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RU2018123315A - Многослойное остекление, содержащее чувствительный к давлению адгезив - Google Patents

Многослойное остекление, содержащее чувствительный к давлению адгезив Download PDF

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Publication number
RU2018123315A
RU2018123315A RU2018123315A RU2018123315A RU2018123315A RU 2018123315 A RU2018123315 A RU 2018123315A RU 2018123315 A RU2018123315 A RU 2018123315A RU 2018123315 A RU2018123315 A RU 2018123315A RU 2018123315 A RU2018123315 A RU 2018123315A
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Prior art keywords
sheet
glazing
pressure
multilayer
sensitive adhesive
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RU2018123315A
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English (en)
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RU2018123315A3 (ru
RU2726536C2 (ru
Inventor
Цзя-Мэй СУН
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Сэн-Гобэн Гласс Франс
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    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10807Making laminated safety glass or glazing; Apparatus therefor
    • B32B17/10816Making laminated safety glass or glazing; Apparatus therefor by pressing
    • B32B17/10871Making laminated safety glass or glazing; Apparatus therefor by pressing in combination with particular heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
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    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165Functional features of the laminated safety glass or glazing
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    • B32B17/10165Functional features of the laminated safety glass or glazing
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    • B32B17/10467Variable transmission
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    • B32B17/10522Electrophoretic layer
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    • B32B17/10165Functional features of the laminated safety glass or glazing
    • B32B17/10431Specific parts for the modulation of light incorporated into the laminated safety glass or glazing
    • B32B17/10467Variable transmission
    • B32B17/10495Variable transmission optoelectronic, i.e. optical valve
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    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
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    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/1077Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyurethane
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    • B32B17/10788Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B17/10807Making laminated safety glass or glazing; Apparatus therefor
    • B32B17/10899Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin
    • B32B17/10935Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin as a preformed layer, e.g. formed by extrusion
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    • B32B17/10807Making laminated safety glass or glazing; Apparatus therefor
    • B32B17/10972Degassing during the lamination
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
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    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/416Reflective
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Liquid Crystal (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)

Claims (39)

1. Многослойное остекление, содержащее
первый стеклянный лист (1);
по меньшей мере один лист-прослойку (3) из термопластичного полимера;
опционально «солнцезащитный» лист (4) или функциональный металлический слой со свойствами отражения в инфракрасной области и/или в области солнечного излучения;
по меньшей мере один лист из чувствительного к давлению адгезива (5), находящийся в прямом контакте с термочувствительным функциональным листом (6);
второй стеклянный лист (2);
причем упомянутый первый стеклянный лист (1) находится в прямом контакте с упомянутым листом-прослойкой (3);
упомянутый второй стеклянный лист (2) находится в прямом контакте с упомянутым листом из чувствительного к давлению адгезива (5);
упомянутый лист из чувствительного к давлению адгезива (5) и упомянутый второй стеклянный лист (2) находятся в прямом контакте на внутренней поверхности этого второго стеклянного листа (2).
2. Многослойное остекление по п. 1, последовательно содержащее
первый стеклянный лист (1),
лист-прослойку (3) из термопластичного полимера,
опционально «солнцезащитный» лист (4) или функциональный металлический слой со свойствами отражения в инфракрасной области и/или в области солнечного излучения,
первый лист из чувствительного к давлению адгезива (5),
термочувствительный функциональный лист (6),
второй лист из чувствительного к давлению адгезива (5),
второй стеклянный лист (2).
3. Многослойное остекление по любому из предшествующих пунктов, в котором термопластичный полимер листа-прослойки (3) выбран из поливинилбутираля, полиуретана, этиленвинилацетата и иономеров.
4. Остекление по любому из предшествующих пунктов, в котором термопластичный полимер листа-прослойки (3) представляет собой ПВБ.
5. Многослойное остекление по любому из предшествующих пунктов, в котором чувствительный к давлению адгезив выбран из чувствительных к давлению адгезивов на основе акрилатов и чувствительных к давлению адгезивов на основе силикона.
6. Многослойное остекление по любому из предшествующих пунктов, в котором термочувствительный функциональный лист (6) выполнен на основе инкапсулированных жидких кристаллов, электрофоретических частиц, диспергированных в носителе, частиц, диспергированных в электрофоретической текучей среде, или частиц для поляризации света.
7. Многослойное остекление по любому из предшествующих пунктов, в котором «солнцезащитный» лист выполнен из серебра или любого другого металла, имеющего светоотражающие свойства, или из металла или соединения металла, имеющего светопоглощающие свойства.
8. Многослойное остекление по любому из предшествующих пунктов, отличающееся тем, что оно является плоским или изогнутым.
9. Многослойное остекление по любому из предшествующих пунктов, отличающееся тем, что оно представляет собой остекление транспортного средства, выбранное из ветрового стекла, переднего бокового остекления, заднего бокового остекления, заднего стекла и остекления крыши.
10. Многослойное остекление по любому из предшествующих пунктов, отличающееся тем, что оно представляет собой остекление транспортного средства, выбранного из автомобиля, поезда, грузовика, самолета и автобуса.
11. Способ изготовления многослойного остекления по любому из предшествующих пунктов, в котором этапы установки различных листов осуществляют, начиная (i) с установки листа-прослойки (3) из термопластичного полимера на внутреннюю сторону первого стеклянного листа (1), начиная (ii) с установки листа из чувствительного к давлению адгезива (5) на внутреннюю сторону второго стеклянного листа (2) или начиная (iii) с установки листа из чувствительного к давлению адгезива (5) на по меньшей мере одну из двух сторон термочувствительного функционального листа (6).
12. Способ изготовления многослойного остекления по предыдущему пункту, содержащий
по меньшей мере один этап установки листа-прослойки (3) из термопластичного полимера на внутреннюю сторону первого стеклянного листа (1), опционально предварительно изогнутого, и опционально установку «солнцезащитного» листа (4) на оставшуюся свободной сторону упомянутого листа-прослойки (3), который таким образом оказывается проложенным между упомянутым первым стеклянным листом (1) и упомянутым опциональным «солнцезащитным» листом (4), образуя первый частичный многослойный материал (7), и/или
по меньшей мере один этап установки первого и/или второго листа из чувствительного к давлению адгезива (5) на по меньшей мере одну из двух сторон термочувствительного функционального листа (6).
13. Способ по п. 11 или 12, в котором первый лист из чувствительного к давлению адгезива (5) располагают на первой стороне термочувствительного функционального листа (6), а второй лист из чувствительного к давлению адгезива (5) располагают на оставшейся свободной второй стороне упомянутого термочувствительного функционального листа (6), получая второй частичный многослойный материал (8).
14. Способ по п. 13, в котором второй частичный многослойный материал (8) укладывают одной из его чувствительных к давлению адгезивных сторон (5) на или под первый частичный многослойный материал (7), либо прямо на свободную сторону его листа из термопластичного полимера, или опционально на свободную сторону «солнцезащитного» листа (4), если он присутствует, этого первого частичного многослойного материала (7), а второй стеклянный лист (2), опционально предварительно изогнутый, укладывают его внутренней стороной на или под сторону получившегося многослойного материала, противоположную той стороне первого стеклянного листа (1), которая осталась свободной.
15. Способ по п. 13, в котором второй стеклянный лист (2), опционально предварительно изогнутый, укладывают его внутренней стороной на или под одну из сторон упомянутого второго частичного многослойного материала (8), формируя третий частичный многослойный материал (9).
16. Способ по п. 15, в котором упомянутый третий частичный многослойный материал (9) устанавливают его чувствительной к давлению адгезивной поверхностью (5) на или под первым частичным многослойным материалом (7), или прямо на свободной стороне его листа из термопластичного полимера (3) или опционально на свободной стороне его «солнцезащитного» листа (4), если он присутствует.
17. Способ изготовления многослойного остекления по любому из пп. 11-16, дополнительно содержащий по меньшей мере
этап удаления газов из получившегося многослойного материала под вакуумом с использованием периферийного уплотнения или вакуумного мешка,
опционально этап термосварки краев упомянутого многослойного материала, и
этап обработки в автоклаве.
18. Способ изготовления многослойного остекления по любому из пп. 11-16, дополнительно содержащий по меньшей мере один этап каландрирования, опционально этап горячего каландрирования.
19. Применение остекления по любому из пп. 1-10 для изготовления остекления транспортного средства, выбранного из ветрового стекла, переднего бокового остекления, заднего бокового остекления, заднего стекла и остекления крыши, и/или для изготовления остекления для транспортного средства, выбранного из автомобиля, поезда, грузовика, летательного аппарата и автобуса.
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