Nothing Special   »   [go: up one dir, main page]

SU1010045A1 - Raw mix for making heat insulating products - Google Patents

Raw mix for making heat insulating products Download PDF

Info

Publication number
SU1010045A1
SU1010045A1 SU813364096A SU3364096A SU1010045A1 SU 1010045 A1 SU1010045 A1 SU 1010045A1 SU 813364096 A SU813364096 A SU 813364096A SU 3364096 A SU3364096 A SU 3364096A SU 1010045 A1 SU1010045 A1 SU 1010045A1
Authority
SU
USSR - Soviet Union
Prior art keywords
polyvinyl acetate
acetate emulsion
emulsion
binder
fiber
Prior art date
Application number
SU813364096A
Other languages
Russian (ru)
Inventor
Галина Ивановна Книгина
Альбина Михайловна Коледина
Татьяна Федоровна Каткова
Владимир Васильевич Коледин
Original Assignee
Новосибирский Ордена Трудового Красного Знамени Инженерно-Строительный Институт Им.В.В.Куйбышева
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Новосибирский Ордена Трудового Красного Знамени Инженерно-Строительный Институт Им.В.В.Куйбышева filed Critical Новосибирский Ордена Трудового Красного Знамени Инженерно-Строительный Институт Им.В.В.Куйбышева
Priority to SU813364096A priority Critical patent/SU1010045A1/en
Application granted granted Critical
Publication of SU1010045A1 publication Critical patent/SU1010045A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/34Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/38Fibrous materials; Whiskers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Paper (AREA)

Abstract

СЫРЬЕВАЯ СМЕСЬ ДЛЯ ИЗГОТОВЛЕНИЯ ТЕПЛОИЗОЛЯЦИОННЫХ ИЗДЕЛИЙ, включающа  доломитомерх листое волокно, алюмохромофосфатное св зующее и бутадиен-стирольный латекс СКС-65, отличаюша с  тем, что, с целью повышени  прочности, она дополнительно содержит поливиниладетатную эмульсию при следующем соотношении компонентов, мае. %: Доломитомергелистое волокно75-92 Алюмохромофосфат- ное св зующее4,5-13 Бутадиен-стирольный латекс CKG-652-8 Поливинилацетатна  эмульси 1,5-4 %RAW MIXTURE FOR THE MANUFACTURE OF HEAT-INSULATING PRODUCTS, including dolomitem sheet fiber, aluminum-chromophosphate binder and styrene-butadiene-styrene latex, is different from the fact that, in order to increase strength, it additionally contains a polyvinyladetate emulsion, which contains a composition that contains a polyvinyl acetate emulsion that contains a composition, which contains a polyvinyl acetate emulsion, which contains a polyvinyl acetate emulsion, which contains a polyvinyl acetate emulsion that contains a polyvinyl acetate emulsion that contains a polyvinyl acetate emulsion that contains a polyvinyl acetate emulsion that contains a polyvinyl acetate emulsion that contains a polyvinyl acetate emulsion that contains a polyvinyl acetate emulsion that contains a polyvinyl acetate emulsion. %: Dolomomergelous fiber 75-92 Alumochromophosphate binder 4,5-13 Styrene butadiene CKG-652-8 Polyvinyl acetate emulsion 1.5-4%

Description

NUNU

СП Изобретение относитс  к cTpoirrenbным материалам, а более конкретно к составам дл  изготовлени  теплоизол  онных изделий. HsteecTeH состав дл  изготовлени  теплоизол ционных изделий, включающий , мае. %: каолиновое волокно (7090 ) и алюмохромофосфатное св зу щее (10-30) 1 . Однако издели  из этого состава имеют недостаточные морозо- и химическую стойкость, что ухудшает эксплу атационные показатели изделий. Известна сырьева  смесь дл  изготовлени  теплоизол ционных изделий, включающа , мае. % доломитомергелис тое волокно (75-92); алюмохромофос фатное св зующее (5,5-15) и бутадие с ирольный латекс СКС-65 (2,510 ) t2j . Издели  из этой смеси имеют недо точную прочность. Целью изофетени   вл етс  повыш ние прочности теплоизол ционных изде лий. Поставленна  цепь достигаетс  тем что сырьева  смесь дл  изготовлени  теплоизол ционных изделий, включающа доломитомергелистое волокно, алюмохр фосфатное св зующее и бутадиен-стирольный латекс СКС-65, дополнительн содержит полнвиниладетаггную эмульсию при следукщем соотношении компонентов , мае. %: Доломитомергелистое ВОЛОКНО75-92 Алкжюхромофосфатное св зующее4,5-13 Бутади ен-с тирольный латекс СКС-65 2-8 Поливишшацетатн а  эмульси 1,5-4 Образцы теплоизол ционного издели из предлагаемой смеси изготавливают следукщим образом. В смеситель зали вают 5О%-ную водную эмульсию апщум хромфосфатного св з ощего (АХФС), бутадиен-стирольный латекс СКС-65, 4S поливиниладетатную эмульбию и перемешттают в течение 4 мин. Затем полученный раствор пульверизацией вврд т в минераловатныи ковер из доломитомер гелистого Волокна следующего химического состава: SiOj. 46,94; А6а.0з 18,8; Ре2рз5,22; СаО 23,4; МрО 1,52; ,54; К.рз2.58. Пропитанный св зующим минераловат ный ковер подвергают тепловой обработ ке путем прососа теплоносител  с темпе-, ратурой 18О®С в течение 1О-15 мин. Конкретные примеры сосхгавов предлагаемой и известной сырьевой смеси дл  изготовлении теплоизол ционных изделий указаны в табл. 1. Физико-технические показатели издели  из предлагаемой и известной сырьевой смеск указаны в табл. 2. Из табл. 1 и 2 следует, что оптимальным составом предлагаемой сырьевой смеси  вл ютс  составы 2-4. Издели  из сырьевой смеси составов .1 и 5 имеют ухудшение физико-механических показателей. Эго объ сн етс  тем, что в составе 1 указанного количества св зующего недостаточно дл  покрыти  минераловатного ковра ид доломитомергелистого волокна, что и приводит к уменьшению адгезии ме сду волокном и св зующим; в составе 5 излишнее количество св зующего приводит к разрушению образцов изделий по затвердевшему св зующему , которое без необходимого количества Волокон так же имеет низкие адгезионные свойства. Поливинилацетатна  эмульси  в предлагаемой сырьевой смеси дл  изготовлени  теплоизол ционных изделий повыщает пластические деформации пленки во врем  ее усадки и снижает температуру остекловывани  св зующего, что и позвол ет уменьшить внутренние напр жени  и увеличить прочность и долговечность изделий . Из табл. 2 следует, что прочность при сжатии изделий из предлагаемой сырьевой смеси превышает прочность изделий из известной смеси.The invention relates to cTpoirrenb materials, and more specifically to compositions for the manufacture of thermal insulation products. HsteecTeH composition for the manufacture of thermal insulation products, including May. %: kaolin fiber (7090) and aluminum-chromophosphate binder (10-30) 1. However, products of this composition have insufficient frost and chemical resistance, which impairs the operational performance of products. The known raw material mixture for the manufacture of thermal insulation products, including May. % dolomitomergel fiber (75-92); alumos-chromophos phate binder (5.5-15) and butadiene with irolic latex SKS-65 (2.510) t2j. Products from this mixture have inadequate strength. The purpose of izofeteniya is to increase the strength of thermal insulation products. The delivered chain is achieved by the fact that the raw material mixture for the manufacture of thermal insulation products, including dolomite gelgel fiber, aluminum phosphate binder, and styrene-butadiene-styrene latex, SKS-65, additionally contains a full-vintable emulsion with the following ratio of components, May. %: Dolomitomergelous FIBER 75-92 Alkzhuhromofosfatnogo binder 4.5–13 Butadiene en-tyrol latex SKS-65 2-8 Polyvish acetate and emulsion 1.5–4 Samples of the heat-insulating product are made of the proposed mixture as a result. A 5O% aqueous emulsion of apchum chromophosphate coupling (AHFS), styrene-butadiene-styrene latex SKS-65, 4S, polyvinylaminetate emulsion is poured into the mixer and mixed for 4 minutes. Then, the resulting solution by spraying of the mineral wool into the mineral wool carpet made of dolomitomer of gelled fiber of the following chemical composition: SiOj. 46.94; A6a.0z 18.8; Pe2pz5,22; CaO 23.4; MRO 1.52; , 54; K.rz2.58. The mineral wool carpet impregnated with a binder is heat treated by heating the substrate with a temperature of 18 ° R for 1 0 –15 min. Specific examples of the proposed and known raw material mixtures for the manufacture of thermal insulation products are listed in Table. 1. Physical and technical indicators of the product from the proposed and known raw mix are shown in Table. 2. From table. 1 and 2, it follows that the optimal composition of the proposed raw mix is 2-4. Products made from raw mixes of compositions .1 and 5 have a deterioration in physico-mechanical parameters. This is explained by the fact that, in the composition of 1, the specified amount of the binder is not enough to cover the mineral wool of the id of dolomitomergel fiber, which leads to a decrease in the adhesion between the fiber and the binder; in composition 5, an excess amount of binder leads to the destruction of product samples by the hardened binder, which, without the required amount, Fibers also has low adhesive properties. The polyvinyl acetate emulsion in the proposed raw material mixture for the manufacture of thermal insulation products increases the plastic deformation of the film during its shrinkage and reduces the vitrification temperature of the binder, which reduces internal stresses and increases the strength and durability of the products. From tab. 2 it follows that the compressive strength of products from the proposed raw material mixture exceeds the strength of products from a known mixture.

ТаблицаTable

ТЭ бпиц 2TE Bpits 2

Claims (1)

СЫРЬЕВАЯ СМЕСЬ ДЛЯ ИЗГОТОВЛЕНИЯ ТЕПЛОИЗОЛЯЦИОННЫХRAW MATERIAL MIXTURE FOR THE PRODUCTION OF HEAT-INSULATING ИЗДЕЛИЙ, включающая доломитомергелистое волокно, алюмохромофосфатное связующее и бутадиен-стирольный латекс СКС-65, отличающаяся тем, чго, с · целью повышения прочности, она дополнительно содержит поливинилацетнтную эмульсию при следующем соотношении компонентов, мае. %:PRODUCTS, including dolomite-mergel fiber, aluminochromophosphate binder and styrene-butadiene latex SKS-65, characterized in that, in order to increase the strength, it additionally contains a polyvinyl acetate emulsion in the following ratio of components, May. %: Доломитомергелистое Dolomite mergelaceous волокно fiber 75-92 75-92 Алюмохромофосфат- Alumochromophosphate - ное связующее new binder 4,5-13 4,5-13 Бутадиен-стирольный Styrene butadiene латекс СКС-65 Поливинилацетатная latex SKS-65 Polyvinyl acetate 2-8 2-8 эмульсия emulsion 1,5-4 1,5-4 ω ω с *•4 ** from *•4 **
сл >next>
SU813364096A 1981-12-17 1981-12-17 Raw mix for making heat insulating products SU1010045A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU813364096A SU1010045A1 (en) 1981-12-17 1981-12-17 Raw mix for making heat insulating products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU813364096A SU1010045A1 (en) 1981-12-17 1981-12-17 Raw mix for making heat insulating products

Publications (1)

Publication Number Publication Date
SU1010045A1 true SU1010045A1 (en) 1983-04-07

Family

ID=20986052

Family Applications (1)

Application Number Title Priority Date Filing Date
SU813364096A SU1010045A1 (en) 1981-12-17 1981-12-17 Raw mix for making heat insulating products

Country Status (1)

Country Link
SU (1) SU1010045A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009016288A3 (en) * 2007-06-28 2009-06-25 Koramic Tuiles Use of a phosphate and/or phosphonate compound in a clay composition to prevent or limit the formation of sulphate-based efflorescences

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
1. Авторское свидетельство СССР № 477149. кп. С 04 В 43/О2, 1972. 2. Авторское свидетельство СССР № 895969, кл. С 04 В 43/О2, 1979 (прототип). *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009016288A3 (en) * 2007-06-28 2009-06-25 Koramic Tuiles Use of a phosphate and/or phosphonate compound in a clay composition to prevent or limit the formation of sulphate-based efflorescences

Similar Documents

Publication Publication Date Title
US4132555A (en) Building board
KR100781338B1 (en) Gypsum plaster base board and preparation thereof
KR870008805A (en) Lightweight insulation board and method of manufacturing the same
US20030138614A1 (en) Plasterboard composition, preparation of this composition and manufacture of plasterboards
EP0420302A1 (en) Fire-retardant additives and their uses
SU1010045A1 (en) Raw mix for making heat insulating products
US5053282A (en) Non-inflammable insulating composite material
EP0466754B2 (en) Insulating product of mineral fibre wool, intended in particular for heat insulation of pipes, and method for making this product
EP0004846A1 (en) Heat resistant composition and method for preparation of a core for doors or panels by using said composition
CN1113898A (en) Inorganic composite insulating material and its making method
US5110084A (en) Form device for cellular concrete and method of making such concrete
JPH02267148A (en) Production of gypsum board
CN1834185A (en) Fire-proof mixed adhesive
SU753824A1 (en) Raw mixture for producing heat-insulating articles
US1901984A (en) Process of making heat insulating bodies
RU2147593C1 (en) Difficultly combustible thermoplast-based composite material
RU2151755C1 (en) Raw mix for preparing phosphate binder
SU1379269A1 (en) Compound for producing thermal insulation articles
SU1756304A1 (en) Composition for manufacturing mineral wool products
SU895969A1 (en) Mixture for producing heat insulation articles
SU1698230A1 (en) Method of manufacture of non-combustible fiber board
SU1313838A1 (en) Method for manufacturing heat-protecting coating
CA1336335C (en) Non-inflammable insulating composite material
SU1724639A1 (en) Ceramic body
SU1351908A1 (en) Method of preparing raw mixure for construction articles