TW201510519A - System and method for measuring properties of thermoelectric module - Google Patents

Abstract

A system and a method for measuring properties of a thermoelectric module are provided. The system includes an adiabatic apparatus, a heating apparatus, a cooling module and three temperature measuring units. In the method for measuring properties of the thermoelectric module, at first, a top surface and a bottom surface of the thermoelectric module are respectively heated and cooled by the heating apparatus and the cooling apparatus, and then a temperature of a thermal conductivity material surface, a temperature of the cooling module surface, an output voltage of the thermoelectric module and a temperature of the adiabatic apparatus are measured for calculating the generation efficiency, performance of an internal electrical resistor and performance of a thermal resistance.

Description

Thermoelectric module property measuring system and measuring method thereof

The invention relates to a measuring system and a measuring method, and in particular to a measuring method of a thermoelectric module property, a power generation efficiency, an internal resistance performance, and a thermal resistance performance measuring method.

[Prior Art] Please refer to Fig. 1. Fig. 1 is a cross-sectional view showing the first conventional thermoelectric module measuring system. In the first conventional thermoelectric module measuring system, the heating sheet 110 generates heat after being heated, and then conducts heat to the upper surface of the thermoelectric module 130 through the heat conducting block 111 covering the heat insulating material 112. In addition, the cooling module 120 Heat is absorbed from the lower surface of the thermoelectric module 130 through the heat conducting block 121 covering the heat insulating material 112. Wherein, a plurality of thermocouples 140 are disposed in the heat conducting blocks 111, 121 for measuring temperatures of different positions of the heat conducting blocks 111, 121, whereby the conventional thermoelectric module measuring system can measure the seats of the thermoelectric module 130 Seebeck coefficient, thermal resistance, internal electrical resistance, power generation, and generation efficiency. However, this traditional thermoelectric module measurement system is different in measurement. When the thermoelectric module 130 of the surface of the surface or the lower surface needs to be replaced with the heat conducting blocks 111 and 121 of the corresponding area, the accuracy of the thermoelectric module 130 can be measured. Therefore, if the thermoelectric module 130 having different area sizes needs to be measured, In its nature, it is necessary to replace the heat conducting blocks 111, 121 to correspond to the area of the thermoelectric module 130, which is not convenient.

Please refer to FIG. 2, which is a cross-sectional view showing a second conventional thermoelectric module measuring system. The second conventional thermoelectric module measuring system is similar to the first conventional thermoelectric module measuring system, and both have heat conducting blocks 111 and 121 covered by the heat insulating material 112, and the heating sheet 110 and the cooling module 120 respectively supply heat to the heat. The upper surface of the electrical module 130 and the lower surface of the thermoelectric module 130 absorb heat. However, in the second conventional thermoelectric module measurement system, only one thermocouple 140 is disposed in each of the thermal conduction blocks 111 and 121, and the thermocouple 140 is closer to the upper surface and the lower surface of the thermoelectric module 130, wherein the thermal conduction blocks 111 and 121 are The area does not need to correspond to the area of the upper surface or the lower surface of the thermoelectric module 130, and the equivalent Sibeck coefficient, internal resistance value and power generation of the thermoelectric module 130 can be measured. However, it has the disadvantage that the power generation efficiency and the thermal resistance value of the thermoelectric module 130 cannot be measured.

In view of the above problems, an aspect of the present invention provides a thermoelectric module property measuring system, a power generation efficiency, an internal resistance performance, and a thermal resistance performance measuring method, so that different sizes of thermoelectric modules can be measured without replacing the size of the heat conducting block. The equivalent Sibeck coefficient, thermal resistance value, internal resistance value, power generation power and power generation efficiency.

According to an embodiment of the invention, the thermoelectric module property measurement system The system is suitable for measuring a thermoelectric module. The thermoelectric module property measuring system comprises a heat insulating device, a heating device, a cooling module, a first temperature measuring unit, a second temperature measuring unit and a third temperature measuring unit. The heat insulating device has a first hollow portion, a second hollow portion, and a heat supply portion, wherein the first hollow portion is located on the second hollow portion and the heat supply portion, and the second hollow portion surrounds the heat supply portion. The heating device is disposed in the heating portion of the heat insulating device for heating the thermoelectric module. The heating device comprises a heat conducting material and a heating module, the surface of the heat conducting material of the heat conducting material is used for contacting the upper surface of the thermoelectric module, and the heating module is disposed in the heat conducting material, and the heating module is configured to provide the heating amount through the heat conducting material to Thermoelectric module. The cooling module is used to cool the thermoelectric module, and the cooling module surface of the cooling module is used to contact the lower surface of the thermoelectric module. The first temperature measuring unit is configured to measure the temperature of the surface of the heat conducting material of the heat conducting material, that is, the temperature of the surface of the heat conducting material contacting the upper surface of the thermoelectric module to obtain the hot end temperature value of the thermoelectric module. The second temperature measuring unit is configured to measure the temperature of the heat insulating device to obtain a temperature value of the heat insulating device. The third temperature measuring unit is configured to measure the temperature of the surface of the cooling module of the cooling module, that is, measure the temperature of the surface of the cooling module and the surface of the thermoelectric module to obtain the cold junction temperature value of the thermoelectric module.

According to another embodiment of the present invention, the thermoelectric module property measuring system further includes a computing device electrically connected to the first temperature measuring unit, the second temperature measuring unit, and the third temperature measuring unit to utilize the heat of the thermoelectric module. The temperature value of the terminal, the temperature of the cold junction of the thermoelectric module, and the temperature value of the insulation device are used to calculate the Scheib coefficient, internal resistance value, thermal resistance value, power generation power or power generation efficiency of the thermoelectric module.

According to still another embodiment of the present invention, the first temperature measurement sheet described above The element, the second temperature measuring unit and the third temperature measuring unit are thermocouples.

According to still another embodiment of the present invention, the cooling module is a water-cooled cooling module or an air-cooled cooling module.

According to another aspect of the present invention, a power generation efficiency measuring method for measuring power generation efficiency of a thermoelectric module is provided. In one embodiment, the heating module is first used to heat the upper surface of the thermoelectric module, wherein the heating module provides heating to the thermoelectric module, and then the cooling module is used to cool the lower surface of the thermoelectric module. After cooling the lower surface of the thermoelectric module, measuring the temperature of the surface of the heat conductive material of the heat conductive material to obtain the temperature value of the heat conductive material, wherein the surface of the heat conductive material is in contact with the upper surface of the thermoelectric module, and the heating module is a heat conductive material. Heat the thermoelectric module. Then, a voltage measuring module is provided, wherein the voltage measuring module comprises a measuring resistor, wherein the resistance value of the measuring resistor is equal to the internal resistance value of the thermoelectric module. After the voltage measurement module is provided, the voltage measurement module is used to measure the output voltage of the thermoelectric module, and the output voltage is used to calculate the power generation of the thermoelectric module. Then, the temperature of the heat insulating device is measured to obtain a temperature value of the heat insulating device, wherein the heat insulating device covers the heating module and the heat conducting material. After measuring the temperature of the thermal insulation device, the heat dissipation temperature value of the thermoelectric module and the temperature value of the thermal insulation device are used to calculate the heat dissipation amount; and the power generation efficiency calculation step is performed to calculate the heating amount, the heat dissipation amount, and the power generation power. The power generation efficiency value of the thermoelectric module.

According to another embodiment of the present invention, the power generation efficiency calculation step described above calculates the power generation efficiency value of the thermoelectric module by using the following formula: Where η is the power generation efficiency value; P is the power generation power of the thermoelectric module; Q _heater is the heating amount provided by the heating module; and Σ Q _loss is the heat dissipation amount.

According to still another embodiment of the present invention, the above formula for calculating the amount of heat dissipation is as follows: Σ Q _loss = 3.144636 × 10 ^-8 . ( T ₁ - T ₂ ) ⁴ -8.539452 × 10 ^-6 . ( T ₁ - T ₂ ) ³ +9.48628×10 ^-4 . ( T ₁ - T ₂ ) ² +0.1193478. ( T ₁ - T ₂ )+0.01331508 wherein T ₁ is the thermoelectric module hot end temperature value; and T ₂ is the thermal insulation device temperature value.

According to still another embodiment of the present invention, the calculation formula of the power generation power of the thermoelectric module is as follows: Where: V _load is the value of the output voltage; and R _load is the internal resistance value.

According to still another aspect of the present invention, an internal resistance performance measuring method for measuring internal resistance performance of a thermoelectric module is provided. In one embodiment, the heating module is first used to heat the upper surface of the thermoelectric module, wherein the heating module provides heating to the thermoelectric module, and then the cooling module is used to cool the lower surface of the thermoelectric module. After cooling the lower surface of the thermoelectric module, measuring the temperature of the surface of the heat conductive material of the heat conductive material to obtain the temperature value of the heat conductive material, wherein the surface of the heat conductive material is in contact with the upper surface of the thermoelectric module, and the heating module is a heat conductive material. The thermoelectric module is heated, and then the temperature of the cooling module surface of the cooling module is measured to obtain a cooling module temperature value, wherein the surface of the cooling module is in contact with the lower surface of the heating module. After measuring the temperature of the surface of the cooling module, a voltage measuring module is provided, wherein the voltage measuring module includes a measuring resistor, and then the voltage measuring module is used to measure the output voltage of the thermoelectric module, and the inner voltage is measured. The resistance calculation step is to calculate the internal resistance value of the thermoelectric module by using the hot junction temperature value of the thermoelectric module, the cold junction temperature value of the thermoelectric module, and the output voltage.

According to another embodiment of the present invention, the internal resistance calculation step uses the following formula to calculate the internal resistance of the thermoelectric module: Where: R _TE is the internal resistance value at the average temperature, and the average temperature is half of the sum of the cold junction temperature value of the thermoelectric module and the hot junction temperature of the thermoelectric module; V _open is the open circuit voltage value of the thermoelectric module; V _load is the output The value of the voltage; and R _load is the resistance value of the measuring resistor.

According to still another aspect of the present invention, a thermal resistance performance measuring method for measuring a thermal resistance performance of a thermoelectric module is provided. In one embodiment, the heating module is first used to heat the upper surface of the thermoelectric module, wherein the heating module provides heating to the thermoelectric module, and then the cooling module is used to cool the lower surface of the thermoelectric module. After cooling the lower surface of the thermoelectric module, measuring the temperature of the surface of the heat conductive material of the heat conductive material to obtain the hot end temperature value of the thermoelectric module, wherein the surface of the heat conductive material is in contact with the upper surface of the thermoelectric module, and the heating module is The heat conductive material is used to heat the thermoelectric module, and then the temperature of the cooling module surface of the cooling module is cooled to obtain the cold junction temperature value of the thermoelectric module, wherein the cooling module surface of the cooling module is in contact with the lower surface of the thermoelectric module. After measuring the temperature of the lower surface of the thermoelectric module, measuring the temperature of the thermal insulation device to obtain the temperature value of the thermal insulation device, wherein the thermal insulation device covers the heating module and the heat conduction material, and performs a thermal resistance calculation step to utilize the heating The amount of heat, the amount of heat dissipation, the temperature of the hot end of the thermoelectric module, and the temperature of the cold junction of the thermoelectric module to calculate the thermal resistance of the thermoelectric module value.

According to another embodiment of the present invention, the above formula for calculating the amount of heat dissipation is as follows: Σ Q _loss = 3.144636 × 10 ^-8 . ( T ₁ - T ₂ ) ⁴ -8.539452 × 10 ^-6 . ( T ₁ - T ₂ ) ³ +9.48628×10 ^-4 . ( T ₁ - T ₂ ) ² +0.1193478. ( T ₁ - T ₂ )+0.01331508 wherein T ₁ is the hot end temperature value of the thermoelectric module; T ₂ is the temperature value of the adiabatic device and Σ Q _loss is the heat dissipation amount.

According to still another embodiment of the present invention, the thermal resistance calculation step described above calculates the thermal resistance value of the thermoelectric module by using the following formula: Where: R _f is the thermal resistance value; T ₁ is the hot end temperature value of the thermoelectric module; T ₃ is the cold end temperature value of the thermoelectric module; Q _heater is the heating amount provided by the heating module and Σ Q _loss is the heat dissipation amount .

Therefore, one of the advantages of the present invention is to provide a thermoelectric module property measuring system, a power generation efficiency, an internal resistance performance, and a thermal resistance performance measuring method, wherein the heat insulating device has two hollow portions to have a better heat insulating effect, and Three temperature measuring units respectively measure the hot end temperature value of the thermoelectric module, the cold end temperature value of the thermoelectric module, and the temperature value of the adiabatic device, thereby calculating the Schiebeck coefficient, internal resistance value, power generation power, power generation efficiency of the thermoelectric module or Thermal resistance value. In addition, the area of the surface of the heat conductive material does not need to correspond to the area of the upper surface of the thermoelectric module. Therefore, in the case where the thermoelectric module having different surface areas needs to be measured, the thermoelectric module property measuring system of the present invention can still be applied.

Regarding the features, implementation and efficacy of the present invention, The preferred embodiment is described in detail below.

110‧‧‧ heating film

111‧‧‧heat conduction block

112‧‧‧Insulation materials

120‧‧‧Cooling module

121‧‧‧heat conduction block

130‧‧‧Thermal module

140‧‧‧ thermocouple

300‧‧‧Thermal Module Nature Measurement System

310‧‧‧Insulation device

311‧‧The Ministry of Heating

312, 313‧‧‧ hollow

320‧‧‧heating device

321‧‧‧heating module

322‧‧‧heat-conducting materials

330‧‧‧Thermal module

340‧‧‧Cooling module

350‧‧‧First temperature measuring unit

360‧‧‧Second temperature measuring unit

370‧‧‧ Third temperature measuring unit

380‧‧‧Voltage measurement module

381‧‧‧Measurement resistance

400‧‧‧Measurement method for power generation efficiency

410, 510, 610, 710‧‧‧ heating steps

420, 520, 620, 720‧‧‧ cooling steps

430, 530, 630, 730 ‧ ‧ Measure the temperature of the upper surface of the thermoelectric module

440, 550, 650‧ ‧ provide voltage measurement module

450‧‧‧Power generation calculation steps

460, 750‧‧‧Measure the temperature of the insulation device

470, 760‧‧‧ Thermal runoff calculation steps

480‧‧‧Power generation efficiency calculation steps

500‧‧‧ Internal resistance performance measurement method

540, 640, 740‧‧‧Measure the temperature of the lower surface of the thermoelectric module

560‧‧‧Measure output voltage step

570‧‧‧ Internal resistance calculation steps

600‧‧ ‧Becker coefficient measurement method

660‧‧‧Measure open circuit voltage steps

670‧‧ ‧Becker coefficient calculation steps

700‧‧‧ Thermal resistance performance measurement method

770‧‧‧ Thermal resistance calculation steps

Figure 1 is a cross-sectional view showing the first conventional thermoelectric module measurement system.

Figure 2 is a cross-sectional view showing the second conventional thermoelectric module measuring system.

Figure 3 is a cross-sectional view showing the thermoelectric module property measuring system in accordance with the present invention.

Fig. 4 is a view showing the steps of the power generation efficiency measuring method of the present invention.

Figure 4a is a schematic diagram showing the measurement of the output voltage by a voltage measuring module having a measuring resistor according to the thermoelectric module property measuring system of the present invention.

Fig. 5 is a view showing the steps of a method for measuring the internal resistance of the present invention.

Fig. 6 is a view showing the steps of a method for measuring the Becker coefficient of the present invention.

Figure 6a is a schematic diagram showing the measurement of the open circuit voltage by a voltage measuring module without a measuring resistor according to the thermoelectric module property measuring system of the present invention.

Fig. 7 is a view showing the steps of the method for measuring the thermal resistance of the present invention.

The making and using of the embodiments of the invention are discussed in detail below. However, it will be appreciated that the embodiments provide many applicable inventive concepts that can be implemented in a wide variety of specific content. The specific embodiments discussed are illustrative only and are not intended to limit the scope of the invention.

Please refer to FIG. 3, which is a cross-sectional view of a thermoelectric module property measuring system 300 in accordance with an embodiment of the present invention. Insulation device 310 There are a heating unit 311 and hollow portions 312 and 313. The hollow portion 312 is located on the hollow portion 313 and the heating portion 311. The hollow portion 313 surrounds the heating portion 311. The hollow portion 312, 313 can selectively set or fill a gas having a heat insulating effect to provide a heat insulating effect. . The heating unit 311 is provided with a heating device 320 for heating the thermoelectric module 330. The heating device 320 includes a heating module 321 and a heat-conducting material 322. The heating module 321 may be a heating sheet or a heating device. The material of the heat-conducting material 322 may be metal or a material having better thermal conductivity. The heat conductive material surface of the heat conductive material 322 is used to contact the upper surface of the thermoelectric module 330, and the heating module 321 is disposed in the heat conductive material 322. The heating module 321 is configured to heat the thermoelectric module 330 through the heat conductive material 322.

In addition, the cooling module 340 is used to cool the thermoelectric module 330. The cooling module surface of the cooling module 340 is used to contact the lower surface of the thermoelectric module 330. Preferably, the cooling module 340 can be a water-cooled cooling module or an air-cooled cooling module. After the thermoelectric module 330 is heated and cooled and stabilized, the first temperature measuring unit 350, the second temperature measuring unit 360, and the third temperature measuring unit 370 respectively measure the temperature of the heat conducting material surface of the heat conducting material 322 and the heat insulating device. The temperature of 310 and the temperature of the surface of the cooling module of the cooling module 340 are obtained to obtain the hot end temperature value of the thermoelectric module, the temperature value of the heat insulating device, and the cold end temperature value of the thermoelectric module. Preferably, the first temperature measuring unit 350, the second temperature measuring unit 360, and the third temperature measuring unit 370 may be thermocouples. In addition, the first temperature measuring unit 350 may be disposed in the heat conductive material 322 and close to the surface of the heat conductive material for contacting the upper surface of the thermoelectric module 330, or the first temperature measuring unit 350 may be disposed on the surface of the heat conductive material; The second temperature measuring unit 360 may be disposed on the hollow portion 312; the third temperature measuring unit 370 may be disposed adjacent to the cooling module surface of the cooling module 340, and the cooling module surface contacts the lower surface of the thermoelectric module 330, or It is the third temperature measuring unit 370 that can be disposed on the surface of the cooling module.

In addition, the thermoelectric module property measuring system of the present invention may further include a computing device (not shown) electrically connected to the first temperature measuring unit 350, the second temperature measuring unit 360, and the third temperature measuring unit 370. The heat cycle temperature value of the thermoelectric module, the cold junction temperature value of the thermoelectric module, and the temperature value of the heat insulating device are used to calculate the Becker coefficient, internal resistance value, power generation power, power generation efficiency or thermal resistance value of the thermoelectric module 330.

The thermoelectric module property measuring system of the embodiment of the invention can calculate the Sieke coefficient, the internal resistance value, the power generation power, the power generation efficiency or the thermal resistance value of the thermoelectric module 330. Please refer to the subsequent paragraphs for detailed measurement methods.

First, a method for measuring power generation efficiency according to an embodiment of the present invention will be described. Referring to FIG. 4, FIG. 4 is a flow chart showing a method for measuring power generation efficiency according to an embodiment of the present invention. The power generation efficiency measuring method 400 first performs step 410 to heat the upper surface of the thermoelectric module 330 by using the heating module 321 , wherein the heating module 321 provides a heating amount to the thermoelectric module 330 . Next, step 420 is performed to cool the lower surface of the thermoelectric module 330 by using the cooling module 340. After step 420, step 430 is performed to measure the surface temperature of the heat conductive material 322 by using the first temperature measuring unit 350, that is, the temperature of the heat conductive material 322 and the thermoelectric module 330 contacting the upper surface to obtain a thermoelectric module. The hot end temperature value, wherein the upper surface of the heating module 321 is heated because the surface of the heat conductive material of the heat conductive material 322 is in contact with the thermoelectric module 330 After being stabilized, the temperature of the surface of the heat conductive material and the upper surface of the heating module 321 will be close to or equal, so that the surface temperature of the heat conductive material 322 is measured, and the temperature of the upper surface of the thermoelectric module 330 is also measured close to or equal. Therefore, the hot end temperature value of the thermoelectric module can be obtained.

Next, step 440 is performed to provide a voltage measurement module. As shown in FIG. 4a, FIG. 4a is a diagram showing the measurement system of the thermoelectric module property measuring system according to the present invention. Schematic diagram of voltage. The voltage measurement module 380 includes a measurement resistor 381, wherein the resistance value of the measurement resistor 381 is equal to the internal resistance value of the thermoelectric module 330. Next, in step 450, the voltage measurement module 380 is used to measure the output voltage of the thermoelectric module 330, and the output voltage is used to calculate the power generation of the thermoelectric module 330. Among them, the calculation formula of power generation is as follows: Where V _load is the value of the output voltage; R _load is the internal resistance value; and P is the power generation of the thermoelectric module.

Next, step 460 is performed to measure the temperature of the heat insulating device 310 to obtain the temperature value of the heat insulating device. After step 460, step 470 is followed to calculate the heat dissipation amount using the thermoelectric module hot end temperature value and the adiabatic device temperature value. Among them, the calculation formula of the heat dissipation amount is as follows: Σ Q _loss =3.144636×10 ^-8 . ( T ₁ - T ₂ ) ⁴ -8.539452 × 10 ^-6 . ( T ₁ - T ₂ ) ³ +9.48628×10 ^-4 . ( T ₁ - T ₂ ) ² +0.1193478. ( T ₁ - T ₂ )+0.01331508 wherein T ₁ is the hot end temperature value of the thermoelectric module; T ₂ is the temperature value of the adiabatic device; Σ Q _loss is the heat dissipation amount.

Next, a power generation efficiency calculation step 480 is performed to calculate the power generation efficiency value of the thermoelectric module 330 using the heating amount, the heat dissipation amount, and the power generation power. The calculation formula of the power generation efficiency value of the thermoelectric module 330 is as follows: Where η is the power generation efficiency value; and Q _heater is the heating amount provided by the heating module. In other words, in the power generation efficiency measuring method of the present invention, the surface of the heat conductive material does not need to correspond to the area of the upper surface of the thermoelectric module 330, and the various values can be measured to calculate the power generation and heat dissipation amount of the thermoelectric module 330 and Power generation efficiency.

In addition, please refer to FIG. 5, which is a step-by-step diagram of the internal resistance performance measuring method 500 of the present invention. The internal resistance performance measuring method 500 of the present invention is used to measure the internal resistance performance of the thermoelectric module 330. The steps 510, 520, and 530 are similar to the steps 410, 420, and 430, and therefore are not described again. After step 530, step 540 is performed to measure the temperature of the surface of the cooling module of the cooling module 340 by using the third temperature measuring unit 370, that is, the temperature of the surface of the cooling module 340 in contact with the thermoelectric module 330. The temperature of the cold junction temperature of the thermoelectric module is obtained, wherein the surface of the cooling module of the cooling module 340 is in contact with the lower surface of the thermoelectric module 330, so that the lower surface of the heating module 330 is cooled and stabilized, and then the cooling module is cooled. The temperature of the surface of the group and the lower surface of the heating module 330 may be close to or equal, so that the surface temperature of the cooling module 340 is measured, and the temperature of the lower surface of the thermoelectric module 330 is also measured, so that the thermoelectricity can be obtained. Module cold junction temperature value. After step 540, step 550 is followed to provide a voltage measurement module 380, as shown in FIG. 4a, wherein the voltage measurement module 380 includes a measurement resistor 381. Next, step 560 is performed to measure the output voltage of the thermoelectric module 330 by using the voltage measurement module 380. In addition, after performing the step 560 of measuring the output voltage of the thermoelectric module 330, the internal resistance calculation step 570 can be performed to calculate the hot junction temperature value of the thermoelectric module, the cold junction temperature value of the thermoelectric module, and the output voltage. The internal resistance of the thermoelectric module 330. The calculation formula of the internal resistance value of the thermoelectric module 330 is as follows: Wherein, R _TE is the internal resistance value at the average temperature, and the average temperature is half of the sum of the cold junction temperature value of the thermoelectric module and the hot end temperature value of the thermoelectric module; V _open is the open circuit voltage value of the thermoelectric module; V _load is the output The value of the voltage; and R _load is the resistance value of the measuring resistor. It is specifically mentioned that the open circuit voltage value refers to the voltage value obtained by the voltage measuring module 380 for measuring the thermoelectric module 330 when the measuring resistor 381 is not included.

The present invention further includes a measurement method aspect of the Sibeck coefficient. Referring to FIG. 6, FIG. 6 is a step diagram showing a method 600 for measuring the Bibeck coefficient of the present invention. First, steps 610 to 640 are similar to steps 510 to 540 of the internal resistance performance measuring method of the present invention, and therefore will not be described again. After step 640 of measuring the temperature of the surface of the cooling module, step 650 provides a voltage measuring module 380, as shown in FIG. 6a, and FIG. 6a shows the thermoelectric module property measuring system according to the present invention. A schematic diagram of measuring the open circuit voltage by a voltage measuring module with a measuring resistor. The voltage measurement module 380 does not include the measurement resistor 381, and then the step 660 uses the voltage measurement module 380 to measure the open circuit voltage of the thermoelectric module 330. Then, the Sibeck coefficient calculation step 670 is performed to calculate the Siekeke coefficient of the thermoelectric module by using the open circuit voltage, the hot end temperature value of the thermoelectric module, and the cold junction temperature value of the thermoelectric module. Among them, the Sibeck coefficient can be calculated by the following formula: Where T _avg is the average temperature of the hot end temperature value T ₁ of the thermoelectric module and the cold end temperature value T ₃ of the thermoelectric module; S ( T _avg ) is the Sibeck coefficient at the average temperature and V _open is the open circuit voltage value.

The present invention further includes a measurement method aspect of the thermal resistance performance. Referring to FIG. 7, FIG. 7 is a step diagram showing a method 700 for measuring the thermal resistance performance of the present invention. First, steps 710 to 740 are similar to steps 510 to 540 of the internal resistance performance measuring method of the present invention, and therefore will not be described again. After step 740, step 750 measures the temperature of the thermal insulation device to obtain a thermal insulation device temperature value, as shown in FIG. 3, wherein the thermal insulation device 310 covers the heating module 321 and the heat conductive material 322. Next, in step 760, the heat dissipation temperature value of the thermoelectric module and the temperature value of the heat insulating device are used to calculate the heat dissipation amount. Then, a thermal resistance calculation step 770 is performed to calculate the thermal resistance value of the thermoelectric module by using the heating amount, the heat dissipation amount, the thermoelectric module hot end temperature value, and the thermoelectric module cold end temperature value. Here, the aforementioned heat dissipation amount can be calculated, for example, but not limited to, by the same calculation formula for the heat dissipation amount in the power generation efficiency measuring method of the present invention.

On the other hand, the aforementioned thermal resistance calculation step can calculate the thermal resistance value of the thermoelectric module by using the following formula: Where: R _f is the thermal resistance value; T ₁ is the hot end temperature value of the thermoelectric module; T ₃ is the cold end temperature value of the thermoelectric module; Q _heater is the heating amount provided by the heating module; and Σ Q _loss is the heat dissipation the amount.

In summary, in the measuring method of the thermoelectric module property measuring system, the power generation efficiency, the internal resistance performance and the thermal resistance performance of the present invention, the two insulating portions are mainly provided with two hollow portions, and the hollow portions are preferably provided through the hollow portions. In addition to the thermal insulation effect, there are three temperature measuring units respectively for measuring the temperature of the surface of the heat conductive material, the surface of the cooling module and the temperature of the heat insulating device. These temperatures can be combined with the output voltage and open circuit voltage measured by the voltage measurement module, and the attendance Becker coefficient, internal resistance value, heat dissipation amount, power generation power, power generation efficiency, or thermal resistance value can be calculated according to the formula provided above. Therefore, even if the upper surface or the lower surface of the thermoelectric module does not correspond to the area of the surface of the heat conductive material, various properties of the thermoelectric module can be calculated.

The present invention has been disclosed in the above embodiments, and is not intended to limit the present invention. Any one of ordinary skill in the art to which the present invention pertains can make various changes without departing from the spirit and scope of the invention. The scope of protection of the present invention is therefore defined by the scope of the appended claims.

300‧‧‧Thermal Module Nature Measurement System

310‧‧‧Insulation device

311‧‧The Ministry of Heating

312, 313‧‧‧ hollow

320‧‧‧heating device

321‧‧‧heating module

322‧‧‧heat-conducting materials

330‧‧‧Thermal module

340‧‧‧Cooling module

350‧‧‧First temperature measuring unit

360‧‧‧Second temperature measuring unit

370‧‧‧ Third temperature measuring unit

Claims (13)

A thermoelectric module property measuring system, which is suitable for measuring a thermoelectric module, wherein the thermoelectric module property measuring system comprises: a heat insulating device having a first hollow portion, a second hollow portion and a heat supply portion, wherein The first hollow portion is located on the second hollow portion and the heating portion, the second hollow portion surrounds the heating portion; a heating device is disposed in the heating portion of the heat insulating device for heating The thermoelectric module, wherein the heating device comprises: a heat conducting material, wherein a surface of the heat conducting material is used to contact an upper surface of the thermoelectric module; and a heating module is disposed in the heat conducting material The heating module is configured to provide a heating amount to the thermoelectric module through the heat conducting material; a cooling module is configured to cool the thermoelectric module, wherein a cooling module surface of the cooling module is used Contacting a lower surface of the thermoelectric module; a first temperature measuring unit for measuring the temperature of the surface of the heat conductive material of the heat conductive material to obtain a hot end temperature value of the thermoelectric module; and a second temperature measuring unit, Used to measure the Means the temperature to obtain a temperature value of the heat insulating means; and a third temperature measuring unit, the temperature of the cooling module is used to measure the surface of the cooling module, to obtain a cold junction temperature of the thermoelectric module. The thermoelectric module property measuring system of claim 1, further comprising a computing device electrically connected to the first temperature measuring unit, The second temperature measuring unit and the third temperature measuring unit calculate the thermoelectric module Schübeck by using the thermoelectric module hot end temperature value, the thermoelectric module cold end temperature value, and the thermal insulation device temperature value. Seebeck) coefficient, internal resistance, thermal resistance, power generation or power generation efficiency. The thermoelectric module property measuring system of claim 1, wherein the first temperature measuring unit, the second temperature measuring unit, and the third temperature measuring unit are a thermocouple. The thermoelectric module property measuring system according to claim 1, wherein the cooling module is a water-cooled cooling module or an air-cooled cooling module. A method for measuring power generation efficiency for measuring power generation efficiency of a thermoelectric module, wherein the method for measuring performance of the thermoelectric module comprises: heating a top surface of one of the thermoelectric modules by using a heating module, wherein the heating module is Providing a heating amount to the thermoelectric module; cooling a lower surface of the thermoelectric module by using a cooling module; measuring a temperature of a surface of the heat conducting material of the heat conducting material to obtain a hot end temperature value of the thermoelectric module, wherein The surface of the heat conductive material is in contact with the upper surface of the thermoelectric module, and the heating module is the heat conductive material to heat the thermoelectric module; and a voltage measuring module is provided, wherein the voltage measuring module comprises an amount Measuring resistance, wherein the resistance value of the measuring resistor is equal to the resistance value in one of the thermoelectric modules; Using the voltage measurement module to measure an output voltage of the thermoelectric module, and using the output voltage to calculate a power generation of the thermoelectric module; measuring the temperature of an adiabatic device to obtain a thermal insulation device temperature value The heat insulating device covers the heating module and the heat conducting material; calculating a heat dissipation amount by using the hot end temperature value of the thermoelectric module and the temperature value of the heat insulating device; and performing a power generation efficiency calculating step to utilize The heating amount, the heat dissipation amount, and the power generation amount are used to calculate a power generation efficiency value of the thermoelectric module. The power generation efficiency measuring method according to claim 5, wherein the power generation efficiency calculating step calculates the power generation efficiency value of the thermoelectric module by using the following formula: Where: η is the power generation efficiency value; P is the power generation power of the thermoelectric module; Q _{heater is} the heating amount provided by the heating module; and Σ Q _{loss is} the heat dissipation amount. The method for measuring power generation efficiency as described in claim 6 wherein the heat dissipation amount is calculated as follows: Σ Q _loss =3.144636×10 ^-8 . ( T ₁ - T ₂ ) ⁴ -8.539452 × 10 ^-6 . ( T ₁ - T ₂ ) ³ +9.48628×10 ^-4 . ( T ₁ - T ₂ ) ² +0.1193478. ( T ₁ - T ₂ )+0.01331508 wherein, T _{1 is} the hot end temperature value of the thermoelectric module; and T _{2 is} the temperature value of the heat insulating device. The method for measuring power generation efficiency according to claim 5, wherein the calculation formula of the power generation power of the thermoelectric module is as follows: Where: V _load is the value of the output voltage; and R _{load is} the internal resistance value. An internal resistance performance measuring method for measuring an internal resistance performance of a thermoelectric module, wherein the internal resistance performance measuring method comprises: heating a top surface of one of the thermoelectric modules by using a heating module, wherein the heating mode The system provides a heating amount to the thermoelectric module; a cooling module is used to cool a lower surface of the thermoelectric module; and a temperature of a thermal conductive material surface of a thermal conductive material is measured to obtain a thermoelectric module hot end temperature value The heat conductive material surface is in contact with the upper surface of the thermoelectric module, and the heating module is the heat conductive material to heat the thermoelectric module; and measuring the temperature of the cooling module surface of the cooling module to Obtaining a cold junction temperature value of the thermoelectric module, wherein the surface of the cooling module is in contact with the lower surface of the thermoelectric module; and providing a voltage measurement module, wherein the voltage measurement module includes an amount Measuring the resistance; measuring the output voltage of the thermoelectric module by using the voltage measuring module; and performing an internal resistance calculating step to utilize the temperature value of the heat conductive material, the cold end temperature value of the thermoelectric module, and the output voltage To calculate the resistance value in one of the thermoelectric modules. The internal resistance performance measuring method according to claim 9, wherein the internal resistance calculating step calculates the internal resistance value of the thermoelectric module by using the following formula: Wherein: R _TE is an internal resistance value at an average temperature, and the average temperature is half of a sum of a cold junction temperature value of the thermoelectric module and a hot junction temperature value of the thermoelectric module; V _{open is} an open circuit voltage of the thermoelectric module Value; V _load is the value of the output voltage; and R _load is the resistance value of the measuring resistor. A thermal resistance performance measuring method for measuring a thermal resistance performance of a thermoelectric module, wherein the thermal resistance performance measuring method comprises: heating a top surface of one of the thermoelectric modules by using a heating module, wherein the heating mode The system provides a heating amount to the thermoelectric module; and a cooling module is used to cool a lower surface of the thermoelectric module; Measuring a temperature of a surface of the heat conductive material of a heat conductive material to obtain a hot end temperature value of the thermoelectric module, wherein the surface of the heat conductive material is in contact with the upper surface of the thermoelectric module, and the heating module is the heat conductive material Heating the thermoelectric module; measuring a temperature of a cooling module surface of the cooling module to obtain a cold junction temperature value of the thermoelectric module, wherein the surface of the cooling module is in contact with the lower surface of the thermoelectric module Measuring the temperature of an adiabatic device to obtain a temperature value of the heat insulating device, wherein the heat insulating device covers the heating module and the heat conducting material; and calculating a temperature value of the hot end of the thermoelectric module and a temperature value of the heat insulating device Generating a heat dissipation amount; and performing a thermal resistance calculation step to calculate the thermoelectric module by using the heating amount, the heat dissipation amount, the hot end temperature value of the thermoelectric module, and the cold junction temperature value of the thermoelectric module A thermal resistance value. The method for measuring thermal resistance performance as described in claim 11 wherein the heat dissipation amount is calculated as follows: Σ Q _loss =3.144636×10 ^-8 . ( T ₁ - T ₂ ) ⁴ -8.539452 × 10 ^-6 . ( T ₁ - T ₂ ) ³ +9.48628×10 ^-4 . ( T ₁ - T ₂ ) ² +0.1193478. ( T ₁ - T ₂ )+0.01331508 wherein T _{1 is} the hot end temperature value of the thermoelectric module; T _{2 is} the temperature value of the heat insulating device; and Σ Q _{loss is} the heat dissipation amount. The thermal resistance performance measuring method according to claim 11, wherein the thermal resistance calculating step calculates the thermal resistance value of the thermoelectric module by using the following formula: Wherein: R _{f is} the thermal resistance value; T _{1 is} the hot end temperature value of the thermoelectric module; T _{3 is} the cold end temperature value of the thermoelectric module; Q _{heater is} the heating amount provided by the heating module; Q _{loss is} the amount of heat dissipation.