密度 化且可靠性亦優良。 The present invention has been made in view of the above problems, and an object of the invention is to provide a method for manufacturing a package substrate for mounting a semiconductor element, a package substrate for mounting a semiconductor element, and a semiconductor package, which can form a close contact force even if it is fine. Flip-chip connection terminals, and by providing flip-chip connection terminals, which ensure the amount of pre-solder necessary for flip-chip connection with bumps of semiconductor elements, and can correspond to high density And reliability is also excellent.
本發明,係有關於下述發明。 The present invention relates to the following invention.
1.一種半導體元件搭載用封裝基板之製造方法,具備有:準備將第1載體金屬箔、第2載體金屬箔與基底金屬箔依此順序層積之多層金屬箔,並將此多層金屬箔的基底金屬箔側與基材層積而形成核心基板之製程;在前述多層金屬箔的第1載體金屬箔與第2載體金屬箔之間,將第1載體金屬箔作物理性剝離之製程;在前述核心基板的第2載體金屬箔上,施行第1圖案鍍膜之製程;在包含前述第1圖案鍍膜之第2載體金屬箔上,形成絕緣層、導體電路與層間連接,而形成層積體之製程;在前述多層金屬箔的第2載體金屬箔與基底金屬箔之間,將前述層積體與第2載體金屬箔一同從核心基板作物理性剝離來分離之製程;與藉由在前述經剝離之層積體的第2載體金屬箔上,形成蝕刻阻劑並進行蝕刻,使第1圖案鍍膜從前述層積體表面的絕緣層露出而形成內埋電路之製程,或在前述層積體表面的第1圖案鍍膜上形成立體電路之製程,或在前述層積體表面的絕緣層上形成立體電路之製程,或在前述層積體表面的第1圖案鍍膜上形成凹陷形狀之製程。 1. A method of producing a package substrate for mounting a semiconductor element, comprising: preparing a plurality of metal foils in which a first carrier metal foil, a second carrier metal foil, and a base metal foil are laminated in this order, and the multilayer metal foil a process of forming a core substrate by laminating a base metal foil side and a base material; and a method of rationally stripping the first carrier metal foil between the first carrier metal foil and the second carrier metal foil of the multilayer metal foil; a process of applying a first pattern plating film on the second carrier metal foil of the core substrate, and a process of forming a laminate by forming an insulating layer, a conductor circuit, and an interlayer connection on the second carrier metal foil including the first pattern plating film. a process in which the laminate and the second carrier metal foil are separated from the core substrate by rational separation between the second carrier metal foil and the base metal foil of the multilayered metal foil; and by being stripped in the foregoing An etching resist is formed on the second carrier metal foil of the laminate, and etching is performed to expose the first pattern plating film from the insulating layer on the surface of the laminate to form a buried circuit, or Forming a three-dimensional circuit on the first pattern plating film on the surface of the laminated body, or forming a three-dimensional circuit on the insulating layer on the surface of the laminated body, or forming a concave shape on the first pattern plating film on the surface of the laminated body Process.
2.一種半導體元件搭載用封裝基板之製造方法,具備有:準備將第1載體金屬箔、第2載體金屬箔與基底金屬箔依此順序層積之多層金屬箔,並將此多層金屬箔的基 底金屬箔側與基材層積而形成核心基板之製程;在前述多層金屬箔的第1載體金屬箔與第2載體金屬箔之間,將第1載體金屬箔作物理性剝離之製程;在前述核心基板的第2載體金屬箔上,施行第1圖案鍍膜之製程;在包含前述第1圖案鍍膜之第2載體金屬箔上,形成絕緣層、導體電路與層間連接,而形成層積體之製程;在前述多層金屬箔的第2載體金屬箔與基底金屬箔之間,將前述層積體與第2載體金屬箔一同從核心基板作物理性剝離來分離之製程;在前述經剝離的層積體之第2載體金屬箔上,施行第2圖案鍍膜之製程;與在第2載體金屬箔的已進行前述第2圖案鍍膜部分以外之部分上,形成蝕刻阻劑並進行蝕刻,以藉由蝕刻來將已進行前述第2圖案鍍膜之部分以及已形成蝕刻阻劑之部分該等以外之第2載體金屬箔除去,使第1圖案鍍膜從前述層積體表面的絕緣層露出而形成內埋電路之製程,或在前述層積體表面的第1圖案鍍膜上形成立體電路之製程,或在前述層積體表面的絕緣層上形成立體電路之製程,或在前述層積體表面的第1圖案鍍膜上形成凹陷形狀之製程。 2. A method of producing a package substrate for mounting a semiconductor element, comprising: preparing a multilayer metal foil in which a first carrier metal foil, a second carrier metal foil, and a base metal foil are laminated in this order, and the multilayer metal foil base a process of forming a core substrate by laminating a bottom metal foil side and a base material; and a method of rationally stripping the first carrier metal foil between the first carrier metal foil and the second carrier metal foil of the multilayer metal foil; a process of applying a first pattern plating film on the second carrier metal foil of the core substrate, and a process of forming a laminate by forming an insulating layer, a conductor circuit, and an interlayer connection on the second carrier metal foil including the first pattern plating film. a process of separating the laminate between the second carrier metal foil of the multilayer metal foil and the base metal foil, and separating the laminate from the second carrier metal foil from the core substrate; and separating the laminate On the second carrier metal foil, a process of applying the second pattern plating film is performed; and an etching resist is formed on the portion of the second carrier metal foil other than the portion where the second pattern plating portion has been formed, and etching is performed by etching. The second carrier metal foil other than the portion where the second pattern plating has been performed and the portion where the etching resist has been formed are removed, and the first pattern plating film is exposed from the insulating layer on the surface of the laminate. a process of forming a buried circuit, or a process of forming a three-dimensional circuit on the first pattern plating film on the surface of the laminate, or a process of forming a three-dimensional circuit on the insulating layer on the surface of the laminate, or in the laminate A process of forming a recessed shape on the first pattern plating film on the surface.
3.如第1項或第2項所記載之半導體元件搭載用封裝基板之製造方法,其中,在包含第1圖案鍍膜之第2載體金屬箔上,形成絕緣體、導體電路與層間連接,而形成層積體之製程;與在多層金屬箔的第2載體金屬箔與基底金屬箔之間,將前述層積體與第2載體金屬箔一同從核心基板作物理性剝離來分離之製程,在此兩製程之間,具備 有:形成所欲之層數的絕緣層與導體電路之製程。 3. The method of manufacturing a package substrate for mounting a semiconductor device according to the first aspect, wherein the second carrier metal foil including the first pattern plating film is formed by forming an insulator, a conductor circuit, and an interlayer connection. a process for laminating a process, and separating the laminate from the second carrier metal foil and the base metal foil of the multilayer metal foil, and separating the laminate from the second carrier metal foil from the core substrate Between processes There are: a process for forming an insulating layer and a conductor circuit of a desired number of layers.
4.如第1~3項中之任一項所記載之半導體元件搭載用封裝基板之製造方法,其中,在使第1圖案鍍膜從層積體表面的絕緣層露出而形成內埋電路之製程中,係形成倒裝晶片連接端子,在於層積體表面的第1圖案鍍膜上形成立體電路之製程中,係形成柱體(pillar)或在倒裝晶片連接端子的長邊方向的一部分形成凸形狀,在於層積體表面的絕緣層上形成立體電路之製程中,係形成虛設端子。 (4) The method for producing a package substrate for mounting a semiconductor device according to any one of the first aspect, wherein the first pattern plating film is exposed from the insulating layer on the surface of the laminate to form a buried circuit. In the process of forming a flip-chip connection terminal on the first pattern plating film on the surface of the laminate, a pillar is formed or a portion of the long-side direction of the flip-chip connecting terminal is formed to be convex. The shape is a dummy terminal formed in a process of forming a three-dimensional circuit on the insulating layer on the surface of the laminate.
5.一種半導體元件搭載用封裝基板,係為藉由如第1~4項中之任一項所記載之半導體元件搭載用封裝基板之製造方法所製造出的半導體元件搭載用封裝基板,其係具備有:絕緣層;內埋電路,以使其頂面露出於該絕緣層之表面的方式而設置;與焊料阻劑,被設置在前述絕緣層上以及內埋電路上;其中,該內埋電路係被配置在該焊料阻劑的開口內且形成倒裝晶片連接端子,此倒裝晶片連接端子係被厚度3μm以上之預焊料所被覆。 The packaged substrate for semiconductor element mounting, which is a package substrate for mounting a semiconductor element, which is manufactured by the method for manufacturing a package substrate for mounting a semiconductor element according to any one of the first to fourth aspects, Providing an insulating layer; a buried circuit is disposed such that a top surface thereof is exposed on a surface of the insulating layer; and a solder resist is disposed on the insulating layer and the buried circuit; wherein the buried The circuit is disposed in the opening of the solder resist and forms a flip chip connection terminal, and the flip chip connection terminal is covered with a pre-solder having a thickness of 3 μm or more.
6.如第5項所記載之半導體元件搭載用封裝基板,其中,在形成倒裝晶片連接端子之內埋電路的底面處連接有通孔。 6. The package substrate for mounting a semiconductor element according to the item 5, wherein a through hole is connected to a bottom surface of the buried circuit in which the flip chip connection terminal is formed.
7.如第5項或第6項所記載之半導體元件搭載用封裝基板,其中,在倒裝晶片連接端子的長邊方向的一部分形成有凸形狀。 7. The package substrate for mounting a semiconductor element according to the fifth aspect of the invention, wherein a part of the longitudinal direction of the flip chip connection terminal is formed in a convex shape.
8.如第5~7項中之任一項所記載之半導體元件搭載用封裝基板,其中,在倒裝晶片連接端子的長邊方向的一 部分形成有凹陷形狀。 The package substrate for mounting a semiconductor element according to any one of the items 5 to 7, wherein the flip chip connection terminal has a longitudinal direction The portion is formed with a concave shape.
9.如第5~8項中之任一項所記載之半導體元件搭載用封裝基板,其中,倒裝晶片連接端子的前端被配置於焊料阻劑的開口內。 The package substrate for mounting a semiconductor element according to any one of the items 5 to 8, wherein the tip end of the flip chip connection terminal is disposed in the opening of the solder resist.
10.如第5~9項中之任一項所記載之半導體元件搭載用封裝基板,其中,所設置之內埋電路,其在倒裝晶片連接端子的長邊方向的兩側或者是單側具備延長部分。 The package substrate for mounting a semiconductor element according to any one of the items 5 to 9, wherein the embedded circuit is provided on both sides or one side in the longitudinal direction of the flip chip connection terminal. With an extension.
11.如第5~10項中之任一項所記載之半導體元件搭載用封裝基板,其中,倒裝晶片連接端子的一部分在短邊方向上被擴張。 The package substrate for mounting a semiconductor element according to any one of the items 5 to 10, wherein a part of the flip chip connection terminal is expanded in a short side direction.
12.一種半導體封裝,係在如第5~11項中之任一項所記載之半導體元件搭載用封裝基板的倒裝晶片連接端子上,藉由倒裝晶片連接來搭載半導體元件的凸塊。 A semiconductor package in which a bump of a semiconductor element is mounted by flip chip bonding on a flip chip connection terminal of a package substrate for mounting a semiconductor element according to any one of items 5 to 11.
若依據本發明,則能夠提供一種半導體元件搭載用封裝基板之製造方法、半導體元件搭載用封裝基板、以及半導體封裝,其能夠形成即使細微也會確保密著力之倒裝晶片連接端子,並且藉由具備有倒裝晶片連接端子,其會確保對於與半導體元件的凸塊之倒裝晶片連接為必要之預焊料的量,而能夠對應高密度化且可靠性亦為優良。 According to the present invention, it is possible to provide a method of manufacturing a package substrate for mounting a semiconductor element, a package substrate for mounting a semiconductor element, and a semiconductor package, which are capable of forming a flip chip connection terminal which secures adhesion even when fine, and The flip-chip connection terminal is provided, which ensures the amount of pre-solder necessary for the flip-chip connection to the bump of the semiconductor element, and can be made higher in density and reliability.
以下,使用圖2~圖9,針對本發明之半導體元件搭 載用封裝基板之例作說明。 Hereinafter, with reference to FIGS. 2 to 9, the semiconductor component of the present invention is used. An example of carrying a package substrate will be described.
作為本發明之半導體元件搭載用封裝基板(以下,稱作「封裝基板」)的第1例,可舉出:如圖2所示之半導體元件搭載用封裝基板1,其係具備有:絕緣層3;內埋電路2,以使其頂面露出於該絕緣層3之表面的方式而設置;與焊料阻劑4,被設置在前述絕緣層3上以及內埋電路2上;其中,該內埋電路係被配置在該焊料阻劑4之開口31內且形成倒裝晶片連接端子26,此倒裝晶片連接端子26係被厚度3μm以上之預焊料19所被覆。若依據此構成,則倒裝晶片連接端子26係由頂面露出於絕緣層3之表面的內埋電路2所形成。因此,由於倒裝晶片連接端子26之側面與底面係內埋至絕緣層3中而被固定,故即使形成倒裝晶片連接端子26之內埋電路2是線寬/線距(line/space)為20μm/20μm以下之等級的細微電路圖案,亦成為能夠形成會確保與絕緣層3之密著力的倒裝晶片連接端子26。因為具備有倒裝晶片連接端子26的長邊方向的兩側被延長之內埋電路2者,會成為內埋電路2亦從兩側固定倒裝晶片連接端子26,故從確保密著力的觀點來看為理想,不過,本發明相較於如圖1所示之凸狀電路32,即會成為能夠形成即使細微也會確保與絕緣層3之密著力之倒裝晶片連接端子26。因此,亦能夠如圖3所示,設置僅在倒裝晶片連接端子26的長邊方向的單側被延長之內埋電路2,在此情況下,由於可以將倒裝晶片連接端子26的尺寸縮小,故在可以謀求更高密度化這點為理想。又 ,亦能夠如圖4所示,設置在倒裝晶片連接端子26的長邊方向的單側以及兩側被延長之內埋電路2二者。如此,由於在倒裝晶片連接端子26的長邊方向被延長之內埋電路2不論是設置在倒裝晶片連接端子26的長邊方向的兩側、或僅設置在單側均可,故能夠將設計的自由度增大。又,由於倒裝晶片連接端子26被厚度3μm以上之預焊料19所被覆,故會成為能夠確保與半導體元件15之凸塊25之倒裝晶片連接中所必要之焊料量。從而,可提供一種半導體元件搭載用封裝基板1,其能夠對應於高密度化且可靠性亦為優良。 A first example of the package substrate for mounting a semiconductor device of the present invention (hereinafter referred to as a "package substrate") is a package substrate 1 for mounting a semiconductor element as shown in FIG. 2, which is provided with an insulating layer. 3; the buried circuit 2 is disposed such that its top surface is exposed on the surface of the insulating layer 3; and the solder resist 4 is disposed on the insulating layer 3 and the buried circuit 2; wherein, the inner The buried circuit is disposed in the opening 31 of the solder resist 4 and forms a flip chip connection terminal 26 which is covered with a pre-solder 19 having a thickness of 3 μm or more. According to this configuration, the flip chip connection terminal 26 is formed by the buried circuit 2 whose top surface is exposed on the surface of the insulating layer 3. Therefore, since the side surface and the bottom surface of the flip chip connection terminal 26 are buried in the insulating layer 3, even if the buried circuit 2 forming the flip chip connection terminal 26 is line/space (line/space) The fine circuit pattern of the order of 20 μm/20 μm or less is also capable of forming a flip chip connection terminal 26 which ensures adhesion to the insulating layer 3. Since the embedded circuit 2 having the both sides in the longitudinal direction of the flip chip connection terminal 26 is provided, the buried circuit 2 is also fixed to the flip chip connection terminal 26 from both sides, so that the viewpoint of ensuring the adhesion is obtained. In view of the above, the present invention can be formed as a flip-chip connecting terminal 26 capable of securing a close contact with the insulating layer 3 even if it is finer than the convex-shaped circuit 32 shown in FIG. Therefore, as shown in FIG. 3, it is also possible to provide the buried circuit 2 which is extended only on one side in the longitudinal direction of the flip-chip connecting terminal 26, in which case the size of the flip-chip connecting terminal 26 can be changed. Since it is reduced, it is desirable to achieve higher density. also Further, as shown in FIG. 4, both of the one side in the longitudinal direction of the flip chip connection terminal 26 and the buried circuit 2 which are extended on both sides can be provided. In this way, the buried circuit 2 that is extended in the longitudinal direction of the flip-chip connecting terminal 26 can be provided on both sides in the longitudinal direction of the flip-chip connecting terminal 26 or on only one side. Increase the freedom of design. Further, since the flip chip connection terminal 26 is covered with the pre-solder 19 having a thickness of 3 μm or more, the amount of solder necessary for ensuring connection to the flip chip of the bump 25 of the semiconductor element 15 is obtained. Therefore, it is possible to provide a package substrate 1 for mounting a semiconductor element, which is excellent in density and reliability.
本發明之所謂絕緣層,係指使用有機絕緣材料所形成之絕緣基板、核心基板、薄膜、層間絕緣層、增疊(build-up)層等。作為此種絕緣層,可使用一般用於封裝基板者,並可舉出使環氧樹脂或聚醯亞胺樹脂含浸於玻璃布(glass cloth)的預浸材、將環氧系黏著薄片或聚醯亞胺系黏著薄片等加熱、加壓所形成者。 The insulating layer of the present invention refers to an insulating substrate, a core substrate, a thin film, an interlayer insulating layer, a build-up layer, or the like formed using an organic insulating material. As such an insulating layer, those generally used for packaging substrates can be used, and a prepreg in which an epoxy resin or a polyimide resin is impregnated into a glass cloth, an epoxy-based adhesive sheet or a polymer can be used. It is formed by heat and pressure of a bismuth imide-based adhesive sheet.
本發明之內埋電路,係指以至少其底面及其側面的一部分內埋至絕緣層中且至少其頂面露出於絕緣層的表面之方式所設置之電路。此種內埋電路,例如,可利用所謂的轉印法等來形成:亦即,將金屬箔作為供電層,並於其上方利用圖案電鍍來形成特定之電路圖案,再於此電路圖案上形成絕緣層,而將電路圖案內埋至絕緣層中之後,利用蝕刻等來將作為供電層之金屬箔除去,而使被內埋至圖案絕緣層中之電路圖案的表面從絕緣層露出。 The buried circuit of the present invention refers to a circuit provided such that at least a portion of the bottom surface and a side surface thereof are buried in the insulating layer and at least the top surface thereof is exposed on the surface of the insulating layer. Such a buried circuit can be formed, for example, by a so-called transfer method or the like: that is, a metal foil is used as a power supply layer, and pattern plating is used thereon to form a specific circuit pattern, and then formed on the circuit pattern. After the insulating layer is buried in the insulating layer, the metal foil as the power supply layer is removed by etching or the like, and the surface of the circuit pattern buried in the pattern insulating layer is exposed from the insulating layer.
本發明之焊料阻劑,係以使預焊料不會附著在成為倒裝晶片連接端子之內埋電路以外的部分之方式來保護封裝基板的表面者。又,藉由透過設置於焊料阻劑之開口來規定內埋電路中成為倒裝晶片連接端子之部分,此開口內的內埋電路會形成倒裝晶片連接端子。作為焊料阻劑,從可以精確度良好地形成用以形成倒裝晶片連接端子且長度100μm×寬度100μm以下之等級之微小開口的觀點來看,較理想是感光性焊料阻劑。 The solder resist of the present invention protects the surface of the package substrate such that the pre-solder does not adhere to a portion other than the buried circuit of the flip chip connection terminal. Further, by inserting an opening provided in the solder resist to define a portion of the buried circuit to be a flip chip connection terminal, the buried circuit in the opening forms a flip chip connection terminal. As the solder resist, a photosensitive solder resist is preferable from the viewpoint of accurately forming a minute opening having a length of 100 μm × a width of 100 μm or less for forming a flip chip connection terminal.
本發明之倒裝晶片連接端子,係指用以將半導體元件藉由倒裝晶片連接來搭載在封裝基板上之連接端子。又,倒裝晶片連接係指將半導體元件之主動元件面朝向封裝基板來連接之方法,其是在半導體元件上形成作為電極之凸塊後,將半導體元件翻轉並對準封裝基板上的搭載位置,以將半導體元件之凸塊與形成於封裝基板上之倒裝晶片連接端子作連接之方法。本發明之倒裝晶片連接端子,不僅指與半導體元件的凸塊實際抵接之連接部,亦指內埋電路與半導體元件之凸塊作連接且在焊料阻劑之開口內露出於絕緣層的表面之部分。在倒裝晶片連接端子的表面上,為了防止表面氧化並確保預焊料之潤濕性,可以設置鎳/金鍍膜(形成有鎳鍍膜與在其上之金鍍膜者)、鎳/鈀/金鍍膜(形成有鎳鍍膜、在鎳鍍膜上之鈀鍍膜、在鈀鍍膜上之金鍍膜者)等保護鍍膜。 The flip chip connection terminal of the present invention is a connection terminal for mounting a semiconductor element on a package substrate by flip chip bonding. Moreover, the flip chip connection refers to a method of connecting the active device surface of the semiconductor element toward the package substrate, which is a mounting position on the package substrate after the semiconductor element is formed as a bump on the semiconductor element and then turned over on the package substrate. A method of connecting a bump of a semiconductor element to a flip chip connection terminal formed on a package substrate. The flip chip connection terminal of the present invention not only refers to a connection portion that actually abuts the bump of the semiconductor element, but also refers to a buried circuit and a bump of the semiconductor element and is exposed in the insulating layer in the opening of the solder resist. Part of the surface. On the surface of the flip-chip connection terminal, in order to prevent surface oxidation and ensure the wettability of the pre-solder, a nickel/gold plating film (formed with a nickel plating film and a gold plating film thereon), a nickel/palladium/gold plating film may be provided. A protective plating film (such as a nickel plating film, a palladium plating film on a nickel plating film, or a gold plating film on a palladium plating film).
本發明之預焊料,係指為了與半導體元件之倒裝晶片連接而設置在倒裝晶片連接端子上之焊料。預焊料可藉由 將焊料糊印刷並回焊之方法、其他公知方法來形成。作為焊料糊的一例,可舉出用於電子零件安裝且係將Sn(錫)-Pb(鉛)系、Sn(錫)-Ag(銀)-Cu(銅)系等焊料粒子與松香和有機溶劑混合者等。在焊料糊之印刷中,可使用金屬遮罩或絲網版(silk screen)等。回焊可使用一般用於電子零件安裝之紅外線回焊、熱風回焊、VPS(vapor phase soldering)回焊等來進行。回焊條件會依焊料糊而不同,但可舉出下述條件:例如,若是Sn-Pb(錫-鉛)系,則峰值溫度為240℃程度,若是Sn(錫)-Ag(銀)-Cu(銅)系,則峰值溫度為260℃程度。 The pre-solder of the present invention refers to a solder provided on a flip chip connection terminal for connection to a flip chip of a semiconductor element. Pre-solder can be used It is formed by a method of printing and reflowing a solder paste, and other known methods. As an example of the solder paste, solder particles such as Sn (tin)-Pb (lead), Sn (tin)-Ag (silver)-Cu (copper), and rosin and organic are used for electronic component mounting. Solvent mixer, etc. In the printing of the solder paste, a metal mask or a silk screen or the like can be used. The reflow can be performed using infrared reflow, hot air reflow, VPS (vapor phase soldering) reflow, which is generally used for electronic component mounting. The reflow conditions vary depending on the solder paste, but the following conditions can be given: for example, in the case of Sn-Pb (tin-lead), the peak temperature is about 240 ° C, and if it is Sn (tin) - Ag (silver) - For the Cu (copper) system, the peak temperature is about 260 °C.
本發明之封裝基板的倒裝晶片連接端子係被厚度3μm以上之預焊料所被覆。若預焊料的厚度未滿3μm,則在倒裝晶片連接端子與半導體元件的凸塊之間會無法充分地形成焊料圓角,而難以確保連接可靠性。另一方面,若預焊料的厚度超過20μm,則會有與相鄰倒裝晶片連接端子上的預焊料產生焊料橋接的可能性。因此,預焊料的厚度較理想是3μm以上且20μm以下。並且,由於倒裝晶片連接端子的頂面一般在俯視時是呈細長之長方形,將焊料糊等回焊所形成之預焊料會由於焊料的表面張力而形成為略半圓柱狀(魚板狀)。因此,預焊料的厚度在倒裝晶片連接端子之長邊方向(長度方向)與短邊方向(寬度方向)的略中央處會形成為最厚。因此,在本發明中,預焊料的厚度係設為:針對在倒裝晶片連接端子的長邊方向(長度方向)與短邊方向(寬度方向)的略中央處,使用非 接觸式階差測定機測定焊料阻劑表面與焊料表面的階差所求得者。 The flip chip connection terminal of the package substrate of the present invention is covered with a pre-solder having a thickness of 3 μm or more. When the thickness of the pre-solder is less than 3 μm, the solder fillet may not be sufficiently formed between the flip chip connection terminal and the bump of the semiconductor element, and it is difficult to ensure connection reliability. On the other hand, if the thickness of the pre-solder exceeds 20 μm, there is a possibility that solder bridging occurs with the pre-solder on the adjacent flip chip connection terminals. Therefore, the thickness of the pre-solder is preferably 3 μm or more and 20 μm or less. Further, since the top surface of the flip chip connection terminal is generally elongated in plan view, the pre-solder formed by reflowing the solder paste or the like is formed into a slightly semi-cylindrical shape (fish plate shape) due to the surface tension of the solder. . Therefore, the thickness of the pre-solder is formed to be the thickest at the center in the longitudinal direction (longitudinal direction) and the short-side direction (width direction) of the flip-chip connecting terminal. Therefore, in the present invention, the thickness of the pre-solder is set to be in the center of the longitudinal direction (longitudinal direction) and the short-side direction (width direction) of the flip-chip connecting terminal, and the non-use is used. A contact step measuring machine determines the difference between the surface of the solder resist and the surface of the solder.
作為本發明之封裝基板的第2例,可舉出如圖5所示且在包含倒裝晶片連接端子26之內埋電路2的底面連接有通孔(via)18者。並且,係省略預焊料而顯示。在圖5中,在倒裝晶片連接端子26的底面、以及從此倒裝晶片連接端子26在長邊方向延長之內埋電路2的底面二者均形成有通孔18,但亦可僅在該等其中之一形成有通孔18。亦即,在此第2例中,通孔18係形成於:內埋至絕緣層3之倒裝晶片連接端子26的底面、從此倒裝晶片連接端子26在長邊方向延長之內埋電路2的底面、或是該等二者的底面。藉由通孔18如此連接於底面,倒裝晶片連接端子26或從倒裝晶片連接端子26在長邊方向延長之內埋電路2會因通孔18而被固定於絕緣層3,故相較於第1例,會成為能夠使倒裝晶片連接端子26與絕緣層3之密著更加強固。 As a second example of the package substrate of the present invention, a via 18 is connected to the bottom surface of the buried circuit 2 including the flip chip connection terminal 26 as shown in FIG. Moreover, the pre-solder is omitted and displayed. In FIG. 5, a through hole 18 is formed in both the bottom surface of the flip chip connection terminal 26 and the bottom surface of the buried circuit 2 which is extended in the longitudinal direction from the flip chip connection terminal 26, but it is also possible only One of them is formed with a through hole 18. That is, in the second example, the through hole 18 is formed in the bottom surface of the flip chip connection terminal 26 buried in the insulating layer 3, and the buried circuit 2 is extended in the longitudinal direction from the flip chip connection terminal 26 The bottom surface, or the bottom surface of the two. By connecting the via hole 18 to the bottom surface in this manner, the flip chip connection terminal 26 or the buried circuit 2 extending from the flip chip connection terminal 26 in the longitudinal direction is fixed to the insulating layer 3 by the via hole 18, so that In the first example, the adhesion between the flip chip connection terminal 26 and the insulating layer 3 can be made stronger.
在本發明中,通孔係指將封裝基板上設置為多層之配線層的層間作連接者,例如可藉由利用雷射等來形成配線層之層間連接用的孔後,再對此孔內進行鍍膜等來形成。並且,為了爭取倒裝晶片連接端子的底面或從倒裝晶片連接端子在長邊方向延長之內埋電路的底面與通孔的連接面積,較理想是藉由所謂的填孔(filled via)鍍膜來形成通孔。 In the present invention, the through hole refers to a layer connecting the wiring layers provided on the package substrate as a plurality of layers, and for example, a hole for interlayer connection of the wiring layer can be formed by using a laser or the like, and then the hole is formed in the hole. Coating or the like is formed. Further, in order to obtain the connection surface of the bottom surface of the flip chip connection terminal or the bottom surface of the buried circuit from the flip chip connection terminal in the longitudinal direction, it is preferable to apply a film by a so-called filled via. To form a through hole.
作為本發明之封裝基板的第3例,可舉出如圖6中所 示且在倒裝晶片連接端子26的長邊方向的一部分形成有凸形狀27者。並且,係省略預焊料19而顯示。此凸形狀27,例如,可藉由形成鍍膜阻劑後對內埋電路中成為倒裝晶片連接端子26處的一部分作圖案鍍膜來形成。又,雖未圖示,但例如可藉由形成其側面的一部分與其頂面從絕緣層3的表面突出之內埋電路後,再形成蝕刻阻劑,並以突出之內埋電路的一部分維持突出地殘留但其他部分成為與絕緣層3的表面同一平面之方式來蝕刻而形成。凸形狀27的高度較理想是3μm~8μm程度,設置凸形狀27之範圍較理想是倒裝晶片連接端子26的短邊方向(寬度方向)的尺寸的50%~100%且是倒裝晶片連接端子26的長邊方向(長度方向)的尺寸的10%~70%程度。由於藉由如此地在倒裝晶片連接端子26的長邊方向的一部分形成凸形狀27,焊料會堆積在凸形狀27的階差部分(未圖示),故相較於表面為平坦之情況,可以使配置於倒裝晶片連接端子26上之焊料的量增加。又,由於凸形狀27會成為使其他部分的焊料集中的原因,焊料會以凸形狀27作為中心而凝集,故也可以將突出的焊料堆積物形成於倒裝晶片連接端子26的長邊方向的選定位置。因此,由於可以對應搭載於倒裝晶片連接端子26之半導體元件的凸塊位置來設置倒裝晶片連接端子26上的突出部分,故可以將倒裝晶片連接端子26與半導體元件的凸塊確實地作連接。 A third example of the package substrate of the present invention is as shown in FIG. It is shown that a convex shape 27 is formed in a part of the longitudinal direction of the flip chip connection terminal 26. Further, the pre-solder 19 is omitted and displayed. The convex shape 27 can be formed, for example, by patterning a portion of the embedded circuit into the flip chip connection terminal 26 by forming a plating resist. Further, although not shown, for example, an etching resistor can be formed by forming a part of the side surface and a top surface thereof protruding from the surface of the insulating layer 3, and the protrusion can be maintained by a part of the buried buried circuit. The ground remains but the other portions are etched so as to be flush with the surface of the insulating layer 3. The height of the convex shape 27 is preferably about 3 μm to 8 μm, and the range in which the convex shape 27 is provided is preferably 50% to 100% of the dimension in the short-side direction (width direction) of the flip-chip connecting terminal 26 and is a flip chip connection. The dimension of the terminal 26 in the longitudinal direction (longitudinal direction) is about 10% to 70%. Since the convex shape 27 is formed in a part of the longitudinal direction of the flip-chip connecting terminal 26 as described above, the solder is deposited on the step portion (not shown) of the convex shape 27, so that the surface is flat compared to the case where the surface is flat. The amount of solder disposed on the flip chip connection terminal 26 can be increased. Further, since the convex shape 27 causes the solder of the other portions to concentrate, the solder is aggregated with the convex shape 27 as the center. Therefore, the protruding solder deposit can be formed in the longitudinal direction of the flip chip connection terminal 26. Selected location. Therefore, since the protruding portion on the flip chip connection terminal 26 can be provided corresponding to the bump position of the semiconductor element mounted on the flip chip connection terminal 26, the flip chip connection terminal 26 and the bump of the semiconductor element can be surely Make a connection.
作為本發明之封裝基板的第4例,可舉出如圖7中所 示且在倒裝晶片連接端子26的長邊方向的一部分形成有凹陷形狀28者。並且,係省略預焊料而顯示。雖未圖示,但此凹陷形狀28例如可藉由形成其頂面從絕緣層3的表面露出之內埋電路後,再形成蝕刻阻劑,並以下述方式來蝕刻而形成:使頂面露出之內埋電路,其頂面的一部分比絕緣層3的表面更凹陷,但其他部分維持原樣地殘留。凹陷形狀28的深度較理想是3μm~8μm程度,凹陷形狀28的範圍較理想是倒裝晶片連接端子26的短邊方向(寬度方向)的尺寸的50%~100%且是倒裝晶片連接端子26的長邊方向(長度方向)的尺寸的10%~70%程度。由於藉由如此地形成凹陷形狀28,已熔融之焊料會堆積於此部分,故可以使配置在倒裝晶片連接端子26上之焊料(未圖示)的量增加。亦即,由於凹陷形狀28發揮作為堆積焊料之容器的功能,焊料會堆積於凹陷形狀28之中,故可以在倒裝晶片連接端子26上形成焊料且此焊料對於形成焊料圓角而言為充分的。 A fourth example of the package substrate of the present invention is as shown in FIG. It is shown that a recessed shape 28 is formed in a part of the longitudinal direction of the flip chip connection terminal 26. Moreover, the pre-solder is omitted and displayed. Although not shown, the recessed shape 28 can be formed, for example, by forming a buried circuit whose top surface is exposed from the surface of the insulating layer 3, and then etching is formed by etching in such a manner that the top surface is exposed. In the buried circuit, a part of the top surface thereof is more recessed than the surface of the insulating layer 3, but the other portions remain as they are. The depth of the recessed shape 28 is preferably about 3 μm to 8 μm, and the range of the recessed shape 28 is preferably 50% to 100% of the dimension in the short-side direction (width direction) of the flip-chip connecting terminal 26 and is a flip-chip connecting terminal. The length of the long side direction (longitudinal direction) of 26 is about 10% to 70%. Since the molten solder is deposited in this portion by forming the recessed shape 28 in this manner, the amount of solder (not shown) disposed on the flip chip connection terminal 26 can be increased. That is, since the recessed shape 28 functions as a container for depositing solder, the solder is deposited in the recessed shape 28, so that solder can be formed on the flip chip connection terminal 26 and the solder is sufficient for forming the solder fillet. of.
作為本發明之封裝基板的第5例,可舉出如圖3所示且倒裝晶片連接端子26的前端係形成於焊料阻劑4的開口31內者。並且,係省略預焊料而顯示。當電路圖案如同以往之一般封裝基板是藉由將黏著於絕緣層3的表面上之金屬箔蝕刻而形成時,此電路圖案為凸狀電路32(圖1),所形成之倒裝晶片連接端子26僅其底面會與絕緣層3黏著。又,因為係經由蝕刻來形成,故由凸狀電路32所成之電路圖案,從剖面來觀察時,會產生有相較於電路圖 案的表面側,其底面側的寬度成為更細之現象,即所謂的底切現象(undercut)。因此,若倒裝晶片連接端子26的尺寸細微化,則由於由凸狀電路32所成之電路圖案的底面與絕緣層3之黏著面積會減少,故其與絕緣層3之密著力會降低,在進行倒裝晶片連接時僅施加些許外力即會有剝離的可能性。因此,為了確保絕緣層3與倒裝晶片連接端子26之密著力,採用有:藉由將電路圖案利用焊料阻劑4作被覆而從上側來作固定,並使倒裝晶片連接端子26從焊料阻劑4的開口31露出,而利用焊料阻劑4將倒裝晶片連接端子26的長邊方向的兩側來作固定的方法。但是,在此方法中,因為焊料阻劑4的開口31的寬度會被焊料阻劑4的解析度極限所限定,故有必要將倒裝晶片連接端子26設為比焊料阻劑4的解析度極限更長。又,因此,電路圖案之佈線(wiring)自由度亦會受限。若依據本發明之封裝基板1的第5例,則由於倒裝晶片連接端子26是藉由其頂面從絕緣層3的表面露出之內埋電路所形成,故會成為即使細微亦能夠確保密著力。因此,不需要藉由焊料阻劑4來將在倒裝晶片連接端子26的長邊方向的兩側被延長之電路圖案從上方被覆作固定,即可以將倒裝晶片連接端子26的前端形成於焊料阻劑4的開口31內。從而,由於不會受到焊料阻劑4之解析度所限制,可以將倒裝晶片連接端子26細微化,故成為能夠謀求更高密度化,並且可以使電路圖案設計的自由度提升。 As a fifth example of the package substrate of the present invention, as shown in FIG. 3, the front end of the flip chip connection terminal 26 is formed in the opening 31 of the solder resist 4. Moreover, the pre-solder is omitted and displayed. When the circuit pattern is formed by etching a metal foil adhered to the surface of the insulating layer 3 as in the prior art, the circuit pattern is a convex circuit 32 (FIG. 1), and the flip chip connection terminal is formed. 26 only its bottom surface will adhere to the insulating layer 3. Moreover, since it is formed by etching, when the circuit pattern formed by the convex circuit 32 is viewed from a cross section, a circuit pattern is generated. On the surface side of the case, the width of the bottom side becomes a finer phenomenon, a so-called undercut. Therefore, if the size of the flip chip connection terminal 26 is made fine, the adhesion area between the bottom surface of the circuit pattern formed by the convex circuit 32 and the insulating layer 3 is reduced, so that the adhesion force with the insulating layer 3 is lowered. There is a possibility of peeling off by applying only a small amount of force when performing flip chip bonding. Therefore, in order to secure the adhesion between the insulating layer 3 and the flip-chip connecting terminal 26, the circuit pattern is fixed from the upper side by coating with the solder resist 4, and the flip-chip connecting terminal 26 is soldered from the solder. The opening 31 of the resist 4 is exposed, and the solder resist 4 is used to fix the both sides of the flip chip connection terminal 26 in the longitudinal direction. However, in this method, since the width of the opening 31 of the solder resist 4 is limited by the resolution limit of the solder resist 4, it is necessary to set the flip chip connection terminal 26 to be larger than the resolution of the solder resist 4. The limit is longer. Moreover, therefore, the wiring freedom of the circuit pattern is also limited. According to the fifth example of the package substrate 1 of the present invention, since the flip chip connection terminal 26 is formed by a buried circuit whose top surface is exposed from the surface of the insulating layer 3, it is possible to ensure the density even if it is fine. Focus on. Therefore, it is not necessary to cover the circuit pattern which is extended on both sides in the longitudinal direction of the flip-chip connecting terminal 26 from above by the solder resist 4, that is, the front end of the flip-chip connecting terminal 26 can be formed. Inside the opening 31 of the solder resist 4. Therefore, since the flip chip connection terminal 26 can be made finer without being limited by the resolution of the solder resist 4, the density can be increased, and the degree of freedom in designing the circuit pattern can be improved.
作為本發明之封裝基板的第6例,可舉出如圖4中所 示且設置有在倒裝晶片連接端子26的長邊方向的兩側或單側被延長之內埋電路2者。若依據本發明之封裝基板的第6例,則與第5例相同地,由於不會受到焊料阻劑4之解析度所限制而可以將倒裝晶片連接端子26細微化,故成為能夠謀求更高密度化,並且可以使電路圖案設計的自由度提升。 As a sixth example of the package substrate of the present invention, it can be mentioned in FIG. It is shown that the circuit 2 is embedded in both sides of the flip chip connection terminal 26 in the longitudinal direction or on one side. According to the sixth example of the package substrate of the present invention, as in the fifth example, since the flip chip connection terminal 26 can be made fine without being restricted by the resolution of the solder resist 4, it is possible to achieve further improvement. The density is increased, and the degree of freedom in circuit pattern design can be improved.
作為本發明之封裝基板的第7例,可舉出如圖8中所示且倒裝晶片連接端子26的一部分具備有在短邊方向(寬度方向)被擴張之部分33者。倒裝晶片連接端子26的前端可形成在焊料阻劑4的開口31內。並且,係省略預焊料而顯示。因為藉由此倒裝晶片連接端子26部分地具備有在短邊方向(寬度方向)被擴張之部分33,與絕緣層3之密著面積會擴大,故可以使倒裝晶片連接端子26與絕緣層3之密著力更進一步提升,並且,可以確保更多之預焊料19的量,又,由於在短邊方向(寬度方向)被擴張之部分33的預焊料19會藉由表面張力將其以外之部分的焊料集中過來而形成焊料堆積物,故可以將焊料堆積物安定地形成在選定之位置。 As a seventh example of the package substrate of the present invention, as shown in FIG. 8, a part of the flip chip connection terminal 26 is provided with a portion 33 which is expanded in the short-side direction (width direction). The front end of the flip chip connection terminal 26 may be formed in the opening 31 of the solder resist 4. Moreover, the pre-solder is omitted and displayed. Since the flip-chip connection terminal 26 is partially provided with the portion 33 which is expanded in the short-side direction (width direction), the adhesion area with the insulating layer 3 is enlarged, so that the flip-chip connection terminal 26 can be insulated. The adhesion of the layer 3 is further enhanced, and more of the amount of the pre-solder 19 can be ensured, and since the pre-solder 19 of the portion 33 which is expanded in the short-side direction (width direction) is caused by the surface tension A part of the solder is concentrated to form a solder deposit, so that the solder deposit can be stably formed at a selected position.
作為本發明之半導體封裝的一例,可舉出如圖9中所示且將半導體元件15藉由倒裝晶片連接來搭載在上述第1~第7之例的封裝基板1上者。在半導體元件15的凸塊25形成面與半導體元件搭載用封裝基板1之具備有倒裝晶片連接端子26的絕緣層3之間,較理想是填充有底部填材(underfill)23。據此,則成為底部填材23能夠使半導 體元件15的凸塊25形成面與具備有倒裝晶片連接端子26的絕緣層3之間的密著力更加強固。從而,可提供一種半導體封裝24,其對應於高密度化且可靠性亦為優良。 An example of the semiconductor package of the present invention is as shown in FIG. 9 and the semiconductor element 15 is mounted on the package substrate 1 of the first to seventh examples by flip chip bonding. The underfill 23 is preferably filled between the bump 25 forming surface of the semiconductor element 15 and the insulating layer 3 including the flip chip connecting terminal 26 of the semiconductor element mounting package substrate 1. According to this, the bottom filler 23 can be made semi-conductive. The adhesion between the surface of the bump 25 of the body element 15 and the insulating layer 3 provided with the flip chip connection terminal 26 is further enhanced. Thus, a semiconductor package 24 can be provided which is high in density and excellent in reliability.
以下,使用圖10~圖18,針對本發明之封裝基板的製造方法的一例作說明。 Hereinafter, an example of a method of manufacturing a package substrate of the present invention will be described with reference to FIGS. 10 to 18.
首先,如圖10中所示,準備將第1載體金屬箔10、第2載體金屬箔11、與基底金屬箔12依此順序層積之多層金屬箔9。 First, as shown in FIG. 10, a plurality of metal foils 9 in which the first carrier metal foil 10, the second carrier metal foil 11, and the base metal foil 12 are laminated in this order are prepared.
第1載體金屬箔10係用以保護第2載體金屬箔11的表面(與第1載體金屬箔10之間)者,並被設為在其與第2載體金屬箔11之間能夠作物理性剝離。只要可以保護第2載體金屬箔11的表面,則不問其材質或厚度,但在通用性與處理性之觀點上,作為材質,較佳是銅箔或鋁箔,作為厚度,較佳是1~35μm。又,在第1載體金屬箔10與第2載體金屬箔11之間,較佳是設置有用以將該等之間的剝離強度安定化之剝離層(未圖示),作為剝離層,較佳是即使將與絕緣樹脂作層積時的加熱、加壓進行複數次,剝離強度也能夠安定化者。作為此種剝離層,可舉出:在日本特開2003-181970號公報中所揭示之形成有金屬氧化物層與有機劑層者、在日本特開2003-094553號公報中所揭示之由Cu-Ni-Mo合金所成者、在日本再公表專利WO2006/013735號公報中所揭示之含有Ni以及W的金屬氧化物或者是Ni以及Mo的金屬氧化物者。並且,當將第1載體金屬箔10在其與第2載體金屬箔11之間作 物理性剝離時,較理想是此剝離層係以附著在第1載體金屬箔10側之狀態下來剝離,而不殘留在第2載體金屬箔11的表面上。 The first carrier metal foil 10 is for protecting the surface of the second carrier metal foil 11 (between the first carrier metal foil 10) and is capable of being stripped between the second carrier metal foil 11 and the second carrier metal foil 11 . When the surface of the second carrier metal foil 11 can be protected, the material or thickness is not required. However, from the viewpoint of versatility and handleability, copper foil or aluminum foil is preferable as the material, and the thickness is preferably 1 to 35 μm. . Further, between the first carrier metal foil 10 and the second carrier metal foil 11, a release layer (not shown) for resolving the peel strength between the two is preferably provided as a release layer. In the case where the heating and pressurization when laminating with the insulating resin are performed plural times, the peel strength can be stabilized. In the case of the above-mentioned release layer, a metal oxide layer and an organic agent layer are disclosed in Japanese Laid-Open Patent Publication No. 2003-181970, which is disclosed in Japanese Laid-Open Patent Publication No. 2003-094553. A metal oxide containing Ni and W or a metal oxide of Ni and Mo disclosed in Japanese Laid-Open Patent Publication No. WO2006/013735. Further, when the first carrier metal foil 10 is made between it and the second carrier metal foil 11, In the case of physical peeling, it is preferable that the peeling layer is peeled off while being attached to the side of the first carrier metal foil 10, and does not remain on the surface of the second carrier metal foil 11.
第2載體金屬箔11係為了在剝離第1載體金屬箔10後的表面上進行第1圖案鍍膜13而成為供給電流之晶種層(供電層)者,並被設為在其與第1載體金屬箔10之間以及其與基底金屬箔12之間能夠作物理性剝離。只要能夠與基底金屬箔12一同地作為供電層來作用,則不特別問其材質或厚度,但在通用性與處理性之觀點上,作為材質,較佳是銅箔或鋁箔,作為厚度,可使用1~18μm者。但是,由於在如後所述地形成外層電路2時(圖16(12)、(13)、(14))其會被利用蝕刻除去,故為了極力降低蝕刻量之偏差而形成高精確度之細微電路,較佳是1~5μm之極薄金屬箔。又,在其與第1載體金屬箔10之間以及與基底金屬箔12之間,為了將該等之間的剝離強度安定化,較佳是設置如上所述之剝離層(未圖示)。並且,此剝離層因為係與第2載體金屬箔11、基底金屬箔12成為一體來作為晶種層作用,故較理想是具備有導電性者。並且,此剝離層在與第2載體金屬箔11、基底金屬箔12之間作物理性剝離時,較理想是以附著在基底金屬箔12側的狀態來剝離而不殘留在第2載體金屬箔11的表面上者。 The second carrier metal foil 11 is a seed layer (power supply layer) for supplying a current in order to perform the first pattern plating film 13 on the surface after the first carrier metal foil 10 is peeled off, and is used as the first carrier. The metal foils 10 and between them and the base metal foil 12 can be stripped rationally. As long as it can function as a power supply layer together with the base metal foil 12, the material or thickness is not particularly required. However, from the viewpoint of versatility and handleability, copper foil or aluminum foil is preferable as the material. Use 1~18μm. However, since the outer layer circuit 2 is formed as described later (FIG. 16 (12), (13), (14)), it is removed by etching, so that high precision is formed in order to minimize the variation in the etching amount. The fine circuit is preferably an extremely thin metal foil of 1 to 5 μm. Further, in order to stabilize the peel strength between the first carrier metal foil 10 and the base metal foil 12, it is preferable to provide a peeling layer (not shown) as described above. Further, since the peeling layer functions as a seed layer together with the second carrier metal foil 11 and the base metal foil 12, it is preferable to have conductivity. Further, when the peeling layer is peeled off from the second carrier metal foil 11 and the base metal foil 12, it is preferable to peel off in a state of being adhered to the base metal foil 12 side without remaining in the second carrier metal foil 11 On the surface.
基底金屬箔12係在將多層金屬箔9與基材16作層積而製作核心基板17時安置在與基材16作層積之側者,並 被設為在其與第2載體金屬箔11之間能夠作物理性剝離。只要是在與基材16作層積時具備有與基材16間之黏著性,則不特別問其材質或厚度,但在通用性與處理性之觀點上,作為材質,較佳是銅箔或鋁箔,作為厚度,較佳是9~70μm。又,在其與第2載體金屬箔11之間,為了將該等之間的剝離強度安定化,較佳是設置如上所述之剝離層(未圖示)。並且,此剝離層在與第2載體金屬箔11、基底金屬箔12之間作物理性剝離時,較理想是以附著在基底金屬箔12側的狀態來剝離,而不殘留在第2載體金屬箔11的表面上者。 The base metal foil 12 is disposed on the side opposite to the substrate 16 when the multilayer metal foil 9 and the substrate 16 are laminated to form the core substrate 17, and It is assumed that the crop can be peeled off rationally between the second carrier metal foil 11 and the second carrier metal foil 11 . The material and the thickness are not particularly required as long as they are adhered to the substrate 16 when laminated with the substrate 16. However, from the viewpoint of versatility and handleability, copper foil is preferable as the material. Or aluminum foil, as the thickness, is preferably 9 to 70 μm. Further, in order to stabilize the peel strength between the second carrier metal foil 11 and the second carrier metal foil 11, it is preferable to provide a peeling layer (not shown) as described above. Further, when the peeling layer is peeled off from the second carrier metal foil 11 and the base metal foil 12, it is preferable to peel off in a state of being adhered to the base metal foil 12 side, and it is not left in the second carrier metal foil. On the surface of 11 people.
作為多層金屬箔9,係使用:為具備有3層以上之金屬箔(例如,如上所述,第1載體金屬箔10、第2載體金屬箔11、與基底金屬箔12)之多層金屬箔9,並至少2處之間(例如,如上所述,在第1載體金屬箔10與第2載體金屬箔11之間、以及在第2載體金屬箔11與基底金屬箔12之間)能夠作物理性剝離者。在將基材16層積於多層金屬箔9之基底金屬箔12側而形成核心基板17之製程時,雖然會有樹脂粉末等異物附著在第1載體金屬箔10的表面上之情況,但即使附著有這樣的異物,由於藉由將第1載體金屬箔10在其與第2載體金屬箔11之間作物理性剝離會形成不被樹脂粉末等異物影響之第2載體金屬箔11的表面,故可以確保高品質之金屬箔表面。從而,由於在將第2載體金屬箔11作為晶種層使用而進行第1圖案鍍膜13之情況下亦可以抑制缺陷之發生,故成為能夠謀 求良率之提升。 The multilayered metal foil 9 is a multilayer metal foil 9 having three or more metal foils (for example, the first carrier metal foil 10, the second carrier metal foil 11, and the base metal foil 12 as described above). Between at least two places (for example, as described above, between the first carrier metal foil 10 and the second carrier metal foil 11 and between the second carrier metal foil 11 and the base metal foil 12) Stripper. When the base material 16 is laminated on the base metal foil 12 side of the multilayered metal foil 9 to form the core substrate 17, a foreign matter such as resin powder may adhere to the surface of the first carrier metal foil 10, even if it is adhered to the surface of the first carrier metal foil 10. When such a foreign matter adheres, the first carrier metal foil 10 is peeled off from the second carrier metal foil 11 to form a surface of the second carrier metal foil 11 which is not affected by foreign matter such as resin powder. A high quality metal foil surface can be ensured. Therefore, when the first pattern plating film 13 is used by using the second carrier metal foil 11 as a seed layer, it is possible to suppress the occurrence of defects. Seek improvement in yield.
接著,如圖11(1)中所示,將多層金屬箔9之基底金屬箔12側與基材16作層積來形成核心基板17。基材16係與多層金屬箔9作層積一體化而形成核心基板17者,作為基材16,可以使用一般作為半導體元件搭載用封裝基板1的絕緣層3所使用者。作為此種基材16,可舉出環氧玻璃布(glass epoxy)、聚醯亞胺玻璃布(glass polyimide)等。核心基板17係使用多層金屬箔9而在製造封裝基板1時成為支持基板者,藉由確保剛性以使作業性提升、以及防止處理時之損傷來使良率提升作為主要功能者。因此,作為基材16,較理想是具備有玻璃纖維等補強材料者,例如,可藉由將環氧玻璃布、聚醯亞胺玻璃布等預浸材與多層金屬箔9重疊,並使用熱壓法等加熱、加壓而作層積一體化來形成。由於藉由在基材16的兩側(圖11(1)之上下兩側)層積多層金屬箔9並進行其後之製程,可以在1次的製程中進行2個製造封裝基板1之製程,故可謀求製程數之降低。又,由於可以構成在核心基板17的兩側為對稱構成之層積板,故可抑制彎曲,亦可抑制因作業性或者是勾卡在製造設備等所導致的損傷。 Next, as shown in Fig. 11 (1), the base metal foil 12 side of the multilayered metal foil 9 is laminated with the substrate 16 to form the core substrate 17. The base material 16 is formed by laminating and integrating the multilayer metal foil 9 to form the core substrate 17. As the base material 16, a user who is generally the insulating layer 3 of the package substrate 1 for semiconductor element mounting can be used. Examples of such a substrate 16 include a glass epoxy, a glass polyimide, and the like. When the core substrate 9 is used as the support substrate when the package substrate 1 is manufactured, the core substrate 17 is used as a support substrate, and the improvement in workability and the prevention of damage during processing are required to improve the yield. Therefore, as the base material 16, it is preferable to provide a reinforcing material such as glass fiber. For example, a prepreg such as an epoxy glass cloth or a polyimide glass cloth may be superposed on the multilayer metal foil 9 and heat may be used. The pressure method is formed by heating and pressurizing and laminating. Since the multilayered metal foil 9 is laminated on both sides of the substrate 16 (the upper and lower sides of FIG. 11 (1)) and the subsequent processes are performed, two processes for manufacturing the package substrate 1 can be performed in one process. Therefore, the number of processes can be reduced. Moreover, since it is possible to form a laminated board which is symmetrically formed on both sides of the core substrate 17, it is possible to suppress the bending, and it is also possible to suppress damage due to workability or hooking in a manufacturing facility or the like.
接著,如圖11(2)中所示,在多層金屬箔9的第1載體金屬箔10與第2載體金屬箔11之間,將第1載體金屬箔10作物理性剝離。在第1載體金屬箔10的表面上,會有附著有層積時來自於成為基材16之材料的預浸材等的樹脂粉末等異物的情況。因此,使用此第1載體金屬箔 10來形成電路時,會有由於附著在表面上之樹脂粉末等異物,而在電路中產生斷路或短路等缺陷之情況,並有涉及良率之降低的可能性。但是,由於藉由如此地將第1載體金屬箔10剝離除去,可以使用未附著有樹脂粉末等異物之第2載體金屬箔11來形成電路,故可以抑制電路缺陷之發生,並成為能夠改善良率。又,因為能夠將第1載體金屬箔10作物理性剝離,故藉由調整第1載體金屬箔10與第2載體金屬箔11之間的剝離強度,可以輕易地進行剝離作業。此時,較理想是多層金屬箔9的第1載體金屬箔10與第2載體金屬箔11之間的剝離層(未圖示)係移轉至第1載體金屬箔10側。藉此,由於在將第1載體金屬箔10剝離後之第2載體金屬箔11側,第2載體金屬箔11的表面會露出,故在後續製程中對於第2載體金屬箔11上所進行之鍍膜阻劑之形成或第1圖案鍍膜13之形成不會被剝離層所阻礙。 Next, as shown in Fig. 11 (2), the first carrier metal foil 10 is peelably peeled off between the first carrier metal foil 10 of the multilayered metal foil 9 and the second carrier metal foil 11. On the surface of the first carrier metal foil 10, foreign matter such as a resin powder such as a prepreg which is a material of the substrate 16 may be deposited. Therefore, the first carrier metal foil is used When the circuit is formed in 10, there is a possibility that a defect such as an open circuit or a short circuit occurs in the circuit due to a foreign matter such as a resin powder adhering to the surface, and there is a possibility that the yield is lowered. However, since the first carrier metal foil 10 is peeled off and removed in this manner, the second carrier metal foil 11 to which foreign matter such as resin powder is not adhered can be used to form the circuit. Therefore, it is possible to suppress the occurrence of circuit defects and improve the quality. rate. Moreover, since the first carrier metal foil 10 can be peeled off rationally, the peeling strength can be easily performed by adjusting the peeling strength between the first carrier metal foil 10 and the second carrier metal foil 11. At this time, it is preferable that the peeling layer (not shown) between the first carrier metal foil 10 and the second carrier metal foil 11 of the multilayered metal foil 9 is transferred to the first carrier metal foil 10 side. As a result, the surface of the second carrier metal foil 11 is exposed on the side of the second carrier metal foil 11 after the first carrier metal foil 10 is peeled off, so that it is performed on the second carrier metal foil 11 in the subsequent process. The formation of the plating resist or the formation of the first pattern plating film 13 is not hindered by the peeling layer.
於此,多層金屬箔9較理想是:第2載體金屬箔11與基底金屬箔12之間的剝離強度形成為比第1載體金屬箔10與第2載體金屬箔11之間的剝離強度更大之多層金屬箔9。藉此,在第1載體金屬箔10與第2載體金屬箔11之間作物理性剝離時,可以抑制第2載體金屬箔11與基底金屬箔12之間也同時剝離。作為剝離強度,在加熱、加壓前之初期,若是設為:於第1載體金屬箔10與第2載體金屬箔11之間設為2N/m~50N/m,於第2載體金屬箔11與基底金屬箔12之間設為10N/m~70N/m,且 於第1載體金屬箔10與第2載體金屬箔11之間的剝離強度成為比於第2載體金屬箔11與基底金屬箔12之間的剝離強度小了5N/m~20N/m,則由於不會在製造製程中因處理而剝離,但另一方面在要剝離時又很容易,而且可以抑制在剝離第1載體金屬箔10同時剝離第2載體金屬箔11,故作業性良好。 Here, it is preferable that the multilayer metal foil 9 has a peeling strength between the second carrier metal foil 11 and the base metal foil 12 that is stronger than the peeling strength between the first carrier metal foil 10 and the second carrier metal foil 11. Multi-layer metal foil 9. Thereby, when the first carrier metal foil 10 and the second carrier metal foil 11 are peeled off from the substrate, the second carrier metal foil 11 and the base metal foil 12 can be prevented from being simultaneously peeled off. The peeling strength is set to 2 N/m to 50 N/m between the first carrier metal foil 10 and the second carrier metal foil 11 at the initial stage before the heating and pressurization, and the second carrier metal foil 11 is used. Between 10N/m and 70N/m and the base metal foil 12, and The peeling strength between the first carrier metal foil 10 and the second carrier metal foil 11 is smaller than the peel strength between the second carrier metal foil 11 and the base metal foil 12 by 5 N/m to 20 N/m. In the manufacturing process, it is not easy to be peeled off by the treatment, but on the other hand, it is easy to peel off, and it is possible to prevent the second carrier metal foil 11 from being peeled off while peeling off the first carrier metal foil 10, so that workability is good.
剝離強度之調整,例如,係如同在日本特開2003-181970號公報或日本特開2003-094553號公報、日本再公表專利WO2006/013735號公報中所示,藉由調整成為剝離層的基底之第2載體金屬箔11的表面(與第1載體金屬箔10之間)的粗度後,調整用以形成成為剝離層之金屬氧化物或合金鍍膜層的鍍液組成或條件而成為可能。 The adjustment of the peeling strength is, for example, as shown in JP-A-2003-181970, JP-A-2003-094553, and JP-A-2006-013735, by adjusting the base of the peeling layer. After the thickness of the surface of the second carrier metal foil 11 (between the first carrier metal foil 10) and the plating solution composition or conditions for forming the metal oxide or alloy plating layer to be the release layer, it is possible to adjust the composition or conditions of the plating solution.
接著,如圖11(3)中所示,在殘留於核心基板17上之第2載體金屬箔11上,進行第1圖案鍍膜13。如上所述,由於在第2載體金屬箔11之表面(與第1載體金屬箔10之間)未附著有來自於在層積時所使用之預浸材等的樹脂粉末等異物,故成為能夠抑制起因於此之電路缺陷。第1圖案鍍膜13可在第2載體金屬箔11上形成鍍膜阻劑(未圖示)後,使用電鍍來進行。作為鍍膜阻劑,可使用在封裝基板1之製造程序中所使用的感光性阻劑。作為電鍍,可使用在封裝基板1之製造程序中所使用的硫酸銅鍍膜法。 Next, as shown in FIG. 11 (3), the first pattern plating film 13 is formed on the second carrier metal foil 11 remaining on the core substrate 17. As described above, since the foreign material such as the resin powder such as the prepreg used in the lamination is not adhered to the surface of the second carrier metal foil 11 (between the first carrier metal foil 10), it is possible to Suppress circuit defects caused by this. The first pattern plating film 13 can be formed by plating on the second carrier metal foil 11 after forming a plating resist (not shown). As the plating resist, a photosensitive resist used in the manufacturing process of the package substrate 1 can be used. As the plating, a copper sulfate plating method used in the manufacturing process of the package substrate 1 can be used.
多層金屬箔9較理想是:在預先設置有平均粗度(Ra)為0.3μm~1.2μm之凹凸之第2載體金屬箔11的表面 上,隔著剝離層(未圖示)而層積有第1載體金屬箔10之多層金屬箔9。藉此,在將第1載體金屬箔10與剝離層一同作物理性剝離後之第2載體金屬箔11的表面,具備有預先設置且平均粗度(Ra)為0.3μm~1.2μm之凹凸。因此,在第2載體金屬箔11的表面(與第1載體金屬箔10之間)上形成第1圖案鍍膜13用之鍍膜阻劑時,可以使鍍膜阻劑的密著性和解析度提升,而對高密度電路之形成成為有利。又,因為藉由在第2載體金屬箔11的表面上先設置凹凸,在剝離第1載體金屬箔10後,不需要對第2載體金屬箔11的表面進行粗面化處理,故可以謀求製程數之降低。 The multilayer metal foil 9 is preferably a surface of the second carrier metal foil 11 which is previously provided with irregularities having an average thickness (Ra) of 0.3 μm to 1.2 μm. The multilayer metal foil 9 of the first carrier metal foil 10 is laminated on the peeling layer (not shown). By the way, the surface of the second carrier metal foil 11 after the first carrier metal foil 10 and the peeling layer are peeled off together with the peeling layer are provided with irregularities having a predetermined average thickness (Ra) of 0.3 μm to 1.2 μm. Therefore, when the plating resist for the first pattern plating film 13 is formed on the surface of the second carrier metal foil 11 (between the first carrier metal foil 10), the adhesion and the resolution of the plating resist can be improved. It is advantageous for the formation of high-density circuits. Further, since the unevenness is first provided on the surface of the second carrier metal foil 11, after the first carrier metal foil 10 is peeled off, it is not necessary to roughen the surface of the second carrier metal foil 11, so that the process can be performed. The number is reduced.
設置在第2載體金屬箔11的表面上之凹凸的表面粗度,在改善鍍膜阻劑的密著性或解析度之同時亦可以確保第1圖案鍍膜13後之剝離性的觀點上,較理想是平均粗度(Ra)為0.3μm~1.2μm。當平均粗度(Ra)為未滿0.3μm的情況時,會有發生鍍膜阻劑之密著性不足之傾向,而當平均粗度(Ra)為超過1.2μm的情況時,鍍膜阻劑會變得難以依循表面,還是會有發生密著性不足之傾向。更且,當鍍膜阻劑之線寬/線距成為比15μm/15μm更細微時,平均粗度(Ra)較理想是0.5μm~0.9μm。於此,平均粗度(Ra)意謂以JIS B 0601(2001)所規定之平均粗度(Ra),並能夠使用觸針式表面粗度計等來測定。並且,若第2載體金屬箔11是銅箔,則藉由調整在形成作為第2載體金屬箔11之銅箔時的銅電鍍的組成(包 含添加劑等)或者是條件,平均粗度(Ra)之調整會成為可能。 The surface roughness of the unevenness provided on the surface of the second carrier metal foil 11 is improved from the viewpoint of improving the adhesion or resolution of the plating resist and ensuring the peelability after the first pattern plating film 13 The average roughness (Ra) is from 0.3 μm to 1.2 μm. When the average roughness (Ra) is less than 0.3 μm, there is a tendency that the adhesion of the coating resist is insufficient, and when the average roughness (Ra) is more than 1.2 μm, the coating resist It becomes difficult to follow the surface, and there is a tendency for insufficient adhesion. Further, when the line width/line distance of the coating resist is finer than 15 μm / 15 μm, the average roughness (Ra) is preferably 0.5 μm to 0.9 μm. Here, the average roughness (Ra) means an average thickness (Ra) prescribed by JIS B 0601 (2001), and can be measured using a stylus type surface roughness meter or the like. Further, when the second carrier metal foil 11 is a copper foil, the composition of the copper plating when forming the copper foil as the second carrier metal foil 11 is adjusted (package) With additives or the like, or conditions, adjustment of the average roughness (Ra) is possible.
接著,如圖12(4)中所示,在包含有第1圖案鍍膜13之第2載體金屬箔11上層積絕緣層3來形成層積體22。作為絕緣層3,可使用一般作為封裝基板1的絕緣層3所使用者。作為此種絕緣層3,可舉出環氧系樹脂、聚醯亞胺系樹脂等,例如,可藉由將環氧系或聚醯亞胺系黏著薄片、環氧玻璃布或聚醯亞胺玻璃布等預浸材,使用熱壓法等加熱、加壓來作層積一體化而形成。於此,層積體22意指在如此經層積一體化的狀態者之中,層積於包含有第1圖案鍍膜13之第2載體金屬箔11上者。在成為絕緣層3之該些樹脂上進一步重疊成為導體層20之金屬箔並同時加熱、加壓來層積一體化之情況下,亦包含此導體層20。又,在如後所述之藉由導體層20形成內層電路6後,形成連接導體層20之層間連接5的情況下,亦包含該些內層電路6和層間連接5。 Next, as shown in FIG. 12 (4), the insulating layer 3 is laminated on the second carrier metal foil 11 including the first pattern plating film 13 to form a laminate 22. As the insulating layer 3, a user who is generally the insulating layer 3 of the package substrate 1 can be used. Examples of the insulating layer 3 include an epoxy resin, a polyimide resin, and the like. For example, an epoxy-based or polyimide-based adhesive sheet, an epoxy glass cloth, or a polyimide may be used. A prepreg such as a glass cloth is formed by laminating and integrating heat and pressure using a hot press method or the like. Here, the laminate 22 means that it is laminated on the second carrier metal foil 11 including the first pattern plating film 13 among the states in which the layers are integrated as described above. When the metal foil which becomes the conductor layer 20 is further superposed on the resin which becomes the insulating layer 3, and it fuses at the same time by heating and pressure-combining, it is also including this conductor layer 20. Further, in the case where the interlayer circuit 6 is formed by the conductor layer 20 as will be described later, and the interlayer connection 5 of the connection conductor layer 20 is formed, the inner layer circuit 6 and the interlayer connection 5 are also included.
接著,如圖12(5)、(6)中所示,形成層間連接孔21,並可形成層間連接5和內層電路6。層間連接5,例如,可藉由使用所謂的保形(conformal)工法來形成層間連接孔21後,再將此層間連接孔21內鍍膜來形成。在此鍍膜中,可進行薄層無電解銅鍍膜來作為基底鍍膜後,再使用無電解銅鍍膜或銅電鍍、填孔鍍膜等來作為厚層鍍膜。為了將受蝕刻之導體層20的厚度薄化而使其容易形成細微電路,較理想是在薄層基底鍍膜後形成鍍膜阻劑,並 利用銅電鍍或填孔鍍膜來進行厚層鍍膜。內層電路6,例如,可藉由在進行對層間連接孔21之鍍膜後,再藉由蝕刻來將不必要部分之導體層20除去而形成。 Next, as shown in Figs. 12 (5), (6), interlayer connection holes 21 are formed, and the interlayer connection 5 and the inner layer circuit 6 can be formed. The interlayer connection 5 can be formed, for example, by forming a layer connection hole 21 by using a so-called conformal method, and then plating the interlayer connection hole 21 therein. In this plating film, a thin layer electroless copper plating film can be used as a base plating film, and then an electroless copper plating film, a copper plating, a hole-fill plating film, or the like can be used as a thick layer plating film. In order to thin the thickness of the etched conductor layer 20 to form a fine circuit, it is preferable to form a plating resist after coating the thin layer substrate, and Thick plating is performed by copper plating or hole filling plating. The inner layer circuit 6 can be formed, for example, by performing plating on the interlayer connection hole 21 and then removing unnecessary portions of the conductor layer 20 by etching.
接著,亦可如圖13(7)、(8)以及圖14(9)、(10)中所示,在內層電路6和層間連接5之上,進一步形成絕緣層3與導體層20,並與圖12(5)、(6)時相同地,以成為所欲之層數的方式,來形成內層電路6和外層電路2、7、層間連接5。並且,在本發明中,係有著將內層電路6與外層電路2、7合併稱為導體電路的情況。 Then, as shown in FIGS. 13(7), (8) and FIGS. 14(9) and (10), the insulating layer 3 and the conductor layer 20 are further formed on the inner layer circuit 6 and the interlayer connection 5, Similarly to the case of Figs. 12 (5) and (6), the inner layer circuit 6, the outer layer circuits 2, 7, and the interlayer connection 5 are formed so as to have a desired number of layers. Further, in the present invention, the inner layer circuit 6 and the outer layer circuits 2, 7 are collectively referred to as a conductor circuit.
接著,如圖15(11)中所示,在多層金屬箔9的第2載體金屬箔11與基底金屬箔12之間,將層積體22與第2載體金屬箔11一同從核心基板17作物理性剝離來分離。此時,較理想是在多層金屬箔9的第2載體金屬箔11與基底金屬箔12之間的剝離層(未圖示)被移轉至基底金屬箔12側。藉此,由於在將基底金屬箔12剝離後之層積體22側,第2載體金屬箔11之表面會露出,故在後續製程中所進行之第2載體金屬箔11的蝕刻不會被剝離層所阻礙。 Next, as shown in Fig. 15 (11), between the second carrier metal foil 11 of the multilayered metal foil 9 and the base metal foil 12, the laminate 22 and the second carrier metal foil 11 are collectively cropped from the core substrate 17 Rational stripping to separate. At this time, it is preferable that the peeling layer (not shown) between the second carrier metal foil 11 of the multilayered metal foil 9 and the base metal foil 12 is transferred to the base metal foil 12 side. Thereby, since the surface of the second carrier metal foil 11 is exposed on the side of the laminate 22 after the base metal foil 12 is peeled off, the etching of the second carrier metal foil 11 performed in the subsequent process is not peeled off. The layer is hindered.
接著,如圖16(12)~(14)中所示,藉由在經分離而剝離之層積體22的第2載體金屬箔11上形成蝕刻阻劑34,並蝕刻層積體22的第2載體金屬箔11,使前述第1圖案鍍膜13露出於絕緣層3之表面而形成內埋電路2後,在第1圖案鍍膜13上或絕緣層3上形成立體電路27。又,亦可如圖17(12)~(14)中所示,藉由在經分離而 剝離之層積體22的第2載體金屬箔11上進行第2圖案鍍膜14,並在進行了第2圖案鍍膜之部分以外的載體金屬箔上形成蝕刻阻劑來進行蝕刻,來將進行了第2圖案鍍膜14之部分以及形成有蝕刻阻劑之部分以外的第2載體金屬箔11藉由蝕刻而除去,並使第1圖案鍍膜13露出於絕緣層3的表面而形成內埋電路2後,在第1圖案鍍膜13上或絕緣層3上形成立體電路27。並且,圖16(12)~(14)以及圖17(12)~(14)僅表示如圖15(11)地分離之層積體22中的下側之部分。藉由圖16(12)~(14)或圖17(12)~(14)之製程來使第1圖案鍍膜13從絕緣層3露出所形成之內埋電路2可形成倒裝晶片連接端子,形成在層積體表面的第1圖案鍍膜上之立體電路27可形成凸塊或柱體(pillar),形成在層積體表面的絕緣層上之立體電路27可形成虛設端子。藉此,由於在形成外層電路2時,因為外層電路2的側面不會被蝕刻所侵蝕,而不會產生底切現象,故可以形成細微之外層電路2。又,利用本發明所形成之外層電路2因為係成為被內埋至絕緣層3中之狀態,故不僅是外層電路2的底面,其兩側之側面亦與絕緣層3密著,因此,即使是細微電路,亦可確保充分之密著性。又,作為第2載體金屬箔11而使用厚度1μm~5μm之極薄銅箔的情況下,因為即使些許之蝕刻量,亦可以將第2載體金屬箔11除去,故被內埋至絕緣層3中但從絕緣層3露出之外層電路2的表面是平坦的,藉由將其設為打線接合端子或倒裝晶片連接端子,可以確保連 接可靠性,而適合作為與半導體元件之連接端子來使用。又,因為能夠將與半導體元件之連接端子設置在俯視時位於與層間連接5相重疊之位置的外層電路2處,故能夠將與半導體元件之連接端子設置在層間連接5的正上方或正下方,而能夠對應於小型化、高密度化。更且,因為藉由在任意處形成立體電路27,能夠形成凸塊或柱體、虛設端子等各種導體電路的構成,藉由改變第2載體金屬箔11或第2圖案鍍膜14之厚度,亦能夠形成為任意之高度,故可以對應於與各種半導體元件(未圖示)或其他封裝基板之連接形態。例如,如圖18中所示,藉由在本發明之封裝基板1的第1圖案鍍膜13上設置立體電路27而形成柱體,來進行與頂部基板之連接,即使不設置孔洞(cavity),亦成為能夠構成PoP(堆疊式封裝)。又,在如圖18中所示之半導體元件35側的凸塊25是週邊式配置(凸塊25並排配置在半導體元件35之周圍)的情況時,若是於倒裝晶片連接時將半導體元件35壓接至半導體元件搭載用封裝基板1側,則半導體元件35的中央部會容易撓曲而變形,但由於藉由先設置虛設端子(在圖18中,係為被形成在絕緣層上之立體電路27)可以支撐半導體元件35的下側之面,故可以抑制變形。又,若是以其與第1圖案鍍膜和層間連接5連接的方式來來形成虛設端子,則亦可以將來自於半導體元件35之熱作放熱。因此,可以提昇可靠性。並且,虛設端子意謂電性獨立且並不作為電子電路來作用者,雖在圖16、圖17中係被形成在 絕緣層上,但亦可連接於被設為不會電性地作用之第1圖案鍍膜或層間連接5。 Next, as shown in FIGS. 16(12) to (14), the etching resist 34 is formed on the second carrier metal foil 11 of the laminate 22 which is separated and separated, and the laminate 22 is etched. In the carrier metal foil 11, the first pattern plating film 13 is exposed on the surface of the insulating layer 3 to form the buried circuit 2, and then the three-dimensional circuit 27 is formed on the first pattern plating film 13 or the insulating layer 3. Also, as shown in FIGS. 17(12) to (14), by being separated The second pattern plating film 14 is formed on the second carrier metal foil 11 of the peeled laminate 22, and an etching resist is formed on the carrier metal foil other than the portion where the second pattern plating film is formed, and etching is performed. The portion of the pattern plating film 14 and the second carrier metal foil 11 other than the portion where the etching resist is formed are removed by etching, and the first pattern plating film 13 is exposed on the surface of the insulating layer 3 to form the buried circuit 2, A stereo circuit 27 is formed on the first pattern plating film 13 or on the insulating layer 3. Further, FIGS. 16(12) to (14) and FIGS. 17(12) to (14) show only the lower portion of the laminate 22 separated as shown in FIG. 15 (11). The flip chip connection terminal can be formed by the buried circuit 2 formed by exposing the first pattern plating film 13 from the insulating layer 3 by the processes of FIGS. 16(12) to (14) or FIGS. 17(12) to (14). The three-dimensional circuit 27 formed on the first pattern plating film on the surface of the laminate may form a bump or a pillar, and the three-dimensional circuit 27 formed on the insulating layer on the surface of the laminate may form a dummy terminal. Thereby, since the side surface of the outer layer circuit 2 is not eroded by the etching when the outer layer circuit 2 is formed, the undercut phenomenon can be formed, so that the fine outer layer circuit 2 can be formed. Further, since the outer layer circuit 2 formed by the present invention is buried in the insulating layer 3, not only the bottom surface of the outer layer circuit 2 but also the side surfaces on both sides thereof are in close contact with the insulating layer 3, so that even It is a fine circuit that also ensures sufficient adhesion. Further, when an extremely thin copper foil having a thickness of 1 μm to 5 μm is used as the second carrier metal foil 11, since the second carrier metal foil 11 can be removed even with a small amount of etching, it is buried in the insulating layer 3 However, the surface of the outer layer circuit 2 is exposed from the insulating layer 3, and the surface of the outer layer circuit 2 is flat, and it can be ensured by setting it as a wire bonding terminal or a flip chip connection terminal. It is suitable for use as a connection terminal to a semiconductor element. Moreover, since the connection terminal with the semiconductor element can be provided in the outer layer circuit 2 at a position overlapping the interlayer connection 5 in a plan view, the connection terminal with the semiconductor element can be provided directly above or below the interlayer connection 5. Moreover, it can respond to miniaturization and high density. Further, by forming the three-dimensional circuit 27 at an arbitrary position, it is possible to form a structure of various conductor circuits such as bumps, pillars, and dummy terminals, and by changing the thickness of the second carrier metal foil 11 or the second pattern plating film 14, Since it can be formed in any height, it can respond to the connection form with various semiconductor elements (not shown) or other package board. For example, as shown in FIG. 18, a column body is provided on the first pattern plating film 13 of the package substrate 1 of the present invention to form a pillar, and the connection to the top substrate is performed, even if no cavity is provided. It also becomes a PoP (Stacked Package). Further, in the case where the bumps 25 on the side of the semiconductor element 35 shown in FIG. 18 are in a peripheral arrangement (the bumps 25 are arranged side by side around the semiconductor element 35), the semiconductor element 35 is formed when the flip chip is connected. When the semiconductor element 35 is bent to the side of the semiconductor element mounting package substrate 1, the central portion of the semiconductor element 35 is easily bent and deformed. However, since the dummy terminal is provided first (in FIG. 18, it is a three-dimensional formed on the insulating layer). The circuit 27) can support the lower surface of the semiconductor element 35, so that deformation can be suppressed. Further, if the dummy terminal is formed so as to be connected to the first pattern plating film and the interlayer connection 5, the heat from the semiconductor element 35 can be released. Therefore, reliability can be improved. Moreover, the dummy terminal means that it is electrically independent and does not function as an electronic circuit, although it is formed in FIG. 16 and FIG. The insulating layer may be connected to the first pattern plating or the interlayer connection 5 which is not electrically operated.
接著,可因應需要而形成焊料阻劑4或保護鍍膜8。作為保護鍍膜8,較理想是一般作為封裝基板之連接端子的保護鍍膜所使用之鎳鍍膜與金鍍膜。 Next, the solder resist 4 or the protective plating film 8 can be formed as needed. As the protective plating film 8, a nickel plating film and a gold plating film which are generally used as a protective plating film for a connection terminal of a package substrate are preferable.
如上所述,若依據本發明之封裝基板之製造方法,則可以形成一種封裝基板,其在與層間連接相重疊的位置具備有平坦且細微之內埋電路,而可以形成適合於打線接合或倒裝晶片連接之封裝基板。又,藉由在任意處形成立體電路,可以形成具備有凸塊或柱體等各種金屬構成之封裝基板。 As described above, according to the manufacturing method of the package substrate of the present invention, it is possible to form a package substrate which is provided with a flat and fine buried circuit at a position overlapping the interlayer connection, and can be formed to be suitable for wire bonding or pouring. A package substrate on which a wafer is attached. Further, by forming a three-dimensional circuit at an arbitrary position, it is possible to form a package substrate including various metals such as bumps or pillars.
接著,針對本發明之封裝基板的其他製造方法之實施例來作說明,但本發明並不限於本實施例。 Next, an embodiment of another manufacturing method of the package substrate of the present invention will be described, but the present invention is not limited to the embodiment.
首先,如圖10中所示,準備了將第1載體金屬箔10、第2載體金屬箔11、與基底金屬箔12依此順序層積之多層金屬箔9。第1載體金屬箔10使用9μm之銅箔,第2載體金屬箔11使用3μm之極薄銅箔,基底金屬箔12使用18μm之銅箔。在基底金屬箔12之表面(與第2載體金屬箔11之間),以能夠作物理性剝離的方式設置了剝離層(未圖示)。又,在第2載體金屬箔11之表面( 與第1載體金屬箔10之間),預先設置有平均粗度(Ra)0.7μm之凹凸。又,在此凹凸上,亦即在與第1載體金屬箔10之間,以成為能夠作物理性剝離之方式設置了剝離層(未圖示)。在基底金屬箔12與第2載體金屬箔11之間、以及在第2載體金屬箔11與第1載體金屬箔10之間的剝離層,均為藉由使用具有Ni 30g/L、Mo 3.0g/L、檸檬酸30g/L之組成的鍍敷浴來形成金屬氧化物層而形成。並且,剝離強度之調整,係藉由調整電流來調整形成剝離層之金屬氧化物量而進行。此時之剝離強度,在基底金屬箔12與第2載體金屬箔11之間係47N/m,在第2載體金屬箔11與第1載體金屬箔10之間係29N/m。並且,在加熱、加壓後(將成為基材16之預浸材作層積而形成了核心基板17後)之剝離強度的變化率,係相對於初期上升了約10%程度之程度。 First, as shown in FIG. 10, the multilayer metal foil 9 in which the first carrier metal foil 10, the second carrier metal foil 11, and the base metal foil 12 are laminated in this order is prepared. The first carrier metal foil 10 used a copper foil of 9 μm, the second carrier metal foil 11 used an ultra-thin copper foil of 3 μm, and the base metal foil 12 used a copper foil of 18 μm. A peeling layer (not shown) is provided on the surface of the base metal foil 12 (between the second carrier metal foil 11) so as to be capable of peeling off the crop. Further, on the surface of the second carrier metal foil 11 ( Concavities and convexities having an average thickness (Ra) of 0.7 μm are provided in advance between the first carrier metal foil 10 and the first carrier metal foil 10 . Further, on the unevenness, that is, a peeling layer (not shown) is provided between the first carrier metal foil 10 and the first carrier metal foil 10 so as to be capable of peeling off the crop. The peeling layer between the base metal foil 12 and the second carrier metal foil 11 and between the second carrier metal foil 11 and the first carrier metal foil 10 is made of Ni 30 g/L and Mo 3.0 g by use. A plating bath having a composition of /L and citric acid of 30 g/L was formed to form a metal oxide layer. Further, the adjustment of the peel strength is performed by adjusting the current to adjust the amount of the metal oxide forming the peeling layer. The peel strength at this time was 47 N/m between the base metal foil 12 and the second carrier metal foil 11, and 29 N/m between the second carrier metal foil 11 and the first carrier metal foil 10. In addition, the rate of change in peel strength after heating and pressurization (after the core substrate 17 is formed by laminating the prepreg of the substrate 16) is about 10% higher than the initial stage.
在圖10中所示之多層金屬箔9的製作,具體而言係如下所示地進行。 The production of the multilayered metal foil 9 shown in Fig. 10 is specifically carried out as follows.
(1)作為基底金屬箔12,使用厚度18μm之電解銅箔,並在硫酸30g/L中作60秒的浸漬,進行酸洗淨後再以流水進行30秒之水洗。 (1) As the base metal foil 12, an electrolytic copper foil having a thickness of 18 μm was used, and immersed in 30 g/L of sulfuric acid for 60 seconds, and after acid washing, it was washed with running water for 30 seconds.
(2)將洗淨之電解銅箔作為陰極,並將施行了氧化銥塗佈之Ti(鈦)極板作為陽極,作為含有Ni(鎳)、Mo(鉬)、檸檬酸之鍍敷浴,在硫酸鎳6水合物30g/L、鉬酸鈉2水合物3.0g/L、檸檬酸3鈉2水合物30g/L、pH6.0、液溫30℃之浴中,於電解銅箔之光澤面上,以 電流密度20A/dm2來電解處理5秒鐘,而形成包含有由鎳與鉬所成之金屬氧化物之剝離層(未圖示)。 (2) using the washed electrolytic copper foil as a cathode, and using a Ti (titanium) plate coated with ruthenium oxide as an anode, and as a plating bath containing Ni (nickel), Mo (molybdenum), and citric acid. In the bath of nickel sulfate 6 hydrate 30g / L, sodium molybdate 2 hydrate 3.0g / L, citrate 3 sodium dihydrate 30g / L, pH 6.0, liquid temperature 30 ° C, the gloss of electrolytic copper foil The surface was electrolytically treated at a current density of 20 A/dm 2 for 5 seconds to form a peeling layer (not shown) containing a metal oxide made of nickel and molybdenum.
(3)在形成剝離層(未圖示)後之表面上,在硫酸銅5水合物200g/L、硫酸100g/L、液溫40℃之浴,將施行了氧化銥塗佈之Ti(鈦)極板作為陽極,以電流密度4A/dm2電鍍200秒,而形成厚度3μm之成為第2載體金屬箔11之金屬層。 (3) On the surface after forming a peeling layer (not shown), Ti (Titanium) coated with yttria is applied in a bath of copper sulfate 5 hydrate 200 g/L, sulfuric acid 100 g/L, and liquid temperature 40 ° C. The electrode plate was used as an anode, and was plated at a current density of 4 A/dm 2 for 200 seconds to form a metal layer of the second carrier metal foil 11 having a thickness of 3 μm.
(4)在形成了成為第2載體金屬箔11之金屬層後的表面上,使用與上述(2)相同之浴以電流密度10A/dm2電解處理10秒,而形成含有由鎳與鉬所成之金屬氧化物之剝離層(未圖示)。 (4) On the surface on which the metal layer to be the second carrier metal foil 11 is formed, the same bath as in the above (2) is subjected to electrolytic treatment at a current density of 10 A/dm 2 for 10 seconds to form a nickel-containing molybdenum layer. A release layer of a metal oxide (not shown).
(5)在形成了剝離層13後的表面上,使用與上述(3)相同之浴,以電流密度4A/dm2來進行600秒之電鍍,而形成厚度9μm之成為第1載體金屬箔10之金屬層。 (5) On the surface on which the peeling layer 13 was formed, the same bath as in the above (3) was used, and plating was performed for 600 seconds at a current density of 4 A/dm 2 to form a first carrier metal foil 10 having a thickness of 9 μm. The metal layer.
(6)在與基材16接觸之面上,藉由硫酸銅鍍膜來形成粒狀之粗化粒子,並施行鉻酸鹽處理以及矽烷耦合劑處理。又,對於不與基材16接觸之面施行鉻酸鹽處理。 (6) Granular roughened particles are formed on the surface in contact with the substrate 16 by copper sulfate plating, and chromate treatment and decane coupling agent treatment are performed. Further, a chromate treatment is applied to the surface not in contact with the substrate 16.
接著,如圖11(1)中所示,將多層金屬箔9之基底金屬箔12側與基材16作層積來形成核心基板17。作為基材16,使用環氧玻璃布之預浸材,並在此預浸材的上下兩側重疊多層金屬箔9,再使用熱壓法進行加熱、加壓而層積一體化。 Next, as shown in Fig. 11 (1), the base metal foil 12 side of the multilayered metal foil 9 is laminated with the substrate 16 to form the core substrate 17. As the base material 16, a prepreg of epoxy glass cloth is used, and the multilayer metal foil 9 is placed on the upper and lower sides of the prepreg, and then heated and pressurized by a hot press method to be integrated.
接著,如圖11(2)中所示,在多層金屬箔9的第1載體金屬箔10與第2載體金屬箔11之間,將第1載體金 屬箔10作物理性剝離。 Next, as shown in Fig. 11 (2), the first carrier gold is placed between the first carrier metal foil 10 of the multilayer metal foil 9 and the second carrier metal foil 11. Is a foil 10 crop rational stripping.
接著,如圖11(3)中所示,在殘留於核心基板17上之第2載體金屬箔11上進行第1圖案鍍膜13。第1圖案鍍膜13係在第2載體金屬箔11上形成感光性之鍍膜阻劑後再使用硫酸銅電鍍來形成。 Next, as shown in FIG. 11 (3), the first pattern plating film 13 is formed on the second carrier metal foil 11 remaining on the core substrate 17. The first pattern plating film 13 is formed by forming a photosensitive plating resist on the second carrier metal foil 11 and then plating it with copper sulfate.
接著,如圖12(4)中所示,在包含有第1圖案鍍膜13之第2載體金屬箔11上,層積絕緣層3與作為導體層20之銅箔(12μm)來形成層積體22。作為絕緣層3,係藉由將環氧系之黏著薄片使用熱壓法加熱、加壓而層積一體化來形成。 Next, as shown in FIG. 12 (4), the insulating layer 3 and the copper foil (12 μm) as the conductor layer 20 are laminated on the second carrier metal foil 11 including the first pattern plating film 13 to form a laminate. twenty two. The insulating layer 3 is formed by laminating and integrating an epoxy-based adhesive sheet by hot pressing and pressurization.
接著,如圖12(5)、(6)中所示,形成層間連接5和內層電路6。層間連接5係藉由在使用保形工法形成了層間連接孔21後,將此層間連接孔21內鍍膜來形成。在此鍍膜中,作為基底鍍膜進行薄層無電解銅鍍膜後,形成感光性之鍍膜阻劑,再以硫酸銅電鍍進行厚層鍍膜。之後,藉由蝕刻來將不必要部分之導體層20除去,以形成內層電路6。 Next, as shown in Figs. 12 (5) and (6), the interlayer connection 5 and the inner layer circuit 6 are formed. The interlayer connection 5 is formed by depositing a layer in the interlayer connection hole 21 after forming the interlayer connection hole 21 by a conformal method. In this plating film, after a thin layer electroless copper plating film is applied as a base plating film, a photosensitive plating resist is formed, and a thick layer plating is performed by copper sulfate plating. Thereafter, the unnecessary portion of the conductor layer 20 is removed by etching to form the inner layer circuit 6.
接著,如圖13(7)、(8)以及圖14(9)、(10)中所示,在內層電路6和層間連接5之上,進一步形成絕緣層3與導體層20,並形成內層電路6和外層電路2、7、層間連接5,而形成了具備有4層之導體層20之層積體22。 Next, as shown in FIGS. 13 (7), (8), and FIGS. 14 (9), (10), on the inner layer circuit 6 and the interlayer connection 5, the insulating layer 3 and the conductor layer 20 are further formed and formed. The inner layer circuit 6 and the outer layer circuits 2, 7 and the interlayer connection 5 form a laminate 22 having four conductor layers 20.
接著,如圖15(11)中所示,在多層金屬箔9的第2載體金屬箔11與基底金屬箔12之間,將層積體22與第2 載體金屬箔11一同地從核心基板17作物理性剝離而分離。 Next, as shown in FIG. 15 (11), between the second carrier metal foil 11 of the multilayer metal foil 9 and the base metal foil 12, the laminate 22 and the second layer are formed. The carrier metal foil 11 is separated from the core substrate 17 by crop rational separation.
接著,如圖16(12)~(14)中所示,在經分離而剝離之層積體22的第2載體金屬箔11上形成蝕刻阻劑14,再蝕刻層積體22的第2載體金屬箔11,使前述第1圖案鍍膜13露出於前述絕緣層3的表面而形成內埋電路2,並在第1圖案鍍膜13上或絕緣層3上形成立體電路27。並且,使第1圖案鍍膜13從絕緣層3露出所形成之內埋電路2係作為倒裝晶片連接端子,形成在層積體表面之第1圖案鍍膜上的立體電路27係作為凸塊,形成在層積體表面之絕緣層上的立體電路27係作為虛設端子。 Next, as shown in FIGS. 16(12) to (14), an etching resist 14 is formed on the second carrier metal foil 11 of the laminated body 22 which is separated and separated, and the second carrier of the laminated body 22 is etched again. In the metal foil 11, the first pattern plating film 13 is exposed on the surface of the insulating layer 3 to form the buried circuit 2, and the three-dimensional circuit 27 is formed on the first pattern plating film 13 or the insulating layer 3. Further, the buried circuit 2 formed by exposing the first pattern plating film 13 from the insulating layer 3 serves as a flip chip connection terminal, and the three-dimensional circuit 27 formed on the first pattern plating film on the surface of the laminate is formed as a bump. The three-dimensional circuit 27 on the insulating layer on the surface of the laminate is used as a dummy terminal.
接著,形成感光性之焊料阻劑,之後,作為保護鍍膜,進行無電解鎳鍍膜與無電解金鍍膜,而形成封裝基板。 Next, a photosensitive solder resist is formed, and then, as a protective plating film, an electroless nickel plating film and an electroless gold plating film are formed to form a package substrate.
在基底金屬箔12與第2載體金屬箔11之間、以及在第2載體金屬箔11與第1載體金屬箔10之間的剝離強度,均藉由將使用具有Ni(鎳)30g/L、Mo(鉬)3.0g/L、檸檬酸30g/L之組成的鍍敷浴形成金屬氧化物層時之電流作改變來調整形成剝離層之金屬氧化物量,以使其作改變。此時之剝離強度,在基底金屬箔12與第2載體金屬箔11之間係23N/m,在第2載體金屬箔11與第1載體金屬箔10之間係18N/m。除此之外,係與實施例1相同地製作了封裝基板。 The peeling strength between the base metal foil 12 and the second carrier metal foil 11 and between the second carrier metal foil 11 and the first carrier metal foil 10 is 30 g/L by using Ni (nickel). The current in the case where the plating bath of Mo (molybdenum) 3.0 g/L and citric acid 30 g/L was formed to form a metal oxide layer was changed to adjust the amount of the metal oxide forming the peeling layer to be changed. The peel strength at this time was 23 N/m between the base metal foil 12 and the second carrier metal foil 11, and 18 N/m between the second carrier metal foil 11 and the first carrier metal foil 10. A package substrate was produced in the same manner as in Example 1 except for the above.
在基底金屬箔12與第2載體金屬箔11之間、以及在第2載體金屬箔11與第1載體金屬箔10之間的剝離強度,均係藉由將使用具有Ni(鎳)30g/L、Mo(鉬)3.0g/L、檸檬酸30g/L之組成的鍍敷浴形成金屬氧化物層時之電流作改變來調整形成剝離層之金屬氧化物量,以使其作改變。此時之剝離強度,在基底金屬箔12與第2載體金屬箔11之間係15N/m,在第2載體金屬箔11與第1載體金屬箔10之間係2N/m。除此之外,係與實施例1相同地製作了封裝基板。 The peeling strength between the base metal foil 12 and the second carrier metal foil 11 and between the second carrier metal foil 11 and the first carrier metal foil 10 is achieved by using Ni (nickel) 30 g/L. The current in the case where the plating bath of Mo (molybdenum) 3.0 g/L and citric acid 30 g/L was formed to form a metal oxide layer was changed to adjust the amount of the metal oxide forming the peeling layer to change it. The peel strength at this time was 15 N/m between the base metal foil 12 and the second carrier metal foil 11, and 2 N/m between the second carrier metal foil 11 and the first carrier metal foil 10. A package substrate was produced in the same manner as in Example 1 except for the above.
在基底金屬箔12與第2載體金屬箔11之間、以及在第2載體金屬箔11與第1載體金屬箔10之間的剝離強度,均係藉由將使用具有Ni(鎳)30g/L、Mo(鉬)3.0g/L、檸檬酸30g/L之組成的鍍敷浴形成金屬氧化物層時之電流作改變來調整形成剝離層之金屬氧化物量,以使其作改變。此時之剝離強度,在基底金屬箔12與第2載體金屬箔11之間係68N/m,在第2載體金屬箔11與第1載體金屬箔10之間係48N/m。 The peeling strength between the base metal foil 12 and the second carrier metal foil 11 and between the second carrier metal foil 11 and the first carrier metal foil 10 is achieved by using Ni (nickel) 30 g/L. The current in the case where the plating bath of Mo (molybdenum) 3.0 g/L and citric acid 30 g/L was formed to form a metal oxide layer was changed to adjust the amount of the metal oxide forming the peeling layer to change it. The peel strength at this time was 68 N/m between the base metal foil 12 and the second carrier metal foil 11, and 48 N/m between the second carrier metal foil 11 and the first carrier metal foil 10.
使用上述所準備之多層金屬箔9,不進行實施例1之圖16(12)~(14)中所示之製程,而如圖17(12)~(14)中所示,在經分離而剝離之層積體22的第2載體 金屬箔11上,進行第2圖案鍍膜14,並在進行了第2圖案鍍膜之部分以外的載體金屬箔上形成蝕刻阻劑34並進行蝕刻後,將進行了第2圖案鍍膜14之部分以及形成有蝕刻阻劑的部分以外的第2載體金屬箔11藉由蝕刻來除去,使第1圖案鍍膜13露出於絕緣層3的表面而形成內埋電路2,並且在第1圖案鍍膜13上或是絕緣層3上形成立體電路27。並且,使第1圖案鍍膜13從絕緣層3露出所形成之內埋電路2係作為倒裝晶片連接端子,形成在層積體表面之第1圖案鍍膜上的立體電路27係作為柱體,形成在層積體表面之絕緣層上的立體電路27係作為虛設端子。除了此製程之外,係與實施例1相同地製作了封裝基板。 Using the multilayer metal foil 9 prepared above, the process shown in FIGS. 16(12) to (14) of the first embodiment is not performed, and as shown in FIGS. 17(12) to (14), it is separated. Second carrier of the peeled laminate 22 The second pattern plating film 14 is formed on the metal foil 11, and the etching resist 34 is formed on the carrier metal foil other than the portion where the second pattern plating film is formed, and the etching is performed, and then the second pattern plating film 14 is formed and formed. The second carrier metal foil 11 other than the portion having the etching resist is removed by etching, and the first pattern plating film 13 is exposed on the surface of the insulating layer 3 to form the buried circuit 2, and is formed on the first pattern plating film 13 or A stereo circuit 27 is formed on the insulating layer 3. Further, the buried circuit 2 formed by exposing the first pattern plating film 13 from the insulating layer 3 serves as a flip chip connecting terminal, and the three-dimensional circuit 27 formed on the first pattern plating film on the surface of the laminated body is formed as a pillar. The three-dimensional circuit 27 on the insulating layer on the surface of the laminate is used as a dummy terminal. A package substrate was produced in the same manner as in Example 1 except for this process.
在基底金屬箔12與第2載體金屬箔11之間、以及在第2載體金屬箔11與第1載體金屬箔10之間的剝離強度,均係藉由將使用具有Ni(鎳)30g/L、Mo(鉬)3.0g/L、檸檬酸30g/L之組成的鍍敷浴形成金屬氧化物層時之電流作改變來調整形成剝離層之金屬氧化物量,以使其作改變。此時之剝離強度,在基底金屬箔12與第2載體金屬箔11之間係43N/m,在第2載體金屬箔11與第1載體金屬箔10之間係28N/m。除此之外,係與實施例4相同地製作了封裝基板。 The peeling strength between the base metal foil 12 and the second carrier metal foil 11 and between the second carrier metal foil 11 and the first carrier metal foil 10 is achieved by using Ni (nickel) 30 g/L. The current in the case where the plating bath of Mo (molybdenum) 3.0 g/L and citric acid 30 g/L was formed to form a metal oxide layer was changed to adjust the amount of the metal oxide forming the peeling layer to change it. The peel strength at this time was 43 N/m between the base metal foil 12 and the second carrier metal foil 11, and 28 N/m between the second carrier metal foil 11 and the first carrier metal foil 10. A package substrate was produced in the same manner as in Example 4 except for the above.
在基底金屬箔12與第2載體金屬箔11之間、以及在第2載體金屬箔11與第1載體金屬箔10之間的剝離強度,均係藉由將使用具有Ni(鎳)30g/L、Mo(鉬)3.0g/L、檸檬酸30g/L之組成的鍍敷浴形成金屬氧化物層時之電流作改變來調整形成剝離層之金屬氧化物量,以使其作改變。此時之剝離強度,在基底金屬箔12與第2載體金屬箔11之間係22N/m,在第2載體金屬箔11與第1載體金屬箔10之間係4N/m。除此之外,係與實施例4相同地製作了封裝基板。 The peeling strength between the base metal foil 12 and the second carrier metal foil 11 and between the second carrier metal foil 11 and the first carrier metal foil 10 is achieved by using Ni (nickel) 30 g/L. The current in the case where the plating bath of Mo (molybdenum) 3.0 g/L and citric acid 30 g/L was formed to form a metal oxide layer was changed to adjust the amount of the metal oxide forming the peeling layer to change it. The peel strength at this time was 22 N/m between the base metal foil 12 and the second carrier metal foil 11, and 4 N/m between the second carrier metal foil 11 and the first carrier metal foil 10. A package substrate was produced in the same manner as in Example 4 except for the above.
於表1中,針對實施例1~6,顯示了內埋至絕緣層3中所形成之外層電路2的最終狀態、第1載體金屬箔10與第2載體金屬箔11之間的剝離強度、第2載體金屬箔11與基底金屬箔12之間的剝離強度、處理時載體金屬箔之剝落的有無。在實施例1~6之任一者中,均可以形成線寬/線距至10μm/10μm程度之細微之外層電路2(表1中之○表示不存在底切現象)。又,觀察剖面之結果,任一者均未發生有底切現象。更且,由剖面之觀察結果,因為第2載體金屬箔11係使用了3μm之極薄銅箔,故僅利用些許之蝕刻量便會均一地除去,且外層電路2之表面的凹凸平坦。又,實施例1~6中之任一者,均並未有由於在製造製程中的處理而在第1載體金屬箔10與第2載體金屬箔11之間、或在第2載體金屬箔11與基底金屬箔12之間剝落的情況(表1之○表示無剝落)。又,在將第 1載體金屬箔10與第2載體金屬箔11之間作剝離時,第2載體金屬箔11與基底金屬箔12之間並無剝離。 In Table 1, in the first to sixth embodiments, the final state of the outer layer circuit 2 formed in the insulating layer 3, the peel strength between the first carrier metal foil 10 and the second carrier metal foil 11, and the peel strength between the first carrier metal foil 10 and the second carrier metal foil 11 are shown. The peeling strength between the second carrier metal foil 11 and the base metal foil 12, and the presence or absence of peeling of the carrier metal foil during the treatment. In any of the first to sixth embodiments, the fine outer layer circuit 2 having a line width/line pitch of about 10 μm/10 μm can be formed (○ in the table 1 indicates that there is no undercut phenomenon). Further, as a result of observing the cross section, no undercut occurred in either of them. Further, as a result of the observation of the cross section, since the second carrier metal foil 11 is made of an ultra-thin copper foil of 3 μm, it is uniformly removed by a small amount of etching, and the unevenness of the surface of the outer layer circuit 2 is flat. Further, none of the examples 1 to 6 is between the first carrier metal foil 10 and the second carrier metal foil 11 or the second carrier metal foil 11 due to the treatment in the manufacturing process. The case of peeling off from the base metal foil 12 (○ in Table 1 indicates no peeling). Again, in the first When the carrier metal foil 10 and the second carrier metal foil 11 are peeled off, there is no peeling between the second carrier metal foil 11 and the base metal foil 12.
如圖18中所示,對實施例4中所製作之封裝基板(圖17(14))的內埋電路2壓接半導體元件35之凸塊25,並使用焊料(未圖示)作倒裝晶片連接。半導體元件35之凸塊25係週邊配置,但因為有將半導體元件35之下側之面作為虛設端子之立體電路27來作支撐,故在半導體元件35中並未發生撓曲的情況。 As shown in FIG. 18, the buried circuit 2 of the package substrate (FIG. 17 (14)) fabricated in Embodiment 4 is crimped to the bump 25 of the semiconductor element 35, and flip-chip is soldered (not shown). Wafer connection. The bumps 25 of the semiconductor element 35 are arranged in the periphery. However, since the surface of the lower surface of the semiconductor element 35 is supported by the three-dimensional circuit 27 as a dummy terminal, no deflection occurs in the semiconductor element 35.
在加熱、加壓前(將成為基材16之預浸材作層積來形成核心基板17之前)的初期剝離強度(N/m)之測定,係製作出裁切為10mm寬度之多層金屬箔樣本,使用Tensilon RTM-100(ORIENTEC股份有限公司製,商品名「Tensilon」係登記商標),並依據JIS Z 0237之90度剝離法,在室溫(25℃)先將第1載體金屬箔朝向90度方向而以每分鐘300mm之速度作剝離並測定,接著,將第2載體金屬箔朝向90度方向而以每分鐘300mm之速度作剝離並測定。又,加熱、加壓後(將成為基材16之預浸材 作層積而形成了核心基板17後)之剝離強度亦與初期剝離強度同樣地作測定,而求取出相對於初期之變化率。並且,在將多層金屬箔9與成為基材16之環氧玻璃布預浸材作層積來形成核心基板17時的加熱、加壓條件,係使用真空壓製法且壓力3MPa、溫度175℃、保持時間1.5hr(小時)。 The initial peel strength (N/m) before heating and pressurization (before the prepreg of the substrate 16 is laminated to form the core substrate 17) was measured, and a multilayer metal foil cut to a width of 10 mm was produced. For the sample, Tensilon RTM-100 (trade name "Tensilon", registered trademark of ORIENTEC Co., Ltd.) was used, and the first carrier metal foil was first oriented at room temperature (25 ° C) according to the 90 degree peeling method of JIS Z 0237. The peeling was measured at a speed of 300 mm per minute in a 90-degree direction, and then the second carrier metal foil was peeled off at a speed of 300 mm per minute in a direction of 90 degrees and measured. Moreover, after heating and pressurization (will become the prepreg of the substrate 16 The peel strength of the core substrate 17 after lamination was also measured in the same manner as the initial peel strength, and the rate of change with respect to the initial stage was taken out. In addition, when the multilayer metal foil 9 and the epoxy glass cloth prepreg which is the base material 16 are laminated to form the core substrate 17, the heating and pressurizing conditions are performed by a vacuum pressing method and the pressure is 3 MPa, and the temperature is 175 ° C. Hold time 1.5 hr (hours).
以下,藉由實施例來具體說明本發明,但本發明並不限定於此些實施例。 Hereinafter, the present invention will be specifically described by way of examples, but the invention is not limited thereto.
藉由與實施例1相同之方法,製作具備有內埋電路之倒裝晶片端子的封裝基板。於此,在形成於封裝基板上之焊料阻劑中設置有開口,在此開口內配置有線寬/線距為20μm/20μm(間距(pitch)40μm)且成為倒裝晶片連接端子之內埋電路。被焊料阻劑之開口所規定出的倒裝晶片連接端子的長邊方向的尺寸(倒裝晶片連接端子之長度)為約100μm。 A package substrate including a flip chip terminal having a buried circuit was produced in the same manner as in the first embodiment. Here, an opening is provided in the solder resist formed on the package substrate, and a buried circuit having a line width/line pitch of 20 μm/20 μm (pitch 40 μm) and being a flip chip connection terminal is disposed in the opening. . The dimension of the flip chip connection terminal defined by the opening of the solder resist in the longitudinal direction (the length of the flip chip connection terminal) is about 100 μm.
接著,藉由在成為倒裝晶片連接端子之內埋電路上印刷焊料糊並作回焊來形成預焊料。就預焊料用之焊料糊而言,係使用Sn(錫)-Ag(銀)-Cu(銅)系之ECOSOLDER M705(千住金屬工業股份有限公司製,商品名ECOSOLDER係登記商標),就回焊而言,係使用紅外線回焊裝置並以峰值溫度260℃之條件來進行。 Next, a pre-solder is formed by printing a solder paste on a buried circuit that becomes a flip chip connection terminal and reflowing it. For the solder paste for pre-solder, the Sn (tin)-Ag (silver)-Cu (copper)-based ECOSOLDER M705 (manufactured by Senju Metal Industry Co., Ltd., trade name ECOSOLDER is registered) is used for reflow soldering. In other words, it was carried out using an infrared reflow device at a peak temperature of 260 °C.
接著,施行切斷加工至封裝尺寸。此受切斷加工之封 裝基板係如圖2中所示,具備有:絕緣層3;內埋電路2,以使頂面露出於該絕緣層3之表面的方式所設置;與焊料阻劑4,被設置在絕緣層3上以及內埋電路2上;設置於此焊料阻劑4的開口31內之內埋電路2形成倒裝晶片連接端子26。又,被覆此倒裝晶片連接端子26之預焊料19的厚度係3~5μm。於此,焊料的厚度係使用為非接觸階差測定機之HISOMET(UNION光學股份有限公司製,商品名,HISOMET為登記商標),在形成預焊料19前後測定焊料阻劑與倒裝晶片連接端子26之間的階差而測定出來。 Next, cutting processing is performed to the package size. This cut-off seal As shown in FIG. 2, the substrate is provided with an insulating layer 3; a buried circuit 2 is provided so that the top surface is exposed on the surface of the insulating layer 3; and the solder resist 4 is disposed on the insulating layer. 3 and on the buried circuit 2; the buried circuit 2 disposed in the opening 31 of the solder resist 4 forms a flip chip connection terminal 26. Further, the thickness of the pre-solder 19 covering the flip-chip connecting terminal 26 is 3 to 5 μm. Here, the thickness of the solder is HISOMET (manufactured by UNION Optics Co., Ltd., trade name, HISOMET is a registered trademark) which is a non-contact step measuring machine, and the solder resist and the flip chip connection terminal are measured before and after the pre-solder 19 is formed. The step difference between 26 was measured.
如圖9中所示,在製作了封裝基板1後,將半導體元件15藉由倒裝晶片連接來搭載。倒裝晶片連接,係以使封裝基板1上的倒裝晶片連接端子26與半導體元件15的凸塊25(係在銅柱上形成有Sn(錫)-3.0質量%Ag(銀)-0.5質量%Cu(銅)焊料者,間距40μm且高度25μm)相對的方式來對準位置後,使用超音波倒裝晶片接合機SH-50MP(ALTECS股份有限公司,製品名)進行倒裝晶片連接。倒裝晶片連接的壓合條件係在併用超音波之同時升溫至230℃且每1凸塊進行50g加壓之狀態下保持4秒鐘。之後,在半導體元件15的凸塊25形成面與封裝基板1的具備有倒裝晶片連接端子26之絕緣層3之間填充底部填材劑23,而得到半導體封裝24。 As shown in FIG. 9, after the package substrate 1 is manufactured, the semiconductor element 15 is mounted by flip chip bonding. The flip chip connection is such that the flip chip connection terminal 26 on the package substrate 1 and the bump 25 of the semiconductor element 15 (formed on the copper pillar with Sn (tin) - 3.0 mass % Ag (silver) - 0.5 mass After the %Cu (copper) solder was placed at a position with a pitch of 40 μm and a height of 25 μm, the flip chip bonding was performed using an ultrasonic flip chip bonding machine SH-50MP (ALTECS Co., Ltd., product name). The pressing conditions of the flip chip connection were maintained at 230 ° C while ultrasonic waves were used in combination, and held for 4 seconds in a state where 50 μg of the bumps were pressed. Thereafter, the underfill material 23 is filled between the surface of the bump 25 formed of the semiconductor element 15 and the insulating layer 3 including the flip chip connection terminal 26 of the package substrate 1, thereby obtaining the semiconductor package 24.
被覆倒裝晶片連接端子之預焊料的厚度係7~10μm。除此之外,係與實施例7相同地來得到第10電路基板以及半導體封裝。 The thickness of the pre-solder covering the flip chip connection terminals is 7 to 10 μm. Otherwise, the tenth circuit board and the semiconductor package were obtained in the same manner as in the seventh embodiment.
被覆倒裝晶片連接端子之預焊料的厚度為17~20μm。除此之外,係與實施例7相同地來得到封裝基板以及半導體封裝。 The thickness of the pre-solder covering the flip chip connection terminals is 17 to 20 μm. Except for this, a package substrate and a semiconductor package were obtained in the same manner as in the seventh embodiment.
被覆倒裝晶片連接端子之預焊料的厚度為1~2μm。除此之外,係與實施例7相同地來得到封裝基板以及半導體封裝。 The thickness of the pre-solder covering the flip chip connection terminals is 1 to 2 μm. Except for this, a package substrate and a semiconductor package were obtained in the same manner as in the seventh embodiment.
被覆倒裝晶片連接端子之預焊料的厚度為25~28μm。除此之外,係與實施例7相同地來得到封裝基板以及半導體封裝。 The thickness of the pre-solder covering the flip chip connection terminals is 25 to 28 μm. Except for this, a package substrate and a semiconductor package were obtained in the same manner as in the seventh embodiment.
與實施例7相同地,在成為倒裝晶片連接端子之內埋電路上形成預焊料。於此,如圖5中所示,在焊料阻劑4設置有開口31,在此開口31內配置有成為倒裝晶片連接端子26之內埋電路2。又,通孔18連接至包含倒裝晶片 連接端子26之內埋電路2的底面。之後,與實施例7相同地,形成了封裝基板以及半導體封裝。 In the same manner as in the seventh embodiment, a pre-solder was formed on the buried circuit which was a flip chip connection terminal. Here, as shown in FIG. 5, the solder resist 4 is provided with an opening 31 in which the buried circuit 2 serving as the flip chip connection terminal 26 is disposed. Also, the via 18 is connected to the flip chip including The bottom surface of the buried circuit 2 is connected to the terminal 26. Thereafter, in the same manner as in the seventh embodiment, a package substrate and a semiconductor package were formed.
利用與實施例4相同之方法,如圖17(12)~(14)中所示,在第2載體金屬箔11上進行第2圖案鍍膜14,並在內埋電路的成為倒裝晶片連接端子處的一部分形成了凸形狀(立體電路)。形成焊料阻劑,並形成作為保護鍍膜之鎳/金鍍膜(鎳鍍膜與其上之金鍍膜)。於此,如圖6中所示,在焊料阻劑4設置有開口31,在此開口31內配置有成為倒裝晶片連接端子26之內埋電路2。又,在倒裝晶片連接端子26的長邊方向的一部分形成有凸形狀27,此凸形狀27的高度係5μm程度。凸形狀27的範圍係倒裝晶片連接端子26的短邊方向的尺寸的100%且是倒裝晶片連接端子26的長邊方向的尺寸的30%程度。在此之後,與實施例7相同地形成了封裝基板以及半導體封裝。 In the same manner as in the fourth embodiment, as shown in Figs. 17 (12) to (14), the second pattern plating film 14 is formed on the second carrier metal foil 11, and the flip chip connection terminal of the buried circuit is formed. A portion of the portion forms a convex shape (a three-dimensional circuit). A solder resist is formed and a nickel/gold plating film (a nickel plating film and a gold plating film thereon) as a protective plating film is formed. Here, as shown in FIG. 6, the solder resist 4 is provided with an opening 31 in which the buried circuit 2 serving as the flip chip connection terminal 26 is disposed. Further, a convex shape 27 is formed in a part of the longitudinal direction of the flip chip connection terminal 26, and the height of the convex shape 27 is about 5 μm. The range of the convex shape 27 is 100% of the dimension of the flip chip connection terminal 26 in the short-side direction and is about 30% of the dimension of the flip chip connection terminal 26 in the longitudinal direction. After that, a package substrate and a semiconductor package were formed in the same manner as in the seventh embodiment.
與實施例1相同地,製作了具備有內埋電路之倒裝晶片端子的封裝基板。之後,形成蝕刻阻劑,並以頂面露出之內埋電路,其頂面的一部分比絕緣層的表面更加凹陷,其他部分則照原樣殘留之方式來進行蝕刻,藉此形成凹陷形狀。之後,形成焊料阻劑,並形成作為保護鍍膜之鎳/金鍍膜(鎳鍍膜與其上之金鍍膜)。於此,如圖7中所示 ,在焊料阻劑4設置有開口31,在此開口31內配置有成為倒裝晶片連接端子26之內埋電路2。又,在倒裝晶片連接端子26的長邊方向的一部分形成有凹陷形狀28,此凹陷形狀28的深度為5μm程度。凹陷形狀28的範圍係倒裝晶片連接端子26的短邊方向的尺寸的100%且係倒裝晶片連接端子26的長邊方向的尺寸的30%程度。在此之後,與實施例7相同地來形成封裝基板以及半導體封裝。 In the same manner as in the first embodiment, a package substrate including a flip chip terminal having a buried circuit was fabricated. Thereafter, an etching resist is formed, and the buried circuit is exposed on the top surface, and a part of the top surface thereof is more recessed than the surface of the insulating layer, and the other portions are etched as they are, thereby forming a depressed shape. Thereafter, a solder resist is formed, and a nickel/gold plating film (a nickel plating film and a gold plating film thereon) as a protective plating film is formed. Here, as shown in FIG. An opening 31 is provided in the solder resist 4, and a buried circuit 2 serving as a flip chip connection terminal 26 is disposed in the opening 31. Further, a recessed shape 28 is formed in a part of the longitudinal direction of the flip chip connection terminal 26, and the depth of the recessed shape 28 is about 5 μm. The range of the recessed shape 28 is 100% of the dimension in the short-side direction of the flip-chip connecting terminal 26 and about 30% of the dimension in the longitudinal direction of the flip-chip connecting terminal 26. After that, the package substrate and the semiconductor package were formed in the same manner as in the seventh embodiment.
與實施例7相同地,製作了具備有內埋電路之倒裝晶片端子的封裝基板。於此,如圖3中所示,在焊料阻劑4設置有開口31,在此開口31內配置有成為倒裝晶片連接端子26之內埋電路2。又,倒裝晶片連接端子26的前端係形成在焊料阻劑4的開口31內。在此之後,與實施例7相同地來形成封裝基板以及半導體封裝。 In the same manner as in the seventh embodiment, a package substrate including a flip chip terminal having a buried circuit was fabricated. Here, as shown in FIG. 3, the solder resist 4 is provided with an opening 31 in which the buried circuit 2 serving as the flip chip connection terminal 26 is disposed. Further, the front end of the flip chip connection terminal 26 is formed in the opening 31 of the solder resist 4. After that, the package substrate and the semiconductor package were formed in the same manner as in the seventh embodiment.
與實施例7相同地,製作了具備有內埋電路之倒裝晶片端子的封裝基板。於此,如圖4中所示,在焊料阻劑4設置有開口31,在此開口31內配置有成為倒裝晶片連接端子26之內埋電路2。又,設置有在倒裝晶片連接端子26的長邊方向的兩側或者是單側被延長之內埋電路2。在此之後,與實施例7相同地來形成封裝基板以及半導體封裝。 In the same manner as in the seventh embodiment, a package substrate including a flip chip terminal having a buried circuit was fabricated. Here, as shown in FIG. 4, the solder resist 4 is provided with an opening 31 in which the buried circuit 2 serving as the flip chip connection terminal 26 is disposed. Further, the buried circuit 2 is provided on both sides in the longitudinal direction of the flip chip connection terminal 26 or on one side. After that, the package substrate and the semiconductor package were formed in the same manner as in the seventh embodiment.
與實施例7相同地,製作了具備有內埋電路之倒裝晶片端子的封裝基板。於此,如圖8中所示,在焊料阻劑4設置有開口31,在此開口31內配置有成為倒裝晶片連接端子26之內埋電路2。又,倒裝晶片連接端子26的長邊方向的一部分形成有在短邊方向(寬度方向)被擴張之部分33。亦即,倒裝晶片連接端子26形成有在短邊方向(寬度方向)上被部分地擴張的部分33。在此之後,與實施例7相同地來形成封裝基板以及半導體封裝。 In the same manner as in the seventh embodiment, a package substrate including a flip chip terminal having a buried circuit was fabricated. Here, as shown in FIG. 8, the solder resist 4 is provided with an opening 31 in which the buried circuit 2 serving as the flip chip connection terminal 26 is disposed. Further, a part of the flip chip connection terminal 26 in the longitudinal direction is formed with a portion 33 that is expanded in the short-side direction (width direction). That is, the flip chip connection terminal 26 is formed with a portion 33 which is partially expanded in the short-side direction (width direction). After that, the package substrate and the semiconductor package were formed in the same manner as in the seventh embodiment.
與實施例7相同地,製作了具備有內埋電路之倒裝晶片端子的封裝基板。於此,如圖16(14)中所示,在內埋電路2之配置有倒裝晶片連接端子的面之相反側之面上,配置有與圖1中所示者相同且由凸狀電路所成之電路圖案(外層電路7)。 In the same manner as in the seventh embodiment, a package substrate including a flip chip terminal having a buried circuit was fabricated. Here, as shown in FIG. 16 (14), on the opposite side of the surface of the buried circuit 2 on which the flip chip connection terminal is disposed, the same configuration as that shown in FIG. 1 is provided and the convex circuit is disposed. The resulting circuit pattern (outer layer circuit 7).
接著,在此由凸狀電路所成之電路圖案(外層電路7)上形成焊料阻劑,並進行作為保護鍍膜之鎳/金鍍膜(鎳鍍膜與其上之金鍍膜)形成。於此,在焊料阻劑設置有開口,在此開口內配置有線寬/線距為20μm/20μm(40μm間距)且成為倒裝晶片連接端子之由凸狀電路所成的電路圖案。 Next, a solder resist is formed on the circuit pattern (outer layer circuit 7) formed by the bump circuit, and a nickel/gold plating film (a nickel plating film and a gold plating film thereon) as a protective plating film is formed. Here, an opening is provided in the solder resist, and a circuit pattern formed by a bump circuit having a line width/line pitch of 20 μm/20 μm (40 μm pitch) and being a flip chip connection terminal is disposed in the opening.
接著,藉由在成為倒裝晶片連接端子且由凸狀電路所 成之電路圖案(外層電路7)上,印刷焊料糊並回焊來形成預焊料。就預焊料用之焊料糊而言,係使用Sn(錫)-Ag(銀)-Cu(銅)系之ECOSOLDER M705(千住金屬工業股份有限公司製,商品名ECOSOLDER係登記商標),就回焊而言,係使用紅外線回焊裝置並以峰值溫度260℃之條件來進行。 Then, by being a flip-chip connection terminal and by a convex circuit On the circuit pattern (outer layer circuit 7), the solder paste is printed and reflowed to form a pre-solder. For the solder paste for pre-solder, the Sn (tin)-Ag (silver)-Cu (copper)-based ECOSOLDER M705 (manufactured by Senju Metal Industry Co., Ltd., trade name ECOSOLDER is registered) is used for reflow soldering. In other words, it was carried out using an infrared reflow device at a peak temperature of 260 °C.
接著,施行切斷加工至封裝尺寸。此封裝基板係如圖1中所示,具備有:絕緣層3;電路圖案,被設置在該絕緣層3之表面上且由凸狀電路32所成;與焊料阻劑4,被設置在絕緣層3上以及由凸狀電路32所成之電路圖案上;設置於此焊料阻劑4的開口31內且由凸狀電路32所成之電路圖案會形成倒裝晶片連接端子26。又,被覆此倒裝晶片連接端子26之預焊料19的厚度為3~5μm。之後,與實施例7相同地來得到半導體封裝。 Next, cutting processing is performed to the package size. The package substrate is as shown in FIG. 1 and is provided with: an insulating layer 3; a circuit pattern disposed on the surface of the insulating layer 3 and formed by the convex circuit 32; and the solder resist 4 being disposed in the insulating layer On the layer 3 and on the circuit pattern formed by the bump circuit 32, the circuit pattern formed in the opening 31 of the solder resist 4 and formed by the bump circuit 32 forms the flip chip connection terminal 26. Further, the thickness of the pre-solder 19 covering the flip-chip connecting terminal 26 is 3 to 5 μm. Thereafter, a semiconductor package was obtained in the same manner as in the seventh embodiment.
被覆倒裝晶片連接端子之預焊料的厚度為17~20μm。除此之外,與比較例3相同地來得到封裝基板以及半導體封裝。 The thickness of the pre-solder covering the flip chip connection terminals is 17 to 20 μm. Except for this, a package substrate and a semiconductor package were obtained in the same manner as in Comparative Example 3.
於表2中,針對實施例7~15、參考例1、比較例1~3之封裝基板,顯示了調查倒裝晶片連接端子的剖面形狀、焊料厚度、焊料橋接的有無之結果。又,針對實施例7~15、參考例1以及比較例1~3之半導體封裝,顯示了調查焊料圓角的狀態之結果。 In Table 2, the results of examining the cross-sectional shape of the flip-chip connecting terminal, the thickness of the solder, and the presence or absence of solder bridging were shown for the package substrates of Examples 7 to 15, Reference Example 1, and Comparative Examples 1 to 3. Moreover, the results of investigating the state of the solder fillet were shown for the semiconductor packages of Examples 7 to 15, Reference Example 1, and Comparative Examples 1 to 3.
由倒裝晶片連接端子的剖面形狀的觀察結果,在實施例7~15中,倒裝晶片連接端子的側面以及底面係內埋至絕緣層中而密著,剖面形狀係略矩形且並未發現到底切現象。另一方面,在比較例2、3中,因為係凸狀電路,故僅有倒裝晶片連接端子的底面與絕緣層密著。又,在倒裝晶片連接端子的剖面形狀觀察到有底切現象,在最為狹窄處係相對於頂部寬度(表面側之寬度)成為未滿一半之寬度。 As a result of observing the cross-sectional shape of the flip-chip connecting terminal, in the seventh to fifteenth embodiments, the side surface and the bottom surface of the flip-chip connecting terminal were buried in the insulating layer to be closely adhered, and the cross-sectional shape was slightly rectangular and was not found. The end is the phenomenon. On the other hand, in Comparative Examples 2 and 3, since the bump circuit was formed, only the bottom surface of the flip chip connection terminal was in close contact with the insulating layer. Further, an undercut phenomenon was observed in the cross-sectional shape of the flip chip connection terminal, and the width at the narrowest portion was less than half the width with respect to the top width (the width on the surface side).
由焊料厚度之測定結果,在實施例7~15中,焊料厚度為3~20μm,又,由焊料橋接之確認結果,在此焊料厚度之範圍內,並未發生焊料橋接。另一方面,在比較例1中,焊料厚度薄,為1~2μm,且並未發生焊料橋接。在 參考例1中,焊料厚度厚達25~28μm厚,在相鄰接之倒裝晶片連接端子之間發生了焊料橋接。在比較例3中,焊料厚度為17~20μm,但因為係凸狀電路,故焊料會繞流至倒裝晶片連接端子的側面而發生焊料橋接。 As a result of measurement of the thickness of the solder, in Examples 7 to 15, the thickness of the solder was 3 to 20 μm, and as a result of the solder bridging, no solder bridging occurred in the range of the thickness of the solder. On the other hand, in Comparative Example 1, the solder thickness was as thin as 1 to 2 μm, and solder bridging did not occur. in In Reference Example 1, the thickness of the solder was as thick as 25 to 28 μm, and solder bridging occurred between adjacent flip chip connection terminals. In Comparative Example 3, the thickness of the solder was 17 to 20 μm, but since it was a convex circuit, the solder was wound around the side surface of the flip chip connection terminal to cause solder bridging.
由半導體封裝之焊料圓角之確認結果,在實施例7~15、參考例1以及比較例3中,與半導體元件之凸塊之間所形成的焊料圓角,其焊料在半導體元件的凸塊以及封裝基板的倒裝晶片連接端子之兩者上潤濕擴展且狀態良好。另一方面,在比較例1以及2中,在半導體元件的凸塊或者是封裝基板的倒裝晶片連接端子的一部分有焊料之潤濕擴展並不充分處,焊料圓角之形成並不充分。 As a result of the confirmation of the solder fillet of the semiconductor package, in Examples 7 to 15, Reference Example 1 and Comparative Example 3, the solder fillet formed between the bumps of the semiconductor element and the bump of the solder in the semiconductor element And both of the flip chip connection terminals of the package substrate are wet spread and in good condition. On the other hand, in Comparative Examples 1 and 2, in the bump of the semiconductor element or the part of the flip-chip connection terminal of the package substrate, the solder spread was insufficient, and the formation of the solder fillet was not sufficient.
倒裝晶片連接端子的剖面形狀係藉由製作出顯微切片並利用金相顯微鏡觀察剖面來進行觀察。倒裝晶片連接端子上的焊料的厚度係藉由使用為非接觸階差測定機之HISOMET(UNION光學股份有限公司製,商品名。HISOMET係登記商標),在形成預焊料前後,測定焊料阻劑與倒裝晶片連接端子之階差來測定。焊料橋接的有無以及焊料圓角的狀態係藉由使用實體顯微鏡在10倍觀察來確認。 The cross-sectional shape of the flip chip connection terminal was observed by making a microsection and observing the cross section with a metallographic microscope. The thickness of the solder on the flip chip connection terminal is determined by using HISOMET (manufactured by UNION Optics Co., Ltd., trade name. HISOMET registered trademark) which is a non-contact step measuring machine, before and after the formation of the pre-solder. Determined by the step difference between the terminals connected to the flip chip. The presence or absence of solder bridging and the state of the solder fillet were confirmed by a 10-fold observation using a solid microscope.
1‧‧‧半導體元件搭載用封裝基板或封裝基板或第10電路基板 1‧‧‧Package substrate or package substrate for semiconductor device mounting or 10th circuit substrate
2‧‧‧外層電路或內埋電路 2‧‧‧Outer circuit or buried circuit
3‧‧‧絕緣層 3‧‧‧Insulation
4‧‧‧焊料阻劑 4‧‧‧ solder resist
5‧‧‧層間連接 5‧‧‧Interlayer connection
6‧‧‧內層電路 6‧‧‧ Inner layer circuit
7‧‧‧外層電路 7‧‧‧Outer circuit
8‧‧‧保護鍍膜 8‧‧‧Protective coating
9‧‧‧多層金屬箔 9‧‧‧Multilayer metal foil
10‧‧‧第1載體金屬箔 10‧‧‧1st carrier metal foil
11‧‧‧第2載體金屬箔 11‧‧‧2nd carrier metal foil
12‧‧‧基底金屬箔 12‧‧‧Base metal foil
13‧‧‧第1圖案鍍膜 13‧‧‧1st pattern coating
14‧‧‧第2圖案鍍膜 14‧‧‧2nd pattern coating
15‧‧‧半導體元件 15‧‧‧Semiconductor components
16‧‧‧基材 16‧‧‧Substrate
17‧‧‧核心基板 17‧‧‧ core substrate
18‧‧‧通孔 18‧‧‧through hole
19‧‧‧預焊料 19‧‧‧Pre-solder
20‧‧‧導體層 20‧‧‧Conductor layer
21‧‧‧層間連接孔 21‧‧‧Interlayer connection holes
22‧‧‧層積體 22‧‧‧Layered
23‧‧‧底部填充材 23‧‧‧Bottom filler
24‧‧‧半導體封裝 24‧‧‧Semiconductor package
25‧‧‧(半導體元件側之)凸塊 25‧‧‧ (on the side of the semiconductor component) bump
26‧‧‧倒裝晶片連接端子 26‧‧‧Flip chip connection terminal
27‧‧‧凸形狀或立體電路 27‧‧‧ convex shape or stereo circuit
28‧‧‧凹陷形狀 28‧‧‧ concave shape
29‧‧‧密封材 29‧‧‧ Sealing material
31‧‧‧(焊料阻劑之)開口 31‧‧‧ (solder resist) opening
32‧‧‧凸狀電路 32‧‧‧ convex circuit
33‧‧‧在短邊方向上被作了擴張的部分 33‧‧‧The part that was expanded in the short-side direction
34‧‧‧蝕刻阻劑 34‧‧‧etching resist
35‧‧‧半導體元件 35‧‧‧Semiconductor components
圖1是先前之封裝基板的倒裝晶片連接端子附近之(a)平面圖、(b)A-A’剖面圖、(c)B-B’剖面圖。 BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a (a) plan view, (b) A-A' sectional view, and (c) B-B' sectional view of a vicinity of a flip chip connection terminal of a conventional package substrate.
圖2是本發明之封裝基板的倒裝晶片連接端子附近之 (a)平面圖、(b)A-A’剖面圖、(c)B-B’剖面圖。 2 is a view of the flip chip connection terminal of the package substrate of the present invention (a) plan view, (b) A-A' sectional view, and (c) B-B' sectional view.
圖3是本發明之封裝基板的倒裝晶片連接端子附近之(a)平面圖以及(b)A-A’剖面圖。 Figure 3 is a (a) plan view and (b) A-A' cross-sectional view of the vicinity of the flip chip connection terminal of the package substrate of the present invention.
圖4是本發明之封裝基板的倒裝晶片連接端子附近之(a)平面圖、(b)A-A’剖面圖、(c)B-B’剖面圖。 Fig. 4 is a (a) plan view, (b) A-A' sectional view, and (c) B-B' sectional view of the vicinity of the flip chip connection terminal of the package substrate of the present invention.
圖5是本發明之封裝基板的倒裝晶片連接端子附近之(a)平面圖以及(b)A-A’剖面圖。 Figure 5 is a (a) plan view and (b) A-A' cross-sectional view of the vicinity of the flip chip connection terminal of the package substrate of the present invention.
圖6是本發明之封裝基板的倒裝晶片連接端子附近之(a)平面圖以及(b)A-A’剖面圖。 Figure 6 is a (a) plan view and (b) A-A' cross-sectional view of the vicinity of the flip chip connection terminal of the package substrate of the present invention.
圖7是本發明之封裝基板的倒裝晶片連接端子附近之(a)平面圖以及(b)A-A’剖面圖。 Figure 7 is a (a) plan view and (b) A-A' cross-sectional view of the vicinity of the flip chip connection terminal of the package substrate of the present invention.
圖8是本發明之封裝基板的倒裝晶片連接端子附近之(a)平面圖、(b)A-A’剖面圖、(c)B-B’剖面圖。 Fig. 8 is a (a) plan view, (b) A-A' sectional view, and (c) B-B' sectional view of the vicinity of the flip chip connection terminal of the package substrate of the present invention.
圖9是本發明之封裝的倒裝晶片連接端子附近之剖面圖。 Figure 9 is a cross-sectional view of the vicinity of a packaged flip chip connection terminal of the present invention.
圖10是在本發明中所使用之多層金屬箔的剖面圖。 Figure 10 is a cross-sectional view of a multilayer metal foil used in the present invention.
圖11是表示本發明之封裝基板的製造方法之一部分的流程圖。 Fig. 11 is a flow chart showing a part of a method of manufacturing a package substrate of the present invention.
圖12是表示本發明之封裝基板的製造方法之一部分的流程圖。 Fig. 12 is a flow chart showing a part of a method of manufacturing a package substrate of the present invention.
圖13是表示本發明之封裝基板的製造方法之一部分的流程圖。 Fig. 13 is a flow chart showing a part of a method of manufacturing a package substrate of the present invention.
圖14是表示本發明之封裝基板的製造方法之一部分的流程圖。 Fig. 14 is a flow chart showing a part of a method of manufacturing a package substrate of the present invention.
圖15是表示本發明之封裝基板的製造方法之一部分的流程圖。 Fig. 15 is a flow chart showing a part of a method of manufacturing a package substrate of the present invention.
圖16是表示本發明之封裝基板的製造方法之一部分的流程圖。 Fig. 16 is a flow chart showing a part of a method of manufacturing a package substrate of the present invention.
圖17是表示本發明之封裝基板的製造方法之一部分的流程圖。 Fig. 17 is a flow chart showing a part of a method of manufacturing a package substrate of the present invention.
圖18是使用本發明之封裝基板之製造方法所製作出的半導體封裝之剖面圖。 Fig. 18 is a cross-sectional view showing a semiconductor package produced by using the method of manufacturing a package substrate of the present invention.
2‧‧‧外層電路或內埋電路 2‧‧‧Outer circuit or buried circuit
3‧‧‧絕緣層 3‧‧‧Insulation
4‧‧‧焊料阻劑 4‧‧‧ solder resist
8‧‧‧保護鍍膜 8‧‧‧Protective coating
19‧‧‧預焊料 19‧‧‧Pre-solder
26‧‧‧倒裝晶片連接端子 26‧‧‧Flip chip connection terminal
31‧‧‧(焊料阻劑之)開口 31‧‧‧ (solder resist) opening
Claims (12)
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- 2012-03-09 WO PCT/JP2012/056125 patent/WO2012121373A1/en active Application Filing
- 2012-03-09 KR KR1020137025239A patent/KR101585305B1/en active IP Right Grant
- 2012-03-09 TW TW101108124A patent/TWI600097B/en active
- 2012-03-09 CN CN201280012341.XA patent/CN103443916B/en active Active
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Also Published As
Publication number | Publication date |
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CN103443916A (en) | 2013-12-11 |
TW201246414A (en) | 2012-11-16 |
KR101585305B1 (en) | 2016-01-13 |
CN103443916B (en) | 2016-03-02 |
KR20130129292A (en) | 2013-11-27 |
WO2012121373A1 (en) | 2012-09-13 |
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